首页 > 最新文献

Ore and Energy Resource Geology最新文献

英文 中文
Evaluating the hydrocarbon potential of source rocks in Northern Borneo, Southeast Asia: a review of organic geochemical and petrological characteristics 东南亚北婆罗洲烃源岩含烃潜力评价:有机地球化学与岩石学特征综述
Pub Date : 2025-08-20 DOI: 10.1016/j.oreoa.2025.100112
Ayodele O. Falade , Yousif M. Makeen , Habeeb A. Ayinla , Abayomi A. Edema
This study provides a comprehensive review of hydrocarbon source rocks in Northern Borneo by integrating findings from previous organic geochemical and petrological studies across the Sabah, Sarawak, and Brunei basins. Unlike earlier basin-specific research, this work offers a broader regional perspective, evaluating sixteen (16) formations ranging from Late Cretaceous to Pleistocene. The majority of the samples exhibit good to excellent organic richness (mean total organic carbon (TOC) content exceeding 1 wt%, with promising S2 and S2/S3 ratios). The hydrogen index (HI) values (7.1 and 401.8 mg HC/g TOC) and HI vs. Oxygen Index (OI) plots indicate that the organic matter is primarily composed of Type II/III, Type III and Type IV kerogen. Remarkably, coal-related samples consistently show excellent organic richness, predominantly plotting within the Type II/III kerogen area, indicating a strong potential for mixed oil and gas generation. Other lithologies primarily contain gas-prone Type III kerogen, while Type IV is largely inert. The thermal maturity assessments, based on Tmax (324–570 °C) and production index (PI) (0.00–0.37), indicate a wide range from immature to overmature source rocks. Vitrinite reflectance (VRo) measurements (0.15–3.10 %) and Tmax vs VRo plots further confirm these maturity trends. The organic petrological analysis reveals that the vitrinite macerals dominate the liptinite and inertinite across all the formations, with coal-related source rocks exhibiting the highest maceral concentrations, reinforcing their generative capacity. Specifically, the coal-rich Nyalau, Tanjong, Liang, Batu Arang, Balingian, and Bergih formations stand out as highly promising, presenting substantial economic significance for unconventional plays such as coalbed methane (CBM). This review highlights the significant hydrocarbon potential across Northern Borneo, while also emphasizing the need for further assessment of the Brunei Basin to refine the current understanding of source rock distribution and quality within the regional petroleum system.
该研究通过整合先前在沙巴、沙捞越和文莱盆地进行的有机地球化学和岩石学研究结果,对北婆罗洲的烃源岩进行了全面的回顾。与早期的盆地特定研究不同,这项工作提供了更广阔的区域视角,评估了从晚白垩纪到更新世的16个地层。大部分样品表现出良好至优异的有机丰富度(平均总有机碳(TOC)含量超过1wt %,具有良好的S2和S2/S3比值)。氢指数(HI)值(7.1和401.8 mg HC/g TOC)和HI -氧指数(OI)图表明有机质主要由II/III型、III型和IV型干酪根组成。值得注意的是,煤类样品始终表现出优异的有机质丰度,主要分布在II/III型干酪根区,表明该区具有很强的混合油气生成潜力。其他岩性主要含有易气的III型干酪根,而IV型干酪根主要是惰性的。基于Tmax(324 ~ 570℃)和生产指数(PI)(0.00 ~ 0.37)的热成熟度评价表明,烃源岩从未成熟到过成熟的范围很广。镜质组反射率(VRo)测量值(0.15 - 3.10%)和Tmax vs VRo图进一步证实了这些成熟度趋势。有机岩石学分析表明,镜质组显微组分在各组中均占主导地位,其中煤系烃源岩显微组分含量最高,增强了烃源岩的生成能力。具体来说,富含煤炭的Nyalau、Tanjong、Liang、Batu Arang、Balingian和Bergih地层非常有前途,对煤层气(CBM)等非常规油气藏具有重大的经济意义。此次回顾强调了北婆罗洲的巨大油气潜力,同时也强调了对文莱盆地进行进一步评估的必要性,以完善目前对区域石油系统中烃源岩分布和质量的认识。
{"title":"Evaluating the hydrocarbon potential of source rocks in Northern Borneo, Southeast Asia: a review of organic geochemical and petrological characteristics","authors":"Ayodele O. Falade ,&nbsp;Yousif M. Makeen ,&nbsp;Habeeb A. Ayinla ,&nbsp;Abayomi A. Edema","doi":"10.1016/j.oreoa.2025.100112","DOIUrl":"10.1016/j.oreoa.2025.100112","url":null,"abstract":"<div><div>This study provides a comprehensive review of hydrocarbon source rocks in Northern Borneo by integrating findings from previous organic geochemical and petrological studies across the Sabah, Sarawak, and Brunei basins. Unlike earlier basin-specific research, this work offers a broader regional perspective, evaluating sixteen (16) formations ranging from Late Cretaceous to Pleistocene. The majority of the samples exhibit good to excellent organic richness (mean total organic carbon (TOC) content exceeding 1 wt%, with promising S<sub>2</sub> and S<sub>2</sub>/S<sub>3</sub> ratios). The hydrogen index (HI) values (7.1 and 401.8 mg HC/g TOC) and HI vs. Oxygen Index (OI) plots indicate that the organic matter is primarily composed of Type II/III, Type III and Type IV kerogen. Remarkably, coal-related samples consistently show excellent organic richness, predominantly plotting within the Type II/III kerogen area, indicating a strong potential for mixed oil and gas generation. Other lithologies primarily contain gas-prone Type III kerogen, while Type IV is largely inert. The thermal maturity assessments, based on T<sub>max</sub> (324–570 °C) and production index (PI) (0.00–0.37), indicate a wide range from immature to overmature source rocks. Vitrinite reflectance (VR<sub>o</sub>) measurements (0.15–3.10 %) and T<sub>max</sub> vs VR<sub>o</sub> plots further confirm these maturity trends. The organic petrological analysis reveals that the vitrinite macerals dominate the liptinite and inertinite across all the formations, with coal-related source rocks exhibiting the highest maceral concentrations, reinforcing their generative capacity. Specifically, the coal-rich Nyalau, Tanjong, Liang, Batu Arang, Balingian, and Bergih formations stand out as highly promising, presenting substantial economic significance for unconventional plays such as coalbed methane (CBM). This review highlights the significant hydrocarbon potential across Northern Borneo, while also emphasizing the need for further assessment of the Brunei Basin to refine the current understanding of source rock distribution and quality within the regional petroleum system.</div></div>","PeriodicalId":100993,"journal":{"name":"Ore and Energy Resource Geology","volume":"19 ","pages":"Article 100112"},"PeriodicalIF":0.0,"publicationDate":"2025-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144907564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of CO₂ treatment on fracture development and mineralogical composition in organic-rich and organic-lean unconventional reservoirs CO₂处理对富贫有机质非常规储层裂缝发育及矿物组成的影响
Pub Date : 2025-08-06 DOI: 10.1016/j.oreoa.2025.100111
Israa S. Abu-Mahfouz , Ahmed Al-Yaseri
Fracturing associated with carbon dioxide (CO2) treatment in unconventional hydrocarbon reservoirs presents a huge potential for CO2 geological sequestration in carbonate mudrock and shale reservoirs and the use of CO2 as a working fluid for oil recovery. This study aims to examine the impact of CO2 treatment on fracture growth and propagation in unconventional carbonate reservoirs. Experimental studies were conducted on both organic-rich (Jordanian) and organic-lean (Wolf Camp) mudrock samples and a careful examination of fracture initiation and propagation induced by CO2 treatment was examined. After an extensive 30-day treatment with carbonate brine (i.e., a mixture of brine and CO2) under 75 °C temperature and 4158 psi pressure, mineralogical and geochemical results revealed an increase in the carbonate mineral content (calcite) in the organic-rich sample, along with a decline in total organic carbon content from after CO2/carbonate brine treatment. The organic-lean sample, inversely, showed negligible change in the calcite content and almost no change in the total inorganic carbon. Microscopic investigations showed that the organic-rich sample exhibited a remarkable development of a new set of horizontal (bedding-parallel) microfractures, while the organic-lean sample did not display any significant fracture development. In addition, the surface roughness of the organic-rich sample increased significantly (from 20 to 37 uµ on average), after carbonate brine treatment, while the organic-lean sample showed a slight increase from 18 to 19 uµ. The outcomes of this study will be used to develop a comprehensive understanding of the mechanisms driving the fracture growth and propagation in organic-rich unconventional reservoirs induced by CO2 treatment, which can inform strategies to enhance oil/gas recovery. They will also aid in defining the potential benefits of CO2-induced fracturing for underground CO2 storage, such as improving the permeability and porosity of unconventional rock formations, and for oil recovery, such as enhancing the recovery factor.
