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Effect of high-intensity ultrasound on the physicochemical, nutritional, rheological, microstructural, and techno-functional properties of a groundnut (Arachis hypogaea L.) paste protein isolate 高强度超声对花生膏体分离蛋白理化、营养、流变学、微观结构和技术功能特性的影响
Pub Date : 2025-06-24 DOI: 10.1039/D5FB00196J
Ángel Efraín Rodríguez Rivera, José Armando Ulloa, Nitzia Thalía Flores Jiménez and Judith Esmeralda Urías-Silvas

With the continuous growth of the global population, obtaining new sources of protein is a priority to meet the nutritional needs of society. In this sense, the recovery of proteins from plant sources such as de-oiled oilseed pastes such as groundnut has gained relevance. In this study, a groundnut paste protein isolate (GPPI) was obtained via alkaline extraction followed by isoelectric precipitation. The GPPI was then treated with high-intensity ultrasound (HI-U) at 200, 400 and 600 W for 15 and 30 min to evaluate the effect on its physicochemical, nutritional, rheological, microstructural and techno-functional properties. Results showed that HI-U increased the GPPI's turbidity by up to 8.85%, antioxidant capacity by 163.71%, protein digestibility by 3.54%, apparent viscosity by 409%, emulsifying activity index by 147% and foaming capacity by 116.17%, while its water activity decreased by up to 18.48%, compared with the control treatment (GPPI without HI-U). The flow and cohesion properties of the GPPI measured as the Carr index and Hausner ratio, respectively, showed enhancements of up to 19.74% and 4.92%, respectively, because of HI-U. According to their fluid behavior, GPPI suspensions showed pseudoplastic characteristics. Furthermore, the apparent viscosity results of the GPPIs were adequately fitted to the power law model (r2 = 0.929–0.966), showing low values in the consistency (0.024–0.085 Pa s) and fluidity (0.945–0.891) indices, confirming their behavior as a pseudoplastic fluid. Moreover, microphotographs revealed larger microstructures by the HI-U impact. The findings of this study can facilitate the use of GPPIs as an important protein ingredient for food production.

随着全球人口的不断增长,获取新的蛋白质来源是满足社会营养需求的一个优先事项。从这个意义上说,从植物来源(如花生等去油油籽糊状物)中回收蛋白质已经获得了相关性。本研究以花生膏蛋白分离物(GPPI)为原料,采用碱法提取,然后等电沉淀法。然后在200、400和600 W的高强度超声(HI-U)下处理GPPI 15和30分钟,以评估其理化、营养、流变学、微观结构和技术功能特性的影响。结果表明,与不加HI-U的对照处理相比,HI-U可使GPPI的浊度提高8.85%,抗氧化能力提高163.71%,蛋白质消化率提高3.54%,表观粘度提高409%,乳化活性指数提高147%,起泡能力提高116.17%,而水活性降低18.48%。以Carr指数和Hausner比值衡量的GPPI的流动性能和内聚性能分别因HI-U而提高了19.74%和4.92%。根据其流体行为,GPPI悬浮液表现出假塑性特征。此外,gppi的表观粘度结果与幂律模型拟合良好(r2 = 0.929-0.966),稠度(0.024-0.085 Pa s)和流动性(0.945-0.891)指标均较低,表明其为假塑性流体。此外,显微照片显示了HI-U撞击后更大的微观结构。本研究结果可以促进gppi作为一种重要的蛋白质成分用于食品生产。
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引用次数: 0
Vanillin reinforced cationic starch/poly(vinyl alcohol) based antimicrobial and antioxidant bioactive films: sustainable food packaging materials† 香兰素增强阳离子淀粉/聚乙烯醇基抗菌和抗氧化生物活性膜:可持续食品包装材料†
Pub Date : 2025-06-24 DOI: 10.1039/D5FB00132C
Lingaraj Kariyappa Kurabetta, Saraswati P. Masti, Manjushree Nagaraj Gunaki, Ajitkumar Appayya Hunashyal, Ravindra B. Chougale, Nagarjuna Prakash Dalbanjan and S. K. Praveen Kumar

