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Late Cenozoic Faunal and Ecological Change in Africa 非洲晚新生代动物和生态变化
IF 14.9 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-01-25 DOI: 10.1146/annurev-earth-031621-114105
J. Tyler Faith, John Rowan, Andrew Du
Africa's fossil record of late Cenozoic mammals documents considerable ecological and evolutionary changes through time. Here, we synthesize those changes in the context of the mechanisms proposed to account for them, including bottom-up (e.g., climate change) and top-down (e.g., hominin impacts) processes. In doing so, we ( a) examine how the incompleteness of the fossil record and the varied spatiotemporal scales of the evidence complicate efforts to establish cause-effect relationships; ( b) evaluate hypothesized drivers of long-term ecological and evolutionary change, highlighting key unknowns; and ( c) synthesize major taxonomic and functional trends through time (e.g., downsizing of faunal communities) considering the proposed drivers. Throughout our review, we point to unresolved questions and highlight research avenues that have potential to inform on the processes that have shaped the history of what are today the most diverse remaining large mammal communities on Earth.▪ The study of late Cenozoic African mammal communities is intertwined with questions about the context, causes, and consequences of hominin evolution. ▪ The fossil record documents major functional (e.g., loss of megaherbivores) and taxonomic (e.g., rise of the Bovidae) changes over the past ∼7 Myr. ▪ Complexities inherent to the fossil record have made it difficult to identify the processes that drove ecological and evolutionary changes. ▪ Unanswered questions about the drivers of faunal change and the functioning of past ecosystems represent promising future research directions.Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 52 is May 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.
非洲晚新生代哺乳动物化石记录记录了生态和进化方面的巨大变化。在此,我们将根据所提出的解释这些变化的机制,包括自下而上(如气候变化)和自上而下(如类人猿的影响)的过程,对这些变化进行综合分析。在此过程中,我们(a)研究了化石记录的不完整性和证据的不同时空尺度如何使建立因果关系的工作复杂化;(b)评估长期生态和进化变化的假定驱动因素,强调关键的未知因素;以及(c)综合考虑所提出的驱动因素,对不同时期的主要分类和功能趋势(如动物群落的缩小)进行综合分析。在我们的综述中,我们指出了一些尚未解决的问题,并强调了一些研究途径,这些途径有可能为塑造当今地球上现存的最多样化大型哺乳动物群落的历史过程提供信息。化石记录记录了过去 ∼7 Myr 期间的主要功能变化(如巨型食草动物的消失)和分类变化(如牛科动物的兴起)。化石记录固有的复杂性使人们难以确定驱动生态和进化变化的过程。关于动物变化的驱动因素和过去生态系统功能的未解之谜是未来大有可为的研究方向。《地球与行星科学年刊》第 52 卷的最终在线出版日期预计为 2024 年 5 月。修订后的预计日期请参见 http://www.annualreviews.org/page/journal/pubdates。
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引用次数: 0
On Dislocation Climb as an Important Deformation Mechanism for Planetary Interiors 论位错攀升是行星内部的重要变形机制
IF 14.9 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-01-18 DOI: 10.1146/annurev-earth-031621-063108
Philippe Carrez, Alexandre Mussi, Patrick Cordier
▪ An understanding of the rheological behavior of the solid Earth is fundamental to provide a quantitative description of most geological and geophysical phenomena. The continuum mechanics approach to describing large-scale phenomena needs to be informed by a description of the mechanisms operating at the atomic scale. These involve crystal defects, mainly vacancies and dislocations. This often leads to a binary view of creep reduced to diffusion creep or dislocation creep. However, the interaction between these two types of defects leading to dislocation climb plays an important role, and may even be the main one, in the high-temperature, low strain rate creep mechanisms of interest to the Earth sciences. Here we review the fundamentals of dislocation climb, highlighting the specific problems of minerals. We discuss the importance of computer simulations, informed by experiments, for accurately modeling climb. We show how dislocation climb increasingly appears as a deformation mechanism in its own right. We review the contribution of this mechanism to mineral deformation, particularly in Earth's mantle. Finally, we discuss progress and challenges, and we outline future work directions. Dislocations can be sources or sinks of vacancies, resulting in a displacement out of the glide plane: climb. ▪ Dislocation climb can be a recovery mechanism during dislocation creep but also a strain-producing mechanism. ▪ The slow natural strain rates promote the contribution of climb, which is controlled by diffusion. ▪ In planetary interiors where dislocation glide can be inhibited by pressure, dislocation climb may be the only active mechanism.Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 52 is May 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.
