Pub Date : 2025-04-22DOI: 10.1007/s10773-025-05985-9
Xingye Wang, Ben Gao
In this paper, we investigate the generalized high-order coupled nonlinear Schrödinger system with modulating coefficients which is used to describe the optical pulses in inhomogeneous media. This work makes two fundamental advances: first, we rigorously derive the Hirota bilinear representation of this system, previously unreported in the literature; second, we use a novel parameter truncation method that enables to obtain the non-degenerate soliton solutions. Specifically, non-degenerate one-, two-soliton solutions are successfully obtained for the first time. Based on inference, we obtain the forms of non-degenerate N-soliton solutions for this system. In addition, by controlling high-order dispersion and self-steepening shift effect, u-shape, v-shape, w-shape, and other shapes of double-hump figures can also be provided. Finally, after selecting appropriate parameters, we analyse the dynamic behaviors of non-degenerate solitons during collisions.
{"title":"Non-Degenerate Solitons and Dynamic Analysis of the Generalized High-Order Coupled Nonlinear Schrödinger system with Modulating Coefficients in Inhomogeneous Media","authors":"Xingye Wang, Ben Gao","doi":"10.1007/s10773-025-05985-9","DOIUrl":"10.1007/s10773-025-05985-9","url":null,"abstract":"<div><p>In this paper, we investigate the generalized high-order coupled nonlinear Schrödinger system with modulating coefficients which is used to describe the optical pulses in inhomogeneous media. This work makes two fundamental advances: first, we rigorously derive the Hirota bilinear representation of this system, previously unreported in the literature; second, we use a novel parameter truncation method that enables to obtain the non-degenerate soliton solutions. Specifically, non-degenerate one-, two-soliton solutions are successfully obtained for the first time. Based on inference, we obtain the forms of non-degenerate <i>N</i>-soliton solutions for this system. In addition, by controlling high-order dispersion and self-steepening shift effect, <i>u</i>-shape, <i>v</i>-shape, <i>w</i>-shape, and other shapes of double-hump figures can also be provided. Finally, after selecting appropriate parameters, we analyse the dynamic behaviors of non-degenerate solitons during collisions.</p></div>","PeriodicalId":597,"journal":{"name":"International Journal of Theoretical Physics","volume":"64 5","pages":""},"PeriodicalIF":1.3,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143856495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-22DOI: 10.1007/s11270-025-08022-x
Qiang Wang, Han Wang, Xulin Chen, Pan Yang, Yunlong Yang, Jibo Xiao
Using a composite ecological remediation system for the long-term field application has been remaining a challenge. To cope with this problem, we fabricated a mussels-bacteria stereo integrated (MBSI) system deployed on a river bank to improve the river water quality. The MBSI system was operated for more than 4 months, and it was found that the turbidity, COD and TN of river water decreased significantly (P < 0.05) after the MBSI system treatment. The mussels layer was dominated by fermentation bacteria like Cetobacterium (7.6%), while ammoxidation bacteria of norank_NS9_marine_group (9.7%), denitrication bacteria of Thauera (9.4%) and anammox bacteria of Pirellula (3.7%) predominated in the immobilization microorganisms, demonstrating that the major responsibility was COD removal for mussels and nitrogen removal for immobilization bacteria. In summary, mussels and bacteria (immobilized) reinforced the synergistic effect, the combination of which provided a simple and feasible system for the improvement of river water quality and a promising tool for the engineering practice.
