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Hexavalent chromium removal from aqueous solution by polymer-enhanced ultrafiltration 利用聚合物强化超滤从水溶液中去除六价铬
IF 2.5 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2023-12-11 DOI: 10.1080/00986445.2023.2291801
Nawaf Bin Darwish, Abdulrahman AlAlawi
This study compares the effects of two different polymers using polymer-enhanced ultrafiltration (PEUF) to remove hexavalent chromium ions from an aqueous solution with a polyacrylonitrile (PAN) me...
本研究比较了两种不同聚合物的效果,即使用聚合物增强超滤(PEUF)去除水溶液中的六价铬离子,以及使用聚丙烯腈(PAN)材料去除水溶液中的六价铬离子。
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引用次数: 0
Determination of optimum parameters using different nano fluids in heat pipe heat exchangers with response surface method 用响应面法确定不同纳米流体在热管换热器中的最佳参数
IF 2.5 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2023-12-02 DOI: 10.1080/00986445.2023.2289146
Ahmet Öztürk, Fatin Sönmez, Abdüssamed Kabakuş
In this study, optimum parameters affecting the thermal efficiency of heat pipes were determined experimentally with response surface method using different types of nanofluids in heat exchangers. ...
在本研究中,利用响应面法实验确定了影响热管热效率的最佳参数,并在换热器中使用不同类型的纳米流体. ...
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引用次数: 0
Growing hydrogen production by merging the glycerol steam reforming and water gas shift reactions into a single reactor 通过将甘油蒸汽重整反应和水煤气转移反应合并到一个反应器中来增加氢气产量
IF 2.5 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2023-11-27 DOI: 10.1080/00986445.2023.2287501
Anmesh Gaire, Susan Stagg-Williams, Christopher Depcik
One promising idea to use excess glycerol generated during biodiesel fabrication is to produce hydrogen (H2) via the steam reforming of glycerol (GSR). This study combined GSR and water-gas shift (...
利用生物柴油制造过程中产生的多余甘油的一个有希望的想法是通过甘油(GSR)的蒸汽重整生产氢气(H2)。该研究结合了GSR和水气转换(…
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引用次数: 0
Green corrosion inhibitor for mild steel extracted from soybean leaves 从大豆叶片中提取的绿色低碳钢缓蚀剂
IF 2.5 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2023-11-24 DOI: 10.1080/00986445.2023.2284732
Alfonso Pepe, Florencia R. Tito, Alejo D. Mandri, Ricardo C. Dommarco, Andrés Pepe
The use of green-soluble inhibitors in the corrosive medium as alternatives to traditional inhibitors has increased due to the toxicity of the commonly used substances. These novel substances are s...
由于常用物质的毒性,在腐蚀性介质中使用绿色可溶性抑制剂作为传统抑制剂的替代品已经增加。这些新物质是……
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引用次数: 0
Current advances and future scope of copper sulphide (CuS) and its conjugates for supercapacitor developments 硫化铜及其偶联物在超级电容器领域的研究进展及前景
IF 2.5 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2023-11-24 DOI: 10.1080/00986445.2023.2284724
Akashdeep Dey, S. Noyel Victoria, Mahendra S. Gaikwad
Supercapacitors (SCs) are devices that can store and release massive amounts of electrical energy, making them ideal for use in a variety of applications. Continuous technological advancements in t...
超级电容器(SCs)是一种可以储存和释放大量电能的设备,这使得它们非常适合用于各种应用。技术的不断进步…
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引用次数: 0
A note on the solution to one-dimensional advection-dispersion-reaction problems 一维平流-分散-反应问题解的注记
IF 2.5 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2023-11-23 DOI: 10.1080/00986445.2023.2284720
Marko V. Lubarda, Vlado A. Lubarda
The series representation of the reactant concentration in one-dimensional advection-dispersion-reaction problems within a container of finite length is derived in a compact and computationally les...
