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Erratum: "Inference of the Local Interstellar Spectra of Cosmic-Ray Nuclei Z ⩽ 28 with the GALPROP-HELMOD Framework" (2020, ApJS, 250, 27). 勘误:“用GALPROP-HELMOD框架推断宇宙射线原子核Z < 28的局部星际光谱”(2020,ApJS, 250, 27)。
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2021-10-01 Epub Date: 2021-10-13 DOI: 10.3847/1538-4365/ac2518
M J Boschini, S Della Torre, M Gervasi, D Grandi, G Jóhannesson, G La Vacca, N Masi, I V Moskalenko, S Pensotti, T A Porter, L Quadrani, P G Rancoita, D Rozza, M Tacconi

[This corrects the article PMC8549769.].

[更正文章PMC8549769.]。
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引用次数: 0
SiO, 29SiO, and 30SiO emission from 67 oxygen-rich stars. A survey of 61 maser lines from 7 to 1 mm. 来自 67 颗富氧恒星的 SiO、29SiO 和 30SiO 辐射。对 7 至 1 毫米的 61 条 maser 线进行了调查。
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2021-03-26 eCollection Date: 2021-04-01 DOI: 10.3847/1538-4365/abe469
J R Rizzo, J Cernicharo, C Garoía-Miró

Circumstellar environments of oxygen-rich stars are among the strongest SiO maser emitters. Physical processes such as collisions, infrared pumping and overlaps favors the inversion of level population and produce maser emission at different vibrational states. Despite numerous observational and theoretical efforts, we still do not have an unified picture including all the physical processes involved in the SiO maser emission. The aim of this work is to provide homogeneous data in a large sample of oxygen-rich stars. We present a survey of 67 oxygen-rich stars from 7 to 1 mm, in their rotational transitions from J = 1 → 0 to J = 5 → 4, for vibrational numbers v from 0 to 6 in the three main SiO isotopologues. We have used one of the 34 m NASA antennas at Robledo and the IRAM 30 m radio telescope. The first tentative detection of a v = 6 line is reported, as well as the detection of new maser lines. The highest vibrational levels seem confined to small volumes, presumably close to the stars. The J = 1 → 0, v = 2 line flux is greater than the corresponding v = 1 in almost half of the sample, which may confirm a predicted dependence on the pulsation cycle. This database is potentially useful in models which should consider most of the physical agents, time dependency, and mass-loss rates. As by-product, we report detections of 27 thermal rotational lines from other molecules, including isotopologues of SiS, H2S, SO, SO2, and NaCl.

富氧恒星的环恒星环境是最强的氧化硅质谱发射器之一。碰撞、红外抽运和重叠等物理过程有利于水平群的反转,并在不同的振动状态下产生maser发射。尽管在观测和理论方面做了大量工作,但我们仍然没有一个包括所有参与氧化硅激光发射的物理过程在内的统一图景。这项工作的目的是提供富氧恒星大样本中的同质数据。我们对从 7 到 1 毫米的 67 颗富氧恒星进行了调查,在它们从 J = 1 → 0 到 J = 5 → 4 的旋转转变过程中,对三种主要氧化硅同素异形体的振动数 v 从 0 到 6 进行了研究。我们使用了美国国家航空航天局在罗布莱多的一个 34 米天线和 IRAM 30 米射电望远镜。报告首次初步探测到了 v = 6 线,并探测到了新的 maser 线。最高振动水平似乎局限在小范围内,可能靠近恒星。在几乎一半的样本中,J = 1 → 0, v = 2 线通量大于相应的 v = 1 线通量,这可能证实了所预测的对脉动周期的依赖性。这个数据库可能对模型很有用,因为模型应该考虑大多数物理因子、时间依赖性和质量损失率。作为副产品,我们还报告了从其他分子中探测到的 27 条热旋转线,包括 SiS、H2S、SO、SO2 和 NaCl 的同位素。
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引用次数: 0
Inference of the Local Interstellar Spectra of Cosmic-Ray Nuclei Z ⩽ 28 with the GalProp-HelMod Framework. 用GalProp-HelMod框架推断宇宙射线原子核Z≤28的局域星际光谱。
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2020-10-01 Epub Date: 2020-09-29 DOI: 10.3847/1538-4365/aba901
M J Boschini, S Della Torre, M Gervasi, D Grandi, G Jóhannesson, G La Vacca, N Masi, I V Moskalenko, S Pensotti, T A Porter, L Quadrani, P G Rancoita, D Rozza, M Tacconi