非常规油气储层中与二氧化碳(CO2)处理相关的压裂为碳酸盐岩泥岩和页岩储层提供了巨大的二氧化碳地质封存潜力,并将二氧化碳作为采油的工作流体。本研究旨在研究CO2处理对非常规碳酸盐岩储层裂缝生长和扩展的影响。实验研究了富有机质(Jordanian)和贫有机质(Wolf Camp)泥岩样品,并仔细检查了CO2处理诱导的裂缝起裂和扩展。在75°C的温度和4158 psi的压力下,用碳酸盐卤水(即卤水和二氧化碳的混合物)进行了30天的处理后,矿物学和地球化学结果显示,富有机质样品中的碳酸盐矿物(方解石)含量增加,同时CO2/碳酸盐卤水处理后的总有机碳含量下降。相反,有机贫样品的方解石含量变化可以忽略不计,总无机碳几乎没有变化。显微研究表明,富有机质样品显示出一组新的水平(层理平行)微裂缝的显著发育,而贫有机质样品没有显示出明显的裂缝发育。碳酸盐卤水处理后,富有机物样品的表面粗糙度显著增加(平均从20到37 uµ),而贫有机物样品的表面粗糙度略有增加,从18到19 uµ。这项研究的结果将用于全面了解CO2处理诱导富有机质非常规油藏裂缝生长和扩展的机制,从而为提高油气采收率提供策略。它们还将有助于确定二氧化碳诱导压裂对地下二氧化碳储存的潜在好处,例如提高非常规岩层的渗透率和孔隙度,以及提高采收率,例如提高采收率。
{"title":"Impact of CO₂ treatment on fracture development and mineralogical composition in organic-rich and organic-lean unconventional reservoirs","authors":"Israa S. Abu-Mahfouz ,&nbsp;Ahmed Al-Yaseri","doi":"10.1016/j.oreoa.2025.100111","DOIUrl":"10.1016/j.oreoa.2025.100111","url":null,"abstract":"<div><div>Fracturing associated with carbon dioxide (CO<sub>2</sub>) treatment in unconventional hydrocarbon reservoirs presents a huge potential for CO<sub>2</sub> geological sequestration in carbonate mudrock and shale reservoirs and the use of CO<sub>2</sub> as a working fluid for oil recovery. This study aims to examine the impact of CO<sub>2</sub> treatment on fracture growth and propagation in unconventional carbonate reservoirs. Experimental studies were conducted on both organic-rich (Jordanian) and organic-lean (Wolf Camp) mudrock samples and a careful examination of fracture initiation and propagation induced by CO<sub>2</sub> treatment was examined. After an extensive 30-day treatment with carbonate brine (i.e., a mixture of brine and CO<sub>2</sub>) under 75 °C temperature and 4158 psi pressure, mineralogical and geochemical results revealed an increase in the carbonate mineral content (calcite) in the organic-rich sample, along with a decline in total organic carbon content from after CO<sub>2</sub>/carbonate brine treatment. The organic-lean sample, inversely, showed negligible change in the calcite content and almost no change in the total inorganic carbon. Microscopic investigations showed that the organic-rich sample exhibited a remarkable development of a new set of horizontal (bedding-parallel) microfractures, while the organic-lean sample did not display any significant fracture development. In addition, the surface roughness of the organic-rich sample increased significantly (from 20 to 37 uµ on average), after carbonate brine treatment, while the organic-lean sample showed a slight increase from 18 to 19 uµ. The outcomes of this study will be used to develop a comprehensive understanding of the mechanisms driving the fracture growth and propagation in organic-rich unconventional reservoirs induced by CO<sub>2</sub> treatment, which can inform strategies to enhance oil/gas recovery. They will also aid in defining the potential benefits of CO<sub>2</sub>-induced fracturing for underground CO<sub>2</sub> storage, such as improving the permeability and porosity of unconventional rock formations, and for oil recovery, such as enhancing the recovery factor.</div></div>","PeriodicalId":100993,"journal":{"name":"Ore and Energy Resource Geology","volume":"19 ","pages":"Article 100111"},"PeriodicalIF":0.0,"publicationDate":"2025-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144858282","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive review of advanced polymer gel technologies in enhanced oil recovery and water production control 先进聚合物凝胶技术在提高采收率和控制产水方面的综合综述
Pub Date : 2025-07-25 DOI: 10.1016/j.oreoa.2025.100109
Amir Javad Borhani, Fatemeh Ghazi, Ali Akbari, Ali Ranjbar, Yousef Kazemzadeh
Excessive water production is a major challenge in the petroleum industry, significantly reducing oil recovery efficiency and increasing operational costs by approximately $50 billion annually. Enhanced Oil Recovery (EOR) methods, such as thermal and non-thermal techniques, aim to improve oil production by altering reservoir and fluid properties. Thermal methods, including steam injection and electromagnetic heating (EMH), have shown oil production increases ranging from 11 % to 500 %, despite high initial costs and operational complexities. Non-thermal methods, such as polymer, surfactant, and alkaline injections, target light to medium viscosity oils, achieving oil recovery improvements between 5 % to 45 %. Chemical methods, particularly polymer gels, have gained prominence for their efficacy in controlling excessive water production and enhancing oil recovery. Polyacrylamide gels, known for their profile control capabilities, can increase oil recovery by 10–30 %. Recent advancements in microgels and nanogels offer better stability and compatibility with harsh reservoir conditions, such as high salinity and temperatures, resulting in recovery improvements up to 35 %. Field studies demonstrate the USA and Canada leading in EOR adoption, with polymer injection projects constituting over 80 % of chemical EOR applications. To further advance oil recovery and address excessive water production, continued research into optimizing polymer gel formulations and exploring new chemical EOR methods is essential. Tailoring EOR techniques to specific reservoir conditions, including temperature, salinity, and rock permeability, will enhance their effectiveness. The integration of nanoparticles into polymer gels shows promise for improving structural strength and performance, highlighting the need for innovative approaches in the petroleum industry.
