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Morphodynamics of Bedrock Rivers 基岩河流的形态动力学
IF 14.9 1区 地球科学 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2025-12-09 DOI: 10.1146/annurev-earth-040523-023051
Jeremy G. Venditti
Landscapes are shaped by the interaction of tectonics, climate, and rock erosion dynamics. Active incision in bedrock rivers sets the pace of landscape evolution because river incision cuts deep valleys and canyons into bedrock, transporting that material to the sea. This unburdens Earth's surface, allowing uplift of majestic mountain peaks in tectonically active settings. Bedrock-bound rivers, where the banks and bed are mostly bedrock, are hard points in the landscape that set the upstream base level of drainage basins and that must be vertically incised to lower landscape elevation and balance erosion against tectonic uplift. There are four distinct bedrock-bound channel morphologies that do not occur in alluvial channels—constriction-pool-widenings, rapids, overfalls, and waterfalls—each of which has a distinct flow structure. Our ability to predict bedrock-bound channel morphodynamics is nascent, but the discovery of mechanistic lateral bedrock erosion models, coupled with existing vertical incision models, allow prediction of bedrock river geometry and adjustments due to changes in water flux, sediment supply, and regional uplift. Coupled lateral and vertical erosion models reveal that the geometry of bedrock rivers is dominantly controlled by sediment supply, not discharge. Coupling observations of nonuniform flow structures and erosion models confirm that bedrock-bound channels are loci of intense erosion along a river's profile. Prediction of the 3D shape of bedrock-bound rivers is possible by combining models for flow, sediment transport, and bedrock erosion. Morphodynamic predictions are limited by poor understanding of nonuniform flow structures, flow resistance, and sediment transport in bedrock-bound channels.
地形是由构造、气候和岩石侵蚀动力学的相互作用形成的。基岩河流的活跃切口决定了景观演变的速度,因为河流切口将深谷和峡谷切割成基岩,将这些物质输送到海洋中。这减轻了地球表面的负担,在构造活跃的环境中,雄伟的山峰得以隆起。基岩河流,其河岸和河床大部分是基岩,是景观中的硬点,它设置了流域上游的基准面,必须垂直切割以降低景观高程,平衡侵蚀和构造隆起。在冲积河道中,有四种不同的基岩边界河道形态——收缩-池-加宽、急流、溢流和瀑布——每一种都有不同的流动结构。我们预测基岩边界河道形态动力学的能力尚处于起步阶段,但机械侧基岩侵蚀模型的发现,加上现有的垂直切口模型,可以预测基岩河流的几何形状,以及由于水通量、沉积物供应和区域隆起的变化而进行的调整。横向和纵向耦合侵蚀模型表明,基岩河流的几何形状主要受泥沙供应而非流量控制。▪对非均匀流动结构和侵蚀模型的耦合观测证实,基岩束缚的河道是河流剖面上强烈侵蚀的地点。▪结合水流、泥沙运输和基岩侵蚀模型,可以预测基岩河流的三维形状。▪形态动力学预测受到不均匀流动结构、流动阻力和基岩通道中沉积物运移的限制。
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引用次数: 0
The Mechanics of Multiphase Magmas: A Perspective from the Scale of Crystals and Bubbles to Magma Reservoirs 多相岩浆的力学:从晶体和气泡尺度看岩浆储层
IF 14.9 1区 地球科学 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2025-11-26 DOI: 10.1146/annurev-earth-032524-124419
Christian Huber, Olivier Bachmann, Darien Florez, E.M. Parmentier, Matěj Peč, Jonas Latt, Maxime Rambosson, Uthkarsh Das
The interplay between melt, crystals, andvolatile bubbles controls the physical properties of magmas in Earth's crust, the rate of phase separation, and, by extension, chemical differentiation. The mechanical processes that couple crystals, bubbles, and melt are nonlinear, and their expression in magmatic systems can vary greatly with the relative phase proportions in the magma. In this review we propose a multiscale perspective on multiphase magmas under crustal storage conditions, with a specific focus on phase separation mechanisms. We start with an inventory of forces acting on a single crystal or volatile bubble in a silicate melt. We follow with a discussion of different upscaling strategies to simplify the description of the dynamics at greater scales, relevant to the evolution of magma reservoirs.We discuss recent progress in the development of models to study the internal dynamics of magma reservoirs, highlight current challenges, and propose possible paths for further progress. The mechanical interaction between the constituents (melt, crystals, and bubbles) at the scale of crystals controls the properties of magmas. The choice of upscaling strategy is controlled by the processes that are considered. Melt-crystal separation processes and their efficiency vary with the relative proportion of the phases involved. Melt extraction by repacking is fast compared to compaction but stalls as the mush reaches the maximum packing.
