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Development of a Machine Learning (ML)-Based Computational Model to Estimate the Engineering Properties of Portland Cement Concrete (PCC) 开发基于机器学习 (ML) 的计算模型以估算波特兰水泥混凝土 (PCC) 的工程特性
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-05-03 DOI: 10.1007/s13369-024-08794-0
Rodrigo Polo-Mendoza, Gilberto Martinez-Arguelles, Rita Peñabaena-Niebles, Jose Duque

Portland cement concrete (PCC) is the construction material most used worldwide. Hence, its proper characterization is fundamental for the daily-basis engineering practice. Nonetheless, the experimental measurements of the PCC’s engineering properties (i.e., Poisson’s Ratio -v-, Elastic Modulus -E-, Compressive Strength -ComS-, and Tensile Strength -TenS-) consume considerable amounts of time and financial resources. Therefore, the development of high-precision indirect methods is fundamental. Accordingly, this research proposes a computational model based on deep neural networks (DNNs) to simultaneously predict the v, E, ComS, and TenS. For this purpose, the Long-Term Pavement Performance database was employed as the data source. In this regard, the mix design parameters of the PCC are adopted as input variables. The performance of the DNN model was evaluated with 1:1 lines, goodness-of-fit parameters, Shapley additive explanations assessments, and running time analysis. The results demonstrated that the proposed DNN model exhibited an exactitude higher than 99.8%, with forecasting errors close to zero (0). Consequently, the machine learning-based computational model designed in this investigation is a helpful tool for estimating the PCC’s engineering properties when laboratory tests are not attainable. Thus, the main novelty of this study is creating a robust model to determine the v, E, ComS, and TenS by solely considering the mix design parameters. Likewise, the central contribution to the state-of-the-art achieved by the present research effort is the public launch of the developed computational tool through an open-access GitHub repository, which can be utilized by engineers, designers, agencies, and other stakeholders.

硅酸盐水泥混凝土(PCC)是全世界使用最多的建筑材料。因此,对其进行正确表征是日常工程实践的基础。然而,对 PCC 的工程特性(即泊松比 -v-、弹性模量 -E-、抗压强度 -ComS- 和抗拉强度 -TenS-)进行实验测量需要耗费大量的时间和财力。因此,开发高精度的间接方法至关重要。因此,本研究提出了一种基于深度神经网络(DNN)的计算模型,用于同时预测 v、E、ComS 和 TenS。为此,采用了长期路面性能数据库作为数据源。在这方面,采用了 PCC 的混合设计参数作为输入变量。通过 1:1 线、拟合优度参数、Shapley 加性解释评估和运行时间分析,对 DNN 模型的性能进行了评估。结果表明,所提出的 DNN 模型的精确度高于 99.8%,预测误差接近零(0)。因此,在无法进行实验室测试的情况下,本研究设计的基于机器学习的计算模型是估算 PCC 工程特性的有用工具。因此,本研究的主要创新点在于创建了一个稳健的模型,只需考虑混合料设计参数即可确定 v、E、ComS 和 TenS。同样,本研究工作对最先进技术的核心贡献在于通过开放访问的 GitHub 存储库公开发布了所开发的计算工具,可供工程师、设计师、机构和其他利益相关者使用。
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引用次数: 0
Improved Cuttings Transport in Horizontal Wells: An Experimental Study Using a Clamp-on Tool for Efficient Hole Cleaning 改进水平井的岩屑输送:使用夹持工具高效清孔的实验研究
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-05-03 DOI: 10.1007/s13369-024-09006-5
Jelena Skenderija, Alexis Koulidis, Mehmet Sorgun, Shehab Ahmed

