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Enhancement of the Mechanical Behavior of Starch-Palm Fiber Composites 淀粉-棕榈纤维复合材料力学性能的增强
Pub Date : 2019-01-01 DOI: 10.21741/9781644900178-15
A. Wifi, H. Megahed, M. Emara, M. Shazly, M. Farag
This study discusses the fabrication of starchbased hybrid composite reinforced with chopped randomly oriented flax, sisal, and date palm fibers. The tensile properties, before and after chemical treatment, as well as the morphology of the fibers were evaluated. The hybrid composites were fabricated using hot compaction technique at 5MPa and 160°C for 30min. Fracture surface investigations using field emission scanning microscopy showed a good adhesion between fibers and matrix. The fracture surface revealed the presence of matrix micro cracks as well as fibers fracture and pullout. Hybrid composites containing 20 vf % sisal, and 5 vf % flax at 25 vf % date palm as well as 35vf% sisal, and 5 vf % flax at 10 vf % date palm had the optimum mechanical properties and consequently can serve as competitive ecofriendly candidates for various applications. A finite element (FE) approach was developed to simplify the treatment of random orientation of chopped fibers and predict elastic modulus using Embedded Element technique. Analyses based on rule of hybrid composite (ROHM), COX rule, and Leowenstein rule are presented to validate both experimental and FE numerical results. The FE results compared favorably with the experimental results. Introduction The construction of natural fiber bio-composite may have very good applications in the automotive and transportation industry such as car door panels which may save up to 45% from door panel carrier weight, bio-based cushions, the driver’s seat back rest, etc. Moreover, reducing cost of bio-composites will be more desirable to industrial economic development [1]. Biodegradable composite materials based on natural fibers and starch had attracted attention over the past several years. Starch is one of polysaccharide matrices. Owing to its low cost, availability as a renewable resource, biodegradable and nontoxic degradation products, it is one of the important raw materials used for packaging, biomedical applications, and in some By-Products of Palm Trees and Their Applications Materials Research Forum LLC Materials Research Proceedings 11 (2019) 201-210 doi: https://doi.org/10.21741/9781644900178-15 202 automotive parts. Starch, however, has some drawbacks such as poor melting process ability, high water solubility, difficulty of processing, and brittleness. Gelatinization process converts starch to thermoplastic starch (TPS) and improves those draw backs [2-3]. Date-Palm fiber (DPF) is a low cost material with mechanical properties that depend on the place of extraction. DPF can be considered one of the best types of fibers regarding several evaluation criteria such as specific strength to cost ratio if compared to other fiber types [4]. Sisal fiber (SF) is known by its high strength but it has some limitations such as high cost and is not cultivated in Egypt [5]. Flax fiber (FF) has mechanical properties near to SF; however, the cultivation of Flax has been diminished in Egypt as it can be replaced by othe
研究了以亚麻纤维、剑麻纤维和椰枣纤维为增强材料的淀粉基杂化复合材料的制备。对化学处理前后纤维的拉伸性能和形貌进行了评价。采用热压技术,在5MPa、160℃、30min条件下制备复合材料。用场发射扫描显微镜观察断口表面,发现纤维与基体之间有良好的粘附性。断口表面存在基体微裂纹,纤维断裂和拉出。混合复合材料中含有20%剑麻和5%亚麻(25%)、35%剑麻和5%亚麻(10%)的枣椰树具有最佳的力学性能,因此可以作为具有竞争力的环保候选材料用于各种应用。提出了一种简化剪切纤维随机取向处理的有限元方法,并利用嵌入单元技术预测弹性模量。基于混合复合规则(ROHM)、COX规则和Leowenstein规则进行了分析,验证了实验结果和数值结果。有限元计算结果与实验结果吻合较好。天然纤维生物复合材料的结构在汽车和交通运输行业有很好的应用,如汽车门板,可节省高达45%的门板载体重量,生物基坐垫,驾驶员座椅靠背等。此外,降低生物复合材料的成本将更有利于工业经济的发展。近年来,以天然纤维和淀粉为基础的可生物降解复合材料备受关注。淀粉是多糖基质之一。由于其成本低,可再生资源,可生物降解和无毒降解产品,它是用于包装,生物医学应用的重要原材料之一,以及一些棕榈树及其应用的副产品材料研究论坛LLC材料研究进展11 (2019)201-210 doi: https://doi.org/10.21741/9781644900178-15 202汽车零部件。然而,淀粉具有熔融加工能力差、水溶性高、加工难度大、易碎等缺点。糊化过程将淀粉转化为热塑性淀粉(TPS)并改善了这些缺陷[2-3]。枣棕榈纤维(DPF)是一种低成本材料,其机械性能取决于提取地点。DPF可以被认为是最好的纤维类型之一,根据几个评估标准,如比强度成本比,如果与其他纤维类型相比[4]。剑麻纤维(SF)以其高强度而闻名,但它有一些局限性,如成本高,并且在埃及没有种植。亚麻纤维(FF)的力学性能接近SF;然而,在埃及,亚麻的种植已经减少,因为它可以被其他进口材料取代[1,6]。几种纤维类型被纳入混合复合材料中,这种复合材料可以比传统复合材料更经济地满足各种设计要求。它们的性能取决于掺入纤维的特性和力学性能。增强材料[8]的纤维类型、长度、取向、表征、树脂类型和体积分数等因素会影响复合材料的力学性能。本研究的目的是研究含有三种纤维(DPF、FF和SF)的淀粉基混杂复合材料的性能,并将其与1:1基质/纤维体积比的亚麻/椰枣混杂复合材料的力学性能进行比较。目前的工作包括实验和数值研究。采用不同体积分数的纤维混合进行复合制备阶段,如表1所示。复合材料分析的第一阶段是基于材料的力学性能测量、断口检测和材料的形态表征。最后是有限元分析阶段;其中使用ABAQUS软件实现了不同的模型。提出了混合有限元分析方法来预测具有随机取向短切纤维的增强复合材料的杨氏模量。提出了一种尝试,以克服在有限元表示中表示短切纤维跨复合材料随机方向的困难。尝试以体积分数为33.3%的单向纤维来表示复合材料中随机取向短切纤维的实际体积分数。材料制备、表征及力学性能测试:玉米淀粉购自埃及Aro Sheri公司,平均粒径为16μm。以纯度为99.7%的甘油为增塑剂。 采用参考[3]方法的淀粉糊化过程,将天然淀粉与30Wt混合形成TPS。%甘油和20Wt。%蒸馏水,温度范围60 - 80℃。添加甘油可通过抑制返级过程提高加工能力,减少脆化。在使用前,将TPS放在聚乙烯袋中过夜以增强其流动性能。亚麻和剑麻是由埃及工业中心E.I.C.捐赠的,DPFs是从开罗美国大学的枣椰树茎中提取的。氢氧化钠(NaOH)分子量为40g/mol。用于纤维的碱性处理。三种纤维(DPF、FF和SF)的化学处理方法如下:1)室温下5% NaOH浸泡3小时。2)用冷水冲洗处理过的纤维。3)将纤维浸泡在5%的醋酸中,去除纤维表面多余的NaOH。4)冷水冲洗,120℃烘箱烘干3小时。5)将处理后的纤维手工切割成短纤维,根据长径比,平均长度从15到30mm不等。采用以下方法进行表征和测试:1)使用徕卡立体显微镜测量化学处理前后的纤维直径,采用10个样品,直径为1 μm。2)使用Mittler Toledo密度计测定10个样品的TPS和纤维密度(以二甲苯为浸泡液,相对密度为0.86)。3)拉伸试验采用Instron 3382万能试验机,在50% RH, 18oC,应变速率0.01/min条件下,片长50mm,应变速率0.01/min。4)利用蔡司扫描电子显微镜(SEM)在真空压力1e- 4mbar和8KV下对纤维断裂面进行研究。混杂随机复合材料制备:按照式14,以纤维与基体体积比为1:1制备不同的复合材料。在不同的SF和FF体积分数百分比下,DPF的纤维含量为50vf% ~ 20vf%。纤维切割长度以纤维长径比为基础。采用浓度为98%的硬脂酸作为脱模剂。将纤维混合物均匀分布在模腔(120X80X10mm)内,形成10种不同纤维体积分数的混杂复合材料,如表1所示。将乳化后的TPS倒在随机混合纤维上。然后将混合物在140±3°c下预热30min,以去除混合物中的多余水分。然后在5MPa和160°c下热压30min,然后以约2°c /min的速度冷却。VT = Vf + Vm = WWf ρf + Wm ρm =(4∗df 2∗lf∗nf) + (Wm∗lm∗hm) (1)
