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Exploring sustainable aesthetics through repurposed studio waste materials for unorthodox finishes 通过重新利用工作室废弃材料进行非正统饰面,探索可持续美学
Pub Date : 2024-04-16 DOI: 10.1016/j.clwas.2024.100147
Samuel Nii Adamah Sampah, Henrietta Meakoa Barfi-Mensah, Ebenezer Fiifi Mensah, Charles Vicku, Mokpokpo Adja-Koadade, Ansah-Asiedu Junior

This study recycles and repurposes discarded studio waste materials, such as broken ceramics, glass fragments, sawdust, and bits of shattered P.O.P molds, to create visually compelling creative works. The interest for this study is inspired by the prolific generation of waste that arises from the studio learning practices of sculpture and ceramic students. A studio-based research approach utilizing Aesthetico-Action Research design is employed in a systematic approach to explore the feasibility and promise of composite amalgamation. The researchers mix resin and fiberglass composite materials with the various types of studio waste. The primary objective is to achieve creative outcomes with unconventional and unique finishes. The technique, philosophical and symbolic application, and usage of these materials in creating distinct art pieces including an exclusive “African woman” offer intriguing insights. The study reveals that the studio can efficiently repurpose waste materials, creating new cast materials for sculptures and ceramic works with distinctive and non-traditional finishes. This highlights the intrinsic transforming capacity of disposable waste materials, presenting a compelling opportunity for new and sustainable artistic practice where material finishes are not concealed.

这项研究回收利用工作室废弃的材料,如破碎的陶瓷、玻璃碎片、锯末和碎裂的 P.O.P 模具,创造出具有视觉冲击力的创意作品。这项研究的灵感来源于雕塑和陶瓷专业学生在工作室学习过程中产生的大量废弃物。以工作室为基础,利用美学行动研究设计的研究方法,系统地探索了复合材料混合物的可行性和前景。研究人员将树脂和玻璃纤维复合材料与各种工作室废弃物混合在一起。主要目的是通过非常规和独特的表面处理实现创造性成果。这些材料在创作独特艺术作品(包括独一无二的 "非洲女人")过程中的技术、哲学和象征意义的应用和使用提供了耐人寻味的见解。研究显示,工作室可以有效地将废弃材料重新利用,为雕塑和陶瓷作品创造新的铸造材料,并进行独特和非传统的表面处理。这凸显了一次性废弃材料的内在转化能力,为新的、可持续的艺术实践提供了一个令人信服的机会,材料的表面处理不会被掩盖。
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引用次数: 0
Exploratory analysis of zero waste theory to examine consumer perceptions of sustainability: A covariance-based structural equation modeling (CB-SEM) 探索性分析零废弃物理论,研究消费者对可持续发展的看法:基于协方差的结构方程建模(CB-SEM)
Pub Date : 2024-03-30 DOI: 10.1016/j.clwas.2024.100146
Tamás Vinkóczi, Éva Heimné Rácz, Judit Petra Koltai

Introduction

The analysis of corporate and consumer sustainability practices is currently the focus of several scientific disciplines due to their environmental impact and diversity.

Objective

This research aims to create a hierarchy of consumer perceptions of zero waste thinking that can guide government decisions regarding university communities' sustainability efforts. To achieve the objectives of this study, Hungarian university citizens (students, faculty, staff) as potential zero waste consumers in Győr were involved in a purposive sampling approach.

Methods

This study adopted the Covariance-Based Structural Equation Modeling (CB-SEM) methodology to prove the hypotheses related to the 7Rs regarding Zero Waste perceptions of university citizens. The rethink element of the hierarchy was defined as the default condition for the 7 R application and therefore remained at the top of the hierarchy as an endogenous variable.

