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Swelling of clay minerals in unconsolidated porous media and its impact on permeability 松散多孔介质中粘土矿物的溶胀及其对渗透率的影响
Pub Date : 2015-09-01 DOI: 10.1016/j.grj.2015.02.003
I. Aksu , E. Bazilevskaya , Z.T. Karpyn

This work combines core-flood experiments with X-ray μ-computed tomography (μ-CT) to investigate the swelling of clay minerals and its impact on permeability of unconsolidated porous media. Both swelling (montmorillonite) and non-swelling (kaolinite) clay were added as coatings on soda lime beads and quartz grains. Clay content varied from 1.4 to 5.5 wt.% in the montmorillonite-coated samples and from 2.0 to 6.8 wt.% in the kaolinite-coated samples. Permeability changes were monitored as a function of time using pure water. Visualization of coated bead and grains columns by μ-CT provided quantitative information on morphological changes of clay grains/coatings among dry and water-saturated samples. All clay-coated samples showed a 10–40% decrease in permeability as compared to uncoated samples. In general, permeability decreases with increasing clay content. A 39% volume increase of montmorillonite particles was observed by μ-CT immediately after the sample was saturated with water, i.e. swelling occurred almost instantaneously after water–clay contact. In contrast, kaolinite particles had a 15% volume increase, which was primarily attributed to the hydration of clay pellets by water. The calculated porosity reduction associated with clay swelling ranged from 0.4% to 1.7% including both montmorillonite- and kaolinite-coated samples. This decrease in porosity was estimated to cause only a 2–5% reduction in permeability, primarily due to the high initial porosity and permeability of the selected samples. This study presents a baseline to estimate changes in permeability as a result of clay swelling for samples with variable clay content, grain size, and porosity.

本文将岩心驱替实验与x射线μ计算机断层扫描(μ-CT)相结合,研究了粘土矿物的膨胀及其对疏松多孔介质渗透率的影响。将溶胀型(蒙脱土)和非溶胀型(高岭石)粘土分别添加到钠石灰珠和石英颗粒上作为涂层。蒙脱石包覆样品的粘土含量变化范围为1.4 ~ 5.5 wt.%,高岭石包覆样品的粘土含量变化范围为2.0 ~ 6.8 wt.%。利用纯水监测渗透率随时间的变化。μ-CT显示了干燥和水饱和样品中粘土颗粒/涂层的形态变化。与未涂覆的样品相比,所有涂覆粘土的样品的渗透率都降低了10-40%。一般来说,渗透率随粘土含量的增加而降低。μ-CT观察到蒙脱土颗粒体积在水饱和后立即增大39%,即在水-粘土接触后几乎瞬间发生膨胀。相比之下,高岭石颗粒的体积增加了15%,这主要是由于粘土颗粒被水水化。包括蒙脱土和高岭石包覆的样品,计算出的与粘土膨胀相关的孔隙率降低幅度在0.4%到1.7%之间。据估计,孔隙度的降低只会导致2-5%的渗透率降低,这主要是由于所选样品的初始孔隙度和渗透率都很高。本研究提出了一个基线,用于估计粘土含量、粒度和孔隙度变化的样品中粘土膨胀引起的渗透率变化。
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引用次数: 128
Immersion freezing of supercooled water drops containing glassy volcanic ash particles 浸入式冷冻的过冷水滴含有玻璃状火山灰颗粒
Pub Date : 2015-09-01 DOI: 10.1016/j.grj.2015.06.002
Amy Gibbs , Matthew Charman , Walther Schwarzacher , Alison C. Rust

The freezing temperatures of hundreds of water drops with radii 20–50 μm containing known average concentrations of suspended, mostly micron- to submicron-sized, volcanic ash particles composed of SiO2-rich glass were recorded using optical microscopy. As expected, the ash suppresses supercooling, and in contrast to earlier studies of much larger ash particles, the median freezing temperature clearly scales with the available ash surface area per drop. The heterogeneous nucleation rate coefficient per unit mass of ash (jm) increases exponentially with decreasing temperature (T) (increasing supercooling) with a possible change in the slope of a plot of logjm against T at T=245±1K. Although uncertainties in the ash surface area limit quantitative comparisons, we conclude that volcanic glass is a less effective ice-nucleating agent than feldspar crystals and more similar to other minerals previously studied.

