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Equivalent Inclusion Approach for Micromechanics Estimates of Nanocomposite Elastic Properties 纳米复合材料弹性性能微力学估计的等效包合法
Pub Date : 2016-02-09 DOI: 10.1061/(ASCE)NM.2153-5477.0000104
L. Dormieux, E. Lemarchand, S. Brisard
AbstractClassical micromechanics approaches for heterogeneous media assume perfect bonding between phases, implying that both displacement and stress vectors are continuous across the interface between the phases. When nanoinclusions are involved, a stress vector discontinuity in the local equilibrium has to be accounted for. In this framework, this paper derives an approximate solution of the Lippmann-Schwinger (L-S) equation, which accounts for these surface stresses. This approach suggests introducing the concept of an equivalent particle that combines the particle with the surrounding interface, which can be directly implemented in any standard homogenization procedure, such as the Mori-Tanaka scheme. Analytical expressions for the stiffness tensor of the equivalent particle is derived for spheroidal inclusions, accounting for a wide range of nanoinclusion shapes and dimensions. Finally, an energy-based analysis proves how the dramatic increase of the elastic properties is controlled, for a given volu...
摘要非均质介质的经典细观力学方法假定相之间有完美的结合,这意味着位移和应力矢量在相之间的界面上是连续的。当涉及纳米包裹体时,必须考虑局部平衡中的应力矢量不连续。在此框架下,本文导出了考虑这些表面应力的Lippmann-Schwinger (L-S)方程的近似解。这种方法建议引入等效粒子的概念,将粒子与周围的界面结合起来,这可以直接在任何标准的均质化过程中实现,例如Mori-Tanaka方案。推导了球形夹杂物等效粒子刚度张量的解析表达式,适用于各种形状和尺寸的纳米夹杂物。最后,基于能量的分析证明了在给定体积下,如何控制弹性性能的急剧增加。
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引用次数: 2
Creep of Lubricated Layered Nano-Porous Solids and Application To Cementitious Materials 润滑层状纳米多孔固体的蠕变及其在胶凝材料中的应用
Pub Date : 2015-12-01 DOI: 10.1061/(ASCE)NM.2153-5477.0000102
M. Vandamme, Z. Bažant, S. Keten
AbstractA variety of geomaterials, such as cementitious or clay-based materials, has on the nano-scale a layered microstructure that can contain fluid in its nano-porous space. The creep of such nano-scale basic units is what causes the macroscopic creep. Here, one nano-pore whose walls consist of two parallel infinite solid layers interacting through Lennard-Jones potential is studied. The authors evaluate numerically the energy barriers that such a system needs to overcome for the two solid layers to slide over each other and show how this sliding depends on the longitudinal and transverse forces applied to the layers. The energy barriers translate into a dependence of the apparent viscosity of the system on the disjoining pressure in a manner consistent with the microprestress theory. This result makes it possible to explain why the longtime creep of cementitious materials is logarithmic. The experimental data on how the long-term logarithmic creep of cementitious materials depends on the temperature a...
各种岩土材料,如胶凝材料或粘土基材料,在纳米尺度上具有层状微观结构,其纳米多孔空间可以容纳流体。这种纳米尺度基本单元的蠕变是造成宏观蠕变的原因。本文研究了一个纳米孔,其壁由两个平行的无限固体层组成,通过Lennard-Jones势相互作用。作者用数值方法评估了这样一个系统需要克服的能量障碍,以使两个固体层相互滑动,并展示了这种滑动是如何取决于施加在层上的纵向和横向力的。能量势垒转化为体系表观粘度对分离压力的依赖关系,与微预应力理论一致。这一结果可以解释为什么胶凝材料的长期蠕变是对数的。本文给出了胶凝材料长期对数蠕变随温度变化的实验数据。
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引用次数: 15
Processing and Mechanical Properties Investigation of Epoxy-Impregnated Graphene Paper 环氧浸渍石墨烯纸的制备及力学性能研究
Pub Date : 2015-11-02 DOI: 10.1061/(ASCE)NM.2153-5477.0000108
L. Cai, A. Al-ostaz, Xiaobing Li, L. Drzal, Brian P. Rook, A. Cheng, H. Alkhateb
AbstractOne-layer (0.15-mm-thick) and 15-layer (5.43-mm-thick) graphene composites have been fabricated through the impregnation of epoxy resin into porous graphene nanoplatelet (GnP) paper. Three different flake sizes of GnPs were used for the 1-layer graphene composites: 5 μm, mixed 5 μm and 25 μm, and 25 μm. The largest graphene flakes showed the best material properties in terms of tensile strength and elongation at break. Both tensile and dynamic mechanical analysis (DMA) test results demonstrated that the 15-layer graphene composite had better material properties than the 1-layer graphene composites. The storage modulus of 15-layer graphene composite was 170% higher than that of neat epoxy. The transverse surface of 15-layer graphene composite exhibited a higher elastic modulus but lower hardness than the top surface. Ballistic limit test results showed that the combination of polyurea (PU) and a 15-layer graphene composite coating can increase the ballistic limit of TC-128 steel plate slightly.
