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Synthesis of Cu2-x Ni0.05 S (x=0.05,0.25,0.30) Compounds and Study of Single Crystals Cu2-x Ni0.05 S (x=0.05,0.25,0.30)化合物的合成及单晶研究
Pub Date : 2023-08-01 DOI: 10.9734/ajopacs/2023/v11i3205
Kh. Kh. Hashimov
In the article, considering the research studies of many scientists and also on the basis of practical applications, the distribution diagram of copper and sulfur atoms in the phase lattice of the  crystal, the structure transformation diagram, the elemental lattice hexagonal  and  crystallographic data were examined and important results were obtained. Analysis of the studies performed shows that some conflicting results in roentgenographic studies on these compounds are related to obtaining these samples by different methods. Our goal is to obtain single crystals of the compounds Cu2-xNi0.05S (x=0.05,0.25,0.30) and draw the lauegrams and debayograms of those crystals. Then the results were analyzed. During the research, it was found that it is possible to buy single crystals of  compounds based on the analysis of existing methods and selection of the optimal method. As a result of the research, the suitable lauegrams of the single crystals obtained by the Bridgman method and the microstructures of the samples were determined and the possibilities of application were determined.
本文结合许多科学家的研究成果,并结合实际应用,对晶体中铜、硫原子在相点阵中的分布图、结构转变图、元素点阵六角形和晶体学数据进行了检验,得到了重要的结果。对所进行的研究的分析表明,在这些化合物的x线摄影研究中,一些相互矛盾的结果与使用不同的方法获得这些样品有关。我们的目标是得到化合物Cu2-xNi0.05S (x=0.05,0.25,0.30)的单晶,并画出这些晶体的失重图和debal图。然后对结果进行分析。在研究过程中,通过对现有方法的分析和最佳方法的选择,发现购买化合物单晶是可能的。研究结果确定了用Bridgman法获得的单晶的合适分子量和样品的微观结构,并确定了应用的可能性。
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引用次数: 0
Effect of Additives on Decomposition of Methyl Orange and Congo Red Dyes Found in Industrial Wastewater 添加剂对工业废水中甲基橙和刚果红染料分解的影响
Pub Date : 2023-08-01 DOI: 10.9734/ajopacs/2023/v11i3206
J. Hossain, S. Monira, M. Shahinuzzaman, Md. Samiul Bari Avick, Md. Shaharul Islam, Mst. Marjia Khatun, S. Razzaque, M. Uddin
A number of textile industries are using different types of dyes which can be a threat to the environment when they are directly exposed without any treatment. The advanced oxidation process (AOP) has become one of the popular methods in which the dye molecules are degraded using microwave irradiation. This method has become popular due to its eco-friendly and cost-efficient characteristics. In this article, the author has reported the degradation of two azo dyes, named methyl orange (MO) and congo red (CR), in the presence of inorganic salts, some additives like charcoal, H2O2, CCl4, tert-butyl alcohol (TBA), glucose and sucrose. A comparative study was conducted to find out the relative degradation rate enhanced by various additives. For both of the dyes, it was found that charcoal was the most effective additive and significantly enhanced the degradation rate mainly due to its high adsorption capability. TBA was found to be the least enhancer. The order of effectiveness based on the irradiation period for MO was 0.01g charcoal > 20 ml NaCl > 20 ml Na2SO4 > 20ml glucose> 10 ml sucrose > 100 μL CCl4 > 200 μL H2O2 > pure MO > TBA. On the other hand, the order of effectiveness for CR for the same condition of irradiation was Combined additives>0.01g charcoal > TBA > 100 μL CCl4> pure CR.