The growing demand for eco-friendly and sustainable packaging solutions has accelerated the development of biodegradable materials for fresh food preservation. In this study, bioactive films were developed using cationic starch (CT) and poly(vinyl alcohol) (PVA), functionalized with varying concentrations of vanillin (VN) via a solvent casting method. The resulting CT/PVA/VN (CPVN) films were systematically characterized to evaluate their functional properties. Notably, films with 3 wt% VN exhibited excellent UV-blocking ability and a remarkable enhancement in tensile strength (∼49.44%) compared to the pristine CT/PVA blend. The incorporation of VN also significantly improved the barrier properties of the films, reducing water vapor permeability (∼60.01%) and moisture adsorption (∼30.54%). Furthermore, the phenolic structure of VN contributed to a substantial increase in antioxidant activity (∼81.33%) and imparted potent antimicrobial activity against foodborne pathogens such as Escherichia coli, Bacillus subtilis, Pseudomonas aeruginosa, Staphylococcus aureus, and Candida albicans. The CPVN films also demonstrated promising environmental compatibility, achieving over 40% biodegradation in soil within 30 days. These findings highlight VN's multifunctional role in enhancing the structural, barrier, and bioactive properties of CT/PVA films, making CPVN films strong candidates for sustainable food packaging applications.

对环保和可持续包装解决方案的需求不断增长,加速了用于保鲜食品的可生物降解材料的发展。本研究以阳离子淀粉(CT)和聚乙烯醇(PVA)为原料,用不同浓度的香兰素(VN)通过溶剂铸造法进行功能化,制备了生物活性膜。对所得的CT/PVA/VN (CPVN)薄膜进行了系统表征,以评价其功能特性。值得注意的是,与原始CT/PVA共混物相比,含有3 wt% VN的薄膜具有出色的紫外线阻挡能力和显著的抗拉强度增强(约49.44%)。VN的加入也显著改善了膜的阻隔性能,降低了水蒸气渗透性(~ 60.01%)和吸湿性(~ 30.54%)。此外,VN的酚类结构有助于显著提高抗氧化活性(约81.33%),并赋予对食源性病原体(如大肠杆菌、枯草芽孢杆菌、铜绿假单胞菌、金黄色葡萄球菌和白色念珠菌)的有效抗菌活性。CPVN膜也表现出良好的环境相容性,在30天内在土壤中实现了40%以上的生物降解。这些发现突出了VN在增强CT/PVA薄膜的结构、屏障和生物活性方面的多功能作用,使CPVN薄膜成为可持续食品包装应用的强有力的候选者。
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引用次数: 0
Valorization of grapevine agricultural waste into transparent and high-strength biodegradable films for sustainable packaging† 用于可持续包装的葡萄农业废弃物转化为透明和高强度可生物降解薄膜†
Pub Date : 2025-06-20 DOI: 10.1039/D5FB00211G
Sandeep Paudel, Sumi Regmi, Sajal Bhattarai, Anne Fennell and Srinivas Janaswamy

The impact of single-use and short-lived plastic food packaging is significant, contributing substantially to environmental waste that harms ecosystems. Microplastic pollution and chemical leaching from plastic packaging pose risks to humans, animals, and plants. Consequently, our environment is increasingly contaminated by plastic waste, microplastics, and nanoplastics, resulting in a pervasive pollutant. In this context, alternative biodegradable and sustainable packaging can help mitigate the harmful effects of plastic waste. Agricultural byproducts, which might otherwise be discarded, hold considerable potential for this purpose. This study demonstrates the use of grapevines as a source of cellulose to develop novel, transparent, and biodegradable films. Grapevine canes are major woody berry crops that generate substantial winter pruning waste. This waste contains a high level of cellulose, approximately 35%. Herein, the cellulose fraction was extracted using alkaline (10% KOH) and bleaching (10% NaClO2) treatments. It was then solubilized in a ZnCl2 solution, crosslinked with calcium ions, and plasticized with glycerol to develop films. These films exhibit a transparency of 83.70–84.30% mm−1 and a tensile strength of 15.42–18.20 MPa. They biodegrade within 17 days in soil at 24% moisture content. These films demonstrate outstanding potential for food packaging applications. Our research approach of repurposing agricultural byproducts to create high-value products helps reduce plastic waste, conserve the environment, and provide economic benefits to farmers.