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引用次数: 3
The Effect of Some Micro-Elements on Free Amino Acids, Indols and total Phenols Production from Embryogenic Callus of Tow Date Palm Cultivars (Sakkoty and Bartamuda) 微量元素对两种枣椰树胚性愈伤组织游离氨基酸、吲哚和总酚产量的影响
Pub Date : 2019-01-01 DOI: 10.21741/9781644900178-19
S. Sharabasy, H. Bosila, Abdel-Monem A. Bana, Bayome M. Mansour
Effect of microelements on some chemicals analysis of secondry metabolits such as free amino acids, total indols content and total phenols content of date palm cultivars (Sakkoty and Bartamuda) were study in this work. Different concentrations of manganese sulfate (MnSO4 2 H2O) (22.3, 44.6 and 66.9 mg/l), zinc sulfate (ZnSO47H2O) (8.6, 17.2 and 25.8 mg/l) and copper sulfate (CuSO45H2O) (0.025, 0.050, 0.075 mg/l) were added into nutrient medium of embryogenic callus stage. The results illustrated that, addtion of manganese sulfate at ( 22.3 mg/l) to culture medium of embryonic callus of Bartamoda cv. gave the highest significant values of total free amino acids (1.75 mg/g fresh weight) and (0.33 mg/g fresh weight) of total indols. Where the addition of manganese sulfate at (66.9 mg/l) to nuutrient medium of growing embryogenic callus of Bartamuda cv. gave the highest significant value of total phenols (1.17 mg/g fresh weight). The addititon of zinc sulfate at (17.2 mg/l) to culture medium of embryogenic callus of Sakkoty cv., recorded the highest significant values of total amino acids (1.64 mg/g fresh weight) and Indoles( 0.40 mg/g fresh weight). While the highest significant values of total phenol content was (1.24 mg/g fresh weight) when embryonic callus of Sakkoty cv. grown on medium contained zinc sulfate at (25.8 mg/l). Data showed also the highest significant values of total free amino acids and total indols content (1.36 and 0.40 mg/g fresh weight respectively) were achived when embryogenic callus of Bartamuda cv. was grown on medium containing of copper sulfate at (0.025 mg/l),wherase the highest significant value of total phenols content (1.83 mg/g fresh weight) were recorded when embryonic callus of Sakkoty cv. was grown on nutrient medium supplemented with copper sulfate at (0.075 mg/l). Introduction Date palm has indispensable utilization in the economy and domestic life of growing countries. It is considered one of the most important commercial crops in the Middle East and Arab World [1]. Secondary metabolites are considered as chemicals that are produced by plants and these chemicals are diverse, Identification of them made into many classes. Each species or plant family has its own mixture of secondary metabolites and that's considered a main advantage in classification of plants. These chemicals could be used for medicinal purposes for humans [2]. Date palms can accumulate many chemicals in their tissues, as a primary metabolites containing carbohydrates and proteins, and secondary metabolites which are produced from primary ones By-Products of Palm Trees and Their Applications Materials Research Forum LLC Materials Research Proceedings 11 (2019) 235-243 doi: https://doi.org/10.21741/9781644900178-19 236 such as phenolics [3].Secondary metabolite production can be induced by medium optimizations [4,5]. Microelements have many diverse roles and they are required in trace amounts for plant growth and development [6]. Culture conditi
研究了微量元素对枣椰树(Sakkoty和Bartamuda)次生代谢产物中游离氨基酸、总吲哚和总酚含量的影响。将不同浓度的硫酸锰(mnso4h2o)(22.3、44.6和66.9 mg/l)、硫酸锌(ZnSO47H2O)(8.6、17.2和25.8 mg/l)和硫酸铜(CuSO45H2O)(0.025、0.050、0.075 mg/l)添加到胚性愈伤组织阶段的营养培养基中。结果表明,添加硫酸锰(22.3 mg/l)对柽柳胚愈伤组织的培养效果较好。总游离氨基酸(1.75 mg/g鲜重)和总吲哚(0.33 mg/g鲜重)的显著值最高。其中,在愈伤组织培养基中添加(66.9 mg/l)硫酸锰。总酚含量最高(1.17 mg/g鲜重)。在Sakkoty cv胚性愈伤组织培养基中添加(17.2 mg/l)硫酸锌。总氨基酸(1.64 mg/g鲜重)和吲哚(0.40 mg/g鲜重)含量最高。总酚含量最高的显著值为(1.24 mg/g鲜重)。在硫酸锌浓度为(25.8 mg/l)的培养基上生长。总游离氨基酸和总吲哚含量均以百达菇胚性愈伤组织最高(分别为1.36和0.40 mg/g鲜重)。在硫酸铜含量为(0.025 mg/l)的培养基上生长,其中Sakkoty cv胚愈伤组织中总酚含量最高,为1.83 mg/g鲜重。在添加硫酸铜(0.075 mg/l)的培养基上生长。枣椰树在种植国的经济和家庭生活中有着不可缺少的用途。它被认为是中东和阿拉伯世界最重要的经济作物之一[1]。次生代谢物是指植物产生的化学物质,这些化学物质种类繁多,鉴定分为许多类。每个物种或植物科都有自己的次生代谢物混合物,这被认为是植物分类的一个主要优势。这些化学物质可用于人类的医药用途[2]。枣椰树可以在其组织中积累许多化学物质,如含有碳水化合物和蛋白质的初级代谢物,以及由初级代谢物产生的次级代谢物,如酚类物质,如棕榈树及其应用材料研究论坛LLC材料研究进展11 (2019)235-243 doi: https://doi.org/10.21741/9781644900178-19 236[3]。培养基优化可以诱导次生代谢物的产生[4,5]。微量元素具有多种作用,是植物生长发育所必需的微量元素[6]。培养条件对通过次生代谢物获得的物质的质量和数量起着重要作用[7]。优化培养条件对提高所需产物的积累是有效的。外界因素如碳源、氮源、生长调节剂、培养基pH、温度、光、氧等被认为容易调控植物次生代谢途径的表达[8]。植物细胞培养基中的成分是次生代谢产物生长和产生的决定因素。必需微量营养素在活性成分产生中的特殊作用是由于它们作为次级代谢酶的组分或激活剂的功能。