熔体、晶体和挥发性气泡之间的相互作用控制着地壳中岩浆的物理性质、相分离的速率,进而控制着化学分异。结晶、气泡和熔体耦合的力学过程是非线性的,它们在岩浆系统中的表现随岩浆相对相比的不同而变化很大。本文从多尺度的角度对地壳储存条件下的多相岩浆进行了研究,重点讨论了相分离机制。我们首先列出作用在硅酸盐熔体中单晶或挥发性气泡上的力。我们随后讨论了不同的升级策略,以简化与岩浆储层演化相关的更大尺度动力学的描述。我们讨论了研究岩浆储层内部动力学模型的最新进展,强调了当前的挑战,并提出了进一步发展的可能途径。▪在晶体尺度上,各成分(熔体、晶体和气泡)之间的机械相互作用控制着岩浆的性质。▪升级战略的选择由所考虑的过程控制。熔融晶体分离过程及其效率随所涉及相的相对比例而变化。与压实相比,通过重新填料进行熔体提取速度快,但当糊状物达到最大填料时,熔体提取速度会减慢。
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引用次数: 0
A Practical Guide to Phylogenetic Paleoecology 系统发育古生态学实用指南
IF 14.9 1区 地球科学 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2025-11-25 DOI: 10.1146/annurev-earth-032524-011040
James C. Lamsdell, Sarah L. Sheffield, Amanda R. Falk
The burgeoning field of phylogenetic paleoecology combines paleoecological data with hypotheses of phylogenetic relationships to tease apart the roles that ecology and relatedness both play in the evolution and function of an organism. The purpose of this review is to make phylogenetic paleontology more accessible to a wider array of scientists and attract new researchers to the discipline. Herein, we use recently published analyses of a diverse array of fossil animals (e.g., arthropods, echinoderms, and carnivorans) to better illustrate the breadth of research questions that can be studied using phylogenetic paleoecology. Phylogenetic paleoecology has been used to discern drivers of morphological change and variations in evolutionary rates, along with the relationship between phylogeny, biogeography, and ecology. Additional avenues of research could focus on modularity and mosaicism in evolution, as well as the impact of mass extinctions and adaptive radiations. By encouraging a greater diversity of scientific backgrounds and plurality of thought, and by incorporating new perspectives from different areas of both geology and biology, the field of phylogenetic paleoecology will lead to the consideration of new questions, avenues, and possibilities that would otherwise go unexplored.
系统发育古生态学这一新兴领域将古生态学数据与系统发育关系假说结合起来,梳理出生态学和亲缘关系在生物进化和功能中所扮演的角色。这篇综述的目的是使系统发育古生物学更容易为更广泛的科学家所接受,并吸引新的研究人员加入这一学科。在此,我们使用最近发表的各种动物化石(如节肢动物、棘皮动物和食肉动物)的分析来更好地说明可以使用系统发育古生态学来研究的研究问题的广度。系统发育古生态学已被用来辨别形态变化和进化速率变化的驱动因素,以及系统发育、生物地理学和生态学之间的关系。其他研究途径可以集中在进化中的模块化和镶嵌现象,以及大规模灭绝和适应性辐射的影响。通过鼓励科学背景的更大多样性和思想的多元化,并通过结合来自地质学和生物学不同领域的新观点,系统发育古生态学领域将导致对新问题、新途径和新可能性的考虑,否则这些问题、新途径和新可能性将得不到探索。
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引用次数: 0
Science and Society's Views of the Anthropocene 科学与社会对人类世的看法
IF 14.9 1区 地球科学 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2025-11-21 DOI: 10.1146/annurev-earth-032524-010346
Melissa Charenko
Stratigraphers’ recent vote to reject the Anthropocene as a geological epoch could have consequences beyond geology, as many other disciplines have adopted the term. This review focuses on the potential effects of this negative vote on the humanities and social sciences by drawing on perspectives from science and society. It argues that stratigraphers’ negative vote is likely to have little effect on other disciplines because most humanists and social scientists are not using the stratigraphic term. Instead, they understand the Anthropocene as shorthand for human-caused environmental change, which is clearly occurring. Humanists and social scientists also remain interested in the Anthropocene because the collapsing distinction between the human and the geological continues to present challenges worth engaging with. While the diverse interpretations and engagements with the Anthropocene may result in incoherence, this review summarizes literature that suggests that this plurality of meanings is what gives the Anthropocene concept its strength.The Anthropocene is likely to remain a key concept in the humanities and social sciences, despite stratigraphers’ rejection of the epoch. The Anthropocene means different things to different disciplines. These multiple meanings are likely to persist. A plurality of meanings and usages of the Anthropocene captures how knowledge is produced and may spur environmental solutions.
