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Effects of long-term flood irrigation and fertilization on greenhouse gas emissions and soil nitrogen in mountain hay meadows 长期漫灌施肥对山地草甸温室气体排放和土壤氮的影响
Pub Date : 2026-01-23 DOI: 10.1002/saj2.70189
Daniel Adamson, Urszula Norton, Linda T. A. van Diepen, Jay B. Norton

Mountain hay meadows are a high-elevation forage-producing agroecosystem dependent on flood irrigation and nitrogen (N) fertilization to maintain yields, meaning management has great potential to influence greenhouse gas (GHG) emissions. To assess GHG fluxes and inorganic N dynamics in meadows, field monitoring was established at four ranches in Wyoming and Colorado for 24 months from October 2021 through September 2023. At each ranch, three long-term management systems were compared: unirrigated rangeland, irrigated-unfertilized meadow, and irrigated-fertilized meadow. Soil carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O) fluxes were measured along with soil samples (0- to 10-cm depth) analyzed for water content, nitrate (NO3), and ammonium (NH4+). Flood irrigation resulted in 41%–91% increase in annual CO2 emissions compared to rangelands. Flood irrigation combined with fertilization increased CO2 emissions by another 19% in 2023. Both irrigated-fertilized and irrigated-unfertilized meadows emitted CH4 during flooding, while rangeland soils assimilated CH4 throughout the study. Unexpectedly, N2O emissions were highest in rangelands and not influenced by irrigation or fertilization in meadows. Soil NO3 and NH4+ concentrations were low during the growing season and no correlation between inorganic N and N2O emissions was observed. Calculated global warming potential in meadows revealed GHG emissions were driven mainly by CO2, indicating that maintaining photosynthetic carbon (C) sequestration in meadows through optimum agronomic management may be an important strategy to balance GHG emissions.

山地干草草甸是一个高海拔的生产牧草的农业生态系统,依靠洪水灌溉和氮(N)施肥来维持产量,这意味着管理有很大的潜力影响温室气体(GHG)排放。为了评估草甸的温室气体通量和无机氮动态,从2021年10月到2023年9月,在怀俄明州和科罗拉多州的四个牧场建立了为期24个月的实地监测。在每个牧场,比较了三种长期管理制度:未灌溉牧场、灌溉-未施肥草甸和灌溉-施肥草甸。测量了土壤二氧化碳(CO2)、甲烷(CH4)和氧化亚氮(N2O)的通量,并分析了土壤样品(0- 10厘米深)的含水量、硝酸盐(NO3−)和铵(NH4+)。与牧场相比,洪水灌溉导致年二氧化碳排放量增加41%-91%。2023年,洪水灌溉与施肥相结合将使二氧化碳排放量再增加19%。灌溉施肥和未灌溉施肥的草甸在洪水期间都释放CH4,而牧场土壤在整个研究过程中都吸收了CH4。出乎意料的是,牧场的N2O排放量最高,而草甸不受灌溉和施肥的影响。生长季土壤NO3−和NH4+浓度较低,无机N和N2O排放量之间无相关性。草甸全球变暖潜势计算表明,草甸温室气体排放主要由CO2驱动,表明通过优化农艺管理维持草甸光合碳(C)固存可能是平衡温室气体排放的重要策略。
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引用次数: 0
Comparison of Laboratory- and field-determined soil water retention curves in a well-aggregated tallgrass prairie soil 高草草原土壤中实验室测定和现场测定的土壤保水曲线的比较
Pub Date : 2026-01-23 DOI: 10.1002/saj2.70174
Nishadini Widanagamage, Andres Patrignani

Soil water retention curves (SWRCs) are traditionally determined in the laboratory, but modern sensors enable their measurement under field conditions. This study compared SWRCs obtained from laboratory and field instrumentation within the same soil volume. A well-aggregated tallgrass prairie soil was instrumented with co-located sensors that measured volumetric water content and matric potential at 3.5-cm depth inside collars that prevented root intrusion, minimized lateral flow, and ensured consistent sensor placement. The field experiment was conducted from June 1 to August 11, 2023, capturing multiple wetting and drying cycles. Afterward, the collars were excavated and analyzed in the laboratory using precision mini-tensiometers and a dewpoint water potential meter. Laboratory-derived SWRCs consistently showed greater water contents near saturation compared to field-derived SWRCs, which were consistent across three drydown periods and collars. The two methods produced nonequivalent SWRCs, likely due to sensor responsiveness, air entrapment, and rapid macropore drainage that limited in situ measurement of near-saturation conditions.