一次性和短寿命塑料食品包装的影响是巨大的,在很大程度上造成了危害生态系统的环境浪费。塑料包装中的微塑料污染和化学浸出对人类、动物和植物构成威胁。因此,我们的环境越来越多地受到塑料废物、微塑料和纳米塑料的污染,造成无处不在的污染物。在这种情况下,可替代的可生物降解和可持续包装可以帮助减轻塑料废物的有害影响。本来可以丢弃的农业副产品在这方面具有相当大的潜力。这项研究展示了利用葡萄藤作为纤维素的来源来开发新型的、透明的、可生物降解的薄膜。葡萄藤是主要的木本浆果作物,会产生大量的冬季修剪废料。这种废物含有高水平的纤维素,约为35%。本文采用碱性(10% KOH)和漂白(10% NaClO2)处理提取纤维素组分。然后将其溶解于ZnCl2溶液中,与钙离子交联,并与甘油塑化以显影。薄膜的透明度为83.70 ~ 84.30% mm−1,抗拉强度为15.42 ~ 18.20 MPa。它们在含水量24%的土壤中可在17天内生物降解。这些薄膜在食品包装应用方面具有突出的潜力。我们的研究方法是重新利用农业副产品来创造高价值的产品,有助于减少塑料废物,保护环境,并为农民提供经济效益。
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引用次数: 0
Design and development of a parabolic trough solar collector for pasteurization of milk† 牛奶巴氏杀菌用抛物面槽太阳能集热器的设计与研制
Pub Date : 2025-06-18 DOI: 10.1039/D5FB00018A
Shyam Kumar Singh and Ashis Kumar Datta

Milk, regardless of its end use, is required by law to be pasteurized to kill spoilage microorganisms and deactivate enzymes. Conventional methods of pasteurization use fossil fuels, which have a harmful effect on the environment. This study presents the design, optimization, fabrication, and experimental evaluation of a solar-powered milk pasteurization system using a parabolic trough collector (PTC) integrated with a single-axis solar tracking mechanism. The design parameters of the PTC including length (3 m), width (1 m), and rim angle (90°) were optimized using a combination of SolidWorks flow simulations and SolTrace, respectively. A single-axis solar tracking device was also developed to increase the efficiency of PTC, and this allowed the PTC to align with the direction of the Sun. The developed PTC was tested to determine whether it could achieve the temperature normally used for milk pasteurization. Milk and water temperature increased from an initial value of 33.03 ± 2.73 °C to 76.03 ± 1.35 °C, and 29.67 ± 2.86 °C to 80.85 ± 2.06 °C in 1 hour, respectively. Temperature increases of 12.43 ± 1.59 °C and 17.90 ± 2.42 °C were found for milk and water at a flow rate of 30 L h−1 in a single pass, respectively. This temperature increase suggests that the developed system has the potential to be used for the pasteurization of milk and similar liquid products utilizing solar energy.

牛奶,无论其最终用途如何,法律都要求进行巴氏消毒,以杀死腐败微生物并使酶失活。传统的巴氏灭菌方法使用化石燃料,这对环境有有害影响。本研究介绍了利用抛物线槽收集器(PTC)集成单轴太阳能跟踪机构的太阳能牛奶巴氏杀菌系统的设计、优化、制造和实验评估。采用SolidWorks flow simulation和SolTrace软件对PTC的长度(3 m)、宽度(1 m)和边缘角(90°)设计参数进行优化。为了提高PTC的效率,还开发了一个单轴太阳跟踪装置,这使得PTC能够与太阳的方向对齐。对研制的PTC进行了测试,以确定它是否能达到通常用于牛奶巴氏杀菌的温度。牛奶和水的温度在1小时内分别从初始值33.03±2.73℃上升到76.03±1.35℃,29.67±2.86℃上升到80.85±2.06℃。在30 L h−1的流速下,牛奶和水的温度分别升高12.43±1.59°C和17.90±2.42°C。这种温度的升高表明,开发的系统有潜力用于利用太阳能对牛奶和类似液体产品进行巴氏消毒。
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引用次数: 0
Apple and grape pomace: emerging upcycled functional ingredients in processed meat products, designed to increase polyphenol and fiber contents† 苹果和葡萄渣:加工肉制品中新兴的功能性成分,旨在增加多酚和纤维含量†
Pub Date : 2025-06-13 DOI: 10.1039/D5FB00040H
Peter R. Gracey and Elad Tako

Apple and grape pomace, byproducts of juice, cider, and wine production, are typically sent to landfills or used as animal feed. At landfills, they release greenhouse gases like methane and carbon dioxide during anaerobic digestion. These pomaces are rich in fiber (31.79–61.71%) and polyphenols, which are lacking in the western diet, particularly in widely consumed meat-based food products. This review aims to explore the current literature that discusses the effects of incorporating apple and grape pomace into meat, focusing on fiber enrichment, prevention of lipid oxidation, and sensory characteristics like color, flavor, and texture. This narrative review consolidates findings from research databases to provide a structured synthesis of current knowledge on the topic. The polyphenols in pomace are as effective as synthetic antioxidants in reducing lipid oxidation. However, high pomace levels can increase meat hardness. Including pomace in meat products could reduce waste, minimize landfill contributions, and enhance meat's nutritional and functional properties.

