首页 > 最新文献

ACS agricultural science & technology最新文献

英文 中文
Seed Priming with Silver Ions Improves Growth and Physicochemical Features of Rice Plants (Oryza sativa L.) under Copper Stress 用银离子为种子打底可改善铜胁迫下水稻(Oryza sativa L.)植株的生长和理化特性
IF 2.3 Q1 AGRICULTURE, MULTIDISCIPLINARY Pub Date : 2024-06-18 DOI: 10.1021/acsagscitech.4c00177
Chunyi Mu, Danyu Huang, Min Wang, Yuliang Li, Xiaolei Wang, Dunfeng Si, Cheng Cheng, Chenghao Ge*, Lijuan Zhao and Dongmei Zhou*, 

Copper (Cu) contamination in paddy fields leads to excessive Cu in rice grains and a low grain yield, posing a serious threat to sustainable agricultural production. We propose the application of seed priming with silver ions (Ag+) as biostimulants to trigger reactive oxygen species (ROS) production and enhance immune responses, thereby improving rice resistance to Cu stress. The results showed that seed priming with 10 μM Ag+ significantly improved rice tolerance to Cu, increased the fresh biomass by 22.1%, and reduced the Cu content in the roots and shoots by 25.3 and 13.4%, respectively, compared to the hydropriming treatments. Furthermore, seed priming with 10 μM Ag+ increased nutrient uptake in rice, leading to higher contents of Ca (15.1%), Fe (14.9%), and Mg (10.2%) in the shoots as well as Ca (21.0%), Mn (37.0%), and Mg (29.1%) in the roots. More Cu was immobilized in the root cell wall, thereby significantly enhancing root cell viability, maintaining the root morphology, and reducing malondialdehyde accumulation. Transcriptomics analyses revealed that Ag+-priming activated the phytohormone signal transduction and mitogen-activated protein kinase (MAPK) signaling pathway and other kinase signaling pathways in rice roots under Cu stress. These signals triggered the upregulation of defense-related gene expression, including the Cu vesicle transporter gene, oxidoreductase activity genes, and hydrogen peroxide catabolic process genes, amino acid metabolism, purine metabolism, and starch and sucrose metabolism. This study suggests that seed Ag+-priming is a simple and effective way to alleviate Cu toxicity and decrease Cu accumulation in rice, which ensures safe rice production in a sustainable way.

水稻田中的铜(Cu)污染会导致水稻籽粒中铜含量过高、产量过低,对可持续农业生产构成严重威胁。我们建议应用银离子(Ag+)作为生物刺激剂进行种子诱导,以引发活性氧(ROS)产生并增强免疫反应,从而提高水稻对铜胁迫的抗性。结果表明,与水刺处理相比,用 10 μM Ag+ 引种能显著提高水稻对铜的耐受性,新鲜生物量增加了 22.1%,根和芽中的铜含量分别降低了 25.3% 和 13.4%。此外,用 10 μM Ag+ 给种子打底可增加水稻对养分的吸收,从而提高芽中钙(15.1%)、铁(14.9%)和镁(10.2%)的含量,以及根中钙(21.0%)、锰(37.0%)和镁(29.1%)的含量。更多的铜被固定在根细胞壁中,从而显著提高了根细胞的活力,保持了根的形态,并减少了丙二醛的积累。转录组学分析表明,Ag+-priming 激活了 Cu 胁迫下水稻根部的植物激素信号转导和丝裂原活化蛋白激酶(MAPK)信号通路以及其他激酶信号通路。这些信号引发了防御相关基因表达的上调,包括 Cu 囊泡转运体基因、氧化还原酶活性基因、过氧化氢分解过程基因、氨基酸代谢、嘌呤代谢、淀粉和蔗糖代谢等。这项研究表明,种子Ag+-priming是缓解水稻Cu毒性和减少Cu积累的一种简单而有效的方法,可确保水稻的可持续安全生产。
{"title":"Seed Priming with Silver Ions Improves Growth and Physicochemical Features of Rice Plants (Oryza sativa L.) under Copper Stress","authors":"Chunyi Mu,&nbsp;Danyu Huang,&nbsp;Min Wang,&nbsp;Yuliang Li,&nbsp;Xiaolei Wang,&nbsp;Dunfeng Si,&nbsp;Cheng Cheng,&nbsp;Chenghao Ge*,&nbsp;Lijuan Zhao and Dongmei Zhou*,&nbsp;","doi":"10.1021/acsagscitech.4c00177","DOIUrl":"https://doi.org/10.1021/acsagscitech.4c00177","url":null,"abstract":"<p >Copper (Cu) contamination in paddy fields leads to excessive Cu in rice grains and a low grain yield, posing a serious threat to sustainable agricultural production. We propose the application of seed priming with silver ions (Ag<sup>+</sup>) as biostimulants to trigger reactive oxygen species (ROS) production and enhance immune responses, thereby improving rice resistance to Cu stress. The results showed that seed priming with 10 μM Ag<sup>+</sup> significantly improved rice tolerance to Cu, increased the fresh biomass by 22.1%, and reduced the Cu content in the roots and shoots by 25.3 and 13.4%, respectively, compared to the hydropriming treatments. Furthermore, seed priming with 10 μM Ag<sup>+</sup> increased nutrient uptake in rice, leading to higher contents of Ca (15.1%), Fe (14.9%), and Mg (10.2%) in the shoots as well as Ca (21.0%), Mn (37.0%), and Mg (29.1%) in the roots. More Cu was immobilized in the root cell wall, thereby significantly enhancing root cell viability, maintaining the root morphology, and reducing malondialdehyde accumulation. Transcriptomics analyses revealed that Ag<sup>+</sup>-priming activated the phytohormone signal transduction and mitogen-activated protein kinase (MAPK) signaling pathway and other kinase signaling pathways in rice roots under Cu stress. These signals triggered the upregulation of defense-related gene expression, including the Cu vesicle transporter gene, oxidoreductase activity genes, and hydrogen peroxide catabolic process genes, amino acid metabolism, purine metabolism, and starch and sucrose metabolism. This study suggests that seed Ag<sup>+</sup>-priming is a simple and effective way to alleviate Cu toxicity and decrease Cu accumulation in rice, which ensures safe rice production in a sustainable way.</p>","PeriodicalId":93846,"journal":{"name":"ACS agricultural science & technology","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141622190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Environmental Impact of Outdoor Cannabis Production 户外大麻生产对环境的影响
IF 2.3 Q1 AGRICULTURE, MULTIDISCIPLINARY Pub Date : 2024-06-10 DOI: 10.1021/acsagscitech.4c00054
Vincent Desaulniers Brousseau, Benjamin P. Goldstein, Charlotte Sedlock and Mark Lefsrud*, 