了解固体地球的流变行为是定量描述大多数地质和地球物理现象的基础。描述大尺度现象的连续介质力学方法需要了解原子尺度的运行机制。这涉及晶体缺陷,主要是空位和位错。这往往导致二元蠕变观点,将蠕变简化为扩散蠕变或位错蠕变。然而,在地球科学感兴趣的高温、低应变速率蠕变机制中,导致位错攀升的这两类缺陷之间的相互作用起着重要作用,甚至可能是主要作用。在此,我们回顾了位错攀升的基本原理,并强调了矿物的具体问题。我们讨论了以实验为基础的计算机模拟对准确模拟位错攀升的重要性。我们展示了位错攀升如何日益成为一种变形机制。我们回顾了这种机制对矿物变形的贡献,尤其是在地球地幔中。最后,我们讨论了所取得的进展和面临的挑战,并概述了未来的工作方向。位错可以是空位的源或汇,从而导致滑移面外的位移:爬升。位错爬升可以是位错蠕变过程中的一种恢复机制,但也是一种应变产生机制。缓慢的自然应变速率会促进攀升,而攀升是由扩散控制的。在行星内部,差排滑行会受到压力的抑制,差排爬升可能是唯一活跃的机制。《地球与行星科学年度综述》第52卷的最终在线出版日期预计为2024年5月。修订后的预计日期请参见 http://www.annualreviews.org/page/journal/pubdates。
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引用次数: 0
Carbon Cycle–Climate Feedbacks in the Post-Paris World 后巴黎世界的碳循环-气候反馈作用
IF 14.9 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-01-18 DOI: 10.1146/annurev-earth-031621-081700
David S. Schimel, Dustin Carroll
The Paris Agreement calls for emissions reductions to limit climate change, but how will the carbon cycle change if it is successful? The land and oceans currently absorb roughly half of anthropogenic emissions, but this fraction will decline in the future. The amount of carbon that can be released before climate is mitigated depends on the amount of carbon the ocean and terrestrial ecosystems can absorb. Policy is based on model projections, but observations and theory suggest that climate effects emerging in today's climate will increase and carbon cycle tipping points may be crossed. Warming temperatures, drought, and a slowing growth rate of CO2 itself will reduce land and ocean sinks and create new sources, making carbon sequestration in forests, soils, and other land and aquatic vegetation more difficult. Observations, data-assimilative models, and prediction systems are needed for managing ongoing long-term changes to land and ocean systems after achieving net-zero emissions. ▪ International agreements call for stabilizing climate at 1.5° above preindustrial, while the world is already seeing damaging extremes below that. ▪ If climate is stabilized near the 1.5° target, the driving force for most sinks will slow, while feedbacks from the warmer climate will continue to cause sources. ▪ Once emissions are reduced to net zero, carbon cycle-climate feedbacks will require observations to support ongoing active management to maintain storage.Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 52 is May 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.