用光学显微镜记录了数百个半径为20-50 μm的水滴的冻结温度,这些水滴含有已知的平均悬浮浓度,其中大部分是微米到亚微米大小的火山灰颗粒,由富含sio2的玻璃组成。正如预期的那样,火山灰抑制了过冷,与早期对大得多的火山灰颗粒的研究相反,中位冻结温度明显与每滴火山灰的可用表面积成正比。单位质量灰分的非均相成核速率系数(jm)随着温度(T)的降低(过冷度的增加)呈指数增长,在T=245±1K时logjm与T的曲线斜率可能发生变化。尽管火山灰表面积的不确定性限制了定量比较,但我们得出结论,火山玻璃是一种不如长石晶体有效的冰核剂,与以前研究的其他矿物更相似。
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引用次数: 13
List of Reviewers in 2014 2014年评审人员名单
Pub Date : 2015-09-01 DOI: 10.1016/S2214-2428(15)00042-X
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引用次数: 0
Peridotite enclaves hosted by Mesoarchaean TTG-suite orthogneisses in the Fiskefjord region of southern West Greenland 西格陵兰岛南部菲斯克峡湾地区由中太古代ttg套件正长石组成的橄榄岩飞地
Pub Date : 2015-09-01 DOI: 10.1016/j.grj.2015.03.003
Kristoffer Szilas , Peter B. Kelemen , Stefan Bernstein

This study presents bulk-rock major, trace, and platinum-group element data, as well as mineral chemistry for peridotites which form large enclaves (up to 500 × 1000 m) within Mesoarchaean orthogneisses of the Akia terrane in the Fiskefjord region, southern West Greenland. The largest peridotite body, known as Seqi, contains highly fosteritic olivine with a median Mg# of 92.6 and hosts extensive layers of chromitite, which can be traced for tens of metres with thicknesses of up to 30 cm. Thinner (<100 m thick), but extensive (up to 2000 m long) peridotite sheets are associated with coarse norite and orthopyroxenite with distinct cumulate textures in the Amikoq complex, located a few tens of kilometres south of Seqi. Intercalated amphibolites of tholeiitic basaltic composition show complementary geochemical evolution to the peridotites, consistent with igneous crystal fractionation trends. The U-shaped trace element patterns of the peridotites may either reflect the parental melt composition from which these olivine-rich rocks were derived, or alternatively this feature may be the result of melt-rock interaction. Overall, we interpret the Fiskefjord region peridotites to have formed as ultramafic cumulates derived from Archaean high-Mg, low Ca/Al magmas, although their geodynamic setting remains to be established.

本研究展示了大块岩石主要元素、痕量元素和铂族元素数据,以及在西格陵兰岛南部菲斯克峡湾地区的基亚地体中太古代正射界内形成大型飞地(高达500 × 1000米)的橄榄岩的矿物化学。最大的橄榄岩体,被称为Seqi,含有高度培养的橄榄石,中位数Mg#为92.6,并含有广泛的铬铁矿层,可以追溯到数十米,厚度可达30厘米。较薄(100米厚),但广泛(长达2000米)的橄榄岩片与粗黑岩和正辉石岩相关联,具有明显的堆积结构,位于塞奇以南几十公里的Amikoq杂岩中。由拉斑玄武岩组成的插片角闪岩与橄榄岩具有互补的地球化学演化特征,与火成岩晶体分异趋势一致。橄榄岩的u型微量元素模式可能反映了母岩熔体组成,这些富含橄榄石的岩石也可能是熔体-岩石相互作用的结果。总的来说,我们认为Fiskefjord地区的橄榄岩是由太古宙高mg、低Ca/Al岩浆形成的超镁质堆积形成的,尽管它们的地球动力学背景仍有待确定。
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引用次数: 32
Maximum depth of magnetisation of Australia, its uncertainty, and implications for Curie depth 澳大利亚的最大磁化深度,它的不确定性,以及对居里深度的影响
Pub Date : 2015-09-01 DOI: 10.1016/j.grj.2015.06.003
Richard Chopping , Brian L.N. Kennett

