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Critical evaluation of the application of filter-assisted separation in analytical atomic spectrometry 过滤辅助分离在原子光谱分析中的应用
IF 6.1 2区 化学 Q1 Physics and Astronomy Pub Date : 2022-10-18 DOI: 10.1080/05704928.2022.2134145
Xin Chen, Kelin Hu, Jinrong Zhou, Xin Yuan, Mei Zhang, Ke Huang, Yi Pan
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引用次数: 2
Review on the elemental analysis of polymetallic deposits by total-reflection X-ray fluorescence spectrometry x射线全反射荧光光谱法分析多金属矿床元素的研究进展
IF 6.1 2区 化学 Q1 Physics and Astronomy Pub Date : 2022-10-13 DOI: 10.1080/05704928.2022.2130350
Yongsheng Zhang, Yaxiong He, W. Zhou, Guanqin Mo, Hui Chen, Tao Xu
Abstract Total reflection X-ray fluorescence (TXRF) has been widely considered as an effective analytical tool for the analysis of a great variety type of polymetallic deposits, because it has many advantages of extremely high sensitivity, high accuracy, minor sample preparation, and the ability of multielement simultaneous analysis. Sample preparation is quite important for TXRF quantitative analysis. Since pretreatment factors, such as sample amount, dispersant type, sample particle size and sample physicochemical properties, are seriously impact the accuracy of results. Based on this reason, investigating an appropriate sample pretreatment strategy is fundamental for accurate assessment of strategic metal elements in polymetallic deposits. This review presents a comprehensive overview of TXRF applications in the field of mineral analysis, including apatite, manganese ore, K-feldspars, granite, copper-nickel sulfide ore, etc. Moreover, the accurate evaluation of TXRF quantitative analysis is detailedly discussed, and the relevant sample preparation methods and preparation factors are also addressed.
摘要全反射x射线荧光(TXRF)由于具有极高的灵敏度、高精度、样品制备量少、多元素同时分析能力等优点,已被广泛认为是分析多种类型多金属矿床的有效分析工具。样品制备是TXRF定量分析的重要环节。由于样品用量、分散剂类型、样品粒度、样品理化性质等预处理因素严重影响结果的准确性。因此,研究合适的样品前处理策略是准确评价多金属矿床中战略金属元素的基础。本文综述了TXRF在磷灰石、锰矿石、钾长石、花岗岩、铜镍硫化矿等矿物分析领域的应用。详细讨论了TXRF定量分析的准确性评价,并对相关的制样方法和制备因素进行了讨论。
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引用次数: 2
Surface-enhanced Raman scattering (SERS) spectroscopy of corrosion inhibitors: High-resolution detection, adsorption property, and inhibition mechanism 缓蚀剂的表面增强拉曼散射(SERS)光谱:高分辨率检测、吸附性能和缓蚀机理
IF 6.1 2区 化学 Q1 Physics and Astronomy Pub Date : 2022-10-06 DOI: 10.1080/05704928.2022.2129667
Jinke Wang, Lingwei Ma, Xiaolun Ding, Shan Wu, Xin Guo, Dawei Zhang
Abstract Corrosion inhibitors are widely employed to retard metal corrosion. Highly sensitive detection and adsorption mechanism analysis are the two important aspects for the systematic research of corrosion inhibitors. Surface-enhanced Raman scattering (SERS) spectroscopy has emerged as a promising tool for the high-resolution detection and inhibition mechanism analysis of corrosion inhibitors in recent decades, and is of considerable importance for their selection and optimization. This paper provides an overview of the SERS technique in the study of corrosion inhibitors adsorbed on noble metals (SERS active substrates) and transition metals (non-SERS active substrates). After surface roughening, the SERS enhancement of metal electrodes can be significantly improved, which intensifies the Raman signals of adsorbed inhibitors to provide sufficient information regarding the binding state and adsorption orientation. In addition to roughening the metal surface to obtain strong SERS signals, novel SERS sensors that can amplify the Raman signals of inhibitors regardless of the type or surface state of the metal substrates are introduced, which is conductive to facilitating the real-time detection of inhibitors. The challenges and future prospects of SERS technique in corrosion inhibitor research are discussed. In summary, SERS technique is expected to promote the research development and engineering applications of corrosion inhibitors.
