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Experimental Study of Discharge with Flexible Electrodes at Intermediate Pressure for Radar Cross Section Reduction 柔性电极中压放电降低雷达截面积的实验研究
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-09-30 DOI: 10.5757/asct.2021.30.5.141
Jangjae Lee, C. Cho, M. Choi, Chang Seok Cho, T. J. Oh, Yong Shik Lee, J. Yim, Heung Cheol Yoo, Hee Soo Jung, S. You
In this experimental research, the characteristics of the discharge generated using a flexible electrode at intermediate pressure were investigated. We confirmed the discharge patterns according to the pulse width and frequency of a pulse generator with a fixed voltage under a pressure of 0.3 atm, which is the pressure at a typical flight altitude. Uniform discharge was found to occur at a frequency of 10 kHz with a pulse width of 4 μs and at a frequency of 20 kHz with a pulse width of 3 μs. To analyze the trend of discharge patterns, the voltage and current waveforms of the discharge in each condition were measured. In addition, the power dissipated by one cycle was calculated from the measured voltage and current waveforms. From the measurement and calculation results, it was confirmed that the dissipated power was large when the discharge occurred at a frequency of 20 kHz with a pulse width of 3 μs, that is, the brighter and more uniform discharge pattern, which was found to be the optimal discharge condition for the flexible electrode at a pressure of 0.3 atm.
实验研究了柔性电极在中压条件下产生的放电特性。在典型飞行高度压力为0.3 atm的条件下,我们根据固定电压下脉冲发生器的脉宽和频率来确定放电模式。在频率为10 kHz时,脉冲宽度为4 μs;在频率为20 kHz时,脉冲宽度为3 μs,放电均匀。为了分析放电模式的变化趋势,测量了各工况下放电的电压和电流波形。此外,根据测量的电压和电流波形计算了一个周期的功耗。测量和计算结果表明,当放电频率为20 kHz,脉宽为3 μs时,放电耗散功率大,放电模式更亮、更均匀,这是0.3 atm压力下柔性电极的最佳放电条件。
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引用次数: 0
Fast Synthesis of Ligand-Coordinated Chromium (II) Acetate with Quadruple Bonds by Seed-Mediated Growth 种子介导快速合成四键配位乙酸铬
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-07-30 DOI: 10.5757/asct.2021.30.4.95
Intek Song
A new way to prepare single crystals of ligand-coordinated chromium (II) acetate with quadruple bonds is presented. Coordination of water and pyridine with crystal growth occur by seed-mediated growth. The product was obtained as crystals with well-defined facets. Raman spectroscopy confirmed the high quality and purity of the products. Mechanism studies showed that the growth reaction is driven by heterogeneous crystallization at the interface of the seeds. Seed-mediated growth results in the high quality and large size of the crystals with improved yield for shorter reaction time.
提出了一种制备四键配位醋酸铬单晶的新方法。水和吡啶与晶体生长的配合是通过种子介导的生长发生的。所得产物为晶面清晰的晶体。拉曼光谱证实了产品的高质量和纯度。机理研究表明,生长反应是由种子界面的非均相结晶驱动的。种子介导生长的结果是高质量和大尺寸的晶体,提高了产率,缩短了反应时间。
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引用次数: 0
Characteristics of SiO2 Etching by Capacitively Coupled Plasma with Different Fluorocarbon Liquids (C7F14, C7F8) and Fluorocarbon Gas (C4F8) 不同碳氟化合物液体(C7F14、C7F8)和碳氟化合物气体(C4F8)电容耦合等离子体刻蚀SiO2的特性
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-07-30 DOI: 10.5757/asct.2021.30.4.102
Seung-Wan Yoo, C. Cho, Kyung Tae Kim, Hyo-Chang Lee, Shinjae You
Fluorocarbon (C 7 F 14 , C 7 F 8 ) plasmas are investigated to verify their etching characteristics as an alternative etchant of SiO 2 etch process because C 7 F 8 and C 7 F 14 precursors are expected to have low Global warming potentials. Comparing the etch results of C 4 F 8 , C 7 F 14 , and C 7 F 8 plasmas, C 7 F 8 provides the highest selectivity for etching SiO 2 at a moderate etching rate of the three fluorocarbons. C 4 F 8 and C 7 F 14 plasmas show similar magnitudes of selectivity at the same O 2 injection. O 2 addition is used to control densities of carbon species and optimize etching conditions. From comparison of the species existing in the C 4 F 8 , C 7 F 14 , and C 7 F 8 plasmas by the electron-emitting source, CF radicals and carbon atoms are important in determining the remarkable selectivity of C 7 F 8 plasma. This understanding is verified using X-ray photoelectron spectroscopy analysis.
