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Persistance of TNT Traces in the Presence of Compounds from Battery Cells 在电池中存在化合物的情况下,TNT痕量的持久性
IF 0.8 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2020-06-26 DOI: 10.22211/cejem/124072
Wojciech Pawłowski, M. Karpińska, Katarzyna Razarenkow-Pawłowska
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引用次数: 0
N-N Bond Lengths and Initiation Reactivity of Nitramines 硝胺的N-N键长与引发反应性
IF 0.8 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2020-06-25 DOI: 10.22211/cejem/122723
S. Zeman, T. Atalar, A. Růžička
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引用次数: 9
Study on the Thermal Stability and Decomposition Kinetics of Polypropylene Glycol - Glycidyl Azide Polymer - Polypropylene Glycol (PPG-GAP-PPG) as a Novel Triblock Copolymer Binder 新型三嵌段共聚物粘结剂丙二醇-叠氮缩水甘油酯聚合物-丙二醇(PPG-GAP-PPG)的热稳定性及分解动力学研究
IF 0.8 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2020-06-25 DOI: 10.22211/cejem/124073
Fahimeh Ghoroghchian, Y. Bayat, F. Abrishami
In this study, the novel energetic triblock copolymer of polypropylene glycolglycidyl azide polymerpolypropylene glycol (PPG-GAP-PPG) (Mn = 1419 g·mol–1) was synthesized by cationic ring-opening polymerization of propylene oxide using low molecular weight glycidyl azide polymer (GAP) (Mn = 1006 g·mol–1) as the initiator and boron trifluoride etherate (BF3·OEt2) as the catalyst. The synthesized GAP and triblock copolymer were characterized by Fourier-transform infrared (FT-IR) spectroscopy, gel permeation chromatography (GPC), and nuclear magnetic resonance spectroscopy (1H and 13C NMR). The thermal stability of the triblock copolymer PPG-GAP-PPG was studied by differential scanning calorimetry (DSC) and thermogravimetry (TG). The DSC results showed that the glass transition temperature (Tg) of the triblock copolymer (Tg = −63 °C) was lower than that of neat low molecular weight GAP (Tg = −53 °C). Furthermore, the results indicated that this triblock copolymer is more stable than GAP. The influence of heating rate (10, 20, 30 and 40 °C·min−1) illustrated that increasing the heating rate results in an increase in the triblock copolymer’s decomposition temperature. Non-isothermal methods, proposed by ASTM E698, Flynn-Wall-Ozawa (FWO) and Kissinger, were used to calculate the kinetic parameters, such as activation energy and frequenc factor, for the thermal decomposition of the triblock copolymer PPG-GAP-PPG, using the DSC-DTG Central European Journal of Energetic Materials ISSN 1733-7178; e-ISSN 2353-1843 Copyright © 2020 Łukasiewicz Research Network – Institute of Industrial Organic Chemistry, Poland 263 Study on the Thermal Stability and Decomposition Kinetics... Copyright © 2020 Łukasiewicz Research Network – Institute of Industrial Organic Chemistry, Poland data. The activation energies calculated by the FWO and ASTM E698 methods were 124.610 and 126.13 kJ·mol–1, respectively.
本研究以低分子量叠氮缩水甘油酯聚合物(GAP)(Mn=1006 g·mol–1)为引发剂,三氟化硼醚化物(BF3·OEt2)为催化剂,通过环氧丙烷的阳离子开环聚合,合成了聚丙烯-乙醇-叠氮缩水缩水甘油酯-聚丙二醇的新型高能三嵌段共聚物(PPG-GAP-PPG)(Mn=1419 g·mol-1)。通过傅立叶变换红外光谱(FT-IR)、凝胶渗透色谱(GPC)和核磁共振波谱(1H和13C NMR)对合成的GAP和三嵌段共聚物进行了表征。采用差示扫描量热法(DSC)和热重分析法(TG)研究了三嵌段共聚物PPG-GAP-PPG的热稳定性。DSC结果表明,三嵌段共聚物的玻璃化转变温度(Tg=−63°C)低于纯低分子量GAP的玻璃化转化温度(Tg=−53°C)。此外,结果表明,该三嵌段共聚物比GAP更稳定。加热速率(10、20、30和40°C·min−1)的影响表明,增加加热速率会导致三嵌段共聚物的分解温度升高。使用ASTM E698、Flynn Wall Ozawa(FWO)和Kissinger提出的非等温方法,使用DSC-DTG《中欧高能材料杂志》ISSN 1733-7178,计算了三嵌段共聚物PPG-GAP-PPG热分解的动力学参数,如活化能和频率因子;e-ISSN 2353-1843版权所有©2020Łukasiewicz研究网络-波兰工业有机化学研究所263热稳定性和分解动力学研究。。。版权所有©2020Łukasiewicz研究网络-波兰工业有机化学研究所数据。FWO和ASTM E698方法计算的活化能分别为124.610和126.13 kJ·mol–1。
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引用次数: 3
Thermochemical Properties, Ballistic Parameters and Sensitivity of New RDX-based Propellants 新型RDX基推进剂的热化学性质、弹道参数和灵敏度
IF 0.8 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2020-06-25 DOI: 10.22211/cejem/122326
M. Hara, W. Trzciński, S. Cudziło, M. Szala, Z. Chyłek, Z. Surma
New RDX-based propellants were obtained and investigated. The heat of combustion was determined in a calorimeter and the pressure history was measured in a manometric bomb. Ballistic parameters, such as maximum pressure, propellant force and covolume of gaseous products, as well as the dynamic vivacity, were determined based on the experimental results. The sensitivities to friction and impact were determined for the tested propellants. Calculations of the ballistic characteristics (the heat of combustion, propellant force, covolume and ratio of specific heats of the combustion products, and ballistic energy) were performed. The theoretical parameters were compared with the experimental data and quite good agreement was found between them. The largest differences occurred in the cases of propellant force and covolume. This disagreement is explained. An analysis of the test results and a comparison of the parameters of the RDX-based propellants and the JA2 propellant allowed the possibility of using the tested propellants in ammunition to be assessed.