Composition and spectra of Galactic cosmic rays (CRs) are vital for studies of high-energy processes in a variety of environments and on different scales, for interpretation of γ-ray and microwave observations, for disentangling possible signatures of new phenomena, and for understanding of our local Galactic neighborhood. Since its launch, AMS-02 has delivered outstanding-quality measurements of the spectra of p ¯ , e ±, and nuclei: 1H-8O, 10Ne, 12Mg, 14Si. These measurements resulted in a number of breakthroughs; however, spectra of heavier nuclei and especially low-abundance nuclei are not expected until later in the mission. Meanwhile, a comparison of published AMS-02 results with earlier data from HEAO-3-C2 indicates that HEAO-3-C2 data may be affected by undocumented systematic errors. Utilizing such data to compensate for the lack of AMS-02 measurements could result in significant errors. In this paper we show that a fraction of HEAO-3-C2 data match available AMS-02 measurements quite well and can be used together with Voyager 1 and ACE-CRIS data to make predictions for the local interstellar spectra (LIS) of nuclei that are not yet released by AMS-02. We are also updating our already-published LIS to provide a complete set from 1H-28Ni in the energy range from 1 MeV nucleon-1 to ~100-500 TeV nucleon-1, thus covering 8-9 orders of magnitude in energy. Our calculations employ the GalProp-HelMod framework, which has proved to be a reliable tool in deriving the LIS of CR p ¯ , e -, and nuclei 1H-8O.

银河宇宙射线(CR)的组成和光谱对于研究各种环境和不同尺度上的高能过程、解释γ射线和微波观测、解开新现象的可能特征以及了解我们当地的银河邻域至关重要。自发射以来,AMS-02已经对p、e±和原子核的光谱进行了卓越的质量测量:1H-8O、10Ne、12Mg、14Si。这些测量取得了一些突破;然而,重原子核,特别是低丰度原子核的光谱预计要到任务后期才能出现。同时,已公布的AMS-02结果与HEAO-3-C2早期数据的比较表明,HEAO-3-C2-数据可能受到未记录的系统错误的影响。利用这些数据来弥补AMS-02测量的不足可能会导致重大误差。在本文中,我们表明HEAO-3-C2数据的一部分与AMS-02的可用测量结果非常匹配,可以与Voyager 1和ACE-CRIS数据一起使用,以预测AMS-02尚未发布的核的局部星际光谱(LIS)。我们也在更新我们已经发表的LIS,以提供一套完整的1H-28Ni,能量范围从1MeV核-1到~100-500TeV核-1,从而覆盖8-9个数量级的能量。我们的计算采用了GalProp-HelMod框架,该框架已被证明是推导CR p’、e-和核1H-8O的LIS的可靠工具。
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引用次数: 49
Octahedron-based Projections as Intermediate Representations for Computer Imaging: TOAST, TEA, and More. 基于八面体的投影作为计算机成像的中间表示:TOAST, TEA等。
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2019-01-29 DOI: 10.3847/1538-4365/aaf79e
Thomas McGlynn, Jonathan Fay, Curtis Wong, Philip Rosenfield

This paper defines and discusses a set of rectangular all-sky projections that have no singular points, notably the Tesselated Octahedral Adaptive Spherical Transformation (or TOAST) developed initially for the WorldWide Telescope. These have proven to be useful as intermediate representations for imaging data where the application transforms dynamically from a standardized internal format to a specific format (projection, scaling, orientation, etc.) requested by the user. TOAST is strongly related to the Hierarchical Triangular Mesh pixelization and is particularly well adapted to situations where one wishes to traverse a hierarchy of images increasing in resolution. Because it can be recursively computed using a very simple algorithm it is particularly adaptable to use with graphical processing units.