许多纺织工业正在使用不同类型的染料,当它们未经任何处理直接暴露在环境中时,它们可能对环境构成威胁。高级氧化法(AOP)是利用微波辐照降解染料分子的常用方法之一。这种方法因其环保和经济的特点而受到欢迎。本文报道了两种偶氮染料甲基橙(MO)和刚果红(CR)在无机盐、木炭、H2O2、CCl4、叔丁醇(TBA)、葡萄糖和蔗糖等添加剂存在下的降解。对比研究了不同添加剂对相对降解率的提高。对于这两种染料,我们发现木炭是最有效的添加剂,并显著提高了降解率,这主要是由于它的高吸附能力。发现TBA是最小的增强剂。不同辐照时间对MO的影响顺序为:0.01g木炭> 20ml NaCl > 20ml Na2SO4 > 20ml葡萄糖> 10 ml蔗糖> 100 μL CCl4 > 200 μL H2O2 >纯MO > TBA。在相同辐照条件下,复合添加剂对CR的影响顺序为>0.01g木炭> TBA > 100 μL CCl4>纯CR。
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引用次数: 0
Formulation and Thermomechanical Characterization of Earth-based Biosourced Composites: Cases of Clay-Hibiscus cannabinus L. Fiber, Clay-sawdust and Clay- Oryza sativa Husk 土基生物源复合材料的配方及热力学特性:以粘土-大麻芙蓉纤维、粘土-锯末和粘土-水稻壳为例
Pub Date : 2023-07-14 DOI: 10.9734/ajopacs/2023/v11i3204
Sandwidi Sayouba, Haro Kayaba, Dabilgou Téré, Sinon Souleymane, S. Oumar, Koulidiati Jean, Béré Antoine
This work concerns the technical study of implementation, thermal and mechanical characterization of a composite material based on clay and plant fibers, in order to meet the need for bioclimatic and sustainable houses. The objective was to find the proportions of clay and fibers to obtain a mixture that would give better thermal properties. A characterization of the thermal properties was made thanks to the KD2 Pro analyzer on samples of various formulas of mixture clay-plant fibers. The results obtained showed that the thermal properties such as thermal conductivity and thermal diffusivity of the clay-fiber mixture samples decrease with the increase of the fiber content in the mixture. Thus, the thermal conductivity of the samples varies from 0.85 to 0.65 W/m.K; from 0.88 to 0.72 W/m.K and from 0.83 to 0.75 W/m.K respectively with Hibiscus cannabinus L. fiber, sawdust and Oryza sativa husk. As for the thermal diffusivity, it varies from 0.37 to 0.25 mm2/s; from 0.45 to 0.30 mm2/s and from 0.47 to 0.27 mm2/s respectively with the addition of Hibiscus cannabinus L. fibers, sawdust and Oryza sativa husk. In sum, the earth samples stabilized with Hibiscus cannabinus L. fibers offer better thermal properties for the construction of bioclimatic houses.
这项工作涉及基于粘土和植物纤维的复合材料的实施、热学和力学特性的技术研究,以满足生物气候和可持续房屋的需求。目的是找到粘土和纤维的比例,以获得一种具有更好热性能的混合物。利用KD2 Pro分析仪对不同配方的粘土-植物混合纤维样品进行了热性能表征。结果表明,随着纤维含量的增加,粘土-纤维混合试样的导热系数和热扩散系数等热性能有所降低。因此,样品的导热系数在0.85 ~ 0.65 W/m.K之间变化;从0.88到0.72瓦/米。从0.83到0.75 W/m。K分别用木槿纤维、锯末和稻壳。热扩散系数为0.37 ~ 0.25 mm2/s;木槿花纤维、木屑和稻谷皮的添加量分别为0.45 ~ 0.30 mm2/s和0.47 ~ 0.27 mm2/s。综上所述,木槿纤维稳定的土样为生物气候房屋的建设提供了更好的热性能。
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引用次数: 0
Measurement of Outdoor and Indoor Background Ionizing Radiation of O.B. Lulu Briggs Health Center, University of Port Harcourt, Choba, Rivers State, Nigeria O.B. Lulu Briggs健康中心室外和室内本底电离辐射测量,哈科特港大学,乔巴,河流州,尼日利亚
Pub Date : 2023-06-27 DOI: 10.9734/ajopacs/2023/v11i3203
B. O., Lulu Briggs, A. Bubu, C. Ononugbo