苹果和葡萄渣是果汁、苹果酒和葡萄酒生产的副产品,通常被送到垃圾填埋场或用作动物饲料。在垃圾填埋场,它们在厌氧消化过程中释放出甲烷和二氧化碳等温室气体。这些果渣富含纤维(31.79-61.71%)和多酚,这是西方饮食中缺乏的,尤其是在广泛食用的肉类食品中。本文综述了苹果渣和葡萄渣对肉类的影响,重点介绍了苹果渣和葡萄渣的纤维富集、防止脂质氧化以及颜色、风味和质地等感官特性。这篇叙述性综述整合了来自研究数据库的发现,提供了关于该主题的当前知识的结构化综合。果渣中的多酚类物质与合成抗氧化剂一样具有降低脂质氧化的作用。然而,高渣含量会增加肉的硬度。在肉制品中加入粪渣可以减少浪费,最大限度地减少垃圾填埋,并提高肉类的营养和功能特性。
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引用次数: 0
Sustainable valorization of tropical fruit peels for sustainable production of natural antioxidants and functional food ingredients† 热带水果果皮的可持续增值,以实现天然抗氧化剂和功能性食品成分的可持续生产
Pub Date : 2025-06-13 DOI: 10.1039/D4FB00371C
Panorjit Nitisuk, Pitchaporn Wanyo, Tossaporn Chamsai and Kiatipong Charoenjit

Tropical fruit peels, frequently discarded during agricultural and food processing, represent an underutilized source of natural antioxidants and bioactive compounds. This study aimed to valorize tropical fruit peels, namely mango, banana, dragon fruit, pineapple, and papaya, by transforming them into functional food ingredients. Ethanol-based ultrasound-assisted extraction was applied to enhance the bioactive compounds and their antioxidant potentials. The variation in physicochemical characteristics, bioactive components, and antioxidant capacity of various fruit peel powders was investigated. 2,2-Diphenyl-1-picrylhydrazyl (DPPH), ferric-reducing antioxidant power (FRAP), and total antioxidant capacity assays were used to evaluate the antioxidant activities. The qualitative method was used for the phytochemical screening. Additionally, reverse-phase high-performance liquid chromatography (RP-HPLC) analysis reveals their phenolic compositions. Then, the selected high-potential components were incorporated into biscuits. The digestion method was conducted following the INFOGEST protocol. Comparing all tested powders, the mango peel powder (MPP) had the highest total phenolic content (TPC) with 69.81 mg GAE per g and the highest antioxidant activity, which corresponded with the presence of gallic acid (13.95 mg g−1), chlorogenic acid (9.62 mg g−1), and quercetin (11.59 mg g−1). The incorporation of MPP (5–15%) into biscuits improved nutritional composition and antioxidant potential while maintaining acceptable sensory characteristics at lower inclusion levels. Simulated in vitro digestion confirmed the retention and bioaccessibility of phenolics and flavonoids, indicating their functional relevance. This study addresses a gap in bioaccessibility and sensory acceptability of tropical fruit peel-fortified functional foods. This valorization framework also adopts circular economy principles, using residual biomass for composting. The findings demonstrate a green, scalable approach to transform fruit peel waste into health-promoting, functional ingredients aligned with sustainable food production.