{"title":"Field Application of Mussels-bacteria Stereo Integrated System for Improving Water Quality of Polluted River","authors":"Qiang Wang, Han Wang, Xulin Chen, Pan Yang, Yunlong Yang, Jibo Xiao","doi":"10.1007/s11270-025-08022-x","DOIUrl":"10.1007/s11270-025-08022-x","url":null,"abstract":"<div><p>Using a composite ecological remediation system for the long-term field application has been remaining a challenge. To cope with this problem, we fabricated a mussels-bacteria stereo integrated (MBSI) system deployed on a river bank to improve the river water quality. The MBSI system was operated for more than 4 months, and it was found that the turbidity, COD and TN of river water decreased significantly (P < 0.05) after the MBSI system treatment. The mussels layer was dominated by fermentation bacteria like <i>Cetobacterium</i> (7.6%), while ammoxidation bacteria of <i>norank_NS9_marine_group</i> (9.7%), denitrication bacteria of <i>Thauera</i> (9.4%) and anammox bacteria of <i>Pirellula</i> (3.7%) predominated in the immobilization microorganisms, demonstrating that the major responsibility was COD removal for mussels and nitrogen removal for immobilization bacteria. In summary, mussels and bacteria (immobilized) reinforced the synergistic effect, the combination of which provided a simple and feasible system for the improvement of river water quality and a promising tool for the engineering practice.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 6","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143856514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-22DOI: 10.1140/epjp/s13360-025-06223-1
Song-Shan Luo, Qing-Quan Jiang, Zhong-Wen Feng, Xia Zhou, Xue-Lin Mu
The generalized uncertainty principle (GUP), as a key model in quantum gravity, is crucial for exploring cosmological properties and related challenges. In this paper, we investigate the effects of a higher-order GUP on primordial Big Bang nucleosynthesis (BBN). First, using a new higher-order GUP, we derive the modified Friedmann equations and the corresponding thermodynamic properties of the universe within the quantum gravity framework. Next, we analyze BBN under these modifications. Finally, by incorporating observational data of BBN and the primordial light element abundances, respectively, we establish constraints on the GUP parameter. The results reveal a significant impact of the GUP on the BBN processes in the early universe. Notably, the GUP parameter is found to take both positive and negative values, which is different from the classical case.
{"title":"The new higher-order generalized uncertainty principle and Big Bang nucleosynthesis","authors":"Song-Shan Luo, Qing-Quan Jiang, Zhong-Wen Feng, Xia Zhou, Xue-Lin Mu","doi":"10.1140/epjp/s13360-025-06223-1","DOIUrl":"10.1140/epjp/s13360-025-06223-1","url":null,"abstract":"<div><p>The generalized uncertainty principle (GUP), as a key model in quantum gravity, is crucial for exploring cosmological properties and related challenges. In this paper, we investigate the effects of a higher-order GUP on primordial Big Bang nucleosynthesis (BBN). First, using a new higher-order GUP, we derive the modified Friedmann equations and the corresponding thermodynamic properties of the universe within the quantum gravity framework. Next, we analyze BBN under these modifications. Finally, by incorporating observational data of BBN and the primordial light element abundances, respectively, we establish constraints on the GUP parameter. The results reveal a significant impact of the GUP on the BBN processes in the early universe. Notably, the GUP parameter is found to take both positive and negative values, which is different from the classical case.</p></div>","PeriodicalId":792,"journal":{"name":"The European Physical Journal Plus","volume":"140 4","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861139","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-22DOI: 10.1134/S1061934824701806
T. A. Kuchmenko, R. U. Umarkhanov, O. V. Zvyagina
<p>Analytical solutions with luminescent labels for the analysis of gaseous media and the detection of volatile organic compounds are discussed. Such solutions can potentially be applied to the development of optical and sorption gas sensors, smart label fillers, and test systems with various carriers for the detection of chemical biomarkers in living systems. To solve the problem, it was proposed to develop and study the properties of modifiers based on cadmium sulfide quantum dots. The aim of the work was to study the sorption properties of CdS quantum dots obtained by a method improved along the line of “green chemistry”, with stabilizing pure and modified chitosan shells modified by rhodamine 6G. Sorption properties of various phases based on quantum dots were studied at a temperature of 22 ± 1°C by a highly sensitive direct