Environmental impacts of cannabis production are of increasing concern because it is a newly legal and growing industry. Although a handful of studies have quantified the impacts of indoor production, very little is known about the impact of outdoor cannabis agriculture. Outdoor production typically uses little direct energy but can require significant fertilizer and other inputs due to dissipative losses via runoff and mineralization. Conversely, fertilizer high in nitrogen can be counterproductive, as it produces flowers with decreased cannabinoid content. This study has two aims: (1) To identify reduced-fertilizer regimes that provide optimal cannabis flower yields with reduced inputs and (2) to quantify how this shifts greenhouse gas emissions, resource depletion (fossil and metal), terrestrial acidification, and the eutrophication potential of outdoor cannabis production. Primary data from a fertilizer response trial are incorporated into a life-cycle assessment model. Results show that outdoor cannabis agriculture can be 50 times less carbon-emitting than indoor production. Dissemination of this knowledge is of utmost importance for producers, consumers, and government officials in nations that have either legalized or will legalize cannabis production.

大麻生产对环境的影响日益受到关注,因为这是一个新近合法且不断发展的行业。虽然有少数研究对室内生产的影响进行了量化,但对室外大麻农业的影响却知之甚少。室外生产通常很少直接使用能源,但由于径流和矿化造成的耗散损失,可能需要大量肥料和其他投入。相反,含氮量高的肥料可能会适得其反,因为它产生的花朵大麻素含量会降低。这项研究有两个目的:(1) 确定减少肥料的制度,以便在减少投入的情况下获得最佳大麻花产量;(2) 量化这种制度如何改变室外大麻生产的温室气体排放、资源损耗(化石和金属)、陆地酸化和富营养化潜力。肥料反应试验的原始数据被纳入生命周期评估模型。结果表明,室外大麻农业的碳排放量比室内生产低 50 倍。对于已经或即将使大麻生产合法化的国家的生产者、消费者和政府官员来说,传播这方面的知识至关重要。
{"title":"Environmental Impact of Outdoor Cannabis Production","authors":"Vincent Desaulniers Brousseau,&nbsp;Benjamin P. Goldstein,&nbsp;Charlotte Sedlock and Mark Lefsrud*,&nbsp;","doi":"10.1021/acsagscitech.4c00054","DOIUrl":"10.1021/acsagscitech.4c00054","url":null,"abstract":"<p >Environmental impacts of cannabis production are of increasing concern because it is a newly legal and growing industry. Although a handful of studies have quantified the impacts of indoor production, very little is known about the impact of outdoor cannabis agriculture. Outdoor production typically uses little direct energy but can require significant fertilizer and other inputs due to dissipative losses via runoff and mineralization. Conversely, fertilizer high in nitrogen can be counterproductive, as it produces flowers with decreased cannabinoid content. This study has two aims: (1) To identify reduced-fertilizer regimes that provide optimal cannabis flower yields with reduced inputs and (2) to quantify how this shifts greenhouse gas emissions, resource depletion (fossil and metal), terrestrial acidification, and the eutrophication potential of outdoor cannabis production. Primary data from a fertilizer response trial are incorporated into a life-cycle assessment model. Results show that outdoor cannabis agriculture can be 50 times less carbon-emitting than indoor production. Dissemination of this knowledge is of utmost importance for producers, consumers, and government officials in nations that have either legalized or will legalize cannabis production.</p>","PeriodicalId":93846,"journal":{"name":"ACS agricultural science & technology","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141363329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Detection of Tylosin Resistance in Fusobacterium necrophorum subspecies necrophorum 检测坏死杆菌亚种对泰乐菌素的抗药性
IF 2.3 Q1 AGRICULTURE, MULTIDISCIPLINARY Pub Date : 2024-06-07 DOI: 10.1021/acsagscitech.4c00159
Cory Schwarz, Jacques Mathieu*, Jenny Laverde Gomez, Marina Tikhonova, T. G. Nagaraja and Pedro J. J. Alvarez, 

In-feed tylosin, a macrolide, is widely used to prevent liver abscessation in feedlot cattle by repressing growth of ruminal Fusobacterium necrophorum. Although tylosin has been used for almost five decades, no resistant F. necrophorum subsp. necrophorum strain has ever been isolated. Here, we report two strains (FN37 and FN38) previously isolated from abscessed livers containing several antibiotic resistance genes: cfr(C), tet(O), ant(6)-Ia, and erm(B), the latter of which confers resistance to macrolides via modification of the ribosome. To evaluate if erm(B) conferred a phenotypic advantage, four strains (deposited strain ATCC 25286, ruminal isolate FNC, and abscess isolates FN37 and FN38) were tested for their responses to tylosin. The two erm(B)-harboring strains showed resistance at concentrations commonly found within the ruminal compartment under current dosing guidelines, and in the case of FN38, up to 100 μg/mL tylosin was tolerated. Tylosin susceptibility varied depending on the growth phase (stationary vs logarithmic) and preconditioning (growth in medium containing tylosin at a concentration of 1 μg/mL) of the inoculum in all four strains, but the two harboring the erm(B) gene demonstrated robust resistance. This discovery along with whole genome sequencing and preliminary annotation indicates horizontal gene transfer and acquisition of resistance genes, highlighting the need to revisit antimicrobial strategies for the feedlot cattle industry.

