Pub Date : 2025-04-15DOI: 10.1134/S1061934824701521
Mayuri S. Kulkarni, Ashok V. Borhade, Prajkta Y. Pachorkar, Ankita M. Rayate
A novel naphthalene-based Schiff base ligand (SBL) was synthesized by the condensation of naphthalene-1-8-diamine with 4-dimethylaminobenzaldehyde as a colorimetric probe for the selective detection of Fe3+ ions in ethanol solution. The UV-Vis spectroscopic technique was employed to study the sensing ability of the probe SBL for Fe3+ ions, which was monitored in ethanol solution (pH 4). The Job’s plot confirmed a 1 : 1 molar complex formation between SBL and Fe3+. Density functional theory computations also supported the binding framework between SBL and Fe3+. The limit of detection for Fe3+ is 6 × 10–6 M, and the limit of quantification is 2 × 10–5 M. The binding constant, evaluated using the Benesi–Hildebrand method, is 6.9 × 104 M. Cyclic voltammetry study shows that there is no change in the electrochemical structure of SBL after complex formation with Fe3+.
{"title":"A Colorimetric Detection Probe for Iron(III) with a Naphthalene-Based Schiff Base","authors":"Mayuri S. Kulkarni, Ashok V. Borhade, Prajkta Y. Pachorkar, Ankita M. Rayate","doi":"10.1134/S1061934824701521","DOIUrl":"10.1134/S1061934824701521","url":null,"abstract":"<p>A novel naphthalene-based Schiff base ligand (<b>SBL</b>) was synthesized by the condensation of naphthalene-1-8-diamine with 4-dimethylaminobenzaldehyde as a colorimetric probe for the selective detection of Fe<sup>3+</sup> ions in ethanol solution. The UV-Vis spectroscopic technique was employed to study the sensing ability of the probe SBL for Fe<sup>3+</sup> ions, which was monitored in ethanol solution (pH 4). The Job’s plot confirmed a 1 : 1 molar complex formation between SBL and Fe<sup>3+</sup>. Density functional theory computations also supported the binding framework between SBL and Fe<sup>3+</sup>. The limit of detection for Fe<sup>3+</sup> is 6 × 10<sup>–6</sup> M, and the limit of quantification is 2 × 10<sup>–5</sup> M. The binding constant, evaluated using the Benesi–Hildebrand method, is 6.9 × 10<sup>4</sup> M. Cyclic voltammetry study shows that there is no change in the electrochemical structure of SBL after complex formation with Fe<sup>3+</sup>.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"50 - 60"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-15DOI: 10.1134/S1061934824701624
Manali Nimse, Saira Mulla
The principal aim of this investigation is to improve the precision and accuracy of quantifying sugars, such as glucose, sucrose, and fructose, through the utilization of hydrophilic interaction liquid chromatography (HILIC) with charged aerosol detection (CAD) in Pueraria tuberosa, a plant renowned for its pharmacological properties. Refractive index detectors are commonly employed to determine sugars in plant extracts. However, it is important to note that these detectors suffer from poor sensitivity and are prone to interference from co-eluting components. Therefore, alternative methods need to be explored to overcome these limitations. HPLC-CAD offers a promising solution by providing improved sensitivity, enhanced precision, and reduced interference from co-eluting sample components. Optimal separation of substances was achieved by implementing an Inertsil HILIC column (250 × 4.6 mm, 5 μm). The mobile phase consisted of 0.1% trifluoroacetic acid in acetonitrile and 0.1% trifluoroacetic acid in water. The flow rate was set at 0.8 mL/min. By employing a systematic approach to modify the chromatographic conditions, this study has successfully improved the sensitivity, resolution, and reliability of sugar determination.
