Pub Date : 2024-09-09DOI: 10.1007/s13369-024-09376-w
Liu Yang, Zhiduo Zhu, He Sun, Wangwen Huo, Yu Wan, Chen Zhang
To achieve a green recycled concrete with excellent mechanical properties and workability, this paper utilized recycled concrete powder, fly ash and granulated ground blast furnace slag as primary materials. Recycled concrete aggregates served as coarse aggregates in the formulation of a recycled concrete powder-based geopolymer recycled concrete (RCPGRC). The study investigated the impact of additional water consumption (AWC), recycled fine aggregate content (RFAC) and the mass ratio of solid powder to aggregate (P/A) on both the mechanical property and workability of RCPGRC. Employing variance and range analysis, the research comprehensively assessed the contributing factors to the concrete's performance and identified the optimum mixture ratio. Characterization of the phase composition and micromorphology were characterized through X-ray diffraction and scanning electron microscopy. The results show that: (1) The AWC had the greatest influence on the unconfined compressive strength (UCS), slump, and setting times, while RFAC and P/A were smaller. AWC of 3%, RFAC of 10%, and P/A of 26% were the inflection points of the UCS, slump, and setting times with AWC, RFAC, and P/A, respectively. (2) The production rate and quantity of geopolymer gels production, as well as the cracks and voids, were affected when the mixture ratios deviated from these optimal inflection points. (3) These inflection points can be utilized as the indexes for rapid judge the optimum mixture ratio of RCPGRC.
{"title":"Development and Performance Evaluation of Waste Concrete Powder-Based Geopolymer Recycled Concrete","authors":"Liu Yang, Zhiduo Zhu, He Sun, Wangwen Huo, Yu Wan, Chen Zhang","doi":"10.1007/s13369-024-09376-w","DOIUrl":"https://doi.org/10.1007/s13369-024-09376-w","url":null,"abstract":"<p>To achieve a green recycled concrete with excellent mechanical properties and workability, this paper utilized recycled concrete powder, fly ash and granulated ground blast furnace slag as primary materials. Recycled concrete aggregates served as coarse aggregates in the formulation of a recycled concrete powder-based geopolymer recycled concrete (RCPGRC). The study investigated the impact of additional water consumption (AWC), recycled fine aggregate content (RFAC) and the mass ratio of solid powder to aggregate (P/A) on both the mechanical property and workability of RCPGRC. Employing variance and range analysis, the research comprehensively assessed the contributing factors to the concrete's performance and identified the optimum mixture ratio. Characterization of the phase composition and micromorphology were characterized through X-ray diffraction and scanning electron microscopy. The results show that: (1) The AWC had the greatest influence on the unconfined compressive strength (UCS), slump, and setting times, while RFAC and P/A were smaller. AWC of 3%, RFAC of 10%, and P/A of 26% were the inflection points of the UCS, slump, and setting times with AWC, RFAC, and P/A, respectively. (2) The production rate and quantity of geopolymer gels production, as well as the cracks and voids, were affected when the mixture ratios deviated from these optimal inflection points. (3) These inflection points can be utilized as the indexes for rapid judge the optimum mixture ratio of RCPGRC.</p>","PeriodicalId":8109,"journal":{"name":"Arabian Journal for Science and Engineering","volume":"25 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142194212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-09DOI: 10.1007/s13369-024-09514-4
Muhammad Rizwan Shakir, Samina Akbar, Imran Raza, Muhammad Awais, Saima Rehman
Electrocatalytic water splitting has been considered as one of the most significant and sustainable approaches for hydrogen production. To make the process more efficient and affordable, there is a need to develop robust, cheap, highly active and stable electrocatalysts. Herein, facile synthesis of copper phosphide nanoparticles (Cu3P NPs) with size ranging from 30 to 80 nm was carried out by using solvothermal process. Variety of characterization techniques like FTIR, XRD, Raman spectroscopy, dynamic light scattering and SEM–EDX, verified the successful synthesis of Cu3P NPs with spherical morphology. Three-electrode system containing glassy carbon, platinum mesh and Hg/HgO as working, counter and reference electrode, respectively, was used for the electrochemical characterization. Electrochemical studies, i.e., CV, LSV and chronoamperometric analysis, revealed efficiency and stability of electrocatalyst for electrolysis of water including hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Briefly, the Cu3P NPs exhibited an excellent OER activity, achieving the current density of 10 mA cm−2 with an overpotential of 450 mV. Tafel slope value 63 mV dec−1 suggested fast OER reaction kinetics. The Cu3P catalyst also exhibited significant HER activity, approaching a current density of 10 mA cm−2 with an overpotential of 447 mV. Fast HER reaction kinetics was observed with a Tafel slope value of 132 mV dec−1. Moreover, the chronoamperometric studies revealed the stability of electrocatalyst providing favorable conditions for sustainable, long-term oxygen and hydrogen production.
