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IMPROVED Cr II log(gf ) VALUES AND ABUNDANCE DETERMINATIONS IN THE PHOTOSPHERES OF THE SUN AND METAL-POOR STAR HD 84937. 改进了太阳和贫金属恒星hd84937光球中铬测井(gf)值和丰度的测定。
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2017-01-01 Epub Date: 2017-01-20 DOI: 10.3847/1538-4365/228/1/10
J E Lawler, C Sneden, G Nave, E A Den Hartog, N Emrahođlu, J J Cowan

New emission branching fraction (BF) measurements for 183 lines of the second spectrum of chromium (Cr II) and new radiative lifetime measurements from laser-induced fluorescence for 8 levels of Cr+ are reported. The goals of this study are to improve transition probability measurements in Cr II and reconcile solar and stellar Cr abundance values based on Cr I and Cr II lines. Eighteen spectra from three Fourier Transform Spectrometers supplemented with ultraviolet spectra from a high-resolution echelle spectrometer are used in the BF measurements. Radiative lifetimes from this study and earlier publications are used to convert the BFs into absolute transition probabilities. These new laboratory data are applied to determine the Cr abundance log ε in the Sun and metal-poor star HD 84937. The mean result in the Sun is 〈logε (Cr II)〉 = 5.624±0.009 compared to 〈logε(Cr I)〉 = 5.644 ± 0.006 on a scale with the hydrogen abundance log ε(H) = 12 and with the uncertainty representing only line-to-line scatter. A Saha (ionization balance) test on the photosphere of HD 84937 is also performed, yielding 〈logε(Cr II)〉 = 3.417 ± 0.006 and 〈log ε(Cr I, lower level excitation potential E. P. >30 eV)〉 = 3.3743±30.011 for this dwarf star. We find a correlation of Cr with the iron-peak element Ti, suggesting an associated nucleosynthetic production. Four iron-peak elements (Cr along with Ti, V, and Sc) appear to have a similar (or correlated) production history-other iron-peak elements appear not to be associated with Cr.

本文报道了铬(Cr II)第二光谱183谱线的新发射分支分数(BF)测量和8个水平Cr+激光诱导荧光辐射寿命的新测量。本研究的目的是改进Cr II的跃迁概率测量,并根据Cr I和Cr II谱线调和太阳和恒星的Cr丰度值。利用3台傅立叶变换光谱仪的18个光谱和一台高分辨率梯队光谱仪的紫外光谱进行BF测量。利用本研究和早期出版物的辐射寿命将BFs转换为绝对跃迁概率。这些新的实验室数据被用于确定太阳和金属贫乏恒星HD 84937中的Cr丰度log ε。太阳的平均结果是< logε(Cr II) > = 5.624±0.009,与< logε(Cr I) > = 5.644±0.006相比,在氢丰度logε(H) = 12的尺度上,不确定度仅表示线对线散射。对hd84937的光球进行了Saha(电离平衡)测试,得到该矮星的< logε(Cr II) > = 3.417±0.006,< logε(Cr I,低能级激发电位e.p. >30 eV) > = 3.3743±30.011。我们发现Cr与铁峰元素Ti的相关性,表明相关的核合成生产。四种铁峰元素(Cr、Ti、V和Sc)似乎有相似的(或相关的)生产历史,其他铁峰元素似乎与Cr无关。
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引用次数: 54
Transition Energies and Absorption Oscillator Strengths for , , and Band Systems in N2 N2中,和能带体系的跃迁能和吸收振子强度
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2017-01-01 DOI: 10.3847/1538-4365/aa656e
C. Lavín, A. M. Velasco
Theoretical transition energies and absorption oscillator strengths for the (v′ = 0–2, 5, 7, 8) − and (v′ = 0, 2) − (v″ = 0–14) Rydberg bands, and (v′ = 0–9, 11, 12, 14–19, 21, 22) − (v″ = 0–14) valence bands of molecular nitrogen are reported. The strong interaction between states has been dealt with through a vibronic interaction matrix. As a consequence of the Rydberg-valence interaction, irregularities in the vibrational structure of the above band systems are observed. Good agreement is found with the scarce high-resolution data that are available for oscillator strengths. The new band oscillator strengths reported here may be useful for a reliable interpretation of the spectra from atmospheres of the Earth, Titan, and Triton, where is the mayor constituent.
