Yansong Bai, Xueping Gu, Shaoyan Li, Tong Liu, Yingshan Wang
In power system restoration (PSR), networks with various voltage levels have different decision-making constraints and restoration characteristics. Specifically, the restoration plan for the lower voltage level network is more adaptable to uncertainty of wind power output, owing to its greater flexibility. First, the restoration scheme decision-making is divided into two parts for the main network level (MNL) and the regional network level (RNL) respectively, according to the voltage levels. Second, a hierarchical coordinated optimisation model is established based on a two-stage framework. In the first stage, the plants/lines restoration sequence of the MNL and the subsystem partitioning scheme are determined. Furthermore, the plants/lines restoration sequence of the RNL and the restoration power scheduling scheme of the MNL and RNL are obtained in the second stage of optimisation, which can be flexibly adjusted to adapt to uncertain wind power outputs. The coordination and allocation of frequency regulation resources across subsystems are considered. Finally, the nested column and constraint generation algorithm is applied to solve the two-stage robust model. Case studies using the IEEE standard and a provincial system in China show that the algorithm converges in 2–3 iterations. Compared to non-hierarchical approaches, the proposed method improves cumulative restored energy by 2% and 5.3% in case 1 and case 2, respectively, while maintaining robustness against wind power uncertainty, highlighting its effectiveness in multi-level PSR.
{"title":"Hierarchical Coordinated Optimisation of the Restoration Decision-Making for Multi-Voltage-Level Power Systems With Wind Power Integration","authors":"Yansong Bai, Xueping Gu, Shaoyan Li, Tong Liu, Yingshan Wang","doi":"10.1049/gtd2.70075","DOIUrl":"https://doi.org/10.1049/gtd2.70075","url":null,"abstract":"<p>In power system restoration (PSR), networks with various voltage levels have different decision-making constraints and restoration characteristics. Specifically, the restoration plan for the lower voltage level network is more adaptable to uncertainty of wind power output, owing to its greater flexibility. First, the restoration scheme decision-making is divided into two parts for the main network level (MNL) and the regional network level (RNL) respectively, according to the voltage levels. Second, a hierarchical coordinated optimisation model is established based on a two-stage framework. In the first stage, the plants/lines restoration sequence of the MNL and the subsystem partitioning scheme are determined. Furthermore, the plants/lines restoration sequence of the RNL and the restoration power scheduling scheme of the MNL and RNL are obtained in the second stage of optimisation, which can be flexibly adjusted to adapt to uncertain wind power outputs. The coordination and allocation of frequency regulation resources across subsystems are considered. Finally, the nested column and constraint generation algorithm is applied to solve the two-stage robust model. Case studies using the IEEE standard and a provincial system in China show that the algorithm converges in 2–3 iterations. Compared to non-hierarchical approaches, the proposed method improves cumulative restored energy by 2% and 5.3% in case 1 and case 2, respectively, while maintaining robustness against wind power uncertainty, highlighting its effectiveness in multi-level PSR.</p>","PeriodicalId":13261,"journal":{"name":"Iet Generation Transmission & Distribution","volume":"19 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/gtd2.70075","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861849","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ki-Hwan Kim, Dae-Hee Seo, Im-Yeong Lee, Su-Hyun Kim
Private set intersection (PSI) is a privacy-preserving scheme that computes the intersection of two datasets without leaking any other information. Additionally, there is multiparty private set intersection (MPSI) to extend the number of parties for computing the intersection of multiple private datasets. In the traditional PSI and MPSI studies, protocol parties input their private datasets, and one or all of them can compute the intersection. However, there are some scenarios where an inputless external party requires the intersection between private datasets of other parties. Thus, the external party PSI protocols have been recently studied for applications such as pandemic contact tracing, computing human genome information and evaluating policy effects. However, they are limited in applications because the external party can compute the intersection of two datasets. In this paper, we propose a new external party compute-MPSI (EPC-MPSI) protocols that allow an external party to compute the intersection of multiple datasets. We provide the extension of the number of parties and solve the limitation of prior external party PSI protocols. In addition, we analyze the correctness, security and the efficiency in terms of communication and computation costs compared to the prior traditional MPSI protocols.