巴黎协定》呼吁通过减排来限制气候变化,但如果该协定获得成功,碳循环将如何变化?目前,陆地和海洋吸收了大约一半的人为排放,但这部分排放在未来将会减少。在气候得到缓解之前能够释放的碳量取决于海洋和陆地生态系统能够吸收的碳量。政策是以模型预测为基础的,但观测和理论表明,当今气候中出现的气候效应将会增加,碳循环临界点可能会被跨越。气温升高、干旱以及二氧化碳本身增长速度的减缓将减少陆地和海洋的碳汇,并产生新的碳源,从而使森林、土壤以及其他陆地和水生植被的碳封存变得更加困难。在实现净零排放后,需要观测、数据同化模型和预测系统来管理陆地和海洋系统正在发生的长期变化。国际协议要求将气候稳定在比工业化前高出 1.5° 的水平,而世界上已经出现了低于这一水平的破坏性极端气候。如果气候稳定在 1.5° 目标附近,大多数汇的驱动力将放缓,而气候变暖的反馈将继续造成源。一旦排放量减少到净零,碳循环-气候反馈将需要观测来支持持续的积极管理,以维持储存。《地球与行星科学年度评论》第 52 卷的最终在线出版日期预计为 2024 年 5 月。修订后的估算请参见 http://www.annualreviews.org/page/journal/pubdates。
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引用次数: 0
Modeling Past Hothouse Climates as a Means for Assessing Earth System Models and Improving the Understanding of Warm Climates 模拟过去的 "暖房气候",以此评估地球系统模型并加深对暖气候的理解
IF 14.9 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-01-18 DOI: 10.1146/annurev-earth-032320-100333
Jiang Zhu, Christopher J. Poulsen, Bette L. Otto-Bliesner
Simulating the warmth and equability of past hothouse climates has been a challenge since the inception of paleoclimate modeling. The newest generation of Earth system models (ESMs) has shown substantial improvements in the ability to simulate the early Eocene global mean surface temperature (GMST) and equator-to-pole gradient. Results using the Community Earth System Model suggest that parameterizations of atmospheric radiation, convection, and clouds largely determine the Eocene GMST and are responsible for improvements in the new ESMs, but they have less direct influence on the equator-to-pole temperature gradient. ESMs still have difficulty simulating some regional and seasonal temperatures, although improved data reconstructions of chronology, spatial coverage, and seasonal resolution are needed for more robust model assessment. Looking forward, key processes including radiation and clouds need to be benchmarked and improved using more accurate models of limited domain/physics. Earth system processes need to be better explored, leveraging the increasing ESM resolution and complexity. ▪ Earth system models (ESMs) are now able to simulate the large-scale features of the early Eocene. ▪ Remaining model-data discrepancies exist at regional and seasonal scales and require improvements in both proxy data and ESMs. ▪ A hierarchical modeling approach is needed to ensure relevant physical processes are parameterized reasonably well in ESMs. ▪ Future work is needed to leverage the continuously increasing resolution and complexity of ESMs.Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 52 is May 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.
自古气候建模开始以来,模拟过去温室气候的温暖和均衡一直是一个挑战。最新一代地球系统模式(ESM)在模拟始新世早期全球平均地表温度(GMST)和赤道到极地梯度的能力方面有了显著提高。利用共同体地球系统模式得出的结果表明,大气辐射、对流和云的参数化在很大程度上决定了始新世全球平均表面温度,也是新的 ESMs 得以改进的原因,但它们对赤道到极地温度梯度的直接影响较小。尽管需要改进年代学、空间覆盖和季节分辨率的数据重建,以便对模型进行更有力的评估,但 ESM 仍然难以模拟某些区域和季节温度。展望未来,包括辐射和云在内的关键过程需要使用更精确的有限领域/物理模型进行基准测试和改进。需要利用不断提高的 ESM 分辨率和复杂性,更好地探索地球系统过程。地球系统模式(ESM)现在能够模拟始新世早期的大尺度特征。在区域和季节尺度上,模型与数据之间仍存在差异,需要改进代用数据和 ESM。需要采用分层建模方法,以确保相关物理过程在 ESM 中得到合理参数化。地球与行星科学年度评论》第 52 卷的最终在线出版日期预计为 2024 年 5 月。修订后的预计日期请参见 http://www.annualreviews.org/page/journal/pubdates。
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引用次数: 0
Sublithospheric Diamonds: Plate Tectonics from Earth's Deepest Mantle Samples 岩石圈下的钻石:从地球最深的地幔样本看板块构造
IF 14.9 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-01-18 DOI: 10.1146/annurev-earth-032320-105438
Steven B. Shirey, D. Graham Pearson, Thomas Stachel, Michael J. Walter