由于c7f8和c7f14前驱体具有较低的全球变暖潜能值,研究了氟碳(c7f14, c7f8)等离子体作为sio2蚀刻工艺替代蚀刻剂的蚀刻特性。比较c4f8、c7f14和c7f8等离子体的刻蚀结果,c7f8在三种碳氟化合物的中等刻蚀速率下对sio2的刻蚀选择性最高。c4f8和c7f14等离子体在相同的o2注入下表现出相似的选择性。o2的加入是用来控制碳种密度和优化蚀刻条件。通过电子发射源对c4f8、c7f14和c7f8等离子体中存在的物质的比较,CF自由基和碳原子是c7f8等离子体具有显著选择性的重要原因。这种理解是用x射线光电子能谱分析验证的。
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引用次数: 2
Influence of Bismuth Oxide on Dielectric Properties of Barium Titanate Solid Solution 氧化铋对钛酸钡固溶体介电性能的影响
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-07-30 DOI: 10.5757/asct.2021.30.4.98
Y. Kim
A Ba 0.9 Bi 0.1 TiO 3 solid solution was prepared by substituting 0.1 mole % Bi 2 O 3 at the Ba 2+ sites in BaTiO 3 , and its dielectric properties were investigated. The Ba 0 . 9 Bi 0 . 1 TiO 3 solid solution was sintered at 1310 ∘ C for 5 h. The stable formation of the perovskite structure was confirmed through X-ray diffraction, energy-dispersive X-ray spectroscopy, and field emission scanning electron microscopy. Unlike pure BaTiO 3 , pyrochlore Bi 2 Ti 2 O 7 was observed in Ba 0 . 9 Bi 0 . 1 TiO 3 at approximately 27.1 ∘ . Overall, the perovskite structure was well formed. The Ba 0 . 9 Bi 0 . 1 TiO 3 solid solution showed typical dielectric properties and followed the modified Curie–Weiss law. In addition, the curve of the dielectric constant vs. temperature showed an extremely gradual change compared to the phase transition behavior of BaTiO 3 .
用0.1摩尔% bi2o3取代batio3中的ba2 +,制备了ba0.9 Bi 0.1 tio3固溶体,并对其介电性能进行了研究。Ba 0。9 . b。将tio3固溶体在1310°C下烧结5小时。通过x射线衍射、能量色散x射线光谱和场发射扫描电子显微镜证实钙钛矿结构的稳定形成。与纯batio3不同,在ba0中观察到焦绿石bi2ti2o7。9 . b。约27.1°的TiO 3。总体而言,钙钛矿结构形成良好。Ba 0。9 . b。tio3固溶体具有典型的介电性质,符合修正的居里-魏斯定律。此外,与batio3的相变行为相比,介电常数随温度的变化曲线表现出极其缓慢的变化。
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引用次数: 0
Graphene Field-Effect Transistor Based High-Performance Wireless Portable Device for H1N1 Detection 基于石墨烯场效应晶体管的H1N1检测高性能无线便携设备
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-07-30 DOI: 10.5757/asct.2021.30.4.111
Kyung Ho Kim, Jaieun An, Jun-Seob Kim, Joonwon Bae, Oh Seok Kwon
In this study, a convenient high-performance portable sensor platform for simple, fast, and efficient detection of H1N1 virus is demonstrated using a graphene-based transistor type architecture. A uniform graphene layer was generated and patterned by conventional methods such as lithography and vapor deposition, subsequently, electrodes were introduced on the patterned graphene layer to obtain transistor type sensor geometry. Then, the graphene surface was functionalized with antibody for H1N1 virus detection and sensor performance test. The transition curve, linearity, and sensitivity (10 pfu/mL) of the sensor component were measured. In addition, the portable H1N1 diagnosis platform for simple, fast, and convenient virus detection was produced and demonstrated. Consequently, the sensor performance was maintained in the portable sensor platform compared with the graphene-based sensor component. This presented portable H1N1 diagnosis platform showed better performance than the lateral flow assay.