The Curie depth is the depth at which the crust and uppermost mantle cease to be ferromagnetic or ferromagnetic, the main cause of crustal magnetism, due to the action of geothermal effects. One method to estimate the Curie depth for Australia is to map the base of magnetisation derived from observations of magnetic intensity. We have used a nonlinear direct sampling inverse technique to fully explore the parameter space of a fractal forward model of magnetisation. This produces an ensemble of models that allow us to produce maps of both the maximum depth of magnetisation and its uncertainty for Australia. The base of magnetisation varies significantly across the continent, between 10 and 70 km depth, with an uncertainty of 7–10 km. The variations in magnetisation depth conform with the boundaries of geological provinces due to their differing magnetic properties: In general, cratons and older provinces generally show a deeper base of magnetisation results and hence may be inferred to have deeper Curie depths, reflecting that these areas are on the whole cooler. We also find general agreement in our results with known geothermal anomalies.

居里深度是地壳和最上层地幔由于地热效应的作用而不再具有铁磁性或铁磁性的深度。铁磁性是地壳磁性的主要原因。估计澳大利亚居里深度的一种方法是绘制由磁场强度观测得出的磁化基础图。我们利用非线性直接抽样反演技术,对磁化分形正演模型的参数空间进行了充分的探索。这产生了一系列模型,使我们能够绘制出澳大利亚最大磁化深度及其不确定性的地图。整个大陆的磁化基础差异很大,深度在10到70公里之间,不确定性为7到10公里。磁化深度的变化符合地质省的边界,因为它们的磁性不同:一般来说,克拉通和更古老的省通常显示出更深的磁化结果基础,因此可以推断出更深的居里深度,反映了这些地区总体上更冷。我们还发现我们的结果与已知的地热异常基本一致。
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引用次数: 28
Environmental control of the isotopic composition of subfossil coccolith calcite: Are laboratory culture data transferable to the natural environment? 亚化石球石方解石同位素组成的环境控制:实验室培养数据可转移到自然环境吗?
Pub Date : 2015-09-01 DOI: 10.1016/j.grj.2015.05.002
Michaël Hermoso , Yaël Candelier , Thomas J. Browning , Fabrice Minoletti

Coccoliths contribute significantly to pelagic sediments formed over the last 200 million years, yet their geochemistry has been largely overlooked as a potential record of palaeoenvironmental information. Recently developed techniques have enabled successful extraction of coccolith-dominated sediment fractions. However, the reliability of palaeoenvironmental interpretations that can be drawn from coccolith analyses is still confounded by a poor understanding of the “vital effect” – the physiological component of the isotopic composition of biominerals. Here we demonstrate that oxygen isotope composition in core-top coccoliths is not only set by the temperature and isotopic composition of seawater, but appears to be controlled to first order by the environmental factors regulating algal growth rate. Partial registration of the isotopic signature of assimilated CO2 (with a heavy isotopic composition relative to other dissolved inorganic carbon species) is confirmed to be the dominant mechanism behind the vital effect recorded in the Noelaerhabdaceae coccoliths. Our data point towards a strong role of growth irradiance on expression of the 18O and 13C vital effects, ranging from limited (near equilibrium composition) in low light regimes to 3‰ offset in oxygen isotopes at higher growth irradiances, such as those found under light-saturated conditions typically imposed in laboratory cultures. This highlights the importance of considering environmental controls when translating oxygen isotope composition of coccoliths into temperature estimates. Furthermore, our calibration suggests that the alkenone-based CO2 palaeobarometer proxy may be refined by combining paired organic/calcite measurements during the Cenozoic.