Results

The study concluded that it is possible to adapt a business 7 R framework for consumer use, but only 5Rs can be applied. The analysis was conducted at a 90% confidence level, under which condition the independent variables together explain 87% of the variance of the rethink factor. The results show that the four constructs, namely rot (β =0.12, ρ<0.1), reduce (β =0.21, ρ<0.1), recycle (β =0.26, ρ<0.05), and reuse (β =0.43, ρ<0.05) significantly affect rethinking. Based on these regression weights, a hierarchy of importance can be established. In line with the original 7 R business concept, rethink is at the top of the hierarchy, followed by the other elements.

Conclusions

The results suggest that the zero waste attitudes of university citizens are currently limited to the 5Rs, which should require government leadership to strengthen these factors or a more consistent presence and support for the 2Rs that are missing from the established model. Governments can use the results of this research in their sustainability-related decisions.

导言由于企业和消费者的可持续发展实践对环境的影响和多样性,对其进行分析是目前多个科学学科的重点。研究目的本研究旨在建立消费者对零废弃物思想的认知层次,以指导政府对大学社区的可持续发展努力做出决策。为了实现本研究的目标,匈牙利 Győr 大学的潜在零废弃物消费者(学生、教职员工)参与了有目的的抽样调查。方法本研究采用了基于协方差的结构方程建模(CB-SEM)方法来证明与 7R 有关的假设,即大学公民对零废弃物的看法。层次结构中的反思要素被定义为 7R 应用的默认条件,因此作为内生变量仍处于层次结构的顶端。结果研究得出结论,有可能将商业 7R 框架调整为消费者使用,但只能应用 5R。分析是在 90% 的置信度下进行的,在此条件下,自变量共同解释了重新思考因子 87% 的方差。结果显示,腐烂(β =0.12,ρ<0.1)、减少(β =0.21,ρ<0.1)、回收(β =0.26,ρ<0.05)和再利用(β =0.43,ρ<0.05)这四个构念对反思有显著影响。根据这些回归权重,可以建立一个重要性等级体系。结果表明,大学生的零废弃态度目前仅限于 5R,这就需要政府领导加强这些因素,或对既定模型中缺失的 2R 提供更一致的存在和支持。各国政府可将本研究的结果用于其与可持续发展相关的决策中。
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引用次数: 0
Environmental assessment of construction waste prevention: A case study in a social housing project in Southeast Brazil 防止建筑垃圾产生的环境评估:巴西东南部社会住房项目案例研究
Pub Date : 2024-03-18 DOI: 10.1016/j.clwas.2024.100145
Beatriz Leão Evangelista de Lara, Carmenlucia Santos Giordano Penteado

This study analyzed construction waste prevention measures applied to a social housing project, with life cycle assessment (LCA), by three scenarios: base case scenario (BCS) – a single family house built with masonry blocks; prevention scenario 1 (PS1) – BCS assuming a theoretical optimization in materials consumption; prevention scenario 2 (PS2) – a house built with cast-in-situ concrete walls. The prevention scenarios showed waste reductions of 4% (PS1) and 36% (PS2). The environmental impacts have been evaluated by using CML baseline v.3.05; the impact categories were selected according to the EN 15.978:2011: global warming potential (GWP), acidification (AP), eutrophication (EP), ozone layer depletion (ODP), photochemical ozone formation (POF), abiotic depletion (AD), and abiotic depletion – fossil fuels (ADF). The PS1 reduced environmental impacts by 5% whereas PS2 increased by 15%, compared with BCS. The most critical construction steps for BCS and PS1 were coating and superstructure, whereas for PS2 were superstructure and painting. The materials extraction and production stage represent about 90% of the total impacts. The most critical materials for BCS and PS1 were concrete, cement, and steel, whereas for PS2 those were concrete, steel, and paint. The most relevant categories for the three scenarios analyzed were GWP, ADF, and AP. The waste management stage was irrelevant in generating impacts, contributing for less than 1% of the total impacts. These results highlight that despite reducing waste generation, prevention does not necessarily reduce the overall impacts of the edification, and therefore, the materials and construction methods used are especially relevant.

