Saqib Ali, S. Ahmad, M. Altaf, S. Shahzadi, A. Badshah
{"title":"Kinetics and Mechanism of the Substitution Reactions of Triphenyltin(IV)[2-(2,6- dichlorophenyl)aminophenyl acetate] with Iodine","authors":"Saqib Ali, S. Ahmad, M. Altaf, S. Shahzadi, A. Badshah","doi":"10.1515/IRM.2006.6.1.49","DOIUrl":"https://doi.org/10.1515/IRM.2006.6.1.49","url":null,"abstract":"","PeriodicalId":8996,"journal":{"name":"BioInorganic Reaction Mechanisms","volume":"26 1","pages":"49 - 58"},"PeriodicalIF":0.0,"publicationDate":"2006-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81524835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2006-01-01DOI: 10.1515/IRM.2006.6.2.151
H. Tsuji, Y. Inada, S. Funahashi
{"title":"Kinetic Study of the Complexation of Bulky TMUSolvated Manganese(II), Iron(II), Cobalt(II), Nickel(II), Copper(II), Zinc(II), and Cadmium(II) Ions in Neat TMU (1,1,3,3-Tetramethylurea) Solvent","authors":"H. Tsuji, Y. Inada, S. Funahashi","doi":"10.1515/IRM.2006.6.2.151","DOIUrl":"https://doi.org/10.1515/IRM.2006.6.2.151","url":null,"abstract":"","PeriodicalId":8996,"journal":{"name":"BioInorganic Reaction Mechanisms","volume":"62 1","pages":"151 - 160"},"PeriodicalIF":0.0,"publicationDate":"2006-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87006295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2006-01-01DOI: 10.1515/IRM.2006.6.2.119
Eman S. H. Khaled
{"title":"Kinetics and Mechanism of Oxidation of a Ternary Complex Involving Dipicolinatochromium(III) and Proline by N-bromsuccinimide","authors":"Eman S. H. Khaled","doi":"10.1515/IRM.2006.6.2.119","DOIUrl":"https://doi.org/10.1515/IRM.2006.6.2.119","url":null,"abstract":"","PeriodicalId":8996,"journal":{"name":"BioInorganic Reaction Mechanisms","volume":"26 1","pages":"119 - 129"},"PeriodicalIF":0.0,"publicationDate":"2006-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83096313","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2005-10-01DOI: 10.1515/IRM.2005.5.4.245
Oleg Pestovsky, A. Bakac
There is a remarkable resemblance in the chemistry and intermediates involved in the autoxidation of a macrocyclic Cr(II) complex LCr(H2O)2 (L1 = 1,4,8,11-tetraazacyclotetradecane, or cyclam) and the activation of molecular oxygen by cytochrome P450 enzymes [1,2]. For every major step in the P450 chemistry there is a corresponding step in the chemistry of L1Cr complex, including the hydroperoxo to high-valent oxo conversion of eq 1. The kinetics of this transformation have been studied earlier [2,3].
{"title":"Competing Coordination and Oxygen Atom Transfer in a Reaction Between Triarylphosphines and a Chromium Hydroperoxo Complex","authors":"Oleg Pestovsky, A. Bakac","doi":"10.1515/IRM.2005.5.4.245","DOIUrl":"https://doi.org/10.1515/IRM.2005.5.4.245","url":null,"abstract":"There is a remarkable resemblance in the chemistry and intermediates involved in the autoxidation of a macrocyclic Cr(II) complex LCr(H2O)2 (L1 = 1,4,8,11-tetraazacyclotetradecane, or cyclam) and the activation of molecular oxygen by cytochrome P450 enzymes [1,2]. For every major step in the P450 chemistry there is a corresponding step in the chemistry of L1Cr complex, including the hydroperoxo to high-valent oxo conversion of eq 1. The kinetics of this transformation have been studied earlier [2,3].","PeriodicalId":8996,"journal":{"name":"BioInorganic Reaction Mechanisms","volume":"17 1","pages":"245 - 254"},"PeriodicalIF":0.0,"publicationDate":"2005-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83695235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2005-01-01DOI: 10.1515/IRM.2005.5.3.181
A. Nolan, J. A. Irwin, R. Burns, G. Lawrance
Oxidation of Mn(II) by HOCl in weakly acidic solution, in the presence of tungstate, results in the formation of the soluble heteropolyoxotungstate [MnW6O24]. The kinetics of formation of this species was studied from 15-35°C over the pH range 4.9-5.4 and found to exhibit solution autocatalytic behaviour. The oxidation kinetics was found to follow an expanded rate expression consisting of two terms:
{"title":"Reaction Kinetics and Mechanism of Formation of [MnW6O24]8- by Hypochlorous Acid Oxidation of Mn(II)aq in the Presence of Tungstate","authors":"A. Nolan, J. A. Irwin, R. Burns, G. Lawrance","doi":"10.1515/IRM.2005.5.3.181","DOIUrl":"https://doi.org/10.1515/IRM.2005.5.3.181","url":null,"abstract":"Oxidation of Mn(II) by HOCl in weakly acidic solution, in the presence of tungstate, results in the formation of the soluble heteropolyoxotungstate [MnW6O24]. The kinetics of formation of this species was studied from 15-35°C over the pH range 4.9-5.4 and found to exhibit solution autocatalytic behaviour. The oxidation kinetics was found to follow an expanded rate expression consisting of two terms:","PeriodicalId":8996,"journal":{"name":"BioInorganic Reaction Mechanisms","volume":"1 1","pages":"181 - 195"},"PeriodicalIF":0.0,"publicationDate":"2005-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72947842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2005-01-01DOI: 10.1515/IRM.2005.5.4.265
J. F. Read, S. Bewick, S. Oikle, Catherine Schaubel, S. N. Taylor, Annie Thériault, K. Watson
{"title":"The Kinetics and Mechanism of the Oxidation of Inorganic Oxysulfur Compounds by Potassium Ferrate Part II - Tetrathionate Ions","authors":"J. F. Read, S. Bewick, S. Oikle, Catherine Schaubel, S. N. Taylor, Annie Thériault, K. Watson","doi":"10.1515/IRM.2005.5.4.265","DOIUrl":"https://doi.org/10.1515/IRM.2005.5.4.265","url":null,"abstract":"","PeriodicalId":8996,"journal":{"name":"BioInorganic Reaction Mechanisms","volume":"16 1","pages":"265 - 280"},"PeriodicalIF":0.0,"publicationDate":"2005-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76425167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}