本文定义并讨论了一组没有奇异点的矩形全天投影,特别是最初为万维望远镜开发的镶嵌八面体自适应球面变换(Tesselated Octahedral Adaptive Spherical Transformation, TOAST)。这些已被证明是有用的成像数据的中间表示,其中应用程序从标准化的内部格式动态转换为用户要求的特定格式(投影、缩放、方向等)。TOAST与分层三角网格像素化密切相关,特别适合于希望遍历分辨率增加的图像层次的情况。因为它可以用一种非常简单的算法递归地计算,所以特别适合与图形处理单元一起使用。
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引用次数: 2
Climates of Warm Earth-like Planets I: 3-D Model Simulations. 暖地类行星的气候I:三维模型模拟。
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2018-12-01 Epub Date: 2018-12-05 DOI: 10.3847/1538-4365/aae9e1
M J Way, Anthony D Del Genio, Igor Aleinov, Thomas L Clune, Maxwell Kelley, Nancy Y Kiang

We present a large ensemble of simulations of an Earth-like world with increasing insolation and rotation rate. Unlike previous work utilizing idealized aquaplanet configurations we focus our simulations on modern Earth-like topography. The orbital period is the same as modern Earth, but with zero obliquity and eccentricity. The atmosphere is 1 bar N2-dominated with CO2=400 ppmv and CH4=1 ppmv. The simulations include two types of oceans; one without ocean heat transport (OHT) between grid cells as has been commonly used in the exoplanet literature, while the other is a fully coupled dynamic bathtub type ocean. The dynamical regime transitions that occur as day length increases induce climate feedbacks producing cooler temperatures, first via the reduction of water vapor with increasing rotation period despite decreasing shortwave cooling by clouds, and then via decreasing water vapor and increasing shortwave cloud cooling, except at the highest insolations. Simulations without OHT are more sensitive to insolation changes for fast rotations while slower rotations are relatively insensitive to ocean choice. OHT runs with faster rotations tend to be similar with gyres transporting heat poleward making them warmer than those without OHT. For slower rotations OHT is directed equator-ward and no high latitude gyres are apparent. Uncertainties in cloud parameterization preclude a precise determination of habitability but do not affect robust aspects of exoplanet climate sensitivity. This is the first paper in a series that will investigate aspects of habitability in the simulations presented herein. The datasets from this study are opensource and publicly available.

我们展示了一个类似地球的世界,其日射和自转速度都在增加。与之前使用理想的水行星配置的工作不同,我们将模拟重点放在现代类地地形上。轨道周期与现代地球相同,但倾角和离心率为零。大气为1巴N2,CO2=400 ppmv,CH4=1 ppmv。模拟包括两种类型的海洋;一个没有系外行星文献中常用的网格单元之间的海洋热传输(OHT),而另一个是完全耦合的动态浴缸型海洋。随着日照时间的增加,发生的动力状态转换会引发气候反馈,产生较冷的温度,首先是通过水蒸气的减少和自转周期的增加,尽管云层的短波冷却减少,然后是通过水蒸汽的减少和短波云冷却的增加,除非在最高日照量。没有OHT的模拟对快速旋转的日照变化更敏感,而慢速旋转对海洋选择相对不敏感。旋转速度更快的OHT运行往往与向极地输送热量的环流相似,使其比没有OHT的环流更温暖。对于较慢的自转,OHT指向赤道,没有明显的高纬度环流。云参数化的不确定性阻碍了对宜居性的精确确定,但不会影响系外行星气候敏感性的稳健方面。这是一系列论文中的第一篇,将在本文的模拟中研究可居住性的各个方面。这项研究的数据集是开源的,可以公开获得。
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引用次数: 54
RELATIVISTIC MR-MP ENERGY LEVELS FOR L-SHELL IONS OF SULFUR AND ARGON. 硫和氩的L壳层离子的相对论MR-MP能级。
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2018-10-01 Epub Date: 2018-10-23 DOI: 10.3847/1538-4365/aae14e
Juan A Santana, Nahyr A Lopez-Dauphin, Emmanuel J Morales Butler, Peter Beiersdorfer