地层学家最近投票反对将人类世作为一个地质时代,这可能会产生地质学以外的影响,因为许多其他学科都采用了这个术语。本文将从科学和社会的角度出发,重点讨论这一否决投票对人文社会科学的潜在影响。它认为,地层学家的反对票可能对其他学科影响不大,因为大多数人文主义者和社会科学家都不使用地层学术语。相反,他们把人类世理解为人类引起的环境变化的简称,而这种变化显然正在发生。人文主义者和社会科学家也对人类世保持着兴趣,因为人类和地质之间逐渐消失的区别继续提出值得参与的挑战。虽然对人类世的不同解释和参与可能会导致不连贯,但本文总结的文献表明,这种多元化的含义正是赋予人类世概念力量的原因。人类世很可能仍然是人文和社会科学的一个关键概念,尽管地层学家拒绝接受这个时代。▪人类世对不同的学科有不同的意义。这些多重含义可能会持续下去。▪人类世的多种含义和用法反映了知识是如何产生的,并可能刺激环境解决方案。
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引用次数: 0
Petrological Constraints on the Thermal History of Magma Storage in the Crust 地壳岩浆储存热史的岩石学约束
IF 14.9 1区 地球科学 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2025-11-11 DOI: 10.1146/annurev-earth-032524-113641
Kari M. Cooper, Adam J.R. Kent
Understanding the links between magmatic evolution and volcanic eruptions requires knowledge of the physical behavior of magmas stored and transported within Earth's crust. The mobility of magmas is fundamentally tied to their rheology and therefore the temperatures they experience during residence—their thermal history. We review petrological and other constraints on magma thermal histories that silicic magmas experience during crustal storage. We also focus on the recent debate between cold and warm magma storage models, using a common conceptual framework that allows a more coherent synthesis of magma storage conditions. Evidence suggests that although most silicic crustal magmatic systems spend most of their time in a rheologically immobile state, variations exist in space and time. The recognition of dominantly immobile but variable storage conditions allows us to move beyond a simple dichotomy and to ask more interesting questions about how these variations in magma storage occur and evolve. Understanding the thermal conditions of crustal magma storage is critical to assessing magma mobility and the ability to erupt. We synthesize available information about thermal histories that magmas experience within a common conceptual framework. Most silicic magmas spend most of their time in a rheologically immobile state, but variability exists over time and space within and between magma systems. We can advance our understanding most effectively by focusing on the controls on these variations and implications for magma evolution and eruption.
