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Synthesis and Characterization of Ordered and Disordered Mesoporous Alumina as High-Performance Molybdenum-99 Adsorbents 高性能钼-99吸附剂有序和无序介孔氧化铝的合成与表征
IF 0.4 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2021-04-16 DOI: 10.17146/AIJ.2021.1000
I. Saptiama, F. Rindiyantono, A. Aries, Y. V. Kaneti, M. Iqbal
Molybdenum-99 (99Mo) is the parent radioisotope of technetium-99m (99mTc),an essential medical radioisotope for diagnostic agents in nuclear medicine.In 99Mo/99mTc generator, a chromatography column system with 99Mo adsorbent as afiller is usually used to produce 99mTc in hospitals. However, it is still challenging to find high-performance adsorbentsfor Mo adsorption.We have synthesized both ordered and disordered mesoporous alumina and compared their performance as 99Mo adsorbents. These materials were prepared via a soft-templated method using a triblock copolymer as the template, followed by air calcination at 400°C.The amount of nitric acid (HNO3) and the drying time were adjusted systematically to synthesize the ordered mesoporous alumina. The obtained ordered and disordered mesoporous alumina were characterized by low-and wide-angle X-ray diffractions (XRD), nitrogen adsorption-desorption, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The 99Mo adsorption capacities of these materials were evaluated by using the batch method. The experimental results show that the ordered mesoporous alumina hasa higher 99Mo adsorption capacity of 72.06 mg(Mo)g-1 than the disordered mesoporous alumina (50.12 mg(Mo)g-1). The results indicate the excellent potential of ordered mesoporous alumina as an adsorbent for the 99Mo/99mTc generator column.
钼-99(99Mo)是锝-99m(99mTc)的母体放射性同位素,锝是核医学诊断试剂的重要医用放射性同位素。在99Mo/999mTc发生器中,医院通常使用以99Mo吸附剂为填料的色谱柱系统来生产99mTc。然而,寻找高性能的Mo吸附剂仍然具有挑战性。我们合成了有序和无序的介孔氧化铝,并比较了它们作为99Mo吸附剂的性能。这些材料是通过软模板法制备的,使用三嵌段共聚物作为模板,然后在400°C下进行空气煅烧。系统地调节硝酸(HNO3)的用量和干燥时间以合成有序的介孔氧化铝。通过低广角X射线衍射(XRD)、氮吸附-脱附、热重分析(TGA)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)对所获得的有序和无序介孔氧化铝进行了表征。采用分批法对这些材料的99Mo吸附性能进行了评价。实验结果表明,有序介孔氧化铝对99Mo的吸附量为72.06mg(Mo)g-1,高于无序介孔氧化铝(50.12mg(Mo)g-1)。结果表明,有序介孔氧化铝作为99Mo/999mTc发生器柱的吸附剂具有良好的潜力。
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引用次数: 0
Investigation on the Background Radiation of Abakaliki Rice Mill in Ebonyi State, Nigeria 尼日利亚埃邦伊州Abakaliki碾米厂本底辐射调查
IF 0.4 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2021-04-07 DOI: 10.17146/AIJ.2021.1040
A. Nwachukwu, F. C. Ikeagwuani, A. Adeboje
This study investigated the background ionizing radiation of Abakaliki rice mills. The requirement to monitor this site is because the prevalent activities in the site suggest that it is a source of ionizing radiation. The activities include fuel stations and excavation sites. Other sources are various chemicals and agrochemicals (like Phosphate, Uranium, Thorium, and Radium) used during the planting of the different rice species. There is, therefore, an urgent need to investigate the radiation level of Abakaliki rice mills in Ebonyi state, Nigeria to ascertain if it has passed the safety standards. The investigation was carried out using the Radalert 100 radiation monitor and a geographical positioning system (Garmin GPSMAP 765). The studied site was split into different points with each representing a mill that houses different grinding plants. This study included all the sections of the mill. The mean background radiation exposure rate ranges from 0.014 mRhr -1 to 0.0204 mRhr -1 . The obtained values are higher than the world standard limit of 0.013 mRhr -1 recommended by ICRP except point 7 which corresponds to the top of the rice husk dumpsite. The calculated absorbed dose rates for the various sections of the mill ranged from 99.18 nGh -1 to 177.48 nGyh -1 . These values of absorbed dose rates were observed to be far higher than the world permissible value of 89 nGyh -1 . The annual effective dose equivalent (AEDE) for the exposure values ranged from 0.122 mSvy -1 to 0.218 mSvy -1 which are far lower than the ICRP permissible limits of 1.00 mSvlyr for the public and therefore implies absence of any immediate radiological risk. The excess lifetime cancer risk for the mill users were all above the 0.29 × 10 -3 world recommended value. This suggests a possibility of the rice mill workers developing radiation-related illnesses over time.
