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Enhanced Removal of Brine From Porous Structures by Supercritical CO2. 超临界二氧化碳增强多孔结构对盐水的去除。
Pub Date : 2025-01-01 Epub Date: 2024-07-24 DOI: 10.1111/gwat.13434
Iris Beatriz Vega Erramuspe, Osei Asafu-Adjaye, Melissa Rojas-Márquez, Brian Via, Bhima Sastri, Sujit Banerjee

Supercritical CO2 (sCO2) removes water from brine held in pumice stone at levels well above the solubility of water in sCO2. The higher water removal results from a combination of passive emulsification of water in sCO2 and viscous fingering of sCO2 through the saturated pumice. This leads to higher levels of salt deposition than that expected from solubility considerations alone. These deposits could impact the injectivity of sCO2 as well as its movement in the subsurface. The finding that the water concentration in sCO2 is not necessarily capped at the solubility limit should influence the parametrization of injection models.

超临界二氧化碳 (sCO2) 能从浮石中的盐水中去除水分,其去除率远高于水在 sCO2 中的溶解度。水在 sCO2 中的被动乳化和 sCO2 在饱和浮石中的粘性指状作用共同导致了较高的水去除率。这导致盐沉积的程度高于仅从溶解度考虑所预期的程度。这些沉积物可能会影响 sCO2 的注入能力及其在地下的移动。发现 sCO2 中的水浓度不一定在溶解度极限时封顶,这应影响注入模型的参数化。
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引用次数: 0
The Effective Vertical Anisotropy of Layered Aquifers. 层状含水层的有效垂直各向异性。
Pub Date : 2025-01-01 Epub Date: 2024-08-16 DOI: 10.1111/gwat.13432
Mark Bakker, Bram Bot

Many sedimentary aquifers consist of small layers of coarser and finer material. When groundwater flow in these aquifers is modeled, the hydraulic conductivity may be simulated as homogeneous but anisotropic throughout the aquifer. In practice, the anisotropy factor, the ratio of the horizontal divided by the vertical hydraulic conductivity, is often set to 10. Here, numerical experiments are conducted to determine the effective anisotropy of an aquifer consisting of 400 horizontal layers of which the homogeneous and isotropic hydraulic conductivity varies over two orders of magnitude. Groundwater flow is simulated to a partially penetrating canal and a partially penetrating well. Numerical experiments are conducted for 1000 random realizations of the 400 layers, by varying the sequence of the layers, not their conductivity. It is demonstrated that the effective anisotropy of the homogeneous model is a model parameter that depends on the flow field. For example, the effective anisotropy for flow to a partially penetrating canal differs from the effective anisotropy for flow to a partially penetrating well in an aquifer consisting of the exact same 400 layers. The effective anisotropy also depends on the sequence of the layers. The effective anisotropy values of the 1000 realizations range from roughly 5 to 50 for the considered situations. A factor of 10 represents a median value (a reasonable value to start model calibration for the conductivity variations considered here). The median is similar to the equivalent anisotropy, defined as the arithmetic mean of the hydraulic conductivities divided by the harmonic mean.

许多沉积含水层由较粗和较细的小层物质组成。在模拟这些含水层中的地下水流时,可将整个含水层的水力传导性模拟为均匀但各向异性。在实践中,各向异性系数,即水平水力传导系数除以垂直水力传导系数的比值,通常设定为 10。这里,我们通过数值实验来确定含水层的有效各向异性,含水层由 400 个水平层组成,其中各向同性的水力传导系数相差两个数量级。模拟了地下水流向部分贯通的水渠和部分贯通的水井。通过改变地层的顺序而不是其导电率,对 400 个地层进行了 1000 次随机实验。实验证明,均质模型的有效各向异性是一个取决于流场的模型参数。例如,在由完全相同的 400 层组成的含水层中,流向部分贯通运河的有效各向异性与流向部分贯通水井的有效各向异性是不同的。有效各向异性还取决于层序。在所考虑的情况下,1000 次模拟的有效各向异性值大致在 5 到 50 之间。系数 10 代表一个中值(对于本文考虑的电导率变化,这是一个开始校准模型的合理值)。中值与等效各向异性相似,等效各向异性的定义是水力电导率的算术平均值除以谐波平均值。
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引用次数: 0
Estimation of Effective Fracture Aperture in Glacial Tills by Analysis of Dye Tracer Penetration. 通过分析染料示踪剂渗透估算冰川丘陵的有效断裂孔径。
Pub Date : 2025-01-01 Epub Date: 2024-06-25 DOI: 10.1111/gwat.13426
Mariam Ouf, Peter R Jørgensen, Klaus Mosthaf, Massimo Rolle