{"title":"Determination of Nourishing Saccharides in Pueraria tuberosa through the Application of an Analytically Validated Method of Hydrophilic Interaction Liquid Chromatography with Charged Aerosol Detection","authors":"Manali Nimse, Saira Mulla","doi":"10.1134/S1061934824701624","DOIUrl":"10.1134/S1061934824701624","url":null,"abstract":"<p>The principal aim of this investigation is to improve the precision and accuracy of quantifying sugars, such as glucose, sucrose, and fructose, through the utilization of hydrophilic interaction liquid chromatography (<b>HILIC</b>) with charged aerosol detection (<b>CAD</b>) in <i>Pueraria tuberosa</i>, a plant renowned for its pharmacological properties. Refractive index detectors are commonly employed to determine sugars in plant extracts. However, it is important to note that these detectors suffer from poor sensitivity and are prone to interference from co-eluting components. Therefore, alternative methods need to be explored to overcome these limitations. HPLC-CAD offers a promising solution by providing improved sensitivity, enhanced precision, and reduced interference from co-eluting sample components. Optimal separation of substances was achieved by implementing an Inertsil HILIC column (250 × 4.6 mm, 5 μm). The mobile phase consisted of 0.1% trifluoroacetic acid in acetonitrile and 0.1% trifluoroacetic acid in water. The flow rate was set at 0.8 mL/min. By employing a systematic approach to modify the chromatographic conditions, this study has successfully improved the sensitivity, resolution, and reliability of sugar determination.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"148 - 153"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-15DOI: 10.1134/S1061934824701533
V. G. Amelin, O. E. Emel’yanov
The non-destructive control of levofloxacin, non-steroidal anti-inflammatory drugs, acetylsalicylic acid, and vinpocetine in medicines by their intrinsic fluorescence and diffuse reflectance of near-IR radiation using a smartphone and a 3D-printed device is proposed. Blister packs and tablet shells slightly reduce the intensity of the diffuse reflectance signal at a wavelength of 850 nm and fluorescence due to UV irradiation (390 nm), which is confirmed by a comparative analysis of the results of colorimetric measurement in samples of medicines in blister packs, without packs, and on a tablet split. A correlation is observed between the analytical signal and the mass of the active substance regardless of the study version. The data array was processed using principal component analysis (PCA), hierarchical cluster analysis (HCA), and partial least squares (PLS) regression methods using the PhotoMetrix PRO® smartphone software. It was shown that these algorithms can be used to identify drugs by their manufacturer and to determine the mass of active substances in tablets. Colorimetric signals from tablets from one manufacturer form separate clusters on dendrograms created using the HCA algorithm. The data obtained using PCA indicate the location of signals from tablets from different manufacturers in separate quadrants, which facilitates the identification of a pharmaceutical company. The use of chemometric analysis methods for determining the mass of the active substance in tablets is considered. The relative standard deviation of the analysis results does not exceed 0.04. The relative error of the analysis results does not exceed the recommended values for the preparation of medicines according to the Order of the Ministry of Health of the Russian Federation dated October 26, 2015 No. 751n.
