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Development and Performance Evaluation of Waste Concrete Powder-Based Geopolymer Recycled Concrete 基于废弃混凝土粉末的土工聚合物再生混凝土的开发与性能评估
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-09-09 DOI: 10.1007/s13369-024-09376-w
Liu Yang, Zhiduo Zhu, He Sun, Wangwen Huo, Yu Wan, Chen Zhang

To achieve a green recycled concrete with excellent mechanical properties and workability, this paper utilized recycled concrete powder, fly ash and granulated ground blast furnace slag as primary materials. Recycled concrete aggregates served as coarse aggregates in the formulation of a recycled concrete powder-based geopolymer recycled concrete (RCPGRC). The study investigated the impact of additional water consumption (AWC), recycled fine aggregate content (RFAC) and the mass ratio of solid powder to aggregate (P/A) on both the mechanical property and workability of RCPGRC. Employing variance and range analysis, the research comprehensively assessed the contributing factors to the concrete's performance and identified the optimum mixture ratio. Characterization of the phase composition and micromorphology were characterized through X-ray diffraction and scanning electron microscopy. The results show that: (1) The AWC had the greatest influence on the unconfined compressive strength (UCS), slump, and setting times, while RFAC and P/A were smaller. AWC of 3%, RFAC of 10%, and P/A of 26% were the inflection points of the UCS, slump, and setting times with AWC, RFAC, and P/A, respectively. (2) The production rate and quantity of geopolymer gels production, as well as the cracks and voids, were affected when the mixture ratios deviated from these optimal inflection points. (3) These inflection points can be utilized as the indexes for rapid judge the optimum mixture ratio of RCPGRC.

为了获得具有优异机械性能和工作性的绿色再生混凝土,本文采用了再生混凝土粉、粉煤灰和粒化高炉矿渣作为主要材料。再生混凝土骨料在基于再生混凝土粉的土工聚合物再生混凝土(RCPGRC)配方中用作粗骨料。研究调查了额外用水量(AWC)、再生细骨料含量(RFAC)和固体粉末与骨料的质量比(P/A)对 RCPGRC 机械性能和工作性的影响。研究采用方差和范围分析法,全面评估了影响混凝土性能的因素,并确定了最佳混合比。通过 X 射线衍射和扫描电子显微镜对相组成和微观形态进行了表征。结果表明(1) AWC 对无压抗压强度(UCS)、坍落度和凝结时间的影响最大,而 RFAC 和 P/A 的影响较小。AWC 为 3%、RFAC 为 10%、P/A 为 26% 分别是无收缩抗压强度、坍落度和凝结时间随 AWC、RFAC 和 P/A 变化的拐点。(2)当混合比偏离这些最佳拐点时,土工聚合物凝胶的生产率和生产量以及裂缝和空隙都会受到影响。(3)这些拐点可作为快速判断 RCPGRC 最佳混合比的指标。
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引用次数: 0
Facile Synthesis and Characterization of Copper Phosphide Nanoparticles as Efficient Electrocatalyst for Hydrogen and Oxygen Evolution Reaction 磷化铜纳米粒子的简便合成与表征--作为氢氧进化反应的高效电催化剂
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-09-09 DOI: 10.1007/s13369-024-09514-4
Muhammad Rizwan Shakir, Samina Akbar, Imran Raza, Muhammad Awais, Saima Rehman

Electrocatalytic water splitting has been considered as one of the most significant and sustainable approaches for hydrogen production. To make the process more efficient and affordable, there is a need to develop robust, cheap, highly active and stable electrocatalysts. Herein, facile synthesis of copper phosphide nanoparticles (Cu3P NPs) with size ranging from 30 to 80 nm was carried out by using solvothermal process. Variety of characterization techniques like FTIR, XRD, Raman spectroscopy, dynamic light scattering and SEM–EDX, verified the successful synthesis of Cu3P NPs with spherical morphology. Three-electrode system containing glassy carbon, platinum mesh and Hg/HgO as working, counter and reference electrode, respectively, was used for the electrochemical characterization. Electrochemical studies, i.e., CV, LSV and chronoamperometric analysis, revealed efficiency and stability of electrocatalyst for electrolysis of water including hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Briefly, the Cu3P NPs exhibited an excellent OER activity, achieving the current density of 10 mA cm−2 with an overpotential of 450 mV. Tafel slope value 63 mV dec−1 suggested fast OER reaction kinetics. The Cu3P catalyst also exhibited significant HER activity, approaching a current density of 10 mA cm−2 with an overpotential of 447 mV. Fast HER reaction kinetics was observed with a Tafel slope value of 132 mV dec−1. Moreover, the chronoamperometric studies revealed the stability of electrocatalyst providing favorable conditions for sustainable, long-term oxygen and hydrogen production.