本文报道了分子氮的(v ' = 0 - 2,5,7,8)−和(v ' = 0,2)−(v″= 0 - 14)Rydberg能带和(v ' = 0 - 9,11,12,14 - 19,21,22)−(v″= 0 - 14)价带的理论跃迁能和吸收振子强度。通过一个振动相互作用矩阵来处理态间的强相互作用。由于里德堡价相互作用的结果,观察到上述能带系统的振动结构中的不规则性。与现有的高分辨率振子强度数据有很好的一致性。这里报告的新的带振子强度可能有助于可靠地解释地球、泰坦和海卫一的大气光谱,其中主要成分。
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引用次数: 0
On the Characteristics of Footpoints of Solar Magnetic Flux Ropes during the Eruption 火山喷发时太阳磁通量绳足点特征研究
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2016-05-13 DOI: 10.3847/0067-0049/225/1/16
Xin Cheng, M. Ding
We investigate the footpoints of four erupted magnetic flux ropes (MFRs) that appear as sigmoidal hot channels prior to the eruptions in the Atmospheric Imaging Assembly high temperaure passbands. The simultaneous Helioseismic and Magnetic Imager observations disclose that one footpoint of the MFRs originates in the penumbra or penumbra edge with a stronger magnetic field, while the other in the moss region with a weaker magnetic field. The significant deviation of the axis of the MFRs from the main polarity inversion lines and associated filaments suggests that the MFRs have ascended to a high altitude, thus being distinguishable from the source sigmoidal ARs. The more interesting thing is that, with the eruption of the MFRs, the average inclination angle and direct current at the footpoints with stronger magnetic field tend to decrease, which is suggestive of a straightening and untwisting of the magnetic field in the MFR legs. Moreover, the associated flare ribbons also display an interesting evolution. They initially appear as sporadical brightenings at the two footpoints of and in the regions below the MFRs and then quickly extend to two slender sheared J-shaped ribbons with the two hooks corresponding to the two ends of the MFRs. Finally, the straight parts of the two ribbons separate from each other, evolving into two widened parallel ones. These features mostly conforms to and supports the recently proposed three-dimensional standard CME/flare model, i.e., the twisted MFR eruption stretches and leads to the reconnection of the overlying field that transits from a strong to weak shear with the increasing height.
在大气成像组件高温通道中,我们研究了四个喷发的磁通绳(MFRs)的脚点,这些磁通绳在喷发前表现为s形热通道。日震和磁成像仪同时观测发现,其中一个足点位于磁场较强的半影或半影边缘,另一个足点位于磁场较弱的苔藓区。MFRs的轴线与主极性反转线及相关细丝的明显偏离表明MFRs已经上升到较高的高度,从而与源s型ar区分开来。更有趣的是,随着磁磁体的喷发,磁场较强的足点处的平均倾角和直流电趋于减小,这表明磁磁体足点处的磁场发生了拉直和解扭。此外,相关的耀斑带也显示出有趣的演变。它们最初在MFRs的两个脚点和下面的区域以零星的亮斑出现,然后迅速扩展到两个细长的剪切j形带,两个钩子对应于MFRs的两端。最后,两条缎带的直线部分彼此分离,演变成两条加宽的平行缎带。这些特征基本符合并支持了最近提出的三维标准CME/耀斑模型,即扭曲的MFR喷发拉伸并导致上覆磁场的重连,并随着高度的增加从强剪切过渡到弱剪切。
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引用次数: 39
RRC-BlecicEtal-2016-ApJS-TEA RRC-BlecicEtal-2016-ApJS-TEA
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2016-04-25 DOI: 10.5281/ZENODO.50378
J. Blecic, J. Harrington, M. Bowman
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引用次数: 1
Conditional Deletion of Bmal1 in Ovarian Theca Cells Disrupts Ovulation in Female Mice. 卵巢癌细胞中 Bmal1 的条件性缺失会破坏雌性小鼠的排卵。
IF 4.8 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2016-02-01 Epub Date: 2015-12-15 DOI: 10.1210/en.2015-1645
Amanda L Mereness, Zachary C Murphy, Andrew C Forrestel, Susan Butler, CheMyong Ko, JoAnne S Richards, Michael T Sellix

Rhythmic events in female reproductive physiology, including ovulation, are tightly controlled by the circadian timing system. The molecular clock, a feedback loop oscillator of clock gene transcription factors, dictates rhythms of gene expression in the hypothalamo-pituitary-ovarian axis. Circadian disruption due to environmental factors (eg, shift work) or genetic manipulation of the clock has negative impacts on fertility. Although the central pacemaker in the suprachiasmatic nucleus classically regulates the timing of ovulation, we have shown that this rhythm also depends on phasic sensitivity to LH. We hypothesized that this rhythm relies on clock function in a specific cellular compartment of the ovarian follicle. To test this hypothesis we generated mice with deletion of the Bmal1 locus in ovarian granulosa cells (GCs) (Granulosa Cell Bmal1 KO; GCKO) or theca cells (TCs) (Theca Cell Bmal1 KO; TCKO). Reproductive cycles, preovulatory LH secretion, ovarian morphology and behavior were not grossly altered in GCKO or TCKO mice. We detected phasic sensitivity to LH in wild-type littermate control (LC) and GCKO mice but not TCKO mice. This decline in sensitivity to LH is coincident with impaired fertility and altered patterns of LH receptor (Lhcgr) mRNA abundance in the ovary of TCKO mice. These data suggest that the TC is a pacemaker that contributes to the timing and amplitude of ovulation by modulating phasic sensitivity to LH. The TC clock may play a critical role in circadian disruption-mediated reproductive pathology and could be a target for chronobiotic management of infertility due to environmental circadian disruption and/or hormone-dependent reprogramming in women.

