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A Comparison of Performance of Artificial Neural Networks for Prediction of Heavy Metals Concentration in Groundwater Resources of Toyserkan Plain 人工神经网络在Toyserkan平原地下水资源重金属浓度预测中的性能比较
Q4 Environmental Science Pub Date : 2017-06-05 DOI: 10.5812/AJEHE.11792
M. Alizamir, S. Sobhanardakani
Nowadays, about 50% the world’s population is living in dry and semi dry regions and has utilized groundwater as a source of drinking water. Therefore, forecasting of pollutant content in these regions is vital. This study was conducted to compare the performance of artificial neural networks (ANNs) for prediction of As, Zn, and Pb content in groundwater resources of Toyserkan Plain. In this study, two types of artificial neural networks (ANNs), namely multi-layer perceptron (MLP) and Radial Basis Function (RBF) approaches, were examined using the observations of As, Zn, and Pb concentrations in groundwater resources of Toyserkan plain, Western Iran. Two statistical indicators, the coefficient of determination (R2) and root mean squared error (RMSE) were employed to evaluate the performances of various models. The results indicated that the best performance could be obtained by MLP, in terms of different statistical indicators during training and validation periods.
如今,世界上约有50%的人口生活在干旱和半干旱地区,并利用地下水作为饮用水的来源。因此,预测这些地区的污染物含量至关重要。本研究比较了人工神经网络(ann)在Toyserkan平原地下水资源As、Zn、Pb含量预测中的应用效果。本文采用多层感知器(MLP)和径向基函数(RBF)两种人工神经网络(ann)方法,对伊朗西部Toyserkan平原地下水资源中As、Zn和Pb的浓度进行了研究。采用决定系数(R2)和均方根误差(RMSE)两个统计指标评价各模型的性能。结果表明,在训练期和验证期的不同统计指标上,MLP的效果最好。
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引用次数: 16
Evaluation of the Efficiency of Wastewater Treatment Plants in the Removal of Common Antibiotics from Municipal Wastewater in Hamadan, Iran 伊朗哈马丹市污水处理厂去除城市污水中常见抗生素的效率评价
Q4 Environmental Science Pub Date : 2017-05-20 DOI: 10.5812/AJEHE.10921
R. Shokoohi, A. Dargahi, Razieh Khamutian, Y. Vaziri
The presence of antibiotics in the environment, especially aquatic environments, is a major health and environmental concern.Wastewater treatment plants play an important role in the treatment of municipal and industrial wastewater and removal of contaminants.The aim of this study was to determine the concentration of prevalent antibiotics in municipal wastewater of Hamadan,Iran and to evaluate the removal efficiency of wastewater treatment plants. During 3 months (April, May, and June 2016), a total of 12 composite influent and effluent samples were collected from the wastewater treatment plants. Solid-phase extraction (SPE) was used for preparing the samples, which were then analyzed using high-performance liquid chromatography (HPLC) with UV detection.Based on the analysis of 6 antibiotics, three antibiotics, including amoxicillin, imipenem, and cefixime, were detected, and their concentrations were measured at 1.6, 10.7, and 5.8 ug/L, respectively. The removal efficiency of these antibiotics in wastewater treatment plants was 55.66%, 34.01%, and 24.33%, respectively. Due to the presence of examined antibiotics in the effluent and influent wastewater treatment plants, they might cause direct and indirect effects on human health and environment if proper measures are not taken by the authorities. Since the removal of these antibiotics from wastewater treatment plants is relatively poor, it is suggested to use advanced wastewater treatment plants to reduce antibiotics in effluent wastewater and decrease the adverse effects of these micropollutants.
