首页 > 最新文献

Chemical technology and engineering. Proceedings.2019.№1最新文献

英文 中文
Synthesis and antibacterial activity of novel 3-substituted 1-(2-methyl-5-nitrophenyl)-5-oxopyrrolidine derivatives 新型3-取代1-(2-甲基-5-硝基苯基)-5-氧吡咯烷衍生物的合成及抗菌活性研究
Pub Date : 2019-01-01 DOI: 10.23939/cte2019.01.247
Benas Balandis, K. Anusevičius, V. Mickevičius, M. Stasevych, V. Novikov
– The synthesis of novel azole derivatives has been accomplished during chemical transformations of the 1-(2-methyl-5-nitrophenyl)-5-oxopyrrolidine-3-carbohydrazide. The structure of the synthesized compounds was determined by NMR and IR spectroscopies. Most of the synthesized compounds were screened for their antibacterial activity against S. aureus, L. monocytogenes, E. coli, and P. aeruginosa bacteria strains. was used as a control for S. aureus, E. coli , P. aeruginosa , and L. monocytogenes .
-在1-(2-甲基-5-硝基苯基)-5-氧吡咯烷-3-碳肼的化学转化过程中合成了新的唑衍生物。合成的化合物的结构通过核磁共振和红外光谱进行了表征。大多数合成的化合物对金黄色葡萄球菌、单核增生乳杆菌、大肠杆菌和铜绿假单胞菌的抑菌活性进行了筛选。以金黄色葡萄球菌、大肠杆菌、铜绿假单胞菌和单核细胞增生乳杆菌为对照。
{"title":"Synthesis and antibacterial activity of novel 3-substituted 1-(2-methyl-5-nitrophenyl)-5-oxopyrrolidine derivatives","authors":"Benas Balandis, K. Anusevičius, V. Mickevičius, M. Stasevych, V. Novikov","doi":"10.23939/cte2019.01.247","DOIUrl":"https://doi.org/10.23939/cte2019.01.247","url":null,"abstract":"– The synthesis of novel azole derivatives has been accomplished during chemical transformations of the 1-(2-methyl-5-nitrophenyl)-5-oxopyrrolidine-3-carbohydrazide. The structure of the synthesized compounds was determined by NMR and IR spectroscopies. Most of the synthesized compounds were screened for their antibacterial activity against S. aureus, L. monocytogenes, E. coli, and P. aeruginosa bacteria strains. was used as a control for S. aureus, E. coli , P. aeruginosa , and L. monocytogenes .","PeriodicalId":9818,"journal":{"name":"Chemical technology and engineering. Proceedings.2019.№1","volume":"44 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75691455","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ionic liquids and supercritical carbon dioxide as solvents for NHPI-catalysed oxidation reactions 离子液体和超临界二氧化碳作为nhpi催化氧化反应的溶剂
Pub Date : 2019-01-01 DOI: 10.23939/cte2019.01.269
Beata Orlińska, G. Dobras, Dawid Lisicki
– Studies on the possibility of application of ionic liquids or scCO 2 as solvents in hydrocarbons oxidation with oxygen in the presence of N-hydrophthalimide have been reported. Various alkylaromatics (cumene, ethylbenzene, mono- and diisopropylnaphthalene, mono- and diisopropylbiphenyl) and α-methylstyrene were used as starting materials.
