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Arsenic removal from natural groundwater using cupric oxide. 利用氧化铜去除天然地下水中的砷。
IF 2.6 Pub Date : 2013-01-01 Epub Date: 2012-03-30 DOI: 10.1111/j.1745-6584.2012.00926.x
K J Reddy, T R Roth

Groundwater is a main source of drinking water for some rural areas. People in these rural areas are potentially at risk from elevated levels of arsenic (As) due to a lack of water treatment facilities. The objectives of this study were to (1) measure As concentrations in approximately 50 groundwater samples from rural domestic wells in the western United States, (2) explore the potential of cupric oxide (CuO) particles in removal of As from groundwater samples under natural conditions (i.e., without adding competing anions and adjusting the pH or oxidation state), and (3) determine the effects of As removal on the chemistry of groundwater samples. Forty-six groundwater well samples from rural domestic areas were tested in this study. More than 50% of these samples exceeded the U.S. Environmental Protection Agency Maximum Contaminant Limit (US EPA MCL) of 10 µg/L for As. CuO particles effectively removed As from groundwater samples across a wide range of pH (7.11 and 8.95) and concentrations of competing anions including phosphate (<0.05 to 3.06 mg/L), silica (<1 to 54.5 mg/L), and sulfate (1.3 to 735 mg/L). Removal of As showed minor effects on the chemistry of groundwater samples, therefore most of the water quality parameters remained within the US EPA MCLs. Overall, results of this study could help develop a simple one-step process to remove As from groundwater.

地下水是一些农村地区饮用水的主要来源。由于缺乏水处理设施,这些农村地区的人们可能面临砷水平升高的风险。本研究的目的是:(1)测量来自美国西部农村家庭水井的大约50个地下水样品中的As浓度,(2)探索在自然条件下(即不添加竞争阴离子和调整pH或氧化态)氧化铜(CuO)颗粒去除地下水样品中As的潜力,以及(3)确定As去除对地下水样品化学性质的影响。本研究选取了46口农村地区的地下水井样进行测试。这些样品中超过50%的砷含量超过了美国环境保护署最高污染物限值(US EPA MCL) 10微克/升。CuO颗粒在很大的pH值(7.11和8.95)和竞争阴离子(包括磷酸盐)浓度范围内有效地去除地下水样品中的砷。
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引用次数: 32
Zombie-science and beyond. 僵尸科学及其他。
IF 2.6 Pub Date : 2013-01-01 DOI: 10.1111/gwat.12008
Franklin W Schwartz
According to Haitian Creole lore, a zombie is a dead person brought back to life using magic. By analogy, zombie-science is research that should be dead, but magically lives on. So what is the origin of zombie-science in groundwater, why does the magic still work to keep research alive, and finally, do we really still have the capacity for innovation? Not every paper written can—nor should be—an innovative blockbuster. Thomas Kuhn’s view on progress in science was that more than just revolutions were needed and “something different must necessarily go on in between” (Kuhn, 2000). That something is what Kuhn called normal science—the incremental work of embellishing ideas and filling in details. Zombie-science is essentially normal science run amok, the land where embellishments and detail-filling never die. In some areas of groundwater, normal science, apparently uninterrupted by revolutionary spurts, has been in progress for more than 50 years. The cost is represented by an inefficient use of human capital in research, stagnation of the field, and journals full of information that only few care about. The cost of research-not-done on key problems is unknowable. I attributed stagnation in the past to comfort with research paradigms; unwillingness to part with methods, facilities, and field sites; or the maturing of the field. Undoubtedly, these factors contribute, but my view has shifted to simply linking zombie-science to a lack of funding. Some fields, most notably, medical science, (e.g., neurobiology, molecular genetics) are awash in full-time researchers taking their studies in unique directions. It is possible to do good science without money. But broadly speaking, even zombie magic cannot put life back into research founded on collections of ordinary data, routine project work, and too little time. Given the present economic conditions and the depressed government support for water sciences, perhaps the best we can hope for future funding is something like the status quo.
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引用次数: 9
Grid refinement in Cartesian coordinates for groundwater flow models using the divergence theorem and Taylor's series. 利用散度定理和泰勒级数在笛卡尔坐标下对地下水流动模型进行网格细化。
IF 2.6 Pub Date : 2013-01-01 Epub Date: 2012-03-12 DOI: 10.1111/j.1745-6584.2012.00924.x
M M Mansour, A E F Spink