在有限长度容器内一维平流-分散-反应问题中,得到了反应物浓度的级数表示。
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引用次数: 0
Synthesis of hybrid layered double hydroxides (HLDH) and application as adsorbent for removal of direct sky-blue dye 杂化层状双氢氧化物(HLDH)的合成及其在直接去除天蓝染料中的应用
4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2023-11-07 DOI: 10.1080/00986445.2023.2276140
Ahsan Maqsood, Ruba Munir, Gadah Albasher, Murtaza Sayed, Raziya Nadeem, Nazish Jahan, Amna Muneer, Muhammad Yaseen, Muhammad Zahid, Fazila Younas, Saima Noreen
AbstractHybrid Layered Double Hydroxides (HLDH) are promising adsorption materials for water treatment due to their excellent anion exchange capacities, abundance of active sites, and eco-friendliness. HLDH was synthesized utilizing the co-precipitation technique in this work to demonstrate its applicability for the removal of direct sky-blue dye via an adsorption procedure. The effects of pH, dose, contact time, initial dye concentration, and temperature on the direct sky-blue dye adsorption efficiency were thoroughly investigated. The adsorbents were analyzed using scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), X-ray powder diffraction (XRD), energy dispersive X-ray (EDX), and Brunauer–Emmett–Teller (BET). Under the best conditions, the maximum adsorption capacity has been achieved for Mg–Cr–Cl (42.95 mg/g) > Zn–Al–CO3 (39.76 mg/g) > Mg–Fe–Cl (38.08 mg/g). The adsorption of dyes on Mg–Cr–Cl, Zn–Al–CO3, and Mg–Fe–Cl followed a pseudo-second-order kinetic model and exhibited Langmuir-type monolayer adsorption. The influence of temperature was studied to determine the thermodynamic parameters. The estimated results showed spontaneous and exothermic adsorption processes. Electrolyte enhances the adsorption capacity to some extent, while surfactants block the sites, thus reducing the adsorption capacity. The maximum desorption of dye was influenced by the sodium hydroxide solution. The research described here might be utilized to create novel adsorbents with improved adsorption capacities for preserving the aquatic environment.Keywords: Adsorption–desorptiondirect sky-blue dyeMg–Cr–Cl HLDHMg–Fe–Clthermodynamic parametersZn–Al–CO3 AcknowledgmentThe authors would like to extend their sincere appreciation to the acknowledgment; research supporting project (RSP-2023/95, King Saud University, Riyadh, Saudi Arabia).Author contribution statementAhsan Maqsood: Methodology, Writing- original draft, Ruba Munir: Methodology, Formal analysis, acquisition of data, Saima Noreen: Supervision, Conceptualization, Formal analysis, Resources, Gadah Albasher: Conceptualization, Resources, Writing-review& editing, Amna Muneer: Statistical analysis, Writing-review & editing, Murtaza Sayed: execution, Writing-review& editing, Muhammad Yaseen: interpretation, Writing-review& editing, Fazila Younas: Conceptualization, interpretation, Raziya Nadeem: Conceptualization, interpretation, Muhammad Zahid: execution, Writing-review& editing, Nazish Jahan: execution, Writing-review& editing.Consent for publicationAll authors have read and approved this manuscript.Consent to participateNot applicable.Data availabilityData will be made available on reasonable request.Disclosure statementThe authors declare no competing interests.Ethical approvalResearch does not involve Human Participants or/and Animals.