-研究了在n -氢邻苯二胺存在下,离子液体或scCO 2作为碳氢化合物与氧氧化的溶剂的可能性。以各种烷基芳体(异丙烯、乙苯、一异丙基和二异丙基萘、一异丙基和二异丙基联苯)和α-甲基苯乙烯为原料。
{"title":"Ionic liquids and supercritical carbon dioxide as solvents for NHPI-catalysed oxidation reactions","authors":"Beata Orlińska, G. Dobras, Dawid Lisicki","doi":"10.23939/cte2019.01.269","DOIUrl":"https://doi.org/10.23939/cte2019.01.269","url":null,"abstract":"– Studies on the possibility of application of ionic liquids or scCO 2 as solvents in hydrocarbons oxidation with oxygen in the presence of N-hydrophthalimide have been reported. Various alkylaromatics (cumene, ethylbenzene, mono- and diisopropylnaphthalene, mono- and diisopropylbiphenyl) and α-methylstyrene were used as starting materials.","PeriodicalId":9818,"journal":{"name":"Chemical technology and engineering. Proceedings.2019.№1","volume":"21 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72935841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modeling of the Saturation Reactor in the Production of Pumpkin Candied Fruits 饱和反应器在南瓜蜜饯生产中的建模
Pub Date : 2019-01-01 DOI: 10.23939/cte2019.01.202
I. Huzova, V. Atamanyuk
With the help of the universal simulation program ChemСad, an isothermal saturation reactor for sugar pumpkin particles was modeled, which operates under the constant concentration of sucrose in syrup and simultaneously increases the concentration of sucrose in candied fruits. Concentration of sucrose and the level of liquid in the reactor is not changed
借助通用模拟程序ChemСad,对糖南瓜颗粒等温饱和反应器进行了建模,该反应器在糖浆中蔗糖浓度不变的情况下运行,同时提高了蜜饯中蔗糖的浓度。反应器内蔗糖浓度和液面不变
{"title":"Modeling of the Saturation Reactor in the Production of Pumpkin Candied Fruits","authors":"I. Huzova, V. Atamanyuk","doi":"10.23939/cte2019.01.202","DOIUrl":"https://doi.org/10.23939/cte2019.01.202","url":null,"abstract":"With the help of the universal simulation program ChemСad, an isothermal saturation reactor for sugar pumpkin particles was modeled, which operates under the constant concentration of sucrose in syrup and simultaneously increases the concentration of sucrose in candied fruits. Concentration of sucrose and the level of liquid in the reactor is not changed","PeriodicalId":9818,"journal":{"name":"Chemical technology and engineering. Proceedings.2019.№1","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81989135","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Decreasing of the level of ecological pollution at processing of chloral-organic wastes of the production of 1,2-dychloro ethane 降低1,2-二氯乙烷生产中氯-有机废弃物处理的生态污染水平
Pub Date : 2019-01-01 DOI: 10.23939/cte2019.01.414
M. Shpariy, V. Starchevskyy
– one of the main challenges for the Ukrainian industry is adopting of the modern environmental standards of production. One of the most promising ways of reaching of those aims is improvement of existing technological schemes by use of new catalytic systems. At the production of 1,2-dychloro ethane by direct chlorination of ethylene amount of obtained DCE is 98,2-99,4%, and as by-products are created created vinyl chloride, four chloro carbon, 3-chloro ethane, 3-chloro ethylene and others, that after rectification are transferred to the burning stage. During this stage are created products such as chloral hydrogen, that requires additional purification of the burned gases from harmful additives. During ammount this dependence
-乌克兰工业面临的主要挑战之一是采用现代环境生产标准。实现这些目标的最有希望的方法之一是通过使用新的催化系统来改进现有的技术方案。在乙烯直接氯化生产1,2-二氯乙烷时,得到的DCE的量为98.2 - 99.4%,作为副产物产生了氯乙烯、四氯碳、3-氯乙烷、3-氯乙烷等,经精馏后转入燃烧阶段。在这一阶段产生的产品,如氯醛氢,需要额外的净化从有害添加剂燃烧的气体。在数量上,这种依赖性
{"title":"Decreasing of the level of ecological pollution at processing of chloral-organic wastes of the production of 1,2-dychloro ethane","authors":"M. Shpariy, V. Starchevskyy","doi":"10.23939/cte2019.01.414","DOIUrl":"https://doi.org/10.23939/cte2019.01.414","url":null,"abstract":"– one of the main challenges for the Ukrainian industry is adopting of the modern environmental standards of production. One of the most promising ways of reaching of those aims is improvement of existing technological schemes by use of new catalytic systems. At the production of 1,2-dychloro ethane by direct chlorination of ethylene amount of obtained DCE is 98,2-99,4%, and as by-products are created created vinyl chloride, four chloro carbon, 3-chloro ethane, 3-chloro ethylene and others, that after rectification are transferred to the burning stage. During this stage are created products such as chloral hydrogen, that requires additional purification of the burned gases from harmful additives. During ammount this dependence","PeriodicalId":9818,"journal":{"name":"Chemical technology and engineering. Proceedings.2019.№1","volume":"94 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80703458","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The sunflower seeds oil extraction: the mechanism and kinetics of the process 葵花籽油的提取:过程机理及动力学