In horizontal well operations, the prevalence of stuck pipe incidents is largely attributed to inadequate hole cleaning, underscoring the critical need for a thorough understanding of this process to mitigate non-productive time and financial losses. Increasing fluid velocity, the major drilling parameter of hole cleaning, diminishes the formation of cuttings beds in a wellbore. This study primarily centered on the mechanical displacement and removal of solid particles, employing advanced image processing techniques to elucidate the dynamic behavior of solid particles in deviated wellbores. The core objective of this study was to experimentally scrutinize the effects of a downhole clamp-on tool on fluid velocity to improve hole cleaning practices. To address this challenge, a customized flow loop was designed and constructed to accurately replicate the conditions encountered in horizontal wells. Pure water was used to demonstrate the effects of the clamp-on tool on cuttings transport for lightweight drilling fluid conditions. Strategically deployed, the clamp-on tool played a pivotal role in agitating cuttings, mitigating their accumulation at the bottom of the borehole. The tool's agitation mechanism noticeably improved cuttings removal by increasing velocity, extending the perturbation of cuttings transport in the tool's downstream flow, and reducing bedding formation. At lower flow rates, the tool led to an over fourfold increase in average particle velocity within the tool and a twofold increase after the tool. Our results demonstrate the substantial potential of mechanical assistance to address hole cleaning challenges and significantly advance horizontal well operations.

在水平井作业中,卡管事故频发的主要原因是清孔不彻底,这说明亟需全面了解这一过程,以减少非生产时间和经济损失。提高清孔的主要钻井参数--流体速度,可以减少井筒中沉积物的形成。这项研究主要围绕固体颗粒的机械位移和清除,采用先进的图像处理技术来阐明固体颗粒在偏斜井筒中的动态行为。这项研究的核心目标是通过实验仔细研究井下夹持工具对流体速度的影响,以改进井眼清理方法。为了应对这一挑战,我们设计并建造了一个定制的流动回路,以精确复制水平井中遇到的情况。在轻质钻井液条件下,使用纯水来演示夹持工具对岩屑输送的影响。通过战略部署,夹持工具在搅拌钻屑、减少钻屑在井底堆积方面发挥了关键作用。钻具的搅拌机制通过提高流速、延长钻具下游流体中泥屑输送的扰动时间以及减少垫层形成,明显改善了泥屑清除效果。在流速较低的情况下,工具内的颗粒平均速度提高了四倍多,工具后的颗粒平均速度提高了两倍。我们的研究结果表明,机械辅助工具在解决清孔难题和大幅推进水平井作业方面具有巨大潜力。
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引用次数: 0
Spectrochemical Analysis of Stainless Steel Using 355 nm and 1064 nm Nd:YAG Laser-induced Breakdown Spectroscopy 利用 355 nm 和 1064 nm Nd:YAG 激光诱导击穿光谱分析不锈钢的光谱化学性质
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-05-02 DOI: 10.1007/s13369-024-09015-4
Ali Khumaeni, Wahyu Setia Budi, Rinda Hedwig, M. A. Gondal, Koo Hendrik Kurniawan, Masahiko Tani

Stainless steel is a notably beneficial product and is widely used in many applications. Controlling the quality of steel products by determining their trace elemental content is essential. The content of trace elements such as Cr in steel protects the alloy from corrosion and enhances its lifetime, especially in the case of steel embedded in concrete structures. This article presents a quantitative analysis of the trace element Cr in steel samples using advanced laser-induced breakdown spectroscopy (LIBS) with an Nd:YAG laser at wavelengths of 355 and 1064 nm. The LIBS emission intensity of Cr at a laser wavelength of 355 nm was improved compared to that at 1064 nm. Notably, the calibration curves exhibit a zero intercept using the LIBS technique at the third harmonic (355 nm) and fundamental (1064 nm) wavelengths generated by the Nd:YAG laser. The detection limits for Cr in steel were determined as 21 and 36 parts per million using the laser wavelengths of 355 and 1064 nm, respectively. This study demonstrated that the wavelength of 355 nm is significantly more suitable for the quantitative analysis of stainless steel than 1064 nm in laser-induced spectroscopy.

不锈钢是一种非常有益的产品,被广泛应用于许多领域。通过测定微量元素含量来控制钢制品的质量至关重要。钢中微量元素(如铬)的含量可保护合金免受腐蚀并延长其使用寿命,尤其是在钢嵌入混凝土结构中的情况下。本文采用先进的激光诱导击穿光谱(LIBS)技术,利用波长为 355 纳米和 1064 纳米的 Nd:YAG 激光对钢材样品中的微量元素铬进行了定量分析。与波长为 1064 nm 的激光相比,波长为 355 nm 的激光诱导击穿光谱的铬发射强度有所提高。值得注意的是,在 Nd:YAG 激光产生的三次谐波波长(355 nm)和基波波长(1064 nm)处,使用 LIBS 技术得到的校准曲线截距为零。使用波长为 355 nm 和 1064 nm 的激光,钢中铬的检测限分别为百万分之 21 和百万分之 36。这项研究表明,在激光诱导光谱法中,355 nm 波长比 1064 nm 波长更适合不锈钢的定量分析。
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引用次数: 0
Parametric Study for the Behavior of Blocks Anchor Embedded in Sand at Various Conditions 不同条件下嵌入沙中的块锚行为的参数研究
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-05-02 DOI: 10.1007/s13369-024-09048-9
Naser Al-Shayea, Alsidqi Hasan