{"title":"A Study on New EPC-MPSI for an Inputless External Party to Compute the Intersection of Multiple Private Datasets","authors":"Ki-Hwan Kim, Dae-Hee Seo, Im-Yeong Lee, Su-Hyun Kim","doi":"10.1049/cmu2.70038","DOIUrl":"https://doi.org/10.1049/cmu2.70038","url":null,"abstract":"<p>Private set intersection (PSI) is a privacy-preserving scheme that computes the intersection of two datasets without leaking any other information. Additionally, there is multiparty private set intersection (MPSI) to extend the number of parties for computing the intersection of multiple private datasets. In the traditional PSI and MPSI studies, protocol parties input their private datasets, and one or all of them can compute the intersection. However, there are some scenarios where an inputless external party requires the intersection between private datasets of other parties. Thus, the external party PSI protocols have been recently studied for applications such as pandemic contact tracing, computing human genome information and evaluating policy effects. However, they are limited in applications because the external party can compute the intersection of two datasets. In this paper, we propose a new external party compute-MPSI (EPC-MPSI) protocols that allow an external party to compute the intersection of multiple datasets. We provide the extension of the number of parties and solve the limitation of prior external party PSI protocols. In addition, we analyze the correctness, security and the efficiency in terms of communication and computation costs compared to the prior traditional MPSI protocols.</p>","PeriodicalId":55001,"journal":{"name":"IET Communications","volume":"19 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/cmu2.70038","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861795","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"计算机科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Si Heon Lim, Geunwoo Kim, Sungjin Cho, Yeong Kwon Kim, Eun Bee Ko, Seon Yeon Choi, Jung A Heo, Daegun Kim, Hocheon Yoo, So-Yeon Lee, YongJoo Kim, Pil-Ryung Cha, Dong Yun Lee, Sunghun Lee, Byung Chul Jang, Yeonhoo Kim, Hyun Ho Kim
Nanostructured Transition Metal Oxides
In article number 2418407, Hyun Ho Kim and co-workers present a universal and ultrafast method for synthesizing nanostructured transition metal oxides (NTMOs) through the induced solidification of microdroplets, enabling rapid production within a minute. Since NTMOs can be directly grown on substrates in ambient air without requiring high-purity carrier gases, this approach facilitates industrial-friendly mass production.
{"title":"Ultrafast and Universal Synthetic Route for Nanostructured Transition Metal Oxides Directly Grown on Substrates (Adv. Mater. 16/2025)","authors":"Si Heon Lim, Geunwoo Kim, Sungjin Cho, Yeong Kwon Kim, Eun Bee Ko, Seon Yeon Choi, Jung A Heo, Daegun Kim, Hocheon Yoo, So-Yeon Lee, YongJoo Kim, Pil-Ryung Cha, Dong Yun Lee, Sunghun Lee, Byung Chul Jang, Yeonhoo Kim, Hyun Ho Kim","doi":"10.1002/adma.202570125","DOIUrl":"https://doi.org/10.1002/adma.202570125","url":null,"abstract":"<p><b>Nanostructured Transition Metal Oxides</b></p><p>In article number 2418407, Hyun Ho Kim and co-workers present a universal and ultrafast method for synthesizing nanostructured transition metal oxides (NTMOs) through the induced solidification of microdroplets, enabling rapid production within a minute. Since NTMOs can be directly grown on substrates in ambient air without requiring high-purity carrier gases, this approach facilitates industrial-friendly mass production.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"37 16","pages":""},"PeriodicalIF":27.4,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adma.202570125","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Frederik Dencker Wisborg MD, Nora Olsen El Caidi MD, Ida Arentz Taraldsen MD, Sandra Tonning MD, Aginsha Kandiah MD, Mohammed El-Sheikh MD, Hashmat S. Z. Bahrami MD, Ove Andersen MDD, MSc, Line Jee Hartmann Rasmussen MSc, PhD, Jens Hove MD, MSc, PhD, Ulrik Dixen MD, PhD, Johannes Grand MD, MPH, PhD
Background
Atrial fibrillation (AF) is associated with a higher incidence of stroke, heart failure, and mortality. Risk assessment of clinical outcomes in patients hospitalized acutely with AF remains a challenge.