Pub Date : 2019-01-01 DOI: 10.23939/cte2019.01.100
O. Dobrovetska, Yevgen Semenyshyn, R. Stadnyk, V. Atamanyuk, O. Ivashchuk
The results of the research of extracting oil from sunflower seeds by the method of extraction are given. The kinetics and mechanism of the extraction process investigated. It is shown that the process of extracting sunflower seed oil is complicated and include as intra-diffusion and outer-diffusion oil transfer is similar to extraction of target components from other seeds of plant material (amaranth, rapeseed, etc.). The technique of experimental calculation of the diffusion coefficient is given and the slowest stage of the extraction process is determined, which determines the speed of the whole process. Кеуwords – extraction, plant raw materials, mechanism and kinetics of process. Introduction The extraction process of target components from plant raw materials is widely used in various industries, especially in food, pharmaceutical, chemical, petroleum, and others. The large demand to agrarian business in Ukraine is a sunflower, which, depending on the natural environment, contains up to 60% of the oil. Sunflower is a base of the agricultural crop because it contains, in addition to oils, protein and other target components which used in the pharmaceutical, chemical, perfumery, and other industries. It should be emphasized that Ukraine exports sunflower oil to over than 100 countries of the world, which requires more efficient technologies for its production for the purpose of providing with world demand. For today, there are two methods of extracting oil plant raw materials: press and extraction. The advantage of the extraction method is the high degree of oil extraction of 97-98 %, the use of simple equipment and lower energy consumption, compared with the previous method. The process of extracting the target components from plant raw materials is rather complicated. The complexity of this process is related to the cellular structure of the raw material and the presence of a poorly-permeable shell in the seeds of plants, and also in that, the target component moving within the seed to the surface of the phase contact with the solvent must overcome a number of barriers associated with the complex structure of the seed. The entire process should be considered as intra-diffusion, outer-diffusion and mixed since diffusion is the basis of these processes. For study and the establishment of a mechanism for the extraction oil process of sunflower seed is used the equation obtained by the method of integral ratios for the extraction processes of the target components from the plant raw material [1-2]. For a mathematical description of the extraction process adopted the physical model of seed in the form of a ball in the pores of which is the target component, has the form:     3 0 0 3 0 2 0 1 3 1 1 3 2 6 1                 Bi (1) For the mixed-diffusion mechanism ( ) the equation (1) is reduced to the form:
给出了用萃取法从葵花籽中提取油脂的研究结果。研究了萃取过程的动力学和机理。结果表明,葵花籽油的提取过程较为复杂,与其他植物原料(苋菜、菜籽等)种子中目标成分的提取过程类似,包括内扩散和外扩散油转移。给出了扩散系数的实验计算方法,确定了萃取过程的最慢阶段,从而决定了整个萃取过程的速度。Кеуwords -萃取,植物原料,过程机理及动力学。从植物原料中提取目标成分的工艺广泛应用于各个行业,特别是食品、制药、化工、石油等行业。乌克兰农业企业的主要需求是向日葵,根据自然环境,向日葵含有高达60%的油。向日葵是农作物的基础,因为它除了含有油脂之外,还含有蛋白质和其他用于制药、化学、香水和其他工业的目标成分。应该强调的是,乌克兰向世界上100多个国家出口葵花籽油,为了满足世界需求,生产葵花籽油需要更有效的技术。目前,提取油料植物原料的方法有两种:压榨和提取。该提取方法的优点是与以前的方法相比,油的提取率高达97- 98%,设备使用简单,能耗更低。从植物原料中提取目标成分的过程比较复杂。这一过程的复杂性与原料的细胞结构和植物种子中存在的渗透性差的壳有关,而且,在种子内移动到与溶剂接触的相表面的目标组分必须克服与种子复杂结构相关的许多障碍。整个过程可以分为内扩散、外扩散和混合,因为扩散是这些过程的基础。为了研究和建立葵花籽的提油过程机理,采用植物原料中目标组分提取过程的积分比值法得到的方程[1-2]。提取过程的数学描述的物理模型采用种子的形式一个球的毛孔目标组件,具有形式:3 0 0 3 0 2 0 1 1 1 3 2 6 1Bi (1) mixed-diffusion机制()的方程(1)是减少形式:
{"title":"The sunflower seeds oil extraction: the mechanism and kinetics of the process","authors":"O. Dobrovetska, Yevgen Semenyshyn, R. Stadnyk, V. Atamanyuk, O. Ivashchuk","doi":"10.23939/cte2019.01.100","DOIUrl":"https://doi.org/10.23939/cte2019.01.100","url":null,"abstract":"The results of the research of extracting oil from sunflower seeds by the method of extraction are given. The kinetics and mechanism of the extraction process investigated. It is shown that the process of extracting sunflower seed oil is complicated and include as intra-diffusion and outer-diffusion oil transfer is similar to extraction of target components from other seeds of plant material (amaranth, rapeseed, etc.). The technique of experimental calculation of the diffusion coefficient is given and the slowest stage of the extraction process is determined, which determines the speed of the whole process. Кеуwords – extraction, plant raw materials, mechanism and kinetics of process. Introduction The extraction process of target components from plant raw materials is widely used in various industries, especially in food, pharmaceutical, chemical, petroleum, and others. The large demand to agrarian business in Ukraine is a sunflower, which, depending on the natural environment, contains up to 60% of the oil. Sunflower is a base of the agricultural crop because it contains, in addition to oils, protein and other target components which used in the pharmaceutical, chemical, perfumery, and other industries. It should be emphasized that Ukraine exports sunflower oil to over than 100 countries of the world, which requires more efficient technologies for its production for the purpose of providing with world demand. For today, there are two methods of extracting oil plant raw materials: press and extraction. The advantage of the extraction method is the high degree of oil extraction of 97-98 %, the use of simple equipment and lower energy consumption, compared with the previous method. The process of extracting the target components from plant raw materials is rather complicated. The complexity of this process is related to the cellular structure of the raw material and the presence of a poorly-permeable shell in the seeds of plants, and also in that, the target component moving within the seed to the surface of the phase contact with the solvent must overcome a number of barriers associated with the complex structure of the seed. The entire process should be considered as intra-diffusion, outer-diffusion and mixed since diffusion is the basis of these processes. For study and the establishment of a mechanism for the extraction oil process of sunflower seed is used the equation obtained by the method of integral ratios for the extraction processes of the target components from the plant raw material [1-2]. For a mathematical description of the extraction process adopted the physical model of seed in the form of a ball in the pores of which is the target component, has the form:     3 0 0 3 0 2 0 1 3 1 1 3 2 6 1                 Bi (1) For the mixed-diffusion mechanism ( ) the equation (1) is reduced to the form:","PeriodicalId":9818,"journal":{"name":"Chemical technology and engineering. Proceedings.2019.№1","volume":"90 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83072274","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Changes in plant material when drying according to IR spectroscopy 根据红外光谱分析,干燥时植物材料的变化
Pub Date : 2019-01-01 DOI: 10.23939/cte2019.01.227
N. Dmytrenko, S. Vdovenko
Infrared spectroscopy of parenchymal tissues of apples subjected to heat drying has shown an increase in the structural hardness of carbohydrates in the removal of water hydrated by them and a gradual violation of the structure of proteins under the influence of heat and dehydration.
热干燥苹果实质组织的红外光谱分析表明,碳水化合物的水合作用使碳水化合物的结构硬度增加,蛋白质的结构在热和脱水作用下逐渐被破坏。
{"title":"Changes in plant material when drying according to IR spectroscopy","authors":"N. Dmytrenko, S. Vdovenko","doi":"10.23939/cte2019.01.227","DOIUrl":"https://doi.org/10.23939/cte2019.01.227","url":null,"abstract":"Infrared spectroscopy of parenchymal tissues of apples subjected to heat drying has shown an increase in the structural hardness of carbohydrates in the removal of water hydrated by them and a gradual violation of the structure of proteins under the influence of heat and dehydration.","PeriodicalId":9818,"journal":{"name":"Chemical technology and engineering. Proceedings.2019.№1","volume":"12 Suppl 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89846369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Foam layered apparatus with foam stabilization 具有泡沫稳定的泡沫分层装置