piezoelectric quartz microweighing method with a resolution of up to 10<sup>–9</sup> g by the sorbent mass in vapors of volatile compounds. The selectivity of the phases based on cadmium sulfide quantum dots in low-mass chitosan (5–10 μg) with respect to volatile organic compounds of different classes was estimated. The relative selectivity and sensitivity of weighing vapor on different phases were evaluated by parameters <i>A</i>(<i>i</i>/<i>j</i>), showing how many times the sorption properties of CdS phases in chitosan differ without and with additions of rhodamine 6G. The method of direct weighing allows us to estimate the rates of sorption and desorption and the capacity of the sorbent phases. It has been found that the substances belonging to one selectivity group in terms of <i>A(i</i>/<i>j</i>), for example, water and ethanol, are characterized by different sorption rates. This feature can be applied to solve problems of the separate detection of vapors; they can be identified at different moments of the exposure of piezobalances with phases based on CdS quantum dots in chitosan without and with additions of rhodamine 6G. The use of cadmium sulfide quantum dots in chitosan as a sorbent of vapors of organic compounds significantly affects sorption kinetics and efficiency. The modification of chitosan with rhodamine 6G changes the sorption properties of quantum dots in chitosan, which can be used for the design of new sorbents for sensor systems. Simple algorithms are proposed for solving problems of the recognition of vapor of volatile compounds according to calculated parameters, even for non-selective sorption systems. Programming the approach can significantly increase the speed of decision-making in integrated analytical systems, for example, “electronic noses” based on sensors, including those with the studied phases. It was found that the mass of the phase based on cadmium sulfide quantum dots in chitosan does not affect sorption properties in the micromass range, which is traditional for nanostructures. Changes in the luminescent properties of phases based on cadmium sulfide, as a possible visually detected
{"title":"Development of Multiple Analytical Labels for Volatile Organic Compounds Based on the Results of Sorption on CdS Quantum Dots in Chitosan without and with Modification by Rhodamine 6G","authors":"T. A. Kuchmenko, R. U. Umarkhanov, O. V. Zvyagina","doi":"10.1134/S1061934824701806","DOIUrl":"10.1134/S1061934824701806","url":null,"abstract":"<p>Analytical solutions with luminescent labels for the analysis of gaseous media and the detection of volatile organic compounds are discussed. Such solutions can potentially be applied to the development of optical and sorption gas sensors, smart label fillers, and test systems with various carriers for the detection of chemical biomarkers in living systems. To solve the problem, it was proposed to develop and study the properties of modifiers based on cadmium sulfide quantum dots. The aim of the work was to study the sorption properties of CdS quantum dots obtained by a method improved along the line of “green chemistry”, with stabilizing pure and modified chitosan shells modified by rhodamine 6G. Sorption properties of various phases based on quantum dots were studied at a temperature of 22 ± 1°C by a highly sensitive direct piezoelectric quartz microweighing method with a resolution of up to 10<sup>–9</sup> g by the sorbent mass in vapors of volatile compounds. The selectivity of the phases based on cadmium sulfide quantum dots in low-mass chitosan (5–10 μg) with respect to volatile organic compounds of different classes was estimated. The relative selectivity and sensitivity of weighing vapor on different phases were evaluated by parameters <i>A</i>(<i>i</i>/<i>j</i>), showing how many times the sorption properties of CdS phases in chitosan differ without and with additions of rhodamine 6G. The method of direct weighing allows us to estimate the rates of sorption and desorption and the capacity of the sorbent phases. It has been found that the substances belonging to one selectivity group in terms of <i>A(i</i>/<i>j</i>), for example, water and ethanol, are characterized by different sorption rates. This feature can be applied to solve problems of the separate detection of vapors; they can be identified at different moments of the exposure of piezobalances with phases based on CdS quantum dots in chitosan without and with additions of rhodamine 6G. The use of cadmium sulfide quantum dots in chitosan as a sorbent of vapors of organic compounds significantly affects sorption kinetics and efficiency. The modification of chitosan with rhodamine 6G changes the sorption properties of quantum dots in chitosan, which can be used for the design of new sorbents for sensor systems. Simple algorithms are proposed for solving problems of the