抗生素在环境中的存在,特别是在水生环境中,是一个主要的健康和环境问题。污水处理厂在处理城市和工业废水以及去除污染物方面发挥着重要作用。本研究的目的是测定伊朗哈马丹市城市污水中常见抗生素的浓度,并评价污水处理厂的去除效率。在2016年4月、5月和6月3个月期间,从污水处理厂共收集了12份进水和出水复合样本。采用固相萃取法(SPE)制备样品,并用高效液相色谱法(HPLC)和紫外检测器对样品进行分析。通过对6种抗生素的分析,检测出阿莫西林、亚胺培南和头孢克肟3种抗生素,其浓度分别为1.6、10.7和5.8 ug/L。污水处理厂对这些抗生素的去除率分别为55.66%、34.01%和24.33%。由于经检查的抗生素存在于流出和流入的废水处理厂,如果当局不采取适当措施,它们可能对人类健康和环境造成直接和间接的影响。由于污水处理厂对这些抗生素的去除率相对较差,建议采用高级污水处理厂来减少出水废水中的抗生素,减少这些微污染物的不良影响。
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引用次数: 9
A Review of Groundwater Pollution Potential Threats from Municipal Solid Waste Landfill Sites: Assessing the Impact on Human Health 城市固体废物填埋场地下水污染潜在威胁评估对人类健康的影响
Q4 Environmental Science Pub Date : 2017-05-16 DOI: 10.5812/AJEHE.11525
P. Kumari, N. Gupta, A. Kaur
An attempt has been made in this paper to review various studies associated with groundwater contamination near landfill sites, basically caused by non-engineered landfills or open dumps in India and overseas, and its impact on human health. Landfill leachate contains different kinds of municipal toxic wastes as well as heavy metal, which finally percolates into the ground and joins the groundwater table. Consuming such water results in severe health hazards and may sometimes be fatal if consumed for long periods. Several studies have shown evidence on the high concentration of heavy metals in leachate as well as in nearby groundwater sources. Moreover, various studies have confirmed the fact that there is an increased threat of adverse health effects (low birth weight, birth defects, and certain types of cancers), congenital malformations in children, and higher risks for malformations of the nervous and musculoskeletal systems for skin, hair, and nails in local residents. Pregnant women and children are more vulnerable to these pollutants, and newborn children are more prone to the health risk. These findings may signify the real health risks associated with residents residing near landfill sites.
本文试图回顾与垃圾填埋场附近地下水污染相关的各种研究,这些污染主要是由印度和海外的非工程垃圾填埋场或露天垃圾场引起的,以及它对人类健康的影响。垃圾渗滤液含有不同种类的城市有毒废物和重金属,最终渗入地下并进入地下水位。饮用这种水会对健康造成严重危害,如果长期饮用,有时可能会致命。几项研究表明,渗滤液和附近地下水来源中重金属浓度较高。此外,各种研究证实,当地居民的不良健康影响(低出生体重、出生缺陷和某些类型的癌症)、儿童先天畸形以及皮肤、头发和指甲神经和肌肉骨骼系统畸形的风险增加。孕妇和儿童更容易受到这些污染物的影响,新生儿更容易受到健康风险的影响。这些发现可能表明居住在垃圾填埋场附近的居民存在真正的健康风险。
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引用次数: 10
Heavy Metal Levels and Potential Health Risk Assessment in Honey Consumed in the West of Iran 伊朗西部地区蜂蜜中重金属含量及潜在健康风险评估
Q4 Environmental Science Pub Date : 2016-12-28 DOI: 10.5812/AJEHE.7795
S. Sobhanardakani, Mona Kianpour
Since the worldwide research on content of heavy metals in honey is narrow, this study was carried out to analyze heavy metals (Cd, Cr, Ni, and Zn) in honey and assess its associated health risk in Hamadan City, Iran, in 2015. Totally, 15 freshly ripened samples of honey were analyzed for heavy metals using ICP-OES with three replications after burning to ash and digesting with dilute nitric acid. The potential health index was then calculated. The results showed that the mean levels of Cd, Cr, Ni, and Zn in the honey samples were 63.18 ± 43.39, 58.05 ± 30.32, 56.15 ± 54.32, and 684.43 ± 190.43 µg kg-1, respectively. Also, the health risk assessment showed no potential risk for children and adults in relation to the consumption of honey in the studied region. According to the results of the current study, although there is no adverse effect for the local population through the consumption of honey, due to the increased discharge of pollutants especially heavy metals into the natural environment, it is very important to assess foodstuff before release to the consumer market