摘要通过环氧树脂浸渍多孔石墨烯纳米板(GnP)纸,制备了1层(0.15 mm厚)和15层(5.43 mm厚)石墨烯复合材料。在单层石墨烯复合材料中使用了3种不同粒径的GnPs: 5 μm、5 μm和25 μm混合、25 μm。最大的石墨烯薄片在拉伸强度和断裂伸长率方面表现出最佳的材料性能。拉伸和动态力学分析(DMA)测试结果表明,15层石墨烯复合材料比1层石墨烯复合材料具有更好的材料性能。15层石墨烯复合材料的存储模量比纯环氧树脂高170%。15层石墨烯复合材料的横向表面具有较高的弹性模量,但硬度较表层低。弹道极限试验结果表明,聚脲(PU)与15层石墨烯复合涂层的组合可以略微提高TC-128钢板的弹道极限。
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引用次数: 5
Effects of Interphase Regions of Particulate-Reinforced Metal Matrix Nanocomposites Using a Discrete Dislocation Plasticity Model 基于离散位错塑性模型的颗粒增强金属基纳米复合材料相区影响
Pub Date : 2015-09-01 DOI: 10.1061/(ASCE)NM.2153-5477.0000098
Kunpeng Lin, E. Law, S. Pang
AbstractMetal matrix nanocomposites (MMNCs) show significant promise for use as structural and/or functional materials. In recent years, discrete dislocation simulations have been used to perform a numerical analysis on MMNCs. Although the trend of increasing flow stress and degree of hardening with a larger particle volume fraction and decreasing particle size were captured by existing simulations, the effects of these parameters on the mechanical behavior of MMNCs shown in these analyses were not as substantial as those reported in experiments. Meanwhile, the presence of thermally induced dislocations and chemical reactions between the matrix and inclusions suggest that interphase regions should be accounted for in the simulation. By using a level set in the extended FEM (XFEM), interphase regions are introduced into the numerical model. The effects of elastic properties, thickness of the interphase regions, and resistance to dislocation motion within the interphase regions are examined in this study.
摘要金属基纳米复合材料(mmnc)在结构和/或功能材料方面具有重要的应用前景。近年来,离散位错模拟已被用于对多孔纳米管进行数值分析。虽然现有的模拟模拟捕捉到了随着颗粒体积分数的增大和颗粒尺寸的减小而增加流动应力和硬化程度的趋势,但这些分析中显示的这些参数对mmnc力学行为的影响并不像实验中报道的那样明显。同时,热诱导位错的存在以及基体与夹杂物之间的化学反应表明,在模拟中应考虑相间区。采用扩展有限元法(XFEM)中的水平集,将相间区引入数值模型。本研究考察了弹性性能、相间区厚度和相间区内的位错运动阻力的影响。
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引用次数: 4
Poroelastic Properties of a Nanoporous Granular Material with Interface Effects 具有界面效应的纳米多孔颗粒材料的孔弹性特性
Pub Date : 2015-09-01 DOI: 10.1061/(ASCE)NM.2153-5477.0000097
Maged Sidhom, L. Dormieux, E. Lemarchand
AbstractMany research activities have contributed to extend the homogenization schemes and variational bounds to account for surface stresses, in the case of matrix-inclusion composite materials. The nanostructure of clay-based and cement-based materials rather exhibits a disordered granular-like morphology which is usually well described by using the self-consistent scheme. Within this context, this paper proposes an extension of Kroener’s self-consistent scheme incorporating the physics of surface stress. The poromechanical coupling is also considered through the concept of disjoining pressure. Closed-form solutions for the homogenized elastic and poroelastic moduli that are derived and simplified expressions of these moduli are reported for asymptotic cases.
