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One-Dimensional Rock and Soil Characteristic Parameters Prediction Method Based on SRR 基于 SRR 的一维岩土特征参数预测方法
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-12 DOI: 10.1007/s13369-024-09393-9
Zeliang Wang, Rui Gao, Xiuren Hu

Acquiring precise geologic parameters for obstructed or complex geologic regions poses a difficult task in practical engineering. Current predictions depend on the expertise of engineers, leading to inadequate levels of precision. Therefore, in this study, geotechnical stratigraphic data were transformed into visualization images containing only red information corresponding to R values in RGB images. The generated visualization images were analyzed using a super-resolution convolutional neural network (SRCNN) for prediction and compared with linear interpolation-based prediction methods. Subsequently, a dataset containing 430,000 patches was generated using real geologic data from a specific project, and this dataset was used for SRCNN training to validate its prediction. The results showed that SRCNN yields a peak signal-to-noise ratio (PSNR) of 40.22 dB, exceeding the linear interpolation on the geologic map (39.93 dB). The SRCNN training was successful and outperformed the linear interpolation. The PSNR values of the SRCNN were higher (34.69 dB, 37.68 dB, 38.79 dB, 37.56 dB, and 44.99 dB) compared to linear interpolation (34.53 dB, 37.43 dB, 38.38 dB, 37.29 dB, and 44.31 dB). These findings confirmed the significant potential of the application of super-resolution reconstruction for predicting soil distribution, and this method is expected to yield more precise soil prediction results as the dataset grows.

在实际工程中,获取受阻或复杂地质区域的精确地质参数是一项艰巨的任务。目前的预测依赖于工程师的专业知识,导致精确度不足。因此,在本研究中,岩土地层数据被转化为可视化图像,其中仅包含与 RGB 图像中 R 值相对应的红色信息。使用超分辨率卷积神经网络(SRCNN)对生成的可视化图像进行预测分析,并与基于线性插值的预测方法进行比较。随后,利用特定项目的真实地质数据生成了一个包含 430,000 个斑块的数据集,并利用该数据集进行 SRCNN 训练,以验证其预测效果。结果表明,SRCNN 的峰值信噪比(PSNR)为 40.22 dB,超过了地质图上的线性插值(39.93 dB)。SRCNN 的训练很成功,性能超过了线性插值。与线性插值(34.53 dB、37.43 dB、38.38 dB、37.29 dB 和 44.31 dB)相比,SRCNN 的 PSNR 值更高(34.69 dB、37.68 dB、38.79 dB、37.56 dB 和 44.99 dB)。这些发现证实了应用超分辨率重建预测土壤分布的巨大潜力,随着数据集的增加,这种方法有望产生更精确的土壤预测结果。
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引用次数: 0
Synthetic Studies of Aluminum-Doped Zn0.5Mn0.5AlxFe2−xO4 Ferrite for Photocatalytic Degradation of Atrazine Under Visible Light 掺铝 Zn0.5Mn0.5AlxFe2-xO4 铁氧体在可见光下光催化降解阿特拉津的合成研究
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-12 DOI: 10.1007/s13369-024-09442-3
Muhammad Yasar, Khalid Javed

The objective of this study was to synthesize and evaluate aluminum-doped zinc-manganese ferrite (Zn0.5Mn0.5AlxFe2−xO4 (X = 0, 0.2)) nanoparticles as efficient visible-light-driven photocatalysts for atrazine degradation in water. The nanoparticles were synthesized via the sol–gel method and characterized using XRD, FTIR, SEM–EDX, BET, UV–Vis DRS, and electrical resistivity measurements. Aluminum doping decreased the bandgap from 2.4 to 2.0 eV and improved the adsorption properties by increasing the surface area and pore volume compared to undoped Zn0.5Mn0.5Fe2O4. Photodegradation experiments revealed that Zn0.5Mn0.5Al0.2Fe1.8O4 achieved 95% atrazine removal in 150 min under visible-light irradiation, outperforming the 75.45% removal achieved by undoped Zn0.5Mn0.5Fe2O4. This enhanced performance was attributed to aluminum-induced structural modifications that facilitated charge-separation and radical generation. The degradation followed first-order kinetics and hydroxyl radicals were identified as the primary reactive species. The effects of operational parameters, including the solution pH, atrazine concentration, catalyst dosage, temperature, light intensity, and H2O2 addition, were systematically investigated. Zn0.5Mn0.5Al0.2Fe1.8O4 demonstrated reusability over five consecutive cycles with a slight decrease in efficiency. These findings highlight the potential of aluminum-doped zinc-manganese ferrites as efficient visible-light photocatalysts for environmental remediation.

