Ground water最新文献

Due to increasing global demand for fresh water, it is increasingly necessary to understand how aquifer pumping affects groundwater chemistry. However, comprehensive predictive relationships between pumping and groundwater quality have yet to be developed, as the available data, which are often collected over inconsistent time intervals, are poorly suited for long-term historical correlation studies. For example, we needed an adequate statistical method to better understand relationships between pumping rate and water quality in the City of Norman (OK, USA). Here we used the interval-scaled change in mean pumping rate combined with the Quadrant method to examine correlations between pumping rates and changes in trace metal concentrations. We found that correlations vary across the study area and are likely dependent on a variety of factors specific to each well. Comparing the Quadrant method to the commonly used Kendall's tau correlation, which requires different assumptions about aquifer behavior, the methods produced similar correlations when sample sizes were large and the time interval between samples was relatively short. Sample sizes were then artificially restricted to determine correlation reproducibility. Despite being less reproducible overall, the Quadrant method was more reproducible when there were large time intervals between samples and very small sample sizes (n ~ 4), but not as reproducible as significant (p ≤ 0.1) Kendall's tau correlations. Therefore, the Quadrant method may be useful for further investigating the effects of pumping in cases where Kendall's tau does not produce significant correlations.

Drilling wells in unconsolidated formations is commonly undertaken to extract drinking water and other applications, such as aquifer thermal energy storage (ATES). To increase the efficiency of an ATES system, the drilling campaigns are targeting greater depths and enlarging the wellbore diameter in the production section to enhance the flow rates. In these cases, wells are more susceptible to collapse. Drilling fluids for shallow formations often have little strengthening properties and, due to single-string well design, come into contact with both the aquifer and the overburden. Drilling fluids and additives are experimentally investigated to be used to improve wellbore stability in conditions simulating field conditions in unconsolidated aquifers with a hydraulic conductivity of around 10 m/d. The impact on wellbore stability is evaluated using a new experimental setup in which the filtration rate is measured, followed by the use of a fall cone penetrometer augmented with an accelerometer to directly test the wellbore strengthening, and imaging with a scanning electron microscope (SEM) to investigate the (micro)structure of the filter cakes produced. Twelve drilling fluids are investigated with different concentrations of bentonite, polyanionic cellulose (PAC), Xanthan Gum, calcium carbonate (CaCO₃), and aluminum chloride hexahydrate ([Al(H₂O)₆]Cl₃). The filtration results indicate that calcium carbonate, average d_p <20 μm, provides pore throat bridging and filter cake formation after approximately 2 min, compared to almost instantaneous discharge when using conventional drilling fluids. The drilling fluid containing 2% [Al(H₂O)₆]Cl₃ forms a thick (4 mm) yet permeable filter cake, resulting in high filtration losses. The fall cone results show a decrease of cone penetration depth up to 20.78%, and a 40.27% increase in deceleration time while penetrating the sample with CaCO₃ compared with conventional drilling fluid containing bentonite and PAC, indicating a significant strengthening effect. The drilling fluids that contain CaCO₃, therefore, show high promise for field implementation.

The potential performance of a hypothetical colloidal-activated carbon (CAC) in situ remedy for perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) in groundwater in coastal zones was evaluated using estimated hydrogeologic and geochemical parameters for a coastal site in the United States. With these parameters, a reactive transport model (ISR-MT3DMS) was used to assess the effects of tidal fluctuations and near-shore geochemistry on CAC performance. The average near-shore ionic strength of 84 mM at the site was conservatively estimated to result in an increase in the adsorption of PFOA to CAC by about 50% relative to non-coastal sites with ionic strength <10 mM. The modeling also confirmed the hypothesis that tidally induced groundwater flow reversals near the shore would result in the accumulation of PFOA at the downgradient edge of the CAC zone. Slow desorption of PFOA from this downgradient CAC boundary may sustain downgradient plume concentrations above a strict cleanup criterion (e.g., USEPA MCL of 0.004 μg/L), for decades; however, there was still a large PFOA mass flux reduction (>99.9%) achieved after several decades at the shore. CAC longevity was substantially greater for PFOS with a similar source concentration; however, the higher PFOS distribution coefficient (K_d) in soil downgradient from the CAC zone resulted in substantially longer flushing times. It is recommended that short-term remedial action objectives for CAC remedies at coastal sites be based on mass flux reduction targets over a period of several decades, given the demonstrated challenges in trying to achieve very low cleanup criteria downgradient of a CAC zone in the short term.