Grid refinement is introduced in a numerical groundwater model to increase the accuracy of the solution over local areas without compromising the run time of the model. Numerical methods developed for grid refinement suffered certain drawbacks, for example, deficiencies in the implemented interpolation technique; the non-reciprocity in head calculations or flow calculations; lack of accuracy resulting from high truncation errors, and numerical problems resulting from the construction of elongated meshes. A refinement scheme based on the divergence theorem and Taylor's expansions is presented in this article. This scheme is based on the work of De Marsily (1986) but includes more terms of the Taylor's series to improve the numerical solution. In this scheme, flow reciprocity is maintained and high order of refinement was achievable. The new numerical method is applied to simulate groundwater flows in homogeneous and heterogeneous confined aquifers. It produced results with acceptable degrees of accuracy. This method shows the potential for its application to solving groundwater heads over nested meshes with irregular shapes.

在地下水数值模型中引入网格细化,在不影响模型运行时间的前提下提高局部区域解的精度。为网格细化而开发的数值方法存在一定的缺陷,例如,在实现插值技术方面存在缺陷;水头计算或流量计算中的非互易性;高截断误差导致的精度不足,以及细长网格结构导致的数值问题。本文提出了一种基于散度定理和泰勒展开式的改进方案。该格式基于De marsiily(1986)的工作,但包含了更多的泰勒级数项以改进数值解。该方案既保持了流的互易性,又实现了高阶的细化。将该数值方法应用于均质和非均质承压含水层的地下水流动模拟。它产生的结果具有可接受的精度。该方法显示了其应用于求解不规则形状嵌套网格上的地下水水头的潜力。
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引用次数: 3
Design and application of a direct-push vadose zone gravel permeameter. 直推式气相带砾石渗透率仪的设计与应用。
IF 2.6 Pub Date : 2012-07-01 Epub Date: 2012-04-26 DOI: 10.1111/j.1745-6584.2012.00938.x
W Daniel Reynolds, Jeffrey K Lewis
We read with interest the recent article by Miller et al. (2011) on the design and application of a new “gravel permeameter” for in situ measurement of field saturated hydraulic conductivity, Kfs [LT−1], in unconsolidated vadose zones comprised of coarse-textured porous media. In this method, a stout pipe with a screened section and a basal drive shoe is pushed, driven or vibrated into the vadose zone. A steady head of water is ponded in the pipe, and the steady water discharge out through the pipe screen and into the vadose zone is measured. In vadose zones where the depth to the water table (or an impermeable layer) is more than three times the water depth in the pipe, Kfs is determined using the zone 1, method 3 “gravity permeability” analysis (USBR, 2001):
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引用次数: 1
Spatial and temporal infiltration dynamics during managed aquifer recharge. 含水层补给过程中的时空入渗动态。
IF 2.6 Pub Date : 2012-07-01 Epub Date: 2011-11-03 DOI: 10.1111/j.1745-6584.2011.00875.x
Andrew J Racz, Andrew T Fisher, Calla M Schmidt, Brian S Lockwood, Marc Los Huertos

Natural groundwater recharge is inherently difficult to quantify and predict, largely because it comprises a series of processes that are spatially distributed and temporally variable. Infiltration ponds used for managed aquifer recharge (MAR) provide an opportunity to quantify recharge processes across multiple scales under semi-controlled conditions. We instrumented a 3-ha MAR infiltration pond to measure and compare infiltration patterns determined using whole-pond and point-specific methods. Whole-pond infiltration was determined by closing a transient water budget (accounting for inputs, outputs, and changes in storage), whereas point-specific infiltration rates were determined using heat as a tracer and time series analysis at eight locations in the base of the pond. Whole-pond infiltration, normalized for wetted area, rose rapidly to more than 1.0 m/d at the start of MAR operations (increasing as pond stage rose), was sustained at high rates for the next 40 d, and then decreased to less than 0.1 m/d by the end of the recharge season. Point-specific infiltration rates indicated high spatial and temporal variability, with the mean of measured values generally being lower than rates indicated by whole-pond calculations. Colocated measurements of head gradients within saturated soils below the pond were combined with infiltration rates to calculate soil hydraulic conductivity. Observations indicate a brief period of increasing saturated hydraulic conductivity, followed by a decrease of one to two orders of magnitude during the next 50 to 75 d. Locations indicating the most rapid infiltration shifted laterally during MAR operation, and we suggest that infiltration may function as a "variable source area" processes, conceptually similar to catchment runoff.