在过去的2亿年里,球粒岩对形成的远洋沉积物起着重要的作用,然而它们的地球化学特征在很大程度上被忽视了,因为它们是古环境信息的潜在记录。最近开发的技术已经能够成功地提取以球石为主的沉积物馏分。然而,由于人们对“生命效应”——生物矿物同位素组成的生理成分——的理解不足,可以从球岩石分析中得出的古环境解释的可靠性仍然受到影响。研究表明,岩心顶球岩芯氧同位素组成不仅受海水温度和同位素组成的影响,还受调节藻类生长速率的环境因子的一级控制。同化二氧化碳同位素特征的部分配准(相对于其他溶解的无机碳物种具有重的同位素组成)被证实是在新叶藻科球岩中记录的生命效应背后的主要机制。我们的数据表明,生长辐照度对18O和13C生命效应的表达起着重要作用,范围从低光条件下的有限(接近平衡成分)到高生长辐照度下氧同位素3‰的偏移,例如在实验室培养中通常施加的光饱和条件下发现的那些。这突出了在将球岩石的氧同位素组成转化为温度估计时考虑环境控制的重要性。此外,我们的校准表明,基于烷烃的CO2古气压计可以通过结合新生代有机/方解石的配对测量来改进。
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引用次数: 22
Maximizing the value of historical bedrock field observations: An example from northwest Canada 最大化历史基岩野外观测的价值:以加拿大西北部为例
Pub Date : 2015-06-01 DOI: 10.1016/j.grj.2015.01.004
Karen M. Fallas, Robert B. MacNaughton, Matthew J. Sommers

Historical bedrock field observations have potential for significant value to the scientific community and the public if they can be rescued from physical records stored in archives of scientific research institutions. A set of historical records from ‘Operation Norman’, a bedrock mapping activity conducted in northwestern Canada by the Geological Survey of Canada (GSC) from 1968 to 1970, was identified as suitable for data rescue and incorporation into a GIS geodatabase. These observational data, including field stations, lithology descriptions, structural measurements, measured section locations, and fossil localities, were digitized as geospatial features with attributes assigned according to the observation records. Over 90% of the original observations were successfully rescued in this manner, allowing for effective incorporation with newer observations. Lack of reliable location information for field observations was the primary impediment to effective data rescue. Access to original participants in Operation Norman was particularly helpful in ensuring successful data rescue, as was the excellent state in which research materials had been curated. The resulting dataset of combined historical and recent observations provides improved distribution of observations to constrain geological analysis and map interpretation. Rescued data from Operation Norman have been incorporated in new bedrock map compilations and other scientific publications.

如果能从科研机构档案中保存的实物记录中抢救出来,历史基岩实地观测对科学界和公众具有重大价值。“诺曼行动”是加拿大地质调查局(GSC)于1968年至1970年在加拿大西北部进行的一项基岩测绘活动,其中一组历史记录被认为适合于数据救援并纳入GIS地理数据库。这些观测数据,包括野外台站、岩性描述、构造测量、测量剖面位置和化石位置,被数字化为地理空间特征,并根据观测记录分配属性。通过这种方式,90%以上的原始观测数据被成功地挽救出来,从而可以有效地与新观测数据相结合。缺乏可靠的现场观测位置信息是有效抢救数据的主要障碍。接触诺曼行动的原始参与者对确保成功的数据救援特别有帮助,研究材料的精心整理也是如此。结果数据集结合了历史和最近的观测,提供了更好的观测分布,以约束地质分析和地图解释。从诺曼行动中获得的数据已被纳入新的基岩地图汇编和其他科学出版物中。
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引用次数: 6
Framework for multiple hypothesis testing improves the use of legacy data in structural geological modeling 多假设检验框架改进了构造地质建模中遗留数据的使用
Pub Date : 2015-06-01 DOI: 10.1016/j.grj.2015.04.001
Soazig Corbel , J. Florian Wellmann

Geological models, as structural representations of the subsurface, are increasingly used for regional scale geological analyses and research studies. In this context, it is often essential to use geological legacy data, for example in the form of printed well logs, seismic sections, or maps and interpreted cross-sections from previous reports. A problem when using this type of data is that standard modeling methods and workflows are optimized towards applications in hydrocarbon and mineral exploration where data are usually newly acquired and of a high quality. Although recent developments address the modeling side for regional models with novel concepts and ideas, the possibility to change the workflow on a conceptual level has, to date, not been addressed.