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引用次数: 1
Mathematical techniques to remove moisture effects from visible–near-infrared–shortwave-infrared soil spectra—review  从可见-近红外-短波-红外土壤光谱中去除水分影响的数学技术
IF 6.1 2区 化学 Q1 Physics and Astronomy Pub Date : 2022-10-03 DOI: 10.1080/05704928.2022.2128365
M. Knadel, F. Castaldi, R. Barbetti, E. Ben-Dor, A. Gholizadeh, R. Lorenzetti
Abstract Visible–near-infrared–shortwave-infrared (VNIR–SWIR) spectroscopy is one of the most promising sensing techniques to meet ever-growing demands for soil information and data. To ensure the successful application of this technique in the field, efficient methods for tackling detrimental moisture effects on soil spectra are critical. In this paper, mathematical techniques for reducing or removing the effects of soil moisture content (SMC) from spectra are reviewed. The reviewed techniques encompass the most common spectral pre-processing and algorithms, as well as less frequently reported methods including approaches within the remote sensing domain. Examples of studies describing their effectiveness in the search for calibration model improvement are provided. Moreover, the advantages and disadvantages of the different techniques are summarized. Future research including further studies on a wider range of soil types, in-field conditions, and systematic experiments considering several SMC levels to enable the definition of threshold values for the effectiveness of the discussed methods is recommended.
可见-近红外-短波红外(VNIR-SWIR)光谱技术是满足日益增长的土壤信息和数据需求的最有前途的传感技术之一。为了确保该技术在野外的成功应用,有效地解决水分对土壤光谱的不利影响至关重要。本文综述了降低或消除土壤含水量对光谱影响的数学方法。回顾的技术包括最常见的光谱预处理和算法,以及较少报道的方法,包括遥感领域的方法。提供了研究实例,描述了它们在寻找校准模型改进方面的有效性。此外,还总结了不同技术的优缺点。建议未来的研究包括对更广泛的土壤类型、田间条件的进一步研究,以及考虑几个SMC水平的系统实验,以确定所讨论方法有效性的阈值。
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引用次数: 6
Liquid-phase extraction combined with X-ray fluorescence spectrometry for the elemental determination 液相萃取联合x射线荧光光谱法测定元素
IF 6.1 2区 化学 Q1 Physics and Astronomy Pub Date : 2022-08-24 DOI: 10.1080/05704928.2022.2113537
Vanessa J. Ferreira, Fernanda B. S. Virgens, Laís N. Pires, F. Dias, V. Lemos, L. Teixeira
Abstract X-ray fluorescence spectrometry (XRF) has been widely used for multi-element determination in various samples. However, when trace level determination is required, separation and preconcentration procedures are often used as a step before detection to avoid or reduce interferences and to increase sensitivity. Liquid-phase extraction (LPE) is one of the most well-known and applied pretreatment techniques associated with atomic spectrometry due to its simplicity, speed, and ease of automation. A review of methods involving LPE combined with XRF is presented. Methods described in the literature are discussed, involving conventional LPE and the three main categories of liquid-phase microextraction (LPME): single-drop microextraction (SDME), dispersive liquid–liquid microextraction (DLLME), and hollow fiber liquid-phase microextraction (HF-LPME). Characteristics of the methods are presented, considering experimental aspects, analytical features, advantages, and disadvantages. In addition, trends in the association between LPME techniques and XRF are presented.