包括排卵在内的女性生殖生理节律事件受到昼夜节律计时系统的严格控制。分子时钟是时钟基因转录因子的反馈回路振荡器,决定着下丘脑-垂体-卵巢轴的基因表达节律。环境因素(如轮班工作)或基因操纵造成的昼夜节律紊乱会对生育能力产生负面影响。尽管蛛网膜上核的中央起搏器通常调节排卵时间,但我们已经证明这种节律也取决于对 LH 的相位敏感性。我们假设这种节律依赖于卵泡特定细胞区的时钟功能。为了验证这一假设,我们培育了卵巢颗粒细胞(GCs)(Granulosa Cell Bmal1 KO; GCKO)或卵巢细胞(TCs)(Theca Cell Bmal1 KO; TCKO)中Bmal1基因座缺失的小鼠。GCKO 或 TCKO 小鼠的生殖周期、排卵前 LH 分泌、卵巢形态和行为均无明显改变。我们在野生型同窝对照(LC)和 GCKO 小鼠中检测到了对 LH 的阶段性敏感性,但在 TCKO 小鼠中没有检测到。对 LH 敏感性的下降与 TCKO 小鼠生育能力受损和卵巢中 LH 受体 (Lhcgr) mRNA 丰度模式的改变相吻合。这些数据表明,TC是一个起搏器,它通过调节对LH的相位敏感性来影响排卵的时间和幅度。TC时钟可能在昼夜节律紊乱介导的生殖病理学中发挥关键作用,并可能成为慢性生物疗法治疗因环境昼夜节律紊乱和/或激素依赖性重编程导致的女性不孕症的靶点。
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引用次数: 57
Decision aids for people considering taking part in clinical trials. 为考虑参加临床试验的人提供决策辅助工具。
IF 8.8 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2015-11-27 DOI: 10.1002/14651858.CD009736.pub2
Katie Gillies, Seonaidh C Cotton, Jamie C Brehaut, Mary C Politi, Zoe Skea
<p><strong>Background: </strong>Several interventions have been developed to promote informed consent for participants in clinical trials. However, many of these interventions focus on the content and structure of information (e.g. enhanced information or changes to the presentation format) rather than the process of decision making. Patient decision aids support a decision making process about medical options. Decision aids support the decision process by providing information about available options and their associated outcomes, alongside information that enables patients to consider what value they place on particular outcomes, and provide structured guidance on steps of decision making. They have been shown to be effective for treatment and screening decisions but evidence on their effectiveness in the context of informed consent for clinical trials has not been synthesised.</p><p><strong>Objectives: </strong>To assess the effectiveness of decision aids for clinical trial informed consent compared to no intervention, standard information (i.e. usual practice) or an alternative intervention on the decision making process.</p><p><strong>Search methods: </strong>We searched the following databases and to March 2015: Cochrane Central Register of Controlled Trials (CENTRAL), The Cochrane Library; MEDLINE (OvidSP) (from 1950); EMBASE (OvidSP) (from 1980); PsycINFO (OvidSP) (from 1806); ASSIA (ProQuest) (from 1987); WHO International Clinical Trials Registry Platform (ICTRP) (http://apps.who.int/trialsearch/); ClinicalTrials.gov; ISRCTN Register (http://www.controlled-trials.com/isrctn/). We also searched reference lists of included studies and relevant reviews. We contacted study authors and other experts. There were no language restrictions.</p><p><strong>Selection criteria: </strong>We included randomised and quasi-randomised controlled trials comparing decision aids in the informed consent process for clinical trials alone, or in conjunction with standard information (such as written or verbal) or alongside alternative interventions (e.g. paper-based versus web-based decision aids). Included trials involved potential trial participants, or their guardians, being asked to consider participating in a real or hypothetical clinical trial.