饲用泰乐菌素是一种大环内酯类药物,通过抑制瘤胃坏死镰刀菌的生长,被广泛用于预防饲养场牛的肝脓肿。尽管泰乐菌素已使用了近五十年,但从未分离出耐药的坏死杆菌亚种菌株。在此,我们报告了先前从脓肿肝脏中分离出的两株菌株(FN37 和 FN38),它们含有多种抗生素耐药基因:cfr(C)、tet(O)、ant(6)-Ia 和 erm(B),后者通过修饰核糖体而产生对大环内酯类药物的耐药性。为了评估erm(B)是否会带来表型优势,我们测试了四个菌株(存放菌株ATCC 25286、瘤胃分离物FNC、脓肿分离物FN37和FN38)对泰乐菌素的反应。两株erm(B)-harboring菌株在瘤胃中常见的浓度下表现出抗药性,而在FN38的情况下,可耐受高达100 μg/mL的泰乐菌素。所有四种菌株对泰乐菌素的敏感性因生长阶段(静止期与对数期)和接种物的预处理(在含有浓度为 1 μg/mL 泰乐菌素的培养基中生长)而异,但携带 erm(B) 基因的两种菌株表现出很强的抗性。这一发现以及全基因组测序和初步注释表明了抗性基因的水平基因转移和获得,突出了重新审视饲养场养牛业抗菌策略的必要性。
{"title":"Detection of Tylosin Resistance in Fusobacterium necrophorum subspecies necrophorum","authors":"Cory Schwarz,&nbsp;Jacques Mathieu*,&nbsp;Jenny Laverde Gomez,&nbsp;Marina Tikhonova,&nbsp;T. G. Nagaraja and Pedro J. J. Alvarez,&nbsp;","doi":"10.1021/acsagscitech.4c00159","DOIUrl":"10.1021/acsagscitech.4c00159","url":null,"abstract":"<p >In-feed tylosin, a macrolide, is widely used to prevent liver abscessation in feedlot cattle by repressing growth of ruminal <i>Fusobacterium necrophorum</i>. Although tylosin has been used for almost five decades, no resistant <i>F. necrophorum</i> subsp. <i>necrophorum</i> strain has ever been isolated. Here, we report two strains (FN37 and FN38) previously isolated from abscessed livers containing several antibiotic resistance genes: <i>cfr</i>(C), <i>tet</i>(O), <i>ant</i>(6)-Ia, and <i>erm</i>(B), the latter of which confers resistance to macrolides via modification of the ribosome. To evaluate if <i>erm</i>(B) conferred a phenotypic advantage, four strains (deposited strain ATCC 25286, ruminal isolate FNC, and abscess isolates FN37 and FN38) were tested for their responses to tylosin. The two <i>erm</i>(B)-harboring strains showed resistance at concentrations commonly found within the ruminal compartment under current dosing guidelines, and in the case of FN38, up to 100 μg/mL tylosin was tolerated. Tylosin susceptibility varied depending on the growth phase (stationary vs logarithmic) and preconditioning (growth in medium containing tylosin at a concentration of 1 μg/mL) of the inoculum in all four strains, but the two harboring the <i>erm</i>(B) gene demonstrated robust resistance. This discovery along with whole genome sequencing and preliminary annotation indicates horizontal gene transfer and acquisition of resistance genes, highlighting the need to revisit antimicrobial strategies for the feedlot cattle industry.</p>","PeriodicalId":93846,"journal":{"name":"ACS agricultural science & technology","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141373591","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Artificial Intelligence for Precision and Sustainable Agricultural 人工智能促进精准和可持续农业发展
Q3 Agricultural and Biological Sciences Pub Date : 2024-06-05 DOI: 10.1021/acsagscitech.4c00290
Ramesh Raliya*, 
{"title":"Artificial Intelligence for Precision and Sustainable Agricultural","authors":"Ramesh Raliya*,&nbsp;","doi":"10.1021/acsagscitech.4c00290","DOIUrl":"https://doi.org/10.1021/acsagscitech.4c00290","url":null,"abstract":"","PeriodicalId":93846,"journal":{"name":"ACS agricultural science & technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141333924","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Plant Response to Biotic and Abiotic Stress: A Study of Adaptation Strategies in Different Glycine max Cultivars 植物对生物和非生物胁迫的反应:不同 Glycine max 栽培品种的适应策略研究
Q3 Agricultural and Biological Sciences Pub Date : 2024-05-29 DOI: 10.1021/acsagscitech.4c00043
Maria Clara S. Aguiar, Marcelo M. Freitas, Carlos A. Freitas, Arlindo L. Boiça Júnior, Renato L. Carneiro and Moacir R. Forim*, 

Insects are still the main competitor of humans for food, and combined with other environmental stresses (such as hydric stress), they cause several yield losses and the reduction in crop quality. Therefore, the effects of the herbivory, hydric stress, methyl jasmonate, and the combination of these stresses on Glycine max cultivars resistant and susceptible to Spodoptera cosmioides were investigated. Chemical profile analyses of volatile and nonvolatile compounds from leaves revealed a clear influence of the stress conditions on the plant response according to the cultivar. Plants susceptible to S. cosmioides under hydric stress showed chemical variations characteristic of plant acclimation. Application of methyl jasmonate to the leaves induced resistance responses in both cultivars. The results indicated the activation of pathways such as glycolysis, tricarboxylic acid cycle, oxylipins, phenylpropanoids, and fatty acids. Thus, this study contributes to a molecular understanding of the resistance mechanisms developed in G. max cultivars.