过量的产水是石油行业面临的主要挑战,它会显著降低石油采收率,每年增加约500亿美元的运营成本。提高采收率(EOR)方法,如热技术和非热技术,旨在通过改变储层和流体性质来提高石油产量。尽管初始成本高,操作复杂,但包括蒸汽注入和电磁加热(EMH)在内的热方法已经表明,石油产量增加了11%到500%。非热方法,如聚合物、表面活性剂和碱性注入,针对轻粘度至中等粘度的油,可将采收率提高5%至45%。化学方法,特别是聚合物凝胶,因其在控制过量产水和提高采收率方面的有效性而受到重视。聚丙烯酰胺凝胶以其剖面控制能力而闻名,可以将石油采收率提高10 - 30%。微凝胶和纳米凝胶的最新进展提供了更好的稳定性和与恶劣储层条件(如高盐度和高温)的兼容性,使采收率提高了35%。现场研究表明,美国和加拿大在提高采收率方面处于领先地位,聚合物注入项目占化学提高采收率应用的80%以上。为了进一步提高采收率和解决过度产水问题,继续研究优化聚合物凝胶配方和探索新的化学提高采收率方法至关重要。根据特定的油藏条件(包括温度、盐度和岩石渗透率)定制EOR技术将提高其有效性。将纳米颗粒整合到聚合物凝胶中,有望提高结构强度和性能,这凸显了石油行业对创新方法的需求。
{"title":"A comprehensive review of advanced polymer gel technologies in enhanced oil recovery and water production control","authors":"Amir Javad Borhani,&nbsp;Fatemeh Ghazi,&nbsp;Ali Akbari,&nbsp;Ali Ranjbar,&nbsp;Yousef Kazemzadeh","doi":"10.1016/j.oreoa.2025.100109","DOIUrl":"10.1016/j.oreoa.2025.100109","url":null,"abstract":"<div><div>Excessive water production is a major challenge in the petroleum industry, significantly reducing oil recovery efficiency and increasing operational costs by approximately $50 billion annually. Enhanced Oil Recovery (EOR) methods, such as thermal and non-thermal techniques, aim to improve oil production by altering reservoir and fluid properties. Thermal methods, including steam injection and electromagnetic heating (EMH), have shown oil production increases ranging from 11 % to 500 %, despite high initial costs and operational complexities. Non-thermal methods, such as polymer, surfactant, and alkaline injections, target light to medium viscosity oils, achieving oil recovery improvements between 5 % to 45 %. Chemical methods, particularly polymer gels, have gained prominence for their efficacy in controlling excessive water production and enhancing oil recovery. Polyacrylamide gels, known for their profile control capabilities, can increase oil recovery by 10–30 %. Recent advancements in microgels and nanogels offer better stability and compatibility with harsh reservoir conditions, such as high salinity and temperatures, resulting in recovery improvements up to 35 %. Field studies demonstrate the USA and Canada leading in EOR adoption, with polymer injection projects constituting over 80 % of chemical EOR applications. To further advance oil recovery and address excessive water production, continued research into optimizing polymer gel formulations and exploring new chemical EOR methods is essential. Tailoring EOR techniques to specific reservoir conditions, including temperature, salinity, and rock permeability, will enhance their effectiveness. The integration of nanoparticles into polymer gels shows promise for improving structural strength and performance, highlighting the need for innovative approaches in the petroleum industry.</div></div>","PeriodicalId":100993,"journal":{"name":"Ore and Energy Resource Geology","volume":"19 ","pages":"Article 100109"},"PeriodicalIF":0.0,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144738660","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structure and mineralization in the Lebowa granite suite: Insights from high-resolution 2D reflection seismic method Lebowa花岗岩组的构造和成矿作用:来自高分辨率二维反射地震方法的见解
Pub Date : 2025-07-21 DOI: 10.1016/j.oreoa.2025.100108
Bibi Ayesha Jogee, Musa S.D. Manzi, Nombuso G. Maduna, Bojan Brodic, Moyagabo K. Rapetsoa, Ian James, Mpofana Sihoyiya, Glen T. Nwaila, Paul A.M. Nex, Leonidas Vonopartis
Rare Earth Elements (REEs) are critical metals that occur in various geological systems including granitic systems. The Lebowa Granite Suite (LGS) of the Bushveld Complex (South Africa) is known as an A-type granitic suite and hosts polymetallic mineralization including tin, fluorine and REE mineralization. High-resolution reflection seismic surveys were conducted to understand the structural architecture and mineralization within the farm boundaries of Blokspruit and Ruigtepoort in the LGS in the North West Province. Two-dimensional (2D) reflection seismic results show that the LGS is approximately 5 km thick in the western portion of the Bushveld Complex and is intruded by dolerite sills of the Umkondo large igneous province. The REE mineralization is structurally controlled and hosted within actinolite intrusive bodies. REE mineralization is associated with NW-SE and NE-SW trending faults, which acted as conduits for ore-forming fluids. In seismic sections, fault zones are delineated as highly attenuated seismic signatures that crosscut strong amplitude seismic horizons. Near the highly attenuated zones are high amplitude reflector packages (HARPs), which correspond to the actinolite intrusive bodies. We demonstrate the value of using the reflection seismic method as an effective and efficient exploration strategy to explore for geological structures that control REEs mineralization, and its potential to become a core component for mineral exploration in hard rock environments.
稀土元素(ree)是存在于包括花岗岩体系在内的各种地质体系中的重要金属。南非Bushveld杂岩的Lebowa花岗岩套件(LGS)被称为a型花岗岩套件,具有锡、氟和稀土矿化等多金属成矿作用。为了了解西北省LGS Blokspruit和Ruigtepoort农场边界内的构造结构和成矿作用,进行了高分辨率反射地震调查。二维反射地震结果表明,Bushveld杂岩体西部的LGS厚度约为5 km,并被Umkondo大火成岩省的白云岩断层侵入。稀土矿化受构造控制,赋存于放光石侵入体内。稀土矿化与NW-SE和NE-SW向断裂有关,为成矿流体提供了通道。在地震剖面中,断裂带被描绘成高度衰减的地震特征,横切强振幅地震层。在高衰减带附近是高振幅反射包体(HARPs),与放光石侵入体相对应。我们证明了反射地震方法作为一种有效和高效的勘探策略,在勘探控制稀土矿化的地质构造方面的价值,以及它在硬岩环境中成为矿产勘探核心组成部分的潜力。
{"title":"Structure and mineralization in the Lebowa granite suite: Insights from high-resolution 2D reflection seismic method","authors":"Bibi Ayesha Jogee,&nbsp;Musa S.D. Manzi,&nbsp;Nombuso G. Maduna,&nbsp;Bojan Brodic,&nbsp;Moyagabo K. Rapetsoa,&nbsp;Ian James,&nbsp;Mpofana Sihoyiya,&nbsp;Glen T. Nwaila,&nbsp;Paul A.M. Nex,&nbsp;Leonidas Vonopartis","doi":"10.1016/j.oreoa.2025.100108","DOIUrl":"10.1016/j.oreoa.2025.100108","url":null,"abstract":"<div><div>Rare Earth Elements (REEs) are critical metals that occur in various geological systems including granitic systems. The Lebowa Granite Suite (LGS) of the Bushveld Complex (South Africa) is known as an A-type granitic suite and hosts polymetallic mineralization including tin, fluorine and REE mineralization. High-resolution reflection seismic surveys were conducted to understand the structural architecture and mineralization within the farm boundaries of Blokspruit and Ruigtepoort in the LGS in the North West Province. Two-dimensional (2D) reflection seismic results show that the LGS is approximately 5 km thick in the western portion of the Bushveld Complex and is intruded by dolerite sills of the Umkondo large igneous province. The REE mineralization is structurally controlled and hosted within actinolite intrusive bodies. REE mineralization is associated with NW-SE and NE-SW trending faults, which acted as conduits for ore-forming fluids. In seismic sections, fault zones are delineated as highly attenuated seismic signatures that crosscut strong amplitude seismic horizons. Near the highly attenuated zones are high amplitude reflector packages (HARPs), which correspond to the actinolite intrusive bodies. We demonstrate the value of using the reflection seismic method as an effective and efficient exploration strategy to explore for geological structures that control REEs mineralization, and its potential to become a core component for mineral exploration in hard rock environments.</div></div>","PeriodicalId":100993,"journal":{"name":"Ore and Energy Resource Geology","volume":"19 ","pages":"Article 100108"},"PeriodicalIF":0.0,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144738658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geochemical characteristics of surface samples in the Mkuju River uranium project, southern Tanzania: implications for uranium geochemical exploration and provenance studies 坦桑尼亚南部Mkuju河铀项目地表样品的地球化学特征:对铀地球化学勘探和物源研究的影响
