Removal of heavy metals from industrial effluents is one of the most important in environmental research. This research was done to investigate the adsorption effect of multiwall carbon nanotubes (MWNTs) and nano Zn-oxide on decreasing chromium (Cr) and cadmium (Cd) concentration in wheat inoculated with Piriformospora indica (P.indica) that irrigated with wastewater of plating industry. Treatments were consist of applying MWCNs (0 and 0.5 % (W/W)) and nano Zn-oxide (0 and 1.5 % (W/W)) in the soil irrigated with the wastewater of plating industry under wheat inoculated with P.indica. This research was done as a factorial experiment in the layout of completely randomized block design in three replication After 90 days, plants were harvested and plant Cd and Cr were measured using atomic absorption spectroscopy. Using MWCNs had significant effect on increasing cation exchangeable capacity of soil. Applying 0.5 % (W/W) MWCNs in the soil irrigated with waste water significantly decreased the soil Cd concentration by 11.7%, while the plant biomass was increased by 13.4%. In addition, applying 1.5 % (W/W) nano Zn-oxide significantly decreased the negative effect of heavy metal toxicity that can be related to the role of nano Zn-oxide on increasing soil sorption properties. However, the interaction effect of Zn and Cd cannot be ignored. The results of this study showed that applying MWCNs and nano Zn-oxide has a significant effect on decreasing phytoremediation efficiency in soil irrigated with wastewater of plating industries. However, the type and the amount of heavy metals in wastewater cannot be ignored.
{"title":"Effect of Organic Nano-Materials on Heavy Metals Concentration of Wheat Plants Inoculated With Piriformospora indica Fungus and Irrigated With Wastewater of Plating Industry","authors":"A. Baghaie","doi":"10.34172/AJEHE.2020.04","DOIUrl":"https://doi.org/10.34172/AJEHE.2020.04","url":null,"abstract":"Removal of heavy metals from industrial effluents is one of the most important in environmental research. This research was done to investigate the adsorption effect of multiwall carbon nanotubes (MWNTs) and nano Zn-oxide on decreasing chromium (Cr) and cadmium (Cd) concentration in wheat inoculated with Piriformospora indica (P.indica) that irrigated with wastewater of plating industry. Treatments were consist of applying MWCNs (0 and 0.5 % (W/W)) and nano Zn-oxide (0 and 1.5 % (W/W)) in the soil irrigated with the wastewater of plating industry under wheat inoculated with P.indica. This research was done as a factorial experiment in the layout of completely randomized block design in three replication After 90 days, plants were harvested and plant Cd and Cr were measured using atomic absorption spectroscopy. Using MWCNs had significant effect on increasing cation exchangeable capacity of soil. Applying 0.5 % (W/W) MWCNs in the soil irrigated with waste water significantly decreased the soil Cd concentration by 11.7%, while the plant biomass was increased by 13.4%. In addition, applying 1.5 % (W/W) nano Zn-oxide significantly decreased the negative effect of heavy metal toxicity that can be related to the role of nano Zn-oxide on increasing soil sorption properties. However, the interaction effect of Zn and Cd cannot be ignored. The results of this study showed that applying MWCNs and nano Zn-oxide has a significant effect on decreasing phytoremediation efficiency in soil irrigated with wastewater of plating industries. However, the type and the amount of heavy metals in wastewater cannot be ignored.","PeriodicalId":8672,"journal":{"name":"Avicenna Journal of Environmental Health Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47713612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Samarghandi, K. Godini, G. Azarian, A. Ehsani, Hassan Zolghadrnasab
Since large amounts of agricultural wastes are produced in Iran and these wastes have lignocellulosic nature, the current study was performed to survey the adsorption performance of methylene blue dye from aqueous solutions by means of raw and modified cantaloupe peel. The adsorbents used were characterized using techniques like scanning electron microscope (SEM), as well as Fourier transform infrared spectroscopy (FTIR). In this study, the effects of a few key variables including pH, reaction time, dye concentration, adsorbent dosage and temperature on the adsorption performance were investigated. Optimum values were attained at 0.04 and 0.08 g doses of modified and raw cantaloupe peel, pH of 7 after mixing for 120 and 90 minutes for raw and modified cantaloupe peel, respectively. The equilibrium information was fitted to the Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich equations and the respective data for all models were tested. An increase in adsorbent dose and temperature caused the efficiency to rise. The mechanism and rate of adsorption were ascertained by analyzing the experimental data at various contact times according to traditional kinetic equations: pseudo-first-order and second order, Elovich, and intra-particle diffusion. The findings illustrated that the data accorded closely with the pseudo-second-order model. Moreover, it was found that these wastes can be applied to remove environmental pollutants, particularly methylene blue dye.