本研究调查了Abakaliki碾米机的本底电离辐射。监测该场址的要求是因为该场址的普遍活动表明它是电离辐射源。这些活动包括加油站和挖掘地点。其他来源是种植不同水稻品种时使用的各种化学品和农用化学品(如磷酸盐、铀、钍和镭)。因此,迫切需要对尼日利亚埃邦伊州Abakaliki碾米厂的辐射水平进行调查,以确定其是否已通过安全标准。调查使用Radalert 100辐射监测仪和地理定位系统(Garmin GPSMAP 765)进行。研究地点被分成不同的点,每个点代表一个容纳不同研磨工厂的磨坊。这项研究包括了轧机的所有部分。平均本底辐射暴露率为0.014 ~ 0.0204 mRhr -1。所得值均高于ICRP推荐的0.013 mRhr -1的世界标准限值,但对应稻壳倾倒场顶部的7点除外。计算出的轧机各部分的吸收剂量率范围为99.18至177.48 nGyh -1。据观察,这些吸收剂量率值远远高于世界允许值89 nGyh -1。照射值的年有效剂量当量范围为0.122毫西维-1至0.218毫西维-1,远低于ICRP对公众允许的1.00毫西维-1限值,因此意味着没有任何直接的辐射风险。饮水机使用者的终生癌症风险均高于世界推荐值0.29 × 10 -3。这表明,随着时间的推移,碾米厂的工人有可能患上与辐射有关的疾病。
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引用次数: 0
Radon Concentrations in Canned Liquid Juice 罐装果汁中的氡浓度
IF 0.4 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2021-04-04 DOI: 10.17146/AIJ.2020.1030
A. Abojassim
This study was performed at University of Kufa, Iraq, using canned liquid juice samples found in Iraqi markets due to the absence of environmental contamination from radionuclides emitting 222 Rn concentrations using RAD-7 detectors. The annual effective dose (AED) of 222 Rn was estimated for children and adults from the ingestion of canned liquid juice samples. The estimated concentrations of 222 Rn in unit (mBq/L) ranged from 35.4 to 249.1, with an average of 77.880.24 ± 15.42. It also shows that the AED values for children and adults in (nSv/y) ranged from 19.11 to 134.48 with an average of 43.31 ± 8.32 and from 22.67 to 159.55 with an average of 51.39 ± 9.88, respectively. All estimated results of 222 Rn concentrations for juice samples were lower than the natural limits provided by the WHO and the European Union Commission to the public (0.5 and 1 Bq/L, respectively). Therefore, there are no health hazards from drinking juice sold in Iraq markets.