电催化水分离被认为是最重要和最可持续的制氢方法之一。为了使这一过程更高效、更经济,有必要开发坚固、廉价、高活性和稳定的电催化剂。在此,我们采用溶解热工艺轻松合成了尺寸为 30 至 80 纳米的磷化铜纳米颗粒(Cu3P NPs)。傅立叶变换红外光谱(FTIR)、X射线衍射(XRD)、拉曼光谱、动态光散射和扫描电子显微镜(SEM-EDX)等多种表征技术验证了球形形态的 Cu3P NPs 的成功合成。电化学表征采用了三电极系统,分别以玻璃碳、铂网和 Hg/HgO 作为工作电极、对电极和参比电极。电化学研究,即 CV、LSV 和时变分析,揭示了电催化剂在电解水(包括氢进化反应(HER)和氧进化反应(OER))方面的效率和稳定性。简而言之,Cu3P NPs 表现出优异的 OER 活性,在 450 mV 的过电位下电流密度达到 10 mA cm-2。塔菲尔斜率值为 63 mV dec-1,表明 OER 反应动力学速度很快。Cu3P 催化剂也表现出显著的 HER 活性,电流密度接近 10 mA cm-2,过电位为 447 mV。观察到快速的 HER 反应动力学,Tafel 斜率值为 132 mV dec-1。此外,时变研究表明,电催化剂具有稳定性,为可持续的、长期的氧气和氢气生产提供了有利条件。
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引用次数: 0
I-CNN-LSTM: An Improved CNN-LSTM for Transient Stability Analysis of More Electric Aircraft Power Systems I-CNN-LSTM:用于更多电动飞机动力系统瞬态稳定性分析的改进型 CNN-LSTM
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-09-08 DOI: 10.1007/s13369-024-09531-3
Cong Gao, Hongjuan Ge

High-power nonlinear load characteristics are one of the typical characteristics of multi-electric aircraft power systems. The study provides an improved CNN-LSTM stability analysis method for solving the stability problem of the aircraft power system caused by high-power nonlinear load switching. To address the issue of sample imbalance, this approach creatively incorporates the cost factor into the CNN loss function. In order to handle the issue of computational complexity, the projection layer is added to the LSTM, and a methodology known as CNN-LSTMP is proposed. This algorithm solves the problems of low computational efficiency and huge computational volume. The time series data utilized by the experiment are created by simulating the transient switching process. The data are then labeled, normalized, and model training is carried out. A deep learning algorithm that satisfies the prediction requirements can be created by applying this method to the established simulation model of a multi-electric aircraft power system for stability analysis. According to the results of the experiments, this method’s transient stability analysis accuracy is 93.32%, which has a positive impact on transient analysis and may satisfy application requirements.

大功率非线性负载特性是多电飞机电力系统的典型特性之一。本研究提供了一种改进的 CNN-LSTM 稳定性分析方法,用于解决大功率非线性负载切换引起的飞机电力系统稳定性问题。为解决样本不平衡问题,该方法创造性地在 CNN 损失函数中加入了成本因子。为了解决计算复杂性问题,在 LSTM 中加入了投影层,并提出了一种称为 CNN-LSTMP 的方法。该算法解决了计算效率低和计算量大的问题。实验使用的时间序列数据是通过模拟瞬态切换过程创建的。然后对数据进行标记、归一化,并进行模型训练。将该方法应用于已建立的多电飞机电力系统仿真模型,进行稳定性分析,可以创建满足预测要求的深度学习算法。实验结果表明,该方法的瞬态稳定性分析准确率为 93.32%,对瞬态分析有积极影响,可以满足应用要求。
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引用次数: 0
Numerical Analysis of Hydrogen-Enriched Natural Gas on Combustion and Emission Characteristics 富氢天然气燃烧和排放特性的数值分析
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-09-07 DOI: 10.1007/s13369-024-09484-7
Radovan Nosek, Branislav Zvada, Peter Ďurčanský, Nikola Čajová Kantová, Pavol Mičko