We examine here how we can use legacy data more efficiently and sustainably, in a model construction workflow that leaves the typical sequential path of model development. In the common approach, a single best-fit model is continuously updated or refined when additional data become available. We test here the application of a parallel type of model construction where multiple models can be generated on the basis of different input data sets. Geological data and models are strictly separated, and this allows us to (a) use geological models to test quickly the spatial consistency of different geological data sets, and (b) to allow for an approach where we finally obtain multiple geological models as different hypotheses about the subsurface structural setting. Both aspects are especially important for the application of legacy data, as the data quality is always difficult to assess.

The concept is applied to a geological model project of the Perth Basin, Australia, where we show how it enables us to quickly revise and update the (previously constructed) model with additional data (e.g. newly available digitized legacy data), to evaluate the spatial consistency between different legacy data sets and interpretations, and to test different hypotheses. In our point of view, this is an important aspect towards a sustainable approach for geological modeling as it allows a very flexible and transparent use of different data sets for model construction – and therefore a more sustainable use of legacy data itself in the increasing use of subsurface representations using 3D geological models.

地质模型作为地下构造的表征,越来越多地用于区域尺度的地质分析和研究。在这种情况下,通常必须使用地质遗留数据,例如打印的测井曲线、地震剖面、地图和以前报告的解释剖面。使用这类数据的一个问题是,标准建模方法和工作流程针对碳氢化合物和矿物勘探的应用进行了优化,这些应用通常是新获得的高质量数据。尽管最近的开发利用新颖的概念和想法解决了区域模型的建模问题,但是到目前为止,还没有解决在概念级别上更改工作流的可能性。在这里,我们将研究如何在模型构建工作流中更有效和可持续地使用遗留数据,该工作流离开了模型开发的典型顺序路径。在常见的方法中,当有额外的数据可用时,单个最佳拟合模型会不断更新或改进。我们在这里测试了并行类型的模型构建的应用程序,其中可以根据不同的输入数据集生成多个模型。地质数据和模型是严格分离的,这使我们能够(a)使用地质模型快速测试不同地质数据集的空间一致性,以及(b)允许我们最终获得多个地质模型作为关于地下构造背景的不同假设的方法。这两个方面对于遗留数据的应用尤其重要,因为数据质量总是难以评估。该概念应用于澳大利亚珀斯盆地的一个地质模型项目,在那里我们展示了它如何使我们能够快速修改和更新(以前构建的)模型与额外的数据(例如,新可用的数字化遗留数据),以评估不同遗留数据集和解释之间的空间一致性,并测试不同的假设。在我们看来,这是地质建模可持续方法的一个重要方面,因为它允许非常灵活和透明地使用不同的数据集进行模型构建,因此在使用3D地质模型越来越多地使用地下表示时,可以更可持续地使用遗留数据本身。
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引用次数: 5
Preservation challenges for geological data at state geological surveys 国家地质调查中地质数据保存的挑战
Pub Date : 2015-06-01 DOI: 10.1016/j.grj.2015.04.002
Sarah Ramdeen

State geological surveys are home to legacy geological data that holds value in the present. Early legislation of geological surveys often included requirements that state surveys have a museum or cabinet to house their physical collections. These collections currently include data such as cores, cuttings, thin sections and fossils. State geological surveys maintain these collections to support scientific research that has value to those in government, industry, academia and the public. Survey collections and other similar science data collections, are in danger of being lost due to various risks such as poor curation, few access points, lack of funding, and space considerations. Efforts to preserve these collections have increased, beginning with a National Research Council report in 2002 highlighting this plight, and the founding of the National Geological and Geophysical Data Preservation Program by the United States Geological Survey (USGS) in 2005. Currently, programs like EarthCube address this problem by focusing on cyberinfrastructure needs that will ease discovery and access to specimen datasets. Even with these efforts, there is still much work to be done.

Increasing preservation and ease of access requires training in data curation and preservation as well as a better understanding of the users of geological data. This paper will introduce geological collections, provide examples of preservation challenges surrounding these types of collections, and suggest future research directions. This includes collaborations with library and information scientists, archivists, museums curators, as well as cross training of domain scientists. Future management systems for these collections should provide increased discovery and access to geological data.