昆虫仍然是人类食物的主要竞争者,再加上其他环境胁迫(如水胁迫),它们会造成一些产量损失和作物品质下降。因此,本研究调查了食草动物、水胁迫、茉莉酸甲酯以及这些胁迫的组合对抗性和易感稻飞虱的甘氨酸马克斯(Glycine max)栽培品种的影响。叶片中挥发性和非挥发性化合物的化学成分分析表明,不同栽培品种的胁迫条件对植物的反应有明显影响。在水胁迫条件下,易感宇宙虫的植物表现出植物适应性特征的化学变化。在两种栽培品种的叶片上施用茉莉酸甲酯都能诱导抗性反应。研究结果表明,糖酵解、三羧酸循环、氧脂质、苯丙氨酸和脂肪酸等途径被激活。因此,这项研究有助于从分子角度了解 G. max 栽培品种的抗性机制。
{"title":"Plant Response to Biotic and Abiotic Stress: A Study of Adaptation Strategies in Different Glycine max Cultivars","authors":"Maria Clara S. Aguiar,&nbsp;Marcelo M. Freitas,&nbsp;Carlos A. Freitas,&nbsp;Arlindo L. Boiça Júnior,&nbsp;Renato L. Carneiro and Moacir R. Forim*,&nbsp;","doi":"10.1021/acsagscitech.4c00043","DOIUrl":"https://doi.org/10.1021/acsagscitech.4c00043","url":null,"abstract":"<p >Insects are still the main competitor of humans for food, and combined with other environmental stresses (such as hydric stress), they cause several yield losses and the reduction in crop quality. Therefore, the effects of the herbivory, hydric stress, methyl jasmonate, and the combination of these stresses on <i>Glycine max</i> cultivars resistant and susceptible to <i>Spodoptera cosmioides</i> were investigated. Chemical profile analyses of volatile and nonvolatile compounds from leaves revealed a clear influence of the stress conditions on the plant response according to the cultivar. Plants susceptible to <i>S. cosmioides</i> under hydric stress showed chemical variations characteristic of plant acclimation. Application of methyl jasmonate to the leaves induced resistance responses in both cultivars. The results indicated the activation of pathways such as glycolysis, tricarboxylic acid cycle, oxylipins, phenylpropanoids, and fatty acids. Thus, this study contributes to a molecular understanding of the resistance mechanisms developed in <i>G. max</i> cultivars.</p>","PeriodicalId":93846,"journal":{"name":"ACS agricultural science & technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsagscitech.4c00043","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141333935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of Novel Zeolite-Based Controlled-Release Zinc Fertilizers: Synthesis, Characterization, and Release Kinetics 开发新型沸石控释锌肥:合成、表征和释放动力学
Q3 Agricultural and Biological Sciences Pub Date : 2024-05-28 DOI: 10.1021/acsagscitech.4c00251
Suman Rani, Rita Dahiya*, Vinay Kumar, Priyanka Berwal, Smriti Sihag and Anushree Jatrana, 

Increasing demand of zinc fertilizers for sustainable food production and low micronutrient fertilizer use efficiency (2–3%) advocate the development of controlled-release fertilizers to enhance the efficacy of inputs and mitigate the environmental pollution caused by leaching losses. In the present work, an ecofriendly zeolite Y-based zinc fertilizer was synthesized via a facile reflux method. The structural and morphological characteristics of the synthesized zinc fertilizer were examined by Fourier transform infrared, X-ray diffraction, field emission scanning electron microscopy–energy-dispersive X-ray spectroscopy, and Brunauer–Emmett–Teller techniques. The characterizations confirmed the presence of 4.9% (wt) zinc in the synthesized fertilizer without alteration in the zeolite framework structure. Langmuir and Freundlich models were used to study the zinc adsorption of zeolite. The Langmuir isotherm was found to best fit the experimental data with a maximum zinc adsorption capacity of 130.72 mg/g. The zinc release studies were carried out in water as well as in soil, and the zinc release mechanism was studied by fitting different release kinetic models. About 55% of the zinc was released in water in 10 days, while in soil, it was found that about 0.017% of the zinc was leached out in 21 days. The mechanism of zinc release from the zeolite-based zinc fertilizer followed the Korsmeyer–Peppas model, indicating zinc diffusion from the synthesized fertilizer as a non-Fickian process, and the zinc release in soil followed the Higuchi model, describing the zinc release through dissolution and diffusion, confirming the controlled release properties of the synthesized fertilizer. Hence, the present findings offer new opportunities for the development of zeolite Y-based fertilizers for controlled utilization of plant nutrients for environmentally friendly and sustainable agriculture.