Purpose
To investigate if soluble urokinase plasminogen activator receptor (suPAR) levels at admission to the Emergency Department (ED) are associated with 1-year all-cause mortality in patients admitted with AF.
Methods
A prospective cohort study of patients consecutively admitted to the medical ED of a university hospital in Copenhagen, Denmark, between 2020 and 2022 with symptoms of COVID-19. Patients were included if they were admitted with AF as the primary or secondary diagnosis. All patients had suPAR measured at the index admission, and follow-up was up to 1 year. The association between suPAR and 1-year mortality was investigated with multivariate Cox regression. We adjusted for age, sex, smoking, C-reactive protein, creatinine, hemoglobin, albumin, and comorbidities.
Results
Of the 7,258 patients included during the period, 362 (5.0%) patients were admitted with AF as the primary or secondary diagnosis. Due to missing data, 23 (6.4%) patients were excluded. Among the remaining 339 patients, 68 (20.1%) patients were dead at follow-up. The multivariate Cox regression showed that elevated suPAR was independently associated with an increased risk of 1-year mortality, with a hazard ratio of 1.12 (95% confidence interval: 1.05–1.20, p < 0.001).
Conclusion
Elevated suPAR levels were significantly associated with 1-year all-cause mortality in patients acutely admitted with AF to the ED.
{"title":"Soluble urokinase plasminogen activator receptor (suPAR) as a prognostic biomarker in acutely admitted patients with atrial fibrillation","authors":"Frederik Dencker Wisborg MD, Nora Olsen El Caidi MD, Ida Arentz Taraldsen MD, Sandra Tonning MD, Aginsha Kandiah MD, Mohammed El-Sheikh MD, Hashmat S. Z. Bahrami MD, Ove Andersen MDD, MSc, Line Jee Hartmann Rasmussen MSc, PhD, Jens Hove MD, MSc, PhD, Ulrik Dixen MD, PhD, Johannes Grand MD, MPH, PhD","doi":"10.1002/joa3.70077","DOIUrl":"https://doi.org/10.1002/joa3.70077","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> Background</h3>\u0000 \u0000 <p>Atrial fibrillation (AF) is associated with a higher incidence of stroke, heart failure, and mortality. Risk assessment of clinical outcomes in patients hospitalized acutely with AF remains a challenge.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Purpose</h3>\u0000 \u0000 <p>To investigate if soluble urokinase plasminogen activator receptor (suPAR) levels at admission to the Emergency Department (ED) are associated with 1-year all-cause mortality in patients admitted with AF.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Methods</h3>\u0000 \u0000 <p>A prospective cohort study of patients consecutively admitted to the medical ED of a university hospital in Copenhagen, Denmark, between 2020 and 2022 with symptoms of COVID-19. Patients were included if they were admitted with AF as the primary or secondary diagnosis. All patients had suPAR measured at the index admission, and follow-up was up to 1 year. The association between suPAR and 1-year mortality was investigated with multivariate Cox regression. We adjusted for age, sex, smoking, C-reactive protein, creatinine, hemoglobin, albumin, and comorbidities.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Results</h3>\u0000 \u0000 <p>Of the 7,258 patients included during the period, 362 (5.0%) patients were admitted with AF as the primary or secondary diagnosis. Due to missing data, 23 (6.4%) patients were excluded. Among the remaining 339 patients, 68 (20.1%) patients were dead at follow-up. The multivariate Cox regression showed that elevated suPAR was independently associated with an increased risk of 1-year mortality, with a hazard ratio of 1.12 (95% confidence interval: 1.05–1.20, <i>p</i> < 0.001).</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Conclusion</h3>\u0000 \u0000 <p>Elevated suPAR levels were significantly associated with 1-year all-cause mortality in patients acutely admitted with AF to the ED.</p>\u0000 </section>\u0000 </div>","PeriodicalId":15174,"journal":{"name":"Journal of Arrhythmia","volume":"41 2","pages":""},"PeriodicalIF":2.2,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/joa3.70077","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861867","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lalechère, E., Marrec, R., & Lenoir, J. (2025). A Non-Equilibrium Species Distribution Model Reveals Unprecedented Depth of Time Lag Responses to Past Environmental Change Trajectories. Ecology Letters, 28(1), e70040. https://doi.org/10.1111/ele.70040
In the ‘Material and Methods’ section and in the ‘Results’ section, the assertation that the distribution of the residual errors followed a normal distribution was unnecessary to assess model validity. This may lead to some confusion about the family of distribution that was used. As stated in the article, we relied on the binomial distribution.