在农业和食品加工过程中经常被丢弃的热带水果果皮是一种未充分利用的天然抗氧化剂和生物活性化合物的来源。本研究旨在将芒果、香蕉、火龙果、菠萝、木瓜等热带水果果皮转化为功能性食品原料。以乙醇为基础,采用超声辅助提取的方法提高其生物活性成分及其抗氧化活性。研究了不同果皮粉的理化特性、生物活性成分和抗氧化能力的变化。采用2,2-二苯基-1-苦味酰肼(DPPH)、铁还原抗氧化能力(FRAP)和总抗氧化能力等方法评价其抗氧化活性。采用定性方法进行植物化学筛选。此外,反相高效液相色谱(RP-HPLC)分析揭示了它们的酚类成分。然后,将选定的高电位组分掺入饼干中。消化方法按照INFOGEST方案进行。芒果皮粉(MPP)的总酚含量(TPC)最高,为69.81 mg GAE / g,抗氧化活性最高,与没食子酸(13.95 mg g−1)、绿原酸(9.62 mg g−1)和槲皮素(11.59 mg g−1)的存在相对应。在饼干中掺入MPP(5-15%)可以改善饼干的营养成分和抗氧化潜力,同时在较低的掺入水平下保持可接受的感官特性。体外消化模拟证实了酚类物质和黄酮类物质的保留和生物可及性,表明它们的功能相关。本研究解决了热带果皮强化功能食品在生物可及性和感官可接受性方面的差距。这种增值框架也采用循环经济原则,利用剩余生物质进行堆肥。研究结果展示了一种绿色、可扩展的方法,可以将果皮废物转化为促进健康的功能性成分,与可持续粮食生产相一致。
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引用次数: 0
Blockchain technology in the food supply chain: a way towards circular economy and sustainability 区块链技术应用于食品供应链:迈向循环经济和可持续发展之路
Pub Date : 2025-06-09 DOI: 10.1039/D5FB00065C
Devraj V. Rajput, Pavankumar R. More, Preeti A. Adhikari and Shalini S. Arya

The current status of the global food supply chain offers several challenges, particularly those related to traceability, transparency, and sustainability. Blockchain technology is recognized as a revolutionary tool that can revolutionize a wide range of sectors, and its implementation in food supply chains shows immense potential for improving circular economy practices and ensuring sustainability. The implementation of blockchain technology in the food supply chain and its tremendous influence on building a more sustainable and circular economy are examined in this review paper. Blockchain, with its decentralized and transparent characteristics, provides a unique approach for improving traceability and decreasing fraud in the food supply chain. This article investigates the many ways in which blockchain, including smart contracts, might increase efficiency and encourage sustainable behavior, eventually decreasing waste. Furthermore, the paper discusses the intriguing prospects of combining blockchain with cutting-edge technologies like the Internet of Things (IoT) and Artificial Intelligence (AI) to transform the food supply chain. Furthermore, using examples, we examine real-world applications, advantages, and constraints of blockchain adoption in the food business. The report finishes with insights into blockchain technology's possible future as an amplifier for increasing transparency, traceability, waste reduction, and improved sustainability in the worldwide food industry.

全球食品供应链的现状带来了一些挑战,特别是与可追溯性、透明度和可持续性有关的挑战。区块链技术被认为是一种革命性的工具,可以使许多部门发生革命性的变化,在食品供应链中实施区块链技术显示出改善循环经济实践和确保可持续性的巨大潜力。本文综述了区块链技术在食品供应链中的实施及其对建立更可持续和循环经济的巨大影响。区块链以其分散和透明的特点,为提高食品供应链的可追溯性和减少欺诈提供了一种独特的方法。本文研究了区块链(包括智能合约)提高效率和鼓励可持续行为的多种方式,最终减少了浪费。此外,本文还讨论了区块链与物联网(IoT)和人工智能(AI)等尖端技术相结合以改变食品供应链的有趣前景。此外,通过实例,我们考察了区块链在食品行业的实际应用、优势和限制。该报告最后对区块链技术的未来前景进行了深入分析,区块链技术将在全球食品行业中提高透明度、可追溯性、减少浪费和提高可持续性。
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引用次数: 0
Sustainable synthesis and optimisation of ethyl oleate from high oleic acid waste: a pathway to valorise industrial byproducts† 从高油酸废物中可持续合成和优化油酸乙酯:工业副产品增值的途径
Pub Date : 2025-06-09 DOI: 10.1039/D5FB00110B
Ana Soares, Ana Luiza Fontes, Francisca Teixeira, Paula Costa, Lígia Pimentel, Manuela Pintado and Luis Miguel Rodríguez-Alcalá