本研究旨在合成和评估铝掺杂锌锰铁氧体(Zn0.5Mn0.5AlxFe2-xO4 (X = 0, 0.2))纳米粒子作为可见光驱动的高效光催化剂,用于降解水中的阿特拉津。纳米粒子通过溶胶-凝胶法合成,并使用 XRD、FTIR、SEM-EDX、BET、UV-Vis DRS 和电阻率测量进行表征。与未掺杂的 Zn0.5Mn0.5Fe2O4 相比,铝掺杂使带隙从 2.4 eV 降至 2.0 eV,并通过增加表面积和孔隙体积改善了吸附性能。光降解实验表明,在可见光照射下,Zn0.5Mn0.5Al0.2Fe1.8O4 在 150 分钟内对阿特拉津的去除率达到 95%,超过了未掺杂 Zn0.5Mn0.5Fe2O4 的 75.45%。性能的提高归功于铝引起的结构改变,这种改变促进了电荷分离和自由基的生成。降解遵循一阶动力学,羟基自由基被确定为主要反应物。系统研究了溶液 pH 值、阿特拉津浓度、催化剂用量、温度、光照强度和 H2O2 添加量等操作参数的影响。结果表明,Zn0.5Mn0.5Al0.2Fe1.8O4 可连续重复使用五个周期,但效率略有下降。这些发现凸显了掺铝锌锰铁氧体作为高效可见光光催化剂用于环境修复的潜力。
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引用次数: 0
Computational Study of the Piezoelectric Performance of Barium Titanate Crystals in the Presence of Vacancy Defect: Molecular Dynamics Approach 存在空位缺陷时钛酸钡晶体压电性能的计算研究:分子动力学方法
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-12 DOI: 10.1007/s13369-024-09424-5
S. Esmaeili, M. H. Ehsani, Davood Toghraie, S. Saber-Samandari

Certain materials (ceramics and polymers) are capable of converting mechanical energy into electrical energy via the piezoelectric effect. The piezoelectric effect is fundamentally associated with momentary electric dipoles that occur in solids. The external surface may be borne directly by molecular groups or excited in the crystal lattice by an asymmetric peripheral charge. Using molecular dynamics simulation, the current study examined the effect of atomic vacancies on the piezoelectric properties of barium titanate crystals. For this reason, the diffusion coefficient, ferroelectric hysteresis loop, piezoelectric hysteresis loop, and strain–polarization curve were all examined. Increasing atomic vacancy to 20% increased the maximum (Max) value of residual strain and polarization in the simulated structure, according to the results. Optimal orientation, appropriate displacement of charged atoms, and the formation of effective dipoles all contributed to this. Consequently, the ferroelectric and piezoelectric properties of the structure were enhanced. In the sample containing 20% atomic vacancies, atomic movement was also extremely high. As opposed to the sample containing 30% atomic vacancy, however, its structure was less porous. Hence, when 20% atomic vacancy was present, the structure exhibited its most optimal polarization.