天然地下水补给本身就难以量化和预测,主要是因为它包括一系列空间分布和时间可变的过程。用于管理含水层补给(MAR)的渗透池提供了在半控制条件下跨多个尺度量化补给过程的机会。我们测量了一个3公顷的MAR入渗池,以测量和比较采用全池和点特异性方法确定的入渗模式。整个池塘的入渗是通过关闭瞬时水收支(考虑输入、输出和储存的变化)来确定的,而特定点的入渗率是使用热量作为示踪剂和时间序列分析在池塘底部的八个地点确定的。在MAR操作开始时,全池入渗量迅速上升至1.0 m/d以上(随着池级的增加而增加),并在接下来的40 d内保持较高的速率,然后在补给季节结束时降至0.1 m/d以下。点特异性入渗率具有较高的时空变异性,其测量值的平均值一般低于全池计算值的平均值。在池下饱和土壤的水头梯度与入渗速率相结合,以计算土壤的水力导电性。观测结果表明,饱和水力导电性短暂增加,随后在接下来的50至75天内下降一到两个数量级。在MAR运行期间,表明入渗最快的地点向横向移动,我们认为入渗可能是一个“可变源区”过程,在概念上类似于汇水径流。
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引用次数: 52
Restoration of wadi aquifers by artificial recharge with treated waste water. 用处理过的废水人工回灌恢复河道含水层。
IF 2.6 Pub Date : 2012-07-01 Epub Date: 2012-04-26 DOI: 10.1111/j.1745-6584.2012.00941.x
Thomas M Missimer, Jörg E Drewes, Gary Amy, Robert G Maliva, Stephanie Keller

Fresh water resources within the Kingdom of Saudi Arabia are a rare and precious commodity that must be managed within a context of integrated water management. Wadi aquifers contain a high percentage of the naturally occurring fresh groundwater in the Kingdom. This resource is currently overused and has become depleted or contaminated at many locations. One resource that could be used to restore or enhance the fresh water resources within wadi aquifers is treated municipal waste water (reclaimed water). Each year about 80 percent of the country's treated municipal waste water is discharged to waste without any beneficial use. These discharges not only represent a lost water resource, but also create a number of adverse environmental impacts, such as damage to sensitive nearshore marine environments and creation of high-salinity interior surface water areas. An investigation of the hydrogeology of wadi aquifers in Saudi Arabia revealed that these aquifers can be used to develop aquifer recharge and recovery (ARR) systems that will be able to treat the impaired-quality water, store it until needed, and allow recovery of the water for transmittal to areas in demand. Full-engineered ARR systems can be designed at high capacities within wadi aquifer systems that can operate in concert with the natural role of wadis, while providing the required functions of additional treatment, storage and recovery of reclaimed water, while reducing the need to develop additional, energy-intensive desalination to meet new water supply demands.

沙特阿拉伯王国境内的淡水资源是一种稀有和珍贵的商品,必须在综合水管理的范围内加以管理。在沙特王国,瓦底含水层含有很高比例的天然新鲜地下水。这种资源目前被过度使用,在许多地方已经枯竭或受到污染。一种可用于恢复或增强瓦底含水层内淡水资源的资源是经过处理的城市废水(再生水)。每年,全国大约80%经过处理的城市废水被排放为废物,没有任何有益的利用。这些排放不仅代表着水资源的损失,而且还造成了许多不利的环境影响,例如对敏感的近岸海洋环境的破坏和高盐度的内部地表水区域的产生。一项对沙特阿拉伯瓦迪含水层水文地质的调查显示,这些含水层可用于开发含水层补给和恢复(ARR)系统,该系统将能够处理水质受损的水,将其储存到需要的地方,并允许回收水以输送到需要的地区。全面设计的ARR系统可以在wadi含水层系统中设计高容量,可以与wadi的自然作用相一致,同时提供额外处理,储存和回收再生水的所需功能,同时减少开发额外的能源密集型海水淡化以满足新的供水需求。
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引用次数: 67
A wet/wet differential pressure sensor for measuring vertical hydraulic gradient. 用于测量垂直水力梯度的湿/湿差压传感器。
IF 2.6 Pub Date : 2010-01-01 Epub Date: 2009-07-31 DOI: 10.1111/j.1745-6584.2009.00609.x
Brad G Fritz, Rob D Mackley