This study advances a methodology to estimate effective apertures of fractures in glacial tills based on dye tracer infiltration tests and numerical simulations. The approach uses the visible penetration depth of the dye tracer along fracture flow paths as primary information to calculate effective fracture apertures. Further data used in the calculation are the dye tracer input concentration and retardation, the duration of the tracer injection, and the hydraulic gradient applied to control the infiltrating water fluxes. The method does not require measurement of hydraulic conductivity for the fractured till and enables direct observation of flow and transport patterns within the fractures (e.g., uniform flow and dye tracer distribution, channeling due to aperture variability, and presence of biogenic macropores in fractures). The approach was successfully verified by using the estimated effective fracture aperture values in Large Undisturbed Columns (LUCs) to consistently simulate both the observed LUC effluent breakthrough of a conservative bromide tracer and the water fluxes with the hydraulic gradient applied in the experiments. Sensitivity analyses revealed that estimation of small effective fracture apertures (<10 μm) required accurate determination of the dye tracer retardation factor. By contrast, in the case of larger effective apertures (>20 μm), the sensitivity of the estimated effective fracture aperture to variations in the porous material and solute transport parameters was low compared to the dominant sensitivity to the water flow through the fractures (cubic relation between flow and aperture). The proposed approach may be extended beyond laboratory applications and assist in characterizing field-scale fracture networks.

本研究基于染料示踪剂渗透试验和数值模拟,提出了一种估算冰川堆积物裂缝有效孔径的方法。该方法将染料示踪剂沿裂缝流动路径的可见渗透深度作为计算有效裂缝孔径的主要信息。计算中使用的其他数据包括染料示踪剂的输入浓度和延迟、示踪剂注入的持续时间以及用于控制渗透水流量的水力梯度。该方法不需要测量断裂耕层的水力传导性,可直接观察断裂内的水流和传输模式(例如,均匀水流和染料示踪剂分布、孔隙变化导致的渠化以及断裂中生物大孔的存在)。通过使用估算的大型未扰动柱(LUC)中的有效裂缝孔径值,成功地验证了该方法,该方法能够稳定地模拟观测到的大型未扰动柱中保守溴化物示踪剂的流出突破,以及实验中应用的水力梯度下的水通量。灵敏度分析表明,在估算小的有效裂缝孔径(20 μm)时,估算的有效裂缝孔径对多孔材料和溶质迁移参数变化的灵敏度较低,而对通过裂缝的水流量(流量与孔径之间的立方关系)的灵敏度则占主导地位。所提出的方法可在实验室应用之外进行推广,并有助于确定实地尺度断裂网络的特征。
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引用次数: 0
Numerical Modeling of Recovery of Moisture from the Unsaturated Zone: A Feasibility Study. 从非饱和带回收水分的数值建模:可行性研究。
Pub Date : 2025-01-01 Epub Date: 2024-08-05 DOI: 10.1111/gwat.13436
Amitabha Mukhopadhyay, Adnan Akber, Harish Bhandary

Numerical modeling of the recovery of moisture by injecting warm air in the unsaturated zone in a 100 m × 100 m plot of agricultural land in Kuwait, a country located in an arid environment, was conducted to provide "proof of concept" of the technique. If technically and economically feasible, it will be a potential additional source of water that could be exploited for farming activities and other uses. The COMSOL software was used to develop the model and, based on the results of the scenario runs, the effects of different hydraulic and operational parameters, including that of well spacing, on moisture recovery were assessed. In general, the results suggested that the recovery should increase with the increase in the hydraulic conductivity of the unsaturated zone, the amount of heat input, and the pressure differential between the unsaturated zone and the well head. Within the period examined (0 to 11 days), the recovery decreases with the increase in the soil moisture content, possibly due to the fall in relative permeability to moisture-rich air with the increased water contents in the pore spaces, although the effects may change over a longer period as water contents decrease with moisture recovery. The moisture recovery from the unsaturated zone through the injection of warm air appears to be a feasible proposition from this study that should be demonstrated through a pilot scale experiment in the field.