电催化水分离被认为是最重要和最可持续的制氢方法之一。为了使这一过程更高效、更经济,有必要开发坚固、廉价、高活性和稳定的电催化剂。在此,我们采用溶解热工艺轻松合成了尺寸为 30 至 80 纳米的磷化铜纳米颗粒(Cu3P NPs)。傅立叶变换红外光谱(FTIR)、X射线衍射(XRD)、拉曼光谱、动态光散射和扫描电子显微镜(SEM-EDX)等多种表征技术验证了球形形态的 Cu3P NPs 的成功合成。电化学表征采用了三电极系统,分别以玻璃碳、铂网和 Hg/HgO 作为工作电极、对电极和参比电极。电化学研究,即 CV、LSV 和时变分析,揭示了电催化剂在电解水(包括氢进化反应(HER)和氧进化反应(OER))方面的效率和稳定性。简而言之,Cu3P NPs 表现出优异的 OER 活性,在 450 mV 的过电位下电流密度达到 10 mA cm-2。塔菲尔斜率值为 63 mV dec-1,表明 OER 反应动力学速度很快。Cu3P 催化剂也表现出显著的 HER 活性,电流密度接近 10 mA cm-2,过电位为 447 mV。观察到快速的 HER 反应动力学,Tafel 斜率值为 132 mV dec-1。此外,时变研究表明,电催化剂具有稳定性,为可持续的、长期的氧气和氢气生产提供了有利条件。
{"title":"Facile Synthesis and Characterization of Copper Phosphide Nanoparticles as Efficient Electrocatalyst for Hydrogen and Oxygen Evolution Reaction","authors":"Muhammad Rizwan Shakir, Samina Akbar, Imran Raza, Muhammad Awais, Saima Rehman","doi":"10.1007/s13369-024-09514-4","DOIUrl":"https://doi.org/10.1007/s13369-024-09514-4","url":null,"abstract":"<p>Electrocatalytic water splitting has been considered as one of the most significant and sustainable approaches for hydrogen production. To make the process more efficient and affordable, there is a need to develop robust, cheap, highly active and stable electrocatalysts. Herein, facile synthesis of copper phosphide nanoparticles (Cu<sub>3</sub>P NPs) with size ranging from 30 to 80 nm was carried out by using solvothermal process. Variety of characterization techniques like FTIR, XRD, Raman spectroscopy, dynamic light scattering and SEM–EDX, verified the successful synthesis of Cu<sub>3</sub>P NPs with spherical morphology. Three-electrode system containing glassy carbon, platinum mesh and Hg/HgO as working, counter and reference electrode, respectively, was used for the electrochemical characterization. Electrochemical studies, i.e., CV, LSV and chronoamperometric analysis, revealed efficiency and stability of electrocatalyst for electrolysis of water including hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Briefly, the Cu<sub>3</sub>P NPs exhibited an excellent OER activity, achieving the current density of 10 mA cm<sup>−2</sup> with an overpotential of 450 mV. Tafel slope value 63 mV dec<sup>−1</sup> suggested fast OER reaction kinetics. The Cu<sub>3</sub>P catalyst also exhibited significant HER activity, approaching a current density of 10 mA cm<sup>−2</sup> with an overpotential of 447 mV. Fast HER reaction kinetics was observed with a Tafel slope value of 132 mV dec<sup>−1</sup>. Moreover, the chronoamperometric studies revealed the stability of electrocatalyst providing favorable conditions for sustainable, long-term oxygen and hydrogen production.</p>","PeriodicalId":8109,"journal":{"name":"Arabian Journal for Science and Engineering","volume":"18 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142194215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-08DOI: 10.1007/s13369-024-09531-3
Cong Gao, Hongjuan Ge
High-power nonlinear load characteristics are one of the typical characteristics of multi-electric aircraft power systems. The study provides an improved CNN-LSTM stability analysis method for solving the stability problem of the aircraft power system caused by high-power nonlinear load switching. To address the issue of sample imbalance, this approach creatively incorporates the cost factor into the CNN loss function. In order to handle the issue of computational complexity, the projection layer is added to the LSTM, and a methodology known as CNN-LSTMP is proposed. This algorithm solves the problems of low computational efficiency and huge computational volume. The time series data utilized by the experiment are created by simulating the transient switching process. The data are then labeled, normalized, and model training is carried out. A deep learning algorithm that satisfies the prediction requirements can be created by applying this method to the established simulation model of a multi-electric aircraft power system for stability analysis. According to the results of the experiments, this method’s transient stability analysis accuracy is 93.32%, which has a positive impact on transient analysis and may satisfy application requirements.