Calculated level energies for valence and K-vacancy states are provided for the ion series S VII - S XIV and Ar IX - Ar XVI. The calculations were performed with the relativistic Multi-Reference Mxller-Plesset Perturbation Theory method (MR-MP). The data set includes all the level energies with configurations 1s 22(s, p) q , 1s 22(s, p) q-1 nl, 1s 12(s, p) q+1, 1s 12(s, p) q nl, 2(s, p) q+2 and 2(s, p) q+1 nl, where 1 ≤ q ≤ 8, n ≤ 5 and l ≤ 3. We have compared our results with data from the National Institute of Standards and Technology (NIST) on-line database and with previous calculations. The average deviation of valence level energies ranges from 0.16 eV in Ne-like ions to 0.01 eV in Li-like ions, showing that the present MR-MP valence level energies are highly accurate. In the case of K-vacancy states, the deviation is generally below 0.3 eV for Li-like S XIV and Ar XVI. The deviation for K-vacancy energies in other L-shell ions (Be-, B-, C-, N- and O-like Ar ions) is higher but likely because the NIST-recommended values have a higher uncertainty. The data set includes many n = 4 and n = 5 valence and K-vacancy levels in L-shell ions of S and Ar not previously reported. The data can be used for line identification and modeling of L-shell ions of S and Ar in astrophysical and laboratory-generated plasmas, and as energy references in the absence of more accurate laboratory measurements.

给出了离子系列SⅦ-SXIV和ArⅨ-Ar XVI的价态和K空位态的能级能量计算结果。用相对论多参考Mxller-Plesset微扰理论方法(MR-MP)进行了计算。数据集包括配置为1s 22(s,p)q、1s 22(s,p)q-1nl、1s 12(s,p)q+1、1s 12)s,p qnl、2(s,普)q+2和2(s、普)q+1nl的所有能级能量,其中1≤q≤8,n≤5和l≤3。我们将我们的结果与美国国家标准与技术研究所(NIST)在线数据库的数据以及之前的计算结果进行了比较。价能级能量的平均偏差范围为类Ne离子中的0.16eV至类Li离子中的0.01eV,表明目前的MR-MP价能级能量是高度准确的。在K空位态的情况下,对于像S XIV和Ar XVI的Li,偏差通常低于0.3eV。其他L壳层离子(Be-、B-、C-、N-和O-类Ar离子)中K空位能量的偏差更高,但可能是因为NIST推荐值具有更高的不确定性。该数据集包括先前未报道的S和Ar的L壳层离子中的许多n=4和n=5价态和K空位能级。这些数据可用于天体物理学和实验室产生的等离子体中S和Ar的L壳层离子的线识别和建模,并在缺乏更准确的实验室测量的情况下作为能量参考。
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引用次数: 4
SIFTING FOR SAPPHIRES: SYSTEMATIC SELECTION OF TIDAL DISRUPTION EVENTS IN iPTF. 筛选蓝宝石:iPTF潮汐破坏事件的系统选择。
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2018-10-01 Epub Date: 2018-09-27 DOI: 10.3847/1538-4365/aad8b1
T Hung, S Gezari, S B Cenko, S van Velzen, N Blagorodnova, Lin Yan, S R Kulkarni, R Lunnan, T Kupfer, G Leloudas, A K H Kong, P E Nugent, C Fremling, Russ R Laher, F J Masci, Y Cao, R Roy, T Petrushevska

We present results from a systematic selection of tidal disruption events (TDEs) in a wide-area (4800 deg2), g + R band, Intermediate Palomar Transient Factory (iPTF) experiment. Our selection targets typical optically-selected TDEs: bright (>60% flux increase) and blue transients residing in the center of red galaxies. Using photometric selection criteria to down-select from a total of 493 nuclear transients to a sample of 26 sources, we then use follow-up UV imaging with the Neil Gehrels Swift Telescope, ground-based optical spectroscopy, and light curve fitting to classify them as 14 Type Ia supernovae (SNe Ia), 9 highly variable active galactic nuclei (AGNs), 2 confirmed TDEs, and 1 potential core-collapse supernova. We find it possible to filter AGNs by employing a more stringent transient color cut (g - r < -0.2 mag); further, UV imaging is the best discriminator for filtering SNe, since SNe Ia can appear as blue, optically, as TDEs in their early phases. However, when UV-optical color is unavailable, higher precision astrometry can also effectively reduce SNe contamination in the optical. Our most stringent optical photometric selection criteria yields a 4.5:1 contamination rate, allowing for a manageable number of TDE candidates for complete spectroscopic follow-up and real-time classification in the ZTF era. We measure a TDE per galaxy rate of 1.7 - 1.3 + 2.9 × 10 - 4 gal - 1 yr - 1 (90% CL in Poisson statistics). This does not account for TDEs outside our selection criteria, thus may not reflect the total TDE population, which is yet to be fully mapped.