We apologize for this mistake.
{"title":"Correction to “A Non-Equilibrium Species Distribution Model Reveals Unprecedented Depth of Time Lag Responses to Past Environmental Change Trajectories”","authors":"","doi":"10.1111/ele.70123","DOIUrl":"https://doi.org/10.1111/ele.70123","url":null,"abstract":"<p>\u0000 <span>Lalechère, E.</span>, <span>Marrec, R.</span>, & <span>Lenoir, J.</span> (<span>2025</span>). <span>A Non-Equilibrium Species Distribution Model Reveals Unprecedented Depth of Time Lag Responses to Past Environmental Change Trajectories</span>. <i>Ecology Letters</i>, <span>28</span>(<span>1</span>), e70040. https://doi.org/10.1111/ele.70040\u0000 </p><p>In the ‘Material and Methods’ section and in the ‘Results’ section, the assertation that the distribution of the residual errors followed a normal distribution was unnecessary to assess model validity. This may lead to some confusion about the family of distribution that was used. As stated in the article, we relied on the binomial distribution.</p><p>We apologize for this mistake.</p>","PeriodicalId":161,"journal":{"name":"Ecology Letters","volume":"28 4","pages":""},"PeriodicalIF":7.6,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/ele.70123","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Min Qi, Jing Wang, Rongle Wang, Yigang Song, Saneyoshi Ueno, Yibo Luo, Fang K. Du
Character displacement refers to the process by which species diverge more in sympatry due to competition for resources. This competition-driven speciation can also occur within populations, known as intraspecific character displacement (ICD). ICD can promote divergence within species by influencing intraspecific competition or encouraging the evolution of alternative phenotypes. Despite its significance, ICD remains understudied and requires further exploration. In this study, we investigate how competition influences genetic and morphological differentiation within species in sympatric and allopatric populations. We focused on Quercus serrata (in China and Japan) and Q. serrata var. brevipetiolata (found only in China), which belong to a small monophyletic group of oak species nested within Section Quercus (white oaks). Using genetic markers, we detected divergence between Chinese and Japanese populations and further diversification within China, with asymmetric historical gene flow primarily from Q. serrata (the earlier diverged species) to Q. serrata var. brevipetiolata (the later variety). Although genetic differentiation did not differ between sympatric and allopatric populations, leaf morphological variation, analyzed through the geometric morphometric method (GMM) and traditional morphological method, revealed greater trait variation in sympatry. In addition, we found an allometric growth relationship between leaf size and leaf mass of Q. serrata and Q. serrata var. brevipetiolata, with the leaf area of Q. serrata var. brevipetiolata decreasing more disproportionately to leaf mass. This suggests a resource trade-off, where Q. serrata var. brevipetiolata, the later diverged variety, adopts more resource-conservative traits in sympatry. Further analysis of trait variation with environmental factors supports these findings, while genetic variation along climate gradients showed significant responses primarily in Q. serrata, regardless of sympatric or allopatric conditions. Although neutral genetic markers are insufficient to capture selection-driven adaptive differentiation, we inferred that Q. serrata var. brevipetiolata is progressing towards ecological divergence from Q. serrata. Overall, our results highlight the role of ICD in driving morphological diversification and resource-use strategies within species in response to competitive pressures.