{"title":"I-CNN-LSTM: An Improved CNN-LSTM for Transient Stability Analysis of More Electric Aircraft Power Systems","authors":"Cong Gao, Hongjuan Ge","doi":"10.1007/s13369-024-09531-3","DOIUrl":"https://doi.org/10.1007/s13369-024-09531-3","url":null,"abstract":"<p>High-power nonlinear load characteristics are one of the typical characteristics of multi-electric aircraft power systems. The study provides an improved CNN-LSTM stability analysis method for solving the stability problem of the aircraft power system caused by high-power nonlinear load switching. To address the issue of sample imbalance, this approach creatively incorporates the cost factor into the CNN loss function. In order to handle the issue of computational complexity, the projection layer is added to the LSTM, and a methodology known as CNN-LSTMP is proposed. This algorithm solves the problems of low computational efficiency and huge computational volume. The time series data utilized by the experiment are created by simulating the transient switching process. The data are then labeled, normalized, and model training is carried out. A deep learning algorithm that satisfies the prediction requirements can be created by applying this method to the established simulation model of a multi-electric aircraft power system for stability analysis. According to the results of the experiments, this method’s transient stability analysis accuracy is 93.32%, which has a positive impact on transient analysis and may satisfy application requirements.</p>","PeriodicalId":8109,"journal":{"name":"Arabian Journal for Science and Engineering","volume":"3 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142194214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-07DOI: 10.1007/s13369-024-09484-7
Radovan Nosek, Branislav Zvada, Peter Ďurčanský, Nikola Čajová Kantová, Pavol Mičko
The integration of hydrogen into natural gas infrastructure presents a viable strategy for mitigating greenhouse gas emissions and advancing toward carbon neutrality. This study investigates the combustion characteristics and emissions profiles of hydrogen-enriched natural gas mixtures, specifically focusing on the composition of Russian pipeline natural gas. A comprehensive mathematical model was developed to predict emission concentrations and simulate fuel mixture combustion using MATLAB Simulink software. This versatile model facilitates further analysis within the MATLAB ecosystem. The simulation results demonstrate a significant correlation between the hydrogen content in the natural gas mixture and the resulting heat power output. With a constant fuel consumption rate, a notable decrease in heat power was observed as the hydrogen concentration increased, reaching a maximum reduction of 44.9% at a 45% hydrogen content. These findings underscore the feasibility of partially substituting natural gas with hydrogen, while also highlighting the necessity for increased fuel flow rates to maintain equivalent power output levels. This poses additional challenges for natural gas grid operators, necessitating infrastructure adaptations to accommodate higher fuel demands. The insights gained from this research contribute to the growing body of knowledge surrounding hydrogen integration in the energy sector, offering valuable implications for decarbonization strategies and the optimization of natural gas infrastructure.
{"title":"Numerical Analysis of Hydrogen-Enriched Natural Gas on Combustion and Emission Characteristics","authors":"Radovan Nosek, Branislav Zvada, Peter Ďurčanský, Nikola Čajová Kantová, Pavol Mičko","doi":"10.1007/s13369-024-09484-7","DOIUrl":"https://doi.org/10.1007/s13369-024-09484-7","url":null,"abstract":"<p>The integration of hydrogen into natural gas infrastructure presents a viable strategy for mitigating greenhouse gas emissions and advancing toward carbon neutrality. This study investigates the combustion characteristics and emissions profiles of hydrogen-enriched natural gas mixtures, specifically focusing on the composition of Russian pipeline natural gas. A comprehensive mathematical model was developed to predict emission concentrations and simulate fuel mixture combustion using MATLAB Simulink software. This versatile model facilitates further analysis within the MATLAB ecosystem. The simulation results demonstrate a significant correlation between the hydrogen content in the natural gas mixture and the resulting heat power output. With a constant fuel consumption rate, a notable decrease in heat power was observed as the hydrogen concentration increased, reaching a maximum reduction of 44.9% at a 45% hydrogen content. These findings underscore the feasibility of partially substituting natural gas with hydrogen, while also highlighting the necessity for increased fuel flow rates to maintain equivalent power output levels. This poses additional challenges for natural gas grid operators, necessitating infrastructure adaptations to accommodate higher fuel demands. The insights gained from this research contribute to the growing body of knowledge surrounding hydrogen integration in the energy sector, offering valuable implications for decarbonization strategies and the optimization of natural gas infrastructure.</p>","PeriodicalId":8109,"journal":{"name":"Arabian Journal for Science and Engineering","volume":"54 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142194218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-06DOI: 10.1007/s13369-024-09491-8
E. Arabzadeh-Ziari, M. Mohammadimehr, M. Arabzadeh-Ziari, M. Asgari
This article discusses the vibration, bending, and buckling analysis of a seven-layer sandwich beam with a balsa wood core reinforced with carbon nanotubes (CNT), shape memory alloy (SMA) nanoparticles, and piezoelectromagnetic layers. The governing equations of motion are obtained using the Hamiltonian principle. To measure the validity of this research, the obtained results are compared with the other results, and the results are in agreement with each other. The primary goal is to enhance the sandwich structure’s strength and rigidity by using CNTs reinforcement and SMA nanoparticles, with the piezoelectromagnetic layers functioning as sensors to improve the overall mechanical performance of the beam The use of CNTs can have a favorable effect on the stiffness of the beam and strength-to-weight ratio and also, the effect of the thickness ratio of core on deflection, critical buckling load, and vibration frequency is significant, so that with a decrease of 11.1% in the thickness ratio, the deflection decreases by about 50.2%, the critical buckling load increases by about 101%, and the vibration frequency increases by about 40.7%. Also, with an increase of 0.5 and 3.5 percent of CNT, the deflection of a sandwich beam reduces by 20 and 50 percent, respectively.