Vertical hydraulic gradient is commonly measured in rivers, lakes, and streams for studies of groundwater-surface water interaction. While a number of methods with subtle differences have been applied, these methods can generally be separated into two categories; measuring surface water elevation and pressure in the subsurface separately or making direct measurements of the head difference with a manometer. Making separate head measurements allows for the use of electronic pressure sensors, providing large datasets that are particularly useful when the vertical hydraulic gradient fluctuates over time. On the other hand, using a manometer-based method provides an easier and more rapid measurement with a simpler computation to calculate the vertical hydraulic gradient. In this study, we evaluated a wet/wet differential pressure sensor for use in measuring vertical hydraulic gradient. This approach combines the advantage of high-temporal frequency measurements obtained with instrumented piezometers with the simplicity and reduced potential for human-induced error obtained with a manometer board method. Our results showed that the wet/wet differential pressure sensor provided results comparable to more traditional methods, making it an acceptable method for future use.

垂直水力梯度通常在河流、湖泊和溪流中测量,用于研究地下水与地表水的相互作用。虽然采用了许多差别不大的方法,但这些方法一般可分为两类;分别测量地表水标高和地下压力或用压力计直接测量水头差。通过使用电子压力传感器进行单独的水头测量,可以提供大量的数据集,当垂直水力梯度随时间波动时,这些数据集尤其有用。另一方面,使用基于压力计的方法可以更容易、更快速地计算垂直水力梯度。在这项研究中,我们评估了用于测量垂直水力梯度的湿/湿差压传感器。这种方法结合了用仪器压力表获得的高时间频率测量的优点,以及用压力计板方法获得的简单性和减少人为误差的可能性。我们的研究结果表明,湿/湿差压传感器提供的结果与更传统的方法相当,使其成为未来使用的可接受的方法。
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引用次数: 7
A forward modeling approach for interpreting impeller flow logs. 一种解释叶轮流动测井曲线的正演建模方法。
IF 2.6 Pub Date : 2010-01-01 Epub Date: 2009-07-24 DOI: 10.1111/j.1745-6584.2009.00600.x
Alison H Parker, L Jared West, Noelle E Odling, Richard T Bown

A rigorous and practical approach for interpretation of impeller flow log data to determine vertical variations in hydraulic conductivity is presented and applied to two well logs from a Chalk aquifer in England. Impeller flow logging involves measuring vertical flow speed in a pumped well and using changes in flow with depth to infer the locations and magnitudes of inflows into the well. However, the measured flow logs are typically noisy, which leads to spurious hydraulic conductivity values where simplistic interpretation approaches are applied. In this study, a new method for interpretation is presented, which first defines a series of physical models for hydraulic conductivity variation with depth and then fits the models to the data, using a regression technique. Some of the models will be rejected as they are physically unrealistic. The best model is then selected from the remaining models using a maximum likelihood approach. This balances model complexity against fit, for example, using Akaike's Information Criterion.

提出了一种严谨实用的方法来解释叶轮流动测井数据,以确定水力导电性的垂直变化,并将其应用于英国白垩含水层的两口井测井。叶轮流量测井包括测量泵井中的垂直流速,并利用流量随深度的变化来推断流入井中的位置和大小。然而,测量的流量测井数据通常是有噪声的,当采用简单的解释方法时,会导致虚假的水力导电性值。本文提出了一种新的解释方法,首先定义了一系列的水导率随深度变化的物理模型,然后利用回归技术将模型拟合到数据中。一些模型将被拒绝,因为它们在物理上是不现实的。然后使用最大似然方法从剩余的模型中选择最佳模型。这平衡了模型的复杂性和拟合,例如,使用赤池的信息标准。
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引用次数: 20
Calibration of parameter fields consisting of multiple statistical populations. 校正由多个统计总体组成的参数场。
IF 2.6 Pub Date : 2010-01-01 Epub Date: 2009-07-31 DOI: 10.1111/j.1745-6584.2009.00607.x
Gijs M C M Janssen, Johan R Valstar