Small island communities often rely on groundwater as their primary source of fresh water. However, the limited land area and high proportion of coastal zones pose unique challenges to groundwater management. A detailed understanding of the subsurface structure can provide valuable insights into aquifer structure, groundwater vulnerability, saltwater intrusion, and the location of water resources. These insights can guide groundwater management strategies, for example, pollution regulation, promotion of sustainable agriculture, establishment of coastal buffer zones, and re-naturalization of land cover. Ordinarily, structural characterization relies on geological mapping and boreholes, however, such approaches can have insufficient spatial resolution to aid groundwater management. In this study, transient electromagnetic (TEM) methods are used to map the subsurface of a small, 13.2 km², Danish Island. The approach successfully identified two previously unknown paleochannels, where the interface between Quaternary aquifer units and an underlying Paleogene Clay aquiclude had maximum depths of 100 and 160 m below sea level. Before this, the interface was assumed to be 15 to 25 m below sea level: therefore, these paleochannels present substantial potential groundwater resources. Resolving geological heterogeneity within the Quaternary deposits was less successful and future work will focus on addressing these limitations. Nonetheless, in several locations, evidence of saltwater intrusion was observed within the Quaternary units. This work demonstrates how TEM mapping can identify water resources, define aquifer boundaries, and aid water management decisions. Such approaches could be applied in other areas, particularly small islands, where similar groundwater challenges exist.

The step-drawdown pumping test often experiences a transition from confined to unconfined conditions due to the continuously increasing pumping rate. However, the current well hydraulics model has not accurately interpreted this phenomenon. In this study, we developed an analytical solution to address the confined-unconfined conversion in step-drawdown pumping tests based on Girinskii's potential and superposition theory. Additionally, a field step-drawdown pumping test featuring confined-unconfined conversion was conducted to apply the proposed analytical solution. The particle swarm optimization algorithm was employed to simultaneously estimate multiple parameters. The results demonstrate that the newly proposed solution provides a better fit to the observed drawdown in the pumping well compared to previous models. The hydrogeological parameters (K, S), well loss coefficient (B), and critical time for confined-unconfined conversion (t_c) were estimated to be K = 7.15 m/d, S = 6.65 × 10^-5, B = 7.48 × 10^-6, and t_c = 1152 min, respectively. Neglecting the confined-unconfined conversion in step-drawdown pumping tests leads to underestimation of drawdown inside the pumping well due to an overestimation of the aquifer thickness. After the conversion from confined to unconfined conditions, the estimated well loss coefficient decreased by 88% compared to its pre-conversion value. This highlights the necessity of adjusting the well loss coefficient in the step-drawdown pumping test model to account for confined-unconfined conversion. In summary, this study introduces a new method for interpreting parameters in step-drawdown pumping tests and provides field validation for its effectiveness.

This study enhances the understanding of riverbank filtration and improves management of the Mississippi River valley alluvial (MRVA) aquifer during a managed aquifer recharge (MAR) pilot project at Shellmound, MS. Using high-resolution electrical resistivity tomography (ERT) and self-potential (SP) geophysical methods, we characterized the heterogeneous MRVA aquifer and monitored groundwater flow near a pumping well. ERT was used to provide detailed spatial characterization, filling gaps left by airborne electromagnetic (AEM) data and soil boring logs, while SP techniques were used to monitor groundwater flow, predict drawdown trends, and investigate surface-groundwater interactions. Results showed that SP signals were influenced by groundwater flow, river infiltration, and water mixing due to pumping disturbance of natural geochemical stratification, with significant river interaction observed after 1 h of pumping. The integration of ERT and SP methods revealed lithologic heterogeneity, explaining greater drawdowns on the northern side of the well and increased flow from the riverside. This comprehensive approach offers valuable insights into aquifer management and sustainability.

Research into land subsidence caused by groundwater withdrawal is hindered by the availability of measured heads, subsidence, and forcings. In this paper, a parsimonious, linked data-driven and physics-based approach is introduced to simulate pumping-induced subsidence; the approach is intended to be applied at observation well nests. Time series analysis using response functions is applied to simulate heads in aquifers. The heads in the clay layers are simulated with a one-dimensional diffusion model, using the heads in the aquifers as boundary conditions. Finally, simulated heads in the layers are used to model land subsidence. The developed approach is applied to the city of Bangkok, Thailand, where relatively short time series of head and subsidence measurements are available at or near 23 well nests; an estimate of basin-wide pumping is available for a longer period. Despite the data scarcity, data-driven time series models at observation wells successfully simulate groundwater dynamics in aquifers with an average root mean square error (RMSE) of 2.8 m, relative to an average total range of 21 m. Simulated subsidence matches sparse (and sometimes very noisy) land subsidence measurements reasonably well with an average RMSE of 1.6 cm/year, relative to an average total range of 5.4 cm/year. Performance is not good at eight out of 23 locations, most likely because basin-wide pumping is not representative of localized pumping. Overall, this study demonstrates the potential of a parsimonious, linked data-driven, and physics-based approach to model pumping-induced subsidence in areas with limited data.