要了解岩浆演化和火山爆发之间的联系,就需要了解岩浆在地壳内储存和运输的物理行为。岩浆的流动性基本上与它们的流变性有关,因此也与它们在停留期间所经历的温度有关,即它们的热历史。我们回顾了岩石学和其他对岩浆热历史的限制,硅质岩浆在地壳储存过程中经历。我们还关注了最近关于冷岩浆储存模型和热岩浆储存模型之间的争论,使用了一个共同的概念框架,可以更连贯地综合岩浆储存条件。有证据表明,尽管大多数硅质地壳岩浆系统大部分时间处于流变不动状态,但在空间和时间上存在变化。认识到主要的不动但可变的储存条件使我们能够超越简单的二分法,并提出更有趣的问题,即岩浆储存的这些变化是如何发生和演变的。▪了解地壳岩浆储存的热条件对评估岩浆流动性和喷发能力至关重要。▪我们在一个共同的概念框架内综合了关于岩浆经历的热历史的现有信息。大多数硅质岩浆大部分时间处于流变不动状态,但随着时间和空间的变化,岩浆系统内部和岩浆系统之间存在变异性。▪我们可以通过关注对这些变化的控制以及对岩浆演化和喷发的影响来最有效地推进我们的理解。
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引用次数: 0
Molten Salts: Fluid Inclusion Record and Role in Forming Mineral Deposits 熔盐:流体包裹体记录及其在矿床形成中的作用
IF 14.9 1区 地球科学 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2025-11-06 DOI: 10.1146/annurev-earth-040523-023602
Matthew Steele-MacInnis
Fluid inclusions provide a wealth of information on the compositions, temperatures, and other properties of fluids that form mineral deposits. Fluid inclusions representative of aqueous-hydrothermal ore-forming fluids have been studied extensively over many years, and our understanding of their properties is comprehensive. But in recent years, evidence has been mounting for widespread occurrence of novel and unexpected types of fluid inclusions. These fluids are composed of molten alkali-calcic chloride, sulfate, and carbonate components, and they contain little to no H 2 O. Their physical and chemical properties are only starting to be explored, but evidence for their capacity to mobilize certain metals, and their participation in crustal ore-forming processes, is growing. The objectives of this review are to showcase these novel solutions and to discuss their origins and roles in forming mineral deposits. Fluid inclusions in minerals reveal widespread occurrence of natural molten salts. Evidence for molten salts, composed of chloride, sulfate, and carbonate components, is reported in numerous ore deposits. Molten salts are low-viscosity fluids, highly chemically reactive, and capable of transporting high concentrations of critical metals. Molten salts represent a novel and unexpected type of crustal ore-forming fluid.
流体包裹体提供了关于构成矿床的流体的成分、温度和其他性质的丰富信息。以水热液成矿流体为代表的流体包裹体多年来得到了广泛的研究,对其性质的认识较为全面。但近年来,越来越多的证据表明,新型和意想不到的流体包裹体广泛存在。这些流体由熔融的碱-氯化钙、硫酸盐和碳酸盐组成,它们几乎不含h2o。人们对它们的物理和化学性质的探索才刚刚开始,但越来越多的证据表明,它们有能力调动某些金属,并参与地壳成矿过程。这篇综述的目的是展示这些新的解决方案,并讨论它们的起源和在形成矿床中的作用。▪矿物中的流体包裹体显示广泛存在天然熔盐。■据报道,在许多矿床中存在由氯化物、硫酸盐和碳酸盐组成的熔盐。熔融盐是低粘度流体,化学反应性强,能够输送高浓度的关键金属。▪熔盐是一种新的、意想不到的地壳成矿流体。
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引用次数: 0
Volcanoes, Climate, and Society 火山、气候和社会
IF 14.9 1区 地球科学 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2025-06-25 DOI: 10.1146/annurev-earth-032524-013254
Ulf Büntgen, Nicola Di Cosmo, Jan Esper, Michael Frachetti, Lamya Khalidi, Franz Mauelshagen, Eleonora Rohland, Clive Oppenheimer
This review examines the societal ramifications of large volcanic eruptions—not the proximal impacts of lava, ash, pumice, and gaseous emissions but rather the consequences of the climate forcing triggered by dispersal of volcanic sulfate aerosol in the stratosphere. Using ice core records of volcanism and tree-ring data of summer temperature anomalies, we analyze 38 preindustrial eruptions that injected an estimated 6 Tg or more of sulfur into the stratosphere. We then explore more than 100 works that consider the volcanism-climate-society nexus, teasing out the key elements of their arguments for or against the role of volcanically forced climate change in far-field societal impacts. As well as summarizing and interrogating the history of ideas and state of the art on this topic, we hope to stimulate further holistic, interdisciplinary approaches to assess the broader implications of volcanic eruptions, particularly for global food security—both in the past and in the future. There are compelling arguments to consider the role of volcanically forced climate change in explanations of history. Such research requires integration of geographical, ecological, demographic, econometric, and other data with historical sources and narratives, and therefore demands cross-disciplinary conversation. Statistical evidence is needed to attribute weather and climate extremes to volcanic forcing, and agricultural and pastoral responses to climate anomalies must be reconstructed at high spatiotemporal resolution. Several prominent climate forcing eruptions in circa 304, 1182, 1345, and 1453 CE have hitherto received comparatively little attention.