摘要x射线荧光光谱法(XRF)已广泛应用于各种样品中的多元素测定。然而,当需要痕量水平测定时,分离和预浓缩程序通常用作检测前的步骤,以避免或减少干扰并提高灵敏度。液相萃取(LPE)由于其简单、快速和易于自动化,是与原子光谱法相关的最知名和应用最广泛的前处理技术之一。本文综述了LPE与XRF相结合的方法。讨论了文献中描述的方法,包括传统的LPE和液相微萃取(LPME)的三大类:单滴微萃取(SDME)、分散液液微萃取(DLLME)和中空纤维液相微萃取(HF-LPME)。从实验方面、分析特点、优缺点等方面介绍了这些方法的特点。此外,在LPME技术和XRF之间的关联趋势提出。
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引用次数: 0
Strategies for sensitivity improvement of localized surface plasmon resonance sensors: experimental and mathematical approaches in plasmonic gold nanostructures 提高局域表面等离子体共振传感器灵敏度的策略:等离子体金纳米结构的实验和数学方法
IF 6.1 2区 化学 Q1 Physics and Astronomy Pub Date : 2022-07-26 DOI: 10.1080/05704928.2022.2104864
J. Ha
Abstract Localized surface plasmon resonance (LSPR) sensors using metallic nanoparticles are extensively used for refractive index (RI) measurements in chemical and biological studies, and their sensitivity is highly influenced by the material and structure of the nanoparticle. Despite the great advantages of LSPR sensors using frequency shifts, there are still major challenges in terms of detection sensitivity as well as the broadening and asymmetry of LSPR peaks. This article provides a general background of the fundamentals of LSPR and RI-based LSPR sensing. Thereafter, recent advances in the improvement of LSPR sensitivity are discussed in the viewpoints of two experimental and mathematical approaches. The experimental approaches, including the fabrication of plasmonic array nanostructures with high uniformity and site-selective immobilization, are briefly discussed. Later, we discuss recent studies using a simple mathematical approach with LSPR inflection point to improve the RI sensitivity in gold nanoparticles with different shapes, sizes, shells, etc.
金属纳米粒子局部表面等离子体共振(LSPR)传感器广泛用于化学和生物学研究中的折射率测量,其灵敏度受纳米粒子的材料和结构的高度影响。尽管采用移频的LSPR传感器具有很大的优势,但在检测灵敏度以及LSPR峰的加宽和不对称性方面仍然存在重大挑战。本文提供了LSPR和基于ri的LSPR传感基本原理的一般背景。然后,从实验和数学两方面讨论了近年来在提高LSPR灵敏度方面的研究进展。简要讨论了高均匀性等离子体阵列纳米结构的制备和位置选择性固定的实验方法。随后,我们讨论了利用LSPR拐点的简单数学方法来提高不同形状、尺寸、壳层等金纳米颗粒的RI灵敏度的最新研究。
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引用次数: 3
Review of near infrared hyperspectral imaging applications related to wood and wood products 近红外高光谱成像在木材和木制品中的应用综述
IF 6.1 2区 化学 Q1 Physics and Astronomy Pub Date : 2022-07-14 DOI: 10.1080/05704928.2022.2098759
L. Schimleck, Te Ma, T. Inagaki, S. Tsuchikawa
Abstract Hyperspectral imaging is a technique that combines spectroscopy and imaging. Originally utilized in the 1980’s by the remote sensing community it is now utilized in a wide variety of applications. Spectral imaging was first used for the detection of compression wood in the late 1990’s and since that time research focused on wood and wood products has steadily increased with a variety of applications reported. While there are several reviews of wood related research utilizing near infrared spectrometers a comprehensive summary of wood—hyperspectral imaging research is lacking. Near infrared hyperspectral imaging systems (NIR-HSI) typically have a wavelength range of 900–1700 nm, whereas short-wave infrared hyperspectral imaging (SWIR-HSI) systems range from 1000 to 2500 nm. We provide a detailed account of the various studies that have been published utilizing both camera types.