{"title":"Nondestructive Control of Medicines by a Colormetric Method Using a Smartphone and the PhotoMetrix PRO® Application","authors":"V. G. Amelin, O. E. Emel’yanov","doi":"10.1134/S1061934824701533","DOIUrl":"10.1134/S1061934824701533","url":null,"abstract":"<p>The non-destructive control of levofloxacin, non-steroidal anti-inflammatory drugs, acetylsalicylic acid, and vinpocetine in medicines by their intrinsic fluorescence and diffuse reflectance of near-IR radiation using a smartphone and a 3D-printed device is proposed. Blister packs and tablet shells slightly reduce the intensity of the diffuse reflectance signal at a wavelength of 850 nm and fluorescence due to UV irradiation (390 nm), which is confirmed by a comparative analysis of the results of colorimetric measurement in samples of medicines in blister packs, without packs, and on a tablet split. A correlation is observed between the analytical signal and the mass of the active substance regardless of the study version. The data array was processed using principal component analysis (PCA), hierarchical cluster analysis (HCA), and partial least squares (PLS) regression methods using the PhotoMetrix PRO<sup>®</sup> smartphone software. It was shown that these algorithms can be used to identify drugs by their manufacturer and to determine the mass of active substances in tablets. Colorimetric signals from tablets from one manufacturer form separate clusters on dendrograms created using the HCA algorithm. The data obtained using PCA indicate the location of signals from tablets from different manufacturers in separate quadrants, which facilitates the identification of a pharmaceutical company. The use of chemometric analysis methods for determining the mass of the active substance in tablets is considered. The relative standard deviation of the analysis results does not exceed 0.04. The relative error of the analysis results does not exceed the recommended values for the preparation of medicines according to the Order of the Ministry of Health of the Russian Federation dated October 26, 2015 No. 751n.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"61 - 69"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-15DOI: 10.1186/s12302-025-01094-w
Phillip J. Haubrock, Ismael Soto, Carlos Cano-Barbacil, Kathrin Theissinger, Catalina Rios-Henriquez, Ben Parker, Guntram Weithoff, Elizabeta Briski
Background
The introduction of non-native species can cause significant ecological and economic impacts by disrupting local habitats and ecosystem services. Due to its central European location and extensive trade networks, Germany is particularly susceptible to the introduction and spread of non-native species. Here, we compiled the first comprehensive list of established non-native species in Germany, detailing the invaded environments, native regions, and documented impacts.
Results
The final list included 1962 established non-native species from 594 families and 35 phyla, with Tracheophyta (n = 839), Arthropoda (n = 612), and Chordata (n = 129) being the most represented. Most of these species were terrestrial (79.3%), followed by semi-aquatic (8.4%), with less than 5% occupying freshwaters and other ecosystems. This study highlights a significant lack of information on the impacts of non-native species in Germany, with 97.9% of species having unknown effects. The greatest number of species included in this list were native to the Palearctic region (n = 813), followed by the Nearctic (n = 365) and Neotropic (n = 127) regions. However, many species were of unknown origin (n = 335), with a smaller subset classified as widespread (n = 166).
Conclusions
This first comprehensive list of established non-native species is essential for guiding management strategies in Germany. By cataloguing established non-native species and their impacts, it provides policymakers and stakeholders with a clearer understanding of which species are present, their patterns of spread, and their potential impacts, enabling them to prioritise management efforts for the most harmful species.
{"title":"Germany’s established non-native species: a comprehensive breakdown","authors":"Phillip J. Haubrock, Ismael Soto, Carlos Cano-Barbacil, Kathrin Theissinger, Catalina Rios-Henriquez, Ben Parker, Guntram Weithoff, Elizabeta Briski","doi":"10.1186/s12302-025-01094-w","DOIUrl":"10.1186/s12302-025-01094-w","url":null,"abstract":"<div><h3>Background</h3><p>The introduction of non-native species can cause significant ecological and economic impacts by disrupting local habitats and ecosystem services. Due to its central European location and extensive trade networks, Germany is particularly susceptible to the introduction and spread of non-native species. Here, we compiled the first comprehensive list of established non-native species in Germany, detailing the invaded environments, native regions, and documented impacts.</p><h3>Results</h3><p>The final list included 1962 established non-native species from 594 families and 35 phyla, with Tracheophyta (<i>n</i> = 839), Arthropoda (<i>n</i> = 612), and Chordata (<i>n</i> = 129) being the most represented. Most of these species were terrestrial (79.3%), followed by semi-aquatic (8.4%), with less than 5% occupying freshwaters and other ecosystems. This study highlights a significant lack of information on the impacts of non-native species in Germany, with 97.9% of species having unknown effects. The greatest number of species included in this list were native to the Palearctic region (<i>n</i> = 813), followed by the Nearctic (<i>n</i> = 365) and Neotropic (<i>n</i> = 127) regions. However, many species were of unknown origin (<i>n</i> = 335), with a smaller subset classified as widespread (<i>n</i> = 166).