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Estimating the variability of contact parameter temperature dependence with the Monte Carlo Markov Chain method 用蒙特卡罗马尔可夫链法估计接触参数温度依赖的变异性
Pub Date : 2014-09-01 DOI: 10.1016/j.grj.2014.09.002
A. Määttänen , M. Douspis

Recent datasets on heterogeneous deposition mode ice nucleation have revealed a strong dependence of the contact parameter m on temperature, ranging from linear to exponential, depending on the experiments. We analyze recent datasets using a Monte Carlo Markov Chain method with the full classical nucleation theory including spherical and planar geometry. The method we use allows us to test models of the temperature dependence of the contact parameter and evaluate their performance. We estimate the applicability of different forms of contact parameter temperature dependence, including a new well-behaved suggestion. Such a function has a more physical behavior at high and low temperatures and might thus be more easily applicable in atmospheric modeling. However, because of their limited temperature range, the present datasets are unable to reveal the behavior of the contact parameter in low temperatures, and we are unable to fully validate the proposed function. We thus call for more heterogeneous nucleation experiments reaching low temperatures (<170 K). Such datasets may be significant for studies on, for example, polar mesospheric clouds, Mars ice clouds, and perhaps exoplanet clouds. This work provides a new framework, valid even for very small ice nucleus sizes, for analyzing heterogeneous nucleation datasets.

最近关于非均质沉积模式冰成核的数据集揭示了接触参数m对温度的强烈依赖,根据实验的不同,其范围从线性到指数。本文采用蒙特卡罗马尔可夫链方法,结合完整的经典成核理论,包括球面几何和平面几何,对最近的数据集进行了分析。我们使用的方法允许我们测试接触参数的温度依赖模型并评估其性能。我们估计了不同形式的接触参数温度依赖的适用性,包括一个新的良好的建议。这种函数在高温和低温下具有更强的物理性质,因此可能更容易适用于大气模拟。然而,由于其有限的温度范围,目前的数据集无法揭示接触参数在低温下的行为,我们无法完全验证所提出的函数。因此,我们需要在低温(170 K)下进行更多的非均质成核实验。这样的数据集可能对极地中间层云、火星冰云以及可能的系外行星云的研究具有重要意义。这项工作为分析非均质核数据集提供了一个新的框架,即使对于非常小的冰核尺寸也是有效的。
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引用次数: 9
The emergence and growth of a submarine volcano: The Kameni islands, Santorini (Greece) 海底火山的出现和发展:希腊圣托里尼岛的Kameni群岛
Pub Date : 2014-03-01 DOI: 10.1016/j.grj.2014.02.002
P. Nomikou , M.M. Parks , D. Papanikolaou , D.M. Pyle , T.A. Mather , S. Carey , A.B. Watts , M. Paulatto , M.L. Kalnins , I. Livanos , K. Bejelou , E. Simou , I. Perros

The morphology of a volcanic edifice reflects the integrated eruptive and evolutionary history of that system, and can be used to reconstruct the time-series of prior eruptions. We present a new high-resolution merged LiDAR-bathymetry grid, which has enabled detailed mapping of both onshore and offshore historic lava flows of the Kameni islands, emplaced in the centre of the Santorini caldera since at least AD 46. We identify three new submarine lava flows: two flows, of unknown age, lie to the east of Nea Kameni and a third submarine flow, located north of Nea Kameni appears to predate the 1925–1928 lava flows but was emplaced subsequent to the 1707–1711 lava flows. Yield strength estimates derived from the morphology of the 1570/1573 lobe suggest that submarine lava strengths are approximately two times greater than those derived from the onshore flows. To our knowledge this is the first documented yield strength estimate for submarine flows. This increase in strength is likely related to cooling and thickening of the dacite lava flows as they displace sea water. Improved lava volume estimates derived from the merged LiDAR-Bathymetry grid suggest typical lava extrusion rates of ∼2–3 m3 s−1 during four of the historic eruptions on Nea Kameni (1707–1711, 1866–1870, 1925–1928 and 1939–1941). They also reveal a linear relationship between the pre-eruption interval and the volume of extruded lava. These observations may be used to estimate the size of future dome-building eruptions at Santorini volcano, based on the time interval since the last significant eruption.