{"title":"Vibration, Bending, and Buckling of a Seven-Layer Sandwich Beam with Balsa Core Reinforced by Nanocomposite and Shape Memory Alloy Face Sheets Using Piezoelectromagnetic Layers","authors":"E. Arabzadeh-Ziari, M. Mohammadimehr, M. Arabzadeh-Ziari, M. Asgari","doi":"10.1007/s13369-024-09491-8","DOIUrl":"https://doi.org/10.1007/s13369-024-09491-8","url":null,"abstract":"<p>This article discusses the vibration, bending, and buckling analysis of a seven-layer sandwich beam with a balsa wood core reinforced with carbon nanotubes (CNT), shape memory alloy (SMA) nanoparticles, and piezoelectromagnetic layers. The governing equations of motion are obtained using the Hamiltonian principle. To measure the validity of this research, the obtained results are compared with the other results, and the results are in agreement with each other. The primary goal is to enhance the sandwich structure’s strength and rigidity by using CNTs reinforcement and SMA nanoparticles, with the piezoelectromagnetic layers functioning as sensors to improve the overall mechanical performance of the beam The use of CNTs can have a favorable effect on the stiffness of the beam and strength-to-weight ratio and also, the effect of the thickness ratio of core on deflection, critical buckling load, and vibration frequency is significant, so that with a decrease of 11.1% in the thickness ratio, the deflection decreases by about 50.2%, the critical buckling load increases by about 101%, and the vibration frequency increases by about 40.7%. Also, with an increase of 0.5 and 3.5 percent of CNT, the deflection of a sandwich beam reduces by 20 and 50 percent, respectively.</p>","PeriodicalId":8109,"journal":{"name":"Arabian Journal for Science and Engineering","volume":"158 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142194090","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-04DOI: 10.1007/s13369-024-09537-x
Roopak Varshney, Param Singh
This study employs a multi-criteria decision-making (MCDM) technique to identify the optimal parameters for the electrical discharge turning (EDT) process used to machine cylindrical EN24 steel alloy. EDT, a significant configuration of EDM, offers a valuable approach for machining cylindrical workpieces. A face-centred central composite design (FCCCD) is employed to establish the experimental design. The CRITIC–TOPSIS method is subsequently implemented to optimize the input parameters: gap current (Ig), pulse on time (Ton), rotational speed (N), and magnetic field assistance (B). Each parameter is investigated at three distinct levels. The study focuses on four response variables: material removal rate (MRR), tool wear rate (TWR), overcut (OC), and surface roughness (Ra). Analysis of variance (ANOVA) is conducted to assess the influence of each input parameter on the observed responses. Criteria importance through inter-criteria correlation (CRITIC) is employed to assign weights to each response, followed by applying the technique for order of preference by similarity to ideal solution (TOPSIS) to identify the ideal machining parameters. The results indicate that run number 16 (Ig: 16A, Ton: 60 µs, N: 1400 RPM, and B: 0.30 T) represents the optimal configuration. Scanning electron microscopy (SEM) analysis further corroborates this finding, confirming superior surface quality compared to other experimental runs.
