Pub Date : 2019-09-30DOI: 10.31613/ceramist.2019.22.3.01
J. Y. Lee
s The development of highly efficient thermally activated delayed fluorescence (TADF) materials is an active area of recent research in organic light emitting diodes (OLEDs) since the first report by Chihaya Adachi in 2011. Traditional fluorescent materials can harvest only singlet excitons, leading to the theoretically highest external quantum efficiency (EQE) of 5% with considering about 20% light out-coupling efficiency in the device. On the other hand, TADF materials can harvest both singlet and triplet excitons through reverse intersystem crossing (RISC) from triplet to singlet excited states. It could provide 100% internal quantum efficiencies (IQE), resulting in comparable high EQE to traditional rare-metal complexes (phosphorescent materials). Thanks to a lot of efforts in this field, many highly efficient TADF materials have been developed. This review focused on recent molecular design concept and optoelectronic properties of TADF materials for high efficiency and long lifetime OLED application.
{"title":"Research Trends of Thermally Activated Delayed Fluorescence Materials for Organic Light-Emitting Diodes","authors":"J. Y. Lee","doi":"10.31613/ceramist.2019.22.3.01","DOIUrl":"https://doi.org/10.31613/ceramist.2019.22.3.01","url":null,"abstract":"s The development of highly efficient thermally activated delayed fluorescence (TADF) materials is an active area of recent research in organic light emitting diodes (OLEDs) since the first report by Chihaya Adachi in 2011. Traditional fluorescent materials can harvest only singlet excitons, leading to the theoretically highest external quantum efficiency (EQE) of 5% with considering about 20% light out-coupling efficiency in the device. On the other hand, TADF materials can harvest both singlet and triplet excitons through reverse intersystem crossing (RISC) from triplet to singlet excited states. It could provide 100% internal quantum efficiencies (IQE), resulting in comparable high EQE to traditional rare-metal complexes (phosphorescent materials). Thanks to a lot of efforts in this field, many highly efficient TADF materials have been developed. This review focused on recent molecular design concept and optoelectronic properties of TADF materials for high efficiency and long lifetime OLED application.","PeriodicalId":9738,"journal":{"name":"Ceramist","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87179075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-09-30DOI: 10.31613/ceramist.2019.22.3.03
Hyunok Jung, Yein Kang
s Graphene, a two-dimensional material with a single atomic layer, has recently become a major research focus in various applications such as electronic devices, sensors, energy storage, catalysts, and adsorbents, because of its large theoretical surface area, excellent electrical conductivity, outstanding chemical stability, and good mechanical properties. Recently, 3D nanoporous graphene structures have received tremendous attention to expand the application of 2D graphene. Here, we overview the synthesis of 3D nanoporous graphene network structure with two-dimensional graphite oxide sheets, the control of porous parameters such as specific surface area, pore volume and pore size etc, and the modification of electronic structure by heteroatom doping along with its various applications. The 3D nanoporous graphene shows superior performance in diverse applications as a promising key material. Consequently, 3D nanoporous graphene can lead the future for advanced nanotechnology.