火山大厦的形态反映了该系统的整体喷发和演化历史,并可用于重建先前喷发的时间序列。我们提出了一种新的高分辨率合并激光雷达测深网格,它可以详细绘制Kameni岛陆上和海上历史熔岩流的地图,Kameni岛位于圣托里尼火山口的中心,至少从公元46年开始。我们确定了三个新的海底熔岩流:两个流,年龄未知,位于Nea Kameni的东部,第三个海底熔岩流位于Nea Kameni的北部,似乎早于1925-1928年的熔岩流,但在1707-1711年的熔岩流之后。从1570/1573叶瓣的形态得出的屈服强度估计表明,海底熔岩的强度大约是陆上熔岩流的两倍。据我们所知,这是首次记录的海底流屈服强度估计。这种强度的增加可能与英安岩熔岩流在取代海水时冷却和增厚有关。由合并的LiDAR-Bathymetry网格得出的改进的熔岩体积估计表明,在Nea Kameni的四次历史喷发(1707-1711、1866-1870、1925-1928和1939-1941)期间,典型的熔岩喷发速率为~ 2-3 m3 s - 1。它们还揭示了喷发前的时间间隔与喷出的熔岩体积之间的线性关系。根据上一次重大喷发的时间间隔,这些观测结果可以用来估计圣托里尼火山未来圆顶建筑喷发的规模。
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引用次数: 72
A new Moho boundary map for the northern Fennoscandian Shield based on combined controlled-source seismic and receiver function data 基于可控震源地震和接收函数数据的芬诺斯坎地盾北部新莫霍边界图
Pub Date : 2014-03-01 DOI: 10.1016/j.grj.2014.03.001
Hanna Silvennoinen , Elena Kozlovskaya , Eduard Kissling , Grigoriy Kosarev , POLENET/LAPNET Working Group

We present a new Moho map for the Early-Proterozoic northwestern part of the Fennoscandian Shield, where the POLENET/LAPNET passive seismic array was located. The map is based on previously published and re-evaluated controlled source seismic data and P-wave receiver functions as well as new estimates of the Moho depth obtained by our analysis of P-wave receiver functions at broadband stations of the POLENET/LAPNET array. We estimated individual data quality for all input data and combined them into a new Moho map using CRUST3D software. The software seeks the simplest (smoothest) Moho surface that is consistent with all seismic data within their individual uncertainty limits. The new Moho map indicates that the crustal thickness in the study region varies between 42 km and 58 km, with the greatest thickness being reached in two separate areas in the northeast and the southeast. Two areas with relatively flat and shallow Moho, with an average Moho depth of c. 44 km, are located in the eastern and south-western parts of the study area. These two areas are separated by the Moho depression, with a maximum depth of 58 km. They can be associated with the Archean core of the Karelian craton and with the part of it that was reworked during the Early Proterozoic, respectively. A region with an average Moho depth of c. 47 km can be seen in the northern part of our study area, deepening to c. 55 km in the northeastern corner.

本文对POLENET/LAPNET被动地震阵列所在的Fennoscandian Shield西北部早元古代的Moho图进行了研究。该地图是基于先前发布和重新评估的可控震源数据和p波接收函数,以及我们通过分析POLENET/LAPNET阵列宽带站的p波接收函数获得的新的莫霍深度估计。我们估计了所有输入数据的单个数据质量,并使用甲壳三维软件将它们组合成新的莫霍图。该软件寻求最简单(最平滑)的莫霍面,与所有地震数据在各自的不确定性范围内一致。新的莫霍图显示,研究区的地壳厚度在42 ~ 58 km之间,其中东北和东南两个区域的厚度最大。研究区东部和西南部有两个相对平坦、较浅的莫霍区,平均莫霍深度为0.44 km。这两个地区被莫霍洼地隔开,最大深度为58公里。它们分别与卡累利阿克拉通的太古宙岩心和早元古代被改造的部分岩心有关。研究区北部莫霍区平均深度为0.47 km,东北角莫霍区平均深度为0.55 km。
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引用次数: 22
Beginnings 开始
Pub Date : 2014-03-01 DOI: 10.1016/j.grj.2013.11.001
Scott King, Steve Donovan, Simon George, Lyatt Jaeglé, David Pyle, Stephan van Gasselt, Vasile Ersek
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引用次数: 0
Reconstructing the link between the Galapagos hotspot and the Caribbean Plateau 重建加拉帕戈斯热点和加勒比高原之间的联系
Pub Date : 2014-03-01 DOI: 10.1016/j.grj.2014.02.001
Rainer Nerlich , Stuart R. Clark , Hans-Peter Bunge