Pub Date : 2025-05-27 DOI: 10.1016/j.oreoa.2025.100107
Athanas S. Macheyeki , Dalaly P. Kafumu
Uranium occurrences in Tanzania are mainly associated with Karoo Formations, including the Namtumbo-Mkuju River and Madaba deposits. Additional occurrences are found in Quaternary-Holocene playa lake deposits in the Manyoni and Bahi areas (Central Tanzania), Galapo and Minjingu (Arusha region) and within magmatic and carbonatite systems at Chimala and Pandahill (Southwestern Tanzania). This study focuses on the Mkuju River uranium deposits in southern Tanzania to characterize elemental distributions, identify geochemical trends and determine uranium provenance. A total of 64 auger samples were collected from depths of 0–3 m at 1 km × 1 km grid intervals. Samples were analyzed using ICP-AES and ICP-MS following aqua regia digestion at SGS Laboratories (South Africa), with duplicates analyzed via XRF at the Geological Survey of Tanzania. Correlation coefficients (R) between uranium and other elements range from -0.07 (Ti) to 0.79 (Zn). Stronger correlations (R > 0.47) were observed between uranium and lithophile elements, or those with mixed lithophile-siderophile or chalcophile-siderophile behavior, indicating multiple uranium sources. Element thresholds varied with depth. Uranium, Sn and Sb showed increasing thresholds, whereas Hf, P, Ca, Zr, Co, Al, Ti, Rb, Sr, Na, Tl, Th, Mn and Cr decreased. Uranium concentrations exceeding 4.65 ppm are considered anomalous. Downhole threshold variability was element-specific. For example, W showed 0 % variability, Mo (siderophile / chalcophile) 12 %, and Cu, Ga, Sn (chalcophile / lithophile) ranged from 10 to 29 %. HFSE lithophiles like Hf and Ta varied by 12–25 %, while chalcophiles such as Zn, Pb, In, As, Tb, Bi, Ag and Cd ranged from 4 to 26 %. Siderophile / chalcophile elements like Co, Fe, Sb and Ni exhibited 6–29 % variability. Lithophiles (e.g., U, V, K, Al, Ce, Mg) varied by 5–40 %. Mn, a siderophile, had the highest variability at 43 %. Geochemical data suggest uranium anomalies in the Namtumbo area originate mainly from greywackes, arkosic sandstones, black shales and partially from weathered igneous granites. This implies a multi-source origin involving sedimentary input, hydrothermal diagenesis and hydrothermal magmatic-volcanic activity. Therefore, uranium in this basin likely formed through (1) syn-sedimentary processes, (2) diagenetic alteration, and (3) magmatic-hydrothermal systems. However, the absence of Eh and pH data limits insight into element mobility. These findings provide new insights into downhole element threshold variability and uranium provenance, offering valuable guidance for exploration geoscientists. The approach may be applied to similar geological contexts for improved sampling strategies and anomaly detection.
坦桑尼亚的铀矿主要与Karoo组有关,包括Namtumbo-Mkuju河和Madaba矿床。在坦桑尼亚中部的Manyoni和Bahi地区,Galapo和Minjingu(阿鲁沙地区)以及Chimala和Pandahill(坦桑尼亚西南部)的岩浆和碳酸盐岩系统中,还发现了第四纪-全新世的playa湖矿床。本研究的重点是坦桑尼亚南部的Mkuju河铀矿床,以表征元素分布,确定地球化学趋势和确定铀的来源。以1 km × 1 km栅格间隔从0 ~ 3 m深度共采集了64个螺旋钻样品。样品在SGS实验室(南非)使用ICP-AES和ICP-MS对王水消解后进行分析,在坦桑尼亚地质调查局使用XRF对重复样品进行分析。铀与其他元素的相关系数R范围为-0.07 (Ti) ~ 0.79 (Zn)。更强的相关性(R >;铀与亲石元素之间存在0.47),或具有亲石-亲铁或亲铜-亲铁混合行为,表明铀源多。元素阈值随深度而变化。铀、Sn、Sb的阈值呈上升趋势,Hf、P、Ca、Zr、Co、Al、Ti、Rb、Sr、Na、Tl、Th、Mn、Cr的阈值呈下降趋势。铀浓度超过4.65 ppm被认为是异常的。井下阈值变异性是元素特定的。例如,W的变异率为0%,Mo(亲铁/亲铜)的变异率为12%,Cu、Ga、Sn(亲铜/亲石)的变异率为10%至29%。HFSE亲石剂如Hf和Ta变化幅度为12 - 25%,而亲铜剂如Zn、Pb、In、as、Tb、Bi、Ag和Cd变化幅度为4 - 26%。亲铁/亲铜元素如Co、Fe、Sb和Ni表现出6 - 29%的变异性。亲石剂(如U、V、K、Al、Ce、Mg)变化幅度为5 - 40%。Mn是一种亲铁物质,其变异率最高,为43%。地球化学资料表明,南腾博地区铀异常主要来源于灰岩、黑砂岩、黑色页岩,部分来源于风化火成岩花岗岩。这暗示了沉积输入、热液成岩作用和热液岩浆-火山活动的多源成因。因此,该盆地的铀可能通过(1)同沉积作用、(2)成岩蚀变作用和(3)岩浆-热液系统形成。然而,缺乏Eh和pH数据限制了对元素迁移率的了解。这些发现为认识井下元素阈值变异性和铀矿物源提供了新的思路,为勘探地球科学家提供了有价值的指导。该方法可以应用于类似的地质环境,以改进采样策略和异常检测。
{"title":"Geochemical characteristics of surface samples in the Mkuju River uranium project, southern Tanzania: implications for uranium geochemical exploration and provenance studies","authors":"Athanas S. Macheyeki ,&nbsp;Dalaly P. Kafumu","doi":"10.1016/j.oreoa.2025.100107","DOIUrl":"10.1016/j.oreoa.2025.100107","url":null,"abstract":"<div><div>Uranium occurrences in Tanzania are mainly associated with Karoo Formations, including the Namtumbo-Mkuju River and Madaba deposits. Additional occurrences are found in Quaternary-Holocene playa lake deposits in the Manyoni and Bahi areas (Central Tanzania), Galapo and Minjingu (Arusha region) and within magmatic and carbonatite systems at Chimala and Pandahill (Southwestern Tanzania). This study focuses on the Mkuju River uranium deposits in southern Tanzania to characterize elemental distributions, identify geochemical trends and determine uranium provenance. A total of 64 auger samples were collected from depths of 0–3 m at 1 km × 1 km grid intervals. Samples were analyzed using ICP-AES and ICP-MS following aqua regia digestion at SGS Laboratories (South Africa), with duplicates analyzed via XRF at the Geological Survey of Tanzania. Correlation coefficients (R) between uranium and other elements range from -0.07 (Ti) to 0.79 (Zn). Stronger correlations (<em>R</em> &gt; 0.47) were observed between uranium and lithophile elements, or those with mixed lithophile-siderophile or chalcophile-siderophile behavior, indicating multiple uranium sources. Element thresholds varied with depth. Uranium, Sn and Sb showed increasing thresholds, whereas Hf, P, Ca, Zr, Co, Al, Ti, Rb, Sr, Na, Tl, Th, Mn and Cr decreased. Uranium concentrations exceeding 4.65 ppm are considered anomalous. Downhole threshold variability was element-specific. For example, W showed 0 % variability, Mo (siderophile / chalcophile) 12 %, and Cu, Ga, Sn (chalcophile / lithophile) ranged from 10 to 29 %. HFSE lithophiles like Hf and Ta varied by 12–25 %, while chalcophiles such as Zn, Pb, In, As, Tb, Bi, Ag and Cd ranged from 4 to 26 %. Siderophile / chalcophile elements like Co, Fe, Sb and Ni exhibited 6–29 % variability. Lithophiles (e.g., U, V, K, Al, Ce, Mg) varied by 5–40 %. Mn, a siderophile, had the highest variability at 43 %. Geochemical data suggest uranium anomalies in the Namtumbo area originate mainly from greywackes, arkosic sandstones, black shales and partially from weathered igneous granites. This implies a multi-source origin involving sedimentary input, hydrothermal diagenesis and hydrothermal magmatic-volcanic activity. Therefore, uranium in this basin likely formed through (1) syn-sedimentary processes, (2) diagenetic alteration, and (3) magmatic-hydrothermal systems. However, the absence of Eh and pH data limits insight into element mobility. These findings provide new insights into downhole element threshold variability and uranium provenance, offering valuable guidance for exploration geoscientists. The approach may be applied to similar geological contexts for improved sampling strategies and anomaly detection.