土壤保水曲线(SWRCs)传统上是在实验室中确定的,但现代传感器使其能够在现场条件下测量。本研究比较了在相同土壤体积内从实验室和现场仪器获得的SWRCs。在聚集良好的高草草原土壤中,共放置传感器,测量环圈内3.5 cm深度的体积含水量和基质电位,以防止根系入侵,减少横向流动,并确保传感器放置一致。田间试验于2023年6月1日至8月11日进行,捕获了多个干湿循环。随后,在实验室使用精密微型张力计和露点水势计进行挖掘和分析。与现场swrc相比,实验室导出的swrc始终显示出更高的接近饱和的含水量,这在三个干枯期和环期内是一致的。这两种方法产生了不等效的swrc,可能是由于传感器响应性、空气夹持和快速大孔排水限制了近饱和条件下的原位测量。
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引用次数: 0
Assessing impact of conservation agriculture practices on soil physical properties under on-farm conditions in Central Ohio, USA 评估美国俄亥俄州中部农田条件下保护性农业做法对土壤物理性质的影响
Pub Date : 2026-01-23 DOI: 10.1002/saj2.70183
Yadunath Bajgai, Rattan Lal, M. Scott Demyan, Klaus Lorenz, Alec Ogg, Noor Us Sabah

Basic indicators of soil health that influence water infiltration, root growth, gaseous exchange, and overall agronomic productivity are soil physical properties such as bulk density (BD), total porosity (TP), particle density (PD), and penetration resistance (PR). Agricultural practices, particularly tillage and land use, are known to alter soil physical properties by disrupting soil structure and altering soil organic matter content. Therefore, this study aimed to assess the effects of conservation agriculture practices, meadows, and woodlands on above-mentioned soil properties. This on-farm study was conducted at 41 sites located within five counties that covered five soil series (Blount, Eldean, Pewamo, Spinks, and Warsaw) in Central Ohio. From November 2023 to July 2024, soils (0- to 10-cm depth) were sampled from cropland under conventional tillage, minimum tillage (MT), and no-tillage (NT), as well as from meadows and woodlands, to evaluate BD, PD, and TP. PR was measured in the field. All land management practices had been in place for at least 15 years prior to sampling. Data were analyzed using a linear fixed-effects model to test the effects of land use within each soil series. Soil TP, BD, and PR varied significantly (p < 0.05) across land management practices and soil series, with woodland soils consistently showing lower BD and PR, and higher TP compared to those under cropland independent of tillage practice and those under meadow, whereas PD did not differ among practices. Soil TP, BD, and PR were significantly related (R2 ≥ 0.33, p < 0.001) to soil organic carbon (SOC) content, reflecting a moderate influence of SOC on reducing soil compaction. Overall, these findings highlight the lasting positive impact of relatively undisturbed land use (woodlands) on soil physical health, while also suggesting that NT and MT may require longer timeframes (>15 years) to induce improvements in soil structure and compaction.