recognition of vapor of volatile compounds according to calculated parameters, even for non-selective sorption systems. Programming the approach can significantly increase the speed of decision-making in integrated analytical systems, for example, “electronic noses” based on sensors, including those with the studied phases. It was found that the mass of the phase based on cadmium sulfide quantum dots in chitosan does not affect sorption properties in the micromass range, which is traditional for nanostructures. Changes in the luminescent properties of phases based on cadmium sulfide, as a possible visually detected ","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 2","pages":"327 - 338"},"PeriodicalIF":1.0,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-22DOI: 10.1134/S1061934824701739
M. D. Shachneva, E. I. Savelieva
Short-chain fatty acids (SCFAs), produced by the gut microbiota, play a crucial role in maintaining the immune status of a body. Chronic kidney diseases are associated with a reduction in microbial diversity in the gut and a disruption in SCFA production. In chronic kidney diseases, the level of SCFAs in the circulating blood decreases; so, the development of highly sensitive methods for determining SCFAs in serum is necessary. We have developed a method for determining SCFAs in serum and tested it in a comparative study of serum samples from healthy volunteers and patients with diagnosed chronic kidney diseases. The determination of SCFAs (acetic, propionic, butyric, valeric, caproic, iso-butyric, and iso-valeric acids) in blood serum was carried out by gas chromatography–mass spectrometry (GC–MS) and gas chromatography–tandem mass spectrometry (GC–MS/MS). The limits of detection for the investigated SCFAs by GC–MS range from 0.05 to 0.09 µg/mL, while the limits of detection by GC–MS/MS range from 0.002 to 0.007 µg/mL. In the serum samples of patients with chronic kidney diseases, the concentrations of all the investigated SCFAs were lower compared to the control group and fell below the limits of detection of the GC–MS method.
{"title":"Determination of Short-Chain Fatty Acids in Blood Serum as Biomarkers of Renal Dysfunction","authors":"M. D. Shachneva, E. I. Savelieva","doi":"10.1134/S1061934824701739","DOIUrl":"10.1134/S1061934824701739","url":null,"abstract":"<p>Short-chain fatty acids (SCFAs), produced by the gut microbiota, play a crucial role in maintaining the immune status of a body. Chronic kidney diseases are associated with a reduction in microbial diversity in the gut and a disruption in SCFA production. In chronic kidney diseases, the level of SCFAs in the circulating blood decreases; so, the development of highly sensitive methods for determining SCFAs in serum is necessary. We have developed a method for determining SCFAs in serum and tested it in a comparative study of serum samples from healthy volunteers and patients with diagnosed chronic kidney diseases. The determination of SCFAs (acetic, propionic, butyric, valeric, caproic, <i>iso</i>-butyric, and <i>iso</i>-valeric acids) in blood serum was carried out by gas chromatography–mass spectrometry (GC–MS) and gas chromatography–tandem mass spectrometry (GC–MS/MS). The limits of detection for the investigated SCFAs by GC–MS range from 0.05 to 0.09 µg/mL, while the limits of detection by GC–MS/MS range from 0.002 to 0.007 µg/mL. In the serum samples of patients with chronic kidney diseases, the concentrations of all the investigated SCFAs were lower compared to the control group and fell below the limits of detection of the GC–MS method.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 2","pages":"262 - 266"},"PeriodicalIF":1.0,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861266","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-22DOI: 10.1134/S1061934824701715
M. Sh. Aigumov, A. P. Novikov, M. V. Vishnevskii, N. A. Chernova, I. V. Maidanets, M. A. Gofenberg, D. V. Kuznetsov, N. V. Samyshkina, L. N. Rizvanova, A. Z. Temerdashev, S. A. Savchuk
This paper describes a two-step algorithm for detecting muscarine, ibotenic acid, and muscimol in urine samples. A two-step procedure was developed for detecting muscarine, muscimol, and ibotenic acid using a data-dependent mode of MRM analysis with the simultaneous full mass spectrum recording of the target substances. Analytes were detected by HPLC coupled with a triple quadrupole mass spectrometric detector (LC–MS/MS Shimadzu 8050). Chromatographic separation was performed in a Phenomenex Kinetex C18 reversed-phase column. At the first step, muscarine was detected in a diluted urine sample. At the second step, muscimol and ibotenic acid were found using a bimolecular dansylation method. The procedure has been successfully applied to routine chemical and toxicological analyses of urine samples from patients suspected of mushroom poisoning.