</div></div>","PeriodicalId":100993,"journal":{"name":"Ore and Energy Resource Geology","volume":"19 ","pages":"Article 100107"},"PeriodicalIF":0.0,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144270841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Remote mapping of lineaments and hydrothermal alteration zones related to unconformity-related uranium deposits in the Badami Group of the western Kaladgi basin, India 印度Kaladgi盆地西部Badami群与不整合型铀矿床相关的地貌和热液蚀变带遥感填图
Pub Date : 2025-05-15 DOI: 10.1016/j.oreoa.2025.100106
R. Kalimuthu , Alok Porwal , Hari Shankar Pandalai
<div><div>In mineral exploration, identifying geophysical, geochemical and mineralogical indicators is crucial and many techniques have been employed to discover the occurrence of mineralization and the associated host rock alterations. In the case of unconformity-related uranium deposits that are spatially-linked to major faults and unconformities between basement rocks and overlying basinal rocks, extensive alteration zones produced by hydrothermal fluid-rock interactions which are used to target mineralization and are therefore vital tools for uranium exploration. The synoptic capability of remote sensing enables precise geological mapping by delineating structural features (faults, folds, shear zones), lithology and mineralogy, addressing field investigation constraints. The present study uses digital elevation model and satellite-borne multispectral data to map major lineaments and hydrothermal alteration zones associated with unconformity-related uranium deposits in the Badami Group of the western Kaladgi basin, India. Geologically, the study area comprises relatively undeformed arenites and conglomerates of the Neoproterozoic Badami Group that unconformably overlie an Archean basement (Peninsular gneiss). A few unconformity-related uranium prospects hosted by the Badami conglomerates and basal arenite have been identified by the Atomic Minerals Directorate in the study area. Conjunctive analysis of SRTM DEM and ASTER VNIR-SWIR data were used to map structures and lithological units. Band ratios, colour composite, least square fitting, principal component analysis and spectral angle mapper methods were further applied to ASTER VNIR-SWIR data to map the hydrothermal alteration zones. Follow-up ground checks were carried out to validate the results of the remote sensing analysis and interpretation. The results reveal that NE-SW and E-W trending lineaments are the major structural features and argillic (kaolinite) and phyllic (illite) are the dominant alteration types present in the study area. There is a strong intercorrelation between lineaments and hydrothermal alteration zones. Field surveys and laboratory analysis including petrographic studies and XRD analysis confirmed the occurrences of such alteration zones. The spatial association of hydrothermal alteration zones with structures indicates that these major lineaments and unconformable contact between the basement and the basinal sandstone could have provided major pathways for uranium-rich fluids and zones of low redox potential may have facilitated uranium precipitation. Several potential exploration targets were demarcated based on the juxtaposition of alteration zones, unconformity surface, major lineaments and cross-cutting structures. The identified targets correlate well with known uranium mineralization. This investigation demonstrates that integrating STRM with ASTER data is a valuable tool that can improve the efficiency of uranium exploration. This study narrows down the are
在矿产勘查中,地球物理、地球化学和矿物学指标的识别是至关重要的,许多技术已被用于发现矿化的产状和伴生的寄主岩石蚀变。对于与不整合相关的铀矿床,它们在空间上与基底岩石和上覆基底岩石之间的大断层和不整合相联系,热液-流体-岩石相互作用产生的广泛蚀变带用于靶化,因此是铀矿勘探的重要工具。遥感的天气学能力可以通过描绘构造特征(断层、褶皱、剪切带)、岩性和矿物学,解决实地调查的限制,实现精确的地质制图。本研究利用数字高程模型和卫星多光谱数据绘制了印度Kaladgi盆地西部Badami群与不整合相关铀矿床相关的主要地貌和热液蚀变带。地质上,研究区由新元古代八达米群相对未变形的砂质岩和砾岩组成,它们不整合地覆盖在太古宙基底(半岛片麻岩)上。原子矿物局在研究地区发现了几个与不整合有关的铀远景区,这些远景区由巴达米砾岩和基砂岩组成。利用SRTM DEM和ASTER VNIR-SWIR数据进行联合分析,绘制构造和岩性单元图。将波段比、彩色复合、最小二乘拟合、主成分分析和光谱角成像仪等方法应用于ASTER VNIR-SWIR数据,绘制热液蚀变带。随后进行了地面检查,以验证遥感分析和判读的结果。结果表明,北东—西向和东西向是主要的构造特征,泥质(高岭石)和叶状(伊利石)是主要的蚀变类型。地貌与热液蚀变带之间有很强的相互关系。现场调查和实验室分析,包括岩石学研究和XRD分析,证实了这种蚀变带的存在。热液蚀变带与构造的空间关联表明,这些主要的地貌和基底与盆地砂岩之间的不整合接触可能为富铀流体提供了主要的通道,低氧化还原电位的带可能促进了铀的沉淀。通过对蚀变带、不整合面、主要地貌和横切构造的并置,圈定了几个潜在的勘探目标。已确定的目标与已知的铀矿化关系良好。研究表明,STRM与ASTER数据相结合是提高铀矿找矿效率的有效手段。这项研究缩小了进一步勘探活动的范围,并为在Kaladgi盆地西部Badami群和其他类似地区寻找与不整合有关的铀矿床提供了一种低成本的方法。
{"title":"Remote mapping of lineaments and hydrothermal alteration zones related to unconformity-related uranium deposits in the Badami Group of the western Kaladgi basin, India","authors":"R. Kalimuthu ,&nbsp;Alok Porwal ,&nbsp;Hari Shankar Pandalai","doi":"10.1016/j.oreoa.2025.100106","DOIUrl":"10.1016/j.oreoa.2025.100106","url":null,"abstract":"&lt;div&gt;&lt;div&gt;In mineral exploration, identifying geophysical, geochemical and mineralogical indicators is crucial and many techniques have been employed to discover the occurrence of mineralization and the associated host rock alterations. In the case of unconformity-related uranium deposits that are spatially-linked to major faults and unconformities between basement rocks and overlying basinal rocks, extensive alteration zones produced by hydrothermal fluid-rock interactions which are used to target mineralization and are therefore vital tools for uranium exploration. The synoptic capability of remote sensing enables precise geological mapping by delineating structural features (faults, folds, shear zones), lithology and mineralogy, addressing field investigation constraints. The present study uses digital elevation model and satellite-borne multispectral data to map major lineaments and hydrothermal alteration zones associated with unconformity-related uranium deposits in the Badami Group of the western Kaladgi basin, India. Geologically, the study area comprises relatively undeformed arenites and conglomerates of the Neoproterozoic Badami Group that unconformably overlie an Archean basement (Peninsular gneiss). A few unconformity-related uranium prospects hosted by the Badami conglomerates and basal arenite have been identified by the Atomic Minerals Directorate in the study area. Conjunctive analysis of SRTM DEM and ASTER VNIR-SWIR data were used to map structures and lithological units. Band ratios, colour