可持续粮食生产对锌肥的需求不断增加,而微量元素肥料的使用效率却很低(2%-3%),这促使人们开发控释肥料,以提高投入品的功效,并减轻浸出损失造成的环境污染。本研究采用简便的回流法合成了一种基于沸石 Y 的生态友好型锌肥。傅立叶变换红外光谱、X 射线衍射、场发射扫描电子显微镜-能量色散 X 射线光谱和布鲁瑙尔-埃美特-泰勒技术检测了合成锌肥的结构和形态特征。表征结果证实,合成肥料中含有 4.9% (重量)的锌,而沸石框架结构没有发生改变。研究采用了 Langmuir 和 Freundlich 模型来研究沸石对锌的吸附。结果发现,Langmuir 等温线最适合实验数据,最大锌吸附容量为 130.72 毫克/克。在水中和土壤中进行了锌释放研究,并通过拟合不同的释放动力学模型研究了锌的释放机理。在水中,约 55% 的锌在 10 天内被释放;而在土壤中,约 0.017% 的锌在 21 天内被沥出。沸石锌肥的锌释放机理遵循 Korsmeyer-Peppas 模型,表明锌从合成肥料中的扩散是一个非费克式过程;锌在土壤中的释放遵循 Higuchi 模型,描述了锌通过溶解和扩散的释放过程,证实了合成肥料的控释特性。因此,本研究结果为开发基于沸石 Y 的肥料提供了新的机遇,可控制植物养分的利用,促进环境友好型和可持续农业的发展。
{"title":"Development of Novel Zeolite-Based Controlled-Release Zinc Fertilizers: Synthesis, Characterization, and Release Kinetics","authors":"Suman Rani,&nbsp;Rita Dahiya*,&nbsp;Vinay Kumar,&nbsp;Priyanka Berwal,&nbsp;Smriti Sihag and Anushree Jatrana,&nbsp;","doi":"10.1021/acsagscitech.4c00251","DOIUrl":"https://doi.org/10.1021/acsagscitech.4c00251","url":null,"abstract":"<p >Increasing demand of zinc fertilizers for sustainable food production and low micronutrient fertilizer use efficiency (2–3%) advocate the development of controlled-release fertilizers to enhance the efficacy of inputs and mitigate the environmental pollution caused by leaching losses. In the present work, an ecofriendly zeolite Y-based zinc fertilizer was synthesized via a facile reflux method. The structural and morphological characteristics of the synthesized zinc fertilizer were examined by Fourier transform infrared, X-ray diffraction, field emission scanning electron microscopy–energy-dispersive X-ray spectroscopy, and Brunauer–Emmett–Teller techniques. The characterizations confirmed the presence of 4.9% (wt) zinc in the synthesized fertilizer without alteration in the zeolite framework structure. Langmuir and Freundlich models were used to study the zinc adsorption of zeolite. The Langmuir isotherm was found to best fit the experimental data with a maximum zinc adsorption capacity of 130.72 mg/g. The zinc release studies were carried out in water as well as in soil, and the zinc release mechanism was studied by fitting different release kinetic models. About 55% of the zinc was released in water in 10 days, while in soil, it was found that about 0.017% of the zinc was leached out in 21 days. The mechanism of zinc release from the zeolite-based zinc fertilizer followed the Korsmeyer–Peppas model, indicating zinc diffusion from the synthesized fertilizer as a non-Fickian process, and the zinc release in soil followed the Higuchi model, describing the zinc release through dissolution and diffusion, confirming the controlled release properties of the synthesized fertilizer. Hence, the present findings offer new opportunities for the development of zeolite Y-based fertilizers for controlled utilization of plant nutrients for environmentally friendly and sustainable agriculture.</p>","PeriodicalId":93846,"journal":{"name":"ACS agricultural science & technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141333936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of pH-Responsive Polymeric Pesticides as Supramolecular Inclusion Complexes for Targeted Control of B. cinerea in Precision Agriculture 开发具有 pH 响应性的聚合物杀虫剂作为超分子包涵复合物,用于在精准农业中靶向控制灰葡萄孢菌
Q3 Agricultural and Biological Sciences Pub Date : 2024-05-15 DOI: 10.1021/acsagscitech.4c00117
Daihan Peng, Zhiyuan Ma, Shengxue Liu* and Xin Jia*, 

Over the past five decades, heavy reliance on pesticides in global food production has raised concerns regarding the efficiency of pest control and environmental contamination. Consequently, the development of supramolecular drug carriers based on host–guest interactions, particularly cyclodextrins, has shown promise in precision agriculture due to their predictable and adjustable properties. In this study, a series of amphiphilic random copolymers incorporating hydrophilic acrylamide and hydrophobic benzotriazole were designed and synthesized through coprecipitation to form a supramolecular inclusion complex. The copolymer and inclusion complex demonstrated pH-responsive behavior, which enabled the controlled release of benzotriazole for the targeted control of B. cinerea, a destructive phytopathogen that causes gray mold disease. The antimicrobial activity of the complex was observed to be superior in targeting specific SF9 cells compared to HepG2 cells and exhibited favorable biosafety. The biological activity and cytotoxicity of these products were evaluated, demonstrating their potential for protecting plants and fruits against B. cinerea.