影响水分入渗、根系生长、气体交换和整体农学生产力的土壤健康的基本指标是土壤的物理性质,如容重(BD)、总孔隙度(TP)、颗粒密度(PD)和渗透阻力(PR)。众所周知,农业实践,特别是耕作和土地利用,会通过破坏土壤结构和改变土壤有机质含量来改变土壤的物理性质。因此,本研究旨在评估保护性农业措施、草地和林地对上述土壤性质的影响。这项农场研究在俄亥俄州中部五个县的41个地点进行,涵盖五个土壤系列(布朗特、埃尔丁、佩瓦莫、斯宾克斯和华沙)。从2023年11月至2024年7月,对常规耕作、免耕、免耕以及草甸和林地的土壤(0 ~ 10 cm)进行采样,评价土壤的BD、PD和TP。在现场测量PR。在抽样之前,所有土地管理做法至少已实行了15年。使用线性固定效应模型分析数据,以检验每个土壤系列内土地利用的影响。土壤TP、BD和PR在不同的土地管理方式和土壤系列中差异显著(p < 0.05),林地土壤的BD和PR始终低于独立耕作方式和草甸土壤,TP始终高于独立耕作方式和草甸土壤,而PD在不同的土地管理方式之间没有差异。土壤TP、BD和PR与土壤有机碳(SOC)含量呈极显著相关(R2≥0.33,p < 0.001),反映了土壤有机碳(SOC)对减少土壤压实的中等影响。总的来说,这些研究结果强调了相对未受干扰的土地利用(林地)对土壤物理健康的持久积极影响,同时也表明NT和MT可能需要更长的时间框架(>;15年)来诱导土壤结构和压实的改善。
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引用次数: 0
Microwave soil treatment effects on lucerne and phalaris pasture production 微波土壤处理对苜蓿和蝴蝶兰牧草生产的影响
Pub Date : 2026-01-22 DOI: 10.1002/saj2.70179
M. S. R. Shishir, A. Leddin, G. Brodie, B. Cullen, Z. Li, M. H. Kabir, T. Reeves, L. Cheng

Microwave (MW) soil treatment has proven to have the potential to reduce weeds and enhance soil nutrient availability and crop yields. This study hypothesized similar benefits in newly established pastures. Four treatments (Lucerne and Phalaris, with and without pre-sowing MW soil treatment for 120 s) were tested with four replicate plots (1.5 m2 each). Three 700 W MW magnetrons, with a frequency of 2.45 GHz, were attached and remotely connected to the controller circuitry of three domestic MW ovens. Soil physio-chemical properties were analyzed, and plots were harvested via mowing three times during the experiment. Pasture samples were assessed for nutritive value. MW treatment increased nitrate, ammonium nitrogen, and potassium in both species plot soil but decreased soil phosphorus. Germination counts significantly increased in MW-treated Lucerne (p = 0.018) and Phalaris (p = 0.002), while weed counts decreased (p = 0.091 and p < 0.001, respectively). MW-treated Phalaris plots had 30% and 26% higher crude protein and metabolizable energy yields compared to controls (p < 0.05). However, MW treatment did not affect Lucerne's nutrient yields (p > 0.05). The findings suggest MW soil treatment can enhance nutrient yields in Phalaris but not Lucerne, while also aiding weed control. Further research is needed to explore the interactions between pasture species and MW treatment. This technology has potential as a sustainable tool for improving pasture productivity and weed management.

微波(MW)土壤处理已被证明具有减少杂草和提高土壤养分有效性和作物产量的潜力。这项研究假设新建立的牧场也有类似的好处。4个处理(Lucerne和Phalaris,有和没有播前MW土壤处理120 s)在4个重复小区(每个1.5 m2)进行试验。将3台频率为2.45 GHz的700 W MW磁控管连接到3台家用MW炉的控制器电路上。对土壤理化性质进行了分析,并在试验期间进行了三次刈割。评估牧草样品的营养价值。MW处理提高了两种样地土壤的硝态氮、铵态氮和钾含量,但降低了土壤磷含量。mw处理的苜蓿萌发数显著增加(p = 0.018), Phalaris萌发数显著增加(p = 0.002),而杂草数显著减少(p = 0.091和p <; 0.001)。mw处理的Phalaris地块的粗蛋白质和代谢能产量分别比对照组高30%和26% (p < 0.05)。MW处理不影响Lucerne的养分产量(p > 0.05)。研究结果表明,MW土壤处理可以提高Phalaris而不是Lucerne的养分产量,同时也有助于杂草控制。牧草种类与MW处理之间的相互作用有待进一步研究。这项技术有潜力成为提高牧场生产力和杂草管理的可持续工具。
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引用次数: 0
Toward a standardization of cryostructure and cryogenic soil structure terminology for the field description of permafrost-affected soils 冻土影响土壤现场描述的低温结构和低温土壤结构术语的标准化
Pub Date : 2026-01-22 DOI: 10.1002/saj2.70182
Megan L. Andersen, Mikhail Kanevskiy, Chien-Lu Ping, M. Torre Jorgenson, Yuri Shur, Julie D. Jastrow, Roser Matamala, Erin C. Rooney, Nicolas A. Jelinski