某些材料(陶瓷和聚合物)能够通过压电效应将机械能转化为电能。压电效应从根本上说与固体中出现的瞬时电偶极子有关。外表面可能由分子基团直接承受,也可能由不对称外围电荷在晶格中激发。本研究利用分子动力学模拟,考察了原子空位对钛酸钡晶体压电特性的影响。为此,研究人员考察了扩散系数、铁电磁滞回线、压电磁滞回线和应变极化曲线。结果表明,将原子空位增加到 20% 会增加模拟结构中残余应变和极化的最大值。最佳取向、带电原子的适当位移以及有效偶极子的形成都对此做出了贡献。因此,该结构的铁电和压电特性得到了增强。在含有 20% 原子空位的样品中,原子移动也非常频繁。然而,与含有 30% 原子空位的样品相比,其结构的多孔性较差。因此,当存在 20% 的原子空位时,该结构表现出最理想的极化效果。
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引用次数: 0
Application of an Inline Mixer to Produce Surfactant-Free Biodiesel-diesel/Water Emulsion Fuel: An Analysis of Water Droplets Characteristics and Drive Cycle Emissions 应用内联混合器生产不含表面活性剂的生物柴油-柴油/水乳化燃料:水滴特性和驱动循环排放分析
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-11 DOI: 10.1007/s13369-024-09408-5
Mohamad Qayyum Mohd Tamam, Wira Jazair Yahya, Hasbullah Abdul Rahman, Ahmad Muhsin Ithnin, Hasannuddin Abd Kadir, Md Mujibur Rahman, Hirofumi Noge, Tsuyoshi Koga, Dhani Avianto Sugeng

Water-in-diesel (W/D) emulsion is a promising alternative fuel candidate, as it can simultaneously reduce nitrogen oxides (NOx) and particulate matter (PM) while improving engine performance. Wide scale adoption of this fuel is difficult due to high production and storage costs. Hence, Real-Time Non-Surfactant Emulsion Fuel Supply System (RTES) is a proposed technology to solve these issues by mixing diesel and water in-line directly to the engine. This study presents an updated RTES prototype which incorporated a modular design, with a feedback system to control water injection rate. In this paper, RTES was installed to a common rail injection diesel-powered vehicle and the biodiesel-diesel W/D produced by RTES was analyzed to determine the effect of common rail pressure toward water droplet size and distribution. The vehicle was then tested under the New European Driving Cycle (NEDC) to evaluate vehicle emissions, which will serve as the basis for evaluating the emissions profile of W/D produced by RTES under urban and extra-urban driving conditions. It was found that when subjected to high common rail pressures, W/D droplets produced by RTES reduced by 21.1% compared to freshly produced W/D. NEDC emissions data revealed that NOx emission was reduced to a maximum of 25.3% in urban driving conditions. Hydrocarbons and carbon monoxide increased marginally throughout urban driving phase; while, carbon dioxide emissions were comparable between biodiesel-diesel and W/D. However, extra-urban driving conditions were unfavorable for RTES activation, as substantial emission increases were observed during high-speed accelerations. Nonetheless, W/D reduced PM emissions by 51% throughout NEDC.

水包柴油(W/D)乳化液是一种很有前途的替代燃料,因为它可以同时减少氮氧化物(NOx)和颗粒物(PM),同时提高发动机性能。由于生产和储存成本较高,这种燃料难以大范围采用。因此,实时非表面活性剂乳化燃料供应系统(RTES)是一项通过将柴油和水直接在线混合到发动机来解决这些问题的拟议技术。本研究介绍了一种最新的 RTES 原型,它采用了模块化设计,并配有反馈系统来控制喷水率。本文将 RTES 安装在共轨喷射柴油动力汽车上,并对 RTES 产生的生物柴油-柴油 W/D 进行了分析,以确定共轨压力对水滴大小和分布的影响。然后在新欧洲行驶循环(NEDC)下对车辆进行测试,以评估车辆排放情况,并以此为基础评估 RTES 在城市和城市外行驶条件下产生的 W/D 的排放情况。研究发现,在高压共轨条件下,RTES 生产的 W/D 液滴比新生产的 W/D 液滴减少了 21.1%。NEDC 排放数据显示,在城市驾驶条件下,氮氧化物排放量最大减少了 25.3%。碳氢化合物和一氧化碳在整个城市驾驶阶段略有增加;而生物柴油-柴油和 W/D 的二氧化碳排放量相当。然而,城市外的驾驶条件不利于启动 RTES,因为在高速加速时观察到排放量大幅增加。尽管如此,在整个 NEDC 行驶过程中,W/D 减少了 51% 的 PM 排放量。
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引用次数: 0
Effect of Aggregate Characteristics and Distribution on the Mechanical Characteristics of Recycled Concrete 骨料特性和分布对再生混凝土机械特性的影响
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-11 DOI: 10.1007/s13369-024-09395-7
Lixia Guo, Yuqing Yang, Ling Zhong, Jianwei Zhang

