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pH-isfet used as a detector in a flow injection titration system ph值在流动注射滴定系统中用作检测器
Pub Date : 1989-08-01 DOI: 10.1016/0250-6874(89)87056-8
Wang Gui-Hua, Yu Dun, Sun Yu-De

Ion-sensitive field effect transistors (ISFETs) have been successfully introduced into a titration system for flow injection analysis (FIA). The influence of the titration parameters of the ISFET-FIA system is discussed and experimentally studied. Various kinds of acid-base titration have been tested. There exists a good linearity between teq (titration time) and log C02 (concentration of analysed substance), with a regression coefficient better than 0.9997. The titration can be done at a rate of up to 75 samples per hour. The reverse titration method can extend the detection limit down to 5 × 10−4 M of the analysed substance.

离子敏感场效应晶体管(isfet)已成功地应用于流动注射分析(FIA)滴定系统中。讨论了ISFET-FIA系统滴定参数的影响,并进行了实验研究。对各种酸碱滴定法进行了试验。teq(滴定时间)与log co2(被分析物质浓度)之间存在良好的线性关系,回归系数大于0.9997。滴定速度可达每小时75个样品。反滴定法可将被分析物质的检出限延长至5 × 10−4 M。
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引用次数: 9
Solid polymer electrolyte-based electrochemical oxygen sensor 基于固体聚合物电解质的电化学氧传感器
Pub Date : 1989-08-01 DOI: 10.1016/0250-6874(89)87055-6
Yan He-Qing, Lu Jun-Tao

An SPE (solid polymer electrolyte)-based solid-state electrochemical oxygen gas sensor is reported. A hydrophobic Teflon-bonded Pt back layer pressed on a piece of Nafion membrane serves as the working (sensing) electrode, with a diffusion-controlling capillary in front. The sensor exhibits fast response, small temperature coefficient and long-term stability.

报道了一种基于固体聚合物电解质的固态电化学氧气气体传感器。一个疏水的聚四氟乙烯粘合的Pt背面层压在一块Nafion膜上作为工作(传感)电极,前面有一个控制扩散的毛细管。该传感器具有响应快、温度系数小、长期稳定等特点。
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引用次数: 25
Integrated multi-function sensor for flow velocity, temperature and vacuum measurements 集成的多功能传感器流速,温度和真空测量
Pub Date : 1989-08-01 DOI: 10.1016/0250-6874(89)87052-0
Huang Jin-Biao, Tong Qin-Yi

An integrated multifunction sensor based on heat transfer at a constant chip temperature (CCT) has been fabricated by a conventional CMOS process. It consists of a temperature-sensing stage for the measurement of the chip temperature, a CMOS operational amplifier for amplification and control, and a heating branch circuit to heat the sensor chip. All three parts are integrated on one chip and connected to form a negative feedback loop for CCT operation. Using this sensor, measurements of flow velocity, temperature and vacuum have been made. The heating power of the chip is used to indicate those measurands that affect the heat transfer between the chip and the ambient. When used for flow measurements, the sensor demonstrates high sensitivity and a large output level (500 mV output at Vf=50 cm/s, N2, and TcTa=15°C). It can be used to measure both gas and liquid flor velocities. The sensor shows a sensitivity of −64 mV/°C when used for temperature measurements and it has the advantage of much easier design of on-chip signal processing circuits over conventional temperature sensors since the chip temperature is kept constant. When used as a vacuum sensor, experiments show that the vacuum range from atmospheric pressure to 10−1 Torr produces an output change of about 300 mV. Lower pressures can also be measured without any problems.

采用传统CMOS工艺制备了一种基于恒片温传热的集成多功能传感器。它由测量芯片温度的温度传感级、放大和控制的CMOS运算放大器以及加热传感器芯片的加热分支电路组成。这三个部分集成在一个芯片上,并连接形成一个负反馈回路,用于CCT操作。利用该传感器,对流速、温度和真空度进行了测量。芯片的发热功率用来表示那些影响芯片和环境之间的热传递的测量。当用于流量测量时,该传感器具有高灵敏度和大输出电平(在Vf=50 cm/s, N2和TcTa=15°C时500 mV输出)。它可以用来测量气体和液体的地面速度。当用于温度测量时,该传感器的灵敏度为- 64 mV/°C,并且由于芯片温度保持恒定,因此与传统温度传感器相比,它具有更容易设计片上信号处理电路的优点。当用作真空传感器时,实验表明,从大气压到10−1 Torr的真空范围会产生约300 mV的输出变化。较低的压力也可以测量,没有任何问题。
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引用次数: 12
Porosity control of humidity-sensitive ceramics and theoretical model of humidity-sensitive characteristics 湿敏陶瓷的孔隙控制及湿敏特性的理论模型
Pub Date : 1989-08-01 DOI: 10.1016/0250-6874(89)87058-1
Sun Hong-Tao, Wu Ming-Tang, Li Ping, Yao Xi

