As the demand for electrification of means of transportation and storage of electrical energy for later use is skyrocketing, rechargeable Li-ion batteries (LIBs) are at the heart of this revolution. Acknowledging the carbon footprints, environmental concerns and cost of the commercial cathode materials, this is the high time to advocate sustainable alternatives. This review aims at establishing the potential of organic redox-active molecules as a burgeoning class of sustainable solid cathode materials for LIBs. The materials are classified according to their structural features (molecules, metallo-organic complexes, and organic/metal–organic frameworks) and electrochemical performance to lay emphasis on practical applications and bottlenecks in commercialization. However, these materials are still in early stages of development, and new frontiers have been explored in the last five years.
{"title":"New Avenues for Organic Redox Materials as Sustainable Lithium-ion Battery Cathodes","authors":"Deepak Gupta, Shilpasubhashini Gupta, A. Vlad","doi":"10.1055/s-0042-1757981","DOIUrl":"https://doi.org/10.1055/s-0042-1757981","url":null,"abstract":"As the demand for electrification of means of transportation and storage of electrical energy for later use is skyrocketing, rechargeable Li-ion batteries (LIBs) are at the heart of this revolution. Acknowledging the carbon footprints, environmental concerns and cost of the commercial cathode materials, this is the high time to advocate sustainable alternatives. This review aims at establishing the potential of organic redox-active molecules as a burgeoning class of sustainable solid cathode materials for LIBs. The materials are classified according to their structural features (molecules, metallo-organic complexes, and organic/metal–organic frameworks) and electrochemical performance to lay emphasis on practical applications and bottlenecks in commercialization. However, these materials are still in early stages of development, and new frontiers have been explored in the last five years.","PeriodicalId":93348,"journal":{"name":"Organic Materials","volume":"5 1","pages":"21 - 34"},"PeriodicalIF":0.0,"publicationDate":"2022-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"57975512","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The scope of a lantern-shaped, triptycene-based Pd2L4 coordination cage to encapsulate various carbon-rich guests was investigated. The cage was found to bind two molecules of corannulene and a variety of C60 derivatives in moderate to quantitative yields. Non-disruptive extraction of encapsulated fullerene derivative PC61BM from the cage was demonstrated by the simple addition of CS2 into an acetonitrile solution of the host-guest complex. This process can be accomplished in a layer-to-layer fashion, and thus, the recovered cage can be further utilized in a recycling process. As this self-assembled host is readily synthesized and able to transfer fullerenes and a range of its derivatives into polar organic solvents, it allows to facilitate purification, chemical modification and solid-state processing of fullerenes for a range of materials applications.
{"title":"Guest Encapsulation Scope of a Triptycene-Based Pd 2 L 4 Coordination Cage","authors":"S. Hasegawa, Ananya Baksi, Bin Chen, G. Clever","doi":"10.1055/a-1953-0155","DOIUrl":"https://doi.org/10.1055/a-1953-0155","url":null,"abstract":"The scope of a lantern-shaped, triptycene-based Pd2L4 coordination cage to encapsulate various carbon-rich guests was investigated. The cage was found to bind two molecules of corannulene and a variety of C60 derivatives in moderate to quantitative yields. Non-disruptive extraction of encapsulated fullerene derivative PC61BM from the cage was demonstrated by the simple addition of CS2 into an acetonitrile solution of the host-guest complex. This process can be accomplished in a layer-to-layer fashion, and thus, the recovered cage can be further utilized in a recycling process. As this self-assembled host is readily synthesized and able to transfer fullerenes and a range of its derivatives into polar organic solvents, it allows to facilitate purification, chemical modification and solid-state processing of fullerenes for a range of materials applications.","PeriodicalId":93348,"journal":{"name":"Organic Materials","volume":"4 1","pages":"222 - 227"},"PeriodicalIF":0.0,"publicationDate":"2022-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48562481","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Christoph Lorenz, Astrid Vogt, J. Millán, E. Mena‐Osteritz, P. Bäuerle
Herein, a novel and versatile method for the synthesis of N-heteroarylated dithieno[3,2-b:2,3’-d]pyrroles (DTP) is reported. By microwave-assisted Cu-catalyzed coupling of parent H-DTP 1 with 5- and 6-membered heteroaromatic halides a variety of novel N-functionalized DTPs was obtained. Supported by quantum chemical calculations and X-ray structure analysis, structural and optoelectronic properties of the π-conjugated systems were investigated and led to valuable structure-property relationships. Selected derivatives were electropolymerized to corresponding conducting DTP-polymers.