在科威特(一个位于干旱环境中的国家)的一块 100 米×100 米的农田中,通过在非饱和区注入暖空气进行水分回收的数值建模,为该技术提供了 "概念验证"。如果在技术和经济上可行,这将是一个潜在的额外水源,可用于农业活动和其他用途。利用 COMSOL 软件开发了模型,并根据情景运行的结果,评估了不同水力和操作参数(包括水井间距)对水分回收的影响。一般来说,结果表明,随着非饱和区水力传导性、输入热量以及非饱和区与井口之间压力差的增加,回采率也会增加。在研究期间(0 到 11 天),土壤水分含量增加,回采率下降,这可能是由于孔隙中含水量增加,富含水分的空气的相对渗透率下降,尽管随着水分回采,含水量下降,这种影响可能会在更长的时间内发生变化。从这项研究来看,通过注入暖空气从非饱和带回收水分似乎是一个可行的提议,应通过在实地进行小规模试验来加以证明。
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引用次数: 0
The Artesian Wells of Batavia, Dutch East-Indies 1872 to 1878. 1872 至 1878 年荷属东印度群岛巴达维亚的自流井。
Pub Date : 2025-01-01 Epub Date: 2024-10-22 DOI: 10.1111/gwat.13449
Paul Whincup, Arjen van Schaijk
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引用次数: 0
A Close-to-Optimal Discretization Strategy for Pumping Test Numerical Simulation. 用于抽水试验数值模拟的接近最优的离散化策略。
Pub Date : 2025-01-01 Epub Date: 2024-09-23 DOI: 10.1111/gwat.13442
Ronny Figueroa, Etienne Bresciani

Numerical modeling offers a valuable alternative to analytical solutions for pumping test analysis. However, little is known about how discretization impacts results accuracy and runtime. This study presents a systematic method for defining the spatiotemporal discretization of pumping test numerical models based on dimensionless parameters. Two types of analysis are considered: one where observations are made in the pumping well, and another one where observations are made in different wells. The influence of the discretization parameters on results accuracy and runtime is investigated and an optimal set of parameters is determined that minimizes runtime while maintaining the maximum error under 1% for an "average" aquifer. Lower runtimes are achieved when the analysis focuses on the pumping well, which is attributed to the steady-state analytical solution approximating drawdown in the well in the numerical scheme employed. Additional tests demonstrate the robustness of the derived set of parameters in different configurations.

数值建模为抽水试验分析提供了一种有价值的替代分析解决方案。然而,人们对离散化如何影响结果精度和运行时间知之甚少。本研究提出了一种基于无量纲参数的系统方法,用于定义抽水试验数值模型的时空离散化。研究考虑了两种类型的分析:一种是在抽水井中进行观测,另一种是在不同的井中进行观测。研究了离散化参数对结果准确性和运行时间的影响,并确定了一组最佳参数,在保持 "平均 "含水层最大误差在 1%以下的同时,最大限度地缩短了运行时间。当分析集中于抽水井时,运行时间较短,这归因于在所采用的数值方案中,稳态分析解近似于抽水井中的缩减。其他测试表明,推导出的参数集在不同配置下具有稳健性。
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引用次数: 0
Parameter ESTimation With the Gauss-Levenberg-Marquardt Algorithm: An Intuitive Guide. 使用高斯-莱文伯格-马夸特算法进行参数ESTimation:直观指南
Pub Date : 2025-01-01 Epub Date: 2024-07-23 DOI: 10.1111/gwat.13433
Michael N Fienen, Jeremy T White, Mohamed Hayek

In this paper, we review the derivation of the Gauss-Levenberg-Marquardt (GLM) algorithm and its extension to ensemble parameter estimation. We explore the use of graphical methods to provide insights into how the algorithm works in practice and discuss the implications of both algorithm tuning parameters and objective function construction in performance. Some insights include understanding the control of both parameter trajectory and step size for GLM as a function of tuning parameters. Furthermore, for the iterative Ensemble Smoother (iES), we discuss the importance of noise on observations and show how iES can cope with non-unique outcomes based on objective function construction. These insights are valuable for modelers using PEST, PEST++, or similar parameter estimation tools.