{"title":"Adsorptive Removal of Methylene Blue in Aqueous Solutions Through Raw and Modified Cantaloupe Peel Wastes: Kinetic and Isotherm Study","authors":"M. Samarghandi, K. Godini, G. Azarian, A. Ehsani, Hassan Zolghadrnasab","doi":"10.34172/AJEHE.2020.06","DOIUrl":"https://doi.org/10.34172/AJEHE.2020.06","url":null,"abstract":"Since large amounts of agricultural wastes are produced in Iran and these wastes have lignocellulosic nature, the current study was performed to survey the adsorption performance of methylene blue dye from aqueous solutions by means of raw and modified cantaloupe peel. The adsorbents used were characterized using techniques like scanning electron microscope (SEM), as well as Fourier transform infrared spectroscopy (FTIR). In this study, the effects of a few key variables including pH, reaction time, dye concentration, adsorbent dosage and temperature on the adsorption performance were investigated. Optimum values were attained at 0.04 and 0.08 g doses of modified and raw cantaloupe peel, pH of 7 after mixing for 120 and 90 minutes for raw and modified cantaloupe peel, respectively. The equilibrium information was fitted to the Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich equations and the respective data for all models were tested. An increase in adsorbent dose and temperature caused the efficiency to rise. The mechanism and rate of adsorption were ascertained by analyzing the experimental data at various contact times according to traditional kinetic equations: pseudo-first-order and second order, Elovich, and intra-particle diffusion. The findings illustrated that the data accorded closely with the pseudo-second-order model. Moreover, it was found that these wastes can be applied to remove environmental pollutants, particularly methylene blue dye.","PeriodicalId":8672,"journal":{"name":"Avicenna Journal of Environmental Health Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49449935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
necessary to consider appropriate health measures against this virus. According to WHO reports, the COVID-19 outbreak is likely to last between 18 and 24 months. In this situation, long-term use of chemical disinfectants, especially chlorinated substances and detergents, in addition to causing harmful effects on human health, can pose a threat to the environment, water, and soil resources. Due to their high efficiency, availability, and affordability, the chlorinated compounds are commonly used as the most important disinfectant in preventing the spread of infectious disease. These compounds have a highly toxic effect on the airways and cause short-term and long-term pulmonary complications. Acute and severe exposure to chlorine gas, especially indoors, can lead to acute and severe shortness of breath, airway spasm, wheezing, and pulmonary embolism. These complications are so severe in some cases that can lead to hospitalization. Long-term complications are also observed such as chronic asthma which may require long-term treatment (5,6). Hence, it seems necessary to provide an effective protocol for disinfection for a long time, which poses a low risk to the environment and to human health. In this regard, the use of disinfectants effective against the SARS-Cov-2 virus with less toxic effects can be a good alternative. Accordingly, it is necessary to pay attention to the following points: • Engineering controls should be considered for decreasing the adverse health effects of frequent use of disinfectants including ventilation and isolation. Therefore, proper ventilation of indoor air in hospitals can prevent overexposure of health care staff and patients with the used disinfectants. Moreover, isolation can be an effective method in engineering control, in which disinfection can mainly be performed in a shift when fewer health care stuff are exposed (7). Received 9 June, 2020; Revised 18 June, 2020; Accepted 25 June, 2020
{"title":"Health Impacts of Long-term Exposure to Disinfectants During SARS-Cov-2 Pandemic","authors":"Ali Reza Rahamani, G. Azarian, A. Poormohammadi","doi":"10.34172/AJEHE.2020.08","DOIUrl":"https://doi.org/10.34172/AJEHE.2020.08","url":null,"abstract":"necessary to consider appropriate health measures against this virus. According to WHO reports, the COVID-19 outbreak is likely to last between 18 and 24 months. In this situation, long-term use of chemical disinfectants, especially chlorinated substances and detergents, in addition to causing harmful effects on human health, can pose a threat to the environment, water, and soil resources. Due to their high efficiency, availability, and affordability, the chlorinated compounds are commonly used as the most important disinfectant in preventing the spread of infectious disease. These compounds have a highly toxic effect on the airways and cause short-term and long-term pulmonary complications. Acute and severe exposure to chlorine gas, especially indoors, can lead to acute and severe shortness of breath, airway spasm, wheezing, and pulmonary embolism. These complications are so severe in some cases that can lead to hospitalization. Long-term complications are also observed such as chronic asthma which may require long-term treatment (5,6). Hence, it seems necessary to provide an effective protocol for disinfection for a long time, which poses a low risk to the environment and to human health. In this regard, the use of disinfectants effective against the SARS-Cov-2 virus with less toxic effects can be a good alternative. Accordingly, it