本研究通过生命周期评估(LCA)分析了应用于社会住房项目的建筑垃圾预防措施,包括三种方案:基础方案(BCS)--使用砖石砌块建造的单户住宅;预防方案 1(PS1)--假定材料消耗理论上优化的基础方案;预防方案 2(PS2)--使用现浇混凝土墙建造的住宅。这些预防方案分别减少了 4% (PS1)和 36% (PS2)的废物。使用 CML baseline v.3.05 对环境影响进行了评估;根据 EN 15.978:2011 选择了影响类别:全球升温潜能值 (GWP)、酸化 (AP)、富营养化 (EP)、臭氧层破坏 (ODP)、光化学臭氧形成 (POF)、非生物损耗 (AD) 和非生物损耗 - 化石燃料 (ADF)。与 BCS 相比,PS1 对环境的影响减少了 5%,而 PS2 则增加了 15%。BCS 和 PS1 最关键的施工步骤是涂层和上层建筑,而 PS2 则是上层建筑和喷漆。材料开采和生产阶段约占总影响的 90%。对 BCS 和 PS1 来说,最关键的材料是混凝土、水泥和钢材,而对 PS2 来说,最关键的材料是混凝土、钢材和油漆。在分析的三种方案中,最相关的类别是 GWP、ADF 和 AP。废物管理阶段产生的影响无关紧要,只占总影响的不到 1%。这些结果突显出,尽管减少了废物的产生,但预防并不一定会减少教育的总体影响,因此,所使用的材料和施工方法尤为重要。
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引用次数: 0
Municipal solid waste management in Scandinavia and key factors for improved waste segregation: A review 斯堪的纳维亚半岛的城市固体废物管理以及改进废物分类的关键因素:综述
Pub Date : 2024-03-14 DOI: 10.1016/j.clwas.2024.100144
Arifin Sandhi, Joacim Rosenlund

The generation of solid waste, more specifically municipal solid waste (MSW), has been considered one of the major global environmental problems since urbanization started. Among Scandinavian states, Denmark and Norway have placed in the top positions (1 and 2 respectively) for high MSW production. Sweden has a steady plan for MSW management/treatments by practising material recycle, biological treatment and energy recovery. The aim of this review is to compare municipal waste generation between Sweden and the rest of Scandinavia. A systematic literature review was performed by screening academic and public articles to assess factors for better MSW management based on technological solutions. Key results include the importance of new tariffs and legislations, producer responsibilities for electronic products, municipality involvement, distribution of responsibilities, and infrastructure developments for better MSW management in Sweden. The application of modern technologies have also been considered for MSW management in Sweden. Societal participation (willingness, awareness and concern) in Sweden also plays a significant role in MSW management. A better packaging system, application of interactive visualization (gamification) in waste sorting, public awareness, and infrastructure development could significantly improve the waste sorting process and conversion of waste management from a linear economy towards a circular economy.

自城市化开始以来,固体废弃物,特别是城市固体废弃物(MSW)的产生一直被认为是全球主要环境问题之一。在斯堪的纳维亚国家中,丹麦和挪威的城市固体废弃物产量位居前列(分别为第 1 位和第 2 位)。瑞典通过实行材料循环利用、生物处理和能源回收,制定了稳定的城市固体废物管理/处理计划。本综述旨在比较瑞典和斯堪的纳维亚半岛其他国家的城市垃圾产生量。通过筛选学术和公开文章,进行了系统的文献综述,以评估基于技术解决方案更好地管理城市固体废物的因素。主要结果包括新关税和立法的重要性、电子产品的生产者责任、市政参与、责任分配和基础设施发展对瑞典更好地管理城市固体废物的重要性。现代技术的应用也被纳入了瑞典城市固体废物管理的考虑范围。瑞典的社会参与(意愿、意识和关注)在 MSW 管理中也发挥着重要作用。一个更好的包装系统、互动可视化(游戏化)在垃圾分类中的应用、公众意识以及基础设施的发展,都能显著改善垃圾分类过程,并将垃圾管理从线性经济转变为循环经济。
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引用次数: 0
Transforming melange fabric waste into mélange yarn employing compact, Siro, and compact-Siro spinning: A cleaner and sustainable strategy 利用紧密纺、Siro 纺和紧密-Siro 纺将混合织物废料转化为混合纱线:更清洁、更可持续的战略
Pub Date : 2024-03-11 DOI: 10.1016/j.clwas.2024.100142
Ahmed Jalal Uddin , Purudeb Roy