摘要/ abstract摘要:混合层状双氢氧化物(HLDH)具有良好的阴离子交换能力、丰富的活性位点和生态友好性,是一种很有前途的水处理吸附材料。本研究利用共沉淀法合成了HLDH,以证明其对吸附法直接去除天蓝染料的适用性。考察了pH、剂量、接触时间、初始染料浓度和温度对天蓝染料直接吸附效率的影响。采用扫描电镜(SEM)、傅里叶变换红外光谱(FTIR)、x射线粉末衍射(XRD)、能量色散x射线(EDX)和布鲁诺尔-埃米特-泰勒(BET)对吸附剂进行了分析。在最佳吸附条件下,mg - cr - cl (42.95 mg/g) > Zn-Al-CO3 (39.76 mg/g) > mg - fe - cl (38.08 mg/g)的吸附量最大。染料在Mg-Cr-Cl、Zn-Al-CO3和Mg-Fe-Cl上的吸附符合准二级动力学模型,表现为langmuir型单层吸附。研究了温度的影响,确定了热力学参数。估计结果显示自发和放热吸附过程。电解质在一定程度上增强了吸附能力,而表面活性剂阻断了这些位点,从而降低了吸附能力。氢氧化钠溶液对染料的最大解吸率有影响。本文所述的研究可能用于创造具有更高吸附能力的新型吸附剂,以保护水生环境。关键词:吸附-解吸直接天蓝染料mg - cr - cl hldhmg - fe - cl热力学参数szn - al - co3致谢作者对致谢表示衷心的感谢;科研支持项目(RSP-2023/95,沙特国王大学,沙特阿拉伯利雅得)。作者贡献声明:ahsan Maqsood:方法论、写作-原稿,Ruba Munir:方法论、形式分析、数据获取,Saima Noreen:监督、概念化、形式分析、资源,Gadah Albasher:概念化、资源、写作-审查和编辑,Amna Muneer:统计分析、写作-审查和编辑,Murtaza Sayed:执行、写作-审查和编辑,Muhammad Yaseen:解释、写作-审查和编辑,Fazila Younas:概念化,解释,Raziya Nadeem:概念化,解释,Muhammad Zahid:执行,写作-审查和编辑,Nazish Jahan:执行,写作-审查和编辑。所有作者都已阅读并批准了本文。同意参加不适用。数据可得性应合理要求,将提供数据。披露声明作者声明无利益竞争。伦理批准研究不涉及人类参与者或/和动物。
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引用次数: 0
Simulation of fluid flow and heat-moisture transfer mechanism in packed bed based on double-diffusion model 基于双扩散模型的填料床流体流动及热湿传递机理模拟
4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2023-10-26 DOI: 10.1080/00986445.2023.2272183
Xin Li, Kaimin Yang, Yuancheng Wang, Xinming Du
AbstractBased on the discrete element method (DEM), four packed beds composed of soybean kernels with diameters of 6.4, 6.8, 7.4 mm, and the mixture of three kinds of particles were established. Then, a double-diffusion heat and mass transfer model between the grain pile and the interstitial air was established based on the local mass and thermal non-equilibrium (LMTNE) mechanism. Finally, employing particle-resolved computational fluid dynamics (PRCFD), the heat and mass transfer between the grain kernels and air during the drying process in the four packed beds were numerically resolved. It was found that the packed bed formed by stacking particles of different diameters had a minimum porosity of 0.4547. The radial porosity of the packed bed oscillates and decreases toward the central axis, while the tortuosity of the airflow path oscillates and decays toward the periphery. The mass transfer Biot number for soybean kernels with diameters of 6.4, 6.8, and 7.4 mm were 2.38 × 106, 2.44 × 106, and 2.53 × 106, respectively. This indicates that the mass transfer rate in the grain pile primarily depends on the magnitude of the moisture diffusion coefficient within the grain kernels. Compared with mass diffusion, thermal diffusion occurs much faster, which results in temperature gradients in packed beds only existing in the first 5 min of drying, and the drying rate in the early stage is higher than that in the later stage. Most importantly, the airflow characteristics, heat and moisture content are not in local equilibrium in the packed bed, and should be considered when designing drying systems.Keywords: Biot numberdouble-diffusionheat-moisture coupling transferporositysoybeantortuosity Disclosure statementThe authors declare that they have no conflicts of interest.Additional informationFundingThis study was supported by the Scientific and Technological Innovation Project for Youth of Shandong Provincial Colleges and Universities (Grant No. 2019KJH012). The Plan of Guidance and Cultivation for Young Innovative Talents of Shandong Provincial Colleges and Universities.
