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Photoelectrochemical Water Splitting using GaN Nanowires with Reverse-Mesa Structures as Photoanode Material 利用反台面结构GaN纳米线作为光阳极材料的光电化学水分解
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-03-31 DOI: 10.5757/asct.2022.31.2.51
S. Noh, Sangmoon Han, J. Shin, Jinseong Lee, Ilgyu Choi, H. Oh, Mee-Yi Ryu, J. S. Kim
We report improved photoelectrochemical water splitting (PEC-WS) using GaN nanowires (NWs) with reverse-mesa structures (RMNWs) formed on Si(111) as a photoanode material. The GaN-RMNWphotoanode exhibited a current density of 2.62 mA/cm2 and an applied photonto-current efficiency of 1.65% at 0.6 V versus a reversible hydrogen electrode. These values are considerably higher than those (1.16 mA/cm2 and 1.24%) of the photoanode based on GaN NWs with uniform hexagonal-pillar structures. The improved PEC-WS using the GaN-RMNW photoanode is attributed to the increase in the number of carriers participating in the PEC-WS reaction. The increase in the effective carriers is primarily due to the high crystallinity of the GaN RMNWs and the increase in the absorption rate of the incident light by the reverse-mesa structures. In addition, the energy-band structure between the GaN RMNWs and Si(111) promotes the separation of photogenerated carriers. Consequently, it reduces carrier recombination inside the photoanode, thereby enabling a high-performance PEC-WS.
我们报道了利用在Si(111)上形成的具有反台面结构(RMNWs)的GaN纳米线(NWs)作为光阳极材料改进的光电化学水分解(PEC-WS)。与可逆氢电极相比,gan - rmnw光阳极在0.6 V电压下的电流密度为2.62 mA/cm2,光子电流效率为1.65%。这些值明显高于具有均匀六边形柱结构的氮化镓NWs光阳极(1.16 mA/cm2和1.24%)。使用GaN-RMNW光阳极改进的PEC-WS归因于参与PEC-WS反应的载流子数量的增加。有效载流子的增加主要是由于GaN RMNWs的高结晶度和反向台面结构对入射光吸收率的增加。此外,GaN RMNWs和Si(111)之间的能带结构促进了光生载流子的分离。因此,它减少了光阳极内部的载流子重组,从而实现了高性能的PEC-WS。
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引用次数: 4
Thermal Plasma Synthesis of Metal-Boride Nanoparticles as a Functional Material for Gamma-Ray Shielding 热等离子体合成金属-硼化物纳米粒子作为伽马射线屏蔽功能材料
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-01-31 DOI: 10.5757/asct.2022.31.1.15
Hye-Young Ko, Jeong-Hwan Oh, Su-Lin Yang, Sooseok Choi
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引用次数: 0
Optical Diagnostics for Dual Jet Interactions of Helium Atmospheric Pressure Plasmas 氦大气压等离子体双射流相互作用的光学诊断
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-01-31 DOI: 10.5757/asct.2022.31.1.19
Jae Wan Kim, Gyoon Kim, Holak Kim, J. Foster, U. Cho, S. Yun, H. Lee
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引用次数: 0
In-Situ High-Temperature Heating Setup for Spectronanoscopy at Pohang Light Source 浦项光源光谱原位高温加热装置
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-01-31 DOI: 10.5757/asct.2022.31.1.9
Mikang Kim, Namdong Kim, H. Hosseinkhannazer, Ki-Jeong Kim, H. Shin
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引用次数: 0
Effect of Antisolvent Application Volume on CH3NH3PbI3 Films 抗溶剂用量对CH3NH3PbI3薄膜的影响
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-01-31 DOI: 10.5757/asct.2022.31.1.28
J. Oh, Mee-Yi Ryu
Antisolventtreatmentmethodsusedtomanufacturehigh-qualityperovskitefilmsusingsolutionprocessesvaryintermsofthetypeofantisolventandprocessingconditionemployed.Weanalyzedthestructuraldependencesofaperovskitefilmintermsoftheappliedvolumeofethylacetateasanantisolventandtheopticalpropertiesresultingtherefrom.Theapplicationofanexcessivevolumeoftheantisolventcausedexcessivepinholesintheentireareaoftheperovskitefilm.Inaddition,thepinholeswerefoundtohinderthetransportofchargecarriers.