Anchors embedded in soil are used to restrain horizontal movement of structures, especially pipelines. Block anchors are not thoroughly studied in the literature as compared to plate anchors. This research paper intended to address this gap and contribute to the field by studying various parameters influencing the behavior of block anchors embedded in sand when subjected to a horizontal load. The behavior focuses on the pullout capacity and displacements/rotation of the block anchor, and the failure mode of the soil. The parameters studied include width, depth, and thickness of the block; depth of embedment below the ground surface; location of the pulling load; and the degree of saturation of the soil. The rigorous research methodology consists of numerical, analytical, and experimental approaches. First, the analytical calculations were based on Rankine, Coulomb, and log spiral theories to obtain values for the pullout capacity, for the 3-D magnification factor, and for the mobilized friction angle. Second, the experimental work included pullout tests, made in the laboratory, on concrete block anchors of various dimensions and on steel plate anchors, embedded in sand at two different depths. The sand was deposited in a box by pluviation to ensure a uniform and reproducible density. Materials properties were determined, and instruments were calibrated. The load and the corresponding horizontal and vertical displacements were recorded, and visual observations of the failed soil surface were captured. Finally, the numerical computations used PLAXIS program for the 2-D cases to obtain the pullout capacity and the deformation for long anchors. The main findings of this study show that the block anchor has a higher pullout capacity than a plate anchor; and the depth of embedment and the moisture condition of the sand significantly affect the pullout capacity, while the thickness of the block and the exact location of the load do not significantly affect the capacity. The capacity of a short block anchor per unit width decreases with increasing width, as the 3-D effect reduces. With reference to dry sand, the capacity of the anchor is doubled if the sand is unsaturated/wet, but it is reduced to only one half if the sand is saturated. The experimental results were compared with the analytical calculations and also with the numerical computations. The analytical results were also utilized for the experimental design. The results of numerical computations were used to validate the experimental design and to explain experimental findings, especially failure mode and deformation. The findings of this research are also compared with other studies reported in the literature. These findings have very significant implications to the analysis and design of the block anchor. They also contribute to the hazard risk assessment of block anchors embedded in sand subjected to variations in the environmental condition of wetting and drying cycles.

嵌入土壤中的锚固件用于限制结构(尤其是管道)的水平移动。与板锚相比,文献中对块锚的研究不够深入。本研究论文旨在弥补这一空白,并通过研究影响嵌入砂中的块状锚固件在承受水平荷载时的行为的各种参数,为该领域做出贡献。该行为的重点是块锚的拉拔能力和位移/旋转,以及土壤的破坏模式。研究的参数包括锚块的宽度、深度和厚度;地表以下的嵌入深度;拉荷载的位置;以及土壤的饱和度。严谨的研究方法包括数值、分析和实验方法。首先,根据朗肯理论、库仑理论和对数螺旋理论进行分析计算,得出拉拔能力值、三维放大系数值和动员摩擦角值。其次,实验工作包括在实验室中对不同尺寸的混凝土块锚固件和钢板锚固件进行拉拔试验,这些锚固件分别嵌入两种不同深度的沙子中。沙子是用碾压法沉积在一个盒子里的,以确保密度均匀且可重复。对材料特性进行了测定,并对仪器进行了校准。记录了荷载以及相应的水平和垂直位移,并对破坏的土壤表面进行了目视观察。最后,使用 PLAXIS 程序对二维情况进行了数值计算,以获得长锚的拉拔能力和变形。研究的主要结果表明,块体锚固比板式锚固具有更高的抗拔能力;埋入深度和砂的湿度条件对抗拔能力有显著影响,而块体的厚度和荷载的确切位置对抗拔能力没有显著影响。由于三维效应减弱,短块锚固件单位宽度的承载力随着宽度的增加而降低。以干沙为例,如果沙子是非饱和/湿的,锚杆的承载力就会增加一倍,但如果沙子是饱和的,承载力就会减少到二分之一。实验结果与分析计算结果以及数值计算结果进行了比较。分析结果也被用于实验设计。数值计算结果用于验证实验设计,并解释实验结果,尤其是失效模式和变形。研究结果还与文献中报道的其他研究结果进行了比较。这些研究结果对块锚的分析和设计具有非常重要的意义。它们还有助于对嵌入砂中的块状锚固件在潮湿和干燥循环的环境条件变化下进行危险风险评估。
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引用次数: 0
A Modified Drucker–Prager Model Considering Tensile Strength Reduction and Its Applications in Slope Stability Analysis 考虑抗拉强度降低的德鲁克-普拉格模型及其在边坡稳定性分析中的应用
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-04-29 DOI: 10.1007/s13369-024-09016-3
Jiayu Qin, Nengxiong Xu, Gang Mei