{"title":"HPLC–MS/MS Methods for Detecting Muscarine, Muscimol, and Ibotenic Acid in Fungal Samples and Biological Matrices","authors":"M. Sh. Aigumov, A. P. Novikov, M. V. Vishnevskii, N. A. Chernova, I. V. Maidanets, M. A. Gofenberg, D. V. Kuznetsov, N. V. Samyshkina, L. N. Rizvanova, A. Z. Temerdashev, S. A. Savchuk","doi":"10.1134/S1061934824701715","DOIUrl":"10.1134/S1061934824701715","url":null,"abstract":"<p>This paper describes a two-step algorithm for detecting muscarine, ibotenic acid, and muscimol in urine samples. A two-step procedure was developed for detecting muscarine, muscimol, and ibotenic acid using a data-dependent mode of MRM analysis with the simultaneous full mass spectrum recording of the target substances. Analytes were detected by HPLC coupled with a triple quadrupole mass spectrometric detector (LC–MS/MS Shimadzu 8050). Chromatographic separation was performed in a Phenomenex Kinetex C18 reversed-phase column. At the first step, muscarine was detected in a diluted urine sample. At the second step, muscimol and ibotenic acid were found using a bimolecular dansylation method. The procedure has been successfully applied to routine chemical and toxicological analyses of urine samples from patients suspected of mushroom poisoning.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"80 2","pages":"242 - 253"},"PeriodicalIF":1.0,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-22DOI: 10.1007/s12665-025-12262-9
Meganathan Raju, Rajan Gandhimathi
Microplastic (MP) pollution in groundwater is a growing concern due to its toxic properties and harmful effects. Meanwhile, landfills and dumpsites act as storage areas for plastic materials, which gradually disintegrate into microplastics over time, leading to pollution of the surrounding environment. Knowledge of the presence of MPs in the groundwater is scarce, and it is the need of the hour. This article focuses on the MPs migration from the dumpsite to the surrounding groundwater by analyzing the MPs in leachate generated from the dumpsite and MPs found in the groundwater near the solid waste dumpsite region in Ariyamangalam, Tiruchirappalli, Tamil Nadu, India. In this study, the Nile Red staining method has been used to quantify the microplastics with sizes as small as 3.42 μm. The results indicated that the MPs abundance in groundwater is about 11 to 77 particles/L with an average size of 45.16 μm, and in leachate on average, 102 to 140 particles/L were identified with the average size of 152 μm. Based on appearance, most of the MPs are of a fragment’s nature; some films and fibers were also found in the groundwater. Meanwhile, in leachate, fragments (45%) and fibers (44%) were found to be in equal proportion, along with a smaller number of films (11%). From micro-Raman characterization, polyethylene was the dominating polymer, followed by polypropylene, polyethylene terephthalate, polystyrene, polyvinyl chloride, poly methyl methacrylate, polyamide, and polyvinyl alcohol in the groundwater. The risk assessment reveals that the groundwater near the dumpsite zone comes under risk category IV based on the polymer risk index, which means that there is a high risk due to the certain kind of highly toxic polymer present in the groundwater.