is necessary to pay attention to the following points: • Engineering controls should be considered for decreasing the adverse health effects of frequent use of disinfectants including ventilation and isolation. Therefore, proper ventilation of indoor air in hospitals can prevent overexposure of health care staff and patients with the used disinfectants. Moreover, isolation can be an effective method in engineering control, in which disinfection can mainly be performed in a shift when fewer health care stuff are exposed (7). Received 9 June, 2020; Revised 18 June, 2020; Accepted 25 June, 2020","PeriodicalId":8672,"journal":{"name":"Avicenna Journal of Environmental Health Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44610731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Farahnaz Kakavand, A. Hedayati, Ali Jafar Nodeh, S. Maddah, Maryam Rezaei Shadegan
The wide use of nano-sized metallic materials could result in the release of these particles into the environment. In addition, due to the dissolution of these nano-materials, some of the adverse effects could result from the dissolved metals. On the other hand, dietary supplements play a key role in improving the immunity of consumers; hence, the use of immune stimulants such as mushroom seems to be very necessary. In this study, the dietary effect of Pleurotus ostreatus mushroom was investigated on serum immunity and liver histopathological indices of Oreochromis niloticus exposed to silver nanoparticles (AgNPs). Serum total protein level enhanced with increasing prebiotic concentration. Serum immunoglobulin and albumin levels increased in the group treated with Pleurotus ostreatus. The amount of these indices significantly increased at the concentration of 0.2 mg/kg; however, glucose value decreased in both of the experimental groups. Serum ALT and ALP levels significantly reduced in the combined treatment group (AgNPs and mushroom) at the concentration of 0.2 mg/kg, in contrast with the control group. In the combination treatment group (AgNPs and mushroom), the serum AST level significantly reduced at concentrations of 0.1 mg/kg and 0.2 mg/kg; however, it increased at the concentration of 0.05 mg/kg compared with the control group, indicating that immunological indices could improve due to the combined use of AgNPs and mushroom. The overall conclusion of this study shows that the use of mushroom at 0.2 mg/kg in combination with AgNPs could partially improve the effect of AgNPs on tilapia.
{"title":"Toxicological Effects of Silver Nanoparticles on Nile Tilapia (Oreochromis niloticus)","authors":"Farahnaz Kakavand, A. Hedayati, Ali Jafar Nodeh, S. Maddah, Maryam Rezaei Shadegan","doi":"10.34172/AJEHE.2020.01","DOIUrl":"https://doi.org/10.34172/AJEHE.2020.01","url":null,"abstract":"The wide use of nano-sized metallic materials could result in the release of these particles into the environment. In addition, due to the dissolution of these nano-materials, some of the adverse effects could result from the dissolved metals. On the other hand, dietary supplements play a key role in improving the immunity of consumers; hence, the use of immune stimulants such as mushroom seems to be very necessary. In this study, the dietary effect of Pleurotus ostreatus mushroom was investigated on serum immunity and liver histopathological indices of Oreochromis niloticus exposed to silver nanoparticles (AgNPs). Serum total protein level enhanced with increasing prebiotic concentration. Serum immunoglobulin and albumin levels increased in the group treated with Pleurotus ostreatus. The amount of these indices significantly increased at the concentration of 0.2 mg/kg; however, glucose value decreased in both of the experimental groups. Serum ALT and ALP levels significantly reduced in the combined treatment group (AgNPs and mushroom) at the concentration of 0.2 mg/kg, in contrast with the control group. In the combination treatment group (AgNPs and mushroom), the serum AST level significantly reduced at concentrations of 0.1 mg/kg and 0.2 mg/kg; however, it increased at the concentration of 0.05 mg/kg compared with the control group, indicating that immunological indices could improve due to the combined use of AgNPs and mushroom. The overall conclusion of this study shows that the use of mushroom at 0.2 mg/kg in combination with AgNPs could partially improve the effect of AgNPs on tilapia.","PeriodicalId":8672,"journal":{"name":"Avicenna Journal of Environmental Health Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49150749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Some of the microorganisms such as Escherichia coli have the ability to migrate to areas in which the intensity of magnetic fields (MFs) is higher, which is called magnetotactic properties. Magnetotaxis is a process implemented by a group of gram-negative bacteria that involves orienting and coordinating movement in response to magnetic fields. This study was conducted to investigate these properties of Escherichia coli in laboratory conditions. By means of coated wires (30 rounds) placed in two parts of the reactor (with five zones and a volume of 250 mL) and direct current (DC), an intensity of 0.18 mT for 42 minutes has been prepared. The most probable number of E. coli per 100 mL (MPN/100 mL) in each zone of the reactor, before and after exposure, was estimated. According to the results of this study, E. coli has magnetotactic properties, and the mean density of these bacteria in higher MFs (0.18 mT) is higher compared to the other zones in the reactor.