If a parameter field to be calibrated consists of more than one statistical population, usually not only the parameter values are uncertain, but the spatial distributions of the populations are uncertain as well. In this study, we demonstrate the potential of the multimodal calibration method we proposed recently for the calibration of such fields, as applied to real-world ground water models with several additional stochastic parameter fields. Our method enables the calibration of the spatial distribution of the statistical populations, as well as their spatially correlated parameterization, while honoring the complete prior geostatistical definition of the multimodal parameter field. We illustrate the implications of the method in terms of the reliability of the posterior model by comparing its performance to that of a "conventional" calibration approach in which the positions of the statistical populations are not allowed to change. Information from synthetic calibration runs is used to show how ignoring the uncertainty involved in the positions of the statistical populations not only denies the modeler the opportunity to use the measurement information to improve these positions but also unduly influences the posterior intrapopulation distributions, causes unjustified adjustments to the cocalibrated parameter fields, and results in poorer observation reproduction. The proposed multimodal calibration allows a more complete treatment of the relevant uncertainties, which prevents the abovementioned adverse effects and renders a more trustworthy posterior model.

如果一个待校准的参数字段包含多个统计总体,通常不仅参数值不确定,而且总体的空间分布也不确定。在这项研究中,我们展示了我们最近提出的多模态校准方法在这些领域的潜力,并将其应用于具有几个额外随机参数场的真实地下水模型。我们的方法能够校准统计总体的空间分布,以及它们的空间相关参数化,同时尊重完整的多模态参数场的先验地统计学定义。我们通过将后验模型的性能与不允许改变统计总体位置的“传统”校准方法的性能进行比较,说明了该方法在后验模型可靠性方面的含义。来自合成校准运行的信息被用来显示忽略统计总体位置所涉及的不确定性如何不仅剥夺了建模者使用测量信息来改善这些位置的机会,而且还会过度影响后验种群内分布,导致对协校准参数场的不合理调整,并导致较差的观测再现。所提出的多模态校准允许更完整地处理相关不确定性,从而防止上述不利影响,并提供更可靠的后验模型。
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引用次数: 2
Studies of water velocity in the capillary fringe: the point velocity probe. 毛细条纹中水流速度的研究:点速度探针。
IF 2.6 Pub Date : 2010-01-01 Epub Date: 2009-07-31 DOI: 10.1111/j.1745-6584.2009.00606.x
S J Berg, R W Gillham

The point velocity probe (PVP) is a device that can measure groundwater velocity at the centimeter scale, and unlike devices that measure velocity within well screens, the PVP operates while in direct contact with the porous medium. Because of this feature, it was postulated that the PVP could be effective in measuring velocity within the capillary fringe. This hypothesis was tested using a laboratory flow-through cell filled with a medium-fine sand from Canadian Forces Base Borden. The cell was constructed to simulate conditions such that the PVP was positioned from 2.5 cm below the water table to 79 cm above the water table. As the water table was lowered, the PVP gave highly consistent values of velocity over the range equivalent to 2.5 cm below the water table to 44 cm above the water table, the approximate extent of the capillary fringe. The average measured velocity was 11.3 cm/d +/- 11.6%, somewhat higher than that calculated based on the measured discharge through the cell (7.5 cm/d +/- 5.5%). With a further decline in the water table there was a progressive decrease in the measured velocity values, consistent with the declining hydraulic conductivity as the sand material drained. Readings could not be made beyond about 57 cm, where the water content was approximately 75% of saturation. These experiments showed that the PVP is capable of measuring groundwater velocity within the saturated zone above the water table and possibly into the unsaturated zone. Currently, this is the only instrument available with this capability.

点速度探头(PVP)是一种可以在厘米尺度上测量地下水速度的设备,与在井筛内测量速度的设备不同,PVP可以直接与多孔介质接触。由于这一特点,PVP可以有效地测量毛细管条纹内的速度。这个假设是用来自加拿大博登军事基地的中细砂填充的实验室流式细胞进行测试的。该细胞的构建是为了模拟PVP从地下水位以下2.5 cm到地下水位以上79 cm的位置。随着地下水位的降低,PVP给出了高度一致的速度值,其范围相当于地下水位以下2.5 cm至地下水位以上44 cm,即毛细条纹的大致范围。测量到的平均流速为11.3 cm/d +/- 11.6%,略高于通过电池测量到的流量(7.5 cm/d +/- 5.5%)。随着地下水位的进一步下降,测量到的流速值逐渐减小,这与砂料排水时水力导电性的下降相一致。读数不能超过约57厘米,那里的含水量约为饱和度的75%。这些实验表明,PVP能够测量地下水位以上饱和带和可能进入非饱和带的地下水流速。目前,这是唯一具有此功能的仪器。
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引用次数: 24
期刊
Ground water
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