The strength reduction method plays a crucial role in the slope stability analysis. Generally, the Mohr–Coulomb (MC) model is commonly used to analyze slope stability. However, the MC model has the computational nonconvergence problem and the overestimated tensile strength. Usually, the Drucker–Prager (DP) model can be used to approximate the MC model on the ({pi }) plane utilizing a circle, which can improve the computational nonconvergence problem. However, the DP yield surface still has a corner on the meridian plane, which results in computational instability in extreme circumstances and requires special attention. Additionally, the DP model overestimates the tensile strength. Another work is the modified MC model, which can enhance the computational stability and describe the tensile strength reasonably. However, the implementation of the modified MC model is uneasy due to its complex derivatives. For both the DP model and the MC model, another problem is that the tensile strength does not exist explicitly in the yield function and cannot be reduced directly, which restricts their applications. To address these problems, this paper proposes a modified Drucker–Prager (DP) model, which is easy to implement, numerically stable, and capable of adjusting the tensile strength. Moreover, a strength reduction method considering tensile strength reduction is proposed, which is applicable to the proposed modified DP model and the modified MC model. Finally, the numerical tests demonstrate the effectiveness of the proposed methods. These methods serve as a beneficial supplement to the MC and DP models in slope stability analysis.

强度降低方法在斜坡稳定性分析中起着至关重要的作用。一般来说,莫尔-库仑(Mohr-Coulomb,MC)模型常用于分析斜坡稳定性。然而,MC 模型存在计算不收敛问题和高估抗拉强度的问题。通常情况下,Drucker-Prager(DP)模型可用于在利用圆的({pi } )平面上近似 MC 模型,从而改善计算不收敛问题。然而,DP屈服面在子午面上仍有一个角,在极端情况下会导致计算不稳定,需要特别注意。此外,DP 模型高估了抗拉强度。另一项工作是修正 MC 模型,它可以增强计算稳定性并合理描述抗拉强度。然而,由于修正 MC 模型的导数比较复杂,因此实施起来并不容易。对于 DP 模型和 MC 模型,另一个问题是抗拉强度并不明确存在于屈服函数中,无法直接还原,这限制了它们的应用。针对这些问题,本文提出了一种改进的德鲁克-普拉格(DP)模型,该模型易于实现,数值稳定,并能调整抗拉强度。此外,还提出了一种考虑抗拉强度降低的强度降低方法,该方法适用于所提出的改进型 DP 模型和改进型 MC 模型。最后,数值试验证明了所提方法的有效性。这些方法可作为斜坡稳定性分析中 MC 和 DP 模型的有益补充。
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引用次数: 0
Comparison of Water-Based Drilling Muds with Hydroxyapatite Nanoparticles and Copper II Oxide Nanoparticles for Lifting Cuttings Through Rotating Drill Pipes at Different Hole Inclinations 含羟基磷灰石纳米颗粒和 II 氧化铜纳米颗粒的水基钻井泥浆在不同钻孔倾角下通过旋转钻杆提升切屑的比较
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-04-28 DOI: 10.1007/s13369-024-09007-4
Jeffrey O. Oseh, M. N. A. M. Norddin, Ugochukwu I. Duru, Issham Ismail, Eugene N. Ngouangna, Muftahu N. Yahya, Afeez O. Gbadamosi, Augustine Agi, Jude E. Odo, Frank O. Ofowena, Usman B. Ndagi