{"title":"Survey of Magneto-tactic Properties of Escherichia coli Under Static Magnetic Fields","authors":"G. Asgari, Ramin Khoshniyat, M. Moradi Golrokhi","doi":"10.34172/AJEHE.2020.03","DOIUrl":"https://doi.org/10.34172/AJEHE.2020.03","url":null,"abstract":"Some of the microorganisms such as Escherichia coli have the ability to migrate to areas in which the intensity of magnetic fields (MFs) is higher, which is called magnetotactic properties. Magnetotaxis is a process implemented by a group of gram-negative bacteria that involves orienting and coordinating movement in response to magnetic fields. This study was conducted to investigate these properties of Escherichia coli in laboratory conditions. By means of coated wires (30 rounds) placed in two parts of the reactor (with five zones and a volume of 250 mL) and direct current (DC), an intensity of 0.18 mT for 42 minutes has been prepared. The most probable number of E. coli per 100 mL (MPN/100 mL) in each zone of the reactor, before and after exposure, was estimated. According to the results of this study, E. coli has magnetotactic properties, and the mean density of these bacteria in higher MFs (0.18 mT) is higher compared to the other zones in the reactor.","PeriodicalId":8672,"journal":{"name":"Avicenna Journal of Environmental Health Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69814204","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Ravanbakhsh, Y. Tahmasebi Birgani, M. Dastoorpoor, K. Ahmadi Angali
Discriminant analysis (DA) and principal component analysis (PCA), as multivariate statistical techniques, are used to interpret large complex water quality data and assess their temporal and spatial variation in the basin of the Zohreh river. In this study, data sets of 16 water quality parameters collected from 1966 to 2013) in 4 stations (1554 observations for each parameter) were analyzed. PCA for data sets of Kheirabad, Poleflour, Chambostan and Dehmolla stations resulted in 4, 4, 4, and 3 latent factors accounting for 88.985%, 93.828%, 88.648%, and 88.68% of the total variance in water quality parameters, respectively. It is indicated that total dissolved solids (TDS), electrical conductivity (EC), chlorides (Cl−), sodium (Na), sodium absorption ratio (SAR), and %Na were responsible for water quality variations which are mainly related to natural and anthropogenic pollution sources including climate effects, gypsum, and salt crystals in the supratidal of Zohreh river delta, fault zones of Chamshir I and II, drainage of sugarcane fields, and domestic and industrial wastewaters discharge into the river. DA reduced the data set to only seven parameters (discharge, temperature, electrical conductivity, HCO3-, Cl-, %Na, and T-Hardness), affording more than 58.5% correct assignations in temporal evaluations and describing responsible parameters for large variations in the quality of the Zohreh river.