{"title":"Optimizing of Novel Magnetic Field-Assisted Electrical Discharge Turning Parameters for Machining EN24 Steel Alloy Using Response Surface Methodology and MCDM-Based CRITIC–TOPSIS Method","authors":"Roopak Varshney, Param Singh","doi":"10.1007/s13369-024-09537-x","DOIUrl":"https://doi.org/10.1007/s13369-024-09537-x","url":null,"abstract":"<p>This study employs a multi-criteria decision-making (MCDM) technique to identify the optimal parameters for the electrical discharge turning (EDT) process used to machine cylindrical EN24 steel alloy. EDT, a significant configuration of EDM, offers a valuable approach for machining cylindrical workpieces. A face-centred central composite design (FCCCD) is employed to establish the experimental design. The CRITIC–TOPSIS method is subsequently implemented to optimize the input parameters: gap current (Ig), pulse on time (Ton), rotational speed (<i>N</i>), and magnetic field assistance (<i>B</i>). Each parameter is investigated at three distinct levels. The study focuses on four response variables: material removal rate (MRR), tool wear rate (TWR), overcut (OC), and surface roughness (<i>R</i><sub>a</sub>). Analysis of variance (ANOVA) is conducted to assess the influence of each input parameter on the observed responses. Criteria importance through inter-criteria correlation (CRITIC) is employed to assign weights to each response, followed by applying the technique for order of preference by similarity to ideal solution (TOPSIS) to identify the ideal machining parameters. The results indicate that run number 16 (Ig: 16A, Ton: 60 µs, <i>N</i>: 1400 RPM, and <i>B</i>: 0.30 T) represents the optimal configuration. Scanning electron microscopy (SEM) analysis further corroborates this finding, confirming superior surface quality compared to other experimental runs.</p>","PeriodicalId":8109,"journal":{"name":"Arabian Journal for Science and Engineering","volume":"24 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142194092","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-03DOI: 10.1007/s13369-024-09532-2
Ghayah M. Alsulaim, Shada A. Alsharif, Kholoud M. Alnahdi, Hanan A. Althikrallah
ZnO-based nanocomposites have attracted a great attention for energy storage systems and detection of volatile organic compounds. In this study, pure and Ce-doped MnO2–ZnO composites were fabricated through a co-precipitation method. The results of X-ray diffraction verified the formation of tetragonal MnO2 and hexagonal ZnO phases. Scanning electron microscope images of pure and Ce-doped MnO2–ZnO composites displayed the formation of rods and semi-spherical particles. The pure and Ce-doped MnO2–ZnO composites exhibited semi-stable colossal dielectric constant values of 2.12 × 105 and 1.36 × 105, respectively, at a frequency of 45 Hz, which are proper for capacitive energy storage applications. Gas sensing measurements demonstrated that Ce-doped MnO2–ZnO composite has a high sensitivity toward 100 ppm acetone gas at operating temperature of 240 °C, while for 100 ppm ethanol this sensor has a high sensitivity at 180 °C. As a result, through adjusting the operating temperature, the selectivity of Ce-doped MnO2–ZnO sensor can be controlled for acetone and ethanol gases. Furthermore, this sensor possesses good selectivity and stability as well as proper linear relations between the sensitivity and concentrations of acetone and ethanol gases.
氧化锌基纳米复合材料在储能系统和挥发性有机化合物检测方面引起了广泛关注。本研究通过共沉淀法制备了纯 MnO2-ZnO 复合材料和掺杂 Ce 的 MnO2-ZnO 复合材料。X 射线衍射结果验证了四方 MnO2 和六方 ZnO 相的形成。纯 MnO2-ZnO 复合材料和掺杂 Ce 的 MnO2-ZnO 复合材料的扫描电子显微镜图像显示形成了棒状和半球状颗粒。纯 MnO2-ZnO 复合材料和掺杂 Ce 的 MnO2-ZnO 复合材料在 45 Hz 频率下的半稳定巨介电常数值分别为 2.12 × 105 和 1.36 × 105,适合电容式储能应用。气体传感测量表明,掺杂 Ce 的 MnO2-ZnO 复合材料在 240 °C 的工作温度下对 100 ppm 丙酮气体具有高灵敏度,而在 180 °C 的工作温度下对 100 ppm 乙醇具有高灵敏度。因此,通过调节工作温度,可以控制掺杂 Ce 的 MnO2-ZnO 传感器对丙酮和乙醇气体的选择性。此外,这种传感器还具有良好的选择性和稳定性,其灵敏度与丙酮和乙醇气体的浓度呈适当的线性关系。
{"title":"Pure and Ce-Doped MnO2–ZnO Nanocomposites for Colossal Dielectric Energy Storage and Gas Sensing Applications","authors":"Ghayah M. Alsulaim, Shada A. Alsharif, Kholoud M. Alnahdi, Hanan A. Althikrallah","doi":"10.1007/s13369-024-09532-2","DOIUrl":"https://doi.org/10.1007/s13369-024-09532-2","url":null,"abstract":"<p>ZnO-based nanocomposites have attracted a great attention for energy storage systems and detection of volatile organic compounds. In this study, pure and Ce-doped MnO<sub>2</sub>–ZnO composites were fabricated through a co-precipitation method. The results of X-ray diffraction verified the formation of tetragonal MnO<sub>2</sub> and hexagonal ZnO phases. Scanning electron microscope images of pure and Ce-doped MnO<sub>2</sub>–ZnO composites displayed the formation of rods and semi-spherical particles. The pure and Ce-doped MnO<sub>2</sub>–ZnO composites exhibited semi-stable colossal dielectric constant values of 2.12 × 10<sup>5</sup> and 1.36 × 10<sup>5</sup>, respectively, at a frequency of 45 Hz, which are proper for capacitive energy storage applications. Gas sensing measurements demonstrated that Ce-doped MnO<sub>2</sub>–ZnO composite has a high sensitivity toward 100 ppm acetone gas at operating temperature of 240 °C, while for 100 ppm ethanol this sensor has a high sensitivity at 180 °C. As a result, through adjusting the operating temperature, the selectivity of Ce-doped MnO<sub>2</sub>–ZnO sensor can be controlled for acetone and ethanol gases. Furthermore, this sensor possesses good selectivity and stability as well as proper linear relations between the sensitivity and concentrations of acetone and ethanol gases.