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Characterization of SiO2 Over Poly-Si Mask Etching in Ar/C4F8 Capacitively Coupled Plasma Ar/C4F8电容耦合等离子体中SiO2的多晶硅掩模刻蚀特性
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-11-30 DOI: 10.5757/asct.2021.30.6.176
Inho Seong, Jangjae Lee, C. Cho, Yeong-Seok Lee, S. Kim, S. You
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引用次数: 15
Temperature-Dependence Study on the Hydrogen Transport Properties of Polymers Used for Hydrogen Infrastructure 氢基础设施用聚合物氢输运特性的温度依赖性研究
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-11-30 DOI: 10.5757/asct.2021.30.6.163
J. Jang, Chunjoong Kim, Nak-Kwan Chung
Polymeric materials used in hydrogen infrastructure degrade with temperature changes, thereby increasing the risk of hydrogen leakage. Therefore, it is essential to evaluate the hydrogen permeation characteristics at varying temperatures, particularly at low temperatures, for the safe use of hydrogen energy. This study aimed to measure hydrogen permeability at a temperature range of 243–313 K for exploring the hydrogen permeation characteristics according to the temperature of ethylene-propylene diene monomer (EPDM), fluorine-rubber (FKM), and nitrilebutadiene rubber (NBR) for hydrogen infrastructure. Results show that permeability and diffusivity rapidly decreased as the temperature decreased; however, there was no significant change in solubility with the variation in temperature. Activation energies of permeability, diffusivity, and solubility were calculated from the measurement results, among which the activation energy for permeability exhibited the largest value in the order of FKM, NBR, and EPDM.
用于氢气基础设施的聚合物材料随着温度的变化而降解,从而增加了氢气泄漏的风险。因此,评估不同温度下,特别是低温下氢气的渗透特性,对于氢能的安全利用至关重要。本研究旨在测量243-313 K温度范围内的氢气渗透率,以探索氢基础设施用三元乙丙橡胶(EPDM)、氟橡胶(FKM)和丁腈橡胶(NBR)的氢气渗透特性。结果表明:随着温度的降低,渗透率和扩散率迅速降低;而溶解度随温度变化无明显变化。根据测量结果计算渗透率活化能、扩散性活化能和溶解度活化能,其中渗透率活化能最大,依次为FKM、NBR、EPDM。
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引用次数: 1
Combination of Vacuum and Solution Processes for Stable Indoor Organic Solar Cell under LED Illumination LED照明下稳定室内有机太阳能电池的真空与溶液结合工艺研究
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-11-30 DOI: 10.5757/asct.2021.30.6.159
Yongju Lee, S. Biswas, Hyeok Kim
The use of tiny, micro-powered electronic devices in indoor environments is increasing daily. The demand for high-performing organic photo- voltaics (OPVs) to power these devices has been rapidly growing because OPVs have favorable absorption properties for indoor environments, excellent mechanical flexibility, and other advantageous attributes. Recently, inexpensive, less acidic, and water-processable polyaniline:poly (4-styrenesulfonic acid) (PANI:PSS) was shown to deliver remarkably high performance as the hole transport layer (HTL) in an indoor OPV device with poly(3-hexylthiophene): indene-C60 bisadduct as the active layer. However, PANI:PSS has not been tested in combination with other active materials, although its universal applicability is of key importance for its commercialization. Thus, we tested the potentiality of using PANI:PSS as the HTL of a highly suitable active material, poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b’]dithiophene-2,6-diyl][3-fluoro-2- [(2-ethylhexyl-l)carbonyl]thieno[3,4-b]thiophendiyl]:phenyl-C70-butyric acid methyl ester (PTB7:PC 70 BM) in an OPV device under an LED lamp. The results reveal that the OPV device based on the PANI:PSS HTL and PTB7:PC 70 BM as the active material has high efficiency (11.80%) and a maximum power density of 42.5 𝜇 W/cm 2 under a 1,000 lx LED.