{"title":"Broadly Applicable Synthesis of Heteroarylated Dithieno[3,2- b :2′,3′- d ]pyrroles for Advanced Organic Materials – Part 1: Conducting Electropolymers","authors":"Christoph Lorenz, Astrid Vogt, J. Millán, E. Mena‐Osteritz, P. Bäuerle","doi":"10.1055/a-1972-5895","DOIUrl":"https://doi.org/10.1055/a-1972-5895","url":null,"abstract":"Herein, a novel and versatile method for the synthesis of N-heteroarylated dithieno[3,2-b:2,3’-d]pyrroles (DTP) is reported. By microwave-assisted Cu-catalyzed coupling of parent H-DTP 1 with 5- and 6-membered heteroaromatic halides a variety of novel N-functionalized DTPs was obtained. Supported by quantum chemical calculations and X-ray structure analysis, structural and optoelectronic properties of the π-conjugated systems were investigated and led to valuable structure-property relationships. Selected derivatives were electropolymerized to corresponding conducting DTP-polymers.","PeriodicalId":93348,"journal":{"name":"Organic Materials","volume":"5 1","pages":"35 - 47"},"PeriodicalIF":0.0,"publicationDate":"2022-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45710417","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Masaud Almalki, Christoph Lorenz, Astrid Vogt, A. Alanazi, Jing Gao, S. Zakeeruddin, P. Bäuerle, F. Eickemeyer, M. Grätzel
Functionalization of heteroarylated dithieno[3,2-b:2’,3’-d]pyrroles (DTP) by triarylamines was elaborated to result in novel hole transport materials (HTMs) for perovskite solar cells. The new HTMs showed promising photovoltaic performance with efficiencies exceeding 18%. A thorough investigation of the electronic and opto-electronic properties revealed that the main efficiency loss mechanisms are not related to the pristine HTM materials but to the suboptimal interface passivation and HTM doping. We provide an optimization strategy for those device fabrication factors, which could render these new materials a potential replacement of current state-of-the-art HTMs.
{"title":"Broadly Applicable Synthesis of Heteroarylated Dithieno[3,2- b :2′,3′- d ]pyrroles for Advanced Organic Materials – Part 2: Hole-Transporting Materials for Perovskite Solar Cells","authors":"Masaud Almalki, Christoph Lorenz, Astrid Vogt, A. Alanazi, Jing Gao, S. Zakeeruddin, P. Bäuerle, F. Eickemeyer, M. Grätzel","doi":"10.1055/a-1972-5978","DOIUrl":"https://doi.org/10.1055/a-1972-5978","url":null,"abstract":"Functionalization of heteroarylated dithieno[3,2-b:2’,3’-d]pyrroles (DTP) by triarylamines was elaborated to result in novel hole transport materials (HTMs) for perovskite solar cells. The new HTMs showed promising photovoltaic performance with efficiencies exceeding 18%. A thorough investigation of the electronic and opto-electronic properties revealed that the main efficiency loss mechanisms are not related to the pristine HTM materials but to the suboptimal interface passivation and HTM doping. We provide an optimization strategy for those device fabrication factors, which could render these new materials a potential replacement of current state-of-the-art HTMs.","PeriodicalId":93348,"journal":{"name":"Organic Materials","volume":"5 1","pages":"48 - 58"},"PeriodicalIF":0.0,"publicationDate":"2022-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44352240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Excimer-containing polymers with supramolecular mechanochromism are an attractive and well-investigated class of mechanoresponsive materials. However, only recently steps toward mechanophore-like mechanochromic systems that are anchored within the parent polymer structure and that show defined optical transitions on the molecular scale have been reported. However, the multi-step syntheses of these constructs are tedious. Here we report the development of a series of pyrene-based macrocrosslinkers that display supramolecular mechanochromism and are readily synthesized from mostly commercial reagents. We incorporate the water-soluble macrocrosslinkers in hydrogel networks and demonstrate their reversible mechanochromic behavior in the elastic deformation regime.