获得并研究了新型RDX基推进剂。燃烧热在量热计中测定,压力历史在测压弹中测量。根据实验结果确定了弹道参数,如最大压力、推进剂力、气体产物体积以及动态寿命。测定了试验推进剂对摩擦和冲击的敏感性。对弹道特性(燃烧热、推进剂力、燃烧产物的体积和比热比以及弹道能量)进行了计算。将理论参数与实验数据进行了比较,发现它们之间有很好的一致性。最大的差异出现在推进剂力和体积的情况下。这一分歧已得到解释。通过对测试结果的分析以及对RDX基推进剂和JA2推进剂参数的比较,可以评估在弹药中使用测试推进剂的可能性。
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引用次数: 1
Numerical Modelling of Detonation Reaction Zone of Nitromethane by EXPLO5 Code and Wood and Kirkwood Theory 用EXPLO5程序和Wood和Kirkwood理论对硝基甲烷爆轰反应区的数值模拟
IF 0.8 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2020-06-25 DOI: 10.22211/cejem/124193
B. Štimac, H. Y. Chan, M. Künzel, M. Sućeska
The detonation reaction zone of nitromethane (NM) has been extensively studied both experimentally and theoretically. The measured particle velocity
硝基甲烷的爆轰反应区在实验和理论上都得到了广泛的研究。测得的粒子速度
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引用次数: 4
Experimental Investigation of the Effect of Polymers and Crystalline Qualities on the Safety Performance of LLM-105-based PBXs under Dynamic Compression and Shear 聚合物和结晶质量对LLM-105基PBX在动态压缩和剪切下安全性能影响的实验研究
IF 0.8 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2020-06-25 DOI: 10.22211/cejem/124173
Xiao-gan Dai, Songwei He, Xiaona Huang, Zhijian Yang, Yushi Wen, Ming Li
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引用次数: 2
Synthesis and Curing of Allyl Urethane NIMMO-THF Copolyether with Three Functional Groups as a Potential Energetic Binder 具有三个官能团的烯丙基聚氨酯NIMMO-THF共聚醚的合成与固化
IF 0.8 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2020-03-26 DOI: 10.22211/cejem/119233
Wang Xiaochuan, Ping Li, Lu Xianming, Mo Hongchang, Xu Minghui, Ning Liu, Y. Shu
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引用次数: 6
Mechanical Properties of HTPE/Bu-NENA Binder and the Kinetics of Bu-NENA Evaporation HTPE/Bu-NENA粘结剂的力学性能及Bu-NENA蒸发动力学
IF 0.8 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2020-03-26 DOI: 10.22211/cejem/119352
Shen Yuan, Yun-jun Luo
The correlation between the mechanical properties of hydroxyl-terminated polyether (HTPE)/N-butyl-N-(2-nitroxyethyl)nitramine (Bu-NENA) binders with different plasticization ratios (pl/po), varied from 0.9 to 1.5, have been studied. The very early stage of evaporation of Bu-NENA from the HTPE/Bu-NENA binder, with a pl/po ratio of 1.2, has been investigated. The results revealed that the pl/po ratio has strong influences on the mechanical properties. When the pl/po ratio was 1.2, the mechanical properties of the HTPE/Bu-NENA binder were satisfactory, the maximum tensile strength and the elongation at break being 2.39 MPa and 93.27%, respectively. The evaporation rate constant of Bu-NENA from HTPE/Bu-NENA binder with a pl/po ratio of 1.2 increased from 0.31·10–5 to 2.32·10–5 s–1 as the temperature was increased from 50 to 90 °C. The value of the activation energy of evaporation was 51.47 kJ/mol and its pre-exponential factor was 6.14·102 s–1.