这项研究是在伊拉克库法大学进行的,使用的是在伊拉克市场上发现的罐装液体果汁样品,因为使用RAD-7探测器,释放222 Rn浓度的放射性核素没有造成环境污染。估计儿童和成人通过摄入罐装液体果汁样品的年有效剂量(AED)为222 Rn。222rn单位(mBq/L)估计浓度范围为35.4 ~ 249.1,平均值为77.880.24±15.42。儿童和成人的AED值(nSv/y)分别为19.11 ~ 134.48(平均43.31±8.32)和22.67 ~ 159.55(平均51.39±9.88)。果汁样品222个氡浓度的估计结果均低于世界卫生组织和欧盟委员会向公众提供的自然限值(分别为0.5 Bq/L和1 Bq/L)。因此,饮用在伊拉克市场上出售的果汁不会危害健康。
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引用次数: 0
Neutronics Assessment of Accident-Tolerant Fuel in Advanced Power Reactor 1400 (APR1400) 先进动力反应堆1400 (APR1400)耐事故燃料的中子学评价
IF 0.4 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2020-12-16 DOI: 10.17146/aij.2020.1073
D. Hartanto, A. Alshamsi, A. AlSuwaidi, A. Bilkhair, H. A. Hukal, M. Zubair
Safety and reliability are the most desirable conditions that each nuclear power plant should improve. Since the Fukushima Daiichi accident, Accident-Tolerant Fuel (ATF) has been extensively researched to improve the performance of the nuclear fuel system. This paper presents the investigation of the ATF system from a neutronics perspective, which positively reflects on the performance of the APR-1400 nuclear power plant. Several advanced fuel candidates such as UC, U 3 Si 2 , and UN, which have better thermophysical properties than current UO 2 nuclear fuel, have been considered. Meanwhile, advanced cladding candidates such as FeCrAl, Zr-alloy with coating, and SiC which can reduce or even eliminate the oxidation rate of current Zr-alloy cladding have been adopted in this study. The Monte Carlo Serpent code, in conjunction with ENDF/B-VII.1 nuclear data library, has been used to calculate and evaluate the important neutronics parameters at the assembly level such as the fuel residence time, discharge burnup, kinetics parameters, pin power distribution, temperature reactivity feedbacks, and fissile evolution. The advanced fuels show better neutronics performance than the current UO 2 fuel. In addition, SiC provides optimum neutronic performance as cladding.
安全性和可靠性是每个核电站最需要改进的条件。自福岛第一核电站事故以来,为了提高核燃料系统的性能,人们对容错燃料进行了广泛的研究。本文从中子学的角度对ATF系统进行了研究,这对APR-1400核电站的性能有积极的影响。研究人员考虑了几种先进的候选燃料,如UC、u3si 2和UN,它们比目前的UO 2核燃料具有更好的热物理性能。同时,本研究采用了FeCrAl、有涂层的zr合金、SiC等先进的包层候选材料,这些材料可以降低甚至消除当前zr合金包层的氧化速率。蒙特卡洛蛇代码,连同ENDF/B-VII。1核数据库,用于计算和评估装配级的重要中子参数,如燃料停留时间、放电燃耗、动力学参数、引脚功率分布、温度反应性反馈和裂变演化。该新型燃料的中子电子学性能优于现有的UO 2燃料。此外,SiC作为包层提供了最佳的中子性能。
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引用次数: 4
Finite-Difference Time-Domain Simulations of Radon Transport in Porous Media 多孔介质中氡输运的时域有限差分模拟
IF 0.4 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2020-12-15 DOI: 10.17146/aij.2020.902
A. Tayebi, H. Bezzout, M. El Maghraoui, H. Faylali
In this work, an efficient algorithm, using a finite-difference time-domain (FDTD) technique, is proposed for modeling the variation of radon concentration as a function of soil structure parameters and vice versa. The development of the FDTD model is based on the simultaneous resolution of the radon transport equation in a porous, homogeneous medium, namely the soil. This equation describes the concentration of radon per pore volume unit. The numerical results are compared with those of the literature or with the theoretical ones.