Pub Date : 2019-01-01 DOI: 10.23939/cte2019.01.072
А. Liaposhchenko, О. Khukhryanskiy, V. Moiseev, Е. Manoilo
In work were studied the expanded models of foaming apparatuses with gratings, made of tubes of different diameters. The questions of intensification of foam devices with the use of coarsegrating lattices are considered. The possibility of deep cleaning and practically complete cleaning of gases from ammonia and fluoride compounds with their separate absorption is noted. Кеуwords – industrial gas emissions; cleaning process; hydrodynamics, mass transfer; foam apparatus; foam layer, research of purification processes; stabilization of foam layer; intensive apparatus
在工作中,研究了由不同直径的管制成的带光栅的发泡装置的扩展模型。讨论了用粗分块格对泡沫装置进行强化的问题。指出了深层清洗和实际上完全清洗氨和氟化物化合物产生的气体并使其单独吸收的可能性。Кеуwords -工业气体排放;清洗过程;流体力学,传质;泡沫装置;泡沫层,净化工艺研究;泡沫层稳定化;密集的装置
{"title":"Foam layered apparatus with foam stabilization","authors":"А. Liaposhchenko, О. Khukhryanskiy, V. Moiseev, Е. Manoilo","doi":"10.23939/cte2019.01.072","DOIUrl":"https://doi.org/10.23939/cte2019.01.072","url":null,"abstract":"In work were studied the expanded models of foaming apparatuses with gratings, made of tubes of different diameters. The questions of intensification of foam devices with the use of coarsegrating lattices are considered. The possibility of deep cleaning and practically complete cleaning of gases from ammonia and fluoride compounds with their separate absorption is noted. Кеуwords – industrial gas emissions; cleaning process; hydrodynamics, mass transfer; foam apparatus; foam layer, research of purification processes; stabilization of foam layer; intensive apparatus","PeriodicalId":9818,"journal":{"name":"Chemical technology and engineering. Proceedings.2019.№1","volume":"23 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88317171","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research of the rheological properties of the gel based on sodium alginate for the local treatment of burns 局部烧伤用海藻酸钠凝胶的流变性能研究
Pub Date : 2019-01-01 DOI: 10.23939/cte2019.01.232
B. Vons, Y. Melnyk, V. Skorokhoda, Taras Grochovuy, Marjana Сhubka
– gels are the most common dosage form for the local treatment of burns, which are safe and easy to use. Important gel parameters are rheological characteristics, such as shear stress, dynamic viscosity, mechanical stability that can predict the behavior of the environment in technological processes, and they are important for the creation of new and improved existing drugs.
-凝胶是局部治疗烧伤最常用的剂型,安全、使用方便。重要的凝胶参数是流变特性,如剪切应力、动态粘度、机械稳定性,它们可以预测技术过程中环境的行为,它们对于创造新的和改进现有药物非常重要。
{"title":"Research of the rheological properties of the gel based on sodium alginate for the local treatment of burns","authors":"B. Vons, Y. Melnyk, V. Skorokhoda, Taras Grochovuy, Marjana Сhubka","doi":"10.23939/cte2019.01.232","DOIUrl":"https://doi.org/10.23939/cte2019.01.232","url":null,"abstract":"– gels are the most common dosage form for the local treatment of burns, which are safe and easy to use. Important gel parameters are rheological characteristics, such as shear stress, dynamic viscosity, mechanical stability that can predict the behavior of the environment in technological processes, and they are important for the creation of new and improved existing drugs.","PeriodicalId":9818,"journal":{"name":"Chemical technology and engineering. Proceedings.2019.№1","volume":"2174 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91383547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Microwave Vacuum Extraction for Rosehips Polyextracts 微波真空提取玫瑰果多提取物的研究
Pub Date : 2019-01-01 DOI: 10.23939/cte2019.01.191
Levtrynska Yuliya, Terziev Sergey, Golinskaya Yana