The integration of hydrogen into natural gas infrastructure presents a viable strategy for mitigating greenhouse gas emissions and advancing toward carbon neutrality. This study investigates the combustion characteristics and emissions profiles of hydrogen-enriched natural gas mixtures, specifically focusing on the composition of Russian pipeline natural gas. A comprehensive mathematical model was developed to predict emission concentrations and simulate fuel mixture combustion using MATLAB Simulink software. This versatile model facilitates further analysis within the MATLAB ecosystem. The simulation results demonstrate a significant correlation between the hydrogen content in the natural gas mixture and the resulting heat power output. With a constant fuel consumption rate, a notable decrease in heat power was observed as the hydrogen concentration increased, reaching a maximum reduction of 44.9% at a 45% hydrogen content. These findings underscore the feasibility of partially substituting natural gas with hydrogen, while also highlighting the necessity for increased fuel flow rates to maintain equivalent power output levels. This poses additional challenges for natural gas grid operators, necessitating infrastructure adaptations to accommodate higher fuel demands. The insights gained from this research contribute to the growing body of knowledge surrounding hydrogen integration in the energy sector, offering valuable implications for decarbonization strategies and the optimization of natural gas infrastructure.

将氢融入天然气基础设施是减少温室气体排放和实现碳中和的可行策略。本研究调查了富氢天然气混合物的燃烧特性和排放概况,特别侧重于俄罗斯管道天然气的成分。使用 MATLAB Simulink 软件开发了一个综合数学模型,用于预测排放浓度和模拟燃料混合物的燃烧。这种多功能模型有助于在 MATLAB 生态系统内进行进一步分析。模拟结果表明,天然气混合物中的氢含量与所产生的热功率输出之间存在明显的相关性。在燃料消耗率不变的情况下,随着氢浓度的增加,热功率明显下降,当氢含量为 45% 时,热功率最大下降 44.9%。这些发现强调了用氢气部分替代天然气的可行性,同时也突出了提高燃料流速以保持同等功率输出水平的必要性。这给天然气电网运营商带来了额外的挑战,需要对基础设施进行调整,以适应更高的燃料需求。这项研究获得的洞察力为能源领域氢能整合方面不断增长的知识做出了贡献,为去碳化战略和天然气基础设施的优化提供了宝贵的启示。
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引用次数: 0
Vibration, Bending, and Buckling of a Seven-Layer Sandwich Beam with Balsa Core Reinforced by Nanocomposite and Shape Memory Alloy Face Sheets Using Piezoelectromagnetic Layers 使用压电磁层对由纳米复合材料和形状记忆合金面片加固的轻木芯材七层夹层梁进行振动、弯曲和屈曲试验
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-09-06 DOI: 10.1007/s13369-024-09491-8
E. Arabzadeh-Ziari, M. Mohammadimehr, M. Arabzadeh-Ziari, M. Asgari

This article discusses the vibration, bending, and buckling analysis of a seven-layer sandwich beam with a balsa wood core reinforced with carbon nanotubes (CNT), shape memory alloy (SMA) nanoparticles, and piezoelectromagnetic layers. The governing equations of motion are obtained using the Hamiltonian principle. To measure the validity of this research, the obtained results are compared with the other results, and the results are in agreement with each other. The primary goal is to enhance the sandwich structure’s strength and rigidity by using CNTs reinforcement and SMA nanoparticles, with the piezoelectromagnetic layers functioning as sensors to improve the overall mechanical performance of the beam The use of CNTs can have a favorable effect on the stiffness of the beam and strength-to-weight ratio and also, the effect of the thickness ratio of core on deflection, critical buckling load, and vibration frequency is significant, so that with a decrease of 11.1% in the thickness ratio, the deflection decreases by about 50.2%, the critical buckling load increases by about 101%, and the vibration frequency increases by about 40.7%. Also, with an increase of 0.5 and 3.5 percent of CNT, the deflection of a sandwich beam reduces by 20 and 50 percent, respectively.