{"title":"Three-dimensional Nanoporous Graphene-based Materials and Their Applications","authors":"Hyunok Jung, Yein Kang","doi":"10.31613/ceramist.2019.22.3.03","DOIUrl":"https://doi.org/10.31613/ceramist.2019.22.3.03","url":null,"abstract":"s Graphene, a two-dimensional material with a single atomic layer, has recently become a major research focus in various applications such as electronic devices, sensors, energy storage, catalysts, and adsorbents, because of its large theoretical surface area, excellent electrical conductivity, outstanding chemical stability, and good mechanical properties. Recently, 3D nanoporous graphene structures have received tremendous attention to expand the application of 2D graphene. Here, we overview the synthesis of 3D nanoporous graphene network structure with two-dimensional graphite oxide sheets, the control of porous parameters such as specific surface area, pore volume and pore size etc, and the modification of electronic structure by heteroatom doping along with its various applications. The 3D nanoporous graphene shows superior performance in diverse applications as a promising key material. Consequently, 3D nanoporous graphene can lead the future for advanced nanotechnology.","PeriodicalId":9738,"journal":{"name":"Ceramist","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78931587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-09-30DOI: 10.31613/ceramist.2019.22.3.04
R. Yu, YooJin Kim
Ceramic nano pigments have attracted much interest owing to recent demand for nontoxic, heavy metal-free pigments. In general, ceramic pigments must possess thermal stability at high temperature, however nanosized powder easily undergoes aggregation at high temperature, and its color turns. serveral groups have focused on to minimize agglomeration and oxidation, a core–shell structure with a silica coating is suggested. In this review, we introduce the reported the trend of nano-ceramic powders and we summarized method improve color and physical properties throuth morphology control and ceramic coating technology. keyword: ceramic nano pigment, coating, coloration,
{"title":"Trend of Ceramic Nano Pigments","authors":"R. Yu, YooJin Kim","doi":"10.31613/ceramist.2019.22.3.04","DOIUrl":"https://doi.org/10.31613/ceramist.2019.22.3.04","url":null,"abstract":"Ceramic nano pigments have attracted much interest owing to recent demand for nontoxic, heavy metal-free pigments. In general, ceramic pigments must possess thermal stability at high temperature, however nanosized powder easily undergoes aggregation at high temperature, and its color turns. serveral groups have focused on to minimize agglomeration and oxidation, a core–shell structure with a silica coating is suggested. In this review, we introduce the reported the trend of nano-ceramic powders and we summarized method improve color and physical properties throuth morphology control and ceramic coating technology. keyword: ceramic nano pigment, coating, coloration,","PeriodicalId":9738,"journal":{"name":"Ceramist","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73951135","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-09-30DOI: 10.31613/ceramist.2019.22.3.02
Changui Ahn, Junyong Park, Seokwoo Jeon
Functional ceramics are widely utilized in a variety of application fields such as structural materials, sensors, energy devices, purification filter and etc due to their high strength, stability and chemical activity. With the breakthrough development of nanotechnology, many researchers have studied new types of nanomaterials including nanoparticle, nanorod, nanowire and nanoplate to realize high-performance ceramics. Especially several groups have focused on the 3D nanostructured ceramics because of their large surface area, efficient load transfer, ultra-fast ion diffusion and superior electrical (or thermal) conductivity. In this review, we introduce the reported fabrication strategies of the 3D nanostructured and functional ceramics, also summarized the 3D nanostructured ceramic based highperformance applications containing photocatalysts, structural materials, energy harvesting and storage devices. KYEWORDS: high-performance, functional ceramics, 3D nanostructures, outstanding materials properties
{"title":"Recent Advances in High-performance Functional Ceramics using 3D Nanostructuring Techniques","authors":"Changui Ahn, Junyong Park, Seokwoo Jeon","doi":"10.31613/ceramist.2019.22.3.02","DOIUrl":"https://doi.org/10.31613/ceramist.2019.22.3.02","url":null,"abstract":"Functional ceramics are widely utilized in a variety of application fields such as structural materials, sensors, energy devices, purification filter and etc due to their high strength, stability and chemical activity. With the breakthrough development of nanotechnology, many researchers have studied new types of nanomaterials including nanoparticle, nanorod, nanowire and nanoplate to realize high-performance ceramics. Especially several groups have focused on the 3D nanostructured ceramics because of their large surface area, efficient load transfer, ultra-fast ion diffusion and superior electrical (or thermal) conductivity. In this review, we introduce the reported fabrication strategies of the 3D nanostructured and functional ceramics, also summarized the 3D nanostructured ceramic based highperformance applications containing photocatalysts, structural materials, energy harvesting and storage devices. KYEWORDS: high-performance, functional ceramics, 3D nanostructures, outstanding materials properties","PeriodicalId":9738,"journal":{"name":"Ceramist","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88310880","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-09-30DOI: 10.31613/ceramist.2019.22.3.08
Seongjin Ha, Dongki Lee, Wenji Jin, Dae-hwan Park
Carbon nitride has drawn broad interdisciplinary attention in diverse fields such as catalyst, energy storage, gas adsorption, biomedical sensing and even imaging. Intensive studies on carbon dioxide (CO2) capture using carbon nitride materials with various nanostructures have been reported since it is needed to actively remove CO2 from the atmosphere against climate change. This is mainly due to its tunable structural features, excellent physicochemical properties, and basic surface functionalities based on the presence of a large number of –NH or –NH2 groups so that the nanostructured carbon nitrides are considered as suitable materials for CO2 capture for future utilization as well. In this review, we summarize and highlight the recent progress in synthesis strategies of carbon nitride nanomaterials. Their superior CO2 adsorption capabilities are also discussed with the structural and textural features. An outlook on possible further advances in carbon nitride is also included.