Antisolventtreatmentmethodsusedtomanufacturehigh-qualityperovskitefilmsusingsolutionprocessesvaryintermsofthetypeofantisolventandprocessingconditionemployed.Weanalyzedthestructuraldependencesofaperovskitefilmintermsoftheappliedvolumeofethylacetateasanantisolventandtheopticalpropertiesresultingtherefrom.Theapplicationofanexcessivevolumeoftheantisolventcausedexcessivepinholesintheentireareaoftheperovskitefilm.Inaddition thepinholeswerefoundtohinderthetransportofchargecarriers。
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引用次数: 0
Large-Scale Transparent Photovoltaics for a Sustainable Energy Future: Review of Inorganic Transparent Photovoltaics 面向可持续能源未来的大规模透明光伏:无机透明光伏的综述
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-01-31 DOI: 10.5757/asct.2022.31.1.1
B. Baby, Malkeshkumar Patel, Kibum Lee, Joondong Kim
Transparent photovoltaics (TPVs) are a crucial energy platform for harvesting solar energy in windows, enabling onsite power generation for widespread applications in buildings, vehicles, displays, sensors, and the Internet of things. TPV devices are fabricated using eco-friendly processing methods and materials, and must perform stably for an adequate societal impact. This review article is focused on the emerging TPV devices made of inorganic materials, including oxides and two-dimensional sulfides. Herein, we briefly review the wide-bandgap inorganic TPVs and their performances. Specifically, the sputtering method is considered for the large-scale and eco-friendly preparation of inorganic heterostructures.
透明光伏(TPVs)是在窗户中收集太阳能的关键能源平台,使现场发电能够广泛应用于建筑物,车辆,显示器,传感器和物联网。TPV设备使用环保的加工方法和材料制造,并且必须稳定地运行以产生足够的社会影响。本文主要综述了由氧化物和二维硫化物等无机材料制成的新型TPV器件。本文简要介绍了宽带隙无机TPVs及其性能。具体地说,溅射方法被认为是大规模和生态友好的无机异质结构的制备。
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引用次数: 2
CH3NH3PbI3-based Perovskite Material Patterning and Thin-Film Transistor Fabrication 基于ch3nh3pbi3的钙钛矿材料图像化和薄膜晶体管制造
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-01-31 DOI: 10.5757/asct.2022.31.1.23
H. Khachatryan, Kyoung-Bo Kim, Moojin Kim
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引用次数: 1
Effects of Surface Contaminants on Interface Dipole Formation of 8-hydroxyquinolinolato-lithium Layer 表面污染物对8-羟基喹啉-锂层界面偶极子形成的影响
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-01-31 DOI: 10.5757/asct.2022.31.1.12
Hyunbok Lee
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引用次数: 0
Simulation Studies on Quasi-Bound States in the Continuum Introduced by Out-of-Plane Symmetry Breaking in Dielectric Metasurfaces 介电超表面面外对称破缺引入的连续介质中准束缚态的模拟研究
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-01-31 DOI: 10.5757/asct.2022.31.1.31
Hyunsung Lim, Jeeyoon Jeong
{"title":"Simulation Studies on Quasi-Bound States in the Continuum Introduced by Out-of-Plane Symmetry Breaking in Dielectric Metasurfaces","authors":"Hyunsung Lim, Jeeyoon Jeong","doi":"10.5757/asct.2022.31.1.31","DOIUrl":"https://doi.org/10.5757/asct.2022.31.1.31","url":null,"abstract":"","PeriodicalId":8223,"journal":{"name":"Applied Science and Convergence Technology","volume":"346 1","pages":""},"PeriodicalIF":0.8,"publicationDate":"2022-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75944617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Control of Cathode Arc Root Behavior in a Reverse Polarity Hollow Electrode Plasma Torch Using an Exit Nozzle 利用出口喷嘴控制反极性空心电极等离子炬阴极电弧根部行为
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-11-30 DOI: 10.5757/asct.2021.30.6.167
Sang-Min Jeong, Darian Figuera-Michal, Dong-Hyun Lee, Min-Gyu Choi, J. Seo
In this study, a hollow electrode plasma torch with a cylindrical exit nozzle was proposed and tested to control the behavior of cathode arc roots in the reverse polarity electrical connection for the non-transferred mode operation. The test results revealed that in the absence of an exit nozzle, cathode arc roots cause arcing on the electrically floated torch housing, producing an unstable plasma jet. However, in the presence of an exit nozzle, when injecting the secondary gas with a swirl through a gap between the exit nozzle and front electrode, it was confirmed that cathode arc roots can be controlled to form only on the surface of the front electrode, producing a stable plasma jet without arcing on the torch housing. Additionally, the presence of an exit nozzle was observed to have little influence on the voltage–current characteristics of a reverse polarity hollow electrode plasma torch. Instead, heat loss to the coolant was reduced compared to that in the absence of an exit nozzle, thereby improving thermal efficiency.
在这项研究中,提出并测试了一种具有圆柱形出口喷嘴的空心电极等离子炬,以控制阴极电弧根在反极性电连接中非转移模式操作的行为。测试结果表明,在没有出口喷嘴的情况下,阴极电弧根会在电浮火炬外壳上产生电弧,产生不稳定的等离子体射流。然而,在存在出口喷嘴的情况下,当通过出口喷嘴与前电极之间的间隙以涡流注入二次气体时,证实阴极弧根可以控制在前电极表面形成,从而产生稳定的等离子体射流,而不会在火炬外壳上产生电弧。此外,观察到出口喷嘴的存在对反极性空心电极等离子炬的电压电流特性影响很小。相反,与没有出口喷嘴的情况相比,冷却剂的热损失减少了,从而提高了热效率。
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引用次数: 1
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