This paper establishes standardized terminology and field documentation protocols for cryostructures and cryogenic soil structures in permafrost-affected soils and provides brief guidance on descriptions of ground ice morphology and ice volume estimates. We consolidate permafrost terminology from Russian and North American literature, clarify long-standing ambiguities, and provide explicit guidelines that align with US Department of Agriculture-Natural Resources Conservation Service soil description standards. Our scheme makes critical distinctions between cryostructure, the distribution of ice within soil, and cryogenic soil structure, the morphological structure of soil resulting from ice formation. The scheme organizes cryostructures into three main categories: non-segregated ice, visible segregated ice, and ice matrices. We introduce standardized codes and parameters for field descriptions of ice and soil that enable machine-readable data collection compatible with existing soil information systems. This standardization will significantly enhance the integration of field observations into landscape-scale assessments of permafrost stability, infrastructure vulnerability, and ecosystem response to permafrost thaw, addressing an urgent need for quantitative data to inform modeling and decision-making in rapidly changing Arctic and subarctic environments.

本文建立了冻土层中低温结构和低温土壤结构的标准化术语和现场文件协议,并提供了对地下冰形态描述和冰体积估计的简要指导。我们整合了俄罗斯和北美文献中的永久冻土术语,澄清了长期存在的歧义,并提供了与美国农业部自然资源保护局土壤描述标准一致的明确指导方针。我们的方案在低温结构(冰在土壤中的分布)和低温土壤结构(冰形成导致的土壤形态结构)之间做出了关键的区分。该方案将冰冻结构分为三大类:非分离冰、可见分离冰和冰基质。我们为冰和土壤的现场描述引入了标准化的代码和参数,使机器可读的数据收集与现有的土壤信息系统兼容。这一标准化将显著增强野外观测与多年冻土稳定性、基础设施脆弱性和生态系统对永久冻土融化响应的景观尺度评估的整合,解决了对定量数据的迫切需求,为快速变化的北极和亚北极环境中的建模和决策提供信息。
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引用次数: 0
Dual versus single inhibitors: Which strategy best mitigates nitrogen losses in coarse-textured soils? A laboratory evaluation 双抑制剂与单抑制剂:哪种策略最能减轻粗质土壤中的氮损失?实验室评估
Pub Date : 2026-01-18 DOI: 10.1002/saj2.70187
Dipesh Giri, Virginia Jin, Joe Luck, Bijesh Maharjan, Javed Iqbal