Sublithospheric diamonds and the inclusions they may carry crystallize in the asthenosphere, transition zone, or uppermost lower mantle (from 300 to ∼800 km), and are the deepest minerals so far recognized to form by plate tectonics. These diamonds are distinctive in their deformation features, low nitrogen content, and inclusions of these major mantle minerals: majoritic garnet, clinopyroxene, ringwoodite, CaSi perovskite, ferropericlase, and bridgmanite or their retrograde equivalents. The stable isotopic compositions of elements within these diamonds (δ11B, δ13C, δ15N) and their inclusions (δ18O, δ56Fe) are typically well outside normal mantle ranges, showing that these elements were either organic (C) or modified by seawater alteration (B, O, Fe) at relatively low temperatures. Metamorphic minerals in cold slabs are effective hosts that transport C as CO3 and H as H2O, OH, or CH4 below the island arc and mantle wedge. Warming of the slab generates carbonatitic melts, supercritical aqueous fluids, or metallic liquids, forming three types of sublithospheric diamonds. Diamond crystallization occurs by movement and reduction of mobile fluids as they pass through host mantle via fractures—a process that creates chemical heterogeneity and may promote deep focus earthquakes. Geobarometry of majoritic garnet inclusions and diamond ages suggest upward transport, perhaps to the base of mantle lithosphere. From there, diamonds are carried to Earth's surface by eruptions of kimberlite magma. Mineral assemblages in sublithospheric diamonds directly trace Earth's deep volatile cycle, demonstrating how the hydrosphere of a rocky planet can connect to its solid interior. ▪ Sublithospheric diamonds from the deep upper mantle, transition zone, and lower mantle host Earth's deepest obtainable mineral samples. ▪ Low-temperature seawater alteration of the ocean floor captures organic and inorganic carbon at the surface eventually to become some of the most precious gem diamonds. ▪ Subduction transports fluids in metamorphic minerals to great depth. Fluids released by slab heating migrate, react with host mantle to induce diamond crystallization, and may trigger earthquakes. ▪ Sublithospheric diamonds are powerful tracers of subduction—a plate tectonic process that deeply recycles part of Earth's planetary volatile budget.Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 52 is May 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.
岩石圈下金刚石及其可能携带的包裹体在星体层、过渡带或最上层下地幔(300 至 800 千米)中结晶,是迄今公认的由板块构造形成的最深层矿物。这些金刚石的独特之处在于它们的变形特征、低含氮量以及这些主要地幔矿物的包裹体:主石榴石、倩辉石、环钨矿、CaSi透辉石、铁闪长岩、桥粒岩或它们的逆行等价物。这些金刚石中的元素(δ11B、δ13C、δ15N)及其包裹体(δ18O、δ56Fe)的稳定同位素组成通常远远超出正常地幔范围,表明这些元素要么是有机元素(C),要么是在相对较低的温度下被海水蚀变(B、O、Fe)而改变的。冷板块中的变质矿物是有效的宿主,它们以 CO3 的形式将 C 和以 H2O、OH 或 CH4 的形式将 H 运送到岛弧和地幔楔以下。板块升温产生碳酸盐熔体、超临界水液或金属液,形成三种岩石圈下金刚石。金刚石的结晶是由流动流体在通过裂缝穿过主地幔时的移动和还原而产生的--这一过程会产生化学异质性,并可能促进深部聚焦地震。橄榄榴石包裹体的测地线和钻石的年龄表明,钻石是向上迁移的,可能迁移到地幔岩石圈的底部。从那里,金伯利岩浆的喷发将钻石带到地球表面。岩石圈下钻石中的矿物组合直接追溯了地球的深层挥发循环,展示了岩石行星的水圈是如何与其固体内部相联系的。来自深层上地幔、过渡带和下地幔的岩石圈下金刚石拥有地球上可获得的最深矿物样本。洋底的低温海水蜕变在表层捕获有机碳和无机碳,最终成为一些最珍贵的宝石钻石。俯冲作用将变质矿物中的流体带到很深的地方。板块加热释放的流体迁移,与主地幔发生反应,诱发钻石结晶,并可能引发地震。岩石圈下的钻石是俯冲--板块构造过程--的强大示踪剂,它深度回收了地球行星挥发性预算的一部分。《地球与行星科学年刊》第52卷的最终在线出版日期预计为2024年5月。修订后的预计日期请参见 http://www.annualreviews.org/page/journal/pubdates。
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引用次数: 0
Stability of Ice Shelves and Ice Cliffs in a Changing Climate 冰架和冰崖在不断变化的气候中的稳定性
IF 14.9 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-01-12 DOI: 10.1146/annurev-earth-040522-122817
Jeremy N. Bassis, Anna Crawford, Samuel B. Kachuck, Douglas I. Benn, Catherine Walker, Joanna Millstein, Ravindra Duddu, Jan Åström, Helen Fricker, Adrian Luckman
The largest uncertainty in future sea-level rise is loss of ice from the Greenland and Antarctic Ice Sheets. Ice shelves, freely floating platforms of ice that fringe the ice sheets, play a crucial role in restraining discharge of grounded ice into the ocean through buttressing. However, since the 1990s, several ice shelves have thinned, retreated, and collapsed. If this pattern continues, it could expose thick cliffs that become structurally unstable and collapse in a process called marine ice cliff instability (MICI). However, the feedbacks between calving, retreat, and other forcings are not well understood. Here we review observed modes of calving from ice shelves and marine-terminating glaciers, and