摘要许多研究活动都有助于扩展均匀化方案和变分边界,以解释基体-夹杂复合材料的表面应力。粘土基和水泥基材料的纳米结构表现出无序的颗粒状形态,通常用自洽方案来描述。在此背景下,本文提出了一个扩展的Kroener的自洽方案,结合表面应力的物理。通过分离压力的概念考虑了孔隙力学耦合。本文报道了均质弹性模量和多孔弹性模量在渐近情况下的封闭解和简化表达式。
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引用次数: 5
Mechanical Properties of Hydrogen Edge–Passivated Chiral Graphene Nanoribbons 氢边钝化手性石墨烯纳米带的力学性能
Pub Date : 2015-07-06 DOI: 10.1061/(ASCE)NM.2153-5477.0000101
Yanbiao Chu, T. Ragab, P. Gautreau, C. Basaran
AbstractUniaxial tension of chiral graphene nanoribbons (GNR) with and without edge hydrogen passivation are simulated using molecular dynamics (MD) simulations to study their mechanical properties. The results demonstrate that hydrogen saturation generally weakens chiral GNRs, although its influence on armchair GNRs is almost negligible. Mechanical properties of GNRs depend on chiral angles. Zigzag GNRs (chiral angle 0°) are always the strongest, whereas armchair GNRs (chiral angle 30°) are weaker. The mechanical properties of other chiral GNRs evolve gradually from these two distinct cases from chiral angles of 30° to 0°, with the smallest value of failure stress and failure strain happening around a chiral angle of 20°. As for the width size effect, wider GNRs always have lower failure strains and failure stress regardless of having edge hydrogen passivation or not.
摘要采用分子动力学方法模拟了无氢钝化和无氢钝化手性石墨烯纳米带(GNR)的单轴张力,研究其力学性能。结果表明,氢饱和通常会削弱手性gnr,但其对扶手椅gnr的影响几乎可以忽略不计。gnr的力学性能与手性角有关。手性角为0°的锯齿形gnr最强,而手性角为30°的扶手形gnr较弱。其他手性gnr的力学性能从这两种不同的情况逐渐演变,从30°手性角到0°手性角,失效应力和失效应变的最小值发生在20°手性角附近。在宽度尺寸效应方面,无论边缘氢钝化与否,宽gnr的破坏应变和破坏应力均较低。
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引用次数: 22
Fire Protection Performance of Nanocoating on a LPG Tank under Fire Based on the Wavelet Finite-Element Method 基于小波有限元法的液化石油气储罐纳米涂层防火性能研究
Pub Date : 2015-06-01 DOI: 10.1061/(ASCE)NM.2153-5477.0000093
Bin Zhao
AbstractTo study the fire protection effect of the nanocoating on the liquefied petroleum gas (LPG) tank under fire, the wavelet finite-element method is applied in analyzing the thermal stress, temperature, and pressures distribution laws of uncoated, coated, and nanocoated LPG tanks. First, the relating research on nanocoating and the wavelet finite-element method is studied, respectively, and the feasibility of this research is analyzed. Second, the theoretical model of fire protection analysis of nanocoating is established, and the property of wavelet analysis, temperature field model, and turbulent flow model are constructed, respectively. Finally, the simulation is carried out, and the distribution laws of thermal stress, temperature, and pressure are obtained. Simulation results show that the nanocoated LPG has better heat insulation character, and it can be used as a passive fireproof system that can cooperate with rain fire extinguishing systems to reduce the explosion hazard of a LPG tank under ...
摘要为了研究纳米涂层对火灾下液化石油气(LPG)储罐的防火效果,采用小波有限元方法分析了未涂层、涂层和纳米涂层液化石油气储罐的热应力、温度和压力分布规律。首先,对纳米涂层和小波有限元法的相关研究进行了研究,并对研究的可行性进行了分析。其次,建立了纳米涂层防火分析的理论模型,分别构建了小波特性分析、温度场模型和湍流模型;最后进行了仿真,得到了热应力、温度和压力的分布规律。仿真结果表明,纳米包覆液化石油气具有较好的隔热性能,可以作为被动防火系统,与雨淋灭火系统配合使用,降低液化石油气储罐在高温下的爆炸危险性。
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引用次数: 0
Size Effect on Functionally Graded Material Fabrication by Sedimentation 沉淀法制备功能梯度材料的尺寸效应
Pub Date : 2015-06-01 DOI: 10.1061/(ASCE)NM.2153-5477.0000087
Po-Hua Lee, H. Yin
AbstractA simple, economic, and scalable material manufacturing method of sedimentation has been used to fabricate functionally graded materials for solar roofing panels. This paper investigates the size effect of aluminum powder on the material gradation in the depth direction when only aluminum powder or the mixture of aluminum and high-density polyethylene (HDPE) powder is uniformly dispersed in ethanol and then subjected to sedimentation for a certain period, respectively. A Stokes’ law–based model is developed to simulate the sedimentation process, in which the concentration of aluminum and HDPE particles temporally and spatially changes in the depth direction due to the nonuniform motion of particles. The concentration variation further changes the effective viscosity of the suspension, and thus affects the drag force of particles. The numerical simulation demonstrates the effect of manufacturing parameters for sedimentation and predicts the graded microstructure of deposition in the depth direction...