在这项工作中,提出了一种使用时域有限差分(FDTD)技术的有效算法,用于建模氡浓度随土壤结构参数的变化,反之亦然。FDTD模型的开发是基于对多孔均匀介质(即土壤)中氡输运方程的同时求解。这个方程描述了每个孔隙体积单位的氡浓度。将数值结果与文献或理论结果进行了比较。
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引用次数: 1
Molecular and in silico Study of TP53 Codon 72 Polymorphism (rs1042522) in a Population Exposed to High Background Radiation in Mamuju-West Sulawesi 西苏拉威西马穆朱高本底辐射人群TP53密码子72多态性(rs1042522)的分子和计算机研究
IF 0.4 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2020-12-15 DOI: 10.17146/aij.2020.984
D. Tetriana, S. Purnami, Tur Rahardjo, Wiwin Mailana, S. Nurhayati, Eko Pudjadi, S. T. Widyaningtyas, T. Ishida, D. Ramadhani
The evaluation of the tumor protein p53 (TP53) codon 72 polymorphism (rs1042522) status in a population exposed to high background radiation was performed in this study. Real-time polymerase chain reaction (Q-PCR) was used to genotype the rs1042522 polymorphism in 100 subjects from Takandeang, Salleto, and Ahu villages in Mamuju district, West Sulawesi. An in silico study was then conducted to identify the potential effects of the proline substitution associated with this polymorphism on protein stability. The in silico analysis was performed using three different computational tools, namely I-Mutant Suite, iStable, and Protein Variation Effect Analyzer (PROVEAN). Secondary and three-dimensional (3D) structural models for wild-type (WT) and variant TP53 were generated to predict potential structural changes in the protein. Electrostatic surface charge calculations were also performed to identify changes in the electrostatic charge of codon 72. The Pro72 and Arg72 frequencies among the inhabitants in the Takandeang, Salleto, and Ahu villages, who are Mandarese Austronesian-speaking ethnic group members, were 0.56 and 0.44, respectively. The in silico analysis revealed no negative effects on protein stability due to the proline substitution at codon 72, although molecular modeling showed several differences in the secondary and 3D structures of the TP53 variant compared with the structure of WT TP53. To determine the impact of the proline-coding allele on individual sensitivity to radiation exposure, we compared the micronucleus (MN) frequencies of each genotype. The results showed that the MN frequencies in individuals harboring the proline-coding allele were not significantly higher than those expressing the arginine-coding allele. In conclusion, this study revealed that the proline-coding allele for codon 72 of the TP53 gene represented the predominant genotype among Takandeang, Salleto, and Ahu villages inhabitants. The present study also demonstrated that individuals who carried the proline-coding allele were not more sensitive to radiation compared with those expressing the arginine-coding allele for codon 72 of the TP53 gene.
本研究评估了暴露于高背景辐射的人群中肿瘤蛋白p53(TP53)密码子72多态性(rs1042522)的状态。使用实时聚合酶链式反应(Q-PCR)对来自西苏拉威西省马穆朱区Takandeang、Salleto和Ahu村的100名受试者的rs1042522多态性进行基因分型。然后进行了一项计算机研究,以确定与这种多态性相关的脯氨酸取代对蛋白质稳定性的潜在影响。使用三种不同的计算工具进行计算机分析,即I-突变体套件、iStable和蛋白质变异效应分析仪(PROVEAN)。生成野生型(WT)和变体TP53的二级和三维(3D)结构模型,以预测蛋白质的潜在结构变化。还进行了静电表面电荷计算,以确定密码子72的静电电荷的变化。Takandeang村、Salleto村和Ahu村居民的Pro72和Arg72频率分别为0.56和0.44。计算机分析显示,由于密码子72处的脯氨酸取代,对蛋白质稳定性没有负面影响,尽管分子建模显示,与WT TP53的结构相比,TP53变体的二级和3D结构存在一些差异。为了确定脯氨酸编码等位基因对个体辐射暴露敏感性的影响,我们比较了每个基因型的微核(MN)频率。结果表明,携带脯氨酸编码等位基因的个体的MN频率并不显著高于表达精氨酸编码等位蛋白的个体。总之,本研究表明,TP53基因第72密码子的脯氨酸编码等位基因代表了Takandeang、Salleto和Ahu村居民的主要基因型。本研究还表明,与那些表达TP53基因密码子72的精氨酸编码等位基因的人相比,携带脯氨酸编码等位蛋白的人对辐射并不更敏感。
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引用次数: 0
Reactivity Initiated Transient Response of TRIGA with the Progress of Core Burnt 随着堆芯燃烧的进展,TRIGA反应性引发的瞬态响应
IF 0.4 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2020-12-14 DOI: 10.17146/aij.2020.983
F. Haque, N. Badrun
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引用次数: 0
Calculation of Energy Levels and Reduced Electric Quadrupole Transition Probability for 22F Isotope Using Oxbash Code 利用Oxbash代码计算22F同位素的能级和降电四极跃迁概率
IF 0.4 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2020-12-07 DOI: 10.17146/aij.2020.1022
A. K. Hasan, B. A. Zayed
A study on the calculation of energy levels and reduced electric quadrupole transition probability for fluorine-22 isotope using Oxbash Code has been carried out. The shell model and OXBASH was used to calculate the energy levels and probability of quadratic transition B(E2) of the 22 F isotope in the SD region through PW, CWH active interactions. A comparison was made between the calculation results and the experimental data. The comparison shows considerable consistency with the experimental results. The total angular momentum of the ground level 4 + 1 was confirmed when comparing with the experimental values. A significant consistency was obtained for the calculated energy values MeV (1.734, 2.387, 2.946) with the available experimental values of the same angular momentum (1 + 1 ,12+,4 + 2 ). It can be concluded that the reduced transition probabilities B(E2) can be calculated using the PW, CWH reactions and OXBASH code.