Recycled concrete is a green material composed of natural aggregate and recycled aggregate mixed with cementing material and water in a certain ratio. The random distribution of aggregate in concrete has a great impact on material properties due to its supporting effect. In order to explore the characteristics of aggregate and the influence of its random distribution on the compressive strength performance of recycled aggregate concrete, numerical simulation is adopted in this paper. By using RAND function in ANSYS software APDL, a five-phase random aggregate model of recycled aggregate concrete was generated based on Monte Carlo method, and numerical simulation of uniaxial compression mechanical properties of concrete specimens under different recycled aggregate substitution rates (0%, 35% and 100%) was carried out. On the basis of reliability of the numerical simulation method verified by laboratory tests, multiple groups of stress–strain characteristic curves were obtained, the failure characteristics and stress characteristics of recycled concrete were analyzed, and Weibull probability statistical distribution was introduced to characterize the randomness and heterogeneity of mechanical characteristic parameters of recycled aggregate concrete. The results show that the compressive strength of recycled aggregate concrete is subject to Weibull distribution under random distribution of aggregate, and the shape coefficient m in Weibull distribution parameter can characterize the randomness and complexity of the failure of recycled concrete. The dispersion of the compressive strength of recycled aggregate concrete shows a decreasing trend with the increase in the substitution rate of recycled aggregate.

再生混凝土是由天然骨料和再生骨料与胶结材料和水按一定比例混合而成的绿色材料。骨料在混凝土中的随机分布具有支撑作用,对材料性能有很大影响。为了探讨骨料的特性及其随机分布对再生骨料混凝土抗压强度性能的影响,本文采用了数值模拟的方法。利用 ANSYS 软件 APDL 中的 RAND 函数,基于 Monte Carlo 方法生成了再生骨料混凝土的五相随机骨料模型,并对不同再生骨料取代率(0%、35% 和 100%)下混凝土试件的单轴压缩力学性能进行了数值模拟。在实验室试验验证数值模拟方法可靠性的基础上,得到了多组应力-应变特性曲线,分析了再生混凝土的破坏特性和应力特性,并引入 Weibull 概率统计分布表征了再生骨料混凝土力学特性参数的随机性和异质性。结果表明,在骨料随机分布的情况下,再生骨料混凝土的抗压强度服从威布尔分布,威布尔分布参数中的形状系数 m 可以表征再生混凝土破坏的随机性和复杂性。随着再生骨料替代率的增加,再生骨料混凝土抗压强度的离散性呈下降趋势。
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引用次数: 0
Enhanced Feature Representation for Multimodal Fake News Detection Using Localized Fine-Tuning of Improved BERT and VGG-19 Models 利用改进型 BERT 和 VGG-19 模型的局部微调增强多模态假新闻检测的特征表示
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-07 DOI: 10.1007/s13369-024-09354-2
Suhaib Kh. Hamed, Mohd Juzaiddin Ab Aziz, Mohd Ridzwan Yaakub

The spread of fake news poses significant challenges across various sectors, including health, the economy, politics, and national stability. Social media and modern technology have facilitated the rapid dissemination of fake news, predominantly in multimedia formats. Despite advancements, multimodal fake news detection models struggle to achieve optimal accuracy, primarily due to the quality of feature representation. This study aims to enhance feature representation to improve fake news identification. Pre-trained models for feature extraction, typically designed for general public domains, may not suit the specific characteristics of our task using the Fakeddit dataset. We propose a localized fine-tuning strategy, refining pre-trained BERT and VGG-19 models for accurate multimodal feature representation in fake news detection. BERT was fine-tuned by retraining all layers, while only the last block of VGG-19 was fine-tuned. To further enhance the representations, we made structural modifications to VGG-19, including the use of a global average pooling layer and a redesigned classifier. This approach significantly improved our multimodal fake news detection model’s performance, achieving a high accuracy of 92%. Compared to state-of-the-art studies that use generic pre-trained models, our model demonstrates superior performance. Our research underscores the importance of feature representation in multimodal contexts and opens avenues for exploring the synergy between textual and visual modalities in fake news detection.