过去五十年来,全球粮食生产对杀虫剂的严重依赖引发了人们对害虫控制效率和环境污染的担忧。因此,开发基于主客体相互作用的超分子药物载体,特别是环糊精,因其具有可预测和可调节的特性,在精准农业中大有可为。本研究设计并合成了一系列两亲性无规共聚物,其中包含亲水性丙烯酰胺和疏水性苯并三唑,通过共沉淀形成超分子包合物。共聚物和包合复合物具有 pH 响应特性,能够控制苯并三唑的释放,从而有针对性地控制导致灰霉病的破坏性植物病原菌 B. cinerea。据观察,与 HepG2 细胞相比,该复合物在靶向特定 SF9 细胞方面具有更强的抗菌活性,并表现出良好的生物安全性。对这些产品的生物活性和细胞毒性进行了评估,证明它们具有保护植物和水果免受灰霉病菌侵害的潜力。
{"title":"Development of pH-Responsive Polymeric Pesticides as Supramolecular Inclusion Complexes for Targeted Control of B. cinerea in Precision Agriculture","authors":"Daihan Peng,&nbsp;Zhiyuan Ma,&nbsp;Shengxue Liu* and Xin Jia*,&nbsp;","doi":"10.1021/acsagscitech.4c00117","DOIUrl":"10.1021/acsagscitech.4c00117","url":null,"abstract":"<p >Over the past five decades, heavy reliance on pesticides in global food production has raised concerns regarding the efficiency of pest control and environmental contamination. Consequently, the development of supramolecular drug carriers based on host–guest interactions, particularly cyclodextrins, has shown promise in precision agriculture due to their predictable and adjustable properties. In this study, a series of amphiphilic random copolymers incorporating hydrophilic acrylamide and hydrophobic benzotriazole were designed and synthesized through coprecipitation to form a supramolecular inclusion complex. The copolymer and inclusion complex demonstrated pH-responsive behavior, which enabled the controlled release of benzotriazole for the targeted control of <i>B. cinerea</i>, a destructive phytopathogen that causes gray mold disease. The antimicrobial activity of the complex was observed to be superior in targeting specific SF9 cells compared to HepG2 cells and exhibited favorable biosafety. The biological activity and cytotoxicity of these products were evaluated, demonstrating their potential for protecting plants and fruits against <i>B. cinerea</i>.</p>","PeriodicalId":93846,"journal":{"name":"ACS agricultural science & technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140975843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing Film Cross-Linking through VTES Copolymerization in Polymer Latex for Increasing Controlled-Release Performance of Film-Coated Fertilizer Granules 通过聚合物胶乳中的 VTES 共聚增强薄膜交联,提高包膜肥料颗粒的控释性能
Q3 Agricultural and Biological Sciences Pub Date : 2024-05-14 DOI: 10.1021/acsagscitech.4c00085
Jiuren Xie, Shaolei Zhao, Rui Tan, Ling Yang and Ting-Jie Wang*, 

To increase the controlled-release performance of film-coated fertilizer granules using polymer latex as a coating reagent, increasing the cross-linking density of the film during spray coating is crucial. In this study, vinyltriethoxysilane (VTES) was incorporated into styrene-acrylate copolymer latex, with film cross-linking achieved by the condensation of silanol groups derived from the hydrolysis of VTES. VTES-copolymerized latex-coated urea granules were prepared by spray coating in a fluidized bed. The film cross-linking density and controlled-release performance were significantly increased. The structural characteristics of the film cross-linked network were theoretically calculated and analyzed. The cross-linked network with high cross-linking density had a smaller size of mesh structure, significantly reducing the free volume of the film and increasing the diffusion resistance of nutrients. The urea diffusion coefficient across the planar film decreased from 2.74 × 10–15 to 0.125 × 10–15 m2/s when the VTES copolymerized ratio reached 10%. At a low coating amount of 4 wt %, the release period of the film-coated urea granules increased to 32 days, surpassing that of the reference sample by over 300%.

为了提高使用聚合物胶乳作为包衣试剂的薄膜包衣肥料颗粒的控释性能,在喷涂过程中提高薄膜的交联密度至关重要。本研究将乙烯基三乙氧基硅烷(VTES)加入苯乙烯-丙烯酸酯共聚物胶乳中,通过 VTES 水解产生的硅醇基团的缩合实现薄膜交联。VTES 共聚胶乳包覆尿素颗粒是在流化床中通过喷涂制备的。薄膜的交联密度和控释性能得到了显著提高。对薄膜交联网络的结构特征进行了理论计算和分析。高交联密度的交联网络具有较小的网状结构尺寸,大大降低了薄膜的自由体积,增加了营养物质的扩散阻力。当 VTES 共聚比例达到 10%时,尿素在平面薄膜上的扩散系数从 2.74 × 10-15 m2/s 降至 0.125 × 10-15 m2/s。在 4 wt % 的低包覆量下,薄膜包覆尿素颗粒的释放期延长至 32 天,比参考样品的释放期延长了 300% 以上。
{"title":"Enhancing Film Cross-Linking through VTES Copolymerization in Polymer Latex for Increasing Controlled-Release Performance of Film-Coated Fertilizer Granules","authors":"Jiuren Xie,&nbsp;Shaolei Zhao,&nbsp;Rui Tan,&nbsp;Ling Yang and Ting-Jie Wang*,&nbsp;","doi":"10.1021/acsagscitech.4c00085","DOIUrl":"10.1021/acsagscitech.4c00085","url":null,"abstract":"<p >To increase the controlled-release performance of film-coated fertilizer granules using polymer latex as a coating reagent, increasing the cross-linking density of the film during spray coating is crucial. In this study, vinyltriethoxysilane (VTES) was incorporated into styrene-acrylate copolymer latex, with film cross-linking achieved by the condensation of silanol groups derived from the hydrolysis of VTES. VTES-copolymerized latex-coated urea granules were prepared by spray coating in a fluidized bed. The film cross-linking density and controlled-release performance were significantly increased. The structural characteristics of the film cross-linked network were theoretically calculated and analyzed. The cross-linked network with high cross-linking density had a smaller size of mesh structure, significantly reducing the free volume of the film and increasing the diffusion resistance of nutrients. The urea diffusion coefficient across the planar film decreased from 2.74 × 10<sup>–15</sup> to 0.125 × 10<sup>–15</sup> m<sup>2</sup>/s when the VTES copolymerized ratio reached 10%. At a low coating amount of 4 wt %, the release period of the film-coated urea granules increased to 32 days, surpassing that of the reference sample by over 300%.</p>","PeriodicalId":93846,"journal":{"name":"ACS agricultural science & technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140982098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Infrared Imaging to Assess the Wild Rocket (Diplotaxis tenuifolia) Response to Fusarium Wilt in the Early Stages of Infection 用红外成像技术评估野生火箭草(Diplotaxis tenuifolia)在感染初期对镰刀菌枯萎病的反应
Q3 Agricultural and Biological Sciences Pub Date : 2024-05-08 DOI: 10.1021/acsagscitech.3c00582
Massimo Rippa*, Andrea Pasqualini, Gelsomina Manganiello, Sheridan Lois Woo, Pasquale Mormile and Catello Pane, 