Enhanced efficiency fertilizers, including urease inhibitors (UIs), nitrification inhibitors (NIs), and dual inhibitors (DIs [UI + NI]), are widely used to reduce nitrogen (N) losses and improve crop nitrogen use efficiency (NUE). However, their relative effectiveness across multiple nitrogen loss pathways remains unclear. This study aimed to address that gap through a 31-day soil column experiment and a 25-day soil incubation study using loamy sand soil. Here we assessed the impact of single and DIs on nitrate (NO3-N) and ammonium (NH4-N) leaching, ammonia (NH3) volatilization, nitrous oxide (N2O) emissions, and residual soil nitrogen. Treatments included UAN alone and UAN with established (Agrotain, Instinct NXTGEN, and Nitrolock) and novel (VLS-UI, VLS-NI, and VLS-UI + NI) inhibitors. The NIs reduced potential NO3-N leaching by up to 20% compared to UAN and outperformed DIs by 10%. In contrast, UIs and DIs did not reduce NO3-N leaching. UI treatments increased NH4⁺-N leaching, while NIs and DIs had no significant effect. DIs were most effective in reducing NH3 volatilization (82%–89% reduction), surpassing UIs and NIs (68%–75%). N2O emissions did not differ significantly among treatments. NIs significantly reduced nitrification potential, with VLS-NI showing the greatest reduction (22%). Soil pH decline correlated with increased NO3-N leaching and nitrification. Total mineral N leaching accounted for 31% of applied N, and gaseous losses (NH3 + N2O) accounted for up to 9%. Overall, NIs were more effective in reducing NO3-N leaching and nitrification, while DIs were best for controlling NH3 volatilization. These findings highlight the importance of selecting nitrogen stabilizers based on dominant loss pathways and site-specific conditions to optimize NUE and reduce environmental impacts.

增效肥料包括脲酶抑制剂(UIs)、硝化抑制剂(NIs)和双重抑制剂(DIs [UI + NI]),被广泛用于减少氮素(N)损失和提高作物氮素利用效率(NUE)。然而,它们在多种氮损失途径中的相对有效性尚不清楚。本研究旨在通过31天的土壤柱实验和25天的壤土沙土培养研究来解决这一差距。在这里,我们评估了单一和DIs对硝态氮(NO3-N)和铵态氮(NH4-N)浸出、氨(NH3)挥发、氧化亚氮(N2O)排放和土壤残氮的影响。治疗包括单纯的UAN和与已建立的(Agrotain, Instinct NXTGEN和Nitrolock)和新型(VLS-UI, VLS-NI和VLS-UI + NI)抑制剂的UAN。与UAN相比,NIs将潜在的NO3−-N浸出率降低了20%,比DIs高出10%。相反,UIs和DIs对NO3−-N浸出没有抑制作用。UI处理增加了NH4 + -N的浸出,而NIs和DIs对NH4 + -N浸出无显著影响。DIs在减少NH3挥发方面最有效(减少82%-89%),超过了ui和NIs(68%-75%)。不同处理间N2O排放量无显著差异。NIs显著降低了硝化潜能,其中VLS-NI的降低幅度最大(22%)。土壤pH下降与硝态氮淋溶和硝化作用增加有关。总矿物N浸出占施氮量的31%,气体损失(NH3 + N2O)占9%。总体而言,NIs在减少NO3−-N淋溶和硝化作用方面效果更好,而DIs在控制NH3挥发方面效果最好。这些发现强调了根据主要损失途径和特定场地条件选择氮稳定剂以优化氮肥利用和减少环境影响的重要性。
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引用次数: 0
The effect of different biochars and leaching solutions on the heavy metals migration and fractions changes 不同生物炭和浸出液对重金属迁移和组分变化的影响
Pub Date : 2026-01-16 DOI: 10.1002/saj2.70185
Jianxiong Sun, Jin Gao, Zhenwei Lu, Yang Shi, Jinlong Yan, Shuipin Xiao, Sihong Ye, Hua Yang, Haodong Chen, Liqiang Cui, Wei Wang