假新闻的传播给卫生、经济、政治和国家稳定等各个领域带来了重大挑战。社交媒体和现代技术促进了以多媒体形式为主的假新闻的快速传播。尽管取得了进步,多模态假新闻检测模型仍难以达到最佳准确度,这主要是由于特征表示的质量造成的。本研究旨在增强特征表示,以提高假新闻识别率。用于特征提取的预训练模型通常是为一般公共领域设计的,可能不适合我们使用 Fakeddit 数据集的任务的具体特点。我们提出了一种局部微调策略,对预先训练的 BERT 和 VGG-19 模型进行改进,从而在假新闻检测中实现准确的多模态特征表示。通过重新训练所有层对 BERT 进行了微调,而只对 VGG-19 的最后一个区块进行了微调。为了进一步增强表征,我们对 VGG-19 进行了结构性修改,包括使用全局平均池化层和重新设计的分类器。这种方法大大提高了多模态假新闻检测模型的性能,准确率高达 92%。与使用通用预训练模型的最先进研究相比,我们的模型表现出了卓越的性能。我们的研究强调了多模态背景下特征表示的重要性,并为探索假新闻检测中文本和视觉模态之间的协同作用开辟了途径。
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引用次数: 0
Biopolymer and Gypsum Added Na Bentonite for a More Effective Clay Liner 添加生物聚合物和石膏的钠基膨润土可制成更有效的粘土衬里
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-07 DOI: 10.1007/s13369-024-09386-8
Ali Hossien Basheer Garoushi, Eris Uygar

Bentonite soil is frequently utilized as a compacted clay liner, which is a critical component of municipal waste landfill systems. This study aims to investigate the feasibility of treating sodium bentonite (NAB) with natural biopolymers to obtain an effective clay liner. The NAB was treated with three biopolymers: sodium alginate (SA), agar gum (A), and xanthan gum (X), at different replacement percentages (2%, 4%, 6%, and 8%). Additionally, an investigation was conducted to determine the extent to which replacing 50% of these additives with gypsum (G) would improve the biopolymer treatments. Fourier-transform infrared spectroscopy (FTIR), pH, one-dimensional swelling, and unconfined compressive strength (UCS) were carried out in this study. The FTIR results indicated the presence of intermolecular hydrogen bonding when NAB was treated with biopolymers and gypsum, which is crucial for enhancing the UCS. Furthermore, the thermal treatment of biopolymers significantly contributes to improving the UCS. Among the various biopolymers tested, agar gum demonstrated the most significant improvement, specifically, replacing 8% of the NAB with agar gum resulted in a 55% increase in UCS. Volume change behavior was most influenced by replacement of NAB with gypsum by 8%, which reduced the vertical swelling to 21% as opposed to 79% for the untreated NAB. The use of SA conversely resulted in an increased vertical swelling of 91%.

膨润土常用作压实粘土衬垫,是城市垃圾填埋场系统的重要组成部分。本研究旨在探讨用天然生物聚合物处理钠基膨润土(NAB)以获得有效粘土衬垫的可行性。用海藻酸钠 (SA)、琼脂胶 (A) 和黄原胶 (X) 三种生物聚合物以不同的替代比例(2%、4%、6% 和 8%)处理 NAB。此外,还进行了一项调查,以确定用石膏(G)替代这些添加剂中的 50%会在多大程度上改善生物聚合物的处理效果。本研究采用了傅立叶变换红外光谱(FTIR)、pH 值、一维膨胀和无侧限抗压强度(UCS)。傅立叶变换红外光谱结果表明,用生物聚合物和石膏处理 NAB 时,分子间存在氢键,这对提高 UCS 至关重要。此外,生物聚合物的热处理也大大有助于提高 UCS。在测试的各种生物聚合物中,琼脂树胶的改善效果最为显著,具体而言,用琼脂树胶替代 8%的 NAB 可使 UCS 提高 55%。用石膏替代 8%的 NAB 对体积变化行为的影响最大,它使垂直膨胀率降低到 21%,而未经处理的 NAB 的垂直膨胀率为 79%。相反,使用 SA 则使垂直膨胀率增加了 91%。
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引用次数: 0
High-Frequency Dual-Branch Network for Steel Small Defect Detection 用于钢材小缺陷检测的高频双分支网络
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-07 DOI: 10.1007/s13369-024-09352-4
Chi Ma, Zhigang Li, Yueyuan Xue, Shujie Li, Xiaochuan Sun

