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ChemInform Abstract: Palladium-Catalyzed Regioselective Direct Cyanation of Acetanilide Derivatives with K4[Fe(CN)6] by C—H Bond Activation. 摘要钯催化K4[Fe(CN)6]区域选择性直接氰化乙酰苯胺衍生物的C-H键活化。
Pub Date : 2016-12-06 DOI: 10.1002/chin.201652152
Ebrahim Kianmehr, Nasser Faghih, Arezoo Tanbakouchian, Mohammad Mahdavi

The high-yielding method has a good functional group tolerance.

高产方法具有良好的官能团耐受性。
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引用次数: 9
ChemInform Abstract: B(C6F5)3 Catalyzed 1,6-Conjugate Allylation of para-Quinone Methides: Expedient Access to Allyl Diarylmethanes. 摘要:B(C6F5)3催化1,6-共轭对苯二酚烯丙基化:烯丙基二乙基甲烷的便捷途径。
Pub Date : 2016-12-06 DOI: 10.1002/chin.201652173
Sriram Mahesh, Guddi Kant, Ramasamy Vijaya Anand
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引用次数: 0
ChemInform Abstract: An Efficient Solvent-Free Synthesis of Isoxazolyl-1,4-dihydropyridines on Solid Support SiO2 under Microwave Irradiation. 摘要:微波辐射下固体载体SiO2上高效无溶剂合成异恶唑-1,4-二氢吡啶。
Pub Date : 2016-12-06 DOI: 10.1002/chin.201652294
Dawei Zhang, Xiaodong Chen, Xue Guo, Yumin Zhang, Yaya Hou, Tianqi Zhao, Qiang Gu

via a multicomponent reaction strategy

通过多组分反应策略
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引用次数: 1
ChemInform Abstract: Palladium—Copper Catalyzed C(sp3)—C(sp2) Bond C—H Activation Cross-Coupling Reaction: Selective Arylation to Synthesize 9-Aryl-9H-xanthene and 9,9-Diaryl-xanthene Derivatives. 摘要钯铜催化C(sp3) -C (sp2)键C - h活化交叉偶联反应:选择性芳基化合成9-芳基- 9h -杂蒽和9,9-二芳基-杂蒽衍生物。
Pub Date : 2016-12-06 DOI: 10.1002/chin.201652292
Guodong Shen, Lingyu Zhao, Yichen Wang, Wenfang Xia, Mingsen Yang, Tongxin Zhang

The Pd/Cu-catalyzed reaction of xanthenes (I) with arenes (II) gives rise to 9-aryl-9H-xanthenes (III) or 9,9-diaryl-xanthenes (VI) depending on the reaction time and temperature.

在Pd/ cu催化下,黄原烯(I)与芳烃(II)的反应取决于反应时间和温度,生成9-芳基- 9h -黄原烯(III)或9,9-二芳基黄原烯(VI)。
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引用次数: 0
ChemInform Abstract: Synthesis of a Novel Magnetic Reusable Organocatalyst Based on 4-Dialkylaminopyridines for Acyl Transformations. 摘要:基于4-二烷基氨基吡啶的新型磁性可重复使用有机催化剂的合成及其在酰基转化中的应用。
Pub Date : 2016-12-06 DOI: 10.1002/chin.201652035
Farhad Panahi, Soheila Khajeh Dangolani, Ali Khalafi-Nezhad

A newly synthesized magnetic nanoparticles-supported 4-(dimethylamino)pyridine (DMAP)-based catalyst is used as a robust heterogeneous organocatalyst in organic transformations as the acylation of hydroxyl and amino functionalized substrates under mild and solvent-free conditions.

新合成的磁性纳米颗粒负载的4-(二甲胺)吡啶(DMAP)基催化剂是一种强大的非均相有机催化剂,用于在温和和无溶剂的条件下进行羟基和氨基功能化底物的酰化。
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引用次数: 1
ChemInform Abstract: Bi(OTf)3-Catalyzed Addition of Isocyanides to 2H-Chromene Acetals: An Efficient Pathway for Accessing 2-Carboxamide-2H-chromenes. 摘要:Bi(OTf)3催化异氰酸酯加成2h -铬缩醛:获得2-羧胺- 2h -铬的有效途径。
Pub Date : 2016-12-06 DOI: 10.1002/chin.201652288
Longyun Lyu, Ming Yu Jin, Qijie He, Han Xie, Zhaoxiang Bian, Jun Wang

An efficient Bi(OTf)3-catalyzed addition reaction for accessing 2H-chromene-2-carboxamide derivatives is reported.

报道了一种高效的Bi(OTf)3催化加成反应制备2h -铬-2-羧酰胺衍生物。
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引用次数: 0
ChemInform Abstract: Stachartins A—E, Phenylspirodrimanes from the Tin Mine Tailings-Associated Fungus Stachybotrys chartarum. 摘要锡矿尾矿伴生真菌Stachybotrys chartarum中的stachartin A-E、Phenylspirodrimanes。
Pub Date : 2016-12-06 DOI: 10.1002/chin.201652386
Wei-Xun Chunyu, Zhang-Gui Ding, Ming-Gang Li, Jiang-Yuan Zhao, Shao-Jie Gu, Yuan Gao, Fei Wang, Jian-Hai Ding, Meng-Liang Wen

isolation and structure elucidation

分离和结构解析
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引用次数: 1
ChemInform Abstract: One-Pot Synthesis of 2-Cyano-1,4-diketones: Applications to Synthesis of Cyanosubstituted Furans, Pyrroles, and Dihydropyridazines. 摘要:一锅法合成2-氰基1,4-二酮:在氰基取代呋喃、吡咯和二氢吡啶合成中的应用。
Pub Date : 2016-12-06 DOI: 10.1002/chin.201652105
Chieh-Kai Chan, Yi-Ling Chan, Yu-Lin Tsai, Meng-Yang Chang
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引用次数: 0
ChemInform Abstract: Cyclic-Protected Hexafluoroacetone as an Air-Stable Liquid Reagent for Trifluoromethylations. 摘要:环保护六氟丙酮作为空气稳定的三氟甲基化液体试剂。
Pub Date : 2016-12-06 DOI: 10.1002/chin.201652069
Kazuyuki Negishi, Kohsuke Aikawa, Koichi Mikami

The title reagent is synthesized from gaseous hexafluoroacetone and (L)-methylproline on a gram scale.

标题试剂是由气态六氟丙酮和(L)-甲基脯氨酸按克合成的。
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引用次数: 0
ChemInform Abstract: Sonication-Assisted Synthesis of (E)-2-Methyl-but-2-enyl Nucleoside Phosphonate Prodrugs. 摘要:超声辅助合成(E)-2-甲基-丁-2-烯基磷酸核苷前药。
Pub Date : 2016-12-06 DOI: 10.1002/chin.201652412
Maxime Bessieres, Ozkan Sari, Vincent Roy, Dawid Warszycki, Andrzej J. Bojarski, Steven P. Nolan, Robert Snoeck, Graciela Andrei, Raymond F. Schinazi, Luigi A. Agrofoglio
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引用次数: 0
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