此外,金属可以抑制植物组织中的某些植物化学物质[9]。本研究旨在研究微量元素对离体枣胚性愈伤组织游离氨基酸、总吲哚和总酚含量的影响。材料与方法采用文献[10,11]所述的枣椰树间接增殖方法,制备Bartamuda和Sakkoty两个品种的愈伤组织外植体。本研究将两个品种的胚愈伤组织外植体培养在MS基础培养基上形成愈伤组织[12],在培养基中添加30 g/l蔗糖和3.0 g/l活性炭,并添加40 mg/l硫酸腺嘌呤、200 mg/l谷氨酰胺、100 mg/l肌醇、0.1 mg/l生物素、170 mg/l NaH2PO4、0.1 mg/l硫胺素HCL、0.5 mg/l吡醇、0.5 mg/l烟酸,3.0 mg/L 2isopentenyl腺嘌呤(2iP) + 10.0 mg/L 2,4 - D二氯苯氧乙酸(2,4 - D)。微量元素化合物,硫酸锰(MnSO4.4H2O),七水合硫酸锌(ZnSO4.7H2O)和硫酸铜(CuSO4.5H2O)添加到Bartamuda和Sakkoty cv的基础营养培养基中。愈伤组织培养,分别采用以下三种不同的分离处理:1-硫酸锰(MnSO4)。 分别在(22.3、44.6和66.9 mg/l)的浓度下加入七水硫酸锌(ZnSO4.7H2O)(8.6、17.2和25.8 mg/l);在(0.025、0.050和0.075 mg/l)的浓度下加入硫酸铜(CuSO4.5H2O),用6.0 g/l的琼脂固化培养基,分布在培养罐中(250 ml);每个罐子装25毫升培养培养基。立即用聚丙烯封口盖上培养罐,在121_C下以1.05 kg/cm2高压灭菌20分钟。培养罐在27±1_C的完全黑暗条件下孵育,每(6周)记录三次传代的总类固醇含量(mg/g干重)数据。采用微量元素处理,分别为硫酸锰(MnSO4.4H2O)、七水合硫酸锌(ZnSO4.7H2O)和硫酸铜(CuSO4.5H2O),收集了Bartamuda和Sakkoty cv的愈伤组织样品。对于下面的实验1。游离氨基酸的测定总氨基氮或游离氨基酸按Rosein法测定[13]。测定时,取1 ml的样品移液到一系列试管中,然后用蒸馏水使总体积达到4 ml。每管加入1 ml茚三酮试剂(4%,4 g茚三酮溶于50 ml丙酮和50 ml醋酸缓冲液中),混合均匀,置于沸水浴中保存15 min,然后在50%乙醇的量瓶中冷却至10 ml。所开发的粉红色是使用棕榈树及其应用的副产品材料研究论坛LLC材料研究进展11 (2019)235-243 doi: https://doi.org/10.21741/9781644900178-19 237分光光度计在570 nm dl -丙氨酸下测量的。根据标准曲线计算丙氨酸总氨基氮浓度。2. 吲哚和酚类物质的提取新鲜样品1 g,分3个重复,切成小片,用5 ml 80%的冷甲醇提取,低温保存24h。收集并过滤组合提取物。然后,用冷甲醇将样品的体积提高到已知体积。用对二甲基氨基苯甲醛(PDAB)试剂测定甲醇提取物中的总吲哚,取1 g溶于50 ml盐酸中。根据Larsen等人[14],50 ml乙醇95%)试验。取甲醇提取物1 ml移入试管中,加入PDAB试剂4 ml, 30 - 40℃孵育1 h,在530 nm处分光光度法测定所得颜色的强度。建立了不同浓度IAA与相应吸光度值的关系标准曲线。B总酚类物质的测定根据daniel和George[15]进行酚类物质的测定。为了估计总酚,将1 ml甲醇组织提取物加入0.5 ml Folin-Ciocalteu 's Phenol Reagent中摇匀3分钟。然后加入1 ml饱和Na2CO3 (25% w/v)和17.5 ml蒸馏水。混合物在3040℃下放置1小时。用波长为730 nm的色度计测定了样品的光密度。不同样品中总酚的浓度以mg苯酚/100g FW计算。根据邻苯甲醇(99.5%)的标准曲线计算总酚类化合物的含量。统计分析对所得资料进行方差分析。在5%的概率水平上,采用LSD检验比较平均值。采用Snedecor & Cochran随机完全区组设计,3个重复[16],将数据制成表格并进行统计析因分析。硫酸锰(MnSO4.4H2O)浓度对离体枣椰树(Sakkoty和Bartamuda品种)胚性愈伤组织阶段某些化学成分(氨基酸总量、吲哚类和酚类)的影响硫酸锰对总氨基酸含量(mg/g鲜重)的影响表(1)中的数据清楚地表明,所研究的两个品种之间没有显著差异(0.90、0.90
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引用次数: 1
Effect of Vitamins (pyridoxine and nicotinic acid), Thiamine-Hcl and Myo-Inositol at Different Concentrations on Free Amino Acids and Indoles Content of Embryogeinic Callus of in vitro Date Oalm (Sakkoty and Bartamuda Cultivar) 不同浓度维生素(吡哆醇和烟酸)、硫胺素-盐酸和肌醇对枣树胚性愈伤组织游离氨基酸和吲哚含量的影响
Pub Date : 2019-01-01 DOI: 10.21741/9781644900178-20
S. Sharabasy
The potential of using tissue culture technique for the production of some bioactive compounds since it allows the manipulation of the biosynthetic routes to increase the production and accumulation of specific compounds. This study was conducted to investigate the effect of vitamins (pyridoxine and nicotinic acid), thiamine-Hcl at different cocentrations (0.5, 1.0 & 2.0 mg/l) and myo-inositol at different concentrations (25, 50, and 100mg/l) at different cocentrations supplemented in MS basal nutrient medium of embryogenic callus of date palm on the production of secondary metabolites of amino acids and indoles. Tow egyption cultivars (Sakkoty and Bartamuda cultivars) of date palm were used. Pyridoxine concentration at 0.5mg/l was the most effective concentration in the production of amino acids and indoles from embryonic callus of the tow studied cultivars of date palm. Nicotinic acid at 0.5mg/l showed also the best results of production of amino acids and indoles from embryogenic callus of two cultivars. Acording to thiamine at 2mg/l concentration was the most effective in inducing the highest significant value of amino acids and indoles from embryonic callus of two cultivars of date palm. Myo-inositol concentration at 25mg/l produced the highest significant value of amino acids and indoles. Introduction Many higher plants are major sources of natural product used as pharmaceuticals, agrochemicals, flavor and fragrance ingredients, food additives, and pesticides [1]. The search for new plant derived. In the search for alternatives to production of desirable medicinal compounds from plants, biotechnological approaches, specifically, plant tissue cultures, are found to have potential as a supplement to traditional agriculture in the industrial production of bioactive plant metabolites [2]. Date palm tree Phoenix dactylifera L. is a multipurpose tree from whole tree, the cultivation of this crop was distributed in North Africa and Middle East specially in Arabian Peninsula. Date palm tree can accumulate many chemicals in their tissues, as primary metabolites containing carbohydrates and proteins, and secondary metabolites which are produced from primary ones [3,4]. The yield of secondary compounds in plants cells can be enhanced by precursor feeding in culture medium it has been a normal and a popular approach to increase this bioactive compounds [5]. secondary metabolite formation has shown that the media components have an influence on metabolism [6]. Vitamins, myoinositol and thiamineHCl are considered important copmonents which induce plant cell growth also thier role in stimulated the bioactve metabolites as precursors has been reported [6-9]. The aim of this work is By-Products of Palm Trees and Their Applications Materials Research Forum LLC Materials Research Proceedings 11 (2019) 244-252 doi: https://doi.org/10.21741/9781644900178-20 245 to study the effect of some vitamins (Pyridoxine hydrochloride, Nicotinic acid, Thiamine hydrochlorid