</p><h3>Conclusions</h3><p>This first comprehensive list of established non-native species is essential for guiding management strategies in Germany. By cataloguing established non-native species and their impacts, it provides policymakers and stakeholders with a clearer understanding of which species are present, their patterns of spread, and their potential impacts, enabling them to prioritise management efforts for the most harmful species.</p></div>","PeriodicalId":546,"journal":{"name":"Environmental Sciences Europe","volume":"37 1","pages":""},"PeriodicalIF":6.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1186/s12302-025-01094-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143830704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-15DOI: 10.1007/s12665-025-12232-1
Lan Ning, Kaiheng Hu, Pu Li, Haiguang Cheng, Shuang Liu, Qiyuan Zhang
Debris flows can significantly amplify both discharge and destructive potential as they flow over a colluvial channel with non-uniform cross-sections. However, the mechanisms driving this growth remain largely unclear. In this study, we examined the influence of channel narrowing or widening on debris flow dynamics through in-situ investigations following the debris flow events in Western China, specifically in Zhouqu in 2010 and Heixiluo in 2020. By introducing two dimensionless parameters, namely the discharge amplification factor and channel narrowness, we found a significant correlation between peak discharges of the debris flows and channel widths. When the channel narrows, the increase in flow velocity leads to flow amplification, intensifying the erosive force of the debris flow and causing more severe localized failure of the bed sediments. In contrast, when the channel widens, fluid dispersion results in a decrease in flow velocity, reducing the overall scale and destructive power of the debris flow. Based on experimental measurements, an exponential relationship between the flow amplification factor and channel narrowness was determined using regression analysis. This research may aid in comprehending the dynamics of debris flow and in the evaluation and mitigation of associated disasters.
{"title":"Peak discharge amplication of debris flows in colluvial channels with varying cross-sections","authors":"Lan Ning, Kaiheng Hu, Pu Li, Haiguang Cheng, Shuang Liu, Qiyuan Zhang","doi":"10.1007/s12665-025-12232-1","DOIUrl":"10.1007/s12665-025-12232-1","url":null,"abstract":"<div><p>Debris flows can significantly amplify both discharge and destructive potential as they flow over a colluvial channel with non-uniform cross-sections. However, the mechanisms driving this growth remain largely unclear. In this study, we examined the influence of channel narrowing or widening on debris flow dynamics through in-situ investigations following the debris flow events in Western China, specifically in Zhouqu in 2010 and Heixiluo in 2020. By introducing two dimensionless parameters, namely the discharge amplification factor and channel narrowness, we found a significant correlation between peak discharges of the debris flows and channel widths. When the channel narrows, the increase in flow velocity leads to flow amplification, intensifying the erosive force of the debris flow and causing more severe localized failure of the bed sediments. In contrast, when the channel widens, fluid dispersion results in a decrease in flow velocity, reducing the overall scale and destructive power of the debris flow. Based on experimental measurements, an exponential relationship between the flow amplification factor and channel narrowness was determined using regression analysis. This research may aid in comprehending the dynamics of debris flow and in the evaluation and mitigation of associated disasters.</p></div>","PeriodicalId":542,"journal":{"name":"Environmental Earth Sciences","volume":"84 8","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143830731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-15DOI: 10.1007/s11128-025-04730-9
Jia Bao, Haoran Yan, Fangying Song, Bin Guo, Zhaoyu Sun
We explore bipartite and multipartite nonlocality in the alternating Heisenberg–Ising spin chain model, emphasizing the contrasting and complementary roles of the relative coupling strength (lambda ) (the ratio of the Ising interaction to the Heisenberg interaction), the external magnetic field h, and the temperature T. Bipartite nonlocality is evaluated using the CHSH inequality, and multipartite nonlocality is assessed through Bell-type inequalities derived from g-grouping model theory. Our results show that (lambda ), h, and T significantly affect nonlocality in distinct ways. Increasing (lambda ) suppresses bipartite nonlocality but enhances multipartite nonlocality, highlighting the interaction-specific roles in the system: The Heisenberg interaction primarily governs bipartite nonlocal correlations, whereas the Ising interaction drives multipartite nonlocal correlations. In contrast, both h and T universally suppress bipartite and multipartite nonlocal correlations, irrespective of the interaction type. We also reveal scaling behaviors of nonlocality near the quantum critical points, denoted as (lambda _{c}), where both bipartite and multipartite nonlocality exhibit clear signatures in their first derivatives. Critical scaling is described by (lambda _{c}(N) = lambda _{c}(infty )-aN^{-b}), allowing precise determination of the critical value (lambda _{c}(infty ) = 2) in the thermodynamic limit.