{"title":"Evaluation of Temporal and Spatial Variations of Water Quality Parameters in Zohreh River, Iran","authors":"M. Ravanbakhsh, Y. Tahmasebi Birgani, M. Dastoorpoor, K. Ahmadi Angali","doi":"10.34172/ajehe.2019.10","DOIUrl":"https://doi.org/10.34172/ajehe.2019.10","url":null,"abstract":"Discriminant analysis (DA) and principal component analysis (PCA), as multivariate statistical techniques, are used to interpret large complex water quality data and assess their temporal and spatial variation in the basin of the Zohreh river. In this study, data sets of 16 water quality parameters collected from 1966 to 2013) in 4 stations (1554 observations for each parameter) were analyzed. PCA for data sets of Kheirabad, Poleflour, Chambostan and Dehmolla stations resulted in 4, 4, 4, and 3 latent factors accounting for 88.985%, 93.828%, 88.648%, and 88.68% of the total variance in water quality parameters, respectively. It is indicated that total dissolved solids (TDS), electrical conductivity (EC), chlorides (Cl−), sodium (Na), sodium absorption ratio (SAR), and %Na were responsible for water quality variations which are mainly related to natural and anthropogenic pollution sources including climate effects, gypsum, and salt crystals in the supratidal of Zohreh river delta, fault zones of Chamshir I and II, drainage of sugarcane fields, and domestic and industrial wastewaters discharge into the river. DA reduced the data set to only seven parameters (discharge, temperature, electrical conductivity, HCO3-, Cl-, %Na, and T-Hardness), affording more than 58.5% correct assignations in temporal evaluations and describing responsible parameters for large variations in the quality of the Zohreh river.","PeriodicalId":8672,"journal":{"name":"Avicenna Journal of Environmental Health Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41442178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Grape is a strategic product in the county of Malayer. Despite the great importance and existence of polluted resources in the vicinity of vineyards in Malayer, there are few studies conducted in this regard. To evaluate the pollution level of toxic elements in these vineyards, 20 sampling stations were selected randomly and samples of garden soil and leaves of grapevine species were collected. After the acidic digestion of the samples, the concentrations of the heavy metals were measured using atomic absorption spectrometer. Then, the indices of contamination factor (Cf), geoaccumulation index (Igeo), biological accumulation coefficient (BAC), and ecological risk index (RI) were calculated. According to the results obtained for Igeo and Cf indices, the soil in the study region was moderately contaminated with copper. However, the ecological risk index and BAC of the studied region were low. To investigate the spatial distribution of copper in the studied region, the spatial distribution map was prepared. To locate the source of copper contamination and investigate the effect of various land uses on the amount of contamination, land use map (LUM) of vineyards was generated. To this end, images were downloaded from Landsat Satellite, and after the exertion of various corrections on the images based on the supervised classification method, the LUM with agricultural, residential, vineyard, brick furnace and pasture classes was prepared. The comparison of the LUM and the copper contamination map illustrated that the copper contamination was higher in the places with urban and adobe furnace land-use types.
{"title":"Ecological Risk Assessment, Interpolation, and Pollution Source Identification of Toxic Elements in Soils and Leaves of the Vineyard of Malayer County","authors":"Mohamad Parsi Mehr, S. Mortazavi","doi":"10.34172/ajehe.2019.11","DOIUrl":"https://doi.org/10.34172/ajehe.2019.11","url":null,"abstract":"Grape is a strategic product in the county of Malayer. Despite the great importance and existence of polluted resources in the vicinity of vineyards in Malayer, there are few studies conducted in this regard. To evaluate the pollution level of toxic elements in these vineyards, 20 sampling stations were selected randomly and samples of garden soil and leaves of grapevine species were collected. After the acidic digestion of the samples, the concentrations of the heavy metals were measured using atomic absorption spectrometer. Then, the indices of contamination factor (Cf), geoaccumulation index (Igeo), biological accumulation coefficient (BAC), and ecological risk index (RI) were calculated. According to the results obtained for Igeo and Cf indices, the soil in the study region was moderately contaminated with copper. However, the ecological risk index and BAC of the studied region were low. To investigate the spatial distribution of copper in the studied region, the spatial distribution map was prepared. To locate the source of copper contamination and investigate the effect of various land uses on the amount of contamination, land use map (LUM) of vineyards was generated. To this end, images were downloaded from Landsat Satellite, and after the exertion of various corrections on the images based on the supervised classification method, the LUM with agricultural, residential, vineyard, brick furnace and pasture classes was prepared. The comparison of the LUM and the copper contamination map illustrated that the copper contamination was higher in the places with urban and adobe furnace land-use types.","PeriodicalId":8672,"journal":{"name":"Avicenna Journal of Environmental Health Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42624627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Developing an adsorbent with natural components is one of the effective methods to reduce the amount of wastewater pollutants. Wastewater reuse can improve the quality of water prior to entering the natural environment. The aim of this study was to evaluate the efficiency of chitosan nano-composite and activated carbon adsorbent in the removal of nitrite, phosphate, and ammonia pollutants from fish farms of Aq-Qala. To prepare the adsorbents, the shrimp shells were converted to nano-chitosan. The date palm kernel was prepared and activated with oxalic acid in pyrolysis furnace by injecting nitrogen gas into activated carbon, then, the nano-composite was prepared from nanochitosan and activated carbon. A field-laboratory study was conducted during the winter of 2018, and then, batches of synthesized nano-composite were investigated and the effects of pH, initial effluent concentration, and adsorption time were investigated. The experiments were performed in the pH range of 5-8, effluent concentration of 25-100 mg/L, and contact time of 15-90 minutes. The results showed that at optimum conditions (pH of 7, effluent concentration of 50 mg/L, and contact time of 60 minutes), the highest removal percentage and adsorption capacity for nitrite, phosphate, and ammonia contaminants were 99.98%, 99.77%, and 65.65%, and 6.65, 6.14, and 7.32 mg/g , respectively. Due to the high removal percentage (99.98%) of the chitosan and activated carbon nano-composite, the adsorbent was highly capable of removing pollutants (nitrite, phosphate, and ammonia).