利用组织培养技术生产某些生物活性化合物的潜力,因为它允许操纵生物合成途径来增加特定化合物的生产和积累。本试验研究了在枣椰树胚性愈伤组织MS基础营养培养基中添加不同浓度的维生素(吡醇和烟酸)、不同浓度的硫胺素-盐酸(0.5、1.0和2.0 mg/l)和不同浓度的肌醇(25、50和100mg/l)对氨基酸和吲哚次生代谢产物产生的影响。枣椰树采用两个埃及品种(Sakkoty和Bartamuda)。吡哆醇浓度为0.5mg/l时,对两种枣椰树胚愈伤组织产生氨基酸和吲哚最有效。0.5mg/l烟酸对两个品种胚性愈伤组织产生氨基酸和吲哚的效果最好。结果表明,硫胺素在2mg/l浓度下对两种枣椰树胚愈伤组织中氨基酸和吲哚的诱导效果最好,显著值最高。肌醇浓度为25mg/l时,氨基酸和吲哚的显著值最高。许多高等植物是用作医药、农用化学品、香精香料、食品添加剂和农药等天然产物的主要来源[1]。对新植物的探索由此衍生。在寻找从植物中生产所需药用化合物的替代品时,人们发现生物技术方法,特别是植物组织培养,在生物活性植物代谢物的工业生产中具有作为传统农业补充的潜力[2]。枣椰树(Phoenix dactylifera L.)是一种全树多用途树种,主要分布在北非和中东地区,特别是阿拉伯半岛。枣椰树可以在组织中积累许多化学物质,如含有碳水化合物和蛋白质的初级代谢物,以及由初级代谢物产生的次级代谢物[3,4]。通过在培养基中饲喂前体可以提高植物细胞中次生化合物的产量,增加这种生物活性化合物已经是一种正常和流行的方法[5]。次生代谢物的形成表明培养基成分对代谢有影响[6]。维生素、肌醇和硫胺素被认为是诱导植物细胞生长的重要成分,它们在刺激生物活性代谢物作为前体中的作用已被报道[6-9]。本研究的目的是研究几种维生素(盐酸吡哆醇、烟酸、盐酸硫胺素、肌醇)对离体枣树(Sakkoty和Bartamuda品种)胚性愈伤组织阶段(游离氨基酸含量、总吲哚含量)的影响。材料与方法采用文献[10,11]所述的枣椰树间接增殖方法,制备Bartamuda和Sakkoty两个品种的愈伤组织外植体。本研究将两个品种的胚愈伤组织外植体培养在MS基础培养基上形成愈伤组织[12],在培养基中添加30 g/l蔗糖和3.0 g/l活性炭,并添加40 mg/l硫酸腺嘌呤、200 mg/l谷氨酰胺、100 mg/l肌醇、0.1 mg/l生物素、170 mg/l NaH2PO4、0.1 mg/l硫胺素HCl、0.5 mg/l吡啶醇、0.5 mg/l烟酸,3.0 mg/l 2isopentenyl adenine (2iP) + 10.0 mg/l 2,4 - D二氯苯氧乙酸(2,4 - D)。采用文献[10,11]所述的枣树微繁间接方案,制备了Bartamuda和Sakkoty两个品种的愈伤组织外植体。本研究将两个品种的胚愈伤组织外植体培养在MS基础培养基上形成愈伤组织[12],在培养基中添加30 g/l蔗糖和3.0 g/l活性炭,并添加40 mg/l硫酸腺嘌呤、200 mg/l谷氨酰胺、100 mg/l肌醇、0.1 mg/l生物素、170 mg/l NaH2PO4、0.1 mg/l硫胺素HCL、0.5 mg/l吡醇、0.5 mg/l烟酸,3.0 mg/L 2异戊基腺嘌呤(2iP) + 10.0 mg/L 2,4 - D二氯苯氧乙酸(2,4 - D)。维生素的影响盐酸吡哆醇浓度对胚性愈伤组织次生代谢产物的影响。盐酸吡哆醇浓度:a) 0.5 mg/l b) 1.0 mg/l c) 2.0 mg/l。烟酸浓度对胚性愈伤组织次生代谢产物的影响。烟酸浓度:a) 0.5 mg/l b) 1.0 mg/l c) 2.0 mg/l。盐酸硫胺素浓度对胚性愈伤组织次生代谢产物的影响。2. 硫胺-盐酸浓度的影响:a) 0。 5mg / b) 1.0 mg/l c) 2.0 mg/l肌醇浓度a) 25 mg/l b) 50 mg/l c) 100 mg/l的影响。用6.0 g/l琼脂固化培养基,分布于培养罐中(250 ml);每个罐子装25毫升培养培养基。立即用聚丙烯密封盖上培养罐,在121°C 1.05 kg/cm高压灭菌20分钟。培养罐在27±1°C的完全黑暗条件下孵育,每(6周)记录三次总类固醇(mg/g干重)传代培养的数据。采用微量元素处理,分别为硫酸锰()、七水硫酸锌(MnSO4.4H2O)和硫酸铜(CuSO4.5H2O),收集了Bartamuda和Sakkoty cv的愈伤组织样品。用于接下来的实验。1. 游离氨基酸的测定总氨基氮或游离氨基酸按Rosein法测定[13]。测定时,取1 ml的样品移液到一系列试管中,然后用蒸馏水使总体积达到4 ml。一毫升的茚三酮试剂(4%,4 g茚三酮溶解在50毫升的副产品棕榈树和他们的应用程序材料研究论坛LLC材料研究学报11 (2019)244 - 252 . doi: https://doi.org/10.21741/9781644900178-20 246丙酮和醋酸50毫升缓冲区)被添加到每个管,混合好,和管在沸水浴15分钟。然后,管冷却,体积是10毫升量瓶乙醇50%。用分光光度计在570 nm dl -丙氨酸处测量所示的粉红色。根据标准曲线计算丙氨酸总氨基氮浓度。2. 吲哚和酚类物质的提取新鲜样品1 g,分3个重复,切成小片,用5 ml 80%的冷甲醇提取,低温保存24h。收集并过滤组合提取物。然后,用冷甲醇将样品的体积提高到已知体积。a -总吲哚的测定甲醇提取物中总吲哚的测定采用对二甲基氨基苯甲醛(PDAB)试剂,取1 g溶于50 ml盐酸中。根据Larsen等[14]进行50 ml乙醇95%)试验。取甲醇提取物1 ml移入试管中,加入PDAB试剂4 ml, 30 - 40℃孵育1 h,在530 nm处分光光度法测定所得颜色的强度。建立了不同浓度IAA与相应吸光度值的关系标准曲线。b -总酚类物质的测定根据daniel和George[15]进行酚类物质的测定。为了估计总酚,将1 ml甲醇组织提取物加入0.5 ml Folin-Ciocalteu 's Phenol Reagent中摇匀3分钟。然后加入1 ml饱和Na2CO3 (25% w/v)和17.5 ml蒸馏水。混合物在3040℃下放置1小时。用波长为730 nm的色度计测定了样品的光密度。不同样品中总酚的浓度以mg苯酚/100g FW计算。根据邻苯甲醇(99.5%)的标准曲线计算总酚类化合物的含量。统计分析对所得资料进行方差分析。在5%的概率水平上,采用LSD检验比较平均值。采用Snedecor & Cochran随机完全区组设计,3个重复[16],将数据制成表格并进行统计析因分析。结果与讨论盐酸吡哆醇对总氨基酸含量(mg/g鲜重)的影响。从表1的数据可以清楚地看出,两个品种间的互作效应差异不显著(分别为0.99、0.94 mg/g鲜重),其中以吡哆醇浓度(0.5mg/l)效果最好,诱导的显著值最高(1.65 mg/g鲜重)。结果表明,Sakkoty和Bartamuda两品种胚性愈伤组织在含有(0.5 mg/l)吡哆醇的培养基上生长时,其鲜重最高(1.65 mg/g
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引用次数: 4
Effect of Natural Additives as Coconut Milk on the Shooting and Rooting Media of in vitro Barhi Date Palm (Phoenix dactylifera L.) 椰奶等天然添加剂对巴氏枣椰树离体发芽和生根培养基的影响
Pub Date : 2019-01-01 DOI: 10.21741/9781644900178-13
S. El-Sharabasy, H. Ghazzawy
The objective of the research study was to determine the effect of addition of different concentrations of three types of natural additives on Date Palm cv. Barhi: (1.25g/l, 2.5g/l, 5.0g/l for Casein Hydrolysate and 10%, 20%, 30% for (Coconut Milk and Yeast Extract), in addition to the control (0.05 BA mg/l) for shooting stage and (0.1 NAA mg/l, 3 g/l AC) for rooting stage. The results show that the use of 30% Coconut Milk achieved a high number of shoots and the highest shoot length was recorded with 10% Coconut Milk. In the date palm rooting stage, the results show that the use of 30% Coconut Milk increased the number of roots, shoot thickness and rooting percentage. However, root length was increased with 10% Coconut Milk. The lowest values were recorded with using Yeast Extract in this stage. Introduction Date palm (Phoenix dactylifera. L.) has a great economical importananc and agricultural uses throughout human’s history. Also, it is one of the oldest cultivated fruit trees in the world. Date palm is a very important crop in the Middle East, since it can grow well in both semi-dry desert areas and the newly cultivated land. The production of Arab world of dates is about 80% of the total production of the world. Egypt is the world largest date producing country i.e. more fruitful female palms (1.5M tonnes/annum) produce 1.694.813 tons of dates [9], [7]. In