their relation to environmental forces. We show that the primary driver of calving is long-term internal glaciological stress, but as ice shelves thin they may become more vulnerable to environmental forcing. This vulnerability—and the potential for MICI—comes from a combination of the distribution of preexisting flaws within the ice and regions where the stress is large enough to initiate fracture. Although significant progress has been made modeling these processes, theories must now be tested against a wide range of environmental and glaciological conditions in both modern and paleo conditions. ▪ Ice shelves, floating platforms of ice fed by ice sheets, shed mass in a near-instantaneous fashion through iceberg calving. ▪ Most ice shelves exhibit a stable cycle of calving front advance and retreat that is insensitive to small changes in environmental conditions. ▪ Some ice shelves have retreated or collapsed completely, and in the future this could expose thick cliffs that could become structurally unstable called ice cliff instability. ▪ The potential for ice shelf and ice cliff instability is controlled by the presence and evolution of flaws or fractures within the ice.Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 52 is May 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.
未来海平面上升的最大不确定因素是格陵兰和南极冰原的冰量减少。冰架是冰原边缘自由漂浮的冰平台,在通过承托作用限制接地冰流入海洋方面发挥着至关重要的作用。然而,自 20 世纪 90 年代以来,一些冰架已经变薄、后退和坍塌。如果这种模式继续下去,可能会暴露出厚厚的悬崖,使其结构变得不稳定,并在一个称为海洋冰崖不稳定性(MICI)的过程中坍塌。然而,人们对冰盖形成、退缩和其他作用力之间的反馈作用还不甚了解。在此,我们回顾了观测到的冰架和海洋末端冰川的碎裂模式及其与环境力量的关系。我们表明,冰架断裂的主要驱动力是长期的内部冰川压力,但随着冰架变薄,它们可能会变得更容易受到环境的影响。这种脆弱性--以及 MICI 的可能性--来自冰层内部预先存在的缺陷的分布以及应力大到足以引发断裂的区域的组合。尽管在这些过程的建模方面已经取得了重大进展,但现在必须根据现代和古生物条件下的各种环境和冰川条件对理论进行检验。冰架是由冰原喂养的浮冰平台,通过冰山崩裂以近乎瞬时的方式形成。大多数冰架表现出稳定的冰山前沿推进和后退周期,对环境条件的微小变化不敏感。一些冰架已经完全后退或坍塌,未来这可能会暴露出厚厚的悬崖,从而导致结构不稳定,即所谓的冰崖不稳定性。冰架和冰崖不稳定性的可能性受控于冰内缺陷或裂缝的存在和演变。《地球和行星科学年度评论》第 52 卷的最终在线出版日期预计为 2024 年 5 月。修订后的预计日期请参见 http://www.annualreviews.org/page/journal/pubdates。
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引用次数: 0
Halogen Cycling in the Solid Earth 固体地球中的卤素循环
IF 14.9 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-01-12 DOI: 10.1146/annurev-earth-031621-111700
Mark A. Kendrick
Each of the halogens constrains a different aspect of volatile cycling in the solid Earth. F is moderately incompatible in the mantle and has a low mobility at Earth's surface, meaning that it is preferentially retained in the mantle and continental crust. In contrast, Cl, Br, and I are strongly incompatible and highly soluble. Chloride is the dominant anion in seawater and many geofluids and a major component of evaporite minerals. Br and I are essential for life and significantly incorporated into organic matter that accumulates in marine sediments. Surficial fluids circulated into continental and oceanic crust incorporate surface-derived halogens into alteration minerals. As a result, subducting slabs and arc lavas are weakly enriched in F and strongly enriched in Cl, Br, and I. Subduction has maintained mantle Cl and Br concentrations at relatively constant levels since Earth's early differentiation, but mantle I/Cl has decreased over time. ▪ Halogen abundances on the early Earth were affected by I partitioning into Earth's core and possible loss of hydrophilic Cl, Br, and I in an early formed ocean. ▪ Halogens are powerful tracers of subduction zone processes on the modern Earth, with Cl, Br, and I having a dominantly subducted origin in Earth's mantle. ▪ The deep subduction cycles of Cl, Br, and I are more similar to that of H2O than they are to F, but the geochemical cycle of each halogen differs in detail. ▪ Halogen abundance ratios and stable isotope ratios vary systematically in Earth's surface reservoirs, meaning that halogens are powerful tracers of geological fluids and melts.Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 52 is May 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.