我们介绍了在广域(4800°g2), g + R波段,中间帕洛玛瞬态工厂(iPTF)实验中系统选择潮汐中断事件(TDEs)的结果。我们的选择目标是典型的光学选择tde:位于红色星系中心的明亮(>60%的通量增加)和蓝色瞬变。利用光度选择标准从总共493个核瞬态中筛选出26个样本源,然后利用尼尔·格瑞尔斯Swift望远镜的后续紫外成像、地面光谱学和光曲线拟合将它们分类为14个Ia型超新星(SNe Ia)、9个高度可变的活动星系核(agn)、2个已确认的tde和1个潜在的核心坍缩超新星。我们发现可以通过采用更严格的瞬态色切(g - r < -0.2 mag)来过滤agn;此外,紫外成像是过滤新光的最佳鉴别器,因为新光Ia在其早期阶段可以像tde一样呈现出光学上的蓝色。然而,当紫外光学颜色不可用时,更高精度的天体测量也可以有效地减少光学中的SNe污染。我们最严格的光学光度选择标准产生4.5:1的污染率,允许在ZTF时代进行完整的光谱跟踪和实时分类的可控数量的TDE候选者。我们测量到每个星系的TDE速率为1.7 - 1.3 + 2.9 × 10 - 4加仑- 1年- 1(泊松统计中的90% CL)。这并没有考虑到我们选择标准之外的TDE,因此可能不能反映TDE人口总数,这尚未得到充分的映射。
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引用次数: 32
PLANETARY CANDIDATES OBSERVED BY Kepler. VIII. A FULLY AUTOMATED CATALOG WITH MEASURED COMPLETENESS AND RELIABILITY BASED ON DATA RELEASE 25. 开普勒观测到的候选行星。8一个完全自动化的目录与测量完整性和可靠性基于数据发布25。
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2018-04-01 Epub Date: 2018-04-09 DOI: 10.3847/1538-4365/aab4f9
Susan E Thompson, Jeffrey L Coughlin, Kelsey Hoffman, Fergal Mullally, Jessie L Christiansen, Christopher J Burke, Steve Bryson, Natalie Batalha, Michael R Haas, Joseph Catanzarite, Jason F Rowe, Geert Barentsen, Douglas A Caldwell, Bruce D Clarke, Jon M Jenkins, Jie Li, David W Latham, Jack J Lissauer, Savita Mathur, Robert L Morris, Shawn E Seader, Jeffrey C Smith, Todd C Klaus, Joseph D Twicken, Jeffrey E Van Cleve, Bill Wohler, Rachel Akeson, David R Ciardi, William D Cochran, Christopher E Henze, Steve B Howell, Daniel Huber, Andrej Prša, Solange V Ramírez, Timothy D Morton, Thomas Barclay, Jennifer R Campbell, William J Chaplin, David Charbonneau, Jørgen Christensen-Dalsgaard, Jessie L Dotson, Laurance Doyle, Edward W Dunham, Andrea K Dupree, Eric B Ford, John C Geary, Forrest R Girouard, Howard Isaacson, Hans Kjeldsen, Elisa V Quintana, Darin Ragozzine, Avi Shporer, Victor Silva Aguirre, Jason H Steffen, Martin Still, Peter Tenenbaum, William F Welsh, Angie Wolfgang, Khadeejah A Zamudio, David G Koch, William J Borucki