Ethyl oleate (EO) is a versatile compound with several industrial applications, such as a vaccine adjuvant, an emollient in cosmetics, and a key component in food products as an additive used for pretreatment in preservation processes such as drying, while preserving valuable nutrients. Ethyl oleate is primarily synthesised from edible oils, which raises concerns regarding competition with food production. This study proposes the use of a high oleic acid waste (HOW) obtained from industrial pipelines as a raw material for EO production, by transesterification with ethanol and using sodium hydroxide as a catalyst. The effects of the HOW :  ethanol ratio and recirculated EO addition on both yield and purity levels were investigated. An HOW : ethanol ratio of 6 : 1 (w/w) and a 10% (w/w) of EO recirculated addition resulted in the highest purity (86.16 ± 0.04%) and yield (96.35 ± 0.01%). The resultant EO samples were characterized towards its composition and physicochemical properties. The study highlights the sustainable valorisation of industrial waste. This approach avoids competition with the food chain and offers an eco-friendly method to produce EO for various industrial applications, particularly in food science.

油酸乙酯(EO)是一种多功能化合物,具有多种工业用途,例如疫苗佐剂、化妆品润肤剂和食品中的关键成分,作为添加剂用于干燥等保存过程中的预处理,同时保存有价值的营养物质。油酸乙酯主要由食用油合成,这引起了人们对与食品生产竞争的担忧。本研究提出利用从工业管道中获得的高油酸废物(HOW)作为生产EO的原料,通过与乙醇酯交换并使用氢氧化钠作为催化剂。考察了HOW: ethanol的比例和循环EO的添加对收率和纯度的影响。HOW: ethanol: ethanol:乙醇比为6:1 (w/w),再循环添加量为10% (w/w)时,纯度为86.16±0.04%,收率为96.35±0.01%。对所得样品的组成和理化性质进行了表征。这项研究强调了工业废物的可持续增值。这种方法避免了与食物链的竞争,并提供了一种环保的方法来生产EO,用于各种工业应用,特别是在食品科学领域。
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引用次数: 0
Cold plasma enhanced gelation and thermal properties of oat protein and its application in a selected model food system 冷等离子体增强燕麦蛋白的凝胶和热性质及其在选定的模型食品体系中的应用
Pub Date : 2025-06-09 DOI: 10.1039/D5FB00129C
Gunaseelan Eazhumalai, Ranjitha Gracy T. K. and Uday S. Annapure

Cold plasma-induced reactions are anticipated to yield structural changes in plant proteins to desirably modify their gelation properties. The present study aimed to investigate the effects of atmospheric pin-to-plate cold plasma treatment on the gelation and thermal properties of oat protein. Oat protein was subjected to cold plasma at different input voltages (170 V and 230 V) and exposure times (15 min and 30 min) and was studied for its rheological and thermal characteristics. Protein gels were made using the thermal gelation method at the lowest gelation concentration (20% w/v) and were studied for their rheological and textural properties. While all the plasma-treated protein dispersions showed increased rheological properties due to the induced aggregation, the gels formed from the 230 V-15 min treated sample exhibited higher viscosity (∼7981 cP), visco-elastic moduli (G′ – 3682.4 Pa; G′′ – 1170.50 Pa) and stability (γc – 2.11%) compared to all other samples owing to the medium-sized aggregates and the positive zeta potential. This might also be attributed to a decreased denaturation temperature (∼93.29 °C) of the sample. Additionally, plasma-treated oat protein-incorporated patties demonstrated improved functional properties, including reduced syneresis loss (∼74% reduction) and increased compression juice loss (∼36% rise) due to enhanced moisture retention and water holding capacity. Textural analysis revealed that patties containing oat protein treated at 230 V for 15 min exhibited superior softness after cooking. These findings suggest that cold plasma treatment enhances the gelation properties of oat protein under specific treatment conditions, improving the textural attributes of the plant-based patties.