每种卤素都对固体地球中的挥发循环有不同方面的影响。F 在地幔中具有中度不相容性,在地球表面的流动性较低,这意味着它优先保留在地幔和大陆地壳中。相比之下,Cl、Br 和 I 具有强烈的不相容性和高溶解性。氯化物是海水和许多地球流体中的主要阴离子,也是蒸发岩矿物的主要成分。溴和碘是生命所必需的,并大量融入海洋沉积物中积累的有机物中。循环到大陆和大洋地壳中的地表流体将地表衍生的卤素纳入蚀变矿物中。因此,俯冲板块和弧状熔岩中 F 的富集程度较低,而 Cl、Br 和 I 的富集程度较高。自地球早期分异以来,俯冲作用使地幔中 Cl 和 Br 的富集程度保持在相对稳定的水平,但地幔中 I/Cl 的富集程度则随着时间的推移而降低。早期地球上的卤素丰度受到 I 分入地核以及早期形成的海洋中亲水性 Cl、Br 和 I 可能流失的影响。卤素是现代地球俯冲带过程的强大示踪剂,Cl、Br 和 I 主要来源于地球地幔的俯冲。与 F 相比,Cl、Br 和 I 的深俯冲周期与 H2O 更为相似,但每种卤素的地球化学周期在细节上都有所不同。卤素丰度比和稳定同位素比在地球表面储层中有系统地变化,这意味着卤素是地质流体和熔体的强大示踪剂。《地球与行星科学年刊》第 52 卷的最终在线出版日期预计为 2024 年 5 月。修订后的预计日期请参见 http://www.annualreviews.org/page/journal/pubdates。
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引用次数: 0
Climate and Tropospheric Oxidizing Capacity 气候与对流层氧化能力
IF 14.9 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-01-12 DOI: 10.1146/annurev-earth-032320-090307
Arlene M. Fiore, Loretta J. Mickley, Qindan Zhu, Colleen B. Baublitz
The hydroxyl radical (OH) largely controls the tropospheric self-cleansing capacity by reacting with gases harmful to the environment and human health. OH concentrations are determined locally by competing production and loss processes. Lacking strong observational constraints, models differ in how they balance these processes, such that the sign of past and future OH changes is uncertain. In a warmer climate, OH production will increase due to its water vapor dependence, partially offset by faster OH-methane loss. Weather-sensitive emissions will also likely increase, although their net impact on global mean OH depends on the balance between source (nitrogen oxides) and sink (reactive carbon) gases. Lightning activity increases OH, but its response to climate warming is of uncertain sign. To enable confident projections of OH, we recommend efforts to reduce uncertainties in kinetic reactions, in measured and modeled OH, in proxies for past OH concentrations, and in source and sink gas emissions. ▪ OH is strongly modulated by internal climate variability despite its lifetime of a few seconds at most, with implications for interpreting trends in methane. ▪ Improved kinetic constraints on key reactions would strengthen confidence in regional and global OH budgets, and in the response of OH to climate change. ▪ Future OH changes will depend on uncertain and compensating processes involving weather-sensitive chemistry and emissions, plus human choices. ▪ Technological solutions to climate change will likely impact tropospheric oxidizing capacity and merit further study prior to implementation.Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 52 is May 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.