{"title":"Application of Chitosan and Activated Carbon Nano-composite in Removal of Nitrite, Phosphate, and Ammonia From Aquaculture Wastewater","authors":"H. Rezaei, S. Rastegar, S. Naseri","doi":"10.34172/ajehe.2019.14","DOIUrl":"https://doi.org/10.34172/ajehe.2019.14","url":null,"abstract":"Developing an adsorbent with natural components is one of the effective methods to reduce the amount of wastewater pollutants. Wastewater reuse can improve the quality of water prior to entering the natural environment. The aim of this study was to evaluate the efficiency of chitosan nano-composite and activated carbon adsorbent in the removal of nitrite, phosphate, and ammonia pollutants from fish farms of Aq-Qala. To prepare the adsorbents, the shrimp shells were converted to nano-chitosan. The date palm kernel was prepared and activated with oxalic acid in pyrolysis furnace by injecting nitrogen gas into activated carbon, then, the nano-composite was prepared from nanochitosan and activated carbon. A field-laboratory study was conducted during the winter of 2018, and then, batches of synthesized nano-composite were investigated and the effects of pH, initial effluent concentration, and adsorption time were investigated. The experiments were performed in the pH range of 5-8, effluent concentration of 25-100 mg/L, and contact time of 15-90 minutes. The results showed that at optimum conditions (pH of 7, effluent concentration of 50 mg/L, and contact time of 60 minutes), the highest removal percentage and adsorption capacity for nitrite, phosphate, and ammonia contaminants were 99.98%, 99.77%, and 65.65%, and 6.65, 6.14, and 7.32 mg/g , respectively. Due to the high removal percentage (99.98%) of the chitosan and activated carbon nano-composite, the adsorbent was highly capable of removing pollutants (nitrite, phosphate, and ammonia).","PeriodicalId":8672,"journal":{"name":"Avicenna Journal of Environmental Health Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48053084","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Maryam Bayat Varkeshi, K. Godini, Mohamad Parsimehr, Maryam Vafaee
A reliable model for any wastewater treatment plant (WWTP) is essential to predict its performance and form a basis for controlling the operation of the process. This would minimize the operation costs and assess the stability of environmental balance. This study applied artificial neural network-genetic algorithm (ANN-GA) and co-active neuro-fuzzy logic inference system (CANFIS) in comparison with ANN for predicting the performance of WWTP. The result indicated that the GA produces more accurate results than fuzzy logic technique. It was found that GA components increased the ANN ability in predicting WWTP performance. The normalized root mean square error (NRMSE) for ANN-GA in predicting chemical oxygen demand (COD), total suspended solids (TSS) and biochemical oxygen demand (BOD) were 0.15, 0.19 and 0.15, respectively. The corresponding correlation coefficients were 0.891, 0.930 and 0.890, respectively. Comparing these results with other studies showed that despite the slightly lower performance of the current model, its requirement for a lower number of input parameters can save the extra cost of sampling.