</p><p><strong>Data collection and analysis: </strong>At least two authors independently assessed studies for inclusion, extracted reported data and assessed risk of bias. Findings were pooled where appropriate. We used GRADE to assess the quality of the evidence for each outcome.</p><p><strong>Main results: </strong>We identified one study (290 randomised participants) that investigated the effectiveness of decision aids compared to standard information in the informed consent process for clinical trials. This study reported two separate decision aid randomised controlled trials (RCTs). The decision aid trials were nested within two different parent trials focusing on breast cancer in postmenopausal women. One tri
背景:为促进临床试验参与者的知情同意,已经制定了一些干预措施。然而,这些干预措施大多侧重于信息的内容和结构(如增强信息或改变演示格式),而不是决策过程。患者决策辅助工具支持有关医疗选择的决策过程。决策辅助工具通过提供有关现有选择及其相关结果的信息,以及使患者能够考虑其对特定结果的价值的信息,来支持决策过程,并为决策步骤提供结构化指导。这些辅助工具已被证明对治疗和筛查决策有效,但有关其在临床试验知情同意方面的有效性的证据尚未汇总:评估临床试验知情同意决策辅助工具与无干预措施、标准信息(即常规做法)或其他干预措施相比在决策过程中的有效性:截至 2015 年 3 月,我们检索了以下数据库:Cochrane 图书馆的 Cochrane Central Register of Controlled Trials (CENTRAL);MEDLINE (OvidSP)(1950 年起);EMBASE (OvidSP)(1980 年起);PsycINFO (OvidSP)(1806 年起);ASSIA (ProQuest)(1987 年起);WHO International Clinical Trials Registry Platform (ICTRP) (http://apps.who.int/trialsearch/);ClinicalTrials.gov;ISRCTN Register (http://www.controlled-trials.com/isrctn/)。我们还检索了纳入研究的参考文献目录和相关综述。我们还联系了研究报告的作者和其他专家。没有语言限制:我们纳入了随机和准随机对照试验,这些试验比较了临床试验知情同意程序中的决策辅助工具单独使用、与标准信息(如书面或口头信息)结合使用或与其他干预措施(如纸质决策辅助工具与网络决策辅助工具)结合使用的情况。纳入的试验涉及要求潜在试验参与者或其监护人考虑参与真实或假设的临床试验:至少有两名作者独立评估研究是否纳入、提取报告数据并评估偏倚风险。在适当的情况下对研究结果进行汇总。我们使用 GRADE 对每项结果的证据质量进行了评估:我们发现一项研究(290 名随机参与者)调查了决策辅助工具与临床试验知情同意程序中标准信息的有效性比较。该研究报告了两项独立的决策辅助随机对照试验(RCT)。决策辅助工具试验嵌套在两个不同的母试验中,重点是绝经后妇女的乳腺癌。其中一项试验的重点是曾接受过乳腺导管原位癌(DCIS)手术的妇女在治疗方面的知情同意,另一项试验的重点是乳腺癌高危妇女在预防方面的知情同意。这些 RCT 中使用了两种不同的决策辅助工具,并与标准信息进行了比较。汇总的研究结果突显了大多数报告结果的不确定性,包括知识、决策冲突、焦虑、试验参与和自然减员。有极低质量的证据表明,决策辅助工具在很小程度上降低了决策后悔的程度(MD -5.53,95% CI -10.29至-0.76)。关于几项预先指定的主要结果,包括准确的风险认知、基于价值观的决策,或潜在参与者是否认识到需要做出决策、能否识别对个人而言最重要的选项特征或是否参与决策,均未找到相关数据:目前尚无充分证据表明,用于支持临床试验知情同意程序的决策辅助工具是否比标准信息更有效。需要在更多不同的临床和社会人群中开展更多设计合理、有充分证据支持的临床试验,以加强本综述的结果。从更广泛的意义上讲,未来对哪些结果最适合在这种情况下进行评估的研究将有所帮助。
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引用次数: 0
THE MOSFIRE DEEP EVOLUTION FIELD (MOSDEF) SURVEY: REST-FRAME OPTICAL SPECTROSCOPY FOR similar to 1500 H-SELECTED GALAXIES AT 1.37 <= z <= 3.8 MOSFIRE深度演化场(MOSDEF)巡天:在1.37 <= z <= 3.8下,对1500个h -选择星系的静止框架光学光谱
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2015-06-01 DOI: 10.1088/00647-0049/218/2/15
M. Kriek, A. Shapley, N. Reddy, B. Siana, A. Coil, B. Mobasher, W. Freeman, L. D. Groot, S. Price, R. Sanders, I. Shivaei, G. Brammer, I. Momcheva, R. Skelton, P. Dokkum, K. Whitaker, J. Aird, Mojegan Azadi, M. Kassis, J. Bullock, C. Conroy, R. Davé, D. Keres̆, M. Krumholz