In this paper, a new method for porosity control of porous humidity-sensitive ceramics is presented. Graphite powder is chosen as the pore former. It is convenient to control the pore size and porosity of porous humidity-sensitive ceramics made from CoFe spinel and MgCr spinel by changing the content and grain size of the pore former. The electrical behaviours can be kept stable for a long time because of the completeness of the solid phase reaction. Experiments indicate that when the weight percentage of graphite is 10–20 wt.%, the humidity sensitivity of these two porous ceramics increases remarkably and the linearity of the resistance and humidity characteristics is clearly improved. It has been shown by XRD, SEM and AES analyses that graphite powder has only a slight influence on the matrix material, but its pore-forming effects are quite favourable. From the electronic—ionic comprehensive conduction model, and use of Grotthuss' transmission mechanism and the phase law of two mixed phases, a new equation of resistance and humidity has been derived theoretically, thus successfully explaining the experimental data. Moreover, the characteristics of resistance and humidity, and those of capacitance and humidity of various types of materials can be determined.

本文提出了一种控制多孔湿敏陶瓷孔隙率的新方法。选择石墨粉作为成孔剂。CoFe尖晶石和MgCr尖晶石制备的多孔湿敏陶瓷可以通过改变孔前的含量和晶粒尺寸来控制孔径和孔隙率。由于固相反应的完备性,电行为可以长时间保持稳定。实验表明,当石墨的质量百分比为10 ~ 20 wt.%时,这两种多孔陶瓷的湿度敏感性显著提高,电阻和湿度特性的线性度明显提高。XRD、SEM和AES分析表明,石墨粉对基体材料的影响很小,但其成孔效果很好。从电子-离子综合传导模型出发,利用Grotthuss传递机理和两相混合的相律,从理论上推导了新的电阻-湿度方程,从而成功地解释了实验数据。此外,还可以确定各种材料的电阻和湿度特性以及电容和湿度特性。
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引用次数: 63
A new sputtered amorphous thin-film pressure transducer 一种新型溅射非晶薄膜压力传感器
Pub Date : 1989-08-01 DOI: 10.1016/0250-6874(89)87053-2
Huang Jun-Qin, Cheng Xian-An, Wang Zhi-Ying

A new sputtered amorphous thin-film pressure transducer is presented. Both the transducer and the material of the amorphous Ni68Si15B17 alloy were developed in our laboratory. The properties of the amorphous alloy are introduced including: (1) the dependence of fractional changes in electrical resistance on the tensile stress; (2) the dependence of electrical resistance on temperature; (3) the behaviour of ΔR/R0=f(σ) after annealing for two hours at 200 °C. The construction, static characteristics and dynamic characteristics of the pressure transducer are then introduced. Many dynamic mathematical models and the dynamic performance of the pressure tranducer are described.

提出了一种新型的溅射非晶薄膜压力传感器。该换能器和非晶Ni68Si15B17合金材料均在本实验室研制完成。介绍了非晶合金的性能,包括:(1)电阻分数变化与拉应力的关系;(2)电阻对温度的依赖性;(3)在200℃下退火2h后ΔR/R0=f(σ)的行为。介绍了该压力传感器的结构、静态特性和动态特性。介绍了各种动态数学模型和压力传感器的动态性能。
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引用次数: 4
Temperauture-humidity-gas multifunctional sensitive ceramics 温度-湿度-气体多功能敏感陶瓷
Pub Date : 1989-08-01 DOI: 10.1016/0250-6874(89)87059-3
Zhou Zhi-Gang, Zhao Gang, Wei Ming, Zhang Zhong-Tai

A new multifunctional sensitive ceramic, BaTiO3BaSnO3 (BTS), which is a p-type metal-oxide porous ceramic semiconductor, has been studied. It is capable of detecting temperature, humidity and gas type with a single sensing element. This paper presents results of research on multifunctional sensitive ceramics. The crystalline phase, porous structure, semiconducting properties and the relationships between the sensitive characteristics and the meso-macrostructure of the pores of BTS porous ceramics have been investigated.