</p>","PeriodicalId":8109,"journal":{"name":"Arabian Journal for Science and Engineering","volume":"62 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142194098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-02DOI: 10.1007/s13369-024-09501-9
M. J. Pellegrini-Cervantes, C. A. Espinoza-Moreno, M. Rodriguez-Rodriguez, C. P. Barrios-Durstewitz, S. P. Arredondo-Rea, R. Corral-Higuera, H. J. Peinado-Guevara, M. J. Chinchillas-Chinchillas, G. Fajardo-San-Miguel
This study advocates for the use of recycled materials, which are more environmentally sustainable as they decrease natural resource consumption. In this research, a mortar anode composed of recycled fine aggregate (RFA) from laboratory concrete blocks, carbon fiber (CF) waste from industrial processes, and graphite powder (GP) was developed, resulting in a conductive recycled mortar (CRM). The manufacturing process utilized Portland composite cement, RFA with a sand/cement ratio of 1.00, a water/cement ratio of 0.6, a GP/cement ratio of 0.50, CF comprising 0.5%, and carboxymethyl cellulose (CMC) comprising 0.4% by weight of cement. Chloride profiles indicated that the specimens with the CRM anode were effective, as the chlorides migrated into the mortar. For M0.5CF (2.81%) and M0.5CF0.5GP (3.72%) of free chlorides, the Ti–RuO2 mesh did not expel the chlorides but rather accumulated them at 1 cm from the surface, resulting in a negative efficiency (− 20.02%). However, at 1 cm from the cathode, the efficiency levels were comparable across the anodes: Ti–RuO2 mesh (84.54%), M0.5CF (84.76%), and M0.5CF0.5GP (81.11%), underscoring the potential of using a CRM anode for electrochemical chloride removal.
{"title":"Use of a Conductive Recycled Mortar as an Anode in the Electrochemical Chloride Extraction in Reinforced Concrete","authors":"M. J. Pellegrini-Cervantes, C. A. Espinoza-Moreno, M. Rodriguez-Rodriguez, C. P. Barrios-Durstewitz, S. P. Arredondo-Rea, R. Corral-Higuera, H. J. Peinado-Guevara, M. J. Chinchillas-Chinchillas, G. Fajardo-San-Miguel","doi":"10.1007/s13369-024-09501-9","DOIUrl":"https://doi.org/10.1007/s13369-024-09501-9","url":null,"abstract":"<p>This study advocates for the use of recycled materials, which are more environmentally sustainable as they decrease natural resource consumption. In this research, a mortar anode composed of recycled fine aggregate (RFA) from laboratory concrete blocks, carbon fiber (CF) waste from industrial processes, and graphite powder (GP) was developed, resulting in a conductive recycled mortar (CRM). The manufacturing process utilized Portland composite cement, RFA with a sand/cement ratio of 1.00, a water/cement ratio of 0.6, a GP/cement ratio of 0.50, CF comprising 0.5%, and carboxymethyl cellulose (CMC) comprising 0.4% by weight of cement. Chloride profiles indicated that the specimens with the CRM anode were effective, as the chlorides migrated into the mortar. For M0.5CF (2.81%) and M0.5CF0.5GP (3.72%) of free chlorides, the Ti–RuO<sub>2</sub> mesh did not expel the chlorides but rather accumulated them at 1 cm from the surface, resulting in a negative efficiency (− 20.02%). However, at 1 cm from the cathode, the efficiency levels were comparable across the anodes: Ti–RuO<sub>2</sub> mesh (84.54%), M0.5CF (84.76%), and M0.5CF0.5GP (81.11%), underscoring the potential of using a CRM anode for electrochemical chloride removal.</p>","PeriodicalId":8109,"journal":{"name":"Arabian Journal for Science and Engineering","volume":"22 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142194123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-02DOI: 10.1007/s13369-024-09522-4
Ziheng Zhao, Elmi Bin Abu Bakar, Norizham Bin Abdul Razak, Mohammad Nishat Akhtar