高光谱成像是光谱学与成像技术相结合的一种技术。它最初是在20世纪80年代由遥感界使用的,现在用于各种各样的应用。光谱成像首次用于压缩木材的检测是在20世纪90年代末,从那时起,对木材和木制品的研究随着各种应用的报道而稳步增加。虽然对木材相关研究利用近红外光谱仪进行了一些综述,但缺乏对木材高光谱成像研究的全面总结。近红外高光谱成像系统(NIR-HSI)通常具有900-1700 nm的波长范围,而短波红外高光谱成像(SWIR-HSI)系统的波长范围为1000至2500 nm。我们提供了利用两种相机类型发表的各种研究的详细说明。
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引用次数: 8
An overview of methodologies for the determination of volatile organic compounds in indoor air 室内空气中挥发性有机化合物测定方法概述
IF 6.1 2区 化学 Q1 Physics and Astronomy Pub Date : 2022-07-12 DOI: 10.1080/05704928.2022.2085735
T. Vera, F. Villanueva, L. Wimmerova, E. Tolis
Abstract Volatile organic compounds are a broad and important class of pollutants affecting the indoor air quality. They are emitted from commercial products, building materials, furniture, occupant activities and even occupants, etc., and can participate in the indoor chemistry reacting with oxidants or being formed from secondary reactions. Some VOCs are classified as carcinogens and are associated with a variety of health effects. Characterizing and quantifying the VOCs in the indoor environments is of paramount importance in order to implement preventive measures to minimize the human exposure. A correct assessment of human exposure or characterization of emission sources and indoor activities requires appropriate and efficient methods for sampling and analysis. Therefore, this review focuses on the different methodologies for monitoring VOC that must be selected when a sampling plan is designed considering the objective of the measure. Selecting the most suitable procedures for assessing VOCs requires proper knowledge on the existing standards and off-line (including the selection of the sorbent media) and online instrumentation. Knowing the advantages and drawbacks of the different techniques available can help to plan future studies.
挥发性有机物是影响室内空气质量的一类广泛而重要的污染物。它们从商业产品、建筑材料、家具、居住者活动甚至居住者等中释放出来,可以参与室内化学与氧化剂的反应或由二次反应形成。一些挥发性有机化合物被列为致癌物,并与各种健康影响有关。表征和量化室内环境中的挥发性有机化合物对于实施预防措施以尽量减少人类接触至关重要。正确评估人类接触或描述排放源和室内活动需要适当和有效的抽样和分析方法。因此,本综述侧重于监测VOC的不同方法,在设计采样计划时必须考虑到测量的目标来选择这些方法。选择最合适的挥发性有机化合物评估程序需要对现有标准和离线(包括吸附介质的选择)以及在线仪器有适当的了解。了解不同可用技术的优缺点有助于规划未来的研究。
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引用次数: 3
Techniques for measuring indoor radicals and radical precursors 室内自由基和自由基前体测定技术
IF 6.1 2区 化学 Q1 Physics and Astronomy Pub Date : 2022-06-25 DOI: 10.1080/05704928.2022.2087666
E. G. Alvarez, N. Carslaw, S. Dusanter, Peter M. Edwards, Viktor Gábor Mihucz, D. Heard, J. Kleffmann, S. Nehr, C. Schoemacker, D. Venables
Abstract Radicals and their precursors play a central role in the chemical transformations occurring in indoor air and on indoor surfaces. Such species include OH, HO2, peroxy radicals, nitrous acid, reactive chlorine species, NO3, N2O5, Criegee intermediates, and glyoxal and methylglyoxal. Recent advances on instrumental analysis and modeling studies have demonstrated the need for a wider range of measurements of radical species and their precursors in indoor air. This work reviews measurement techniques and provides considerations for indoor measurements of several radicals and their precursors. Techniques to determine the actinic flux are also presented owing to the relevance of photolytically-initiated processes indoors. This review is also intended to provide pointers for those wanting to learn more about measurements of radicals indoors.