这篇综述考察了大型火山爆发的社会后果——不是熔岩、火山灰、浮石和气体排放的近端影响,而是火山硫酸盐气溶胶在平流层扩散引发的气候强迫的后果。利用火山活动的冰芯记录和夏季温度异常的树木年轮数据,我们分析了38次工业前喷发,这些喷发向平流层注入了大约6 Tg或更多的硫。然后,我们探索了100多部考虑火山-气候-社会关系的作品,梳理出他们支持或反对火山强迫气候变化在远场社会影响中的作用的关键因素。除了总结和询问关于这一主题的思想和现状的历史,我们希望激发进一步的整体,跨学科的方法来评估火山爆发的更广泛的影响,特别是对过去和未来的全球粮食安全的影响。■有令人信服的论据表明,火山喷发导致的气候变化在解释历史时所起的作用。▪此类研究需要将地理、生态、人口、计量经济学和其他数据与历史来源和叙述相结合,因此需要跨学科的对话。▪将极端天气和气候归因于火山强迫需要统计证据,农业和畜牧业对气候异常的反应必须以高时空分辨率重建。在公元304年、1182年、1345年和1453年前后发生的几次突出的气候强迫喷发迄今为止受到的关注相对较少。
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引用次数: 0
Wave Structuring in the Shock Compression of Geologic Matter at the Planetary and Laboratory Scales 行星和实验室尺度下地质物质激波压缩中的波结构
IF 14.9 1区 地球科学 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2025-05-30 DOI: 10.1146/annurev-earth-040523-124246
Dennis Grady
The response of geologic matter when subjected to large-scale impact or explosion is dependent on the time history of the encompassing shock wave. The kinetics of localized physical and chemical transitions brought about by the shock wave are responsive to this time history. Solid-state viscosity of the media is responsible for establishing the time history of a shock wave. In 2003, researcher H. Jay Melosh recognized the need for an understanding of solid viscosity spanning the petrologic and lithologic scales, and accordingly, he undertook the assessment and analysis of available nuclear ground shock measurements. This review furthers Melosh's epic efforts. In pursuing both the nuclear ground shock data and supporting laboratory test data, it undertakes methods for determining and calculations of the viscosity of solid materials on the respective scales. Further, applicability of viscoelasticity in modeling the shock response on the scales of concern is demonstrated and applied. The review closes with a discussion of universal features of the shock wave viscous time history in solid materials. Solid viscosity as an adiabatic invariant is presented, and commonalties of the solid shock wave with the nonlinear dynamics of ocean waves are noted. This article reviews Melosh's analysis of nuclear ground shock measurements with application to shock wave structuring viscosity. It discusses viscoelastic calculations with application to wave structure of nuclear ground shocks and laboratory shock waves in brittle granular solids, and universal features of the viscous shock wave structure and invariance of the dissipative action are considered. It also discusses wave action invariance in both the nonlinear dynamics of ocean waves and the steady wave structure of shock waves in solid matter.
地质物质在遭受大规模撞击或爆炸时的反应取决于周围冲击波的时程。激波引起的局部物理和化学转变动力学响应于这一时间历史。介质的固体粘度是建立激波时程的原因。2003年,研究人员H. Jay Melosh认识到有必要了解岩石学和岩性尺度上的固体粘度,因此,他对可用的核地面冲击测量进行了评估和分析。这篇评论进一步推动了米洛什史诗般的努力。在研究核地面冲击数据和辅助实验室测试数据时,它采用了在各自尺度上确定和计算固体材料粘度的方法。此外,粘弹性模型在关注尺度上的冲击响应建模中的适用性得到了证明和应用。最后讨论了固体材料中激波黏性时程的普遍特征。提出了固体粘度作为绝热不变量,并指出了固体激波与海浪非线性动力学的共性。▪本文回顾了Melosh对核地面冲击测量的分析,并将其应用于冲击波结构粘度。■讨论了粘弹性计算在脆性颗粒固体中核地面冲击和实验室冲击波波结构中的应用,并考虑了粘性冲击波结构的普遍特征和耗散作用的不变性。▪它还讨论了海浪的非线性动力学和固体物质中激波的稳定波结构中的波作用不变性。
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引用次数: 0
Submarine Volcanic Eruptions and Their Impacts on Hydrothermal Systems and Biological Communities 海底火山喷发及其对热液系统和生物群落的影响
IF 14.9 1区 地球科学 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2025-05-30 DOI: 10.1146/annurev-earth-040522-095654
Rebecca J. Carey, David A. Butterfield, Malcolm R. Clark
More than 70% of Earth's magmatic output occurs in the ocean. This volcanism shapes major features of the seafloor, directly impacts the chemical composition of the oceans through water/rock interactions, and drives hydrothermal circulation of seawater. The formation of seafloor mineral deposits and chemosynthetic habitats that encircle the globe along mid-ocean ridges, volcanic arcs, and hotspots is driven by volcanism. The style, magnitude, depth, and frequency of seafloor eruptions create a wide range of physical, chemical, and biological impacts on the seafloor. Research and exploration over the past 30 years have revealed some of the diversity of seafloor eruptions and their impact on the undersea environment. Submarine eruptions are simultaneously the most common and the least observed form of volcanism on Earth. Hydrostatic pressure at the vent depth modulates explosive versus effusive eruption and the form of eruptive behavior. Submarine eruptions have significant impacts on marine biological communities and chemical fluxes to the ocean. Resilience of fauna to eruption events is also variable, and recovery dynamics can be slow with many years or decades required for communities to reform.