We present the Kepler Object of Interest (KOI) catalog of transiting exoplanets based on searching four years of Kepler time series photometry (Data Release 25, Q1-Q17). The catalog contains 8054 KOIs of which 4034 are planet candidates with periods between 0.25 and 632 days. Of these candidates, 219 are new in this catalog and include two new candidates in multi-planet systems (KOI-82.06 and KOI-2926.05), and ten new high-reliability, terrestrial-size, habitable zone candidates. This catalog was created using a tool called the Robovetter which automatically vets the DR25 Threshold Crossing Events (TCEs) found by the Kepler Pipeline (Twicken et al. 2016). Because of this automation, we were also able to vet simulated data sets and therefore measure how well the Robovetter separates those TCEs caused by noise from those caused by low signal-to-noise transits. Because of these measurements we fully expect that this catalog can be used to accurately calculate the frequency of planets out to Kepler's detection limit, which includes temperate, super-Earth size planets around GK dwarf stars in our Galaxy. This paper discusses the Robovetter and the metrics it uses to decide which TCEs are called planet candidates in the DR25 KOI catalog. We also discuss the simulated transits, simulated systematic noise, and simulated astrophysical false positives created in order to characterize the properties of the final catalog. For orbital periods less than 100 d the Robovetter completeness (the fraction of simulated transits that are determined to be planet candidates) across all observed stars is greater than 85%. For the same period range, the catalog reliability (the fraction of candidates that are not due to instrumental or stellar noise) is greater than 98%. However, for low signal-to-noise candidates found between 200 and 500 days, our measurements indicate that the Robovetter is 73.5% complete and 37.2% reliable across all searched stars (or 76.7% complete and 50.5% reliable when considering just the FGK dwarf stars). We describe how the measured completeness and reliability varies with period, signal-to-noise, number of transits, and stellar type. Also, we discuss a value called the disposition score which provides an easy way to select a more reliable, albeit less complete, sample of candidates. The entire KOI catalog, the transit fits using Markov chain Monte Carlo methods, and all of the simulated data used to characterize this catalog are available at the NASA Exoplanet Archive.

我们提出了开普勒感兴趣的对象(KOI)目录的凌日系外行星基于搜索四年的开普勒时间序列光度(数据发布25,Q1-Q17)。该目录包含8054颗koi,其中4034颗是周期在0.25至632天之间的候选行星。在这些候选者中,219个是新发现的,包括两个多行星系统的候选者(KOI-82.06和KOI-2926.05),以及10个新的高可靠性,陆地大小,宜居带候选者。该目录是使用一种名为Robovetter的工具创建的,该工具可以自动审查开普勒管道发现的DR25阈值交叉事件(tce) (Twicken et al. 2016)。由于这种自动化,我们也能够审查模拟数据集,从而测量Robovetter区分由噪声引起的tce和由低信噪转换引起的tce的能力。由于这些测量结果,我们完全期望这个目录可以用来精确地计算出开普勒探测极限之外的行星的频率,其中包括我们银河系中围绕GK矮星的温带、超级地球大小的行星。本文讨论了Robovetter以及它用来决定哪些tce被称为DR25 KOI星表中的候选行星的指标。我们还讨论了模拟的凌日、模拟的系统噪声和模拟的天体物理假阳性,这些假阳性是为了描述最终星表的特性而产生的。对于轨道周期小于100 d的所有观测恒星,Robovetter完备性(被确定为行星候选者的模拟凌日的比例)大于85%。在同一时期范围内,星表可靠性(不是由仪器或恒星噪声引起的候选星的比例)大于98%。然而,对于在200至500天内发现的低信噪比候选者,我们的测量表明,在所有搜索的恒星中,Robovetter的完成率为73.5%,可靠性为37.2%(仅考虑FGK矮星时,完成率为76.7%,可靠性为50.5%)。我们描述了测量的完整性和可靠性如何随周期、信噪比、凌日次数和恒星类型而变化。此外,我们还讨论了一个被称为性格分数的值,它提供了一种简单的方法来选择更可靠的候选人样本,尽管不太完整。整个KOI目录,凌日使用马尔可夫链蒙特卡罗方法拟合,所有用于描述该目录的模拟数据都可以在NASA系外行星档案中获得。
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引用次数: 265
An Infrared Spectroscopic Study Toward the Formation of Alkylphosphonic Acids and Their Precursors in Extraterrestrial Environments. 地外环境中烷基膦酸及其前体形成的红外光谱研究。
IF 8.6 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2018-01-01 Epub Date: 2018-01-12 DOI: 10.3847/1538-4365/aa9183
Andrew M Turner, Matthew J Abplanalp, Tyler J Blair, Remwilyn Dayuha, Ralf I Kaiser

