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Lumped Parameter Analysis of Bridge Wire in an Electro Explosive Device of a Power Cartridge for Water-Jet Application: A Case Study 水射流装药筒电爆装置桥丝的集中参数分析——一个实例
IF 0.8 4区 工程技术 Q3 Materials Science Pub Date : 2020-09-28 DOI: 10.22211/CEJEM/127814
B. Parate, S. Chandel, H. Shekhar
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引用次数: 5
Synthesis and Characterization of New Energetic Plasticizers: Benzoyl-terminated Poly(epichlorohydrin) Modified by Phenylhydrazine and its Derivatives 新型高能增塑剂苯肼及其衍生物改性苯甲酰封端聚环氧氯丙烷的合成与表征
IF 0.8 4区 工程技术 Q3 Materials Science Pub Date : 2020-09-28 DOI: 10.22211/CEJEM/127514
Fariborz Atabaki, Naser Noorollahy Bastam, H. R. Hafizi-Atabak, Mehran Radvar, Shahrzad Jahangiri
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引用次数: 0
Study of Ammonium Perchlorate-based Molecular Perovskite (H2DABCO)[NH4(ClO4)3]/Graphene Energetic Composite with Insensitive Performance 高氯酸铵基分子钙钛矿[NH4(ClO4)3]/石墨烯含能钝感复合材料的研究
IF 0.8 4区 工程技术 Q3 Materials Science Pub Date : 2020-09-28 DOI: 10.22211/CEJEM/127934
Yang Liu, Lishuang Hu, Shida Gong, Chunyu Guang, Lianqiang Li, Shuang-qi Hu, Peng Deng
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引用次数: 11
A Simple Approach for Predicting the Density of High Nitrogen Organic Compounds as Materials for Providing Clean Products and Enormous Energy Release 一种简单的预测高氮有机化合物密度的方法作为提供清洁产品和巨大能量释放的材料
IF 0.8 4区 工程技术 Q3 Materials Science Pub Date : 2020-06-26 DOI: 10.22211/cejem/124210
M. Keshavarz, R. Ebadpour, M. Jafari
: High nitrogen organic compounds (N>50 wt.%) are important for chemical industries because they can provide clean products with generally low-molecular weight product gases and enormous energy release. The density of these materials at or near room temperature is an important physical property for the assessment of their detonation and combustion performances. A novel method is introduced here for the prediction of the density of various classes of organic compounds, including different derivatives of triazole, tetrazole, triazine, tetrazine, furazan, and some organic nitrogen-containing chains. The core model is based on elemental composition, where its reliability has been improved by considering some molecular fragments including specific functional groups. The high reliability of these simple model has been compared with the output from two complex quantum mechanical approaches. For 91 high nitrogen compounds, the values of the standard deviation ( SD ) of the core and improved correlations were 0.076 and 0.047 g·cm –3 . For a further 32 materials, the values of SD were 0.057 and 0.042 g·cm –3 for the core and improved correlations, respectively. These data are close to core and improved quantum mechanical methods, i.e. 0.056 and 0.042 g·cm –3 , respectively, where the calculated data from complex quantum mechanical approaches were available. organic compounds, molecular structure, clean enormous energy release