{"title":"Intraspecific character displacement in oaks","authors":"Min Qi, Jing Wang, Rongle Wang, Yigang Song, Saneyoshi Ueno, Yibo Luo, Fang K. Du","doi":"10.1111/tpj.70165","DOIUrl":"https://doi.org/10.1111/tpj.70165","url":null,"abstract":"<div>\u0000 \u0000 <p>Character displacement refers to the process by which species diverge more in sympatry due to competition for resources. This competition-driven speciation can also occur within populations, known as intraspecific character displacement (ICD). ICD can promote divergence within species by influencing intraspecific competition or encouraging the evolution of alternative phenotypes. Despite its significance, ICD remains understudied and requires further exploration. In this study, we investigate how competition influences genetic and morphological differentiation within species in sympatric and allopatric populations. We focused on <i>Quercus serrata</i> (in China and Japan) and <i>Q. serrata</i> var. <i>brevipetiolata</i> (found only in China), which belong to a small monophyletic group of oak species nested within Section <i>Quercus</i> (white oaks). Using genetic markers, we detected divergence between Chinese and Japanese populations and further diversification within China, with asymmetric historical gene flow primarily from <i>Q. serrata</i> (the earlier diverged species) to <i>Q. serrata</i> var. <i>brevipetiolata</i> (the later variety). Although genetic differentiation did not differ between sympatric and allopatric populations, leaf morphological variation, analyzed through the geometric morphometric method (GMM) and traditional morphological method, revealed greater trait variation in sympatry. In addition, we found an allometric growth relationship between leaf size and leaf mass of <i>Q. serrata</i> and <i>Q. serrata</i> var. <i>brevipetiolata</i>, with the leaf area of <i>Q. serrata</i> var. <i>brevipetiolata</i> decreasing more disproportionately to leaf mass. This suggests a resource trade-off, where <i>Q. serrata</i> var<i>. brevipetiolata</i>, the later diverged variety, adopts more resource-conservative traits in sympatry. Further analysis of trait variation with environmental factors supports these findings, while genetic variation along climate gradients showed significant responses primarily in <i>Q. serrata</i>, regardless of sympatric or allopatric conditions. Although neutral genetic markers are insufficient to capture selection-driven adaptive differentiation, we inferred that <i>Q. serrata</i> var<i>. brevipetiolata</i> is progressing towards ecological divergence from <i>Q. serrata.</i> Overall, our results highlight the role of ICD in driving morphological diversification and resource-use strategies within species in response to competitive pressures.</p>\u0000 </div>","PeriodicalId":233,"journal":{"name":"The Plant Journal","volume":"122 2","pages":""},"PeriodicalIF":6.2,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Programmable Bio-Inspired Magnetic Heart Valve System
Soft magnetic valve (SMV) system introduces a miniaturized, biomimetic magnetic heart valve inspired by the human aortic valve, designed for precise cardiovascular simulations. The valve, composed of a silicone elastomer embedded with neodymium magnetic micro-particles, responds dynamically to controlled magnetic fields generated by electromagnets. This programmable system replicates diverse blood pressure waveforms by regulating fluid flow and pressure with high accuracy. With a compact and versatile design, the artificial valve system offers potential applications in clinical trials, biomimetic robotics, and advanced biomedical research. More details can be found in article number 2419504 by Jeongmin Yoo, Gooyoon Chung, and Yoonseok Park.