本文讨论了一种七层夹心梁的振动、弯曲和屈曲分析,该梁的芯材是用碳纳米管(CNT)、形状记忆合金(SMA)纳米颗粒和压电磁层增强的轻木。利用哈密顿原理获得了支配运动方程。为了衡量这项研究的有效性,将获得的结果与其他结果进行了比较,结果彼此一致。主要目标是通过使用 CNTs 增强材料和 SMA 纳米粒子来提高夹层结构的强度和刚度,同时压电层作为传感器来提高梁的整体机械性能。 CNTs 的使用对梁的刚度和强度重量比有良好的影响,同时,芯材厚度比对挠度、临界屈曲载荷和振动频率的影响也很显著,因此,当厚度比降低 11.厚度比降低 11.1%,挠度降低约 50.2%,临界屈曲载荷增加约 101%,振动频率增加约 40.7%。此外,随着碳纳米管的含量增加 0.5%和 3.5%,夹层梁的挠度分别减少了 20%和 50%。
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引用次数: 0
Optimizing of Novel Magnetic Field-Assisted Electrical Discharge Turning Parameters for Machining EN24 Steel Alloy Using Response Surface Methodology and MCDM-Based CRITIC–TOPSIS Method 利用响应面方法和基于 MCDM 的 CRITIC-TOPSIS 方法优化加工 EN24 钢合金的新型磁场辅助放电车削参数
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-09-04 DOI: 10.1007/s13369-024-09537-x
Roopak Varshney, Param Singh

This study employs a multi-criteria decision-making (MCDM) technique to identify the optimal parameters for the electrical discharge turning (EDT) process used to machine cylindrical EN24 steel alloy. EDT, a significant configuration of EDM, offers a valuable approach for machining cylindrical workpieces. A face-centred central composite design (FCCCD) is employed to establish the experimental design. The CRITIC–TOPSIS method is subsequently implemented to optimize the input parameters: gap current (Ig), pulse on time (Ton), rotational speed (N), and magnetic field assistance (B). Each parameter is investigated at three distinct levels. The study focuses on four response variables: material removal rate (MRR), tool wear rate (TWR), overcut (OC), and surface roughness (Ra). Analysis of variance (ANOVA) is conducted to assess the influence of each input parameter on the observed responses. Criteria importance through inter-criteria correlation (CRITIC) is employed to assign weights to each response, followed by applying the technique for order of preference by similarity to ideal solution (TOPSIS) to identify the ideal machining parameters. The results indicate that run number 16 (Ig: 16A, Ton: 60 µs, N: 1400 RPM, and B: 0.30 T) represents the optimal configuration. Scanning electron microscopy (SEM) analysis further corroborates this finding, confirming superior surface quality compared to other experimental runs.

本研究采用多标准决策(MCDM)技术来确定用于加工圆柱形 EN24 钢合金的放电加工(EDT)工艺的最佳参数。EDT 是放电加工的一种重要配置,为加工圆柱形工件提供了一种有价值的方法。实验设计采用了面心中心复合设计(FCCCD)。随后采用 CRITIC-TOPSIS 方法优化输入参数:间隙电流 (Ig)、脉冲开启时间 (Ton)、转速 (N) 和磁场辅助 (B)。每个参数都在三个不同的层次上进行研究。研究重点是四个响应变量:材料去除率 (MRR)、刀具磨损率 (TWR)、过切 (OC) 和表面粗糙度 (Ra)。通过方差分析(ANOVA)来评估每个输入参数对观察到的响应的影响。通过标准间相关的标准重要性(CRITIC)为每个响应分配权重,然后应用与理想解决方案相似的优先顺序技术(TOPSIS)来确定理想的加工参数。结果表明,运行编号 16(Ig:16A,Ton:60 µs,N:1400 RPM,B:0.30 T)代表了最佳配置。扫描电子显微镜 (SEM) 分析进一步证实了这一结论,与其他实验运行相比,其表面质量更优。
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引用次数: 0
Pure and Ce-Doped MnO2–ZnO Nanocomposites for Colossal Dielectric Energy Storage and Gas Sensing Applications 纯锰氧化物和掺杂铈的锰氧化物-氧化锌纳米复合材料在巨型介质储能和气体传感中的应用
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-09-03 DOI: 10.1007/s13369-024-09532-2
Ghayah M. Alsulaim, Shada A. Alsharif, Kholoud M. Alnahdi, Hanan A. Althikrallah