The concept of sustainable and eco-friendly production of textiles has gained significant traction in recent years. Utilizing sustainable raw materials, processes, and recycling methods are fundamental strategies in the development of cleaner and more eco-conscious textile manufacturing. The current work reports a sustainable approach to manufacturing melange yarn from recycled fibers shredded from pre-consumer cotton/viscose mélange fabric waste. The recycled fibers obtained by the shredding method are short and lumpy, necessitating the blending with virgin fibers which serve as carriers throughout the spinning process. In the traditional ring spinning system, the poor inter-fiber cohesion, especially shorter recycled fibers, inhibits achieving the optimum yarn quality. With a view to their better control during spinning, advanced spinning systems such as Siro, compact and compact-Siro spinning were adopted. Experimental results revealed that all these spinning systems led to superior yarn qualities. Among them, yarn produced with compact-Siro spinning demonstrated the most significant improvements in yarn structure (reduced hairiness, unevenness & imperfections) and properties (increased strength & elongation). Through adept engineering and precise process control, 30-Ne (19.68 Tex) melange yarns containing up to 60% recycled mélange fiber were successfully produced. These melange yarns proved to be suitable for manufacturing knit fabrics with aesthetics similar to commercial mélange fabrics. The innovation of producing melange yarn, incorporating 60% recycled fibers, introduces a revolutionary concept aimed at supporting the Sustainable Development Goal (SDG) 12. This initiative aims to reduce the reliance on production of viscose, and cultivating and processing cotton, thereby making significant contributions to environmental conservation in various dimensions. Moreover, embracing this approach offers the potential for cost savings in the production of melange clothing.

近年来,可持续和生态友好型纺织品生产的概念得到了广泛关注。利用可持续原材料、工艺和回收方法是发展更清洁、更具生态意识的纺织品生产的基本战略。目前的研究报告介绍了一种利用从消费前棉花/粘胶混合织物废料中粉碎的回收纤维制造混合纱线的可持续方法。通过切碎法获得的回收纤维较短且呈块状,因此必须与原生纤维混合,原生纤维在整个纺纱过程中充当载体。在传统的环锭纺纱系统中,纤维间的凝聚力较差,尤其是较短的回收纤维,阻碍了纱线质量的优化。为了在纺纱过程中更好地控制纤维,我们采用了先进的纺纱系统,如 Siro 纺纱系统、紧密纺纱系统和紧密-Siro 纺纱系统。实验结果表明,所有这些纺纱系统都能生产出质量上乘的纱线。其中,采用紧密-锡罗纺纱生产的纱线在纱线结构(毛羽、不匀度和纱疵减少)和性能(强力和伸长率提高)方面的改善最为显著。通过精湛的工程设计和精确的工艺控制,成功生产出了含有高达 60% 再生混合纤维的 30-Ne (19.68 Tex)混合纱线。事实证明,这些法兰绒纱线适用于生产针织面料,其美观度与商用法兰绒面料相似。生产含有 60% 再生纤维的法兰绒纱线这一创新引入了一个革命性的概念,旨在支持可持续发展目标(SDG)12。这一举措旨在减少对粘胶生产、棉花种植和加工的依赖,从而在多个方面为环境保护做出重大贡献。此外,采用这种方法还可在生产混色服装时节约成本。
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引用次数: 0
Heat input optimization for the ignition of self-sustained smoldering remediation of contaminated soils using concentrated solar power 利用聚光太阳能点燃受污染土壤自持焚烧修复技术的热输入优化
Pub Date : 2024-03-11 DOI: 10.1016/j.clwas.2024.100143
Corey M. Trujillo , Nathaniel Saldana Campos , Daniel C. Segal , Karl G. Linden