Strip surface defect detection is pivotal in the steel industry for improving strip production quality. However, there is still a big gap between the existing working and the detection of small defects in strip steel in practical applications. In this paper, we propose the SSD-YOLO model, which is designed specifically for detecting small defects on strip steel surfaces. Given the challenge of feature extraction due to the small defect size, it utilizes a dual-branch feature extraction and channel-level feature fusion to enhance the expression capability of small defects. Moreover, it integrates a multiscale high-resolution detection module to achieve precise segmentation, thereby improving the overall detection accuracy of the model. The experimental results illustrate that the SSD-YOLO model, as proposed, attains a 98.0% mean average precision (mAP) and operates at 66 frames per second (FPS) when evaluated on the SSDD (Steel Small Defect Dataset). In comparison with YoloV8s, the SSD-YOLO achieves a significant improvement in accuracy, with an increase of 19.9%. The inference time and performance of our SSD-YOLO is well balanced, making it suitable for real-world deployment.

带钢表面缺陷检测是钢铁行业提高带钢生产质量的关键。然而,在实际应用中,现有工作与带钢小缺陷检测之间仍存在很大差距。本文提出了 SSD-YOLO 模型,该模型专为检测带钢表面的小缺陷而设计。考虑到小缺陷尺寸给特征提取带来的挑战,它利用双分支特征提取和通道级特征融合来增强小缺陷的表达能力。此外,它还集成了多尺度高分辨率检测模块,实现了精确分割,从而提高了模型的整体检测精度。实验结果表明,在 SSDD(钢铁小缺陷数据集)上评估时,所提出的 SSD-YOLO 模型达到了 98.0% 的平均精度 (mAP),运行速度为每秒 66 帧 (FPS)。与 YoloV8s 相比,SSD-YOLO 的精确度显著提高,提高了 19.9%。我们的 SSD-YOLO 在推理时间和性能方面达到了很好的平衡,适合实际部署。
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引用次数: 0
Multi-objective Optimal Antiwindup Compensation of Discrete-Time Nonlinear Systems Under Input Saturation 输入饱和状态下离散时间非线性系统的多目标最优防逆风补偿
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-06 DOI: 10.1007/s13369-024-09385-9
Faisal Iqbal, Muhammad Rehan, Muntazir Hussain, Ijaz Ahmed, Muhammad Khalid

This paper deals with the discrete-time antiwindup compensator (AWC) synthesis for nonlinear discrete-time systems under input saturation. The proposed method considers the objective of an optimal AWC design for fast convergence and for improved performance against the saturation nonlinearity. A discrete-time full-order AWC architecture is presented for nonlinear discrete-time systems to achieve an improved performance against the saturation nonlinearity. Additionally, an equivalent decoupled AWC architecture for nonlinear discrete-time system is derived through algebraic analysis and transformation of saturation to dead-zone function. To achieve fast convergence, a more generic Lyapunov function has been applied for the AWC design by incorporating an exponential term in the Lyapunov function. Then, new conditions for the AWC synthesis are revealed by application of the resultant decoupled discrete-time architecture, nonlinearity condition, a modified quadratic-exponential Lyapunov function, optimally exponential (L_{2}) approach, and input saturation properties. The design conditions are provided for both global and local design scenarios, which can be applied to both stable and unstable plants. Compared with the conventional methods, the proposed approach deals with nonlinear systems, can be more practical due to discrete-time scenario, provides an optimal design for both fast convergence and performance, and applicable to both stable and unstable plants. A simulation example has been provided to demonstrate the efficacy of the proposed nonlinear AWC design.