Egypt, date palm trees distribution covers a large area extends from Aswan to north Delta, beside the Oasis of Siwa, Bahriya, Farafra, Kharga, Dakhla. Egypt is one of the most productive countries of dates in the world, the number of fruitful female palms in Egypt is about 15 million produce 1.694.813 tons of dates [9]. Date palm is commonly propagated by ground offshoots; however, a female date palm produces only 10-20 offshoots in its entire life [20], which is a limiting factor for the propagation of commercial cultivars. A non-conventional technique of in vitro culture is widely used in many species including date palm [14]. The production of plants through in vitro culture is successfully introduced in many species [23]. The technique of tissue culture for propagation date palm, also called in vitro propagation, has many advantages as larg scale multiplication troughout the year, production healthy female cultivars, (disease and pest-free), or males having superior pollen; production of genetically uniform plants [19]. Recently, the natural products is using Yeast and plant extracts in vitro which have been discovered. Some undefined components such as Yeast Extracts, Frnit Juices and Protein Hydrolysate were frequently used in nutrient media as opposed to defined amino acids or vitamins as a further supplementation [4]. In addition, some other natural additives as Coconut Milk is frequently used as a popular addition to the media of orchid cultures in the floral industry of tissue culturing [5]. Natural extract could be By-Products of Palm Trees and Their Applications Materials Resea
本研究的目的是确定添加不同浓度的三种天然添加剂对枣椰树cv的影响。Barhi:酪蛋白水解物1.25g/l, 2.5g/l, 5.0g/l, 10%, 20%, 30%(椰奶和酵母膏),除拔节期对照(0.05 BA mg/l)和生根期对照(0.1 NAA mg/l, 3g /l AC)外。结果表明,30%椰奶用量可获得较高的芽数,10%椰奶用量可获得最高的芽长。结果表明,在枣椰树生根期,施用30%椰奶可提高枣椰树的根数、茎粗和生根率。但添加10%椰浆后,根长增加。在这一阶段使用酵母浸膏记录了最低的数值。枣椰树(凤凰属)。在人类历史上具有重要的经济意义和农业用途。同时,它也是世界上最古老的果树之一。枣椰树在中东地区是一种非常重要的作物,因为它既可以在半干旱的沙漠地区生长,也可以在新开垦的土地上生长。阿拉伯世界的枣子产量约占世界总产量的80%。埃及是世界上最大的枣子生产国,即更多产的雌棕榈(150万吨/年)生产1694.813吨枣子[9],[7]。在埃及,枣椰树的分布覆盖了从阿斯旺到北部三角洲的大片地区,旁边是Siwa绿洲、Bahriya绿洲、Farafra绿洲、Kharga绿洲、Dakhla绿洲。埃及是世界上枣子产量最高的国家之一,埃及硕果累累的雌棕榈数量约为1500万株,枣子产量为1694.813吨[9]。枣椰树通常由地面分枝繁殖;然而,雌枣树一生中只产生10-20个分枝[20],这是制约商品品种繁殖的一个因素。一种非传统的离体培养技术被广泛应用于包括枣椰树在内的许多物种中[14]。通过离体培养生产植物已成功地应用于许多物种中[23]。枣椰树组织培养繁殖技术,又称离体繁殖技术,具有一年四季大规模繁殖、生产健康(无病虫害)的雌株或花粉优良的雄株等优点;生产基因一致的植物[19]。近年来,天然产品是利用酵母和植物提取物体外开发的。一些未定义的成分,如酵母提取物、酵母汁和水解蛋白,经常被用于营养培养基中,而不是作为进一步补充的氨基酸或维生素[4]。此外,在组织培养花卉行业中,椰奶等其他一些天然添加剂也经常被用作兰花培养培养基的热门添加物[5]。天然提取物可能是棕榈树及其应用的副产品材料研究论坛有限责任公司材料研究进展11 (2019)186-192 doi: https://doi.org/10.21741/9781644900178-13 187以6%的浓度用作蔗糖的替代品[7]在培养基中使用天然添加剂化合物代替激素可能会减少植物遗传不稳定性的可能性。有机添加剂如椰子水和酪蛋白水解物已被用于促进几种植物物种和枣椰树的胚性愈伤组织生长和体细胞胚胎发生[6]。本研究的目的是确定不同浓度的天然添加剂如椰奶、酪蛋白水解物和酵母提取物的组合,以提高枣椰树的体外cv。巴氏茎和根增生。材料和方法外植体和灭菌:实验在埃及吉萨农业研究中心枣椰树研究与开发组织培养实验室进行。枣椰树4年雌枝cv。收集Barhi作为外植体。外植体的制备是通过从枝条上去除根和外层成熟的绿色叶片,然后缩小到小于25 cm。在实验室中,从底部分枝到顶部逐渐去除剩余的成熟叶片[14]。逐渐去除白色幼叶和周围白色纤维叶鞘,形成5厘米的茎尖,进一步修剪至2厘米用于外植体。所有切除的茎尖在表面消毒前暂时保存在抗氧化溶液(150 mg/l抗坏血酸和100 mg/l柠檬酸)中。在无菌条件下,茎尖在70%乙醇溶液中浸泡30秒,然后在(1.0 g/l)氯化汞溶液中浸泡5分钟,用灭菌蒸馏水彻底清洗一次。 之后,从灭菌的外植体中去除额外的原始叶片,然后将这些外植体在50%(v/v)商业漂白剂(Clorox) 5.25% w/v,次氯酸钠NaOCl)加1滴Tween 20中消毒15分钟,旋转搅拌,用灭菌的蒸馏水冲洗三次。不同天然添加剂对发芽和生根阶段的影响:本实验采用(El-Dawayati et al .,2018)推荐的间接体细胞胚发生获得的芽团作为外植体。三种天然添加剂的不同浓度如下:(酪蛋白水解物1.25g/l, 2.5g/l, 5.0g/l,椰奶和酵母提取物10%,20%,30%),添加到标准营养生长培养基(不含天然添加剂的对照处理)中,用于拔节和生根,对照(处理)通过在相同培养基上培养相同外植体,在相同条件下不添加任何添加剂,研究其在拔节和生根阶段对芽发育的影响。所有精制工艺均在无菌条件下完成。拔节期标准培养基配制为3 / 4 MS含维生素的Murashige和Skoog基础营养培养基[16,22],添加100 mg/l肌醇;80硫酸腺嘌呤;170 mg/l NaH2PO4.2H2O;0.3 mg /l Ca泛硫酸;0.4 mg/l硫胺hcl;2甘氨酸;烟酸0.5 mg/l;0.5 mg/l吡哆毒素hcl;100肌醇;30 g / l蔗糖;0.05 mg/l (BA)和0.1 NAA mg/l生长调节剂和6 g/l琼脂;7000[琼脂/胶琼脂](Sigma Chem.)Co., St. Louis, MO)(英文版)[1]。生根期标准培养基制备生根期标准培养基制备生根期标准培养基制备生根期标准培养基制备生根期标准培养基制备生根期标准培养基制备生根期标准培养基制备生根期标准培养基制备生根期标准培养基制备生根期标准培养基制备生根培养基制备生根期标准培养基制备生根培养基制备生根培养基。和。0.3 mg /l Ca泛硫酸;0.4 mg/l硫胺hcl;2甘氨酸;烟酸0.5 mg/l;0.5 mg/l吡哆毒素hcl;100肌醇;200谷氨酰胺;1 g;30000蔗糖;6000琼脂。材料研究论坛有限责任公司材料研究进展11 (2019)186-192 doi: https://doi.org/10.21741/9781644900178-13 188在加入琼脂gerlite并在1.2 Kg高压消毒培养基之前,将pH值调整为5.7。取25 ml的营养培养基分装于小瓶中,用于拍摄阶段。试管大小(25 × 250 mm),每个试管含25 ml,用于生根期。将各处理和对照处理的外植体转移到相同成分的新鲜培养基中,每8周重复培养2次。[10]。所有样品在萌发期1500勒克斯光照条件和生根期3000勒克斯光照条件下培养16 h。然后在27±2°C的黑暗条件下进行8小时的芽增殖阶段。对照样品进行2次传代培养,天然添加剂3种不同浓度进行3次传代培养[4]。所有程序都在净化的水平层流罩中进行。试验设计完全随机化,每个处理3个重复。首先采用上述统计设计对10个处理记录的数据进行整体分析,然后将数据分组如下[14]:表1,酪蛋白水解物(1.25、2.5、5.0 mg.L)和椰奶、酵母提取物(10%、20%、30%)三种不同浓度的天然添加剂5ba毫克。L(拍摄阶段)。T2控制0。1naa毫克。L +3AC g.L(生根期)。T3酪蛋白水解物1.25 mg.L。T4酪蛋白水解物2.5 mg.L。T5酪蛋白水解物5mg。L T6椰奶10%。T7椰奶20%。T8椰奶30%。T9酵母膏1.25 mg.L。T10酵母提取物2.5 mg.L。T11酵母提取物5毫克。L采梢数据通过估算梢数、每簇茎长(cm)、每簇茎粗(cm)、成根数(生根%)和每簇根长(cm)计算。统计分析:采用完全随机安排的析因设
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引用次数: 2
Rediscovering Date Palm by-products: an Opportunity for Sustainable Development 重新发现椰枣副产品:可持续发展的机遇
Pub Date : 2019-01-01 DOI: 10.21741/9781644900178-1
H. El-Mously