In this paper, we explore the industrial-scale feasibility of using concentrated solar power (CSP) as the heat source in the smoldering remediation of petroleum-contaminated soil. Approximately 5 L soil samples were loaded in a narrow-channel reaction chamber and heated from the bottom with CSP to identify the required heat input to achieve ignition. Both petroleum and granular activated carbon (GAC) were used as combustible media. GAC was selected as a cleaner-burning alternative to petroleum and could emulate petroleum-contaminated soil at a mixture of 40 g GAC per kg pool sand on a 1.5 cm bed of GAC. This mixture of GAC showed robust ignition with a minimum power input of 240 W, which was slightly higher than the power input required to ignite industrially generated petroleum-contaminated soil. Preheat temperatures in excess of 300°C were achieved in most experiments, allowing for robust ignition of the smoldering remediation process. CSP was collected using parabolic reflectors 600 mm in diameter and was delivered to the reaction chamber with fiber optic bundles. Each solar concentrator delivered between 50 and 80 W to the reaction chamber, and four concentrators were required to reliably achieve the required power input.

本文探讨了利用聚光太阳能(CSP)作为热源对石油污染土壤进行烟熏修复的工业规模可行性。将大约 5 升的土壤样本装入一个窄通道反应室,用 CSP 从底部加热,以确定实现点火所需的输入热量。石油和颗粒活性炭 (GAC) 都被用作可燃介质。GAC 被选为石油的清洁燃烧替代物,可以模拟石油污染的土壤,在 1.5 厘米的 GAC 床上每公斤池沙混合 40 克 GAC。这种 GAC 混合物显示出强大的点火能力,最低输入功率为 240 W,略高于点燃工业生产的石油污染土壤所需的输入功率。在大多数实验中,预热温度都超过了 300°C,从而实现了对燃烧的修复过程的强力点火。利用直径为 600 毫米的抛物面反射器收集 CSP,并通过光纤束输送到反应室。每个太阳能聚光器向反应室提供 50 到 80 瓦的功率,需要四个聚光器才能可靠地达到所需的功率输入。
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引用次数: 0
A comprehensive analysis of the barriers to effective construction and demolition waste management: A bibliometric approach 全面分析有效管理建筑和拆除废物的障碍:文献计量学方法
Pub Date : 2024-03-09 DOI: 10.1016/j.clwas.2024.100141
Gulden Gumusburun Ayalp , Merve Anaç

The past few decades have witnessed a significant increase in the generation of construction and demolition (C&D) waste, posing a considerable sustainability challenge for the construction industry and environmental sustainability efforts. Due to its detrimental environmental effects, reducing C&D waste has become a crucial priority. However, the construction industry encounters various obstacles to effectively managing C&D waste. This research is centered on a comprehensive examination of these challenges. A systematic literature review was conducted, and the RStudio Bibliometrix package was used to analyze the barriers. This study thoroughly assessed 72 articles concerning C&D waste management (CDWM) from 2003 to 2023, sourced from the Web of Science database. The results revealed five distinct clusters of CDWM barriers, namely “managerial barriers,” “culturally ingrained waste behaviors in the construction industry,” “financial barriers,” “challenges in waste quantification,” and “insufficient information modeling.” This study makes a significant contribution to the existing literature on C&D waste management by applying quantitative analytical analyses via RStudio software, such as trend topic analysis, h-index, cluster analysis, and thematic mapping, which provide a deeper insight into the domain of CDWM barriers. Unlike previous studies, this work offers a holistic exploration of CDWM barriers and the intellectual structure within the field. This study advances the understanding of CDWM barriers by offering innovative quantitative methodologies and comprehensive insights. It is a valuable resource for researchers and practitioners seeking to address CDWM challenges, ultimately promoting sustainable practices in the construction industry.