Wild rocket is a baby-leaf vegetable crop devoted to the high-convenience food chain for the preparation of ready-to-eat salads. Healthiness and ecological management of crops are the requirements increasingly demanded by the market. On the other hand, very intensive cultivations under greenhouse are prone to fungal soil-borne pathogen attacks, such as Fusarium oxysporum f. sp. raphani, the causal agent of wilting. Control strategies currently include chemical and nonchemical means, but the implementation of digital systems able to support detection of outbreaks and promote optimization of interventions may concur to increase efficacy of management strategies. Thermography, based on the recording and analysis of thermal energy emitted by plant canopy in the infrared spectral range, is a well-known imaging technique able to monitor plants at both proximal and remote scales providing information on incipient plant stresses. In this work, wild rocket plants subjected to artificial infection with pathogen conidia performed by a dipping or flooding method were monitored during the pathogenesis by both passive and active thermographic approaches. Canopy temperature changes were compared with symptom severity indices measured by visual inspection on both inoculated and control plants. As key result of this study, depending on the inoculum concentration, passive thermography allowed classifying infected plants 30–48 h post inoculation (hpi) by dipping, and in coherence with the disease symptoms detection by visual inspection. Similar results were found in the case of the flooding inoculation, where infected plants were detected by thermography at 48 h.p.i. Active thermography revealed a decrease in leaf heat capacity attributable to the fungal infection and the subsequent tissue colonization over time. These findings constitute a solid base of knowledge about the thermal imaging applied to wild rocket affected by Fusarium wilting, and they can contribute to the development of new remote sensing systems for the detection of primary outbreaks.

野生火箭菜是一种嫩叶蔬菜作物,专门用于制作即食沙拉的高便利食品链。市场对作物的健康和生态管理要求越来越高。另一方面,大棚内的密集栽培很容易受到土传真菌病原体的侵袭,例如枯萎病的病原体 Fusarium oxysporum f. sp. raphani。目前的控制策略包括化学和非化学手段,但实施能够支持检测疫情和促进优化干预措施的数字系统,可能会提高管理策略的效率。热成像技术基于对植物冠层在红外光谱范围内发出的热能的记录和分析,是一种著名的成像技术,能够在近距离和远距离监测植物,提供有关植物初期压力的信息。在这项工作中,通过被动和主动热成像方法,对采用浸渍或浸水方法人工感染病原体分生孢子的野生火箭草进行了病原发生过程的监测。将冠层温度变化与接种植株和对照植株通过目测测量的症状严重程度指数进行了比较。这项研究的主要结果是,根据接种物浓度的不同,被动热成像技术可在浸渍接种后 30-48 小时对受感染的植物进行分类,并与目测发现的病害症状保持一致。主动热成像显示,随着时间的推移,真菌感染和随后的组织定殖导致叶片热容量下降。这些发现为应用于受枯萎镰刀菌影响的野生火箭的热成像技术奠定了坚实的知识基础,并有助于开发新的遥感系统来检测原发性疫情。
{"title":"Infrared Imaging to Assess the Wild Rocket (Diplotaxis tenuifolia) Response to Fusarium Wilt in the Early Stages of Infection","authors":"Massimo Rippa*,&nbsp;Andrea Pasqualini,&nbsp;Gelsomina Manganiello,&nbsp;Sheridan Lois Woo,&nbsp;Pasquale Mormile and Catello Pane,&nbsp;","doi":"10.1021/acsagscitech.3c00582","DOIUrl":"10.1021/acsagscitech.3c00582","url":null,"abstract":"<p >Wild rocket is a baby-leaf vegetable crop devoted to the high-convenience food chain for the preparation of ready-to-eat salads. Healthiness and ecological management of crops are the requirements increasingly demanded by the market. On the other hand, very intensive cultivations under greenhouse are prone to fungal soil-borne pathogen attacks, such as <i>Fusarium oxysporum</i> <i>f. sp.</i> <i>raphani</i>, the causal agent of wilting. Control strategies currently include chemical and nonchemical means, but the implementation of digital systems able to support detection of outbreaks and promote optimization of interventions may concur to increase efficacy of management strategies. Thermography, based on the recording and analysis of thermal energy emitted by plant canopy in the infrared spectral range, is a well-known imaging technique able to monitor plants at both proximal and remote scales providing information on incipient plant stresses. In this work, wild rocket plants subjected to artificial infection with pathogen conidia performed by a dipping or flooding method were monitored during the pathogenesis by both passive and active thermographic approaches. Canopy temperature changes were compared with symptom severity indices measured by visual inspection on both inoculated and control plants. As key result of this study, depending on the inoculum concentration, passive thermography allowed classifying infected plants 30–48 h post inoculation (hpi) by dipping, and in coherence with the disease symptoms detection by visual inspection. Similar results were found in the case of the flooding inoculation, where infected plants were detected by thermography at 48 h.p.i. Active thermography revealed a decrease in leaf heat capacity attributable to the fungal infection and the subsequent tissue colonization over time. These findings constitute a solid base of knowledge about the thermal imaging applied to wild rocket affected by Fusarium wilting, and they can contribute to the development of new remote sensing systems for the detection of primary outbreaks.</p>","PeriodicalId":93846,"journal":{"name":"ACS agricultural science & technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141000747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and Properties of Fomesafen@SiO2-Starch Microspheres for Herbicide-Controlled Release 用于除草剂控释的福美沙芬@SiO2-淀粉微球的制备及其特性
Q3 Agricultural and Biological Sciences Pub Date : 2024-05-07 DOI: 10.1021/acsagscitech.4c00094
Leiyu Yang, Yifan Luo, Yapeng Chen, Sanyan Wang, Huashan Wang and Meiyi Wang*, 