The date palm was the pivot of cultural, social and economic life for long centuries in rural areas in the Arab region. The basic needs of millions of people in rural areas were being satisfied relying on the by-products of date palms. With the drastic change of the style of life most of these byproducts became redundant leading to the neglect of pruning of date palms, and thus becoming a direct cause of fire accidents and infestation by dangerous insects. This situation represents a real challenge to those concerned with development. How to compose a new vision to palm by-products transcending the traditional forms of utilization of these by-products being treated as waste? The path of rediscovery of these by-products is paramount. How to develop new forms of utilization of palm by-products to satisfy modern demands on the local, national and international levels? An approach has been suggested for the industrial utilization of date palm by-products. The research conducted at the premises of the Faculty of Engineering, Ain Shams University has proven that the date palm midribs enjoy mechanical properties similar to those for imported wood species. It was also proven that the date palm midrib can be used as a core layer for the manufacture of blockboards competing with those manufactured from wood. Lumber-like blocks have been successfully made from palm midribs. The palm midribs were successfully used for the production of Mashrabiah (Arabesque) products as a substitute for beech wood. Particleboards and MDF boards satisfying the international standards have been also manufactured from palm midribs. Poultry and livestock feed, as well as compost have been produced using the date palm midribs. Space trusses and claddings have been successfully made from palm midribs. New machines have been successfully designed and manufactured for the conversion of palm midribs into strips of regular cross-section. There are wide future prospects for the use of date palm by-products us a substitute for wood, for paper manufacture and for the reinforcement of polymers. Within the framework of bioeconomy there are high potentialities for the use of the date waste, as well as the ligne-cellulosic by-products in a wide spectrum of bioindustries. To guarantee the continuation of endeavors to support the use of palm by-products on the international level it is necessary to establish The International Association For Palm ByProducts as a forum for all parties interested and involved in the use of palm by-products. Introduction The palm plantations were the pivot of cultural, social, and economic life for long centuries in rural areas in the South: in Latin America, Africa, and Asia. The basic needs of millions of people in rural areas were being satisfied relying on the by-products of palms (PBP). The way of life in these vast areas was woven using these available indigenous sustainable secondary products of palms. Via this process very rich technical heritage blossome
几个世纪以来,枣椰树一直是阿拉伯地区农村地区文化、社会和经济生活的中心。农村地区数百万人的基本需要依靠椰枣的副产品得到满足。随着生活方式的急剧变化,这些副产品中的大多数变得多余,导致修剪椰枣的工作被忽视,从而成为火灾事故和危险昆虫侵扰的直接原因。这种情况对关心发展的人是一个真正的挑战。如何超越传统的将棕榈副产品作为废物的利用方式,构建棕榈副产品的新愿景?重新发现这些副产品的途径是至关重要的。如何开发新的棕榈副产品利用形式,以满足地方、国家和国际层面的现代需求?提出了枣椰树副产品工业利用的途径。在艾因沙姆斯大学工程学院进行的研究证明,枣椰树的中脉具有与进口木材相似的机械性能。还证明,枣椰树中脉可以用作制造细木工板的核心层,与木材制造的细木工板竞争。像木材一样的积木已经成功地用棕榈的中脉制成。棕榈中肋被成功地用于生产Mashrabiah (Arabesque)产品,作为山毛榉木的替代品。还生产了符合国际标准的刨花板和中密度纤维板。家禽和牲畜饲料以及堆肥都是用枣椰树的中脉生产的。空间桁架和包层已经成功地由棕榈中脉制成。已成功地设计和制造了将棕榈中筋转化为规则截面条的新机器。利用枣椰树副产品作为木材的替代品、造纸和增强聚合物具有广阔的前景。在生物经济的框架内,在广泛的生物工业中利用椰枣废料以及木质纤维素副产品具有很高的潜力。为了保证在国际层面上继续努力支持棕榈副产品的使用,有必要建立国际棕榈副产品协会,作为所有对棕榈副产品使用感兴趣和参与的各方的论坛。几个世纪以来,棕榈种植园一直是拉丁美洲、非洲和亚洲南部农村地区文化、社会和经济生活的中心。农村地区数百万人的基本需要依靠棕榈树的副产品得到满足。这些广阔地区的生活方式是利用这些可获得的本地可持续棕榈次级产品编织而成的。通过这一过程,非常丰富的技术遗产开花,主要是棕榈树及其应用的副产品材料研究论坛有限责任公司材料研究学报11 (2019)3-61 doi: https://doi.org/10.21741/9781644900178-1 4农村地区当地社区穷人的财产。从普遍的自给经济向资本主义生产方式的转变和经济作物意识形态的主导地位,加上西方生活方式的传播,导致了对PBP的忽视和相关技术遗产的冻结。因此,南方许多国家的农村人口从当地社区发展的生产者和积极参与者变成了可以从城市或国外购买的任何东西的单纯消费者。这种情况对关心发展的人是一个真正的挑战。如何构建PBP的新愿景,超越传统的PBP利用形式,并设想新的现代途径来利用这些目前被视为废物的几乎无价的可再生材料?在这种情况下,重新发现PBP的途径是至关重要的。如何开发新的PBP利用形式,以满足地方、国家和国际层面的现代需求?采用一种参与式的方法,这种思想趋势可能会引发一波创新浪潮:从农村地区开始,到达城市地区。PBP的经济利用将在地方一级提供劳动力机会,吸引青年作为创新者和企业家回到村庄,并将村庄从单纯依赖农业活动(受农产品价格波动的影响)转变为包括农业、工业和贸易以外的广泛经济活动。因此,PBP的经济利用将为棕榈种植园退出的当地社区带来活力,并为可持续发展提供适当的条件。 椰子被用来制作洗涤和沐浴海绵,以及用于
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引用次数: 5
Investigations on the Effects of Cement Replacement and Calcium Chloride Addition on Selected Properties of Coconut Husk Fibre-Reinforced Roofing Tiles 水泥替代和氯化钙添加对椰壳纤维增强屋面瓦性能影响的研究
Pub Date : 2019-01-01 DOI: 10.21741/9781644900178-21
A. Adeniji, A. Olorunnisola