Biochar consistently improves soil physicochemical properties and lowers the bioavailability of Cd and Pb, yet the exact mechanisms controlling metal mobility under field-relevant flow conditions remain unresolved. We therefore conducted a leaching column experiment to quantify the vertical migration of Cd and Pb in a sandy-loam paddy soil. The soil was amended with wheat straw biochar and shrub branch and leave-biochar and leached with two concentrations (5 and 10 mM) of citric acid or sodium humate. The results revealed distinct patterns for Cd and Pb in response to biochar treatments. Biochar accelerated the migration of surface layer Cd but simultaneously reduced exchangeable Cd content by 4.5%–10.7% compared to control treatment. In contrast, Pb migration was retarded, and breakthrough was delayed even though the proportion of bioavailable (reducible + oxidizable) Pb increased by 3.1%–4.7%, reflecting ligand-enhanced dissolution that was later re-immobilized along the profile. Organic acid concentration governed the extent of transport. At 5 mM, neither citric acid nor sodium humate appreciably moved Cd or Pb beyond 4 cm. At 10 mM, however, sodium humate doubled leachate velocity and transported both metals to 8–12 cm, enhancing subsoil concentrations and increasing groundwater risk. However, biochar also increased the proportion of residual fractions of both Cd and Pb in the 4- to 8-cm layer, indicating its role in transforming bioavailable forms into stable and non-bioavailable forms. Collectively, the data show that Cd mobility is controlled primarily by leachate ionic strength, whereas Pb transport is driven by the concentration of water-soluble organic ligands. Thus, biochar can be an effective long-term immobilization agent only if coupled with management practices that limit the buildup of strong organic acid solutions in the profile.

生物炭持续改善土壤理化性质,降低Cd和Pb的生物有效性,但在田间相关流动条件下控制金属流动性的确切机制尚不清楚。因此,我们进行了淋溶柱试验,以量化镉和铅在砂壤土水稻土中的垂直迁移。用小麦秸秆生物炭和灌木枝、叶生物炭对土壤进行改良,并用浓度为5和10 mM的柠檬酸或腐植酸钠进行浸出。结果表明,不同生物炭处理对土壤中Cd和Pb含量的影响不同。与对照处理相比,生物炭加速了表层Cd的迁移,但同时使可交换性Cd含量降低了4.5% ~ 10.7%。相比之下,尽管生物可利用(可还原+可氧化)Pb的比例增加了3.1%-4.7%,但铅的迁移被延缓,突破被推迟,这反映了配体增强的溶解,随后沿着剖面重新固定。有机酸浓度决定了运输的程度。在5毫米处,柠檬酸和腐植酸钠都没有明显移动Cd或Pb超过4厘米。然而,在10毫米处,腐植酸钠使渗滤液流速加倍,并将两种金属输送到8-12厘米处,增加了底土浓度,增加了地下水风险。然而,生物炭也增加了4 ~ 8 cm土层中Cd和Pb残留组分的比例,表明其在将生物可利用形态转化为稳定和非生物可利用形态方面的作用。总的来说,这些数据表明,镉的迁移主要由渗滤液离子强度控制,而铅的迁移则由水溶性有机配体的浓度驱动。因此,生物炭可以成为一种有效的长期固定化剂,只有与限制强有机酸溶液在剖面中的积累的管理实践相结合。
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引用次数: 0
Yield and quality enhancement of lettuce plants using mycorrhizal fungi and phosphorus nanofertilizer 菌根真菌和磷纳米肥对生菜产量和品质的提高
Pub Date : 2026-01-07 DOI: 10.1002/saj2.70180
Hawar Sleman Halshoy

Lettuce (Lactuca sativa) is a widely consumed leafy vegetable with high nutritional value. Enhancing its yield and quality through sustainable practices is crucial. This study aimed to investigate the combined effects of arbuscular mycorrhizal fungi (AMF) and phosphorus nanofertilizer (PNPs) on lettuce growth, productivity, and nutritional traits. A total of eight treatment combinations were established and replicated three times under greenhouse conditions, including the control (no AMF, no PNPs), AMF inoculation at 20 g plant−1, foliar application of PNPs at 250, 500, and 750 mg L−1, and their respective combinations with AMF, using a randomized complete block design. Results indicated that both AMF and PNPs, particularly when combined at 500 mg L−1, significantly enhanced plant growth (plant height and root dry weight), folded leaf number, plant weight (fresh weight), and total biomass (root and shoot system), nutritional value (ascorbic acid, chlorophyll a and b, carotenoids, and total phenolic content), and mineral content (phosphorus and potassium) compared to the control, the individual applications, and the other combination treatments. The next most effective treatments were AMF with 750 mg L−1 PNPs and 500 mg L−1 PNPs alone. This combined approach enhanced physiological performance and increased the levels of bioactive compounds. These results suggest that combining bio- and nano-fertilizers can synergistically improve lettuce productivity and nutrition, providing a promising method for sustainable crop production. Future studies should explore the long-term and field-scale impacts of these treatments.