Measurement of outdoor and indoor background ionizing radiation (BIR) of O.B. Lulu Briggs Health Centre in the University of Port Harcourt, Rivers State, Nigeria was carried out using a well-calibrated Radalert-100 (Radiation meter) and Digilert-200 meters and Global Positioning System (Garmin 765). 30 selected locations were considered. The outdoor and indoor results are as follows respectively, average exposure rates are 0.012±0.001 and 0.013±0.001 mR/h, mean absorbed dose rate (ADR) are 105.6 and 96.28 nGy/h, estimated value of the annual effective dose equivalent (AEDE) are 0.17 and 0.27 mSv/y and mean excess lifetime cancer risk (ELCR) are (0.60 and 0.92) x 10-3. The obtained values for BIR in O.B. Lulu Briggs Health Centre are not above the recommended standard limit of 0.013mR/h by International Commission on Radiological protection (ICRP). AEDE that was calculated in the entire O.B. Lulu Briggs Health Centre is within safe values, the ELCR and the ADR estimated were higher than the world permissible values of 0.29 x 10-3 and 84.0 nGy/h respectively. The calculated dose to organs for O.B. Lulu Briggs showed that the testes have the highest organ dose of (0.140667 and 0.218053) mSv/y for outdoor and indoor respectively.
利用校准良好的Radalert-100(辐射计)和Digilert-200米以及全球定位系统(Garmin 765),对尼日利亚河流州哈科特港大学O.B. Lulu Briggs健康中心的室外和室内本底电离辐射(BIR)进行了测量。审议了30个选定地点。室外和室内结果分别为:平均暴露率分别为0.012±0.001和0.013±0.001 mR/h,平均吸收剂量率(ADR)分别为105.6和96.28 nGy/h,年有效剂量当量(AEDE)估计值分别为0.17和0.27 mSv/y,平均过量终身癌症风险(ELCR)分别为(0.60和0.92)× 10-3。在O.B. Lulu Briggs健康中心获得的BIR值不超过国际放射防护委员会(ICRP)建议的0.013mR/h标准限值。在整个O.B. Lulu Briggs健康中心计算的AEDE在安全范围内,估计的ELCR和ADR分别高于世界允许值0.29 x 10-3和84.0 nGy/h。露露布里格斯对器官的剂量计算表明,室外和室内的睾丸器官剂量最高,分别为(0.140667和0.218053)mSv/y。
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引用次数: 0
Experimental Investigation for Augmentation of Thermal Performance of Solar Air Collector 提高太阳能空气集热器热性能的实验研究
Pub Date : 2023-06-23 DOI: 10.9734/ajopacs/2023/v11i3201
Souleymane Sinon, Salifou Tera, O. Sanogo, Sayouba Sandwidi, B. Korgo, S. Kam
This paper presents a study of the thermal performance of a solar air collector used to heat the drying air of a fruit and vegetable dryer. The prototype collector could be a viable solution to improve energy efficiency and food security in Burkina Faso and other developing countries, by contributing to the reduction of post-harvest losses and the increase of income for local agricultural producers. The collector is first realized by using black painted cans as air ducts, perforated to increase turbulence, and a glass covering the collection surface. After realization, the collector is connected to the dryer and a measurement campaign is conducted to evaluate the thermal performance of it. The measured parameters are the sunshine and the air temperature by keeping the air speed fixed at 0.3 m/s. The analysis of the results shows an important variation of the air temperature difference going from 0.1°C to 74.4°C, between the inlet and the outlet of the collector for an irradiation which varies between 142 W/m2 and 837 W/m2. The black painted surface of the air ducts as well as the increase in turbulence contributed to improve the efficiency of the collector which varies between 0.94% and 50.68% and allowing to record air temperatures ranging from 27.2°C to 69.2°C inside the dryer. This temperature range is favorable for the drying of most food products.