{"title":"Nonlocality in the alternating Heisenberg–Ising spin chain: effects of coupling, magnetic field, and temperature","authors":"Jia Bao, Haoran Yan, Fangying Song, Bin Guo, Zhaoyu Sun","doi":"10.1007/s11128-025-04730-9","DOIUrl":"10.1007/s11128-025-04730-9","url":null,"abstract":"<div><p>We explore bipartite and multipartite nonlocality in the alternating Heisenberg–Ising spin chain model, emphasizing the contrasting and complementary roles of the relative coupling strength <span>(lambda )</span> (the ratio of the Ising interaction to the Heisenberg interaction), the external magnetic field <i>h</i>, and the temperature <i>T</i>. Bipartite nonlocality is evaluated using the CHSH inequality, and multipartite nonlocality is assessed through Bell-type inequalities derived from <i>g</i>-grouping model theory. Our results show that <span>(lambda )</span>, <i>h</i>, and <i>T</i> significantly affect nonlocality in distinct ways. Increasing <span>(lambda )</span> suppresses bipartite nonlocality but enhances multipartite nonlocality, highlighting the interaction-specific roles in the system: The Heisenberg interaction primarily governs bipartite nonlocal correlations, whereas the Ising interaction drives multipartite nonlocal correlations. In contrast, both <i>h</i> and <i>T</i> universally suppress bipartite and multipartite nonlocal correlations, irrespective of the interaction type. We also reveal scaling behaviors of nonlocality near the quantum critical points, denoted as <span>(lambda _{c})</span>, where both bipartite and multipartite nonlocality exhibit clear signatures in their first derivatives. Critical scaling is described by <span>(lambda _{c}(N) = lambda _{c}(infty )-aN^{-b})</span>, allowing precise determination of the critical value <span>(lambda _{c}(infty ) = 2)</span> in the thermodynamic limit.</p></div>","PeriodicalId":746,"journal":{"name":"Quantum Information Processing","volume":"24 4","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143830886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-15DOI: 10.1007/s10661-025-13980-0
V. B. Yadav, Vandana A. Pulhani, A. Vinod Kumar
Elemental [Total Organic Carbon (TOC) and Total Nitrogen (TN)] compositions and stable isotope ratio of carbon (δ13C), and nitrogen (δ15N) compositions were measured in four sediment core samples from Mumbai Harbour Bay (MHB), Mumbai, India, to assess the impact of anthropogenic discharges on organic matter in the area and to identify the contribution of terrestrial and marine sources to sedimentary organic carbon. The average values for TOC (%), TN (%) and TOC/TN ratio at different sampling locations in the study area ranges from 1.86% to 2.29%, 0.16% to 0.22%, and 10.49 to 12.01, respectively. Similarly, the average values for δ13C and δ15N were found to vary from - 23.53‰ to - 21.12‰ and from 1.22‰ to 3.14‰, respectively. The sediment from regions impacted by anthropogenic activities had a higher terrestrial organic matter. Application of a two end-member mixing model indicated the contribution of marine sources to organic matter increased from 53.40 ± 11.24% at the northern end to 90.51 ± 6.91% at the southern end of the bay. The correlation between the measured parameters indicates that the organic matter in the region has undergone significant diagenesis and bacterial decomposition. Overall, this study highlights the importance of stable isotope ratios in understanding the complex dynamics of marine ecosystems and the source of organic matter.