在这项研究中,我们展示了一种方便的高性能便携式传感器平台,用于简单、快速、高效地检测H1N1病毒,该平台采用基于石墨烯的晶体管型架构。通过光刻和气相沉积等传统方法生成均匀的石墨烯层并进行图像化,随后在图像化的石墨烯层上引入电极以获得晶体管型传感器的几何形状。然后,用抗体对石墨烯表面进行功能化,用于H1N1病毒检测和传感器性能测试。测量传感器组分的过渡曲线、线性度和灵敏度(10 pfu/mL)。制作并演示了简易、快速、方便的便携式H1N1病毒检测平台。因此,与基于石墨烯的传感器组件相比,在便携式传感器平台上保持了传感器的性能。该便携式H1N1诊断平台的性能优于侧流法。
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引用次数: 2
Distinctive Spectroscopic Characteristics Observed in Colloidal Perovskite CsPbBr3 Quantum Dot 胶体钙钛矿CsPbBr3量子点独特光谱特性的观察
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-07-30 DOI: 10.5757/asct.2021.30.4.107
Sangeun Cho, S. Noh, Hyungsang Kim, H. Im
Distinctive spectroscopic characteristics are observed in colloidal perovskite CsPbBr 3 quantum dot (QD) dispersed in octane doped with PPO. As the content of CsPbBr 3 -QD increases, the emission and the absorption energies decrease due to QD-cluster formed in case of the inter-QD distance smaller than diameter of QD. Spectroscopic evidences supporting QD-cluster are found in the Urbach energy and the carrier lifetime. Unusual absorption lines showing explicit QD dependence are observed in Fourier-transform infrared spectra, which is explained by vibrational modes of bound PPO hybridized with CsPbBr 3 -QD.
胶体钙钛矿cspbbr3量子点(QD)分散在掺杂PPO的辛烷中,观察到其独特的光谱特征。随着CsPbBr 3 -QD含量的增加,当量子点间距小于量子点直径时,由于形成量子点团簇,发射和吸收能量降低。在厄巴赫能量和载流子寿命中找到了支持量子点团簇的光谱证据。在傅里叶变换红外光谱中观察到异常的吸收谱线显示出明显的QD依赖性,这可以用结合PPO与CsPbBr 3 -QD杂化的振动模式来解释。
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引用次数: 1
Enhancement of Photocatalytic Activity of Tris (bipyridine) Ruthenium by Encapsulation in Zeolitic Imidazolate Framework-11 and 12 咪唑酸分子筛包封增强三(联吡啶)钌光催化活性-11和12
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-07-30 DOI: 10.5757/asct.2021.30.4.115
Hyun Sung Kim
In this study, Ru(bpy) 3 @ZIF-11 and Ru(bpy) 3 @ZIF-12 catalysts (bpy = 2,2 ′ ‐bipyridine) were synthesized by encapsulating [Ru(bpy) 3 ] 2+ in zeolitic imidazolate frameworks (ZIFs) ZIF-11 and ZIF-12, respectively, and their photocatalytic activities were compared. Samples of different composites were prepared from their powders, and their crystal morphologies and photocatalytic activities were evaluated by X-ray diffraction analysis and UV-visible absorption spectrometry. [Ru(bpy) 3 ] 2+ @ZIF-12 catalysts possessed excellent photocatalytic stability and exhibited a synergistic effect of [Ru(bpy) 3 ] 2+ and Co in the Ru(bpy) 3 @ZIF-12 composite, and efficient electron transfer from the [Ru(bpy) 3 ] 2+ moiety to the ZIF- 11 framework.