用Oxbash程序计算了氟-22同位素的能级和还原电四极跃迁几率。利用壳层模型和OXBASH计算了SD区22F同位素通过PW、CWH活性相互作用发生二次跃迁B(E2)的能级和概率。并将计算结果与实验数据进行了比较。比较结果与实验结果相当一致。当与实验值比较时,确认了地面4+1的总角动量。计算的能量值MeV(1.734,2.387,2.946)与相同角动量的可用实验值(1+1,12+,4+2)具有显著的一致性。可以得出结论,可以使用PW、CWH反应和OXBASH代码来计算减少的跃迁概率B(E2)。
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引用次数: 1
Natural Radionuclides Determination and Radiological Hazard Assessments in Soil from Tual and Kei Islands, Indonesia 印度尼西亚图尔岛和基岛土壤中天然放射性核素的测定和放射性危害评估
IF 0.4 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2020-08-21 DOI: 10.17146/aij.2020.995
S. Syarbaini, K. Kusdiana, M. Wiyono, D. Iskandar
Natural radionuclides 226 Ra, 232 Th and 40 K in soil are the primary component of the background exposure sources of the population. Study of the external exposure due to gamma-ray radiation of natural radionuclides is important because this may contribute significantly to the total annual individual dose. The purpose of this study is to investigate the natural radionuclides in soils collected from Tual and Kei islands and assess the radiological hazard due to natural radionuclides contents in soil. The soil samples were analyzed for natural radionuclides 226 Ra, 232 Th and 40 K using gamma ray spectrometry. Radiological hazard parameters were estimated from the activity concentration of these radionuclides in order to assess health implication of exposure of the general public. The activity concentrations of 226 Ra, 232 Th and 40 K in soil samples varied from 7.50 Bq kg -1 to 6326 Bq kg -1 , 0.99 Bq kg -1 to 157 Bq kg -1 , 2.97 kg -1 to 98.91 Bq kg -1 with the average value of 2162 Bq kg -1 ; 69.68 Bq kg -1 and 30.74 Bq kg -1 , respectively. The absorbed dose rates due to the presence of 226 Ra, 232 Th and 40 K, in soil samples in the studied area vary between the range of 4.88 nGy h -1 and 3018.80 nGy h -1 with the average value of 1042 nGy h -1 . The corresponding outdoor annual effective doses ranged between 0.01 mSv y -1 and 3.70 mSv y -1 with the average value of 1.28 mSv y -1 . Radium equivalent activities are calculated to be in the range of 10.42 Bq kg -1  - 6553.03 Bq kg -1 with the average value of 2264 Bq kg -1 . The external and internal hazard indexes vary from 0.03 to 17.71 with the average value of 6.12 and 0.05 to 34.81 with the average value of 11.96, respectively. All calculated average radiological hazard indices were higher than the limits recommended for individual members of the public.