研究了端羟基聚醚(HTPE)/N-丁基-N-(2-硝基氧乙基)硝胺(Bu-NENA)粘合剂在不同塑化比(pl/po)(0.9-1.5)下的力学性能之间的相关性。研究了从pl/po比为1.2的HTPE/Bu-NENA粘合剂中蒸发Bu-NENA的早期阶段。结果表明,pl/po比对力学性能有很大影响。当pl/po比为1.2时,HTPE/Bu-NENA粘合剂的力学性能令人满意,最大拉伸强度和断裂伸长率分别为2.39MPa和93.27%。当温度从50°C增加到90°C时,pl/po比为1.2的HTPE/Bu-NENA粘合剂的Bu-NENA蒸发速率常数从0.31·10–5增加到2.32·10–5s–1。蒸发活化能为51.47 kJ/mol,其指数前因子为6.14·102 s–1。
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引用次数: 0
Microcellular Oblate Propellant with Skin-core Structure Deterred by Poly(neopentanediol adipate) 聚己二酸新戊二醇阻聚皮芯结构的微孔扁圆推进剂
IF 0.8 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2020-03-20 DOI: 10.22211/cejem/119050
Yajun Ding, S. Ying, Zhongliang Xiao, Wenlong Wu, Chunzhi Li, Yun He
In order to solve the issues of high muzzle flash, smoke, residue, migration rate and carcinogenicity of double-base oblate propellants deterred by dibutyl phthalate (DBP), skin-core structure microporous oblate propellants to replace DBP deterring technology were fabricated in the present work by supercritical carbon dioxide (SC-CO2) foaming technology. Poly(neopentanediol adipate) (NA) was employed as the deterrent to modify the combustion properties because of ist lower migration rate in storage. Scanning electron microscopy (SEM) was used to observe the morphology of the microporous oblate propellants generated by different processing conditions, and the combustion properties were investigated by closed bomb tests. The SEM images indicated that the skin region displayed smaller cell diameters and lower cell density compared with cells in the core region. The closed bomb tests demonstrated that it was feasible to adjust the progressive combustion performance by controlling the skin-core structure and the NA deterred layer. The burning time values of the original, the microcellular, and the NA deterred samples were 3.45, 2.14, Central European Journal of Energetic Materials ISSN 1733-7178; e-ISSN 2353-1843 Copyright © 2020 Łukasiewicz Research Network – Institute of Industrial Organic Chemistry, Poland 50 Y. Ding, S. Ying, Z. Xiao, W. Wu, C. Li, Y. He Copyright © 2020 Łukasiewicz Research Network – Institute of Industrial Organic Chemistry, Poland and 4.20 ms, respectively. Microcellular oblate propellants, with a skin-core structure foamed by SC-CO2 and deterred by NA, provides a novel and promising method to realize progressive combustion performance.
为了解决邻苯二甲酸二丁酯(DBP)对双基扁圆推进剂阻蚀后存在的高枪口闪光、高烟度、高残留、高迁移率和致癌性等问题,采用超临界二氧化碳(SC-CO2)发泡技术制备了皮芯结构微孔扁圆推进剂来代替DBP阻蚀技术。聚己二酸新戊二醇(NA)由于其在储存中的迁移率较低,被用作改变燃烧性能的威慑物。利用扫描电子显微镜(SEM)观察了不同工艺条件下微孔扁推进剂的形貌,并通过闭弹试验研究了其燃烧性能。SEM图像表明,与核心区域中的细胞相比,皮肤区域显示出更小的细胞直径和更低的细胞密度。闭式炸弹试验表明,通过控制皮芯结构和NA威慑层来调节渐进燃烧性能是可行的。原始样品、微孔样品和NA阻止样品的燃烧时间值分别为3.45、2.14,《中欧高能材料杂志》ISSN 1733-7178;e-ISSN 2353-1843版权所有©2020Łukasiewicz研究网络-波兰工业有机化学研究所50 Y.Ding,S.Ying,Z.Xiao,W.Wu,C.Li,Y.He版权所有©2021Ł。采用SC-CO2发泡皮芯结构和NA阻聚的微孔扁推进剂,为实现渐进燃烧性能提供了一种新的、有前景的方法。
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引用次数: 0
Theoretical Study on Nitroimine Derivatives of Azetidine as High-Energy-Density Compounds 氮啶的硝基亚胺衍生物作为高能量密度化合物的理论研究
IF 0.8 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2020-03-20 DOI: 10.22211/cejem/119139
Butong Li, Lu-Lin Li
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引用次数: 1
期刊
Central European Journal of Energetic Materials
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