Provision of adequate and affordable housing is one of the continuing challenges posed by unprecedented urbanization in Nigeria and many other African countries. One of the solutions to this chronic problem is the development of non-conventional low cost building materials from recyclable agro-industrial wastes. This study was conducted to investigate the effects of CaCl2 addition and partial replacement of cement with Rice Husk Ash (RHA) and calcium carbide waste (lime) on the density, water resistance and impact strength of cementbonded composite roofing tiles reinforced with coconut husk (Cocos nucifera) fibres. Results indicated that CaCl2 enhanced impact strength and dimensional stability of the composite samples, while RHA and lime lowered the impact strength of the roofing tiles. Introduction The need to improve housing supply in developing countries is great. So also are the needs to manage agro-industrial wastes in a sustainable manner and reduce the use of cement in building construction. Accumulation of unmanaged wastes results in environmental pollution. Recycling of such wastes, particularly agro-industrial wastes, as sustainable building construction materials appears to be viable solution not only to pollution problems but also to the problem of economic design of buildings. The major types of roofing materials available in Nigeria are corrugated iron and aluminum sheets, slates and asbestos sheets. While corrugated iron sheets are prone to rusting and can be noisy when it is raining, asbestos roofing sheets are relatively expensive and have been outlawed in many countries due to the carcinogenic nature of asbestos fibres. Cement-bonded composites (CBCs) represent an important class of engineered construction materials in which some agroindustrial wastes could be used as partial replacement of cement, while others could serve as fibre reinforcement. Fibrous materials suitable for cement-bonded composite roofing and ceiling tile production in Nigeria include bamboo (Bambusa vulgaris), rattan cane, sugar cane bagasse (Saccharum officinarum), raffia palm (Raphia africana), luffa (luffa cylindrica), Cissus populnea, and coconut husk (Cocos nucifera Linn) among others [1-6]. There are about three million coconut palm trees producing approximately 70 million coconuts annually in Nigeria [7]. The average mature coconut weighs 680 g about 42% of which is made up of the husk [8]. The husk fibres, largely treated as waste, are a candidate material for CBC reinforcement. Potential agro-industrial waste products for partial replacement of cement in the country include welder’s used carbide waste (lime) derived from ethyne (C2H2) gas, by the action of cold water on calcium carbide and plant ashes that have relatively high silica content and are therefore suitable as a pozzolana, including, RHA. It is generally believed that calcium By-Products of Palm Trees and Their Applications Materials Research Forum LLC Materials Research Proceedings 11 (2
提供足够和负担得起的住房是尼日利亚和许多其他非洲国家前所未有的城市化所带来的持续挑战之一。解决这一长期问题的方法之一是从可回收的农业工业废料中开发非常规的低成本建筑材料。本研究研究了CaCl2的添加和稻壳灰(RHA)和电石废料(石灰)部分替代水泥对椰壳纤维增强水泥粘结复合屋面瓦的密度、耐水性和冲击强度的影响。结果表明,CaCl2提高了复合材料的冲击强度和尺寸稳定性,而RHA和石灰降低了复合材料瓦的冲击强度。发展中国家非常需要改善住房供应。以可持续的方式管理农业-工业废物和减少建筑施工中水泥的使用的需要也是如此。未经管理的废物积累造成环境污染。回收这些废物,特别是农工废物,作为可持续的建筑材料,似乎不仅是解决污染问题的可行办法,也是解决建筑物经济设计问题的可行办法。尼日利亚可用的主要屋顶材料类型是波纹铁和铝板、石板和石棉板。虽然波纹铁皮容易生锈,下雨时可能会发出噪音,但石棉屋面板相对昂贵,由于石棉纤维的致癌性质,在许多国家已被禁止使用。水泥粘合复合材料是一类重要的工程建筑材料,其中一些农工废料可部分替代水泥,而另一些则可作为纤维增强材料。适用于尼日利亚水泥结合复合屋面和天花瓦生产的纤维材料包括竹子(Bambusa vulgaris)、藤条、甘蔗渣(Saccharum officinarum)、油棕(Raphia africana)、丝瓜(luffa ica)、西葫芦(Cissus populnea)和椰子皮(Cocos nucifera Linn)等[1-6]。尼日利亚大约有300万棵椰子树,每年生产约7000万个椰子[7]。成熟的椰子平均重680克,其中约42%是由外壳组成的[8]。稻壳纤维,大部分作为废物处理,是CBC加固的候选材料。该国部分替代水泥的潜在农业工业废物包括电焊工用过的碳化石废物(石灰),这些废物是由乙烷(C2H2)气体通过冷水对电石和植物灰烬的作用产生的,它们具有相对较高的二氧化硅含量,因此适合作为火山灰,包括RHA。一般认为棕榈树及其应用的钙副产品Materials Research Forum LLC Materials Research Proceedings 11 (2019) 253-259 doi: https://doi.org/10.21741/9781644900178-21 254碳化物渣富含氢氧化钙,表现为水合石灰。因此,它也被推荐为混凝土工程中部分替代水泥的潜在材料[9]。本研究的目的是评价CaCl2的添加和水泥的部分替代对椰子壳纤维增强复合屋面瓦的选定性能的影响。将椰子纤维从外壳中取出,分离成单链,切成25毫米。稻壳被风干5天,在700摄氏度的温度下烧焦并焚烧成白色灰烬。从机械车间获得的焊工用过的硬质合金废料(石灰)进行了风干、粉碎和筛分。将纤维(2%)与波特兰水泥、河砂、水和着色材料(氧化铁)混合,使用预先确定的水灰比(对照)。对于第一组实验样品,CaCl2分别以2,3和4%的水平添加。氧化铁以2%的速率加入。对于第二组和第三组,分别用5%、10%和15%的RHA和石灰代替部分水泥。所有的百分比都是基于水泥的质量。用每种混合物制作600 (L) x 300 (B) x 6 (T) mm瓦楞屋面瓦的三份样品,在50 Hz下振动60秒,固化28天。使用先前报道的标准方法对样品进行含水率、密度、冲击能、吸水率和厚度膨胀测试[10,11]。方差分析在5%显著性水平上进行。所生产的红色椰壳纤维增强复合屋面瓦样品的密度和含水率如图1所示。在可接受的水分含量范围为2.5 - 5.5%(干基)时,平均密度范围为1.3 - 1.6 g/cm。 然而,方差分析(表2)显示,加入CaCl2和用RHA和石灰部分替代水泥对密度都没有显著影响,尽管部分替代水泥的样品密度普遍较低,这与以往类似研究的结果一致[10,11]。这表明水泥可以部分替代,以减轻复合屋面瓦的重量。图1所示。椰壳纤维增强屋面瓦样品。材料研究论坛有限责任公司材料研究学报11 (2019)253-259 doi: https://doi.org/10.21741/9781644900178-21 255表1:复合材料的水分含量和密度。样品成分平均含水率(%)平均密度(克/厘米)归一化密度5% RHA 3.8 1.5 0.94 10% RHA RHA 15% 3.4 1.3 0.81 3.7 1.4 0.87 5%石灰4.1 1.5 0.94 10%石灰石灰4.0 1.4 0.87 4.3 1.6 1.0 15%氯化钙2%氯化钙3% 4.9 1.6 1.0 2.5 1.7 1.1 4%氯化钙控制3.0 1.4 0.87 5.5 1.6 1.0的平均标本密度除以平均密度控制标本表2:方差分析的部分替代水泥密度的影响。变异源SS df MS F值F临界值组间0.230427 6 0.038405 2.451591 0.078271 2.847726组内0.219312 14 0.015665
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引用次数: 0
Production of Biochar from Date Palm Fronds and its Effects on Soil Properties 枣椰叶生产生物炭及其对土壤性质的影响
Pub Date : 2019-01-01 DOI: 10.21741/9781644900178-11
M. Badawi
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引用次数: 8
Adsorption of Methylene Blue onto Chemically Prepared Activated Carbon from Date Palm Pits: Kinetics and Thermodynamics 化学制备的枣椰核活性炭对亚甲基蓝的吸附:动力学和热力学