本文研究了用于加热果蔬干燥机干燥空气的太阳能集热器的热性能。通过减少收获后的损失和增加当地农业生产者的收入,这种原型收集器可能成为提高布基纳法索和其他发展中国家能源效率和粮食安全的可行解决方案。收集器首先通过使用黑色喷漆罐作为空气管道来实现,穿孔以增加湍流,并在收集表面覆盖玻璃。实现后,收集器连接到干燥器,并进行测量活动,以评估其热性能。在风速为0.3 m/s的条件下,测量的参数为日照和空气温度。分析结果表明,在142w /m2 ~ 837w /m2的辐照条件下,集热器进出口空气温差在0.1℃~ 74.4℃之间变化较大。风管的黑色涂漆表面以及湍流的增加有助于提高收集器的效率,在0.94%到50.68%之间变化,并允许记录空气温度范围从27.2°C到69.2°C在干燥器内。这个温度范围对大多数食品的干燥是有利的。
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引用次数: 0
Influence of the Mirror Reflectance Coefficient on the Performance of the Compound Parabolic Trough Concentrator (CPC): Numerical and Experimental Simulation in a Sahelian Environment 镜面反射系数对复合抛物槽聚光器(CPC)性能的影响:萨赫勒环境下的数值与实验模拟
Pub Date : 2023-06-23 DOI: 10.9734/ajopacs/2023/v11i3202
S. Ouédraogo, Augustin S. Zongo, J. Nzihou, T. Daho, A. Béré
The objective of our study is to numerically and experimentally simulate the CPC operation according to three different values of the mirror reflectance coefficient. The study not only showed the importance of mirror reflectance in the performance of solar collectors but also estimated which of these three values fits well with the reality in the city of Ouagadougou. The thermal exchanges that took place in the CPC were presented. A matlab program was developed for the calculation and simulation of the different parameters of the solar concentrator. The differential equations governing the heat transfers in the different components of the device were discretized by the advanced finite difference method. They were solved by the Gauss-Seidel method. As for the experimental part, it consisted in the direct measurement of the global solar radiation, of the ambient temperature and of the fluid temperature by means of thermocouples placed on the different parts of the sensor. The experimental values are directly recorded with a datalogger. A statistical study was made using some indicators like coefficient of determination of  R2 , root mean square error (RMSE) and percentage of mean absolute error (MAPE). A validation of the obtained results by comparing the calculated values with the experimental values was presented. The results show that among the three values of the reflectance coefficient, the best results on the temperature of the fluid are obtained with the reflectance coefficient equal to 0.68 on the site of Ouagadougou.
我们的研究目的是根据三种不同的镜面反射系数数值和实验模拟CPC操作。该研究不仅表明了镜面反射率对太阳能集热器性能的重要性,而且还估计了这三个值中哪一个更符合瓦加杜古市的实际情况。介绍了在CPC中发生的热交换。编写了matlab程序,对太阳能聚光器的不同参数进行了计算和仿真。采用先进的有限差分法对控制装置各部件传热的微分方程进行离散化。用高斯-赛德尔法求解。至于实验部分,它包括通过放置在传感器不同部分的热电偶直接测量太阳总辐射、环境温度和流体温度。用数据记录仪直接记录实验值。采用R2决定系数、均方根误差(RMSE)、平均绝对误差百分比(MAPE)等指标进行统计学研究。通过将计算值与实验值进行比较,验证了所得结果。结果表明:在3个反射系数值中,瓦加杜古地区的反射系数为0.68时对流体温度的影响效果最好;
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引用次数: 0
Analytical Comparison of Path Loss Models for Radio Wave Propagation over Yenagoa–Southern Nigeria 奈及利亚南部地区无线电波传播路径损耗模式的分析比较
Pub Date : 2023-05-31 DOI: 10.9734/ajopacs/2023/v11i2200
C. Emeruwa, E. J. Oduobuk
Using propagation models helps with communication system planning and maximizes the use of the radio spectrum, a limited natural resource. Here is a comparative analysis between some propagation models and actual measurements from Yenagoa, Southern Nigeria. Electric field strength measurements made during drive tests for two television transmitters operating at 210.25 MHz and 577.10 MHz make up the experimental data. Analytical comparisons were made between verified predictions for the free space, Okumura, and Hata models and measured data. The results demonstrate that these empirical models fail to take into account Yenagoa's actual terrain profile for television broadcast. The Okumura model is the best fit, with ideal values for root mean square error (RMSE) of 34.9136 and 33.2841 and average relative error of 0.13212 and 0.4327 for 210.25 MHz and 577.10 MHz, respectively. However, if the Okumura model is tailored for Yenagoa to improve electric field strength prediction and coverage estimation, better results can be attained.