{"title":"From trash to tap: assessment of microplastics contamination in leachate and groundwater","authors":"Meganathan Raju, Rajan Gandhimathi","doi":"10.1007/s12665-025-12262-9","DOIUrl":"10.1007/s12665-025-12262-9","url":null,"abstract":"<div><p>Microplastic (MP) pollution in groundwater is a growing concern due to its toxic properties and harmful effects. Meanwhile, landfills and dumpsites act as storage areas for plastic materials, which gradually disintegrate into microplastics over time, leading to pollution of the surrounding environment. Knowledge of the presence of MPs in the groundwater is scarce, and it is the need of the hour. This article focuses on the MPs migration from the dumpsite to the surrounding groundwater by analyzing the MPs in leachate generated from the dumpsite and MPs found in the groundwater near the solid waste dumpsite region in Ariyamangalam, Tiruchirappalli, Tamil Nadu, India. In this study, the Nile Red staining method has been used to quantify the microplastics with sizes as small as 3.42 μm. The results indicated that the MPs abundance in groundwater is about 11 to 77 particles/L with an average size of 45.16 μm, and in leachate on average, 102 to 140 particles/L were identified with the average size of 152 μm. Based on appearance, most of the MPs are of a fragment’s nature; some films and fibers were also found in the groundwater. Meanwhile, in leachate, fragments (45%) and fibers (44%) were found to be in equal proportion, along with a smaller number of films (11%). From micro-Raman characterization, polyethylene was the dominating polymer, followed by polypropylene, polyethylene terephthalate, polystyrene, polyvinyl chloride, poly methyl methacrylate, polyamide, and polyvinyl alcohol in the groundwater. The risk assessment reveals that the groundwater near the dumpsite zone comes under risk category IV based on the polymer risk index, which means that there is a high risk due to the certain kind of highly toxic polymer present in the groundwater.</p></div>","PeriodicalId":542,"journal":{"name":"Environmental Earth Sciences","volume":"84 9","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study focused on the Daluxi River, a small watershed and a primary tributary of the Yangtze River. Based on the nonlinear characteristics of water quality parameters and environmental factors such as meteorological and hydrological influences, a comparative analysis was conducted using Kernel Principal Component Analysis (KPCA) and Principal Component Analysis (PCA). KPCA extracted four potential sources for both the upstream and downstream sections, accounting for 79% of the total variance in each case—an increase of 7% and 6% compared to PCA, respectively. To address the limitation of KPCA in directly revealing the relationship between principal components and the original water quality data, six machine learning algorithms—Extreme Learning Machine (ELM), Backpropagation Neural Network (BPNN), Support Vector Regression (SVR), Decision Tree (DT), Random Forest (RF), and Gradient Boosting Decision Tree (GBDT)—were employed to perform regression analysis between the kernel principal components and the original water quality parameters, thereby elucidating source characteristics. The results indicated that GBDT exhibited the best fitting performance (R2 = 0.988, MAE = 0.05, RMSE = 7.13%). Based on the extracted KPC, the Absolute Principal Component Score-Multiple Linear Regression (APCS-MLR) model was used to calculate the contribution rates of various pollution sources in the Wandang and Siming areas. The results indicate that combining KPCA with GBDT and APCS-MLR can effectively uncover the complex relationships among water quality, meteorological, and hydrological factors, thereby enhancing the accuracy and reliability of pollution source analysis. This study advances research by using KPCA to capture nonlinear relationships and integrating machine learning for enhanced pollution source analysis.
{"title":"Identification of water pollution sources in the Daluxi River using kernel principal component analysis and gradient boosting decision tree","authors":"Ying Liu, Nairui Zheng, Shuhan Yang, Fangfei Liu, Miaohan Liu, Yu Chen","doi":"10.1007/s12665-025-12241-0","DOIUrl":"10.1007/s12665-025-12241-0","url":null,"abstract":"<div><p>This study focused on the Daluxi River, a small watershed and a primary tributary of the Yangtze River. Based on the nonlinear characteristics of water quality parameters and environmental factors such as meteorological and hydrological influences, a comparative analysis was conducted using Kernel Principal Component Analysis (KPCA) and Principal Component Analysis (PCA). KPCA extracted four potential sources for both the upstream and downstream sections, accounting for 79% of the total variance in each case—an increase of 7% and 6% compared to PCA, respectively. To address the limitation of KPCA in directly revealing the relationship between principal components and the original water quality data, six machine learning algorithms—Extreme Learning Machine (ELM), Backpropagation Neural Network (BPNN), Support Vector Regression (SVR), Decision Tree (DT), Random Forest (RF), and Gradient Boosting Decision Tree (GBDT)—were employed to perform regression analysis between the kernel principal components