{"title":"A Review on Nanostructured Carbon Nitrides for CO2 Capture","authors":"Seongjin Ha, Dongki Lee, Wenji Jin, Dae-hwan Park","doi":"10.31613/ceramist.2019.22.3.08","DOIUrl":"https://doi.org/10.31613/ceramist.2019.22.3.08","url":null,"abstract":"Carbon nitride has drawn broad interdisciplinary attention in diverse fields such as catalyst, energy storage, gas adsorption, biomedical sensing and even imaging. Intensive studies on carbon dioxide (CO2) capture using carbon nitride materials with various nanostructures have been reported since it is needed to actively remove CO2 from the atmosphere against climate change. This is mainly due to its tunable structural features, excellent physicochemical properties, and basic surface functionalities based on the presence of a large number of –NH or –NH2 groups so that the nanostructured carbon nitrides are considered as suitable materials for CO2 capture for future utilization as well. In this review, we summarize and highlight the recent progress in synthesis strategies of carbon nitride nanomaterials. Their superior CO2 adsorption capabilities are also discussed with the structural and textural features. An outlook on possible further advances in carbon nitride is also included.","PeriodicalId":9738,"journal":{"name":"Ceramist","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79568470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-06-30DOI: 10.31613/CERAMIST.2019.22.2.06
Jin Goo Lee
{"title":"Various Problems in Oxygen-evolution Reaction Catalysts in Alkaline Conditions and Perovskites Utilization","authors":"Jin Goo Lee","doi":"10.31613/CERAMIST.2019.22.2.06","DOIUrl":"https://doi.org/10.31613/CERAMIST.2019.22.2.06","url":null,"abstract":"","PeriodicalId":9738,"journal":{"name":"Ceramist","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78785879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-06-30DOI: 10.31613/CERAMIST.2019.22.2.01
C. Baek, Jun-hyung Seo, Jin-sang Cho, Ji-Whan Ahn, Kye-Hong Cho
s The possibility of economic exchange with North Korea is increasing, but there is still a shortage of information of cement industry, which occupies the largest proportion of North Korean construction material industry. Therefore, this study researched the status of cement production facility management using satellite photographs of 16 cement factories in North Korea, and examined the operating status of North Korean cement industry by observing smoke discharged from the chimneys of the cement production facilities. When the satellite photographs were analyzed, it was observed that the monthly stack fog ratio of the North Korean cement factories was 55% in 2016, 60% in 2017 and nearly 65% in 2018. This demonstrates that the average operating ratio has been increasing continuously. However, the operation rate of the five major cement factories reaches the limit, actual cement production is estimated to have maintained the previous level or small increased. keyword: North Korea, Cement, Kiln, Limestone, Satellite image
{"title":"North Korea Cement Industry in Satellite Imagery","authors":"C. Baek, Jun-hyung Seo, Jin-sang Cho, Ji-Whan Ahn, Kye-Hong Cho","doi":"10.31613/CERAMIST.2019.22.2.01","DOIUrl":"https://doi.org/10.31613/CERAMIST.2019.22.2.01","url":null,"abstract":"s The possibility of economic exchange with North Korea is increasing, but there is still a shortage of information of cement industry, which occupies the largest proportion of North Korean construction material industry. Therefore, this study researched the status of cement production facility management using satellite photographs of 16 cement factories in North Korea, and examined the operating status of North Korean cement industry by observing smoke discharged from the chimneys of the cement production facilities. When the satellite photographs were analyzed, it was observed that the monthly stack fog ratio of the North Korean cement factories was 55% in 2016, 60% in 2017 and nearly 65% in 2018. This demonstrates that the average operating ratio has been increasing continuously. However, the operation rate of the five major cement factories reaches the limit, actual cement production is estimated to have maintained the previous level or small increased. keyword: North Korea, Cement, Kiln, Limestone, Satellite image","PeriodicalId":9738,"journal":{"name":"Ceramist","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89745261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-06-30DOI: 10.31613/CERAMIST.2019.22.2.03
Jae-Hwan Jung, Dong-Min Lee, Young Jun Kim, Sang Woo Kim
s Triboelectric nanogenerators and piezoelectric nanogenerators are a spotlighted energy harvesting method that converts the wasted mechanical energy from the environment into usable electrical energy. In the case of triboelectric nanogenerators, researches have been mainly focused on high permittivity and flexible polymer materials, and in the case of piezoelectric nanogenerators, researches have been focused on ceramic materials exhibiting high polarization characteristics. Recently, many researches have been conducted to improve durability and power in various environments by using composite materials which have flexible properties of polymer, high permittivity, thermal resistance and high polarization properties of ceramics. This article reviews the energy harvesting studies reported about composites materials using ceramics and polymers.