由于国际上对蜂蜜中重金属含量的研究较少,本研究于2015年在伊朗哈马丹市开展了蜂蜜中重金属(Cd、Cr、Ni和Zn)的分析,并评估其相关的健康风险。用ICP-OES对15份新鲜成熟的蜂蜜样品进行了3次重复的重金属分析,这些样品经过烧成灰和稀硝酸消化。然后计算潜在健康指数。结果表明,蜂蜜样品中Cd、Cr、Ni和Zn的平均含量分别为63.18±43.39、58.05±30.32、56.15±54.32和684.43±190.43µg kg-1。此外,健康风险评估显示,在研究地区,食用蜂蜜对儿童和成人没有潜在风险。根据目前的研究结果,虽然食用蜂蜜对当地居民没有不良影响,但由于污染物特别是重金属排放到自然环境中,因此在食品进入消费市场之前进行评估非常重要
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引用次数: 21
The Efficiency of Electrocoagulation and Electroflotation Processes for Removal of Polyvinyl Acetate From Synthetic Effluent 电絮凝和电浮选法去除合成废水中聚氯乙烯的效果研究
Q4 Environmental Science Pub Date : 2016-12-27 DOI: 10.5812/AJEHE.7469
Zeinab Atashzaban, A. Seidmohammadi, D. Nematollahi, G. Azarian, Omid Heydari Shayesteh, A. Rahmani
Polyvinyl acetate (PVAc) is a type of thermoplastic resin generated by a polymerization of vinyl acetate. Effluent of this polymer is highly rich with chemical oxygen demand (COD) and total solids (TS). Due to lack of studies on the above problem, the current study aimed at obtaining a sufficient method for the effluent pre-treatment. In fact, the study discussed PVAC effluent treatment by electrocoagulation (EC) and electroflotation processes.The study considered the effect of various operating parameters such as pH and current density, initial concentration of pollutant, inter-electrode distance, electrolysis times, and types of electrode materials (iron and aluminum); COD and TS removal efficiency and optimal values of operational parameters were calculated. In the study, COD and TS reduction rates in the optimized conditions in batch flow reactor were 83% and 78%, and 80% and 72% for Fe and Al electrodes, respectively. Optimized conditions were taken as 24 mA cm -2, 20 g/L PVAC, and neutral pH in 20 minutes for Al-Al electrodes and 15 minutes for Fe-Fe electrodes, 1 cm distance between electrodes with parallel-type monopole of connection modes. According to the results, electrochemical process with batch flow tends to be a suitable pre-treatment process that is inexpensive, easily operated, and highly sufficient for effluent treatment, which contains polyvinyl acetate.
聚醋酸乙烯酯(PVAc)是一种由醋酸乙烯酯聚合而成的热塑性树脂。该聚合物出水具有丰富的化学需氧量(COD)和总固体(TS)。由于缺乏对上述问题的研究,目前的研究旨在获得一种充分的废水预处理方法。实际上,研究讨论了电絮凝(EC)和电浮选工艺处理PVAC废水。研究考虑了pH值、电流密度、污染物初始浓度、电极间距离、电解次数、电极材料类型(铁和铝)等各种操作参数的影响;计算了COD和TS的去除率及最佳操作参数。优化后的间歇流反应器中COD和TS的还原率分别为83%和78%,Fe和Al电极的COD和TS的还原率分别为80%和72%。优化条件为:24 mA cm -2, 20 g/L PVAC,中性pH, Al-Al电极20分钟,Fe-Fe电极15分钟,电极间距1 cm,采用并联单极连接方式。结果表明,间歇流电化学法是一种经济、操作方便、处理含聚醋酸乙烯的废水的有效预处理方法。
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引用次数: 12
Tetrachloroethylene Removal Rate from Aqueous Solutions by Pumice Doped with Copper: An Evaluation of the Effect of pH 掺铜浮石对水溶液中四氯乙烯的去除率:pH影响的评价
Q4 Environmental Science Pub Date : 2016-12-27 DOI: 10.5812/AJEHE.5658
A. Almasi, M. Soltanian, F. Asadi, Parvin Nokhasi, K. Godini, M. Mohammadi, G. Azarian, A. Mohammadi
Tetrachloroethylene (TCE) is a chlorinated aliphatic hydrocarbon, used in many industries. Effective and efficient treatment of industrial wastewater, containing TCE, is one of the environmental requirements. The purpose of this study was to determine the role of alkaline environments in TCE removal rate from aqueous solutions, using copper-doped pumice. This experimental study was performed, using granulated pumice stones with a mesh 4 (8.4 mm) in alkaline conditions; the samples were coated with copper. Copper-doped pumice was prepared as a bed at doses of 1, 2, and 3 g/L; the study was performed at pH ranges of 3, 7, and 11. Based on the results, copper-doped pumice showed good efficacy in TCE removal; in addition, its performance increased in alkaline conditions. Therefore, use of this stone for the treatment of wastewater, containing TCE, is effective due to its availability and low cost. Besides, it can be considered a good option, given its high efficiency in the absorption process.