{"title":"Pyrene-Based Macrocrosslinkers with Supramolecular Mechanochromism for Elastic Deformation Sensing in Hydrogel Networks","authors":"Dustin Rasch, Robert Göstl","doi":"10.1055/s-0042-1757972","DOIUrl":"https://doi.org/10.1055/s-0042-1757972","url":null,"abstract":"Excimer-containing polymers with supramolecular mechanochromism are an attractive and well-investigated class of mechanoresponsive materials. However, only recently steps toward mechanophore-like mechanochromic systems that are anchored within the parent polymer structure and that show defined optical transitions on the molecular scale have been reported. However, the multi-step syntheses of these constructs are tedious. Here we report the development of a series of pyrene-based macrocrosslinkers that display supramolecular mechanochromism and are readily synthesized from mostly commercial reagents. We incorporate the water-soluble macrocrosslinkers in hydrogel networks and demonstrate their reversible mechanochromic behavior in the elastic deformation regime.","PeriodicalId":93348,"journal":{"name":"Organic Materials","volume":"4 1","pages":"170 - 177"},"PeriodicalIF":0.0,"publicationDate":"2022-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43291086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Introducing polar functionalities to polyolefin such as polyethylene and polypropylene is highly desired for improving physical properties of the otherwise non-polar material. The synthesis of stereoregular functionalized polyolefins, however, has been a relatively underdeveloped area compared to that of functionalized polyethylene because of the lack of suitable catalysts that tolerate polar groups while possessing stereoselectivity. This review summarizes recent advances concerning the access to stereoregular functionalized polyolefins, including synthetic strategies such as post-functionalization, chain transfer and direct copolymerization methods. The focus of the review lies in the copolymerization approach, in which various polar comonomers and versatile stereoselective polymerization catalysts based on both early and late transition metals are involved. Polymer properties and potential applications for these materials are simply discussed.
{"title":"Stereoselective Copolymerization of Olefin with Polar Monomers to Access Stereoregular Functionalized Polyolefins","authors":"Hongliang Mu, Zhongbao Jian","doi":"10.1055/a-1945-0777","DOIUrl":"https://doi.org/10.1055/a-1945-0777","url":null,"abstract":"Introducing polar functionalities to polyolefin such as polyethylene and polypropylene is highly desired for improving physical properties of the otherwise non-polar material. The synthesis of stereoregular functionalized polyolefins, however, has been a relatively underdeveloped area compared to that of functionalized polyethylene because of the lack of suitable catalysts that tolerate polar groups while possessing stereoselectivity. This review summarizes recent advances concerning the access to stereoregular functionalized polyolefins, including synthetic strategies such as post-functionalization, chain transfer and direct copolymerization methods. The focus of the review lies in the copolymerization approach, in which various polar comonomers and versatile stereoselective polymerization catalysts based on both early and late transition metals are involved. Polymer properties and potential applications for these materials are simply discussed.","PeriodicalId":93348,"journal":{"name":"Organic Materials","volume":"4 1","pages":"178 - 189"},"PeriodicalIF":0.0,"publicationDate":"2022-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47793131","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sunil Kumar, Mangal S Yadav, Tarkeshwar Maddeshiya, surabhi asthana, M. Jaiswal, V. Tiwari, Mrituanjay D. Pandey
A prompt and modular Cupper (I) Catalyzed Azide-Alkyne Cycloaddition (CuAAC) ‘click’ approach has been exploited for the synthesis of galactose- and mannose-coated calixarene-cored G1 generation glycodendrimers. The developed calixarene glycodendrimers were characterized by using spectral techniques (1H NMR, 13C NMR and IR). In photophysical evaluation, UV and fluorescence spectra of developed compounds were recorded in the CH3CN/ H2O.