composite, least square fitting, principal component analysis and spectral angle mapper methods were further applied to ASTER VNIR-SWIR data to map the hydrothermal alteration zones. Follow-up ground checks were carried out to validate the results of the remote sensing analysis and interpretation. The results reveal that NE-SW and E-W trending lineaments are the major structural features and argillic (kaolinite) and phyllic (illite) are the dominant alteration types present in the study area. There is a strong intercorrelation between lineaments and hydrothermal alteration zones. Field surveys and laboratory analysis including petrographic studies and XRD analysis confirmed the occurrences of such alteration zones. The spatial association of hydrothermal alteration zones with structures indicates that these major lineaments and unconformable contact between the basement and the basinal sandstone could have provided major pathways for uranium-rich fluids and zones of low redox potential may have facilitated uranium precipitation. Several potential exploration targets were demarcated based on the juxtaposition of alteration zones, unconformity surface, major lineaments and cross-cutting structures. The identified targets correlate well with known uranium mineralization. This investigation demonstrates that integrating STRM with ASTER data is a valuable tool that can improve the efficiency of uranium exploration. This study narrows down the are","PeriodicalId":100993,"journal":{"name":"Ore and Energy Resource Geology","volume":"19 ","pages":"Article 100106"},"PeriodicalIF":0.0,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144204265","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geochemical characteristics of stream sediments as a preliminary tool for exploration in the Mbengwi area, Northwestern Cameroon 喀麦隆西北部Mbengwi地区水系沉积物地球化学特征初探
Pub Date : 2025-05-10 DOI: 10.1016/j.oreoa.2025.100104
Ralain Bryan Ngatcha , Ngambu Aloysius Afahnwie , Mary Ewokolo Molua Etutu , Fuofu Hanson Fombalang , Oliver Anoh Njoh
The Mbengwi area is located along the Cenozoic volcano-plutonic Cameroon Volcanic Line (CVL) within the Northern Domain of the Pan-African Neoproterozoic Fold Belt of Cameroon. Important magnetite filings are continuously recovered in the area along drainage trails. The source of this concealed mineralization has not been established. A total of ten active stream sediment samples were recovered and analyzed for major and trace elements by the inductively coupled plasma mass spectrometry (ICP-MS) technique. The mineralogical population (phases) of the heavy mineral concentrates consists of zircon, rutile, quartz, and opaque mineral phases, with angular to sub-rounded morphologies indicating moderate to long transport distances. Sediment geochemistry shows high contents in Fe2O3 up to 37.43 wt.%, with low contents in Al2O3, MgO, CaO, Na2O, and K2O. The concentrations of siderophiles (e.g., Fe, Bi, Co, Cr, Ga, Mn, Mo, and Ni) and chalcophiles (e.g., In, Sn, and Hg) are slightly elevated with respect to their average upper continental crust values. The spatial distribution of iron and other elements is presented as point symbol maps, and the data is analyzed using multivariate statistics. From the principal component analysis (PCA), the Ag-Hg-Tl-Mo-As-Sb-Cd-Se-Pb-Au-In-Nb, as well as the Zn-Co-Ga-Mn-Ni-In-Fe-Cu factors, point to the presence of a hydrothermal fluid circulation in the area associated with possible Au-Ag-Mo and Fe-Cu mineralization. Ag, Hg, Mo, and As could serve as a pathfinder for Au in the area. The single element factor with Sn reflects the occurrence of cassiterite host rocks in the area. The sediments from the Mbengwi area were deposited under humid tropical and equatorial climates. The geochemical parameters (CIA, CIW, and PIA) point to a strong weathering of feldspar-bearing source rocks. The dominant mafic to intermediate igneous provenance suggests that mica schists, granodiorites, monzogranites, monzonites, and basanites could be potential source rocks in the area.
Mbengwi地区位于喀麦隆泛非新元古代褶皱带北域的新生代火山-深成喀麦隆火山岩线(CVL)沿线。重要的磁铁矿屑沿着排水道不断被回收。隐伏矿化的来源尚未确定。采用电感耦合等离子体质谱(ICP-MS)技术对10份活动水系沉积物样品进行了主微量元素分析。重矿物精矿的矿物学种群(相)由锆石、金红石、石英和不透明矿物相组成,具有角状到次圆形的形态,表明中等到长距离的运输距离。沉积物中Fe2O3含量较高,达37.43 wt.%, Al2O3、MgO、CaO、Na2O和K2O含量较低。亲铁元素(如Fe、Bi、Co、Cr、Ga、Mn、Mo和Ni)和亲铜元素(如In、Sn和Hg)的浓度相对于它们的大陆上地壳平均值略有升高。以点符号图的形式呈现铁等元素的空间分布,并采用多元统计方法对数据进行分析。主成分分析(PCA)表明,Ag-Hg-Tl-Mo-As-Sb-Cd-Se-Pb-Au-In-Nb和Zn-Co-Ga-Mn-Ni-In-Fe-Cu因子表明该区存在热液循环,可能与Au-Ag-Mo和Fe-Cu成矿有关。Ag、Hg、Mo和As可以作为该地区Au的探路者。含锡的单元素因子反映了该区锡石寄主岩的产状。Mbengwi地区的沉积物是在潮湿的热带和赤道气候下沉积的。地球化学参数(CIA、CIW和PIA)表明含长石烃源岩风化作用强。基性—中火成岩物源优势表明,云母片岩、花岗闪长岩、二长花岗岩、二长岩和玄武岩可能是该区潜在的烃源岩。
{"title":"Geochemical characteristics of stream sediments as a preliminary tool for exploration in the Mbengwi area, Northwestern Cameroon","authors":"Ralain Bryan Ngatcha ,&nbsp;Ngambu Aloysius Afahnwie ,&nbsp;Mary Ewokolo Molua Etutu ,&nbsp;Fuofu Hanson Fombalang ,&nbsp;Oliver Anoh Njoh","doi":"10.1016/j.oreoa.2025.100104","DOIUrl":"10.1016/j.oreoa.2025.100104","url":null,"abstract":"<div><div>The Mbengwi area is located along the Cenozoic volcano-plutonic Cameroon Volcanic Line (CVL) within the Northern Domain of the Pan-African Neoproterozoic Fold Belt of Cameroon. Important magnetite filings are continuously recovered in the area along drainage trails. The source of this concealed mineralization has not been established. A total of ten active stream sediment samples were recovered and analyzed for major and trace elements by the inductively coupled plasma mass spectrometry (ICP-MS) technique. The mineralogical population (phases) of the heavy mineral concentrates consists of zircon, rutile, quartz, and opaque mineral phases, with angular to sub-rounded morphologies indicating moderate to long transport distances. Sediment geochemistry shows high contents in Fe<sub>2</sub>O<sub>3</sub> up to 37.43 wt.%, with low contents in Al<sub>2</sub>O<sub>3</sub>, MgO, CaO, Na<sub>2</sub>O, and K<sub>2</sub>O. The concentrations of siderophiles (e.g., Fe, Bi, Co, Cr, Ga, Mn, Mo, and Ni) and chalcophiles (e.g., In, Sn, and Hg) are slightly elevated with respect to their average upper continental crust values. The spatial distribution of iron and other elements is presented as point symbol maps, and the data is analyzed using multivariate statistics. From the principal component analysis (PCA), the Ag-Hg-Tl-Mo-As-Sb-Cd-Se-Pb-Au-In-Nb, as well as the Zn-Co-Ga-Mn-Ni-In-Fe-Cu factors, point to the presence of a hydrothermal fluid circulation in the area associated with possible Au-Ag-Mo and Fe-Cu mineralization. Ag, Hg, Mo, and As could serve as a pathfinder for Au in the area. The single element factor with Sn reflects the occurrence of cassiterite host rocks in the area. The sediments from the Mbengwi area were deposited under humid tropical and equatorial climates. The geochemical parameters (CIA, CIW, and PIA) point to a strong weathering of feldspar-bearing source rocks. The dominant mafic to intermediate igneous provenance suggests that mica schists, granodiorites, monzogranites, monzonites, and basanites could be potential source rocks in the area.</div></div>","PeriodicalId":100993,"journal":{"name":"Ore and Energy Resource Geology","volume":"19 ","pages":"Article 100104"},"PeriodicalIF":0.0,"publicationDate":"2025-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143931521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Assessing CO2 sequestration potential in Cenozoic basaltic rocks of Harrat Al-Shaam, Jordan 约旦Harrat Al-Shaam新生代玄武岩中CO2封存潜力评估