地球上70%以上的岩浆都来自海洋。这种火山活动塑造了海底的主要特征,通过水/岩石的相互作用直接影响海洋的化学成分,并推动了海水的热液循环。海底矿藏和化学合成栖息地的形成沿着大洋中脊、火山弧和热点环绕地球,是由火山活动驱动的。海底喷发的形式、强度、深度和频率对海底产生了广泛的物理、化学和生物影响。过去30年的研究和探索揭示了海底喷发的一些多样性及其对海底环境的影响。■海底喷发是地球上最常见的火山活动,同时也是最少被观测到的火山活动。▪喷口深度的静水压力调节爆炸性喷发与喷涌性喷发以及喷发行为的形式。▪海底喷发对海洋生物群落和流入海洋的化学物质有重大影响。▪动物群对火山爆发事件的恢复能力也是多变的,恢复动态可能缓慢,群落需要多年或数十年的时间进行改革。
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引用次数: 0
Experimental Thermochemistry Through the Years with Application to Chalcogenides 多年来的实验热化学及其在硫属化合物中的应用
IF 14.9 1区 地球科学 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2025-05-30 DOI: 10.1146/annurev-earth-041023-094742
Alexandra Navrotsky, Manuel Scharrer
Chalcogenides (sulfides, selenides, tellurides, arsenides, antimonides) are important in natural processes, including formation of ore deposits on Earth, early stages of planetary accretion, and formation of condensates in planetary atmospheres. Their physicochemical properties render them suitable for a wide range of industrial applications. While thermodynamic data are available for many endmembers, there are significant gaps in both thermodynamic and associated structural constraints, especially for complex systems. The continuous evolution of high temperature calorimetry into oxidative drop solution calorimetry has facilitated the measurement of enthalpies of formation and mixing and surface energies involving nonoxides, including chalcogenides. These are essential for modeling processes in nature and technology and for understanding the underlying properties that define their stabilities. This article reviews the development of these calorimetric techniques and summarizes available thermochemical data for common chalcogenides. Over the last century, calorimetric instruments and techniques have evolved to enable accurate measurement of a wide range of materials, including chalcogenides. Despite the growing interest in the thermodynamic characterization of chalcogenides, a systematic review of the available data indicates that there is still a significant scope for further research. A systematic understanding of chalcogenides will facilitate the modeling of geological environments and enable the prediction and improvement of geo-inspired materials for industrial applications.
硫属化合物(硫化物、硒化物、碲化物、砷化物、锑化物)在自然过程中很重要,包括地球上矿床的形成、行星吸积的早期阶段以及行星大气中凝析物的形成。它们的物理化学性质使它们适用于广泛的工业应用。虽然许多端元的热力学数据是可用的,但在热力学和相关结构约束方面存在重大差距,特别是对于复杂系统。高温量热法不断演变为氧化滴液量热法,这使得包括硫族化合物在内的非氧化物的生成焓、混合焓和表面能的测量变得容易。这些对于自然和技术中的过程建模以及理解定义其稳定性的潜在属性是必不可少的。本文综述了这些量热技术的发展,并对常见硫属化合物的热化学数据进行了总结。在上个世纪,量热仪器和技术已经发展到能够精确测量包括硫属化合物在内的各种材料。▪尽管人们对硫属化合物的热力学特性越来越感兴趣,但对现有数据的系统审查表明,进一步研究仍有很大的余地。▪对硫属化合物的系统了解将有助于地质环境的建模,并能够预测和改进用于工业应用的地质启发材料。
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引用次数: 0
期刊
Annual Review of Earth and Planetary Sciences
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