使用传播模型有助于通信系统规划,并最大限度地利用无线电频谱这一有限的自然资源。这是尼日利亚南部叶纳戈阿的一些传播模型和实际测量结果之间的比较分析。在210.25兆赫和577.10兆赫的两个电视发射机的驱动测试中进行的电场强度测量构成了实验数据。对自由空间、Okumura和Hata模型的验证预测与实测数据进行了分析比较。结果表明,这些经验模型未能考虑电视广播的叶纳戈阿实际地形剖面。在210.25 MHz和577.10 MHz时,Okumura模型的均方根误差(RMSE)理想值分别为34.9136和33.2841,平均相对误差分别为0.13212和0.4327。但是,如果针对Yenagoa量身定制Okumura模型,以改进电场强度预测和覆盖估计,则可以获得更好的结果。
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引用次数: 1
Evaluation of Radionuclide Concentration in Suspended Particulate Matter from Two Quarry Sites in Nigeria 尼日利亚两个采石场悬浮颗粒物中放射性核素浓度的评价
Pub Date : 2023-05-27 DOI: 10.9734/ajopacs/2023/v11i2199
M. Onwuka, G. Avwiri, C. Ononugbo
Evaluation of Radionuclide contents of suspended particulate matter from two quarry sites in Nigeria, have been carried out using High Volume air sampler and Gamma ray spectrometer NaI (Tl) Detector. The results obtained showed the mean value for 226 Ra, 232Th and 40k for Ishiagu sampleswere 2.76, 1.57 and 5.29 Bq/Kg respectively while that obtained in Okpella sampleswere 1.84, 2.21 and 6.2 Bq/kg respectively. The values obtained were higher than their control values but lower than the world recommended safe values. The results obtained in Okpella are slightly higher than that obtained in Ishiagu sites. This could be due to different geological constituents and other mining activities going on at Okpella that might have contributed to the slight change. All the radiological health risk parameter estimated were within their safe values as recommended by UNSCEAR. Comparison of results with other similar works shows positive correlation. We therefore conclude that inhalable suspended particulate matter within quarry sites does not constitute immediate radiological health hazard though precaution should be taken to avoid long term accumulation that can lead to stochastic health risk.
利用高容量空气采样器和伽马射线光谱仪对尼日利亚两个采石场悬浮颗粒物的放射性核素含量进行了评价。结果表明,石谷样品中226 Ra、232Th和40k的平均值分别为2.76、1.57和5.29 Bq/Kg,奥佩拉样品中226 Ra、232Th和40k的平均值分别为1.84、2.21和6.2 Bq/Kg。所得值高于对照值,但低于世界推荐的安全值。在Okpella得到的结果略高于在Ishiagu得到的结果。这可能是由于不同的地质成分和在Okpella进行的其他采矿活动可能导致了轻微的变化。估计的所有放射健康风险参数均在辐射科委会建议的安全值范围内。结果与其他同类研究结果的比较显示出正相关关系。因此,我们得出结论,采石场内可吸入的悬浮颗粒物不会立即构成放射性健康危害,但应采取预防措施,避免长期积累,从而导致随机健康风险。
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引用次数: 0
Energy Losses by the Interaction of Charged Particles with a Graphene Sheet 带电粒子与石墨烯片相互作用的能量损失
Pub Date : 2023-04-19 DOI: 10.9734/ajopacs/2023/v11i2198
Lijun Wang, Dong Sun, X. Hua, Daqing Liu
Using the fluid dynamics model, we studied the formation of graphene surface plasma when the charge is tilted to the graphene sheet for motion. We calculated the electron energy loss spectrum of electrons at different angles and proved that the resonance in the spectrum is related to the frequency of graphene surface plasma, as the electron velocity decreases, the dispersion shifts to higher energies. An increase in the tilt angle will also shift the dispersion energy in a higher range.