在分子筛咪唑盐框架(ZIFs) ZIF-11和ZIF-12中分别包封[Ru(bpy) 3] 2+,制备了Ru(bpy) 3 @ZIF-11和Ru(bpy) 3 @ZIF-12催化剂(bpy = 2,2′‐联吡啶),并比较了它们的光催化活性。通过x -射线衍射分析和紫外-可见吸收光谱法对其晶体形态和光催化活性进行了表征。[Ru(bpy) 3] 2+ @ZIF-12催化剂具有优异的光催化稳定性,在Ru(bpy) 3 @ZIF-12复合材料中表现出[Ru(bpy) 3] 2+和Co的协同作用,并且电子从[Ru(bpy) 3] 2+部分高效地转移到ZIF- 11框架中。
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引用次数: 1
A Study on Beam Extraction Characteristics of RF and DC Filament Ion Source for High Current Ion Implanters 用于大电流离子注入的射频和直流灯丝离子源光束提取特性研究
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-05-31 DOI: 10.5757/ASCT.2021.30.3.92
Ju-Hong Cha, Sang‐Woo Kim, Ho‐Jun Lee
In high current implantation, improving the ion extractability is a decisive factor contributing to the equipment efficiency and process cost reduction. A direct current filament ion source and inductively coupled plasma ion source were prepared to observe the degree of plasma extraction according to the ion source characteristics. The plasma parameters used to optimize beam extraction for the filament and RF discharges were 600 W, Ar 2 × 10 −5 Torr, and Ø200 × 250 mm discharge space. In the thermionic ion source, the ion density, electron temperature, and Bohm current density were 5 × 10 9 1/cm 3 , ≥ 6 eV, and ≈ 3.5 A/m 2 , respectively. In the RF ion source, the ion density, electron temperature, and Bohm current density were approximately 5 × 10 10 1/cm 3 , ≈ 3 ∼ 4 eV, and ≈ 25 A/m 2 , respectively. Optimization and analysis of ion extraction according to the plasma and accelerator parameters were calculated using IBSimu. The beam emittance, which is the most important parameter of the ion beam quality, was measured as the beam envelope onto the phase space by an ellipse. A change in the plasma meniscus shape was observed according to the plasma parameters in the ion source, and the emittance of the extracted ion beam was calculated according to the electrode gap distance and aperture structure.
在大电流注入中,提高离子可萃取性是提高设备效率和降低工艺成本的决定性因素。根据离子源的特性,制备了直流灯丝离子源和电感耦合等离子体离子源,观察等离子体的萃取程度。用于优化长丝和射频放电光束提取的等离子体参数为600 W, Ar 2 × 10−5 Torr, Ø200 × 250 mm放电空间。在热离子源中,离子密度为5 × 10 9 1/cm 3,电子温度为≥6 eV,玻姆电流密度为≈3.5 A/m 2。在RF离子源中,离子密度、电子温度和玻姆电流密度分别约为5 × 10 10 1/cm 3、≈3 ~ 4 eV和≈25 A/ m2。利用IBSimu软件对等离子体和加速器参数对离子提取过程进行了优化分析。作为离子束质量最重要的参数,光束发射度以椭圆包络线到相空间的形式测量。根据离子源中的等离子体参数观察等离子体半月板形状的变化,并根据电极间隙距离和孔径结构计算提取离子束的发射度。
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引用次数: 1
Growth and Optical Absorption of CoIn2S4 Thin Films by Spray Pyrolysis Method 喷雾热解法制备co2s4薄膜及其光吸收
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-05-31 DOI: 10.5757/ASCT.2021.30.3.74
Changdae Kim
CoIn 2 S 4 thin films were grown onto glass substrates by a spray pyrolysis method. For the growth, the substrate temperature was varied between 250 and 320 ∘ C, and the spray rate was fixed at 6 ml/min. The grown thin films were characterized X-ray diffraction (XRD), field-emission scanning electron microscope (FE-SEM), and optical spectroscopy. The XRD analysis showed that the thin films grown at 320 ∘ C were well crystallized in cubic spinel structure. The FE-SEM results demonstrated that the thin films have a uniform and homogeneous surface. The direct band gap energy was first obtained from the measurement of optical absorption spectra near the fundamental absorption edge at 292 K, and was founded to be 1.59 eV. We also observed two group absorption bands in the near-infrared region, which originate in cobalt ions of the constituent elements of CoIn 2 S 4 . The absorption bands were well assigned as due to the crystal-field transitions of Co 2 + ions occupying tetrahedral sites of the cubic spinel CoIn 2 S 4 host lattice.