在本文中,我们回顾了高斯-莱文伯格-马夸特(GLM)算法的推导及其在集合参数估计中的扩展。我们探讨了图形方法的使用,以深入了解算法在实践中是如何运行的,并讨论了算法调整参数和目标函数构造对性能的影响。其中的一些启示包括,我们理解了作为调整参数函数的 GLM 参数轨迹和步长的控制。此外,对于迭代集合平滑器(iES),我们讨论了噪声对观测结果的重要性,并展示了 iES 如何在目标函数构造的基础上应对非唯一结果。这些见解对于使用 PEST、PEST++ 或类似参数估计工具的建模人员很有价值。
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引用次数: 0
Utility of an Instantaneous Salt Dilution Method for Measuring Streamflow in Headwater Streams. 瞬时盐分稀释法在测量上游溪流中的实用性。
Pub Date : 2025-01-01 Epub Date: 2024-08-13 DOI: 10.1111/gwat.13437
Karli M Rogers, Jennifer B Fair, Nathaniel P Hitt, Karmann G Kessler, Zachary A Kelly, Martin Briggs

Streamflow records are biased toward large streams and rivers, yet small headwater streams are often the focus of ecological research in response to climate change. Conventional flow measurement instruments such as acoustic Doppler velocimeters (ADVs) do not perform well during low-flow conditions in small streams, truncating the development of rating curves during critical baseflow conditions dominated by groundwater inflow. We revisited an instantaneous solute tracer injection method as an alternative to ADVs based on paired measurements to compare their precision, efficiency, and feasibility within headwater streams across a range of flow conditions. We show that the precision of discharge measurements using salt dilution by slug injection and ADV methods were comparable overall, but salt dilution was more precise during the lowest flows and required less time to implement. Often, headwater streams were at or below the depth threshold where ADV measurements could even be attempted and transects were complicated by coarse bed material and cobbles. We discuss the methodological benefits and limitations of salt dilution by slug injection and conclude that the method could facilitate a proliferation of streamflow observation across headwater stream networks that are highly undersampled compared to larger streams.

溪流记录偏重于大的溪流和河流,而小的源头溪流往往是应对气候变化的生态研究重点。声学多普勒流速仪(ADV)等传统流量测量仪器在小溪流的低流量条件下表现不佳,导致在地下水流入为主的关键基流条件下无法绘制等级曲线。我们重新研究了一种基于配对测量的瞬时溶质示踪剂注入法,作为 ADV 的替代方法,以比较其在各种水流条件下的精度、效率和可行性。我们的研究表明,使用盐稀释注入法和 ADV 法测量排水量的精度总体上相当,但盐稀释注入法在最低流量时精度更高,而且实施所需的时间更短。通常情况下,上游溪流的深度处于或低于可以尝试 ADV 测量的临界值,而且横断面因粗糙的河床材料和鹅卵石而变得复杂。我们讨论了通过蛞蝓注入法稀释盐分的方法优势和局限性,并得出结论认为,这种方法可以促进溪流观测在源头溪流网络中的普及,因为与较大的溪流相比,源头溪流的取样严重不足。
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引用次数: 0
Applying 224Ra and 223Ra to Trace Lateral Groundwater Discharge into Lake Qinghai, China. 应用 224Ra 和 223Ra 追踪流入中国青海湖的侧向地下水。
Pub Date : 2024-12-29 DOI: 10.1111/gwat.13461
Weigang Su, Yujun Ma, Qiugui Wang

Quantifying lacustrine groundwater discharge (LGD) is important for understanding the dynamics of lake ecosystems and their expansion. This study focuses on Lake Qinghai, employing radium isotope models to evaluate the contributions of both shallow and deep groundwater. The data indicate that the activity of 223Ra and 224Ra demonstrates a pronounced gradient, decreasing from the shoreline to the center of Lake Qinghai. Additionally, vertical stratification characteristics were observed. The spatial distribution of radium isotope activity suggests that there is discharge of both shallow and deep groundwater into the lake. Deep groundwater migrates slowly and its apparent age reflects the time elapsed since the water became enriched in Ra and was isolated from the source, in the study system this age is estimated to be 10.1 d. In contrast, shallow groundwater displayed varied apparent ages in different regions: 7.9 d in the north, 13.1 d in the south, and 7.4 d in the southeastern area of the lake. The LGDs of shallow groundwater discharge in the north, south, and southeast areas of Lake Qinghai were estimated by 224Ra as 1.89 × 106 to 2.69 × 106 m3/d, 3.25 × 106 to 3.99 × 106 m3/d, and 4.51 × 106 to 6.33 × 106 m3/d, respectively. For deep groundwater, the LGD was 0.16 × 106 to 0.29 × 106 m3/d. Annually, the total LGD fluxes of shallow and deep groundwater are 27.86 × 108 to 37.59 × 108 m3/year and 0.58 × 108 to 1.06 × 108 m3/year, respectively. This study is the first to evaluate shallow and deep groundwater discharge around the lake. Understanding these discharge dynamics is essential for developing effective management strategies to preserve lake environments.