羟基自由基(OH)通过与对环境和人类健康有害的气体发生反应,在很大程度上控制着对流层的自净能力。羟基自由基的浓度是由相互竞争的产生和损失过程决定的。由于缺乏强有力的观测约束,模型在如何平衡这些过程方面存在差异,因此过去和未来 OH 变化的迹象并不确定。在气候变暖的情况下,由于羟基甲烷依赖于水汽,羟基甲烷的产生量将会增加,但羟基甲烷的损失速度会加快,从而部分抵消羟基甲烷的产生量。对天气敏感的排放物也可能会增加,尽管它们对全球平均 OH 的净影响取决于源气体(氮氧化物)和汇气体(活性碳)之间的平衡。闪电活动会增加 OH,但其对气候变暖的反应还不确定。为了能够对 OH 进行可靠的预测,我们建议努力减少动力学反应、测量和模拟的 OH、过去 OH 浓度的代用指标以及源和汇气体排放中的不确定性。尽管 OH 的寿命最长只有几秒钟,但它受到内部气候变异的强烈调节,这对解释甲烷的变化趋势有影响。改进对关键反应的动力学约束将增强对区域和全球 OH 预算以及 OH 对气候变 化响应的信心。未来 OH 的变化将取决于涉及对天气敏感的化学和排放的不确定补偿过程,以及人 类的选择。气候变化的技术解决方案可能会影响对流层的氧化能力,在实施之前值得进一步研究。《地球和行星科学年度评论》第 52 卷的最终在线出版日期预计为 2024 年 5 月。修订后的估计日期请参见 http://www.annualreviews.org/page/journal/pubdates。
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引用次数: 0
Lunar Evolution in Light of the Chang'e-5 Returned Samples 从嫦娥五号返回的样本看月球演变
IF 14.9 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-01-02 DOI: 10.1146/annurev-earth-040722-100453
Fu-Yuan Wu, Qiu-Li Li, Yi Chen, Sen Hu, Zong-Yu Yue, Qin Zhou, Hao Wang, Wei Yang, Heng-Ci Tian, Chi Zhang, Jin-Hua Li, Lin-Xi Li, He-Jiu Hui, Chun-Lai Li, Yang-Tin Lin, Xian-Hua Li, John W. Delano
The Chinese spacecraft Chang'e-5 (CE-5) landed on the northern Ocean Procellarum and returned 1,731 grams of regolith. The CE-5 regolith is composed mostly of fragments of basalt, impact glass, agglutinates, and mineral fragments. The basalts could be classified as of a low-Ti and highly fractionated type based on their TiO2 content of ∼5.3 wt% and Mg# of ∼28. Independent of petrographic texture, the CE-5 basalts have a uniform eruption age of 2,030 ± 4 Ma, demonstrating that the Moon remained volcanically active until at least ∼2.0 Ga. Although the CE-5 landing site lies within the so-called Procellarum KREEP [potassium (K), rare earth elements (REE), and phosphorus (P)] Terrane, neither the CE-5 basalts nor the mantle source regions of those basalts were enriched in KREEP components, such as incompatible elements, water, sulfur, or chlorine. Therefore, it would be a new and stimulating task in the future to look for the triggering mechanism of the young volcanism on the Moon. ▪ The CE-5 spacecraft returned 1,731 grams of lunar regolith in December 2020. It was the first new lunar sample since the last collection in August 1976. ▪ CE-5 regolith is basaltic in chemical composition, with only ∼1% highland materials of anorthosite, Mg suite, alkali suite, and KREEP. ▪ The CE-5 basalt is low Ti and highly differentiated. It was extruded at ∼2.0 Ga, being the youngest lunar basalt identified so far from the Moon. ▪ The triggering mechanism of the ∼2.0 Ga lunar volcanism is not clearly understood because its mantle source was dry and contained low abundances of KREEP elements.Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 52 is May 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.