:高氮有机化合物(N>50wt.%)对化学工业很重要,因为它们可以提供具有通常低分子量产物气体和巨大能量释放的清洁产品。这些材料在室温或接近室温时的密度是评估其爆震和燃烧性能的重要物理性质。本文介绍了一种预测各类有机化合物密度的新方法,包括三唑、四唑、三嗪、四嗪、呋咱和一些有机含氮链的不同衍生物。核心模型基于元素组成,通过考虑包括特定官能团的一些分子片段,提高了其可靠性。将这些简单模型的高可靠性与两种复杂量子力学方法的输出进行了比较。对于91种高氮化合物,核心的标准偏差(SD)值和改进的相关性分别为0.076和0.047 g·cm–3。对于另外32种材料,核心的SD值分别为0.057和0.042 g·cm–3,并改善了相关性。这些数据接近核心和改进的量子力学方法,即分别为0.056和0.042 g·cm–3,其中可以获得复杂量子力学方法的计算数据。有机化合物,分子结构,清洁巨大的能量释放
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引用次数: 4
Persistance of TNT Traces in the Presence of Compounds from Battery Cells 在电池中存在化合物的情况下,TNT痕量的持久性
IF 0.8 4区 工程技术 Q3 Materials Science Pub Date : 2020-06-26 DOI: 10.22211/cejem/124072
Wojciech Pawłowski, M. Karpińska, Katarzyna Razarenkow-Pawłowska
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引用次数: 0
N-N Bond Lengths and Initiation Reactivity of Nitramines 硝胺的N-N键长与引发反应性
IF 0.8 4区 工程技术 Q3 Materials Science Pub Date : 2020-06-25 DOI: 10.22211/cejem/122723
S. Zeman, T. Atalar, A. Růžička
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引用次数: 9
Study on the Thermal Stability and Decomposition Kinetics of Polypropylene Glycol - Glycidyl Azide Polymer - Polypropylene Glycol (PPG-GAP-PPG) as a Novel Triblock Copolymer Binder 新型三嵌段共聚物粘结剂丙二醇-叠氮缩水甘油酯聚合物-丙二醇(PPG-GAP-PPG)的热稳定性及分解动力学研究
IF 0.8 4区 工程技术 Q3 Materials Science Pub Date : 2020-06-25 DOI: 10.22211/cejem/124073
Fahimeh Ghoroghchian, Y. Bayat, F. Abrishami
In this study, the novel energetic triblock copolymer of polypropylene glycolglycidyl azide polymerpolypropylene glycol (PPG-GAP-PPG) (Mn = 1419 g·mol–1) was synthesized by cationic ring-opening polymerization of propylene oxide using low molecular weight glycidyl azide polymer (GAP) (Mn = 1006 g·mol–1) as the initiator and boron trifluoride etherate (BF3·OEt2) as the catalyst. The synthesized GAP and triblock copolymer were characterized by Fourier-transform infrared (FT-IR) spectroscopy, gel permeation chromatography (GPC), and nuclear magnetic resonance spectroscopy (1H and 13C NMR). The thermal stability of the triblock copolymer PPG-GAP-PPG was studied by differential scanning calorimetry (DSC) and thermogravimetry (TG). The DSC results showed that the glass transition temperature (Tg) of the triblock copolymer (Tg = −63 °C) was lower than that of neat low molecular weight GAP (Tg = −53 °C). Furthermore, the results indicated that this triblock copolymer is more stable than GAP. The influence of heating rate (10, 20, 30 and 40 °C·min−1) illustrated that increasing the heating rate results in an increase in the triblock copolymer’s decomposition temperature. Non-isothermal methods, proposed by ASTM E698, Flynn-Wall-Ozawa (FWO) and Kissinger, were used to calculate the kinetic parameters, such as activation energy and frequenc factor, for the thermal decomposition of the triblock copolymer PPG-GAP-PPG, using the DSC-DTG Central European Journal of Energetic Materials ISSN 1733-7178; e-ISSN 2353-1843 Copyright © 2020 Łukasiewicz Research Network – Institute of Industrial Organic Chemistry, Poland 263 Study on the Thermal Stability and Decomposition Kinetics... Copyright © 2020 Łukasiewicz Research Network – Institute of Industrial Organic Chemistry, Poland data. The activation energies calculated by the FWO and ASTM E698 methods were 124.610 and 126.13 kJ·mol–1, respectively.