Extraction in microwave field in vacuum is investigated in paper. Decrease in pressure and influence of microwaves on intensification of extraction of waterand liposoluble components. Use of water extractant instead of two-phase solvent systems simplifies technological process for production of polyextracts. Кеуwords – extraction, microwave assisted extraction, vacum, polyextracts, carotolin, rose hips. Introduction Rosehips are valuable raw materials for the production of phytopreparations and health food products. 100 grams of ripe cinnamon rose (Rosa cinnamomea L.) hip fruits contains about 2400 mg of vitamin C and carotenoids, causing bright coloration. Today, modern technologies of rosehips processing are divided into several basic stages, which include water extraction of fruits for preparation of ascorbic acid products in the Hezenko diffusers, and extraction with organic solvents of rosehip seeds and skin to obtain carotenoid preparations (carotolin) and rose oil (vitamin E). To extract liposoluble carotenoids organic solvents are used. Technology of obtaining polystracts with the two-phase systems of extractants, proposed by Kogan G.Ya., allowed to receive a convenient medical form combining water-soluble and liposoluble components [2]. The school of microwave extraction is developing in the Odessa National Academy of Food Technologies scientific school by professor O. Burdo`s group [3]. Barodiffusion effect occurring during impact of microwave field is investigated. Intensification of the process is achieved by boiling extractant in the capillaries of plant material, which forming steam bubbles, pushing the flow of components to the extract. Combined with the soluble components, water-insoluble components can also pass into the extract, for example: carotenoids. Consequently, there is a possibility of obtaining polystracts in devices with water solvent. Research results For the experimental researches hip fruits of cinnamon rose (Rosa cinnamomea L.), produced by "Lubnifarm" company, with humidity of 15% are selected. Extraction carried out with water solvent (distilled water). The temperature was determined by the GM320 radiation pyrometer. The measuring range is 0 ... 330 ° C, with an error of ± 1.5 ° C. Measurement accuracy (scale interval) is 0.1 ° C. Amperage, voltage and field intensity indicators were determined using the KSP-50 measuring complex. Digital portable refractometer HI 96801, “Hanna Instruments”, were used to determine concentration of the extract. Measuring range: 0 ... 85 ° brix. Accuracy: ± 0.2 ° brix. To determine the amount of vitamin C in the extract, the Thilmans titration method were used. Extraction is carried out in a dilution installation. Main components of the extractor are: magnetron, extraction chamber, condenser, water cooler, vacuum pump. Before the experiment rarefaction is formed in the extraction chamber with a vacuum pump. During the experiment, pressure in the extraction chamber was stabilized by
本文对真空微波场萃取进行了研究。降低压力和微波对水和脂溶性成分提取强化的影响。采用水萃取剂代替两相溶剂系统,简化了生产多提取物的工艺过程。Кеуwords -萃取,微波辅助萃取,真空萃取,多提取物,胡萝卜素,玫瑰果。玫瑰果是生产植物修复剂和保健食品的重要原料。100克成熟的肉桂玫瑰(Rosa cinnamomea L.)果实含有约2400毫克的维生素C和类胡萝卜素,颜色鲜艳。今天,现代玫瑰果加工技术分为几个基本阶段,其中包括在Hezenko扩散器中制备抗坏血酸产品的水果水提取,以及用有机溶剂提取玫瑰果种子和皮肤以获得类胡萝卜素制剂(胡萝卜素)和玫瑰油(维生素E)。提取脂溶性类胡萝卜素使用有机溶剂。Kogan G.Ya提出的萃取剂两相体系制备多抽提物的技术。,可以获得水溶性和脂溶性成分结合的方便的医疗形式[2]。微波萃取学校是由O. Burdo教授的小组在敖德萨国家食品技术学院科学学校发展起来的[3]。研究了微波场冲击过程中的气压扩散效应。该过程的强化是通过在植物材料的毛细血管中沸腾萃取剂来实现的,这些萃取剂形成蒸汽泡,推动组分流向萃取物。与可溶性成分结合,水不溶性成分也可以进入提取物,例如:类胡萝卜素。因此,有可能在具有水溶剂的装置中获得多聚物。实验研究选用Lubnifarm公司生产的肉桂玫瑰(Rosa cinnamomea L.)果实,湿度为15%。用水溶剂(蒸馏水)进行萃取。温度由GM320辐射高温计测定。测量范围为0…测量精度(刻度间隔)为0.1°C。安培、电压和场强指标采用KSP-50测量复合物测定。采用汉纳仪器(Hanna Instruments)的HI 96801型数字便携式折光仪测定提取物的浓度。测量范围:0…85°白锐度。精度:±0.2°白度。采用Thilmans滴定法测定提取物中维生素C的含量。萃取在稀释装置中进行。萃取器的主要部件有:磁控管、萃取室、冷凝器、水冷器、真空泵。实验前用真空泵在抽气室内形成稀薄。在实验过程中,通过调节供给的电磁能和排热系统的功率来稳定萃取室的压力。反制冷机用于冷凝蒸发的溶剂。真空微波萃取器的温度状态为
{"title":"Microwave Vacuum Extraction for Rosehips Polyextracts","authors":"Levtrynska Yuliya, Terziev Sergey, Golinskaya Yana","doi":"10.23939/cte2019.01.191","DOIUrl":"https://doi.org/10.23939/cte2019.01.191","url":null,"abstract":"Extraction in microwave field in vacuum is investigated in paper. Decrease in pressure and influence of microwaves on intensification of extraction of waterand liposoluble components. Use of water extractant instead of two-phase solvent systems simplifies technological process for production of polyextracts. Кеуwords – extraction, microwave assisted extraction, vacum, polyextracts, carotolin, rose hips. Introduction Rosehips are valuable raw materials for the production of phytopreparations and health food products. 