四氯乙烯(TCE)是一种氯化脂肪族烃,在许多工业中都有应用。有效和高效地处理含TCE的工业废水是环境要求之一。本研究的目的是利用掺铜浮石确定碱性环境对水溶液中TCE去除率的影响。本实验研究是在碱性条件下使用粒径为4 (8.4 mm)的浮石颗粒进行的;样品被镀上了一层铜。在1、2和3 g/L的剂量下制备掺杂铜的浮石作为床层;研究在3、7和11的pH范围内进行。结果表明,掺铜浮石对TCE有较好的去除效果;此外,在碱性条件下,其性能有所提高。因此,使用这种石头来处理含有TCE的废水,由于其可用性和低成本,是有效的。此外,考虑到它在吸收过程中的高效率,它可以被认为是一个很好的选择。
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引用次数: 1
Increasing Methane Production by Anaerobic Co-Digestion of Slaughterhouse with Fruit and Vegetable Wastes 屠宰场与果蔬废弃物厌氧共消化提高甲烷产量
Q4 Environmental Science Pub Date : 2016-12-27 DOI: 10.5812/AJEHE.8541
M. Samadi, M. Leili, H. Alizadeh, K. Godini, D. Ahmadi
Despite fossil fuels, the energy supply from biogas process is of renewable energy resources; this kind of energy can be generated in all parts of the world. Thus, the potential of anaerobic co-digestion for production of methane from wastes of an industrial slaughterhouse and fruit and vegetable center in the Hamadan city, west of Iran, was investigated. The digester was operated under the mesophilic (35 - 37°C) condition for a period of 40 days with 3 different C/N ratios (20/1, 30/1 and 40/1). Before operation of digester, the amounts of C and N in the wastes were measured and during the experiments pH and composition of the biogas were determined. The cumulative amounts of the generated total biogas and methane at the 3 examined C/N ratios 20/1, 30/1 and 40/1 were, respectively 181, 201.7 and 162.5 L and 129.8, 149.2 and 114 L. The results indicated that the highest contents of biogas and methane (201.68 and 149.29 L, respectively) were obtained at C/N of 30 within 31 days.