过去几十年来,建筑和拆除(C&D)废物的产生量大幅增加,给建筑业和环境可持续发展工作带来了巨大挑战。由于其对环境的有害影响,减少建筑和拆除废物已成为当务之急。然而,建筑业在有效管理 C&D 废弃物方面遇到了各种障碍。本研究的核心就是全面考察这些挑战。研究人员进行了系统的文献综述,并使用 RStudio Bibliometrix 软件包对障碍进行了分析。本研究全面评估了 2003 年至 2023 年期间有关 C&D 废物管理 (CDWM) 的 72 篇文章,这些文章均来自 Web of Science 数据库。结果发现了五类不同的 CDWM 障碍,即 "管理障碍"、"建筑行业根深蒂固的废物行为文化"、"财务障碍"、"废物量化挑战 "和 "信息模型不足"。本研究通过 RStudio 软件应用定量分析方法,如趋势主题分析、h 指数、聚类分析和主题图谱等,对现有的建筑和加固行业废物管理文献做出了重要贡献,从而对建筑和加固行业废物管理障碍领域有了更深入的了解。与以往的研究不同,本研究对 CDWM 障碍和该领域的知识结构进行了全面的探讨。本研究通过提供创新的定量方法和全面的见解,推进了对 CDWM 障碍的理解。它是研究人员和从业人员应对 CDWM 挑战的宝贵资源,最终将促进建筑行业的可持续发展实践。
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引用次数: 0
Investigating waste recycling intentions of top management in Bangladesh's leather industry: A hybrid analytical framework 调查孟加拉国皮革业高层管理人员的废物回收意向:混合分析框架
Pub Date : 2024-03-08 DOI: 10.1016/j.clwas.2024.100140
Md Shamimul Islam , Najmul Hasan , Mohammad Shahidul Islam , Tania Akter , Muhtasim Fuad Rafsun , Mr. Mahmudul Hasan Fouji

The leather industry in Bangladesh grapples with significant environmental challenges related to harmful waste discharge, intensifying the urgency for industry leaders to address pollution concerns through effective waste management. In light of this, waste recycling becomes a viable avenue to mitigate environmental degradation. However, limited research exists that specifically focuses on the behavioral inclination of top management toward waste recycling, especially within the context of the leather industry. To address this literature gap, this research seeks to investigate the intention of top management to recycle waste in Bangladesh's leather industry. The foundational theoretical framework for constructing the research structure is the Theory of Planned Behavior (TPB). A hybrid multi-method technique was employed, combining Structural Equation Modeling (SEM) and fuzzy-set Qualitative Comparative Analysis (fsQCA) approaches to uncover symmetric and asymmetric effects of various antecedents on waste recycling intention. The PLS-SEM findings reveal a significant impact of attitude, perceived behavioral control, and perceived environmental concern on the intention to recycle waste. While fsQCA results suggest the continued importance of subjective norms in the model by revealing its moderate causal impact, a finding that diverges from the initial PLS-SEM results, which found it to be non-significant. The study extends and contextualizes the TPB theory in waste recycling intention and applies a hybrid method, making significant contributions to the existing literature. Furthermore, these findings offer valuable insights for practitioners and policymakers in the leather industry, aiding in crafting impactful interventions to foster pro-environmental actions.