Corrosion is one of the most significant challenges for oil pipelines. It can occur due to various factors such as moisture, oxygen, and contaminants in the oil. Corrosion weakens the pipeline material, leading to leaks, ruptures, and structural failure. To enhance the ability to decrease the corrosion problems of oil pipelines, an efficient Back Propagation Neural Network is developed to predict the corrosion rate and analyse the importance of the features that affect the corrosion. This method is based on the database generated by coupling an analytical corrosion rate model and Monte Carlo simulation by using Spearman’s (SP) correlation coefficient to generate the relevance between each feature, negating the feature variables with a strong correlation and then combining with a Genetic Algorithm (GA) and a Back Propagation (BP) Neural Network to build a regression prediction model. The proposed approach has been termed SP-GA-BP. The results showed that the proposed method can predict well with R2 = 0.99519 MAE = 0.18926 MSE = 0.0072213 RMSE = 0.084978, thereby indicating that the Temperature, CO2 Pressure, and Corrosion Inhibitor efficiency can affect the corrosion rate efficaciously. Furthermore, with the introduction of external interference, the results exhibited a high level of precision. The proposed method and the obtained results may provide a good reference value for oil pipeline maintenance.
{"title":"An Efficient Corrosion Prediction Model Based on Genetic Feedback Propagation Neural Network","authors":"Ziheng Zhao, Elmi Bin Abu Bakar, Norizham Bin Abdul Razak, Mohammad Nishat Akhtar","doi":"10.1007/s13369-024-09522-4","DOIUrl":"https://doi.org/10.1007/s13369-024-09522-4","url":null,"abstract":"<p>Corrosion is one of the most significant challenges for oil pipelines. It can occur due to various factors such as moisture, oxygen, and contaminants in the oil. Corrosion weakens the pipeline material, leading to leaks, ruptures, and structural failure. To enhance the ability to decrease the corrosion problems of oil pipelines, an efficient Back Propagation Neural Network is developed to predict the corrosion rate and analyse the importance of the features that affect the corrosion. This method is based on the database generated by coupling an analytical corrosion rate model and Monte Carlo simulation by using Spearman’s (SP) correlation coefficient to generate the relevance between each feature, negating the feature variables with a strong correlation and then combining with a Genetic Algorithm (GA) and a Back Propagation (BP) Neural Network to build a regression prediction model. The proposed approach has been termed SP-GA-BP. The results showed that the proposed method can predict well with R<sup>2</sup> = 0.99519 MAE = 0.18926 MSE = 0.0072213 RMSE = 0.084978, thereby indicating that the Temperature, CO<sub>2</sub> Pressure, and Corrosion Inhibitor efficiency can affect the corrosion rate efficaciously. Furthermore, with the introduction of external interference, the results exhibited a high level of precision. The proposed method and the obtained results may provide a good reference value for oil pipeline maintenance.</p>","PeriodicalId":8109,"journal":{"name":"Arabian Journal for Science and Engineering","volume":"27 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142194096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-02DOI: 10.1007/s13369-024-09525-1
V. S. Sujitha, B. Ramesh, Joseph Raj Xavier
The impacts of incorporating silane-functionalized halloysite nanoclay (SNC) in sodium polyacrylamide (PA) superabsorbent polymer (SAP) and its reinforcement potential in cementitious materials are carefully investigated. Unlike previous studies, this work uniquely explored the dual functionality of SNC to enhance both the water absorption capacity and mechanical strength of SAPs and, subsequently, its reinforcing effects on cementitious materials. This study comprehensively examines the mechanical and durability characteristics of cement mortar and concrete when a small percentage of SNC/SAP composite is added at 0.2, 0.4, 0.6, and 0.8%. The optimum concentration of SNC/SAP composite in the cement mix was found to significantly improve the hydration of cement, thereby enhancing its mechanical properties and strength by filling the micropores. X-ray diffraction (XRD), thermogravimetric analysis (TGA), transmission electron microscopy (TEM), and scanning electron microscopy (SEM) analyses were carried out to characterize the surface morphology and its influence on cementitious materials. The results indicate that the SNC/SAP cementitious nanocomposite enhances the compressive, flexural, and tensile strengths by up to 54%, 63%, and 67%, respectively, compared to those of conventional mortar specimens at 56 days. Furthermore, shrinkage tests revealed the excellent water-holding capacity of the composite hydrogel, which promoted internal curing and reduced microcrack formation. The findings demonstrate that SNC not only improves the properties of SAP hydrogels but also significantly enhances the mechanical properties and durability of cementitious materials, making it a promising additive for protective cementitious coatings in buildings. This study addresses the critical need for durable, crack-resistant concrete, providing a novel approach to enhancing the longevity and performance of cementitious materials.