Drilling deviated wellbores has raised concerns about proper cutting transport. Cuttings settling downhole can create stationary cutting beds, causing drilling mishaps like stuck pipes. High fluid velocity is typically required to efficiently erode a stationary bed, but this is constrained by hydraulic and wellbore geometry. When this occurs, pipe rotation can erode the bed mechanically and enable efficient cutting transport even with lower fluid velocities. Therefore, this study formulated water-based mud (WBM) with hydroxyapatite nanoparticles (n-HAp) to examine the effect of pipe rotation on cutting transport in deviated wells. It was compared with copper II oxide nanoparticles (CuO NP) in terms of rheology, filtration, and cutting transfer efficiency (CTE). The CTE of n-HAp amounts (0.4–2.0 g) in moving cuttings with diameters of 0.80 to 3.60 mm through deviated wellbores of 40 to 65° at a 3.5 m/s fluid velocity with 60 and 120 rpm pipe rotation speeds was determined. Compared with CuO NP, n-HAp findings demonstrated enhanced rheology and CTE. However, for fluid loss control, n-HAp was slightly less effective compared to CuO NP. For all deviated angles, n-HAp increased the CTE by 9.5–50%, while CuO NP increased it by 3.4–38.7% at 120 rpm. Compared with 60 rpm, a higher CTE occurred at 120 rpm. Moreover, CTE occurs in the following manner: 40° > 65° > 45° > 60° > 50° > 55°. It suggests that stationary bed formation is more likely to occur at inclinations of 50–55°. These findings are crucial for drilling deviated wells.

钻偏斜井筒引起了人们对正确切割运输的关注。沉淀在井下的切屑会形成固定的切削层,造成卡管等钻井事故。通常需要较高的流体速度才能有效地侵蚀固定切削层,但这受到水力和井筒几何形状的限制。当出现这种情况时,管道旋转可以机械地侵蚀井床,即使流体速度较低,也能实现高效的切割输送。因此,本研究在水基泥浆(WBM)中添加了羟基磷灰石纳米颗粒(n-HAp),以研究管道旋转对偏差井中切割输送的影响。在流变性、过滤性和切割传输效率(CTE)方面,将其与纳米氧化铜颗粒(CuO NP)进行了比较。在流体速度为 3.5 米/秒、管道旋转速度为 60 和 120 转/分钟的条件下,测定了 n-HAp 量(0.4-2.0 克)在直径为 0.80 至 3.60 毫米的切屑通过 40 至 65° 的偏斜井筒时的 CTE。与 CuO NP 相比,n-HAp 的流变性和 CTE 均有所提高。然而,在流体损失控制方面,n-HAp 的效果略逊于 CuO NP。在所有偏差角度下,n-HAp 使 CTE 增加了 9.5-50%,而 CuO NP 在 120 rpm 时使 CTE 增加了 3.4-38.7%。与 60 rpm 相比,120 rpm 时的 CTE 值更高。此外,CTE 以下列方式发生:40° > 65° > 45° > 60° > 50° > 55°。这表明,在倾角为 50-55° 时更容易形成固定床。这些发现对于钻探偏斜井至关重要。
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引用次数: 0
Study of the Effect of Acid Number on the Interfacial Tension Between Carbon Dioxide and Different Combinations of Diesel Fuel and Gasoline at Different Pressures 研究酸值对不同压力下二氧化碳与不同柴油和汽油组合之间界面张力的影响
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-04-28 DOI: 10.1007/s13369-024-09031-4
Mohammad Reza Zaeri, Feridun Esmaeilzadeh, Mohammad Noor Ghasemi, Abbas Elhambakhsh, G. Reza Vakili-Nezhaad