Pub Date : 2025-05-08 DOI: 10.1016/j.oreoa.2025.100105
Ahmed Hammam , Ahmed Nagy , Israa S. Abu-Mahfouz , Ahmed Al-Yaseri
Carbon geo-sequestration is a promising approach to mitigate greenhouse gas emissions, particularly through the long-term storage of CO2 in suitable geological formations. This study investigates the potential of the Harrat Al-Shaam Volcanic Field (HSVF) in Jordan as a host site for CO2 mineralization, focusing on its textural, mineralogical, and geochemical characteristics. Basaltic rocks, known for their chemical composition rich in calcium (Ca), iron (Fe), and magnesium (Mg), demonstrate a favorable capacity for CO2 sequestration. They undergo chemical reactions with injected CO2 and brine, leading to the formation of stable carbonate minerals. In this work, we conducted a series of laboratory experiments involving the injection of supercritical CO2 mixed with brine and freshwater into basalt core and powder samples to evaluate their mineralization potential under controlled conditions. Parameters such as mineral composition, alteration, and porosity were assessed. Microscopic investigations and geochemical analyses revealed changes in textural and mineralogical composition after CO2 treatment. Notably, rapid neutralization of carbonic acid during injection was observed, resulting in the formation of calcite through water-rock reactions, which underscores the swift mineralization process inherent to these basaltic formations. The study confirms the moderate potential for carbonate mineralization and CO2 storage capacity within the basaltic rocks of HSVF, attributed to their alkaline composition, enrichment of Ca and Fe-bearing minerals, and structural features such as fractures that enhance porosity and permeability. These findings highlight the effectiveness of mafic rocks as reliable candidates for geological CO2 storage and indicate a need for further research to fully explore their long-term sequestration capabilities.
碳地质封存是一种很有前景的减少温室气体排放的方法,特别是通过将二氧化碳长期储存在合适的地质构造中。本研究探讨了约旦Harrat Al-Shaam火山田(HSVF)作为二氧化碳矿化宿主的潜力,重点研究了其结构、矿物学和地球化学特征。玄武岩以其富含钙(Ca)、铁(Fe)和镁(Mg)的化学成分而闻名,具有良好的二氧化碳封存能力。它们与注入的二氧化碳和盐水发生化学反应,形成稳定的碳酸盐矿物。在本次工作中,我们进行了一系列的实验室实验,包括将混合盐水和淡水的超临界CO2注入玄武岩岩心和粉末样品中,以评估其在受控条件下的矿化潜力。评估了矿物成分、蚀变和孔隙度等参数。显微观察和地球化学分析揭示了CO2处理后的结构和矿物组成的变化。值得注意的是,在注入过程中观察到碳酸的快速中和,通过水-岩反应形成方解石,这强调了这些玄武岩地层固有的快速矿化过程。研究证实,由于其碱性成分、富钙、富铁矿物以及裂缝等增强孔隙度和渗透率的构造特征,HSVF玄武岩具有中等的碳酸盐矿化潜力和二氧化碳储存能力。这些发现强调了基性岩石作为地质二氧化碳储存的可靠候选者的有效性,并表明需要进一步研究以充分探索其长期封存能力。
{"title":"Assessing CO2 sequestration potential in Cenozoic basaltic rocks of Harrat Al-Shaam, Jordan","authors":"Ahmed Hammam ,&nbsp;Ahmed Nagy ,&nbsp;Israa S. Abu-Mahfouz ,&nbsp;Ahmed Al-Yaseri","doi":"10.1016/j.oreoa.2025.100105","DOIUrl":"10.1016/j.oreoa.2025.100105","url":null,"abstract":"<div><div>Carbon geo-sequestration is a promising approach to mitigate greenhouse gas emissions, particularly through the long-term storage of CO<sub>2</sub> in suitable geological formations. This study investigates the potential of the Harrat Al-Shaam Volcanic Field (HSVF) in Jordan as a host site for CO<sub>2</sub> mineralization, focusing on its textural, mineralogical, and geochemical characteristics. Basaltic rocks, known for their chemical composition rich in calcium (Ca), iron (Fe), and magnesium (Mg), demonstrate a favorable capacity for CO<sub>2</sub> sequestration. They undergo chemical reactions with injected CO<sub>2</sub> and brine, leading to the formation of stable carbonate minerals. In this work, we conducted a series of laboratory experiments involving the injection of supercritical CO<sub>2</sub> mixed with brine and freshwater into basalt core and powder samples to evaluate their mineralization potential under controlled conditions. Parameters such as mineral composition, alteration, and porosity were assessed. Microscopic investigations and geochemical analyses revealed changes in textural and mineralogical composition after CO<sub>2</sub> treatment. Notably, rapid neutralization of carbonic acid during injection was observed, resulting in the formation of calcite through water-rock reactions, which underscores the swift mineralization process inherent to these basaltic formations. The study confirms the moderate potential for carbonate mineralization and CO<sub>2</sub> storage capacity within the basaltic rocks of HSVF, attributed to their alkaline composition, enrichment of Ca and Fe-bearing minerals, and structural features such as fractures that enhance porosity and permeability. These findings highlight the effectiveness of mafic rocks as reliable candidates for geological CO<sub>2</sub> storage and indicate a need for further research to fully explore their long-term sequestration capabilities.</div></div>","PeriodicalId":100993,"journal":{"name":"Ore and Energy Resource Geology","volume":"19 ","pages":"Article 100105"},"PeriodicalIF":0.0,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144084669","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrogeochemical provenance and evolution in Ganhai Well’s groundwater, Eastern Tibetan Plateau 青藏高原东部干海井地下水水文地球化学物源及演化
Pub Date : 2025-05-08 DOI: 10.1016/j.oreoa.2025.100101
Guanchun Chen , Liang Tang , Long-Fei Gou , Chuan Jiang , Yang Xu
The Ganhai Well (27.48° N, 101.46° E), an earthquake monitoring well since September 1980, is situated in the earthquake-prone of the eastern Tibetan Plateau, China. Despite years of monitoring, the hydrogeochemical origins and evolution of groundwater in the well remain unclear. Based on a weekly water sampling in 2022, the hydrochemical characteristics of the Ganhai Well were extrapolated. (1) The groundwater’s ions are derived from evaporite (45.2–48.0 %) and silicate rocks (36.4–40.9 %), followed by carbonate rocks (12.2–15.4 %), and negligible anthropogenic inputs (less than 1 %). In the Ganhai Well, calcite tends to precipitate and crystallise, whereas dolomite maintains equilibrium with the solution. (2) It is a significant observation that the groundwater within the Ganhai Well is deep-seated, confined soda water (HCO₃·Cl-Na type), characterised by minor temporal fluctuations in its ionic concentrations and high stability. This hydrogeochemical profile establishes it as an extremely valuable and sustainable water resource, offering considerable support for regional ecological preservation and economic development.