在室内环境中使用微型、微功率电子设备的情况日益增多。高性能有机光伏(opv)为这些设备供电的需求一直在迅速增长,因为opv对室内环境具有良好的吸收特性,优异的机械灵活性和其他优势属性。最近,以聚(3-己基噻吩):茚- c60双合物为活性层的室内OPV装置中,廉价、低酸性、可水处理的聚苯胺:聚(4-苯乙烯磺酸)(PANI:PSS)作为空穴传输层(HTL)提供了非常高的性能。然而,PANI:PSS尚未与其他活性材料结合进行测试,尽管其普遍适用性对其商业化至关重要。因此,我们在LED灯下的OPV装置中测试了使用PANI:PSS作为一种非常合适的活性材料聚[[4,8-二[(2-乙基己基)氧]苯并[1,2-b:4,5-b ']二噻吩-2,6-二基][3-氟-2-[(2-乙基己基- 1)羰基]噻吩[3,4-b]噻吩基]:苯基c70 -丁酸甲酯(PTB7: pc70 BM)的HTL的潜力。结果表明,在1000 lx LED下,基于PANI:PSS HTL和PTB7: pc70 BM作为活性材料的OPV器件具有较高的效率(11.80%),最大功率密度为42.5≥W/ cm2。
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引用次数: 0
Numerical Analysis of Thermal Flow Characteristics Inside Waste Combustion Chamber with Multiple Thermal Plasma Jets 多个热等离子体射流的废燃烧室热流特性数值分析
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-11-30 DOI: 10.5757/asct.2021.30.6.172
Hyeokjun Kang, Jeong-Hwan Oh, Daeun Choi, H. Takana, Sooseok Choi
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引用次数: 0
Detection of Carbon Dioxide Using Cucurbit[6]uril-Functionalized Gold Nanorod Gas Sensor Based on Localized Surface Plasmon Resonance 基于局域表面等离子体共振的瓜[6]脲功能化金纳米棒气体传感器检测二氧化碳
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-11-30 DOI: 10.5757/asct.2021.30.5.186
Seongjae Jo, Jinyeong Kim, Yejin Kim, Oh Seok Kwon
Owing to rapid climate change and increasingly stringent carbon regulations, carbon dioxide detection is becoming more important. In this study, we fabricate a cucurbit[6]uril-functionalized gold nanorod-based localized surface plasmon resonance (LSPR) gas sensor to detect carbon dioxide. The gold nanorods provide a high refractive index unit that enables the measurement of gas molecules with low molecular weights, while cucurbit[6]uril is a chemical receptor that binds to carbon dioxide owing to its structural characteristics. Therefore, cucurbit[6]uril was functionalized through direct adhesion on the surface of gold nanorods, which was replaced with citrate. The manufactured sensor can detect the presence of carbon dioxide at a maximum concentration of 400 ppm in the atmosphere. The high potential applicability of the cucurbit[6]uril-applied LSPR gas sensors is demonstrated in this study.
由于气候的迅速变化和日益严格的碳法规,二氧化碳的检测变得越来越重要。在这项研究中,我们制作了一个基于葫芦[6]脲功能化金纳米棒的局域表面等离子体共振(LSPR)气体传感器来检测二氧化碳。金纳米棒提供了一个高折射率单元,可以测量低分子量的气体分子,而葫芦[6]脲是一种化学受体,由于其结构特征,可以与二氧化碳结合。因此,通过直接粘附在金纳米棒表面来实现葫芦[6]脲的功能化,并用柠檬酸盐代替金纳米棒。制造的传感器可以检测大气中最大浓度为400ppm的二氧化碳的存在。本研究证明了葫芦[6]应用于LSPR气体传感器的高潜在适用性。
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引用次数: 0
Spin-Orbit-Entangled Nature of Magnetic Moments and Kitaev Magnetism in Layered Halides 层状卤化物中磁矩和基塔耶夫磁性的自旋-轨道纠缠性质
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-11-24 DOI: 10.5757/ASCT.2021.30.6.191
Heung-Sik Kim
$alpha$-RuCl$_3$ has been extensively studied recently because of potential bond-dependent Kitaev magnetic exchange interactions and the resulting quantum spin liquid phase that can be realized therein. It has been known that the covalency between Ru 4$d$- and Cl $p$-orbitals is crucial to induce large Kitaev interactions in this compound, therefore replacing Cl into heavier halogen elements such as Br or I can be a promising way to promote the Kitaev interaction even further. In a timely manner, there have been reports on synthesis of $alpha$-RuBr$_3$ and $alpha$-RuI$_3$, which are expected to host the same spin-orbit-entangled orbitals and Kitaev exchange interactions with $alpha$-RuCl$_3$. Here in this work we investigate electronic structures of $alpha$-RuCl$_3$, $alpha$-RuBr$_3$, and $alpha$-RuI$_3$ in a comparative fashion, focusing on the cooperation of the spin-orbit coupling and on-site Coulomb repulsions to realize the spin-orbit-entangled pseudospin-1/2 at Ru sites. We further estimate magnetic exchange interactions of all three compounds, showing that $alpha$-RuBr$_3$ can be promising candidates to realize Kitaev spin liquid phases in solid-state systems.