孟加拉国的皮革业面临着与有害废物排放有关的重大环境挑战,行业领导者迫切需要通过有效的废物管理来解决污染问题。有鉴于此,废物回收利用成为缓解环境恶化的可行途径。然而,专门针对高层管理人员对废物回收利用的行为倾向,尤其是在皮革行业背景下的废物回收利用行为倾向的研究十分有限。为了填补这一文献空白,本研究试图调查孟加拉国皮革业高层管理者对废物回收利用的意向。构建研究结构的基础理论框架是计划行为理论(TPB)。研究采用了混合多方法技术,结合结构方程建模(SEM)和模糊集定性比较分析(fsQCA)方法,以揭示各种前因对废物回收意向的对称和非对称影响。PLS-SEM 的研究结果表明,态度、感知行为控制和感知环境关注对废物回收意向有显著影响。而 fsQCA 的结果表明,主观规范在模型中仍然具有重要意义,它显示出中等程度的因果影响,这一结果与最初的 PLS-SEM 结果不同,最初的 PLS-SEM 发现主观规范并不显著。本研究扩展了废物回收意向中的 TPB 理论,并将其应用于混合方法中,为现有文献做出了重要贡献。此外,这些研究结果还为皮革行业的从业人员和政策制定者提供了宝贵的见解,有助于制定有影响力的干预措施来促进环保行动。
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引用次数: 0
Physicochemical characterization, valorization of lignocellulosic waste (Kola nut seed shell) via pyrolysis, and ultrasonication of its crude bio-oil for biofuel production 木质纤维素废料(柯拉果壳)的物理化学特征、热解增值以及用于生产生物燃料的粗生物油的超声波处理
Pub Date : 2024-02-20 DOI: 10.1016/j.clwas.2024.100138
Abiodun Oluwatosin Adeoye , Rukayat Oluwatobiloba Quadri , Olayide Samuel Lawal , Emmanuel Oghenero Emojevu

Kola nut seed shell is a largely generated food waste that can be explored as an alternative energy source to reduce the damaging effects of the combustion of fossil fuels on the environment and reduce its usage since it’s limited in nature. The seed shell’s proximate and ultimate data were obtained using standard procedures; ash deposition indices were obtained using XRF data; crystallinity of its cellulosic component was determined using XRD data; pyrolysis was done using a fixed bed pyrolyzer; and ultrasonication of crude bio-oil and its alcoholic blends was done using an ultrasound bath rated at 55 W. Its shell has moderate Moisture Content (MC) (5.84%), high C (51.92%), low amounts of S (0.020%), N (0.11%), ash content (5.26%), high VM (84.85%), Fixed Carbon (FC) (4.05%), C/N (472), H/C (0.096), and Higher Heating Value (HHV) (17.23 MJ/kg). Its mass ratio combination gave the empirical formula CH0.096O0.82N0.002. It pyrolytically degrades at a thermal temperature range of 400–550 °C. XRF analysis of its ash base on Na2O+K2O/SiO2 was 0.0897, which means no sintering inclination; B/A (0.27, low ash deposition tendency); SiO2/Al2O3 (22.92) and Fe2O3/CaO (0.135) (low and high ash deposition tendencies, respectively); slagging viscosity index (83.48, high slagging tendency); %SiO2 (71.52); babcock (Rs, 5.4 × 10−5); fouling indices (1.7 × 10−2, low deposition tendencies); and total alkalis (0.0642, low fouling tendency). GC and FTIR of the upgraded bio-oil showed complex compounds suitable as biofuel. Its co-pyrolysis with other biomass could reduce fouling, sintering, ash, and corrosion issues.

科拉果籽壳是一种主要由食物产生的废弃物,可作为一种替代能源进行开发,以减少化石燃料燃烧对环境的破坏性影响,并减少其使用量,因为它在自然界中是有限的。种壳的近似和最终数据采用标准程序获得;灰分沉积指数采用 XRF 数据获得;纤维素成分的结晶度采用 XRD 数据确定;热解采用固定床热解器进行;粗生物油及其酒精混合物的超声波处理采用额定功率为 55 W 的超声波浴进行。其外壳的水分含量(MC)适中(5.84%),C 含量高(51.92%),S 含量低(0.020%),N 含量低(0.11%),灰分含量低(5.26%),VM 含量高(84.85%),固定碳(FC)含量高(4.05%),C/N 含量高(472),H/C 含量低(0.096),热值高(17.23 MJ/kg)。其质量比组合的经验公式为 CH0.096O0.82N0.002。其热解降解温度范围为 400-550 ℃。通过 XRF 分析,其灰基 Na2O+K2O/SiO2 为 0.0897,即无烧结倾向;B/A(0.27,低灰沉积倾向);SiO2/Al2O3(22.92)和 Fe2O3/CaO(0.135)(分别为低灰沉积倾向和高灰沉积倾向);结渣粘度指数(83.48,高结渣倾向);%SiO2(71.52);Babcock(Rs,5.4×10-5);污垢指数(1.7×10-2,低沉积倾向);总碱(0.0642,低污垢倾向)。升级生物油的气相色谱和傅立叶变换红外光谱显示出适合用作生物燃料的复杂化合物。它与其他生物质共同热解可减少结垢、烧结、灰分和腐蚀问题。
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引用次数: 0
Combination of technologies for nutrient recovery from wastewater: A review 从废水中回收营养物的组合技术:综述
Pub Date : 2024-02-20 DOI: 10.1016/j.clwas.2024.100139
Natalia Rey-Martínez , Gemma Torres-Sallan , Nicolás Morales , Elvira Serra , Iemke Bisschops , Miriam H.A. van Eekert , Eduard Borràs , Sonia Sanchis