干海井(27.48°N, 101.46°E)位于中国青藏高原东部地震多发区,是1980年9月以来的地震监测井。尽管经过多年的监测,该井中地下水的水文地球化学起源和演化仍不清楚。根据2022年每周的采样数据,推断了干海井的水化学特征。(1)地下水离子主要来源于蒸发岩(45.2% ~ 48.0%)和硅酸盐(36.4% ~ 40.9%),其次是碳酸盐岩(12.2% ~ 15.4%),人为输入可以忽略不计(小于1%)。甘海井中方解石趋于沉淀结晶,白云石与溶液保持平衡。(2)观察到赣海井区地下水为深部承压苏打水(HCO₃·Cl-Na型),具有离子浓度时间波动小、稳定性高的特点。这一水文地球化学剖面为区域生态保护和经济发展提供了重要支撑。
{"title":"Hydrogeochemical provenance and evolution in Ganhai Well’s groundwater, Eastern Tibetan Plateau","authors":"Guanchun Chen ,&nbsp;Liang Tang ,&nbsp;Long-Fei Gou ,&nbsp;Chuan Jiang ,&nbsp;Yang Xu","doi":"10.1016/j.oreoa.2025.100101","DOIUrl":"10.1016/j.oreoa.2025.100101","url":null,"abstract":"<div><div>The Ganhai Well (27.48° N, 101.46° E), an earthquake monitoring well since September 1980, is situated in the earthquake-prone of the eastern Tibetan Plateau, China. Despite years of monitoring, the hydrogeochemical origins and evolution of groundwater in the well remain unclear. Based on a weekly water sampling in 2022, the hydrochemical characteristics of the Ganhai Well were extrapolated. (1) The groundwater’s ions are derived from evaporite (45.2–48.0 %) and silicate rocks (36.4–40.9 %), followed by carbonate rocks (12.2–15.4 %), and negligible anthropogenic inputs (less than 1 %). In the Ganhai Well, calcite tends to precipitate and crystallise, whereas dolomite maintains equilibrium with the solution. (2) It is a significant observation that the groundwater within the Ganhai Well is deep-seated, confined soda water (HCO₃·Cl-Na type), characterised by minor temporal fluctuations in its ionic concentrations and high stability. This hydrogeochemical profile establishes it as an extremely valuable and sustainable water resource, offering considerable support for regional ecological preservation and economic development.</div></div>","PeriodicalId":100993,"journal":{"name":"Ore and Energy Resource Geology","volume":"19 ","pages":"Article 100101"},"PeriodicalIF":0.0,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143941337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimising gold exploration in Northeast Sudan using analytical hierarchy process with multidisciplinary geodata 基于多学科地理数据的层次分析法优化苏丹东北部金矿找矿
Pub Date : 2025-05-08 DOI: 10.1016/j.oreoa.2025.100103
Abu Nasser Hussain, Biswajit Thander, Siddhartha Kumar Lahiri
Orogenic gold deposits, responsible for about one-third of the world’s gold production, typically form in tectonically active zones, where shear zones, suture zones, and faults serve as pathways for hydrothermal fluids, promoting gold mineralisation. Sudan’s diverse geology, characterised by Pan-African terrains within the Arabian-Nubian Shield, is a globally significant gold province with a rich history of ancient and modern mining activities. Despite having a rich legacy of gold exploration, there is an absence of an optimised strategy that helps reduce the cost of exploration. This research aims to seek how a geoscientific decision-making tool, the Analytical Hierarchy Process (AHP), optimises orogenic gold exploration by systematically weighing key geological and geophysical parameters in regions with complex tectonic histories. By evaluating four key parameters, lineament density, mineral composite map, lithological classification and free air gravity anomalies, available through open-access geospatial data sources, and introducing an empirical Relative Gold Mineralised Index (RGMI), this study applies AHP to assign weights to these variables, reflecting their influence on gold mineralisation. This structured approach identifies high-potential gold zones in northeast Sudan and proposes a scalable methodology for strategic orogenic gold exploration in similar geological settings worldwide.
造山带金矿约占世界黄金产量的三分之一,通常形成于构造活动区,其中剪切带、缝合带和断层是热液流体的通道,促进了金矿化。苏丹地质多样,以阿拉伯-努比亚地盾内的泛非地形为特征,是全球重要的黄金省,拥有丰富的古代和现代采矿活动历史。尽管拥有丰富的黄金勘探经验,但缺乏有助于降低勘探成本的优化策略。本研究旨在探索层次分析法(AHP)这一地球科学决策工具如何通过系统地权衡复杂构造历史地区的关键地质和地球物理参数来优化造山带金矿勘探。通过评估开放地理空间数据源可获得的四个关键参数,即纹理密度、矿物复合图、岩性分类和自由空气重力异常,并引入经验相对金矿化指数(RGMI),本研究应用层次分析法为这些变量分配权重,反映它们对金矿化的影响。这种结构化的方法确定了苏丹东北部的高潜力金矿带,并提出了一种可扩展的方法,用于在全球类似的地质环境中进行战略性造山带金矿勘探。
{"title":"Optimising gold exploration in Northeast Sudan using analytical hierarchy process with multidisciplinary geodata","authors":"Abu Nasser Hussain,&nbsp;Biswajit Thander,&nbsp;Siddhartha Kumar Lahiri","doi":"10.1016/j.oreoa.2025.100103","DOIUrl":"10.1016/j.oreoa.2025.100103","url":null,"abstract":"<div><div>Orogenic gold deposits, responsible for about one-third of the world’s gold production, typically form in tectonically active zones, where shear zones, suture zones, and faults serve as pathways for hydrothermal fluids, promoting gold mineralisation. Sudan’s diverse geology, characterised by Pan-African terrains within the Arabian-Nubian Shield, is a globally significant gold province with a rich history of ancient and modern mining activities. Despite having a rich legacy of gold exploration, there is an absence of an optimised strategy that helps reduce the cost of exploration. This research aims to seek <em>how a geoscientific decision-making tool, the Analytical Hierarchy Process (AHP), optimises orogenic gold exploration by systematically weighing key geological and geophysical parameters in regions with complex tectonic histories</em>. By evaluating four key parameters, lineament density, mineral composite map, lithological classification and free air gravity anomalies, available through open-access geospatial data sources, and introducing an empirical Relative Gold Mineralised Index (RGMI), this study applies AHP to assign weights to these variables, reflecting their influence on gold mineralisation. This structured approach identifies high-potential gold zones in northeast Sudan and proposes a scalable methodology for strategic orogenic gold exploration in similar geological settings worldwide.</div></div>","PeriodicalId":100993,"journal":{"name":"Ore and Energy Resource Geology","volume":"19 ","pages":"Article 100103"},"PeriodicalIF":0.0,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144068023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Ore and Energy Resource Geology
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1