Author(s): Kriek, Mariska; Shapley, Alice E; Reddy, Naveen A; Siana, Brian; Coil, Alison L; Mobasher, Bahram; Freeman, William R; de Groot, Laura; Price, Sedona H; Sanders, Ryan; Shivaei, Irene; Brammer, Gabriel B; Momcheva, Ivelina G; Skelton, Rosalind E; van Dokkum, Pieter G; Whitaker, Katherine E; Aird, James; Azadi, Mojegan; Kassis, Marc; Bullock, James S; Conroy, Charlie; Dave, Romeel; Keres, Dusan; Krumholz, Mark
作者:Kriek, Mariska;Alice E . Shapley;Reddy, Naveen A;布莱恩Siana;线圈,艾莉森·L;Mobasher检测;威廉·弗里曼;劳拉·德·格鲁特;塞多娜·H·普莱斯;桑德斯,瑞安;艾琳Shivaei;加布里埃尔·B·布拉默;艾维琳娜·蒙切娃;斯克尔顿,罗莎琳德·E;范多库姆,彼得·G;凯瑟琳·惠特克;Aird,詹姆斯;阿扎迪,Mojegan;Kassis,马克;詹姆斯·布洛克;康罗伊,查理;戴夫,Romeel;凯瑞斯语,科维奇;Krumholz,马克
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引用次数: 1
Finding Warm Debris Disks with WISE Around Bright Stars 用WISE在明亮恒星周围寻找温暖的碎片盘
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2014-06-18 DOI: 10.5281/ZENODO.10573
R. Patel, A. Heinze, S. Metchev
The WISE All-Sky Survey Catalog presents an opportunity to expand the number of detections of warm (>100K) circumstellar dust in asteroid belt-analog regions. Such detections are useful to statistically constrain the occurrence rate of dusty systems, and imaging campaigns aiming to characterize the morphology of the dust populations can choose their targets form the nearest ( 30μm excesses (289, with 171 in common), even if the latter have been found to have a higher occurrence rate. 114 Finding Warm Debris Disks with WISE Around Bright Stars
WISE全天巡天目录提供了一个机会,可以在小行星带类似区域扩大探测到温暖的(bbb100k)星周尘埃的数量。这样的检测在统计上限制尘埃系统的发生率是有用的,并且旨在表征尘埃种群形态的成像运动可以选择最近的目标(30μm过量(289,共有171)),即使后者被发现具有更高的发生率。114用WISE在明亮恒星周围寻找温暖的碎片盘
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引用次数: 0
TRANSIT TIMING VARIATION OF NEAR-RESONANCE PLANETARY PAIRS. II. CONFIRMATION OF 30 PLANETS IN 15 MULTIPLE-PLANET SYSTEMS 近共振行星对凌日时变。2确认了15个多行星系统中的30颗行星
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2014-01-01 DOI: 10.1088/0067-0049/210/2/25
Ji-Wei 伟 Xie 谢基
Following on from Paper I in this series, I report the confirmation of a further 30 planets in 15 multiple-planet systems via transit timing variations (TTVs), using the publicly available Kepler light curves (Q0–Q16). All 15 pairs are near first-order mean motion resonances, showing sinusoidal TTVs consistent with theoretically predicted periods, which demonstrate they are orbiting and interacting in the same systems. Although individual masses cannot be accurately extracted based only on TTVs (because of the well known degeneracy between mass and eccentricity), the measured TTV phases and amplitudes can still place relatively tight constraints on their mass ratios and upper limits on their masses, which confirm their planetary nature. Some of these systems (KOI-274, KOI-285, KOI-370, and KOI-2672) are relatively bright and thus suitable for further follow-up observations.