ZnO-based nanocomposites have attracted a great attention for energy storage systems and detection of volatile organic compounds. In this study, pure and Ce-doped MnO2–ZnO composites were fabricated through a co-precipitation method. The results of X-ray diffraction verified the formation of tetragonal MnO2 and hexagonal ZnO phases. Scanning electron microscope images of pure and Ce-doped MnO2–ZnO composites displayed the formation of rods and semi-spherical particles. The pure and Ce-doped MnO2–ZnO composites exhibited semi-stable colossal dielectric constant values of 2.12 × 105 and 1.36 × 105, respectively, at a frequency of 45 Hz, which are proper for capacitive energy storage applications. Gas sensing measurements demonstrated that Ce-doped MnO2–ZnO composite has a high sensitivity toward 100 ppm acetone gas at operating temperature of 240 °C, while for 100 ppm ethanol this sensor has a high sensitivity at 180 °C. As a result, through adjusting the operating temperature, the selectivity of Ce-doped MnO2–ZnO sensor can be controlled for acetone and ethanol gases. Furthermore, this sensor possesses good selectivity and stability as well as proper linear relations between the sensitivity and concentrations of acetone and ethanol gases.

氧化锌基纳米复合材料在储能系统和挥发性有机化合物检测方面引起了广泛关注。本研究通过共沉淀法制备了纯 MnO2-ZnO 复合材料和掺杂 Ce 的 MnO2-ZnO 复合材料。X 射线衍射结果验证了四方 MnO2 和六方 ZnO 相的形成。纯 MnO2-ZnO 复合材料和掺杂 Ce 的 MnO2-ZnO 复合材料的扫描电子显微镜图像显示形成了棒状和半球状颗粒。纯 MnO2-ZnO 复合材料和掺杂 Ce 的 MnO2-ZnO 复合材料在 45 Hz 频率下的半稳定巨介电常数值分别为 2.12 × 105 和 1.36 × 105,适合电容式储能应用。气体传感测量表明,掺杂 Ce 的 MnO2-ZnO 复合材料在 240 °C 的工作温度下对 100 ppm 丙酮气体具有高灵敏度,而在 180 °C 的工作温度下对 100 ppm 乙醇具有高灵敏度。因此,通过调节工作温度,可以控制掺杂 Ce 的 MnO2-ZnO 传感器对丙酮和乙醇气体的选择性。此外,这种传感器还具有良好的选择性和稳定性,其灵敏度与丙酮和乙醇气体的浓度呈适当的线性关系。
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引用次数: 0
Use of a Conductive Recycled Mortar as an Anode in the Electrochemical Chloride Extraction in Reinforced Concrete 在钢筋混凝土电化学提取氯化物过程中使用导电回收砂浆作为阳极
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-09-02 DOI: 10.1007/s13369-024-09501-9
M. J. Pellegrini-Cervantes, C. A. Espinoza-Moreno, M. Rodriguez-Rodriguez, C. P. Barrios-Durstewitz, S. P. Arredondo-Rea, R. Corral-Higuera, H. J. Peinado-Guevara, M. J. Chinchillas-Chinchillas, G. Fajardo-San-Miguel