100 grams of ripe cinnamon rose (Rosa cinnamomea L.) hip fruits contains about 2400 mg of vitamin C and carotenoids, causing bright coloration. Today, modern technologies of rosehips processing are divided into several basic stages, which include water extraction of fruits for preparation of ascorbic acid products in the Hezenko diffusers, and extraction with organic solvents of rosehip seeds and skin to obtain carotenoid preparations (carotolin) and rose oil (vitamin E). To extract liposoluble carotenoids organic solvents are used. Technology of obtaining polystracts with the two-phase systems of extractants, proposed by Kogan G.Ya., allowed to receive a convenient medical form combining water-soluble and liposoluble components [2]. The school of microwave extraction is developing in the Odessa National Academy of Food Technologies scientific school by professor O. Burdo`s group [3]. Barodiffusion effect occurring during impact of microwave field is investigated. Intensification of the process is achieved by boiling extractant in the capillaries of plant material, which forming steam bubbles, pushing the flow of components to the extract. Combined with the soluble components, water-insoluble components can also pass into the extract, for example: carotenoids. Consequently, there is a possibility of obtaining polystracts in devices with water solvent. Research results For the experimental researches hip fruits of cinnamon rose (Rosa cinnamomea L.), produced by \"Lubnifarm\" company, with humidity of 15% are selected. Extraction carried out with water solvent (distilled water). The temperature was determined by the GM320 radiation pyrometer. The measuring range is 0 ... 330 ° C, with an error of ± 1.5 ° C. Measurement accuracy (scale interval) is 0.1 ° C. Amperage, voltage and field intensity indicators were determined using the KSP-50 measuring complex. Digital portable refractometer HI 96801, “Hanna Instruments”, were used to determine concentration of the extract. Measuring range: 0 ... 85 ° brix. Accuracy: ± 0.2 ° brix. To determine the amount of vitamin C in the extract, the Thilmans titration method were used. Extraction is carried out in a dilution installation. Main components of the extractor are: magnetron, extraction chamber, condenser, water cooler, vacuum pump. Before the experiment rarefaction is formed in the extraction chamber with a vacuum pump. During the experiment, pressure in the extraction chamber was stabilized by ","PeriodicalId":9818,"journal":{"name":"Chemical technology and engineering. Proceedings.2019.№1","volume":"54 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90656423","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mathematical modeling of the dynamics of heat and mass transfer, phase transformations and thermal decomposition at high temperature drying of biomass 生物质高温干燥过程中传热传质、相变和热分解动力学的数学建模
Pub Date : 2019-01-01 DOI: 10.23939/cte2019.01.299
Natalia Sorokova, D. Korinchuk
A mathematical model and method for calculating heat and mass transfer, phase transformations and shrinkage during drying of colloidal porous bodies in the form of a final cylinder are presented. A mathematical simulation of high-temperature drying of willow accompanied by the destruction of hemicellulose was carried out using the data obtained on the values of the activation energy of various types of biomass.
本文提出了一种计算胶状多孔体干燥过程中传热传质、相变和收缩率的数学模型和方法。利用不同类型生物质的活化能数据,对柳树高温干燥过程中半纤维素的破坏进行了数学模拟。
{"title":"Mathematical modeling of the dynamics of heat and mass transfer, phase transformations and thermal decomposition at high temperature drying of biomass","authors":"Natalia Sorokova, D. Korinchuk","doi":"10.23939/cte2019.01.299","DOIUrl":"https://doi.org/10.23939/cte2019.01.299","url":null,"abstract":"A mathematical model and method for calculating heat and mass transfer, phase transformations and shrinkage during drying of colloidal porous bodies in the form of a final cylinder are presented. A mathematical simulation of high-temperature drying of willow accompanied by the destruction of hemicellulose was carried out using the data obtained on the values of the activation energy of various types of biomass.","PeriodicalId":9818,"journal":{"name":"Chemical technology and engineering. Proceedings.2019.№1","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89327291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Chemical technology and engineering. Proceedings.2019.№1
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1