国家地质调查是遗留地质数据的所在地,这些数据在当前具有价值。地质调查的早期立法通常包括要求州调查有一个博物馆或橱柜来存放他们的实物收藏品。这些藏品目前包括岩心、岩屑、薄片和化石等数据。国家地质调查局保存这些藏品,以支持对政府、工业、学术界和公众有价值的科学研究。由于管理不善、存取点少、缺乏资金和空间考虑等各种风险,调查收集和其他类似的科学数据收集有丢失的危险。2002年,美国国家研究委员会的一份报告强调了这一困境,2005年,美国地质调查局(USGS)成立了国家地质和地球物理数据保存计划,保护这些藏品的努力有所增加。目前,像EarthCube这样的项目通过关注网络基础设施需求来解决这个问题,这些需求将简化对样本数据集的发现和访问。即使有了这些努力,仍有许多工作要做。增加保存和方便获取需要在数据管理和保存方面进行培训,以及更好地了解地质数据的用户。本文将介绍地质藏品,提供围绕这些类型的藏品的保存挑战的例子,并提出未来的研究方向。这包括与图书馆和信息科学家、档案管理员、博物馆馆长的合作,以及领域科学家的交叉培训。未来的地质资料管理系统应能提供更多的地质资料的发现和获取。
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引用次数: 7
Seismic shothole drillers’ lithostratigraphic logs: Unearthing a wealth of regional geoscience information in northwestern Canada 地震钻孔钻井人员的岩石地层测井:在加拿大西北部发掘了丰富的区域地球科学信息
Pub Date : 2015-06-01 DOI: 10.1016/j.grj.2015.01.005
I. Rod Smith

Seismic shothole drillers’ logs, record the near-surface (avg. 18.6 m deep) lithostratigraphy encountered when drilling holes to place explosive charges. These records offer a largely unrecognized wealth of geoscience information in areas for which little may be otherwise known. Stored in the Basic Files archives of petroleum exploration and seismic acquisition companies, this study first convinced companies of the potential utility of this data, then recovered the hard copy and digitally scanned records (paper, fiche, microfilm) and rendered these into a digital database and GIS. The final database of 343,989 records provides the largest source of geoscience information of its kind in northwestern Canada, and in many cases contains unique and original records on a host of subjects including surficial-, bedrock-, and hydro-geology, permafrost, and geohazards. The drillers’ log records have further been used to create geospatial models of drift, till, muskeg, massive ice and ground ice thicknesses, and continue to be applied to new avenues of research such as temporal variations of bottomfast ice extents in offshore shallow marine environments. Published in freely downloadable Geological Survey of Canada Open File reports and providing commonly used database and GIS file formats, this data rescue exercise preserves and greatly enhances what was becoming an increasingly discarded corporate data set of unrecognized potential.

地震钻孔钻井人员的测井记录了在钻孔放置炸药时所遇到的近地表(平均18.6米深)岩石地层。这些记录提供了大量未被认识到的地球科学信息,这些信息在其他方面可能知之甚少。这项研究储存在石油勘探和地震采集公司的基本档案中,首先使公司相信这些数据的潜在用途,然后恢复硬拷贝和数字扫描记录(纸张、胶片、缩微胶片),并将其转化为数字数据库和GIS。最终数据库的343,989条记录提供了加拿大西北部同类地球科学信息的最大来源,并且在许多情况下包含了许多主题的独特和原始记录,包括地表、基岩、水文地质、永久冻土和地质灾害。钻井人员的测井记录已进一步用于创建漂移、till、muskeg、大块冰和地面冰厚度的地理空间模型,并继续应用于新的研究途径,如近海浅海环境中底部冰范围的时间变化。加拿大地质调查局公开文件报告可免费下载,并提供常用的数据库和GIS文件格式,这项数据救援工作保留并极大地增强了日益被丢弃的企业数据集,这些数据集具有未被认识到的潜力。
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引用次数: 5
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