本研究仔细探讨了在聚丙烯酰胺钠(PA)超吸水聚合物(SAP)中加入硅烷功能化海泡石纳米土(SNC)的影响及其在水泥基材料中的增强潜力。与以往的研究不同,这项工作独特地探索了 SNC 的双重功能,即增强 SAP 的吸水能力和机械强度,进而增强其对水泥基材料的增强效果。本研究全面考察了添加小比例 SNC/SAP 复合材料(0.2%、0.4%、0.6% 和 0.8%)时水泥砂浆和混凝土的机械和耐久性特征。研究发现,水泥混合料中 SNC/SAP 复合材料的最佳浓度能显著改善水泥的水化,从而通过填充微孔提高水泥的机械性能和强度。通过 X 射线衍射 (XRD)、热重分析 (TGA)、透射电子显微镜 (TEM) 和扫描电子显微镜 (SEM) 分析来表征表面形态及其对胶凝材料的影响。结果表明,与传统砂浆试样相比,SNC/SAP 水泥基纳米复合材料在 56 天时的抗压、抗弯和抗拉强度分别提高了 54%、63% 和 67%。此外,收缩测试表明,复合水凝胶具有出色的保水能力,可促进内部固化并减少微裂缝的形成。研究结果表明,SNC 不仅能改善 SAP 水凝胶的性能,还能显著提高水泥基材料的机械性能和耐久性,是一种很有前途的建筑水泥基保护涂层添加剂。这项研究满足了对耐久抗裂混凝土的迫切需求,为提高水泥基材料的寿命和性能提供了一种新方法。
{"title":"Investigation of Bi-functionalized Clay-Superabsorbent Polymer Nanocomposite for Improved Mechanical and Durability Properties of Cementitious Materials","authors":"V. S. Sujitha, B. Ramesh, Joseph Raj Xavier","doi":"10.1007/s13369-024-09525-1","DOIUrl":"https://doi.org/10.1007/s13369-024-09525-1","url":null,"abstract":"<p>The impacts of incorporating silane-functionalized halloysite nanoclay (SNC) in sodium polyacrylamide (PA) superabsorbent polymer (SAP) and its reinforcement potential in cementitious materials are carefully investigated. Unlike previous studies, this work uniquely explored the dual functionality of SNC to enhance both the water absorption capacity and mechanical strength of SAPs and, subsequently, its reinforcing effects on cementitious materials. This study comprehensively examines the mechanical and durability characteristics of cement mortar and concrete when a small percentage of SNC/SAP composite is added at 0.2, 0.4, 0.6, and 0.8%. The optimum concentration of SNC/SAP composite in the cement mix was found to significantly improve the hydration of cement, thereby enhancing its mechanical properties and strength by filling the micropores. X-ray diffraction (XRD), thermogravimetric analysis (TGA), transmission electron microscopy (TEM), and scanning electron microscopy (SEM) analyses were carried out to characterize the surface morphology and its influence on cementitious materials. The results indicate that the SNC/SAP cementitious nanocomposite enhances the compressive, flexural, and tensile strengths by up to 54%, 63%, and 67%, respectively, compared to those of conventional mortar specimens at 56 days. Furthermore, shrinkage tests revealed the excellent water-holding capacity of the composite hydrogel, which promoted internal curing and reduced microcrack formation. The findings demonstrate that SNC not only improves the properties of SAP hydrogels but also significantly enhances the mechanical properties and durability of cementitious materials, making it a promising additive for protective cementitious coatings in buildings. This study addresses the critical need for durable, crack-resistant concrete, providing a novel approach to enhancing the longevity and performance of cementitious materials.</p>","PeriodicalId":8109,"journal":{"name":"Arabian Journal for Science and Engineering","volume":"37 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142194095","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}