This study advocates for the use of recycled materials, which are more environmentally sustainable as they decrease natural resource consumption. In this research, a mortar anode composed of recycled fine aggregate (RFA) from laboratory concrete blocks, carbon fiber (CF) waste from industrial processes, and graphite powder (GP) was developed, resulting in a conductive recycled mortar (CRM). The manufacturing process utilized Portland composite cement, RFA with a sand/cement ratio of 1.00, a water/cement ratio of 0.6, a GP/cement ratio of 0.50, CF comprising 0.5%, and carboxymethyl cellulose (CMC) comprising 0.4% by weight of cement. Chloride profiles indicated that the specimens with the CRM anode were effective, as the chlorides migrated into the mortar. For M0.5CF (2.81%) and M0.5CF0.5GP (3.72%) of free chlorides, the Ti–RuO2 mesh did not expel the chlorides but rather accumulated them at 1 cm from the surface, resulting in a negative efficiency (− 20.02%). However, at 1 cm from the cathode, the efficiency levels were comparable across the anodes: Ti–RuO2 mesh (84.54%), M0.5CF (84.76%), and M0.5CF0.5GP (81.11%), underscoring the potential of using a CRM anode for electrochemical chloride removal.

本研究提倡使用再生材料,因为它们能减少自然资源的消耗,在环境上更具可持续性。本研究开发了一种砂浆阳极,由实验室混凝土砌块中的再生细骨料(RFA)、工业生产过程中产生的碳纤维(CF)废料和石墨粉(GP)组成,形成了导电再生砂浆(CRM)。生产过程中使用了波特兰复合水泥、砂/水泥比为 1.00 的 RFA、水/水泥比为 0.6、GP/水泥比为 0.50、CF 占水泥重量的 0.5%、羧甲基纤维素 (CMC) 占水泥重量的 0.4%。氯化物曲线表明,使用 CRM 阳极的试样是有效的,因为氯化物迁移到了砂浆中。对于 M0.5CF(2.81%)和 M0.5CF0.5GP(3.72%)的游离氯化物,Ti-RuO2 网片没有将氯化物排出,而是将其积聚在距离表面 1 厘米处,导致负效率(-20.02%)。不过,在距离阴极 1 厘米处,各种阳极的效率水平相当:Ti-RuO2网(84.54%)、M0.5CF(84.76%)和 M0.5CF0.5GP(81.11%),这突出了使用 CRM 阳极进行电化学除氯的潜力。
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引用次数: 0
An Efficient Corrosion Prediction Model Based on Genetic Feedback Propagation Neural Network 基于遗传反馈传播神经网络的高效腐蚀预测模型
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-09-02 DOI: 10.1007/s13369-024-09522-4
Ziheng Zhao, Elmi Bin Abu Bakar, Norizham Bin Abdul Razak, Mohammad Nishat Akhtar

Corrosion is one of the most significant challenges for oil pipelines. It can occur due to various factors such as moisture, oxygen, and contaminants in the oil. Corrosion weakens the pipeline material, leading to leaks, ruptures, and structural failure. To enhance the ability to decrease the corrosion problems of oil pipelines, an efficient Back Propagation Neural Network is developed to predict the corrosion rate and analyse the importance of the features that affect the corrosion. This method is based on the database generated by coupling an analytical corrosion rate model and Monte Carlo simulation by using Spearman’s (SP) correlation coefficient to generate the relevance between each feature, negating the feature variables with a strong correlation and then combining with a Genetic Algorithm (GA) and a Back Propagation (BP) Neural Network to build a regression prediction model. The proposed approach has been termed SP-GA-BP. The results showed that the proposed method can predict well with R2 = 0.99519 MAE = 0.18926 MSE = 0.0072213 RMSE = 0.084978, thereby indicating that the Temperature, CO2 Pressure, and Corrosion Inhibitor efficiency can affect the corrosion rate efficaciously. Furthermore, with the introduction of external interference, the results exhibited a high level of precision. The proposed method and the obtained results may provide a good reference value for oil pipeline maintenance.