$ α $-RuCl$_3$由于其潜在的键依赖基塔耶夫磁交换相互作用以及由此产生的量子自旋液相,近年来得到了广泛的研究。已知Ru 4$d$-和Cl $p$-轨道之间的共价对于在该化合物中诱导较大的基塔耶夫相互作用至关重要,因此将Cl替换为Br或I等较重的卤素元素可能是进一步促进基塔耶夫相互作用的有希望的方法。及时地,已经有报道合成了$alpha$-RuBr$_3$和$alpha$-RuI$_3$,它们有望具有相同的自旋轨道纠缠轨道,并与$alpha$-RuCl$_3$具有Kitaev交换作用。本文以比较的方式研究了$alpha$-RuCl$_3$、$alpha$-RuBr$_3$和$alpha$-RuI$_3$的电子结构,重点研究了自旋-轨道耦合和现场库仑斥力的协同作用,以实现Ru位上自旋-轨道纠缠的伪自旋-1/2。我们进一步估计了这三种化合物的磁交换相互作用,表明$alpha$-RuBr$_3$是在固态体系中实现基塔耶夫自旋液相的有希望的候选化合物。
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引用次数: 4
Surface Modification of Steel Foils by Depositing Cr/Al or Al/Cr Thin Films: Effect of Rapid Heat Treatment 沉积Cr/Al或Al/Cr薄膜对钢箔的表面改性:快速热处理的效果
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-09-30 DOI: 10.5757/asct.2021.30.5.146
H. Khachatryan, Kyoung-Bo Kim, Moojin Kim
In this study, Al and Cr films were deposited onto steel substrates, and the film growth and microstructure were tracked. In the first set of experiments, Al was directly deposited onto steel, and Cr films were then deposited on top of the formed Al films. In the second set of experiments, it was vice versa ; that is, Cr films were deposited onto the steel substrate, followed by Al film deposition. This technique was aimed at controlling the reflection property of the steel substrate to enable using steel foils for flexible display fabrication. It was observed that temperature significantly influenced grain formation and growth processes. When the temperature reached 550 ∘ C, segregation occurred in the system where Cr contacted the steel, and Al was on the top layer. However, a similar phenomenon was not observed in the steel/Al/Cr system. The reflection value significantly decreased from 92 to 5–7 %, owing to these segregations.
在本研究中,将Al和Cr薄膜沉积在钢基体上,并对薄膜的生长和微观结构进行了跟踪。在第一组实验中,将Al直接沉积在钢上,然后在形成的Al膜上沉积Cr膜。在第二组实验中,情况正好相反;即先在钢基体上沉积Cr膜,再沉积Al膜。该技术旨在控制钢衬底的反射特性,使使用钢箔柔性显示制造成为可能。温度对晶粒的形成和生长过程有显著影响。当温度达到550°C时,在与钢接触的系统中发生偏析,而Al在最上层。然而,在钢/铝/铬体系中没有观察到类似的现象。由于这些分离,反射值从92%显著下降到5 - 7%。
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引用次数: 0
Effect of Reaction Time on Optical Properties of CsPbBr3 Perovskite Nanocrystals 反应时间对CsPbBr3钙钛矿纳米晶体光学性质的影响
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-09-30 DOI: 10.5757/asct.2021.30.5.152
Sung Hun Kim, Yong-Ryun Jo, Yong Bin Kim, Ju Seok Kim, S. Yim, Hong Seok Lee
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引用次数: 1
Comparison of Ionic Liquid and Ion-Gel Top-Gate MoS2 Field-Effect Transistors 离子液体和离子凝胶顶栅MoS2场效应晶体管的比较
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-09-30 DOI: 10.5757/asct.2021.30.5.156
Guen Hyung Oh, Taewan Kim
Polymer electrolytes and ionic liquids (ILs) have attracted significant interest in applications as gate dielectrics. In this study, we fabricated top-gated molybdenum disulfide (MoS2) thin-film transistors using IL and ion-gel (IG) gate dielectrics. Room-temperature Raman spectra measurements indicated a dominant peak spectral emission at 358 cm−1 (E1 2g) and 406.44 cm−1 (A1g) associated with bilayer MoS2 films. The fabricated thin-film field-effect transistors (FET) with IG gate dielectric exhibited band transport with a highest mobility of 0.5 cm2/V⋅s, and a poor ION/IOFF ratio of ~10. By contrast, the FET with IL gate dielectric exhibited a 3400 % improvement in terms of the mobility (17.9 cm2/V⋅s), and a 1000 % improvement of the ION/IOFF ratio (~100).