{"title":"Click Chemistry-Inspired Synthesis and Photophysical Studies of Calix[4]arene-Cored Galactosylated and Mannosylated Glycodendrimers","authors":"Sunil Kumar, Mangal S Yadav, Tarkeshwar Maddeshiya, surabhi asthana, M. Jaiswal, V. Tiwari, Mrituanjay D. Pandey","doi":"10.1055/a-2063-1445","DOIUrl":"https://doi.org/10.1055/a-2063-1445","url":null,"abstract":"A prompt and modular Cupper (I) Catalyzed Azide-Alkyne Cycloaddition (CuAAC) ‘click’ approach has been exploited for the synthesis of galactose- and mannose-coated calixarene-cored G1 generation glycodendrimers. The developed calixarene glycodendrimers were characterized by using spectral techniques (1H NMR, 13C NMR and IR). In photophysical evaluation, UV and fluorescence spectra of developed compounds were recorded in the CH3CN/ H2O.","PeriodicalId":93348,"journal":{"name":"Organic Materials","volume":"5 1","pages":"112 - 117"},"PeriodicalIF":0.0,"publicationDate":"2022-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43715602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The temperature-dependent dual fluorescence from a single component of small organic molecules (SOMs) is very promising for the ratiometric fluorescence sensing of temperature. However, the SOM-based fluorophores typically only show one fluorescence band. It is thus very challenging to achieve dual fluorescence, let alone the dual fluorescence that is sensitive to temperature. Herein, in this short review, we briefly summarized the examples of SOM-based fluorophores exhibiting temperature-dependent dual fluorescence. Through representative examples, we mainly focus on the illustration of the intrinsic mechanisms of this unusual phenomenon, which may take place because of the presence of two local minimum conformations that are thermally equilibrated in the ground state, the presence of two local minimum conformations in the first excited state as the result of significant structural relaxation upon excitation, or the presence of thermal equilibrium between the first and second excited states. Hopefully, the discussions in this short review will provide some important guidelines for the further rational molecular design of such fluorophores.
{"title":"Temperature-Dependent Dual Fluorescence from Small Organic Molecules","authors":"Min Wang, Runxin Wang, Cui‐Hua Zhao","doi":"10.1055/a-1953-0322","DOIUrl":"https://doi.org/10.1055/a-1953-0322","url":null,"abstract":"The temperature-dependent dual fluorescence from a single component of small organic molecules (SOMs) is very promising for the ratiometric fluorescence sensing of temperature. However, the SOM-based fluorophores typically only show one fluorescence band. It is thus very challenging to achieve dual fluorescence, let alone the dual fluorescence that is sensitive to temperature. Herein, in this short review, we briefly summarized the examples of SOM-based fluorophores exhibiting temperature-dependent dual fluorescence. Through representative examples, we mainly focus on the illustration of the intrinsic mechanisms of this unusual phenomenon, which may take place because of the presence of two local minimum conformations that are thermally equilibrated in the ground state, the presence of two local minimum conformations in the first excited state as the result of significant structural relaxation upon excitation, or the presence of thermal equilibrium between the first and second excited states. Hopefully, the discussions in this short review will provide some important guidelines for the further rational molecular design of such fluorophores.","PeriodicalId":93348,"journal":{"name":"Organic Materials","volume":"4 1","pages":"204 - 215"},"PeriodicalIF":0.0,"publicationDate":"2022-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43057044","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nisha Odedara, Niteen Borane, R. Patel, Rajamouli Boddula
Since 1987 in the field of optoelectronics, organic light-emitting diodes (OLEDs) have secured their position because of their extreme use in panels of lighting applications such as TV and smartphone displays. At present, OLEDs are at top-notch position in the lighting market for their promising features. The field of OLEDs is rapidly growing day by day in academia and industry due to the success of OLEDs in the form of excellent efficiency, feasible methods, excellent lifetime, color purity, and superb device architecture. As a result, OLEDs are new profitable leading devices of the 21st century. However, the OLED industry has evolved in optoelectronics in the last 30 years and is advancing rapidly just because of the development in OLED materials (fluorescent, phosphorescent, thermally activated delayed fluorescent, and blue light-emitting materials). Blue light-emitting materials have achieved incredible popularity nationally and internationally. At the international level, USA, Japan, Korea, and Germany are at the top of the list in the production of OLEDs. India has also seen rapid progress in OLED development in the last 12 years and details of research in blue OLEDs by key players of India are involved in this report.1 Introduction1.1 OLED Construction1.2 Working of OLED2 OLED Development2.1 Historical Background of OLED2.1.1 International Status2.1.2 National Status3 Progress of Blue Emitters in India4 Present Scenario of Blue OLEDs5 Conclusions and Outlook