Fomesafen serves as a widely employed selective herbicide for addressing broadleaf weeds, but the short duration of efficacy limits utilization efficiency. There exists an exigent requirement to extend its efficacy through controlled release mechanisms. Fomesafen@SiO2-starch microspheres with α-amylase responsiveness were synthesized through the direct binding of drug-loaded silica microspheres and modified starch. This fabrication method capitalizes on the enzymatic degradation potential of the outer starch layer by amylase. In contrast with earlier analogous structures that exhibited inferior drug loading efficacy, the prepared fomesafen@SiO2-starch microspheres demonstrated a significantly enhanced drug loading capacity of up to 35.7%. Furthermore, in comparison to fomesafen technical, the prepared fomesafen@SiO2-starch microspheres exhibited a notable capacity to mitigate the photolysis of fomesafen through the utilization of the starch outer layer. Additionally, the fomesafen@SiO2-starch microspheres demonstrated favorable wettability and adhesive properties. At the recommended dosage, the herbicidal efficacy of fomesafen@SiO2-starch microspheres against Brassica napus L. and Portulaca oleracea L. over 14 days was observed to be comparable to that of the fomesafen technical, concurrently exhibiting a degree of sustained release. These findings underscore the potential of microspheres in regulating the release of fomesafen, thereby presenting a promising avenue for the development of sustainable drug delivery systems in agriculture.

福美双是一种广泛使用的选择性除草剂,可用于防治阔叶杂草,但药效持续时间短,限制了使用效率。因此,迫切需要通过控释机制来延长其药效。通过将载药二氧化硅微球与改性淀粉直接结合,合成了具有α-淀粉酶响应性的Fomesafen@SiO2-淀粉微球。这种制造方法利用了淀粉酶对淀粉外层的酶降解潜力。与早期表现出较低药物负载功效的类似结构相比,所制备的福美沙芬@SiO2-淀粉微球的药物负载能力显著提高,最高可达35.7%。此外,与福美沙芬技术相比,所制备的福美沙芬@SiO2-淀粉微球通过利用淀粉外层,在缓解福美沙芬的光解方面表现出明显的能力。此外,fomesafen@SiO2-淀粉微球还表现出良好的润湿性和粘合性。在推荐剂量下,14 天内观察到 fomesafen@SiO2 淀粉微球对甘蓝和马齿苋的除草效果与 fomesafen 技术剂相当,同时还表现出一定程度的持续释放。这些发现凸显了微球在调节福美沙芬释放方面的潜力,从而为在农业领域开发可持续给药系统提供了一条前景广阔的途径。
{"title":"Preparation and Properties of Fomesafen@SiO2-Starch Microspheres for Herbicide-Controlled Release","authors":"Leiyu Yang,&nbsp;Yifan Luo,&nbsp;Yapeng Chen,&nbsp;Sanyan Wang,&nbsp;Huashan Wang and Meiyi Wang*,&nbsp;","doi":"10.1021/acsagscitech.4c00094","DOIUrl":"10.1021/acsagscitech.4c00094","url":null,"abstract":"<p >Fomesafen serves as a widely employed selective herbicide for addressing broadleaf weeds, but the short duration of efficacy limits utilization efficiency. There exists an exigent requirement to extend its efficacy through controlled release mechanisms. Fomesafen@SiO<sub>2</sub>-starch microspheres with α-amylase responsiveness were synthesized through the direct binding of drug-loaded silica microspheres and modified starch. This fabrication method capitalizes on the enzymatic degradation potential of the outer starch layer by amylase. In contrast with earlier analogous structures that exhibited inferior drug loading efficacy, the prepared fomesafen@SiO<sub>2</sub>-starch microspheres demonstrated a significantly enhanced drug loading capacity of up to 35.7%. Furthermore, in comparison to fomesafen technical, the prepared fomesafen@SiO<sub>2</sub>-starch microspheres exhibited a notable capacity to mitigate the photolysis of fomesafen through the utilization of the starch outer layer. Additionally, the fomesafen@SiO<sub>2</sub>-starch microspheres demonstrated favorable wettability and adhesive properties. At the recommended dosage, the herbicidal efficacy of fomesafen@SiO<sub>2</sub>-starch microspheres against <i>Brassica napus L.</i> and <i>Portulaca oleracea L.</i> over 14 days was observed to be comparable to that of the fomesafen technical, concurrently exhibiting a degree of sustained release. These findings underscore the potential of microspheres in regulating the release of fomesafen, thereby presenting a promising avenue for the development of sustainable drug delivery systems in agriculture.</p>","PeriodicalId":93846,"journal":{"name":"ACS agricultural science & technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141002859","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
ACS agricultural science & technology
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1