The process of injecting carbon dioxide (CO2) into oil reservoirs involves intricate interactions between the reservoir’s hydrocarbons and CO2, resulting in changes to various physiochemical properties such as interfacial tension (IFT) between complex acidic hydrocarbons and CO2. The IFT plays a crucial role in enhanced oil recovery by altering capillary force. Hydrocarbon mixtures usually contain a percentage of acidic organic compounds that pose a crucial effect on IFT measurement. In this study, benzoic acid was chosen as a representative of acidic compounds to study the effect of acid number (0.0–0.8 g/L) on the IFT between CO2 and different combinations of diesel fuel (representing aliphatic hydrocarbons) and gasoline (representing aromatic hydrocarbons). The volume ratios of the mixtures were varied at 0:100, 25:75, 50:50, 75:25 and 100:0%. Results revealed that increasing the acid number in gasoline from 0.2 to 0.8 g/L led to a significant change of more than 10 dyne/cm in the IFT between aromatic hydrocarbons and CO2. On the other hand, IFT alteration for aliphatic hydrocarbons was observed to be up to 5 dyne/cm. A new correlation for estimating IFT between CO2 and different hydrocarbons was also proposed with an average relative error of less than 9%.

向油藏注入二氧化碳(CO2)的过程涉及油藏碳氢化合物与二氧化碳之间错综复杂的相互作用,从而导致各种理化性质发生变化,例如复合酸性碳氢化合物与二氧化碳之间的界面张力(IFT)。通过改变毛细管力,IFT 在提高石油采收率方面发挥着至关重要的作用。碳氢化合物混合物中通常含有一定比例的酸性有机化合物,它们对 IFT 测量具有重要影响。本研究选择苯甲酸作为酸性化合物的代表,研究酸数(0.0-0.8 g/L)对二氧化碳与柴油(代表脂肪族碳氢化合物)和汽油(代表芳香族碳氢化合物)不同组合之间的 IFT 的影响。混合物的体积比分别为 0:100、25:75、50:50、75:25 和 100:0%。结果显示,将汽油中的酸数从 0.2 克/升增加到 0.8 克/升会导致芳香烃和二氧化碳之间的 IFT 发生超过 10 达因/厘米的显著变化。另一方面,脂肪族碳氢化合物的 IFT 变化最多为 5 达因/厘米。此外,还提出了一种用于估算二氧化碳和不同碳氢化合物之间 IFT 的新相关性,其平均相对误差小于 9%。
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引用次数: 0
Exploring Machine Learning Techniques for Accurate Prediction of Methane Hydrate Formation Temperature in Brine: A Comparative Study 探索用于准确预测卤水中甲烷水合物形成温度的机器学习技术:比较研究
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-04-27 DOI: 10.1007/s13369-024-09030-5
Waqas Aleem, Sheraz Ahmad, Sabih Qamar, Maham Hussain, Omer Ali, Abdul Rauf

Accurate estimation of formation conditions plays a pivotal role in effectively managing various processes related to hydrates, including flow assurance, deep-water drilling, and hydrate-based technology development. The formation temperature of methane hydrates in the presence of brine greatly affects the efficacy and accuracy of these processes. This work presents a comprehensive and novel comparative analysis of nine distinct machine learning models for accurate prediction of formation temperatures of methane hydrate. This study investigated the application of major machine learning (ML) algorithms including multiple linear regression (MLR), long short-term memory (LSTM), radial basis function (RBF), support vector machine (SVM), artificial neural network (ANN), gradient boosting regression (GBR), gradient process regression (GPR), random forest (RF), and K-nearest neighbor (KNN). The model accuracy was validated against a large dataset comprising of over 1000 data points with diverse range of salt concentrations. In this regard, model accuracies were compared using several metrics including R2, ARD, and AARD. The experimental results exhibited KNN algorithm to be fast-converging, accurate, and consistent over the entire range of data points with an R2 score of 0.975 and AARD of 0.385%. The results enable efficient and accurate temperature estimation with ML algorithms for multiple hydrate-related processes.