摘要基于离散元法(DEM),建立了直径分别为6.4、6.8、7.4 mm的大豆籽粒和3种颗粒混合组成的4个填充床。然后,基于局部质热不平衡(LMTNE)机理,建立了颗粒堆与间隙空气之间的双扩散传热传质模型。最后,利用粒子解析计算流体力学(PRCFD)对四层填料床干燥过程中籽粒与空气之间的传热传质进行了数值解析。结果表明,不同粒径颗粒堆积形成的充填床孔隙率最小为0.4547。充填床的径向孔隙率沿中心轴方向振荡减小,而气流路径的弯曲度沿外围方向振荡衰减。直径为6.4、6.8和7.4 mm的大豆籽粒传质Biot值分别为2.38 × 106、2.44 × 106和2.53 × 106。这表明谷粒堆内的传质速率主要取决于谷粒内水分扩散系数的大小。与质量扩散相比,热扩散发生的速度要快得多,这导致充填床内的温度梯度只存在于干燥前5 min,且干燥初期的干燥速率高于后期。最重要的是,填料床内的气流特性、热量和水分含量不处于局部平衡状态,在设计干燥系统时应予以考虑。关键词:生物数字双扩散-热-湿耦合转移孔隙率化学扭曲性公开声明作者声明无利益冲突。本研究由山东省高校青年科技创新项目(批准号:2019KJH012)资助。山东省省级高校青年创新人才引导培养计划。
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引用次数: 0
Modeling spinel oxide based-photocatalytic degradation of organic pollutants from industrial wastewater 氧化尖晶石基光催化降解工业废水中有机污染物的模拟
4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2023-10-17 DOI: 10.1080/00986445.2023.2269526
Sajda S. Alsaedi, Seba Saeed Mohammed, Alyaa Esam Mahdi, Zainab Y. Shnain, Hasan Sh. Majdi, Adnan A. AbdulRazak, Asawer A. Alwasiti
AbstractRapid population growth has resulted in rapid growth in industrialization to meet various human needs. As a result of this, huge volume of effluent is being generated from the industrial processes and released into the water bodies. These anthropogenic activities are often detrimental to human and aquatic lives. In this study, a modeling approach to evaluate the photocatalytic degradation of organic pollutants from industrial wastewater using spinel oxide is investigated. Four machine learning algorithms namely, linear regression, decision tree ensemble, medium Gaussian support vector machine, and exponential Gaussian process regression were employed. The parametric analysis of the predictors (particle size of the spinel oxides, the initial dye concentration, the amount of photocatalysts, the band gap, and the irradiation time) and the targeted output of the photocatalytic degradation efficiency shows that a non-linear relationship exists between the predictors and the targeted output. This was further confirmed by the linear regression model with R2 of 0.220. Besides, the decision tree ensemble and medium Gaussian support vector machine regression offer poor performances in predicting the photocatalytic degradation efficiency as indicated by R2 of 0.420 and 0.490, respectively. A superior performance in predicting the photocatalytic degradation efficiency was displayed by the exponential Gaussian process regression with R2 of 0.991.Keywords: Degradationdyemachine learningspinel oxidesupport vector machinewastewater AcknowledgmentsThe authors acknowledge the support of Department of Chemical Engineering, University of Technology, Iraq.Disclosure statementNo potential conflict of interest was reported by the author(s).