The growing human population is increasing the need for crop production, which has resulted in elevated requirements of Nitrogen-Phosphorous-Potassium (NPK) fertilisers. This tremendous demand cannot be sustained on traditional processes, which cause significant resource depletion and unacceptable environmental impacts due to their heavy reliance on fossil fuels. To overcome this, alternative sources to obtain fertilisers have been explored, including the recovery of nutrients from wastewater and waste streams. However, this approach faces several challenges, such as the dilution of the streams, low public acceptance, and lack of support. With the aim of surpassing these barriers, the present study provides a review of existing Research & Development (R&D) projects in the field, comparing the available technologies to identify the optimal train of technologies for nutrient recovery: Anaerobic Digestion followed by the valorisation of the digestate (directly or producing P-based fertilisers such as P salts, CaP, H3PO4 and P2O5) and the liquid fraction (obtaining struvite, ammonium sulphate/nitrate, and reclaimed water). Moreover, an innovative strategy for nutrient recovery based on the decentralised treatment of separated concentrated streams is proposed as a useful strategy for valorising nutrients, developing a Strengths, Weaknesses, Opportunities and Threats (SWOT) analysis. Finally, non-technological strategies are suggested to mainstream waste valorisation, aimed at overcoming social barriers by promoting stakeholder acceptance and producing recycled fertilisers with low associated rejection. Nutrient valorisation through the decentralised treatment of source separated waste/wastewater using optimised train of technologies seems a sustainable strategy for addressing the current and future massive demand of fertilisers.

不断增长的人口增加了对作物生产的需求,从而导致对氮磷钾(NPK)肥料的需求增加。这种巨大的需求无法依靠传统工艺来维持,因为传统工艺严重依赖化石燃料,会造成严重的资源损耗和不可接受的环境影响。为了克服这一问题,人们开始探索获取肥料的替代来源,包括从废水和废物流中回收养分。然而,这种方法面临着一些挑战,如废水稀释、公众接受度低以及缺乏支持等。为了克服这些障碍,本研究回顾了该领域现有的研究与开发(R&D)项目,对现有技术进行了比较,以确定营养物质回收的最佳技术组合:先进行厌氧消化,然后对沼渣(直接利用或生产以 P 为基础的肥料,如 P 盐、CaP、H3PO4 和 P2O5)和液体部分(获得硬石膏、硫酸铵/硝酸铵和再生水)进行增值。此外,通过对优势、劣势、机会和威胁(SWOT)进行分析,提出了一种基于分散处理分离浓缩水流的养分回收创新战略,作为一种有用的养分增值战略。最后,还提出了将废物价值化纳入主流的非技术战略,旨在通过促进利益相关者的接受度来克服社会障碍,并生产出相关排斥率较低的再生肥料。通过分散处理源头分离的废物/废水,利用优化的一系列技术进行养分增值,似乎是解决当前和未来肥料大量需求的一种可持续战略。
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引用次数: 0
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Cleaner Waste Systems
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