中国航天器嫦娥五号(CE-5)在北大洋原星体着陆,并返回了 1,731 克的残积岩。嫦娥五号的残留岩主要由玄武岩碎片、撞击玻璃、凝集物和矿物碎片组成。根据其二氧化钛含量(TiO2)∼5.3 wt%和镁含量(Mg#)∼28,可将玄武岩归类为低钛和高分馏类型。与岩相质地无关,CE-5玄武岩的统一喷发年龄为2,030 ± 4 Ma,表明月球至少在2.0 Ga之前一直保持着火山活动。虽然CE-5着陆点位于所谓的Procellarum KREEP[钾(K)、稀土元素(REE)和磷(P)]地层中,但CE-5玄武岩和这些玄武岩的地幔源区都不富含KREEP成分,如不相容元素、水、硫或氯。因此,寻找月球年轻火山活动的触发机制将是未来一项新的刺激性任务。CE-5 号飞船于 2020 年 12 月返回了 1731 克月球碎屑。这是自 1976 年 8 月最后一次采集以来的第一个新的月球样本。CE-5 号回归岩的化学成分为玄武岩,仅含有 1%的正长岩、镁岩、碱岩和 KREEP 等高原物质。CE-5 玄武岩的钛含量低,分化程度高。CE-5玄武岩Ti含量低,分化程度高,挤出时间为2.0 Ga,是迄今为止从月球上发现的最年轻的月球玄武岩。2.0 Ga月球火山活动的触发机制尚不清楚,因为它的地幔源是干燥的,并且含有低丰度的KREEP元素。《地球与行星科学年刊》第52卷的最终在线出版日期预计为2024年5月。修订后的预计日期请参见 http://www.annualreviews.org/page/journal/pubdates。
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引用次数: 0
Origin and Early Evolution of Echinoderms 棘皮动物的起源和早期进化
IF 14.9 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-01-02 DOI: 10.1146/annurev-earth-031621-113343
Imran A. Rahman, Samuel Zamora
Echinoderms are a major group (phylum) of invertebrate animals with a rich fossil record stretching back to the Cambrian period, approximately 518 million years ago. While all modern species are characterized by pentaradial (i.e., fivefold) symmetry, Cambrian echinoderms also include taxa with different types of symmetry (e.g., bilateral symmetry). These distinct forms were present from very early in the phylum's history, demonstrating that the initial diversification of echinoderm body plans was extremely rapid. The phylogenetic relationships of Cambrian echinoderms have long been debated, hindering efforts to reconstruct the evolution of the phylum, but recent analyses have consistently recovered bilaterally symmetrical forms as the earliest-diverging echinoderms. This reveals the sequence of character acquisition in echinoderm evolution, indicating that radial symmetry is a derived character of the group, which evolved after the acquisition of a mineralized skeleton. Cambrian echinoderms were adapted to diverse modes of life, with ecology an important factor shaping their early evolution. However, the reasons why echinoderms evolved their unique pentaradial body plan remain unclear. ▪ The Cambrian fossil record provides valuable insights into the origin and early evolution of echinoderms over half a billion years ago. ▪ Cambrian echinoderms were morphologically diverse, with several extinct groups exhibiting character combinations that distinguish them from living species. ▪ Phylogenetic analyses of bilateral, asymmetrical, triradial, and pentaradial fossils have allowed us to decipher the assembly of the modern echinoderm body plan. ▪ Echinoderms became ecologically diverse early in their history, with varied modes of feeding, locomotion, and attachment.Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 52 is May 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.
棘皮动物是无脊椎动物的一个主要类群(门),其丰富的化石记录可追溯到大约 5.18 亿年前的寒武纪。虽然所有现代物种都具有五对称(即五重对称)的特征,但寒武纪棘皮动物也包括具有不同对称类型(如两侧对称)的类群。这些不同的形态在棘皮动物门的历史上很早就出现了,这表明棘皮动物最初的身体形态多样化极为迅速。寒武纪棘皮动物的系统发育关系长期以来一直存在争议,阻碍了重建棘皮动物门进化的努力,但最近的分析一致认为两侧对称的形态是最早出现分化的棘皮动物。这揭示了棘皮动物进化过程中获得特征的顺序,表明辐射对称是该类群的衍生特征,是在获得矿化骨骼之后进化而来的。寒武纪棘皮动物适应多种多样的生活方式,生态学是影响其早期进化的重要因素。然而,棘皮动物进化出独特的五边形身体结构的原因仍不清楚。寒武纪化石记录为了解 5 亿多年前棘皮动物的起源和早期进化提供了宝贵的信息。寒武纪棘皮动物在形态上多种多样,一些已灭绝的类群表现出不同于现生物种的特征组合。对双侧、不对称、三裂片和五裂片化石的系统发生学分析使我们能够破译现代棘皮动物的身体结构。棘皮动物在其历史早期就具有生态多样性,其进食、运动和附着方式多种多样。《地球与行星科学年刊》第52卷的最终在线出版日期预计为2024年5月。修订后的预计日期请参见 http://www.annualreviews.org/page/journal/pubdates。
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引用次数: 0
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Annual Review of Earth and Planetary Sciences
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