{"title":"Bio-Inspired, Miniaturized Magnetic Heart Valve System for Superior Performance Cardiovascular Simulator (Adv. Mater. 16/2025)","authors":"Jeongmin Yoo, Gooyoon Chung, Yoonseok Park","doi":"10.1002/adma.202570124","DOIUrl":"https://doi.org/10.1002/adma.202570124","url":null,"abstract":"<p><b>Programmable Bio-Inspired Magnetic Heart Valve System</b></p><p>Soft magnetic valve (SMV) system introduces a miniaturized, biomimetic magnetic heart valve inspired by the human aortic valve, designed for precise cardiovascular simulations. The valve, composed of a silicone elastomer embedded with neodymium magnetic micro-particles, responds dynamically to controlled magnetic fields generated by electromagnets. This programmable system replicates diverse blood pressure waveforms by regulating fluid flow and pressure with high accuracy. With a compact and versatile design, the artificial valve system offers potential applications in clinical trials, biomimetic robotics, and advanced biomedical research. More details can be found in article number 2419504 by Jeongmin Yoo, Gooyoon Chung, and Yoonseok Park.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"37 16","pages":""},"PeriodicalIF":27.4,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adma.202570124","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Amina Tabet, Abderrhmane Bouafia, Khansaa Al-Essa, Ibtissam Laib, Salah Eddine Laouini, Fahad Alharthi, Abdullah Al Souwaileh, Mokni-Tlili Sonia, Tomasz Trzepieciński
This study explores the innovative synthesis and versatile applications of Ca₅(PO₄)₃F@Ca₅P₈ nanocomposites (NCs), crafted from phosphate waste sourced from Djebel Onk, Algeria, advancing sustainable material use and environmental remediation. FTIR analysis unveiled distinct functional groups, including C─H, P─H, P─O, and F─Ca, underscoring the material's chemical richness, while XRD revealed a crystalline architecture blending hexagonal (Ca₅(PO₄)₃F) and monoclinic (Ca₅P₈) phases, with a precise crystallite size of 22.45 ± 1.18 nm. SEM and EDS showcased uniform spherical particles averaging 24 nm, brimming with Ca, P, O, and F elements. Optical properties dazzled with peak absorption at 391 nm, direct and indirect bandgaps of 1.62 and 2.98 eV, and an Urbach energy of 0.435 eV, signaling exceptional UV–visible absorption capabilities. Beyond its structural elegance, the nanocomposite exhibited remarkable antioxidant prowess, neutralizing nearly 100% of hydrogen peroxide, and delivered striking photocatalytic performance, degrading 99.2% of Evans Blue dye in just 140 min (rate constant 0.01334 min−1). Antibacterial assays further highlighted its potency, effectively combating S. aureus, C. albicans, and other microbes. These compelling results position Ca₅(PO₄)₃F@Ca₅P₈ NCs as a multifunctional powerhouse for water treatment, photocatalysis, and antibacterial applications, paving the way for sustainable technological breakthroughs.
{"title":"Unveiling the Synthesis, Characterization, and Multifunctional Applications of Ca₅(PO₄)₃F@Ca₅P₈ Nanocomposites From Phosphate Waste for Antioxidant Activity and Evans Bleu Decomposition","authors":"Amina Tabet, Abderrhmane Bouafia, Khansaa Al-Essa, Ibtissam Laib, Salah Eddine Laouini, Fahad Alharthi, Abdullah Al Souwaileh, Mokni-Tlili Sonia, Tomasz Trzepieciński","doi":"10.1002/slct.202406193","DOIUrl":"https://doi.org/10.1002/slct.202406193","url":null,"abstract":"<p>This study explores the innovative synthesis and versatile applications of Ca₅(PO₄)₃F@Ca₅P₈ nanocomposites (NCs), crafted from phosphate waste sourced from Djebel Onk, Algeria, advancing sustainable material use and environmental remediation. FTIR analysis unveiled distinct functional groups, including C─H, P─H, P─O, and F─Ca, underscoring the material's chemical richness, while XRD revealed a crystalline architecture blending hexagonal (Ca₅(PO₄)₃F) and monoclinic (Ca₅P₈) phases, with a precise crystallite size of 22.45 ± 1.18 nm. SEM and EDS showcased uniform spherical particles averaging 24 nm, brimming with Ca, P, O, and F elements. Optical properties dazzled with peak absorption at 391 nm, direct and indirect bandgaps of 1.62 and 2.98 eV, and an Urbach energy of 0.435 eV, signaling exceptional UV–visible absorption capabilities. Beyond its structural elegance, the nanocomposite exhibited remarkable antioxidant prowess, neutralizing nearly 100% of hydrogen peroxide, and delivered striking photocatalytic performance, degrading 99.2% of Evans Blue dye in just 140 min (rate constant 0.01334 min<sup>−1</sup>). Antibacterial assays further highlighted its potency, effectively combating <i>S. aureus</i>, <i>C. albicans</i>, and other microbes. These compelling results position Ca₅(PO₄)₃F@Ca₅P₈ NCs as a multifunctional powerhouse for water treatment, photocatalysis, and antibacterial applications, paving the way for sustainable technological breakthroughs.