Most authors agree that parts of the Caribbean plate are an igneous Plateau underlain by Farallon lithosphere that was trapped in between the North and South American plates. However, the origin of the thickened crust is debated. The theory of oceanic plateaus forming as magmatic outpouring related to a plume arrival became prominent when Large Igneous Provinces could be traced back to hotspots. The present-day proximity of the Galapagos hotspot made it an obvious candidate for associating its plume head arrival with the formation of the Caribbean Plateau. However, it was shown that in a fixed or moving Indian-Atlantic hotspot reference frame, plate reconstructions predicted the Galapagos hotspot a thousand or more kilometres away from the Caribbean plate at the time of Plateau formation (∼88–94 Ma). Here, we calculate the goodness of fit for the Pacific hotspot reference frame and the recently developed Global Moving Hotspot Reference Frame. We show that both frames lead to good correlations between the paleo-positions of the Caribbean Plate and the Galapagos hotspot, when a docking time of the Caribbean plate to South America of 54.5 Ma is assumed. As this result is consistent with abundant evidence that lends support for a Galapagos hotspot origin of the rocks that form the Caribbean Plateau, proposed alternative mechanisms to explain the thickened crust of the Caribbean Plateau seem to be unnecessary. Finally, based on our model, we also derived an age distribution of the lithosphere underneath the thickened crust of the Caribbean Plateau.

大多数作者都认为,加勒比海板块的一部分是被困在南北美洲板块之间的法拉龙岩石圈下的火成岩高原。然而,厚地壳的起源是有争议的。当大火成岩省可以追溯到热点地区时,与羽流到达有关的岩浆喷涌形成海洋高原的理论变得突出。如今加拉帕戈斯群岛热点的邻近使其成为将其羽头到达与加勒比高原形成联系起来的明显候选者。然而,研究表明,在一个固定或移动的印度洋-大西洋热点参考框架中,板块重建预测了高原形成时(~ 88-94 Ma)加拉帕戈斯热点距离加勒比板块1000公里或更远。在这里,我们计算了太平洋热点参考系和最近发展的全球移动热点参考系的拟合优度。当加勒比海板块与南美洲的对接时间为54.5 Ma时,我们发现这两种框架在加勒比海板块与加拉帕戈斯热点的古位置之间具有良好的相关性。由于这一结果与大量证据相一致,这些证据支持加拉帕戈斯群岛是形成加勒比高原的岩石的热点来源,因此提出解释加勒比高原地壳增厚的其他机制似乎是不必要的。最后,基于我们的模型,我们还得到了加勒比高原增厚地壳下岩石圈的年龄分布。
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引用次数: 29
Modeling of synchrotron-based laboratory simulations of Titan’s ionospheric photochemistry 基于同步加速器的实验室模拟土卫六电离层光化学模型
Pub Date : 2014-03-01 DOI: 10.1016/j.grj.2014.03.002
Z. Peng , N. Carrasco , P. Pernot

The APSIS reactor has been designed to simulate in the laboratory with a VUV synchrotron irradiation the photochemistry occurring in planetary upper atmospheres. A N2CH4 Titan-like gas mixture has been studied, whose photochemistry in Titan’s ionospheric irradiation conditions leads to a coupled chemical network involving both radicals and ions. In the present work, an ion–neutral coupled model is developed to interpret the experimental data, taking into account the uncertainties on the kinetic parameters by Monte Carlo sampling. The model predicts species concentrations in agreement with mass spectrometry measurements of the methane consumption and product blocks intensities. Ion chemistry and in particular dissociative recombination are found to be very important through sensitivity analysis. The model is also applied to complementary environmental conditions, corresponding to Titan’s ionospheric average conditions and to another existing synchrotron setup. An innovative study of the correlations between species concentrations identifies two main competitive families, leading respectively to saturated and unsaturated species. We find that the unsaturated growth family, driven by C2H2, is dominant in Titan’s upper atmosphere, as observed by the Cassini INMS. But the saturated species are substantially more intense in the measurements of the two synchrotron experimental setups, and likely originate from catalysis by metallic walls of the reactors.

APSIS反应器设计用于在实验室用VUV同步辐射模拟行星高层大气中发生的光化学反应。研究了一种N2-CH4类泰坦气体混合物,其在泰坦电离层辐照条件下的光化学反应导致了一个涉及自由基和离子的耦合化学网络。在本工作中,考虑到动力学参数在蒙特卡罗采样中的不确定性,建立了一个离子-中性耦合模型来解释实验数据。该模型预测的物种浓度与甲烷消耗和产物块强度的质谱测量结果一致。通过灵敏度分析,发现离子化学,特别是解离重组是非常重要的。该模型也适用于互补的环境条件,对应于土卫六的电离层平均条件和另一个现有的同步加速器设置。一项关于物种浓度相关性的创新研究确定了两个主要的竞争家族,分别导致饱和和不饱和物种。我们发现,由C2H2驱动的不饱和生长家族在土卫六的高层大气中占主导地位,正如卡西尼INMS所观察到的那样。但在两个同步加速器实验装置的测量中,饱和物质的强度要大得多,可能是由反应堆金属壁的催化作用产生的。
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引用次数: 11
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GeoResJ
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