摘要:一种简单、经济、可扩展的沉积材料制造方法已被用于制造太阳能屋面板的功能梯度材料。本文研究了分别将纯铝粉或铝与高密度聚乙烯(HDPE)粉的混合物均匀分散在乙醇中沉淀一定时间后,铝粉在深度方向上对物料级配的粒度效应。建立了基于Stokes定律的沉降模型,模拟了由于颗粒运动不均匀,铝和HDPE颗粒浓度在深度方向上的时空变化。浓度的变化进一步改变了悬浮液的有效粘度,从而影响颗粒的阻力。数值模拟表明了制造参数对沉积的影响,并预测了沉积在深度方向上的梯度微观结构。
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引用次数: 7
Nanoscale Structure and Mechanical Properties of Cross-Linked Hydrogels 交联水凝胶的纳米级结构和力学性能
Pub Date : 2015-06-01 DOI: 10.1061/(ASCE)NM.2153-5477.0000091
H. Salahshoor, M. Tootkaboni, N. Rahbar
AbstractRecently, hydrogels have been employed in a variety of engineering applications as promising materials, since their porous structure and hydrophilicity enables them to absorb a large amount of water. Atomistic simulations lead to a better understanding of their properties at nanoscale, especially mechanical properties. In this study, hydrogel is studied using a molecular dynamics (MD) framework, considering condensed-phased optimized molecular potential (COMPASS) as the force field. Polyethylene glycol diglycidyl ether (PEDGE) and poly-oxy-alkylene-amines (Jeffamine) are the epoxy and curing agent used for hydrogels, and a novel cross-linking method is applied. Radial Distribution Functions (RDFs) show that the cross-links are the hydrophilic part of hydrogel. RDFs and mechanical properties are reported for different water amounts. The results show that an increase in water content leads to a decrease in elastic modulus of the hydrogel.
摘要近年来,水凝胶由于其多孔结构和亲水性使其能够吸收大量的水,作为一种很有前途的材料被应用于各种工程应用中。原子模拟可以更好地理解它们在纳米尺度上的特性,尤其是机械特性。本研究采用分子动力学(MD)框架,考虑凝聚相优化分子势(COMPASS)作为力场,对水凝胶进行了研究。聚乙二醇二甘油酯醚(PEDGE)和聚氧烷基胺(Jeffamine)是水凝胶的环氧固化剂和固化剂,采用了一种新的交联方法。径向分布函数(rdf)表明交联是水凝胶的亲水性部分。报告了不同含水量下的RDFs和力学性能。结果表明,水凝胶的弹性模量随着水凝胶含水量的增加而降低。
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引用次数: 1
Modeling Random Short Nanofiber- and Microfiber-Reinforced Composites Using the Extended Finite-Element Method 基于扩展有限元法的随机短纳米纤维和微纤维增强复合材料建模
Pub Date : 2015-03-01 DOI: 10.1061/(ASCE)NM.2153-5477.0000092
Matthew G. Pike, Caglar Oskay
AbstractThis manuscript presents the formulation and implementation of an extended finite-element method (XFEM) for random short fiber-reinforced composite materials. A new enrichment function is proposed to incorporate the effect of random fiber inclusions within the XFEM framework to eliminate the need of using finite-element meshes compliant with fiber inclusions. The motion of the fiber inclusions are modeled by constraining the deformation field along the domain of the fiber inclusions. Coupling the XFEM along with the new enrichment function and constraint equations formulate the elastic response of short fiber-reinforced composites. Numerical integration procedures are provided for accurate evaluation of the system response for fiber tips that lie on arbitrary positions within the problem domain. The performance of the proposed model is verified against the direct finite-element method.
摘要本文提出了随机短纤维增强复合材料的扩展有限元法(XFEM)的建立和实现。提出了一种新的富集函数,将随机纤维夹杂物的影响纳入XFEM框架,从而消除了使用纤维夹杂物的有限元网格的需要。通过约束沿纤维夹杂物区域的变形场来模拟纤维夹杂物的运动。将XFEM与新的富集函数和约束方程耦合,得到了短纤维增强复合材料的弹性响应。数值积分程序提供了准确评估系统响应的光纤尖端位于任意位置的问题域。通过直接有限元法验证了该模型的性能。
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引用次数: 11
期刊
Journal of nanomechanics & micromechanics
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