{"title":"Predicting the Performance of Gorgan Wastewater Treatment Plant Using ANN-GA, CANFIS, and ANN Models","authors":"Maryam Bayat Varkeshi, K. Godini, Mohamad Parsimehr, Maryam Vafaee","doi":"10.34172/ajehe.2019.12","DOIUrl":"https://doi.org/10.34172/ajehe.2019.12","url":null,"abstract":"A reliable model for any wastewater treatment plant (WWTP) is essential to predict its performance and form a basis for controlling the operation of the process. This would minimize the operation costs and assess the stability of environmental balance. This study applied artificial neural network-genetic algorithm (ANN-GA) and co-active neuro-fuzzy logic inference system (CANFIS) in comparison with ANN for predicting the performance of WWTP. The result indicated that the GA produces more accurate results than fuzzy logic technique. It was found that GA components increased the ANN ability in predicting WWTP performance. The normalized root mean square error (NRMSE) for ANN-GA in predicting chemical oxygen demand (COD), total suspended solids (TSS) and biochemical oxygen demand (BOD) were 0.15, 0.19 and 0.15, respectively. The corresponding correlation coefficients were 0.891, 0.930 and 0.890, respectively. Comparing these results with other studies showed that despite the slightly lower performance of the current model, its requirement for a lower number of input parameters can save the extra cost of sampling.","PeriodicalId":8672,"journal":{"name":"Avicenna Journal of Environmental Health Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48798673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Two metal-amino acid complexes, Cr(III)-alanine and Cr(III)-valine, were synthesized and characterized by IR spectroscopy, powder X-ray diffraction (XRD) analysis, magnetic susceptibility, and molar conductivity measurements. Molar conductivity measurements indicated that the composition of the metal complexes corresponds to a metal-amino acid ligand ratio of 1:3. The IR spectra indicated that the amino acids act as bidentate ligands with coordination involving the carboxyl oxygen and the nitrogen of the amino group. Magnetic susceptibility measurements revealed a six-coordinate local symmetry around the Cr(III) ions which depicted that the complexes were paramagnetic with magnetic moment values ranging from 5.10 to 6.00 BM. Powder XRD studies confirmed that the amino acid complexes were crystalline with monoclinic crystal structure. The in vitro biological activity of the investigated chromium(III) complexes with alanine and valine was tested against Bacillus subtilis, Staphylococcus aureus, Salmonella typhi, Pseudomonas aeruginosa, and Escherichia coli. All the microorganisms were standardized using 0.5 McFarland standard. The antimicrobial studies showed that the ligands were biologically active with an inhibition zone range of 10-17 mm and their metal complexes showed significantly enhanced antimicrobial sensitivity with an inhibition zone range of 12-21 mm. The standard drug showed slightly better activity with an inhibition zone range of 24-38 mm.
{"title":"Synthesis, Characterization, and Biological Evaluation of Chromium(III) Complexes of Alanine and Valine","authors":"Shuaibu Musa, S. Idris, David A. Onu, A. Suleiman","doi":"10.34172/ajehe.2019.13","DOIUrl":"https://doi.org/10.34172/ajehe.2019.13","url":null,"abstract":"Two metal-amino acid complexes, Cr(III)-alanine and Cr(III)-valine, were synthesized and characterized by IR spectroscopy, powder X-ray diffraction (XRD) analysis, magnetic susceptibility, and molar conductivity measurements. Molar conductivity measurements indicated that the composition of the metal complexes corresponds to a metal-amino acid ligand ratio of 1:3. The IR spectra indicated that the amino acids act as bidentate ligands with coordination involving the carboxyl oxygen and the nitrogen of the amino group. Magnetic susceptibility measurements revealed a six-coordinate local symmetry around the Cr(III) ions which depicted that the complexes were paramagnetic with magnetic moment values ranging from 5.10 to 6.00 BM. Powder XRD studies confirmed that the amino acid complexes were crystalline with monoclinic crystal structure. The in vitro biological activity of the investigated chromium(III) complexes with alanine and valine was tested against Bacillus subtilis, Staphylococcus aureus, Salmonella typhi, Pseudomonas aeruginosa, and Escherichia coli. All the microorganisms were standardized using 0.5 McFarland standard. The antimicrobial studies showed that the ligands were biologically active with an inhibition zone range of 10-17 mm and their metal complexes showed significantly enhanced antimicrobial sensitivity with an inhibition zone range of 12-21 mm. The standard drug showed slightly better activity with an inhibition zone range of 24-38 mm.","PeriodicalId":8672,"journal":{"name":"Avicenna Journal of Environmental Health Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47082338","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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