自由基及其前体在室内空气和室内表面发生的化学转化中起着核心作用。这些物质包括OH、HO2、过氧自由基、亚硝酸盐、活性氯、NO3、N2O5、Criegee中间体、乙二醛和甲基乙二醛。仪器分析和建模研究的最新进展表明,需要对室内空气中的自由基及其前体进行更广泛的测量。这项工作回顾了测量技术,并提供了室内测量几种自由基及其前体的考虑。由于与室内光敏引发的过程相关,还提出了确定光化通量的技术。这篇综述也旨在为那些想要更多地了解室内自由基测量的人提供指导。
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引用次数: 1
Toward a better understanding of indoor air quality holistically integrating improved and new instrumental analytical techniques 朝着更好地理解室内空气质量整体整合改进和新的仪器分析技术
IF 6.1 2区 化学 Q1 Physics and Astronomy Pub Date : 2022-06-22 DOI: 10.1080/05704928.2022.2090952
N. Carslaw, V. Mihucz
People in developed countries are estimated to spend 80–90% of their time indoors, where they can be exposed to poor air quality from numerous and diverse sources. These include mold growth and other microbial pollutants in humid air, to the chemical pollutants that result from emissions from human activities such as cooking, cleaning, smoking and home refurbishments. In fact, the concentrations of many air pollutants can be higher indoors than out, particularly following activities such as cleaning and cooking. Despite these facts, regulation for air pollution focuses mainly on outdoors and the indoor environment is much less well characterized or indeed regulated. With increasing climate change impacts expected in the future, related energy efficiency measures are making buildings considerably more airtight leading to the potential for even higher indoor air pollutant concentrations. Therefore, to reduce our exposure to air pollution, we must consider air pollutant sources and sinks in both the indoor and outdoor environments. We also need to consider the role of ventilation in mixing air between the two, in order to mitigate through appropriate building operation, use and design. Cost Action 17136 INDAIRPOLLNET (INDoor AIR POLLution NETwork) aims to improve our understanding of the cause of high concentrations of indoor air pollutants. It assembles experts in chemistry, biology, standardization, particulate matter characterization, toxicology, exposure assessment, building materials (including green materials), building physics and engineering and building design, performing laboratory and chamber experiments, modeling studies and measurements of relevance to indoor air quality, including outdoor air chemists. This Action is significantly advancing the field of indoor air pollution science, and highlighting future research areas, as well as aiming to to bridge the gap between research and business. In this way, we will be able to identify appropriate mitigation strategies that optimize indoor air quality. One of the objectives of our Action has been to explore the best ways to measure key indoor air pollutants given specific requirements (research question, available funds, building location and characteristics etc.). This special issue therefore summarizes the various measurement techniques that are currently available for indoor air measurements and the advantages and disadvantages of each for the indoor environment. For more information, please visit: https://indairpollnet.eu/
据估计,发达国家的人们有80-90%的时间在室内度过,在室内,他们可能会接触到各种来源的劣质空气。这些污染物包括潮湿空气中的霉菌生长和其他微生物污染物,以及烹饪、清洁、吸烟和家庭装修等人类活动排放的化学污染物。事实上,许多空气污染物的浓度在室内可能高于室外,特别是在清洁和烹饪等活动之后。尽管有这些事实,对空气污染的监管主要集中在室外,而室内环境的特征和监管要少得多。随着未来气候变化影响的增加,相关的能源效率措施正在使建筑物更加密闭性,从而可能导致更高的室内空气污染物浓度。因此,为了减少我们对空气污染的暴露,我们必须考虑室内和室外环境中的空气污染源和汇。我们还需要考虑通风在两者之间混合空气中的作用,以便通过适当的建筑操作,使用和设计来缓解。inairpollnet(室内空气污染网络)旨在提高我们对室内空气污染物高浓度的原因的理解。它汇集了化学、生物学、标准化、颗粒物质表征、毒理学、暴露评估、建筑材料(包括绿色材料)、建筑物理、工程和建筑设计、执行实验室和室内实验、建模研究和与室内空气质量相关的测量方面的专家,包括室外空气化学家。这一行动显著推进了室内空气污染科学领域,突出了未来的研究领域,并旨在弥合研究与商业之间的差距。通过这种方式,我们将能够确定适当的缓解策略,优化室内空气质量。我们行动的目标之一是在给定具体要求(研究问题、可用资金、建筑物位置和特征等)的情况下,探索测量主要室内空气污染物的最佳方法。因此,本期特刊总结了目前可用于室内空气测量的各种测量技术以及每种测量技术在室内环境中的优缺点。欲了解更多信息,请访问:https://indairpollnet.eu/
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引用次数: 0
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Applied Spectroscopy Reviews
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