采用喷雾热解法在玻璃基板上生长了co2s4薄膜。生长时,衬底温度在250 ~ 320°C之间变化,喷雾量固定为6 ml/min。采用x射线衍射(XRD)、场发射扫描电镜(FE-SEM)和光谱学对生长的薄膜进行了表征。XRD分析表明,在320°C下生长的薄膜结晶良好,呈立方尖晶石结构。FE-SEM结果表明,薄膜表面均匀均匀。直接带隙能量首先通过测量292 K时基吸收边附近的光吸收光谱得到,并确定为1.59 eV。我们还在近红外区观察到两个基团吸收带,它们起源于co2s4组成元素的钴离子。由于Co 2 +离子的晶体场跃迁占据了立方尖晶石co2s4主晶格的四面体位,吸收带被很好地分配。
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引用次数: 0
Numerical Simulation of Thermal Flow Characteristics in Plasma Reactor for Rotten Citrus Fruits Drying 柑桔腐烂果实干燥等离子体反应器热流特性数值模拟
IF 0.8 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-05-31 DOI: 10.5757/ASCT.2021.30.3.70
Hye-Young Ko, Dong H. Shin, Jeong-Hwan Oh, Hyeokjun Kang, Daeun Choi, S. Choi
Rotten citrus fruits, which spread odor gas during shipping season, pose a severe problem in Jeju Island, Republic of Korea. The existing methods for food waste management such as composting using electro-drying and microorganisms have a high electricity cost and require a precise temperature control, respectively. Herein, we conducted a basic numerical study on a plasma reactor using microwave plasma and liquefied petroleum gas as a combined heat source for drying and composting rotten citrus fruits. To determine the design and operating conditions of the plasma reactor, the thermal flow characteristics inside the reactor were analyzed using a computational fluid dynamics code in ANSYS-fluent. In particular, the temperature distribution in the plasma reactor was simulated at different air flow rates of the centrifugal fan. The numerical simulation accuracy was evaluated by comparing the numerical results and actual experimental data. The temperature of the reactor decreased with the increase in the air flow rate of the centrifugal fan. Above 10 m/s, the temperature of the drying chamber and the exhaust gas remained almost constant at 507 K. In the present work, the calculated temperature shows a difference 1.13 % from the measured temperature at the combustion chamber. were caused by the latent heat of water vaporization. The numerical simulation, however, show the correct prediction in the combustion chamber where the heat is suppled and provides reasonable trend of the temperature distribution according to the fresh air supply in the centrifugal fan. Using the simulation results of this study, the oper- ating condition of the plasma reactor as a treatment facility for rotten citrus fruits in Jeju Island are derived and it can be used as basic data for research on food waste disposal facilities.
在韩国济州岛,在航运季节,腐烂的柑橘会散发出难闻的气体,这是一个严重的问题。现有的食物垃圾处理方法,如电干燥堆肥和微生物堆肥,分别需要很高的电力成本和精确的温度控制。本文对以微波等离子体和液化石油气为复合热源的等离子体反应器进行了柑桔腐果干燥和堆肥的基础数值研究。为了确定等离子体反应器的设计和运行条件,利用ANSYS-fluent计算流体动力学软件对反应器内部的热流特性进行了分析。特别模拟了离心风机不同风量下等离子体反应器内的温度分布。通过数值结果与实际实验数据的比较,对数值模拟的精度进行了评价。反应器温度随离心风机风量的增大而降低。在10m /s以上,干燥室温度和废气温度基本保持在507 K不变。在本工作中,计算温度与燃烧室实测温度相差1.13%。都是由水的蒸发潜热引起的。数值模拟结果表明,在供热燃烧室内的预测是正确的,并根据离心风机的新风送风情况,给出了合理的温度分布趋势。利用本研究的模拟结果,推导出济州岛柑桔腐烂处理设施等离子体反应器的运行工况,可作为研究餐厨垃圾处理设施的基础数据。
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引用次数: 0
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Applied Science and Convergence Technology
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