{"title":"A Review on the Milestones of Blue Light-Emitting Materials in India","authors":"Nisha Odedara, Niteen Borane, R. Patel, Rajamouli Boddula","doi":"10.1055/s-0042-1757980","DOIUrl":"https://doi.org/10.1055/s-0042-1757980","url":null,"abstract":"Since 1987 in the field of optoelectronics, organic light-emitting diodes (OLEDs) have secured their position because of their extreme use in panels of lighting applications such as TV and smartphone displays. At present, OLEDs are at top-notch position in the lighting market for their promising features. The field of OLEDs is rapidly growing day by day in academia and industry due to the success of OLEDs in the form of excellent efficiency, feasible methods, excellent lifetime, color purity, and superb device architecture. As a result, OLEDs are new profitable leading devices of the 21st century. However, the OLED industry has evolved in optoelectronics in the last 30 years and is advancing rapidly just because of the development in OLED materials (fluorescent, phosphorescent, thermally activated delayed fluorescent, and blue light-emitting materials). Blue light-emitting materials have achieved incredible popularity nationally and internationally. At the international level, USA, Japan, Korea, and Germany are at the top of the list in the production of OLEDs. India has also seen rapid progress in OLED development in the last 12 years and details of research in blue OLEDs by key players of India are involved in this report.1 Introduction1.1 OLED Construction1.2 Working of OLED2 OLED Development2.1 Historical Background of OLED2.1.1 International Status2.1.2 National Status3 Progress of Blue Emitters in India4 Present Scenario of Blue OLEDs5 Conclusions and Outlook","PeriodicalId":93348,"journal":{"name":"Organic Materials","volume":"5 1","pages":"1 - 20"},"PeriodicalIF":0.0,"publicationDate":"2022-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44078026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Carolina Braga Barbosa, Patrick Gass, Daniel J. Hamsch, Stefan Kubik
Qualitative NMR spectroscopic and quantitative calorimetric binding studies were performed to characterize the interaction of nontoxic mimics of the V-type nerve agent VX and the Novichok nerve agent A-234 with a series of receptors in 100 mM aqueous phosphate buffer at pH 7.4 and 37 °C. These investigations provided information about the preferred geometry with which the nerve agent mimics are included into the receptor cavities and about the stability of the complexes formed. According to the results, the positively charged VX mimic prefers to bind to cation receptors such as sulfonated calixarenes and an acyclic cucurbituril but does not noticeably interact with cyclodextrins. While binding to the acyclic cucurbituril is stronger than that to calixarenes, the mode of inclusion into the sulfonatocalix[4]arene cavity is better suited for the development of scavengers that bind and detoxify V-type nerve agents. The neutral Novichok mimic, on the other hand, only interacts with the acyclic cucurbituril with a strength required for scavenger development. These binding studies thus provided guidelines for the further development of nerve agent scavengers.
{"title":"Characterization of the Interaction of Nerve Agent Mimics with Selected Synthetic Receptors","authors":"Carolina Braga Barbosa, Patrick Gass, Daniel J. Hamsch, Stefan Kubik","doi":"10.1055/a-1939-6455","DOIUrl":"https://doi.org/10.1055/a-1939-6455","url":null,"abstract":"Qualitative NMR spectroscopic and quantitative calorimetric binding studies were performed to characterize the interaction of nontoxic mimics of the V-type nerve agent VX and the Novichok nerve agent A-234 with a series of receptors in 100 mM aqueous phosphate buffer at pH 7.4 and 37 °C. These investigations provided information about the preferred geometry with which the nerve agent mimics are included into the receptor cavities and about the stability of the complexes formed. According to the results, the positively charged VX mimic prefers to bind to cation receptors such as sulfonated calixarenes and an acyclic cucurbituril but does not noticeably interact with cyclodextrins. While binding to the acyclic cucurbituril is stronger than that to calixarenes, the mode of inclusion into the sulfonatocalix[4]arene cavity is better suited for the development of scavengers that bind and detoxify V-type nerve agents. The neutral Novichok mimic, on the other hand, only interacts with the acyclic cucurbituril with a strength required for scavenger development. These binding studies thus provided guidelines for the further development of nerve agent scavengers.","PeriodicalId":93348,"journal":{"name":"Organic Materials","volume":"4 1","pages":"146 - 152"},"PeriodicalIF":0.0,"publicationDate":"2022-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48104575","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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