and the original water quality parameters, thereby elucidating source characteristics. The results indicated that GBDT exhibited the best fitting performance (R<sup>2</sup> = 0.988, MAE = 0.05, RMSE = 7.13%). Based on the extracted KPC, the Absolute Principal Component Score-Multiple Linear Regression (APCS-MLR) model was used to calculate the contribution rates of various pollution sources in the Wandang and Siming areas. The results indicate that combining KPCA with GBDT and APCS-MLR can effectively uncover the complex relationships among water quality, meteorological, and hydrological factors, thereby enhancing the accuracy and reliability of pollution source analysis. This study advances research by using KPCA to capture nonlinear relationships and integrating machine learning for enhanced pollution source analysis.</p></div>","PeriodicalId":542,"journal":{"name":"Environmental Earth Sciences","volume":"84 9","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143856412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-04-22DOI: 10.1007/s10854-025-14697-z
Ajay Kumar, Prashant Kumar, Radhapiyari Laishram, Shivnath Kumar, J. S. Rawat, Amit Jain
A large-area centimeter-scale (2 cm × 1 cm) high-quality continuous MoS2 film was grown on a SiO2/Si substrate via the Chemical Vapor Deposition (CVD) technique to ensure the scalability and uniformity of the MoS2 film across a large area, rendering it suitable for wafer-scale applications. We further establish the transfer of MoS2 film from the grown substrate (SiO2/Si) to Interdigitated Electrodes (IDE) structures fabricated on GaAs substrate via a wet etching process utilizing Hydrogen Fluoride (HF) solution, effectively removing the MoS2 layer from SiO2/Si substrate within 2–3 min, while preserving the structural integrity and quality of the MoS2 film. Characterization studies involving Raman analysis, Photoluminescence (PL) mapping, SEM imaging, and optoelectronics measurements confirm the high quality and integrity of the transferred MoS2 film onto IDE structures fabricated on GaAs substrate for photodetection application. Optoelectronic measurements revealed a significant responsivity enhancement from 2.13 to 26.4 mA/W at a 20 V bias under 780 nm laser illuminations (5 mW), due to the incorporation of gold nanoparticles between the IDE fingers by employing RF sputtering. Thus, integrating nanoparticles in the active region of optoelectronic devices can markedly enhance the optical efficiency of 2D material-based optoelectronic systems. Overall, this CVD technique presents a viable approach for the scalable production of large-area MoS2 films and their transfer onto fabricated structures, opening avenues for the integration of MoS2 films into advanced technological devices and systems, particularly in micro and Nano-electromechanical systems.
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Pub Date : 2025-04-22DOI: 10.1140/epja/s10050-025-01545-1
David Verney
This article provides a comprehensive review of the evolution of the nuclear shape concept, a cornerstone in nuclear physics. Tracing its historical development from the early 20th century, we highlight key milestones and paradigm shifts that have shaped our understanding. The review explores the transition from the initial spherical model to the introduction of nuclear deformation, emphasizing the contributions of the liquid drop model and the unified model. The pivotal role of nuclear shapes in elucidating various nuclear phenomena and their profound impact on both theoretical and experimental nuclear physics are discussed in depth. The article underscores the relevance of nuclear shape in contemporary physics, particularly in light of groundbreaking findings from ultra-relativistic heavy ion collisions. These recent results illustrate the enduring significance of nuclear shape in advancing our comprehension of nuclear structure and reactions.
{"title":"History of the concept of nuclear shape","authors":"David Verney","doi":"10.1140/epja/s10050-025-01545-1","DOIUrl":"10.1140/epja/s10050-025-01545-1","url":null,"abstract":"<div><p>This article provides a comprehensive review of the evolution of the nuclear shape concept, a cornerstone in nuclear physics. Tracing its historical development from the early 20th century, we highlight key milestones and paradigm shifts that have shaped our understanding. The review explores the transition from the initial spherical model to the introduction of nuclear deformation, emphasizing the contributions of the liquid drop model and the unified model. The pivotal role of nuclear shapes in elucidating various nuclear phenomena and their profound impact on both theoretical and experimental nuclear physics are discussed in depth. The article underscores the relevance of nuclear shape in contemporary physics, particularly in light of groundbreaking findings from ultra-relativistic heavy ion collisions. These recent results illustrate the enduring significance of nuclear shape in advancing our comprehension of nuclear structure and reactions.</p></div>","PeriodicalId":786,"journal":{"name":"The European Physical Journal A","volume":"61 4","pages":""},"PeriodicalIF":2.6,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1140/epja/s10050-025-01545-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}