腐蚀是石油管道面临的最大挑战之一。发生腐蚀的原因有多种,如水分、氧气和石油中的污染物。腐蚀会削弱管道材料,导致泄漏、破裂和结构失效。为了提高减少石油管道腐蚀问题的能力,开发了一种高效的反向传播神经网络来预测腐蚀率,并分析影响腐蚀的重要特征。该方法基于分析腐蚀率模型和蒙特卡洛模拟耦合生成的数据库,使用斯皮尔曼(SP)相关系数生成每个特征之间的相关性,否定相关性强的特征变量,然后与遗传算法(GA)和反向传播(BP)神经网络相结合,建立回归预测模型。所提出的方法被称为 SP-GA-BP。结果表明,所提出的方法预测效果良好,R2 = 0.99519 MAE = 0.18926 MSE = 0.0072213 RMSE = 0.084978,从而表明温度、二氧化碳压力和缓蚀剂效率能够有效地影响腐蚀率。此外,在引入外部干扰的情况下,结果显示出较高的精度。所提出的方法和得到的结果可为石油管道维护提供良好的参考价值。
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引用次数: 0
Investigation of Bi-functionalized Clay-Superabsorbent Polymer Nanocomposite for Improved Mechanical and Durability Properties of Cementitious Materials 研究双功能粘土-超吸水性聚合物纳米复合材料,以改善水泥基材料的力学性能和耐久性能
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-09-02 DOI: 10.1007/s13369-024-09525-1
V. S. Sujitha, B. Ramesh, Joseph Raj Xavier

The impacts of incorporating silane-functionalized halloysite nanoclay (SNC) in sodium polyacrylamide (PA) superabsorbent polymer (SAP) and its reinforcement potential in cementitious materials are carefully investigated. Unlike previous studies, this work uniquely explored the dual functionality of SNC to enhance both the water absorption capacity and mechanical strength of SAPs and, subsequently, its reinforcing effects on cementitious materials. This study comprehensively examines the mechanical and durability characteristics of cement mortar and concrete when a small percentage of SNC/SAP composite is added at 0.2, 0.4, 0.6, and 0.8%. The optimum concentration of SNC/SAP composite in the cement mix was found to significantly improve the hydration of cement, thereby enhancing its mechanical properties and strength by filling the micropores. X-ray diffraction (XRD), thermogravimetric analysis (TGA), transmission electron microscopy (TEM), and scanning electron microscopy (SEM) analyses were carried out to characterize the surface morphology and its influence on cementitious materials. The results indicate that the SNC/SAP cementitious nanocomposite enhances the compressive, flexural, and tensile strengths by up to 54%, 63%, and 67%, respectively, compared to those of conventional mortar specimens at 56 days. Furthermore, shrinkage tests revealed the excellent water-holding capacity of the composite hydrogel, which promoted internal curing and reduced microcrack formation. The findings demonstrate that SNC not only improves the properties of SAP hydrogels but also significantly enhances the mechanical properties and durability of cementitious materials, making it a promising additive for protective cementitious coatings in buildings. This study addresses the critical need for durable, crack-resistant concrete, providing a novel approach to enhancing the longevity and performance of cementitious materials.

本研究仔细探讨了在聚丙烯酰胺钠(PA)超吸水聚合物(SAP)中加入硅烷功能化海泡石纳米土(SNC)的影响及其在水泥基材料中的增强潜力。与以往的研究不同,这项工作独特地探索了 SNC 的双重功能,即增强 SAP 的吸水能力和机械强度,进而增强其对水泥基材料的增强效果。本研究全面考察了添加小比例 SNC/SAP 复合材料(0.2%、0.4%、0.6% 和 0.8%)时水泥砂浆和混凝土的机械和耐久性特征。研究发现,水泥混合料中 SNC/SAP 复合材料的最佳浓度能显著改善水泥的水化,从而通过填充微孔提高水泥的机械性能和强度。通过 X 射线衍射 (XRD)、热重分析 (TGA)、透射电子显微镜 (TEM) 和扫描电子显微镜 (SEM) 分析来表征表面形态及其对胶凝材料的影响。结果表明,与传统砂浆试样相比,SNC/SAP 水泥基纳米复合材料在 56 天时的抗压、抗弯和抗拉强度分别提高了 54%、63% 和 67%。此外,收缩测试表明,复合水凝胶具有出色的保水能力,可促进内部固化并减少微裂缝的形成。研究结果表明,SNC 不仅能改善 SAP 水凝胶的性能,还能显著提高水泥基材料的机械性能和耐久性,是一种很有前途的建筑水泥基保护涂层添加剂。这项研究满足了对耐久抗裂混凝土的迫切需求,为提高水泥基材料的寿命和性能提供了一种新方法。
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Arabian Journal for Science and Engineering
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