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"10 16","pages":""},"PeriodicalIF":1.9,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861859","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Olli Siltanen, Kimmo Luoma, Andrew J. Musser, Konstantinos S. Daskalakis
Enhancing Polariton OLEDs
In article 2403046, Olli Siltanen, Konstantinos S. Daskalakis, and co-workers propose a theoretical model for triplet harvesting in polariton OLEDs. Rates for polaritonic reverse inter-system crossing and triplet-triplet annihilation are derived, and delocalization effects on singlet-singlet annihilation are studied, paving the way for more efficient OLEDs. Cover image by Konstantinos S. Daskalakis.
{"title":"Enhancing the Efficiency of Polariton OLEDs in and Beyond the Single-Excitation Subspace (Advanced Optical Materials 12/2025)","authors":"Olli Siltanen, Kimmo Luoma, Andrew J. Musser, Konstantinos S. Daskalakis","doi":"10.1002/adom.202570083","DOIUrl":"https://doi.org/10.1002/adom.202570083","url":null,"abstract":"<p><b>Enhancing Polariton OLEDs</b></p><p>In article 2403046, Olli Siltanen, Konstantinos S. Daskalakis, and co-workers propose a theoretical model for triplet harvesting in polariton OLEDs. Rates for polaritonic reverse inter-system crossing and triplet-triplet annihilation are derived, and delocalization effects on singlet-singlet annihilation are studied, paving the way for more efficient OLEDs. Cover image by Konstantinos S. Daskalakis.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":116,"journal":{"name":"Advanced Optical Materials","volume":"13 12","pages":""},"PeriodicalIF":8.0,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adom.202570083","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In article number 2421571, Xuelin Wang, Jing Liu, and co-workers present the concept and theoretical framework of ubiquitous liquid metal (LM) 3D printing aiming to provide a generalized fabrication category. The review comprehensively clarifies interactions between LM inks and various media, spanning from gases, liquids, soft matters, biological tissues to rigid structures, highlighting key mechanisms of chemistry, physics, and materials. This principle would serve to guide optimizing LM 3D printing, offering versatile opportunities for future smart manufacturing and innovative applications.
{"title":"Ubiquitous Liquid Metal 3D Printing: From Gas, Liquid to Rigid Media (Adv. Funct. Mater. 16/2025)","authors":"Xiaohui Shan, Weichen Feng, Ziliang Cui, Minghui Guo, Hongshi Huang, Jian Wang, Xiyu Zhu, Ruizhi Yuan, Yingjie Cao, Bo Wang, Huiyu Qiao, Xuelin Wang, Jing Liu","doi":"10.1002/adfm.202570095","DOIUrl":"https://doi.org/10.1002/adfm.202570095","url":null,"abstract":"<p><b>Liquid Metal 3D Printing</b></p><p>In article number 2421571, Xuelin Wang, Jing Liu, and co-workers present the concept and theoretical framework of ubiquitous liquid metal (LM) 3D printing aiming to provide a generalized fabrication category. The review comprehensively clarifies interactions between LM inks and various media, spanning from gases, liquids, soft matters, biological tissues to rigid structures, highlighting key mechanisms of chemistry, physics, and materials. This principle would serve to guide optimizing LM 3D printing, offering versatile opportunities for future smart manufacturing and innovative applications.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"35 16","pages":""},"PeriodicalIF":18.5,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adfm.202570095","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861917","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}