研究了一种新型多功能敏感陶瓷BaTiO3BaSnO3 (BTS),它是一种p型金属氧化物多孔陶瓷半导体。它能够用单个传感元件检测温度,湿度和气体类型。本文介绍了多功能敏感陶瓷的研究成果。研究了BTS多孔陶瓷的晶相、孔结构、半导体性能以及敏感特性与孔中宏观结构的关系。
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引用次数: 25
Signal superimposition of piezoresistive pressure transducers 压阻式压力传感器的信号叠加
Pub Date : 1989-08-01 DOI: 10.1016/0250-6874(89)87054-4
Yu Lian-Zhong, Bao Min-Hang

Signal superimposition for silicon pressure transducers is an approach to make full use of the vast area available on silicon diaphragms to boost signal output, to eliminate the sensitivity to a magnetic field for transverse-voltage type pressure sensors and some other possible applications. Three types of signal superimposition methods are proposed here and a monolithic integrated circuit pressure transducer using active amplifiers is presented.

硅压力传感器的信号叠加是一种充分利用硅膜片上的广阔面积来增强信号输出,消除横向电压型压力传感器对磁场的敏感性和其他一些可能应用的方法。本文提出了三种信号叠加方法,并提出了一种采用有源放大器的单片集成电路压力传感器。
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引用次数: 0
A versatile thermal biosensor 一种多功能热生物传感器
Pub Date : 1989-08-01 DOI: 10.1016/0250-6874(89)87057-X
Xie Bin, Ren Shu

A newly designed thermal biosensor (TBS) is reported. It is constructed by integrating a temperature sensor with a bioreactor, which can be easily dismantled. Such a design makes the TBS versatile. Both differential and adiabatic techniques are used to improve its precision and resolution. As an example of application, a glucose assay is described: resolution 2 × 10−8 mol, linear range 2 × 10−8 mol−1.7 × 10−6 mol, relative error < 6%, lifetime more than one month and sample volume 4 × 10−2 ml.

报道了一种新型热生物传感器(TBS)。它由一个温度传感器和一个生物反应器组成,可以很容易地拆卸。这样的设计使TBS多功能。采用微分技术和绝热技术来提高其精度和分辨率。作为应用示例,描述了葡萄糖测定:分辨率2 × 10 - 8 mol,线性范围2 × 10 - 8 mol - 1.7 × 10 - 6 mol,相对误差<6%,寿命1个月以上,进样量4 × 10 - 2 ml。
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引用次数: 1
Conference announcements 会议公告
Pub Date : 1989-08-01 DOI: 10.1016/0250-6874(89)87060-X
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引用次数: 0
Electrochemical encapsulation for sensors 传感器电化学封装
Pub Date : 1989-07-01 DOI: 10.1016/0250-6874(89)87047-7
Karin Potje-Kamloth, Petr Janata , Jiri Janata , Mira Josowicz

A high-resolution encapsulation procedure suitable for chemical sensors has been developed. It is based on the electrochemical generation of a poly-(oxyphenylene) film at the electrically active areas of the device. The 1.5 to 5 μ thick encapsulation film is selectively deposited on gold, platinum or carbon surfaces. No deposition takes place on aluminium, which allows this metal to be used as a mask. The resistivity of a 2 μm thick film after a four-week exposure to 0.1 M NaCl is 7 × 1011 Ω cm.

开发了一种适用于化学传感器的高分辨率封装程序。它是基于在装置的电活性区域产生聚(氧苯)薄膜的电化学。将1.5 ~ 5 μ厚的包封膜选择性地沉积在金、铂或碳表面。铝上不会发生沉积,这使得这种金属可以用作掩模。2 μm厚薄膜在0.1 M NaCl中暴露4周后的电阻率为7 × 1011 Ω cm。
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引用次数: 24
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Sensors and Actuators
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