莴苣(Lactuca sativa)是一种营养价值高、消费广泛的叶菜。通过可持续做法提高其产量和质量至关重要。本研究旨在探讨丛枝菌根真菌(AMF)与磷纳米肥(PNPs)联合施用对生菜生长、产量和营养性状的影响。在温室条件下,采用随机完全区组设计,共建立了8个处理组合,并重复了3次,包括对照(无AMF、无PNPs)、接种20 g植株−1 AMF、叶面施用250、500和750 mg L−1 PNPs,以及它们各自与AMF的组合。结果表明,与对照、单独施用和其他组合处理相比,AMF和PNPs,特别是在500 mg L−1的组合处理下,显著提高了植株生长(株高和根干重)、折叠叶数、植株重(鲜重)、总生物量(根和梢系统)、营养价值(抗坏血酸、叶绿素a和b、类胡萝卜素和总酚含量)和矿物质含量(磷和钾)。其次是AMF加750 mg L - 1 PNPs和500 mg L - 1 PNPs。这种结合的方法提高了生理性能,增加了生物活性化合物的水平。综上所述,生物肥料与纳米肥料配合施用可以协同提高生菜的产量和营养,为作物的可持续生产提供了一种有前景的方法。未来的研究应该探索这些处理的长期和田间规模的影响。
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引用次数: 0
Is selective identification of poorly crystalline aluminum hydroxides in soils of temperate latitude possible? 是否有可能在温带土壤中选择性地鉴定出结晶性差的氢氧化铝?
Pub Date : 2026-01-07 DOI: 10.1002/saj2.70177
Thilo Rennert, Svetlana Antonova, Jan Dietel

Aluminum (Al) is one of the most abundant elements in soils. As poorly crystalline Al hydroxides are reactive toward soil organic matter (SOM), they are thought to be involved in SOM stabilization. This is also inferred from correlations between soil organic carbon contents and those of Al extracted by acid oxalate in darkness (AOD), although it is known that several species release Al by this extraction. We tested the completeness of dissolution by AOD of synthesized poorly crystalline Al hydroxides and models of Al in organic association, which included dissolved organic matter flocculated by Al ions and Al adsorbed on peat. While Al was almost completely extracted from the organic models, all hydroxides were completely dissolved by AOD extraction. A review of the literature revealed frequent misinterpretation of data on the extraction of Al from hydroxides. An approximation of the detection limit of a combination of extractions, X-ray diffractometry, and X-ray fluorescence spectroscopy revealed that unambiguous quantification of oxidic Al in soils of temperate latitudes is not possible because of the low contents. Therefore, we consider statements about the importance of Al hydroxides for stabilizing SOM in these soils to be questionable as long as adequate analytical technology is unavailable to identify and selectively quantify Al in poorly crystalline phases.

铝是土壤中含量最丰富的元素之一。由于结晶性差的氢氧化铝对土壤有机质(SOM)具有反应性,因此它们被认为参与了土壤有机质的稳定。这也可以从土壤有机碳含量与草酸在黑暗(AOD)中提取的Al之间的相关性中推断出来,尽管已知一些物种通过这种提取释放Al。我们测试了AOD对合成的低结晶度铝氢氧化物的溶解完整性,以及铝在有机缔合中的模型,包括被铝离子絮凝的溶解有机物和吸附在泥炭上的铝。虽然Al几乎完全从有机模型中被提取出来,但所有的氢氧化物都被AOD萃取完全溶解。对文献的回顾揭示了从氢氧化物中提取铝的数据经常被误解。对提取、x射线衍射和x射线荧光光谱相结合的检出限的近似计算表明,温带土壤中氧化铝的明确定量是不可能的,因为含量低。因此,我们认为,只要没有足够的分析技术来识别和选择性地量化低结晶相中的铝,关于氢氧化铝对稳定这些土壤中SOM的重要性的陈述就值得怀疑。
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引用次数: 0
Chemical speciation of zinc in fertilized neutral soils governs zinc mobility and phytoavailability 中性施肥土壤中锌的化学形态决定了锌的流动性和植物可利用性
Pub Date : 2026-01-07 DOI: 10.1002/saj2.70176
Sevendeep K. Chahal, Ganga M. Hettiarachchi, Nathan Nelson, Mary Guttieri