湖泊地下水流量的定量研究对于认识湖泊生态系统的动态及其扩展具有重要意义。本研究以青海湖为研究对象,采用镭同位素模型评价了浅层和深层地下水的贡献。数据表明,223Ra和224Ra的活度呈现明显的梯度,由湖岸向湖心递减。此外,还观察了垂直分层特征。镭同位素活度的空间分布表明,湖内既有浅层地下水,也有深层地下水。深层地下水迁移缓慢,其表观年龄反映了水富集Ra并与源分离的时间,在研究系统中估计其年龄为10.1 d。不同区域浅层地下水的表观年龄差异较大,北部为7.9 d,南部为13.1 d,东南部为7.4 d。利用224Ra估算青海湖北部、南部和东南部浅层地下水排放LGDs分别为1.89 × 106 ~ 2.69 × 106 m3/d、3.25 × 106 ~ 3.99 × 106 m3/d和4.51 × 106 ~ 6.33 × 106 m3/d。深层地下水LGD为0.16 × 106 ~ 0.29 × 106 m3/d。年浅层和深层地下水LGD总通量分别为27.86 × 108 ~ 37.59 × 108 m3/年和0.58 × 108 ~ 1.06 × 108 m3/年。本研究首次对环湖浅层和深层地下水流量进行了评价。了解这些排放动态对于制定有效的管理策略以保护湖泊环境至关重要。
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引用次数: 0
A Reduced Order Model for Sea Water Intrusion Simulation Using Proper Orthogonal Decomposition. 利用适当正交分解模拟海水入侵的低阶模型
Pub Date : 2024-12-27 DOI: 10.1111/gwat.13462
Mohammadali Geranmehr, Domenico Bau, Alex S Mayer, Weijiang Yu

Sea water intrusion (SWI) simulators are essential tools to assist the sustainable management of coastal aquifers. These simulators require the solution of coupled variable-density partial differential equations (PDEs), which reproduce the processes of groundwater flow and dissolved salt transport. The solution of these PDEs is typically addressed numerically with the use of density-dependent flow simulators, which are computationally intensive in most practical applications. To this end, model surrogates are generally developed as substitutes for full-scale aquifer models to trade off accuracy in exchange for computational efficiency. Surrogates represent an attractive option to support groundwater management situations in which fast simulators are required to evaluate large sets of alternative pumping strategies. Reduced-order models, a sub-category of surrogate models, are based on the original model equations and may provide quite accurate results at a small fraction of computational cost. In this study, a variable-density flow reduced-order model based on proper orthogonal decomposition (POD) and utilizing a fully coupled flow and solute-transport model is implemented with a finite-difference (FD) approach for simulating SWI in coastal aquifers. The accuracy and computational efficiency of the FD-POD approach for both homogeneous and-more realistic-heterogeneous systems are investigated using test cases based on the classic Henry's problem (Henry 1964). The findings demonstrate that the combined FD-POD approach is effective in terms of both accuracy and computational gain and can accommodate the output of the most popular variable-density flow models, such as those from USGS's MODFLOW family.

海水入侵(SWI)模拟器是协助沿海含水层可持续管理的重要工具。这些模拟器需要求解耦合变密度偏微分方程(PDEs),该方程再现了地下水流动和溶解盐运移的过程。这些偏微分方程的解决方案通常是通过使用密度相关的流动模拟器来解决的,这在大多数实际应用中都是计算密集型的。为此,模型替代品通常被开发为全尺寸含水层模型的替代品,以换取计算效率的准确性。在需要快速模拟器来评估大量替代抽水策略的情况下,替代品是支持地下水管理的一个有吸引力的选择。降阶模型是替代模型的一个子类别,它基于原始模型方程,可以以很小的计算成本提供相当准确的结果。本文采用有限差分(FD)方法,建立了基于适当正交分解(POD)的变密度流降阶模型,并利用完全耦合的流动和溶质输运模型来模拟沿海含水层SWI。使用基于经典Henry问题(Henry 1964)的测试用例,研究了FD-POD方法对同质系统和更现实的异构系统的准确性和计算效率。研究结果表明,FD-POD组合方法在精度和计算增益方面都是有效的,并且可以适应最流行的变密度流模型的输出,例如USGS的MODFLOW系列模型。
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引用次数: 0
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Ground water
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