{"title":"Recent Trends in Energy Harvesting Technology Using Composite Materials","authors":"Jae-Hwan Jung, Dong-Min Lee, Young Jun Kim, Sang Woo Kim","doi":"10.31613/CERAMIST.2019.22.2.03","DOIUrl":"https://doi.org/10.31613/CERAMIST.2019.22.2.03","url":null,"abstract":"s Triboelectric nanogenerators and piezoelectric nanogenerators are a spotlighted energy harvesting method that converts the wasted mechanical energy from the environment into usable electrical energy. In the case of triboelectric nanogenerators, researches have been mainly focused on high permittivity and flexible polymer materials, and in the case of piezoelectric nanogenerators, researches have been focused on ceramic materials exhibiting high polarization characteristics. Recently, many researches have been conducted to improve durability and power in various environments by using composite materials which have flexible properties of polymer, high permittivity, thermal resistance and high polarization properties of ceramics. This article reviews the energy harvesting studies reported about composites materials using ceramics and polymers.","PeriodicalId":9738,"journal":{"name":"Ceramist","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86899903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-06-30DOI: 10.31613/CERAMIST.2019.22.2.02
S. Ji, J. Yun
s Wearable electronic devices with batteries must be lightweight, flexible and highly durable. Most importantly, the battery should be able to self-generate to operate the devices without having to be too frequently charged externally. An eco-friendly energy harvesting technology from various sources, such as solar energy, electromagnetic energy and wind energy, has been developed for a self-charging flexible battery. Although the energy harvesting from such sources are often unstable according to the surrounding environment, the energy harvesting from body movements and vibrations has been less affected by the surrounding environment. In this regard, flexible piezoelectric modules are the most attractive solution for this issue, because they convert mechanical energy to electrical energy and harvest energy from the human body motions. Among the various flexible piezoelectric modules, piezoelectric nanofibers have advantages when used as an energy harvester in wearable devices, due to their simple manufacturing process with good applicability to polymers and ceramics. This review focused on diverse flexible piezoelectric nanofibers and discusses their applications as various energy harvesting systems.
{"title":"Recent Research Trends of Flexible Piezoelectric Nanofibers for Energy Conversion Materials","authors":"S. Ji, J. Yun","doi":"10.31613/CERAMIST.2019.22.2.02","DOIUrl":"https://doi.org/10.31613/CERAMIST.2019.22.2.02","url":null,"abstract":"s Wearable electronic devices with batteries must be lightweight, flexible and highly durable. Most importantly, the battery should be able to self-generate to operate the devices without having to be too frequently charged externally. An eco-friendly energy harvesting technology from various sources, such as solar energy, electromagnetic energy and wind energy, has been developed for a self-charging flexible battery. Although the energy harvesting from such sources are often unstable according to the surrounding environment, the energy harvesting from body movements and vibrations has been less affected by the surrounding environment. In this regard, flexible piezoelectric modules are the most attractive solution for this issue, because they convert mechanical energy to electrical energy and harvest energy from the human body motions. Among the various flexible piezoelectric modules, piezoelectric nanofibers have advantages when used as an energy harvester in wearable devices, due to their simple manufacturing process with good applicability to polymers and ceramics. This review focused on diverse flexible piezoelectric nanofibers and discusses their applications as various energy harvesting systems.","PeriodicalId":9738,"journal":{"name":"Ceramist","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79245852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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