准确估算地层条件对于有效管理与水合物有关的各种流程(包括流量保证、深水钻探和基于水合物的技术开发)起着至关重要的作用。存在盐水的甲烷水合物的地层温度在很大程度上影响着这些过程的有效性和准确性。本研究对九种不同的机器学习模型进行了全面而新颖的比较分析,以准确预测甲烷水合物的形成温度。这项研究调查了主要机器学习 (ML) 算法的应用情况,包括多元线性回归 (MLR)、长短期记忆 (LSTM)、径向基函数 (RBF)、支持向量机 (SVM)、人工神经网络 (ANN)、梯度提升回归 (GBR)、梯度过程回归 (GPR)、随机森林 (RF) 和 K-nearest neighbor (KNN)。模型的准确性通过一个大型数据集进行了验证,该数据集由 1000 多个数据点组成,盐浓度范围各不相同。在这方面,使用 R2、ARD 和 AARD 等多个指标对模型准确性进行了比较。实验结果表明,KNN 算法在整个数据点范围内具有快速收敛性、准确性和一致性,R2 得分为 0.975,AARD 为 0.385%。这些结果使得使用 ML 算法对多种水合物相关过程进行高效、准确的温度估算成为可能。
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引用次数: 0
Hydrocracking of Crude Oil Recovered from Ixachi Onshore Field: Kinetic Modeling by Lumping Approach 伊萨奇陆上油田开采的原油的加氢裂化:采用结块法建立动力学模型
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-04-26 DOI: 10.1007/s13369-024-09053-y
Luis A. Soto-Azuara, J. Felipe Sánchez-Minero, Ignacio Elizalde

The purpose of this work was to obtain the kinetic model parameters of hydrocracking of crude oil recovered from Ixachi onshore well, México. Recovered crude oil was purified to remove water and sediments, and then, the feedstock was subject of hydrocracking at 395 and 410 °C of reaction temperature, 1000 psi of initial hydrogen pressure, 0.84 wt.% catalyst-to-oil, stirring at 750 rpm, by using a batch reactor of 100 mL. The reaction time was varied from 1 to 4 h for each reaction temperature. 40/60 mesh NiMo supported ZSM-5 catalyst was used, firstly activated in gas phase by using 15 vol% H2S/85 vol% H2. The parameter estimation for kinetic modeling of hydrocracking was carried out using a nonlinear algorithm and five lumps. The experimental data demonstrated that, as reaction time increased, the naphtha and kerosene fraction increased, while residue cut was reduced, being the yields higher at 410 °C in any case compared with those yields at 395 °C. The secondary hydrocracking was more evident for light gasoil, and heavy gas oil cuts at the two reaction temperatures. Regarding the kinetic modeling, the overall error of estimation of kinetic parameters was 0.24 and the coefficient of determination of the linear regression of the parity graph was 0.9919 at confidence interval of 95%; the values of the activation energies ranged from 31 to 297 kJ/mol.

这项工作的目的是获得从墨西哥 Ixachi 陆上油井回收的原油加氢裂化的动力学模型参数。回收的原油经过净化以去除水分和沉淀物,然后,使用 100 mL 的间歇式反应器在 395 和 410 °C 的反应温度、1000 psi 的初始氢气压力、0.84 wt.% 催化剂对油、750 rpm 的搅拌条件下对原料进行加氢裂化。在每个反应温度下,反应时间从 1 小时到 4 小时不等。使用 40/60 目 NiMo 支承的 ZSM-5 催化剂,首先在气相中使用 15 Vol% H2S/85 Vol% H2 进行活化。加氢裂化动力学模型的参数估计采用了非线性算法和五个块体。实验数据表明,随着反应时间的延长,石脑油和煤油馏分增加,而残渣减少,与 395 °C 时的产率相比,410 °C 时的产率更高。在两种反应温度下,轻质气油和重质气油的二次加氢裂化更为明显。在动力学建模方面,动力学参数估计的总误差为 0.24,在置信区间为 95% 的情况下,奇偶图线性回归的确定系数为 0.9919;活化能的值范围为 31 至 297 kJ/mol。
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引用次数: 0
A Novel Repair Technique of Pre-damaged T-Beams Failing in Shear Using Eco-Friendly Steel Fibre-Reinforced Geopolymer Concrete 使用生态友好型钢纤维增强土工聚合物混凝土修复剪切失效的预损坏 T 型梁的新型修复技术
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-04-24 DOI: 10.1007/s13369-024-08842-9
Ashraf J. Khalifa, Abo El-Wafa M. El-Thakeb, Ahmed M. El-Sebai, Ahmed S. Elmannaey
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引用次数: 0
期刊
Arabian Journal for Science and Engineering
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