除化石燃料外,沼气过程的能源供应是可再生能源;这种能源可以在世界各地产生。因此,对伊朗西部哈马丹市的一个工业屠宰场和水果蔬菜中心的废物进行厌氧共消化生产甲烷的潜力进行了调查。在中温(35 ~ 37℃)条件下,以3种不同的C/N比(20/ 1,30 /1和40/1)运行了40天。在沼气池运行前,测定了废水中C、N的含量,实验过程中测定了沼气的pH值和组成。在C/N比值为20/ 1,30 /1和40/1的3种条件下,累积产生的总沼气和甲烷量分别为181、2011.7和162.5 L, 129.8、149.2和114 L。结果表明,在C/N为30时,31 d内沼气和甲烷含量最高,分别为201.68和149.29 L。
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引用次数: 4
Synthesis of Manganese Tetroxide Nanoparticles Using Precipitation and Study of Its Structure and Optical Characteristics 沉淀法合成四氧化二锰纳米颗粒及其结构和光学特性研究
Q4 Environmental Science Pub Date : 2016-12-27 DOI: 10.5812/AJEHE.8565
R. Shokoohi, M. Samadi, G. Asgari, M. V. Tabar, K. Godini
Considering extensive applications of manganese tetroxide nanoparticles in various industries due to its special properties, conducting studies on how to achieve more suitable ways to produce smaller nanoparticles is of great importance. In this study, nanoparticles of manganese tetroxide (Mn3O4) were synthesized by a co-precipitation method. In order to determine the characteristics of the structure, size, and specific surface of the resulting nanoparticles, techniques such as XRD, BET, BJH, FESEM, and FTIR were employed. Also, the nanoparticles were quantified with EDS and their colony size was examined using DLS experiments. The findings revealed a production of crystalline manganese tetroxide nanoparticles with a space group of 141/amd (S.G.) (141) and a molecular weight of 228.81 with the international code of ICSD Card # 89 - 4837. The specific surface area was 32.147 m2 /g with a pore volume of 0.1041 cm3 /g. The XRD and EDX analyses verify the production of the Mn3O4 nanoparticles. The size of the nanostructures is approximately 19 nm. The method used in this study could produce the Mn3O4 nanoparticles in a much easier way without the need for surfactants. Compared to the nanoparticles produced in other studies, the size of the nanoparticles produced in the present study is remarkably smaller. Moreover, less amount of the metal salt was used.
四氧化二锰纳米颗粒由于其特殊的性能在各个行业中有着广泛的应用,研究如何找到更合适的方法来生产更小的纳米颗粒是非常重要的。本研究采用共沉淀法合成了四氧化锰纳米颗粒。采用XRD、BET、BJH、FESEM和FTIR等技术对纳米颗粒的结构、尺寸和比表面进行了表征。用能谱仪对纳米颗粒进行定量,用DLS法测定纳米颗粒的集落大小。研究结果表明,制备的结晶四氧化二锰纳米粒子空间基为141/amd (S.G.)(141),分子量为228.81,国际代码为ICSD卡# 89 - 4837。比表面积为32.147 m2 /g,孔体积为0.1041 cm3 /g。XRD和EDX分析验证了Mn3O4纳米颗粒的制备。纳米结构的尺寸约为19纳米。本研究中使用的方法可以在不需要表面活性剂的情况下以更简单的方式生产Mn3O4纳米颗粒。与其他研究中产生的纳米颗粒相比,本研究中产生的纳米颗粒的尺寸明显更小。此外,金属盐的用量也较少。
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引用次数: 6
Prevalence and Removal Efficiency of Enterococcal Species and Vancomycin-resistant Enterococci of a Hospital Wastewater Treatment Plant 某医院污水处理厂肠球菌种类及耐万古霉素肠球菌的流行及去除率
Q4 Environmental Science Pub Date : 2016-12-27 DOI: 10.5812/AJEHE.8623
F. Karimi, M. Samarghandi, R. Shokoohi, K. Godini, M. Arabestani
Simultaneous presence of various antibiotics and bacteria in hospital wastewaters creates a suitable environment, in which the bacteria, such as enterococci become resistant to the antibiotics. The aim of this study was to evaluate the performance of different units of the hospital wastewater treatment plant (HWTP) to remove Enterococcus spp and Vancomycin-resistant Enterococcus (VRE). The study was performed on the 27 samples collected from HWTP in Hamedan, Iran during December 2014 to August 2015. Enterococcus spp and VRE were identified by biochemical tests and then the isolates were confirmed by PCR. Finally, the antibiotic susceptibility test was performed using disk diffusion methods. Of the 27 samples examined, 315 a total of enterococcal isolates were obtained. Of the 315 isolates of enterococci investigated, 162 (51.42%) were identified as E. faecium, 87 (27.61%) as E. hirae, 35 (11.11%) as E. faecalis, 11 (3.5%) as E. gallinarum, 7 (2.22%) as E. casseliflavus, 4 (1.26%) E. avium, and 9 (2.85%) isolates VR E. faecium.The results of antibiotic susceptibility testing showed that of the total 315 isolates, 146 (46.34%) were resistance to tetracycline, 9 (2.85%) were resistance to vancomycin and Teicoplanin. Lower antibiotic resistance was seen with Nitrofurantoin 2 (1.26%). This study indicates a high prevalence of multidrug resistance among E. faecium isolated from HWTP, thus, it could be considered as a threat to the health and safety of wastewater workers and even public health.