土壤中的天然放射性核素226 Ra、232 Th和40 K是人群背景暴露源的主要成分。研究自然放射性核素的伽马射线辐射引起的外部暴露很重要,因为这可能对年度个人总剂量有很大贡献。本研究的目的是调查从Tual岛和Kei岛采集的土壤中的天然放射性核素,并评估土壤中天然放射性核素含量造成的放射性危害。使用伽马射线光谱法分析土壤样品中的天然放射性核素226 Ra、232 Th和40 K。根据这些放射性核素的活动浓度估计辐射危害参数,以评估公众暴露对健康的影响。土壤样品中226 Ra、232 Th和40 K的活性浓度在7.50 Bq kg-1至6326 Bq kg-1、0.99 Bq kg–1至157 Bq kg-1、2.97 kg-1至98.91 Bq kg—1之间,平均值为2162 Bq kg-1;分别为69.68 Bq kg-1和30.74 Bq kg-1。研究区域土壤样品中226 Ra、232 Th和40 K的吸收剂量率在4.88 nGy h-1和3018.80 nGy h-1之间变化,平均值为1042 nGy h-1。相应的室外年有效剂量在0.01mSv y-1和3.70mSv y-1之间,平均值为1.28mSv y-1。经计算,镭当量活度在10.42 Bq kg-1-6553.03 Bq kg-1之间,平均值为2264 Bq kg–1。外部和内部危险指数分别为0.03至17.71,平均值6.12和0.05至34.81,平均值11.96。所有计算出的平均放射性危害指数均高于建议公众个人的限值。
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引用次数: 1
Construction and Evaluation of a Multipurpose Performance Check Phantom for Computed Tomography 计算机断层扫描多功能性能检查模型的构建与评价
IF 0.4 Q4 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2020-08-07 DOI: 10.17146/aij.2020.1004
L. E. Lubis, I. Hariyati, D. Ryangga, I. Mu’minah, T. Mart, D. Soejoko
The use of computed tomography (CT) has become a common practice in medical diagnosis in Indonesia. Its number, however, is not matched by the availability of dedicated-performance-check phantoms. This paper aims to describe the design, construction, and evaluation of an in-house phantom for CT performance check that accommodates both radiation dose measurement and image quality performance checks. The phantom is designed as laser-cut polymethyl methacrylate (PMMA) slabs glued together to form a standard cylindrical shape, with spaces to place dose measurement and image quality modules. In this paper, measurement results on both aspects are discussed and compared with standard phantoms and other works. For dose measurement, the constructed phantom exhibited the greatest absolute discrepancy against the reference standard phantom of 8.89 %. Measurement of the CT number linearity and modulation transfer function (MTF) yielded, at most, 7.51 % and 5.07 % discrepancies against Catphan 604, respectively. Meanwhile, although found to be more linear in the phantom-based contrast linearity test, the use of the in-house phantom for clinical image contrast threshold determination requires further study. For noise power spectrum (NPS) measurement, accurate results were obtained within a limited range of spatial frequency .
在印度尼西亚,使用计算机断层扫描(CT)已成为医学诊断的一种常见做法。然而,它的数量与专用性能检查幻像的可用性不匹配。本文旨在描述一种用于CT性能检查的内部体模的设计、构造和评估,该体模可同时进行辐射剂量测量和图像质量性能检查。该模型被设计为激光切割的聚甲基丙烯酸甲酯(PMMA)板,粘合在一起形成标准的圆柱形,并有空间放置剂量测量和图像质量模块。本文讨论了这两方面的测量结果,并与标准体模和其他工作进行了比较。对于剂量测量,构建的体模与参考标准体模的绝对差异最大,为8.89%。CT数线性和调制传递函数(MTF)的测量与Catphan 604的差异最多分别为7.51%和5.07%。同时,尽管在基于体模的对比度线性测试中发现更具线性,但使用内部体模确定临床图像对比度阈值需要进一步研究。对于噪声功率谱(NPS)测量,在有限的空间频率范围内获得了准确的结果。
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引用次数: 3
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Atom Indonesia
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