本研究以低分子量叠氮缩水甘油酯聚合物(GAP)(Mn=1006 g·mol–1)为引发剂,三氟化硼醚化物(BF3·OEt2)为催化剂,通过环氧丙烷的阳离子开环聚合,合成了聚丙烯-乙醇-叠氮缩水缩水甘油酯-聚丙二醇的新型高能三嵌段共聚物(PPG-GAP-PPG)(Mn=1419 g·mol-1)。通过傅立叶变换红外光谱(FT-IR)、凝胶渗透色谱(GPC)和核磁共振波谱(1H和13C NMR)对合成的GAP和三嵌段共聚物进行了表征。采用差示扫描量热法(DSC)和热重分析法(TG)研究了三嵌段共聚物PPG-GAP-PPG的热稳定性。DSC结果表明,三嵌段共聚物的玻璃化转变温度(Tg=−63°C)低于纯低分子量GAP的玻璃化转化温度(Tg=−53°C)。此外,结果表明,该三嵌段共聚物比GAP更稳定。加热速率(10、20、30和40°C·min−1)的影响表明,增加加热速率会导致三嵌段共聚物的分解温度升高。使用ASTM E698、Flynn Wall Ozawa(FWO)和Kissinger提出的非等温方法,使用DSC-DTG《中欧高能材料杂志》ISSN 1733-7178,计算了三嵌段共聚物PPG-GAP-PPG热分解的动力学参数,如活化能和频率因子;e-ISSN 2353-1843版权所有©2020Łukasiewicz研究网络-波兰工业有机化学研究所263热稳定性和分解动力学研究。。。版权所有©2020Łukasiewicz研究网络-波兰工业有机化学研究所数据。FWO和ASTM E698方法计算的活化能分别为124.610和126.13 kJ·mol–1。
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引用次数: 3
Numerical Modelling of Detonation Reaction Zone of Nitromethane by EXPLO5 Code and Wood and Kirkwood Theory 用EXPLO5程序和Wood和Kirkwood理论对硝基甲烷爆轰反应区的数值模拟
IF 0.8 4区 工程技术 Q3 Materials Science Pub Date : 2020-06-25 DOI: 10.22211/cejem/124193
B. Štimac, H. Y. Chan, M. Künzel, M. Sućeska
The detonation reaction zone of nitromethane (NM) has been extensively studied both experimentally and theoretically. The measured particle velocity
硝基甲烷的爆轰反应区在实验和理论上都得到了广泛的研究。测得的粒子速度
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引用次数: 4
Thermochemical Properties, Ballistic Parameters and Sensitivity of New RDX-based Propellants 新型RDX基推进剂的热化学性质、弹道参数和灵敏度
IF 0.8 4区 工程技术 Q3 Materials Science Pub Date : 2020-06-25 DOI: 10.22211/cejem/122326
M. Hara, W. Trzciński, S. Cudziło, M. Szala, Z. Chyłek, Z. Surma
New RDX-based propellants were obtained and investigated. The heat of combustion was determined in a calorimeter and the pressure history was measured in a manometric bomb. Ballistic parameters, such as maximum pressure, propellant force and covolume of gaseous products, as well as the dynamic vivacity, were determined based on the experimental results. The sensitivities to friction and impact were determined for the tested propellants. Calculations of the ballistic characteristics (the heat of combustion, propellant force, covolume and ratio of specific heats of the combustion products, and ballistic energy) were performed. The theoretical parameters were compared with the experimental data and quite good agreement was found between them. The largest differences occurred in the cases of propellant force and covolume. This disagreement is explained. An analysis of the test results and a comparison of the parameters of the RDX-based propellants and the JA2 propellant allowed the possibility of using the tested propellants in ammunition to be assessed.
获得并研究了新型RDX基推进剂。燃烧热在量热计中测定,压力历史在测压弹中测量。根据实验结果确定了弹道参数,如最大压力、推进剂力、气体产物体积以及动态寿命。测定了试验推进剂对摩擦和冲击的敏感性。对弹道特性(燃烧热、推进剂力、燃烧产物的体积和比热比以及弹道能量)进行了计算。将理论参数与实验数据进行了比较,发现它们之间有很好的一致性。最大的差异出现在推进剂力和体积的情况下。这一分歧已得到解释。通过对测试结果的分析以及对RDX基推进剂和JA2推进剂参数的比较,可以评估在弹药中使用测试推进剂的可能性。
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引用次数: 1
Experimental Investigation of the Effect of Polymers and Crystalline Qualities on the Safety Performance of LLM-105-based PBXs under Dynamic Compression and Shear 聚合物和结晶质量对LLM-105基PBX在动态压缩和剪切下安全性能影响的实验研究
IF 0.8 4区 工程技术 Q3 Materials Science Pub Date : 2020-06-25 DOI: 10.22211/cejem/124173
Xiao-gan Dai, Songwei He, Xiaona Huang, Zhijian Yang, Yushi Wen, Ming Li
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引用次数: 2
期刊
Central European Journal of Energetic Materials
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