人口的快速增长导致了工业化的快速发展,以满足人类的各种需求。因此,工业生产过程产生了大量的污水,并排放到水体中。这些人为活动往往对人类和水生生物有害。本文研究了氧化尖晶石光催化降解工业废水中有机污染物的模拟方法。采用了线性回归、决策树集成、中高斯支持向量机和指数高斯过程回归四种机器学习算法。对尖晶石氧化物粒度、初始染料浓度、光催化剂用量、带隙和照射时间等预测因子和光催化降解效率的目标输出进行参数化分析,结果表明,预测因子和光催化降解效率的目标输出之间存在非线性关系。通过R2为0.220的线性回归模型进一步证实了这一点。此外,决策树集成和中高斯支持向量机回归对光催化降解效率的预测效果较差,R2分别为0.420和0.490。指数高斯过程回归对光催化降解效率的预测效果较好,R2为0.991。关键词:降解、机器学习、尖晶石氧化物、支持向量机、废水致谢作者感谢伊拉克理工大学化学工程系的支持。披露声明作者未报告潜在的利益冲突。
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引用次数: 1
Application of integrated molecular distillation-adsorption process for deacidification and recovery of vitamin E and carotenoids from palm oil 分子蒸馏-吸附一体化工艺在棕榈油中维生素E和类胡萝卜素脱酸回收中的应用
4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2023-10-16 DOI: 10.1080/00986445.2023.2269527
Eluize Vayne Maziero, Maurício Dalla Costa Rodrigues da Silva, Cristiano Augusto Ballus, Eduardo Hiromitsu Tanabe, Daniel Assumpção Bertuol
AbstractPalm oil is a natural source of phytonutrients such as vitamin E and carotenoids. However, these high-value compounds are lost during conventional refining. These phytonutrients can be separated and recovered from crude palm oil (CPO) through methods which prevents the degradation of these compounds. This study evaluated the integrated approach of molecular distillation and adsorption, with the aim of deacidifying and separating vitamin E and carotenoids from CPO, allowing their recovery. Wiped-film molecular distillation (WFMD) was used for deacidification and vitamin E enrichment, the best results were obtained at 200 °C and 21 mL/min. The distillate stream was enriched 937.8% in vitamin E, and the residue stream (named deacidified palm oil - DAPO), enriched in carotenoids, reached 0.1% free fatty acids (FFA). Integration with the adsorption process achieved a carotenoids removal of 79.4% from the DAPO stream. Moreover, the kinetic constant (k2) of adsorption increased by around 87% for DAPO, a result attributed to the absence of fat crystals on the adsorbent surface verified by scanning electron microscopy. Notably, the integrated process approach used is an innovative methodology for the vegetable oil industry presenting an alternative route that allows the preservation and recovery of phytonutrients, and the oil deacidification.Keywords: Bioactive compoundsenrichmentfood ingredientsintegrated processpalm oilphytonutrients AcknowledgmentsThe authors thank Bioesans Biotechnological Products S.A. for financial support and Itochu Chemicals America Inc. for adsorbent donation. The following Brazilian agencies supported this study: Foundation for the Support of Research in the State of Rio Grande do Sul (FAPERGS); National Council for Scientific and Technological Development (CNPq); Coordination for the Improvement of Higher Education Personnel (CAPES); and Secretariat of Economic Development, Science and Technology of the State of Rio Grande do Sul (SDECT).Disclosure statementThe authors declare no competing interests.
棕榈油是维生素E和类胡萝卜素等植物营养素的天然来源。然而,这些高价值的化合物在常规精炼过程中会丢失。这些植物营养素可以通过防止这些化合物降解的方法从粗棕榈油(CPO)中分离和回收。本研究评估了分子蒸馏和吸附相结合的方法,目的是脱酸和分离CPO中的维生素E和类胡萝卜素,使其回收。采用擦膜分子蒸馏(WFMD)进行脱酸和维生素E富集,在200℃、21 mL/min的条件下效果最佳。馏出液中维生素E的含量为937.8%,残留液(命名为脱酸棕榈油- DAPO)中类胡萝卜素含量为0.1%,游离脂肪酸(FFA)含量较高。结合吸附过程,类胡萝卜素的去除率为79.4%。此外,DAPO的吸附动力学常数(k2)增加了约87%,这是由于扫描电镜证实了吸附剂表面没有脂肪晶体。值得注意的是,所使用的综合工艺方法是植物油行业的一种创新方法,提供了一种可选择的途径,允许植物营养素的保存和恢复,以及油的脱酸。关键词:生物活性化合物;食品成分;综合工艺;棕榈油;植物营养素;下列巴西机构支持这项研究:支持南里奥格兰德州研究基金会(FAPERGS);国家科学技术发展委员会;高等教育人才培养协调机制(CAPES)南里奥格兰德州经济发展和科学技术秘书处(SDECT)。披露声明作者声明无利益竞争。
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引用次数: 0
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Chemical Engineering Communications
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