本文论述了输入饱和状态下非线性离散时间系统的离散时间反逆风补偿器(AWC)合成。所提出的方法考虑的目标是优化 AWC 设计,以实现快速收敛并提高抗饱和非线性性能。针对非线性离散时间系统,提出了一种离散时间全阶 AWC 架构,以提高对抗饱和非线性的性能。此外,通过代数分析和饱和到死区函数的变换,还推导出了非线性离散时间系统的等效解耦 AWC 架构。为了实现快速收敛,通过在 Lyapunov 函数中加入指数项,在 AWC 设计中应用了更通用的 Lyapunov 函数。然后,通过应用由此产生的解耦离散时间架构、非线性条件、改进的二次-指数 Lyapunov 函数、最优指数 (L_{2}) 方法和输入饱和特性,揭示了 AWC 综合的新条件。为全局和局部设计方案提供了设计条件,既适用于稳定工厂,也适用于不稳定工厂。与传统方法相比,所提出的方法可以处理非线性系统,由于采用了离散时间方案,因此更加实用,同时提供了快速收敛和性能的最优设计,并适用于稳定和不稳定的工厂。我们提供了一个仿真实例来证明所提出的非线性 AWC 设计的有效性。
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引用次数: 0
Fabrication of New Hyper-cross-linked Polymer for Efficient Heavy Metal Adsorption from Industrial Wastewater 制备新型超交联聚合物以高效吸附工业废水中的重金属
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-06 DOI: 10.1007/s13369-024-09259-0
Isham Areej, Saqlain Raza, Amin Abid, Ahmad Kaleem Qureshi, Umer Shafique, Bien Tan

Water pollution is the emerging issue in modern world that may cause water scarcity for our future generations. Therefore, it is ultimate need to develop highly efficient and cost-effective methods to solve this issue. Due to this intense demand, a new hyper-cross-linked polymer (HCP) of resorcinol (1, 3-dihydroxybenzol) “R-HCP” is synthesized using Friedel–Craft reaction for the removal of cadmium metal ions from industrial wastewater. Real industrial wastewater samples are used to evaluate the adsorption capability of R-HCP. Fabricated R-HCP is characterized through Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction analysis (XRD), EDX (energy-dispersive X-ray spectroscopy) and BET (Brunauer–Emmett–Teller). The BET surface area of R-HCP is 221.5848 m2g−1. Through salt addition method, the point of zero charge (PZC) was also determined, and its value is 2.0 pH. The maximum adsorption capacity of R-HCP is 10 mg/g for cadmium metal ions. The greatest adsorption value of 93% was obtained at pH 10 with 0.5 g of adsorbent and 9-min contact time and favors exothermic reaction. Langmuir, Freundlich and Temkin isotherms were studied, and results shows that Freundlich model is the best fit with R2 value of 0.9917. Adsorption kinetic investigation shows that it follows pseudo-first-order kinetic model R2 value 0.9874. The study of the effect of interfering ions including calcium, magnesium, sodium and potassium demonstrates the decrease in the adsorption capacity to a little extent. R-HCP can be recycled and have regeneration capacity, which is novel and distinguished feature of this adsorbent.

水污染是现代世界新出现的问题,可能会导致我们的子孙后代缺水。因此,我们亟需开发高效、经济的方法来解决这一问题。基于这种强烈的需求,我们利用 Friedel-Craft 反应合成了一种新型间苯二酚(1, 3-二羟基苯酚)超交联聚合物 (HCP) "R-HCP",用于去除工业废水中的金属镉离子。真实的工业废水样本被用来评估 R-HCP 的吸附能力。通过傅立叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X 射线衍射分析(XRD)、EDX(能量色散 X 射线光谱)和 BET(布鲁瑙尔-艾美特-泰勒)对制备的 R-HCP 进行表征。R-HCP 的 BET 表面积为 221.5848 m2g-1。通过加盐法,还测定了零电荷点(PZC),其值为 2.0 pH。R-HCP 对金属镉离子的最大吸附容量为 10 mg/g。在 pH 值为 10、吸附剂用量为 0.5 克、接触时间为 9 分钟的条件下,吸附率最高,达到 93%,并且有利于放热反应。研究了 Langmuir、Freundlich 和 Temkin 等温线,结果表明 Freundlich 模型的拟合效果最好,R2 值为 0.9917。吸附动力学研究表明,它遵循伪一阶动力学模型,R2 值为 0.9874。对包括钙、镁、钠和钾在内的干扰离子的影响研究表明,其吸附能力会略有下降。R-HCP 可以循环使用,具有再生能力,这是该吸附剂的新颖之处和突出特点。
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Arabian Journal for Science and Engineering
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