医院废水中同时存在的各种抗生素和细菌创造了一个合适的环境,在这个环境中,肠球菌等细菌对抗生素产生耐药性。本研究旨在评价医院污水处理厂(HWTP)不同单元对肠球菌(Enterococcus spp)和万古霉素耐药肠球菌(VRE)的去除效果。该研究是在2014年12月至2015年8月期间从伊朗Hamedan的HWTP采集的27份样本上进行的。经生化试验鉴定为肠球菌和VRE,再经PCR鉴定为分离株。最后采用纸片扩散法进行药敏试验。在检查的27个样本中,共获得315个肠球菌分离株。315株肠球菌中,粪肠球菌162株(51.42%)、黑肠球菌87株(27.61%)、粪肠球菌35株(11.11%)、鸡肠球菌11株(3.5%)、casseliflavus 7株(2.22%)、鸟肠球菌4株(1.26%)、VR粪肠球菌9株(2.85%)。药敏试验结果显示,315株分离菌中,对四环素耐药146株(46.34%),对万古霉素和替柯planin耐药9株(2.85%)。呋喃妥英2的耐药性较低(1.26%)。本研究表明,从HWTP中分离出的粪肠杆菌具有较高的多药耐药率,可能对污水处理工人的健康安全乃至公众健康构成威胁。
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引用次数: 9
Performance of A Pilot-Scale Vermifilter for the Treatment of A Real Hospital Wastewater 中试规模vermfilter处理某医院污水的性能研究
Q4 Environmental Science Pub Date : 2016-12-27 DOI: 10.5812/AJEHE-7585
Nahid Ghobadi, R. Shokoohi, A. Rahmani, M. Samadi, K. Godini, M. Samarghandi
In this study, the performance of a pilot-scale vermifilter (VF) for the treatment of hospital wastewater using the earthworm species Eisenia fetida was evaluated. The earthworms’ gut acts as a bioreactor and can ingest the wastewater solid and liquid organic wastes and expel these as vermicompost. A pilot-scale vermifilter was installed and operated for 133 days in one of hospitals in Hamadan city; the designed system was fed with the influent passed through coarse and fine grillage and the sedimentation tank of the hospital’s sanitary collection system. In order to study the efficiency of the system, the variations of pH value, chemical oxygen demand (COD), biochemical oxygen demand (BOD5), and total suspended solids (TSS) were measured. In addition, a conventional geofilter (GF) without Earthworm was used as the experimental control. The vermifiltration caused a significant decrease in the levels of COD (75%), BOD5 (93%), and TSS (89%) as well as neutralized pH in the wastewater. Also, these contents in the geofilter were observed to be 65%, 71%, and 71%, respectively. The vermifiltration technology can, therefore, be applied as an environmentally friendly method for hospital wastewater treatment.
在这项研究中,研究了一个中试规模的蚯蚓过滤器(VF)处理医院废水的性能。蚯蚓的肠道就像一个生物反应器,可以吸收废水中的固体和液体有机废物,并将它们作为蚯蚓堆肥排出体外。在哈马丹市的一家医院安装了一个中试规模的蠕虫过滤器,并运行了133天;设计的系统以医院卫生收集系统的粗、细格栅和沉淀池的进水为原料。为了研究该系统的效率,测定了pH值、化学需氧量(COD)、生化需氧量(BOD5)和总悬浮物(TSS)的变化。此外,采用常规的不含蚯蚓的地滤(GF)作为实验对照。经渗滤后,废水中COD(75%)、BOD5(93%)、TSS(89%)和中和pH值均显著降低。此外,这些含量在地质过滤器中分别为65%,71%和71%。因此,该渗透技术可以作为一种环境友好的方法用于医院废水处理。
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引用次数: 7
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Avicenna Journal of Environmental Health Engineering
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