{"title":"Study of sedimentary organic carbon using δ13C, δ15N and TOC/TN as indicator in sediment core samples from Mumbai Harbor Bay","authors":"V. B. Yadav, Vandana A. Pulhani, A. Vinod Kumar","doi":"10.1007/s10661-025-13980-0","DOIUrl":"10.1007/s10661-025-13980-0","url":null,"abstract":"<div><p>Elemental [Total Organic Carbon (TOC) and Total Nitrogen (TN)] compositions and stable isotope ratio of carbon (δ<sup>13</sup>C), and nitrogen (δ<sup>15</sup>N) compositions were measured in four sediment core samples from Mumbai Harbour Bay (MHB), Mumbai, India, to assess the impact of anthropogenic discharges on organic matter in the area and to identify the contribution of terrestrial and marine sources to sedimentary organic carbon. The average values for TOC (%), TN (%) and TOC/TN ratio at different sampling locations in the study area ranges from 1.86% to 2.29%, 0.16% to 0.22%, and 10.49 to 12.01, respectively. Similarly, the average values for δ<sup>13</sup>C and δ<sup>15</sup>N were found to vary from - 23.53‰ to - 21.12‰ and from 1.22‰ to 3.14‰, respectively. The sediment from regions impacted by anthropogenic activities had a higher terrestrial organic matter. Application of a two end-member mixing model indicated the contribution of marine sources to organic matter increased from 53.40 ± 11.24% at the northern end to 90.51 ± 6.91% at the southern end of the bay. The correlation between the measured parameters indicates that the organic matter in the region has undergone significant diagenesis and bacterial decomposition. Overall, this study highlights the importance of stable isotope ratios in understanding the complex dynamics of marine ecosystems and the source of organic matter.</p></div>","PeriodicalId":544,"journal":{"name":"Environmental Monitoring and Assessment","volume":"197 5","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10661-025-13980-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143830708","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Designing advanced photofunctional materials within the core of ionic liquids (ILs) has stimulated considerable attention within the scientific communities due to their impactful significance and physicochemical properties such as ionic nature, low melting point, non-volatility, and tunability without hampering their inherent photofunctionality. Herein, we have synthesized a photoluminescent IL, HTIL from 8-hydroxy pyrene-1,3,6-trisulfonic acid trisodium salt [HPTS] and trihexyltetradecylphosphonium chloride ([TTP]Cl) by simple ionic exchange reaction. Water-dispersible IL-based low-dimensional materials referred to as nHTIL were developed by a reprecipitation technique and validated using various spectroscopic and microscopic analyses methods. We have successfully demonstrated that neat HTIL could be used as a solvent-free fluorescent ink and checked its superiority as a security writing tool. A ratiometric cyanish to bluish fluorometric change is observed upon the addition of diethylchlorophosphate (DCP), a sarin mimic in the solution having detection and quantification limits within the µM range. Also, a portable and super handy paper-based test kit experiment has been illustrated and performed verifying DCP detection in the solid phase. A vapor strip–based experiment by nHTIL was conducted to explore the vapor phase detection of DCP. This report presents an innovative way to develop DCP-sensitive IL-based low-dimensional materials exhibiting remarkable properties compared to traditional ones for forensic and environmental monitoring.