预计冷等离子体诱导的反应会产生植物蛋白的结构变化,以理想地改变其凝胶特性。本研究旨在研究常压针板冷等离子体处理对燕麦蛋白凝胶化和热性能的影响。将燕麦蛋白置于不同输入电压(170 V和230 V)和不同暴露时间(15 min和30 min)的冷等离子体中,研究其流变学和热特性。在最低凝胶浓度(20% w/v)下,采用热凝胶法制备蛋白质凝胶,并对其流变学和结构特性进行了研究。虽然所有经血浆处理的蛋白分散体由于诱导聚集而表现出增加的流变性能,但经230 V-15 min处理的样品形成的凝胶具有更高的粘度(~ 7981 cP),粘弹性模量(G′- 3682.4 Pa;G ' ' - 1170.50 Pa)和稳定性(γc - 2.11%)与所有其他样品相比,由于中等团聚体和正zeta电位。这也可能是由于样品的变性温度降低(~ 93.29°C)。此外,经血浆处理的燕麦蛋白掺入肉饼显示出改善的功能特性,包括减少协同作用损失(减少约74%)和增加压缩汁损失(增加约36%),这是由于增强的保湿和保水能力。质地分析表明,在230 V下处理15分钟后,含有燕麦蛋白的肉饼在烹饪后表现出优异的柔软性。这些发现表明,在特定的处理条件下,冷等离子体处理增强了燕麦蛋白的凝胶特性,改善了植物性肉饼的质地属性。
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引用次数: 0
Utilizing spent coffee grounds as sustainable fillers in biopolymer composites: influence of particle size and content† 利用废咖啡渣作为生物聚合物复合材料的可持续填料:粒径和含量的影响
Pub Date : 2025-06-06 DOI: 10.1039/D5FB00187K
Gabriel Mäder, Nadine Rüegg, Tobias Tschichold and Selçuk Yildirim

This study presents the first systematic investigation of spent coffee grounds (SCG) particle size effects in polybutylene succinate (PBS) and polybutylene adipate terephthalate (PBAT) biocomposites, evaluating their potential as sustainable fillers in biodegradable polymers. Composites containing 30–60 wt% SCG were produced using unfractionated (SCG_m), coarse (SCG_L), and fine (SCG_S) particle size fractions. Thermogravimetric analysis (TGA) confirmed that both PBS and PBAT composites retained thermal stability up to processing temperatures of 220 °C, with onset degradation temperatures ranging from 266 °C to 294 °C for PBS and from 267 °C to 294 °C for PBAT. DSC analysis for PBS revealed an increase in glass transition temperature from −29.83 °C (neat) to −13.48 °C (60% SCG_m), while crystallinity remained stable (26.38–28.64%). Mechanical testing showed that SCG_m increased stiffness in both matrices. Young's modulus rose from 675 MPa (PBS) and 52 MPa (PBAT) up to 1016 MPa and 210 MPa, respectively. However, tensile strength declined from 34.5 MPa to 9.0 MPa (PBS) and from 18.8 MPa to 4.3 MPa (PBAT), and elongation at break dropped sharply, particularly in PBS (148% to 2.7%) and to a lesser extent in PBAT (446% to 12.4%). Finer SCG particles (SCG_S) enhanced ductility and water uptake (up to 3.40% for PBS and 4.42% for PBAT), while coarser particles (SCG_L) provided higher stiffness. Water contact angle and colour changes were minor across all samples. These results demonstrate that SCG can partially replace virgin biopolymer content in PBS and PBAT, enabling property tuning through particle size and promoting material circularity.

本研究首次系统研究了废咖啡渣(SCG)在聚丁二酸丁二酯(PBS)和聚己二酸丁二酯(PBAT)生物复合材料中的粒径效应,评估了它们作为可生物降解聚合物可持续填料的潜力。含30-60 wt% SCG的复合材料采用未分馏(SCG_m),粗(SCG_L)和细(SCG_S)粒度馏分生产。热重分析(TGA)证实,PBS和PBAT复合材料在220°C的加工温度下仍保持热稳定性,PBS的起始降解温度为266°C至294°C, PBAT的起始降解温度为267°C至294°C。DSC分析显示PBS的玻璃化转变温度从- 29.83°C(纯)增加到- 13.48°C (60% SCG_m),而结晶度保持稳定(26.38-28.64%)。力学试验表明,SCG_m增加了两种基体的刚度。杨氏模量分别从675 MPa (PBS)和52 MPa (PBAT)增加到1016 MPa和210 MPa。然而,拉伸强度从34.5 MPa (PBS)下降到9.0 MPa,从18.8 MPa下降到4.3 MPa (PBAT),断裂伸长率急剧下降,尤其是PBS(148%至2.7%),PBAT(446%至12.4%)下降幅度较小。更细的SCG颗粒(SCG_S)增强了延展性和吸水性(PBS为3.40%,PBAT为4.42%),而更粗的颗粒(SCG_L)提供了更高的刚度。所有样品的水接触角和颜色变化都很小。这些结果表明,SCG可以部分取代PBS和PBAT中原始生物聚合物的含量,从而通过粒径调整性能并促进材料循环。
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Sustainable Food Technology
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