Pub Date : 2019-01-01 DOI: 10.21741/9781644900178-23
H. El-Didamony, A. Youssef, M. Sobhy, S. Sharabasy
Three activated carbons were prepared using phosphoric acid (P) as an activating agent from date palm pits (DPP) as a precursor via thermal pretreatment producing (CP212, CP214 and CP124) samples, where the ratio of raw material to phosphoric acid is (2:1and 1:2) respectively at curing time two days for first sample and four days for the second and third sample, the activating temperature was 550°C, the precursor was washed with distilled water, dried, crushed, and then sieved. In order to study the effect of phosphoric acid modification, the characteristics of the activated carbon produced were determined before and after acid modification and subsequently compared. These characteristics include surface morphology, surface area, average pore diameter and pore volume. Characterization results showed that modification of date palm pits with phosphoric acid enhanced the surface area of the activated carbon from 427.8 to620.3 m/g. The average pore diameter was also enhanced from 1.14 to 1.82 nm. SEM analysis confirmed the improvement in surface area and pore development resulting from the phosphoric acid modification. Introduction MB is synthetic thiazine dye of an amorphous nature with a molecular formula C16H18ClN3S.xH2O. It is also called basic blue, tetra methylthionine chloride and colour index (Cl) number 52012. The molecular weight of MB is 320 and its maximum wave length 662nm. It is dark green powder, with a characteristic deep blue colour in aqueous solution where it dissociates into an MB cation and a chloride anion dye, Methylene blue is a common dye mostly used by industries involve in textile, rubber, paper, plastics, leather, pharmaceutical cosmetics, and food industries. Effluents discharged from such industries contain residues of dyes. Consequently, the presence of very low concentrations in effluent is highly visible [1, 2]. Discharge of colored waste water without proper treatment can results in numerous problems such as chemical oxygen demand (COD) by the water body, and an increase in toxicity. Organic dyes are harmful to human beings the need to remove color from waste water become environmentally important. It is rather difficult to treat dye effluents because of their synthetic origins and mainly aromatic structures, which are biologically non-degradable. Moreover, their degradation products may be mutagenic and carcinogenic [3,4]. Many dyes may cause allergic dermatitis, skin irritation, and dyes function of kidney, liver, and brain, reproductive and central nervous system [5]. It is estimated that 10–15%of the dyes are lost in the effluent during the dyeing processes. Activated carbon has been extensively used in wastewater treatment, chemical By-Products of Palm Trees and Their Applications Materials Research Forum LLC Materials Research Proceedings 11 (2019) 275-285 doi: https://doi.org/10.21741/9781644900178-23 276 recovery and catalytic support industries primarily due to large surface area and presence of different po
以枣椰核(DPP)为前驱体,以磷酸(P)为活化剂,经热预处理制得三种活性炭(CP212、CP214和CP124)样品,其中原料与磷酸的比例分别为2:1和1:2,固化时间为第一个样品2天,第二个和第三个样品4天,活化温度为550℃,前驱体用蒸馏水洗涤、干燥、粉碎、过筛。为了研究磷酸改性的效果,测定了酸改性前后生产的活性炭的特性,并进行了比较。这些特征包括表面形貌、表面积、平均孔径和孔隙体积。表征结果表明,磷酸对枣椰核进行改性后,活性炭的比表面积由427.8 m/g提高到620.3 m/g。平均孔径由1.14 nm增加到1.82 nm。扫描电镜分析证实了磷酸修饰导致的比表面积和孔隙发育的改善。MB是一种非晶态合成噻嗪染料,分子式为C16H18ClN3S.xH2O。它也被称为碱性蓝,四甲基硫氨酸氯,颜色指数(Cl)为52012。MB的分子量为320,最大波长为662nm。亚甲基蓝是一种常见的染料,主要用于纺织、橡胶、造纸、塑料、皮革、制药、化妆品和食品工业等行业。这些工业排放的废水含有染料残留物。因此,废水中极低浓度的存在是非常明显的[1,2]。有色废水的排放未经适当处理会导致水体的化学需氧量(COD)和毒性增加等诸多问题。有机染料对人体有害,废水脱色成为环境保护的重要问题。染料废水的处理相当困难,因为它们的合成来源和主要芳香结构是生物不可降解的。此外,它们的降解产物可能具有诱变和致癌作用[3,4]。许多染料可能引起过敏性皮炎、皮肤刺激,并染色肾、肝、脑、生殖和中枢神经系统的功能。据估计,在染色过程中,10 - 15%的染料在废水中丢失。活性炭已广泛应用于废水处理、棕榈树的化学副产品及其应用材料研究论坛有限责任公司材料研究进展11 (2019)275-285 doi: https://doi.org/10.21741/9781644900178-23 276回收和催化支持行业,主要是由于大表面积和不同孔径的存在[6]。在大多数报道的情况下,化学活化是首选的,因为它可以获得更好的多孔性,更大的表面积和高产量的活性炭。枣椰树核被认为是最有用的和丰富的可再生农业废弃物之一,2006年世界枣椰树的产量约为700万吨。大约14%的果实是种子形式的废料。枣核约占枣重量的10%。枣核的化学成分由半纤维素(23%)、木质素(15%)和纤维素(57%)组成。人类不得以任何形式食用枣椰核;它含有高含量的粗纤维(约19%),也可能引起反刍动物的消化问题。本研究的主要目的是利用枣椰核制备磷酸(H3PO4)活性炭。采用以下方法对制备的活性炭进行表征:-196℃下的氮气吸附,扫描电镜分析表面化学,pHpzc,表面pH分析,不同温度下MB吸附量的测定。特别注意动力学研究。材料与方法本研究所用的主要化学试剂均为分析级化学试剂。纯度为99.99%的亚甲基蓝由Sigma-Aldrich公司和磷酸制得。在整个实验过程中,使用蒸馏水制备溶液和清洗玻璃器皿。2.活性炭的制备在我们的研究中,我们使用(沙枣棕榈核),材料来自(Shubra Al Khaimah)的糕点厂。用热去离子水清洗枣椰核,去除灰尘和其他杂质,并在105℃下干燥。将原料磨成细颗粒,筛分至(2mm)粒度。用50 wt浸泡椰枣核制备磷酸活性炭样品。 可以说,活化剂具有分解灰分的能力;水分含量是棕榈树的副产品之一
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引用次数: 2
Evaluation of Palm Fiber Components as Alternative Biomass Wastes for Medium Density Fiberboard Manufacturing 棕榈纤维组分作为替代生物质废弃物用于中密度纤维板制造的评价
Pub Date : 2019-01-01 DOI: 10.21741/9781644900178-7
A. Basta, A. Abdel-Baset, H. El-saied
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引用次数: 0
期刊
By-Products of Palm Trees and Their Applications
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