聚合物电解质和离子液体在栅极介质方面的应用引起了人们的极大兴趣。在这项研究中,我们使用IL和离子凝胶(IG)栅极介质制备了顶门控二硫化钼(MoS2)薄膜晶体管。室温拉曼光谱测量表明,与双层MoS2薄膜相关的主要光谱发射峰为358 cm−1 (E1 2g)和406.44 cm−1 (A1g)。采用IG栅极介质制备的薄膜场效应晶体管(FET)表现出带输运,迁移率最高为0.5 cm2/V·s, ION/IOFF比较差,为~10。相比之下,具有IL栅极介质的FET在迁移率方面提高了3400% (17.9 cm2/V·s),离子/IOFF比提高了1000%(~100)。
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引用次数: 0
A Study on Direct Current Arc Plasma Torch Design with Preserve Nozzle for Perfluorinated Compounds (PFCs) Decomposition in Cement Kiln 水泥窑全氟化合物分解用保存喷嘴直流电弧等离子炬设计研究
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-09-30 DOI: 10.5757/asct.2021.30.5.137
Tae-Wook Kim, Gye-Young Jo, Soo-Min Lee, Kyu-Hang Lee, Yetang Jin, Byung-Koo Son
Perfluorinated compounds (PFCs), including sulfur hexafluoride (SF 6 ), are used as insulating gases for heavy electric equipment, and are green- house gases with a very high global warming potential. For the thermal decomposition of greenhouse gases, a high temperature of 3,000 K or more and a technology to prevent recombination of the decomposed gases are required. A direct current plasma arc with a flame temperature of 6,000 K or higher provides an effective ultra-high temperature for the decomposition of chemically stable PFCs. A large amount of CaO, which is a raw material for clinker, is in the cement kiln, hence the S and F radicals decomposed from SF 6 react with CaO to quickly convert it to CaF 2 and CaSO 4 and prevent their recombination. Therefore, the convergence technology of plasma and cement kiln is known as an effective method for treating PFCs. However, the interior of the cement kiln causes erosion of the plasma torch due to the turbulent flow of a large amount of combustion air at a high temperature of 1,500 ∘ C or more, and the scattering of the raw material particles of the clinker, which greatly affects the operation stability. In this study, a plasma torch was developed that can maintain stable plasma in a vulnerable environment and effectively decompose PFCs. Moreover, the design and results of the experiment on the torch were presented to enable stable plasma operation for a long time in vulnerable environmental conditions through durability, plasma efficiency, and analysis of the discharge characteristics. thermal efficiency, and durability of the plasma torch were analyzed. Continuous operation of the plasma torch for more than 1,000 h while maintaining the plasma characteristics even in en- vironments with a high temperature, vibration, and strong turbulent flow was verified using a molybdenum preserve nozzle. At this time, the plasma efficiency was measured as 79.1%, confirming the supe-rior durability and efficiency of the developed plasma torch to those of the conventional PFC treatment torch. These results show that the high-temperature plasma torch can be considered advanced technol- ogy with high utility in various waste gas treatment processes and plasma incineration fields by overcoming the short lifespan due to electrode erosion, which is a known disadvantage of high-temperature plasma torches.
全氟化合物(PFCs),包括六氟化硫(sf6),被用作重型电气设备的绝缘气体,是具有非常高的全球变暖潜势的温室气体。对于温室气体的热分解,需要3000 K以上的高温和防止分解气体再结合的技术。直流电浆电弧的火焰温度为6000 K或更高,为化学稳定的pfc的分解提供了有效的超高温。水泥窑中存在大量的熟料原料CaO,因此SF - 6分解出的S、F自由基与CaO发生反应,迅速转化为caf2和caso4,阻止了它们的复合。因此,等离子体与水泥窑融合技术被认为是处理全氟碳化合物的有效方法。但是,水泥窑内部由于大量燃烧空气在1500°C以上高温下的紊流,以及熟料原料颗粒的散射,造成等离子炬的侵蚀,极大地影响了运行的稳定性。在本研究中,开发了一种等离子炬,可以在脆弱的环境中保持稳定的等离子体,并有效地分解pfc。此外,介绍了火炬的设计和实验结果,通过耐久性、等离子体效率和放电特性分析,实现了等离子体在脆弱环境条件下的长时间稳定运行。对等离子炬的热效率和耐久性进行了分析。使用钼保护喷嘴验证了等离子体炬在高温、振动和强湍流环境中连续运行1000小时以上,同时保持等离子体特性。此时,测量到的等离子体效率为79.1%,证实了所开发的等离子体炬比传统PFC处理炬具有更高的耐用性和效率。这些结果表明,高温等离子体炬克服了高温等离子体炬电极腐蚀寿命短的缺点,在各种废气处理工艺和等离子体焚烧领域具有很高的实用性。
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引用次数: 1
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Applied Science and Convergence Technology
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