利用流体动力学模型,研究了电荷向石墨烯薄片倾斜运动时石墨烯表面等离子体的形成。我们计算了电子在不同角度下的电子能量损失谱,证明谱中的共振与石墨烯表面等离子体的频率有关,随着电子速度的降低,色散向更高的能量转移。倾斜角度的增加也会使色散能量在更高的范围内移动。
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引用次数: 0
Design and Development of an MRI Compatible Circuit Suitable for Pre-Clinical Physiological Monitoring in a 4.7T Magnetic Resonance Imaging 适用于4.7T磁共振成像临床前生理监测的MRI兼容电路的设计与开发
Pub Date : 2023-04-14 DOI: 10.9734/ajopacs/2023/v11i2196
B. Eze, N. A. Akonjom, A. Bassey
As monitoring preclinical MRI is essential, it is important that the equipment used must be MRI-compatible. This is because interaction with an MRI radiofrequency (RF) transmitting field can cause RF burns due to inappropriate equipment. And non-compatible MRI monitoring equipment can give inaccurate readings in the MRI system if the equipment has ferromagnetic components. Preclinical MRI is designed for animals, the model used to study diseases related to humans. Animal models are imaged using a smaller scanner with high magnetic fields like the 4.7T. The main parameters of interest are the respiratory rate, the temperature, the pressure transducer and the electrocardiogram (ECG), this is because the animal model is used as a laboratory experiment for human disease. An MRI-compatible lead Ⅱ ECG simulator, with approximately 0.5 mV output amplitude was attached to the input of the ECG preamplifier to represent a small animal’s signal. The transmitted signal is the ECG, the pressure sensor, the temperature, and the battery (voltage), these are all linked to different channels (outside, near and inside magnet) and were acquired with the pressure sensor pad taped on a male adult volunteer’s thumb to record the human pulse of 70 bpm, which is similar to the respiration rate of an anaesthetized mouse or rat. The use of a signal gating generator should be explored in future work, this could make the monitoring parameters to be independent of the RF pulse influence. Finally, fibre optics should be included in the design process.
由于监测临床前MRI是必不可少的,因此使用的设备必须与MRI兼容是很重要的。这是因为与MRI射频(RF)发射场的相互作用可能由于设备不合适而导致射频烧伤。不兼容的MRI监测设备如果有铁磁元件,则会在MRI系统中给出不准确的读数。临床前MRI是为动物设计的,该模型用于研究与人类相关的疾病。动物模型使用像4.7T这样的高磁场的小型扫描仪成像。主要感兴趣的参数是呼吸频率、温度、压力传感器和心电图(ECG),这是因为动物模型被用作人类疾病的实验室实验。在ECG前置放大器的输入端连接一个与mri兼容的导联ⅡECG模拟器,输出幅度约为0.5 mV,以表示小动物的信号。传输的信号是心电图、压力传感器、温度和电池(电压),这些都连接到不同的通道(外部、附近和内部的磁铁),并通过贴在男性成年志愿者拇指上的压力传感器板获得,以记录每分钟70次的人类脉搏,这与麻醉小鼠或大鼠的呼吸速率相似。在今后的工作中应探索使用信号门控发生器,使监测参数不受射频脉冲的影响。最后,光纤应包括在设计过程中。
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引用次数: 0
期刊
Asian Journal of Physical and Chemical Sciences
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