Applied Zn undergoes multiple biogeochemical reactions that determine the available Zn concentration in soil. The choice of Zn fertilizer should depend on the chemical reactions it undergoes, namely, adsorption-desorption, precipitation-dissolution, and complexation-dissociation. The treatments included four different Zn fertilizers: ZnO, ZnSO4.7H2O (ZnSO4), ZnEDTA, and Zn mix (a new Zn product with 60% ZnO, 36% ZnSO4·7H2O, and 4% ZnEDTA by weight). The treatments also included a control (No-Zn) and an ethylenediamine tetraacetic acid (EDTA) treatment (No-Zn + EDTA). The overall objective of this study was to compare the above treatments based on relative Zn diffusion, water extractability, plant biomass, and plant Zn uptake using incubation (soil only) and greenhouse (soil + plant) studies. The X-ray absorption near-edge structure (XANES) spectroscopy was used to evaluate the Zn reaction products in soil. Zinc sulfate and ZnEDTA showed greater diffusion, water extractability, plant concentration, and diethylenetriaminepentaacetic acid extractability of Zn in soil than ZnO and Zn mix treatments. The XANES analysis showed that Zn mainly existed as Zn aluminum nitrate double-layered hydroxide (ZnALDHnitrate)-like species in all treatments except ZnEDTA, complementing our understanding from the incubation and greenhouse studies that Zn gets sorbed quickly to metal oxides or soil surfaces. Plant uptake, Zn concentration, and biomass were comparable between ZnSO4 and ZnEDTA, indicating that both can serve as effective Zn sources under neutral soil conditions. Given its comparable performance and lower cost, ZnSO4 represents a practical alternative to chelated Zn sources such as ZnEDTA.

施锌经过多种生物地球化学反应,决定了土壤中有效锌的浓度。锌肥的选择应取决于其所经历的化学反应,即吸附-解吸,沉淀-溶解和络合-解离。采用ZnO、ZnSO4.7H2O (ZnSO4)、ZnEDTA和混合锌(一种新型锌产品,含60% ZnO、36% ZnSO4·7H2O和4% ZnEDTA) 4种不同的锌肥料处理。处理还包括对照(No-Zn)和乙二胺四乙酸(EDTA)处理(No-Zn + EDTA)。本研究的总体目标是通过培养(仅土壤)和温室(土壤+植物)研究,比较上述处理在相对锌扩散、水分可提取性、植物生物量和植物锌吸收方面的差异。采用x射线吸收近边结构(XANES)光谱对土壤中锌的反应产物进行了评价。硫酸锌和ZnEDTA处理对土壤锌的扩散、水萃取性、植物浓度和二乙烯三胺五乙酸萃取性均优于ZnO和Zn混合处理。XANES分析表明,除ZnEDTA外,其余处理中Zn主要以Zn -铝硝酸盐双层氢氧化物(znaldnitrate)样形态存在,这与我们从培养和温室研究中得到的Zn快速吸附到金属氧化物或土壤表面的认识相辅相成。ZnSO4和ZnEDTA的植物吸收量、Zn浓度和生物量具有可比性,表明在中性土壤条件下,两者都可以作为有效的Zn源。鉴于其相当的性能和更低的成本,ZnSO4代表了螯合锌源(如ZnEDTA)的实用替代品。
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引用次数: 0
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Proceedings - Soil Science Society of America
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