继本系列的第一篇论文之后,我报告了在15个多行星系统中通过凌日时间变化(TTVs)确认了另外30颗行星,使用公开可用的开普勒光曲线(Q0-Q16)。所有15对都接近一阶平均运动共振,显示出与理论预测周期一致的正弦ttv,这表明它们在同一系统中绕轨道运行并相互作用。虽然单个质量不能仅仅基于TTV精确地提取(因为众所周知的质量和偏心率之间的简并),但测量的TTV相位和振幅仍然可以对它们的质量比和质量上限施加相对严格的约束,这证实了它们的行星性质。其中一些星系(KOI-274、KOI-285、KOI-370和KOI-2672)相对明亮,因此适合进一步的后续观测。
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引用次数: 3
The Infrared Spectra of Polycyclic Aromatic Hydrocarbons with Excess Peripheral H Atoms (Hn-PAHs) and their Relation to the 3.4 and 6.9 µm PAH Emission Features. 外周含过量H原子的多环芳烃(Hn-PAHs)红外光谱及其与3.4和6.9µm多环芳烃发射特征的关系
IF 8.7 1区 物理与天体物理 Q1 ASTRONOMY & ASTROPHYSICS Pub Date : 2013-01-01 Epub Date: 2013-03-01 DOI: 10.1088/0067-0049/205/1/8
Scott A Sandford, Max P Bernstein, Christopher K Materese

Polycyclic aromatic hydrocarbons (PAHs) are likely responsible for the family of infrared emission features seen in a wide variety of astrophysical environments. A potentially important subclass of these materials are PAHs whose edges contain excess H atoms (Hn-PAHs). This type of compound may be present in space, but it has been difficult to assess this possibility because of a lack of suitable laboratory spectra to assist with analysis of astronomical data. We present 4000-500 cm-1 (2.5-20 µm) infrared spectra of 23 Hn-PAHs and related molecules isolated in argon matrices under conditions suitable for interpretation of astronomical data. Spectra of molecules with mixed aromatic and aliphatic domains show characteristics that distinguish them from fully aromatic PAH equivalents. Two major changes occur as PAHs become more hydrogenated: (1) aromatic C-H stretching bands near 3.3 µm weaken and are replaced with stronger aliphatic bands near 3.4 µm, and (2) aromatic C-H out-of-plane bending mode bands in the 11-15 µm region shift and weaken concurrent with growth of a strong aliphatic -CH2-deformation mode near 6.9 µm. Implications for interpreting astronomical spectra are discussed with emphasis on the 3.4 and 6.9 µm features. Laboratory data is compared with emission spectra from IRAS 21282+5050, an object with normal PAH emission features, and IRAS 22272+5435 and IRAS 0496+3429, two protoplanetary nebulae with abnormally large 3.4 µm features. We show that 'normal' PAH emission objects contain relatively few Hn-PAHs in their emitter populations, but less evolved protoplanetary nebulae may contain significant abundances of these molecules.

多环芳烃(PAHs)可能是在各种天体物理环境中看到的红外发射特征家族的原因。这些材料的一个潜在的重要子类是多环芳烃,其边缘含有多余的氢原子(Hn-PAHs)。这种类型的化合物可能存在于太空中,但由于缺乏适当的实验室光谱来协助天文数据的分析,很难评估这种可能性。我们在适合天文数据解释的条件下,在氩气基质中分离了23个h - pahs和相关分子的4000-500 cm-1(2.5-20µm)红外光谱。具有混合芳香和脂肪结构域的分子的光谱显示出与完全芳香的多环芳烃等同物区分的特征。随着多环芳烃氢化程度的提高,发生了两个主要变化:(1)3.3µm附近芳烃C-H伸展带减弱,被3.4µm附近较强的脂肪族带所取代;(2)11-15µm区域芳烃C-H面外弯曲带随着6.9µm附近强脂肪族- ch2变形模式的增长而移动和减弱。讨论了天文光谱解释的意义,重点讨论了3.4和6.9 μ m特征。将实验室数据与具有正常多环芳烃发射特征的IRAS 21282+5050和具有异常大3.4µm特征的原行星状星云IRAS 22272+5435和IRAS 0496+3429的发射光谱进行了比较。我们发现,“正常”的多环芳烃发射天体在其发射体种群中含有相对较少的Hn-PAHs,但进化程度较低的原行星状星云可能含有这些分子的显著丰度。
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引用次数: 65
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Astrophysical Journal Supplement Series
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