Graphical Abstract
{"title":"A ratiometric ionic liquids-based micro-optode for instant and specific detection of nerve agent analog","authors":"Najmin Tohora, Sabbir Ahamed, Jyoti Chourasia, Upika Darnal, Subekchha Pradhan, Shraddha Rai, Shubham Lama, Sudhir Kumar Das","doi":"10.1007/s00604-025-07153-6","DOIUrl":"10.1007/s00604-025-07153-6","url":null,"abstract":"<div><p>Designing advanced photofunctional materials within the core of ionic liquids (ILs) has stimulated considerable attention within the scientific communities due to their impactful significance and physicochemical properties such as ionic nature, low melting point, non-volatility, and tunability without hampering their inherent photofunctionality. Herein, we have synthesized a photoluminescent IL, <b>HTIL</b> from 8-hydroxy pyrene-1,3,6-trisulfonic acid trisodium salt [HPTS] and trihexyltetradecylphosphonium chloride ([TTP]Cl) by simple ionic exchange reaction. Water-dispersible IL-based low-dimensional materials referred to as <b>nHTIL</b> were developed by a reprecipitation technique and validated using various spectroscopic and microscopic analyses methods. We have successfully demonstrated that neat <b>HTIL</b> could be used as a solvent-free fluorescent ink and checked its superiority as a security writing tool. A ratiometric cyanish to bluish fluorometric change is observed upon the addition of diethylchlorophosphate (DCP), a sarin mimic in the solution having detection and quantification limits within the µM range. Also, a portable and super handy paper-based test kit experiment has been illustrated and performed verifying DCP detection in the solid phase. A vapor strip–based experiment by <b>nHTIL</b> was conducted to explore the vapor phase detection of DCP. This report presents an innovative way to develop DCP-sensitive IL-based low-dimensional materials exhibiting remarkable properties compared to traditional ones for forensic and environmental monitoring.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":705,"journal":{"name":"Microchimica Acta","volume":"192 5","pages":""},"PeriodicalIF":5.3,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-15DOI: 10.1134/S1061934825010083
E. A. Yuskina, V. V. Panchuk, D. O. Kirsanov
{"title":"Erratum to: Evolution of Contactless Conductometry Methods","authors":"E. A. Yuskina, V. V. Panchuk, D. O. Kirsanov","doi":"10.1134/S1061934825010083","DOIUrl":"10.1134/S1061934825010083","url":null,"abstract":"","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 1","pages":"202 - 202"},"PeriodicalIF":1.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S1061934825010083.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
We propose a systematic method to block-diagonalize the finite volume effective Hamiltonian for two-particle systems with arbitrary spin in both the rest and moving frame. The framework is convenient and efficient for addressing the left-hand cut issue arising from long-range potential, which are challenging in the framework of standard Lüscher formula. Furthermore, the method provides a foundation for further extension to three-particle systems. We first benchmark our method by examining several toy models, demonstrating its consistency with standard Lüscher formula in the absence of long-range potential. In the presence of long-range potential, we investigate and resolve the effects and issues of left-hand cut. As a realistic application, we calculate the finite volume spectra of isoscalar ( D{overline{D}}^{ast } ) system, where the well-known exotic state χc1(3872) is observed. The results are qualitatively consistent with the lattice QCD calculation, highlighting the reliability and potential application of our framework to the study of other exotic states in hadron physics.
{"title":"Finite volume Hamiltonian method for two-particle systems containing long-range potential on the lattice","authors":"Kang Yu, Guang-Juan Wang, Jia-Jun Wu, Zhi Yang","doi":"10.1007/JHEP04(2025)108","DOIUrl":"10.1007/JHEP04(2025)108","url":null,"abstract":"<p>We propose a systematic method to block-diagonalize the finite volume effective Hamiltonian for two-particle systems with arbitrary spin in both the rest and moving frame. The framework is convenient and efficient for addressing the left-hand cut issue arising from long-range potential, which are challenging in the framework of standard Lüscher formula. Furthermore, the method provides a foundation for further extension to three-particle systems. We first benchmark our method by examining several toy models, demonstrating its consistency with standard Lüscher formula in the absence of long-range potential. In the presence of long-range potential, we investigate and resolve the effects and issues of left-hand cut. As a realistic application, we calculate the finite volume spectra of isoscalar <span>( D{overline{D}}^{ast } )</span> system, where the well-known exotic state <i>χ</i><sub><i>c</i>1</sub>(3872) is observed. The results are qualitatively consistent with the lattice QCD calculation, highlighting the reliability and potential application of our framework to the study of other exotic states in hadron physics.</p>","PeriodicalId":635,"journal":{"name":"Journal of High Energy Physics","volume":"2025 4","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/JHEP04(2025)108.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835751","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}