The only known phosphorus-containing organic compounds of extraterrestrial origin, alkylphosphonic acids, were discovered in the Murchison meteorite and have accelerated the hypothesis that reduced oxidation states of phosphorus were delivered to early Earth and served as a prebiotic source of phosphorus. While previous studies looking into the formation of these alkylphosphonic acids have focused on the iron-nickel phosphide mineral schreibersite and phosphorous acid as a source of phosphorus, this work utilizes phosphine (PH3), which has been discovered in the circumstellar envelope of IRC +10216, in the atmosphere of Jupiter and Saturn, and believed to be the phosphorus carrier in comet 67P/Churyumov-Gerasimenko. Phosphine ices prepared with interstellar molecules such as carbon dioxide, water, and methane were subjected to electron irradiation, which simulates the secondary electrons produced from galactic cosmic rays penetrating the ice, and probed using infrared spectroscopy to understand the possible formation of alkylphosphonic acids and their precursors on interstellar icy grains that could become incorporated into meteorites such as Murchison. We present the first study and results on the possible synthesis of alkylphosphonic acids produced from phosphine-mixed ices under interstellar conditions. All functional groups of alkylphosphonic acids were detected through infrared spectroscopically, suggesting that this class of molecules can be formed in interstellar ices.

唯一已知的地外来源的含磷有机化合物烷基膦酸是在Murchison陨石中发现的,这加速了磷氧化态减少被输送到早期地球并作为磷的益生元来源的假设。虽然之前对这些烷基膦酸形成的研究主要集中在磷化铁镍矿物schreibersite和作为磷来源的亚磷酸上,但这项工作利用了磷化氢(PH3),它是在木星和土星大气中IRC+10216的星周包层中发现的,并被认为是67P/Churyumov Gerasimenko彗星中的磷载体。用二氧化碳、水和甲烷等星际分子制备的磷化氢冰受到电子辐射,模拟银河系宇宙射线穿透冰产生的二次电子,并使用红外光谱进行探测,以了解烷基膦酸及其前体在星际冰粒上可能形成的情况,这些冰粒可能会融入Murchison等陨石中。我们首次对星际条件下由磷化氢混合冰制备烷基膦酸的可能性进行了研究和结果。通过红外光谱法检测到烷基膦酸的所有官能团,表明这类分子可以在星际冰中形成。
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引用次数: 0
RELATIVISTIC MR-MP ENERGY LEVELS FOR L-SHELL IONS OF SILICON. 硅l -壳层离子的相对论mr-mp能级。
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2018-01-01 Epub Date: 2018-01-15 DOI: 10.3847/1538-4365/aa94d2
Juan A Santana, Nahyr A Lopez-Dauphin, Peter Beiersdorfer

Level energies are reported for Si V, Si VI, Si VII, Si VIII, Si IX, Si X, Si XI and Si XII. The energies have been calculated with the relativistic Multi-Reference Møller-Plesset Perturbation Theory method and include valence and K-vacancy states with nl up to 5f. The accuracy of the calculated level energies is established by comparison with the recommended data listed in the National Institute of Standards and Technology (NIST) on-line database. The average deviation of valence level energies ranges from 0.20 eV in Si V to 0.04 eV in Si XII. For K-vacancy states, the available values recommended in the NIST database are limited to Si XII and Si XIII. The average energy deviation is below 0.3 eV for K-vacancy states. The extensive and accurate dataset presented here greatly augments the amount of available reference level energies. We expect our data to ease the line identification of L-shell ions of Si in celestial sources and laboratory generated plasmas, and to serve as energy references in the absence of more accurate laboratory measurements.

用相对论的多参考Møller-Plesset微扰理论方法计算了其能量,包括了nl到5f的价态和k空位态。通过与美国国家标准与技术研究院(NIST)在线数据库中列出的推荐数据进行比较,确定了计算能级能的准确性。价能级能的平均偏差在Si V的0.20 eV到Si XII的0.04 eV之间。对于k -空位态,NIST数据库中推荐的可用值仅限于Si XII和Si XIII。k空位态的平均能量偏差小于0.3 eV。这里提供的广泛而准确的数据集大大增加了可用参考能级能量的数量。我们希望我们的数据能够简化天体源和实验室产生的等离子体中Si的l -壳离子的线识别,并在缺乏更精确的实验室测量时作为能量参考。
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引用次数: 4
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