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Potato peel-based PBS/PBAT biocomposites: influence of composition and filler content on injection molded properties 马铃薯皮基PBS/PBAT生物复合材料:成分和填料含量对注塑成型性能的影响
Pub Date : 2025-10-14 DOI: 10.1039/D5FB00333D
Susanna Miescher, Florine Schleiffer, Eliane Wegenstein and Selçuk Yildirim

The growing demand for sustainable materials has intensified interest in bio-based and biodegradable polymers as alternatives to fossil-based plastics. This study investigated the development of injection-molded biocomposites based on poly(butylene succinate) (PBS), poly(butylene adipate-co-terephthalate) (PBAT), and their blends, reinforced with 30–70 wt% potato peels (PP), an abundant by-product of food processing. The effects of filler content and polymer composition on thermal, mechanical, and moisture-related properties were systematically evaluated. All composites remained thermally stable below 228 °C, confirming the suitability of PP for melt processing. FTIR spectroscopy showed no evidence of chemical bonding between filler and polymer matrices, although weak physical interactions were observed, particularly in PBS-rich systems. In contrast, blending PBS with PBAT indicated polymer–polymer interactions, suggesting partial compatibilization, as reflected in a 1.8-fold increase in elongation at break. PP addition consistently altered composite structure and significantly enhanced stiffness, with the elastic modulus increasing from 698 to 1825 MPa for PBS (+162%) and from 77 to 1161 MPa for PBAT (+1418%) at 70 wt% PP. Conversely, tensile strength decreased from 35.0 to 10.6 MPa (PBS) and from 17.1 to 6.5 MPa (PBAT), and elongation at break dropped below 3% for all composites containing ≥40 wt% PP. Overall, PBS/PBAT-potato peel composites exhibited more balanced mechanical performance compared to neat PBS or PBAT composites. DSC analysis revealed that PP acted as a nucleating agent in PBS and PBS-rich blends, increasing crystallization temperature with only minor impact on overall crystallinity. Collectively, these findings demonstrate the feasibility of producing high-filler-content biocomposites for sustainable packaging and agricultural materials.

对可持续材料的需求日益增长,增强了人们对生物基和可生物降解聚合物作为化石基塑料替代品的兴趣。本研究研究了以聚丁二酸丁二酯(PBS)、聚己二酸丁二酯-对苯二甲酸乙二醇酯(PBAT)及其共混物为基础的注射成型生物复合材料的开发,并以30 - 70%重量%的马铃薯皮(PP)作为增强材料。系统地评价了填料含量和聚合物组成对热学、力学和水分相关性能的影响。所有复合材料在228℃以下保持热稳定,证实了PP适合熔融加工。FTIR光谱显示填料和聚合物基体之间没有化学键,尽管观察到弱的物理相互作用,特别是在富含pbs的体系中。相比之下,PBS与PBAT共混表明聚合物-聚合物相互作用,表明部分相容,断裂伸长率增加1.8倍。PP的加入改变了复合材料的结构,显著提高了复合材料的刚度,当PP含量为70 wt%时,PBS的弹性模量从698增加到1825 MPa (+162%), PBAT的弹性模量从77增加到1161 MPa(+1418%)。相反,拉伸强度从35.0下降到10.6 MPa (PBS),从17.1下降到6.5 MPa (PBAT),所有含PP≥40 wt%的复合材料的断裂伸长率都下降到3%以下。与纯PBS或PBAT复合材料相比,PBS/PBAT-马铃薯皮复合材料表现出更平衡的力学性能。DSC分析显示,PP在PBS和富PBS共混物中起到成核剂的作用,提高结晶温度,但对整体结晶度影响较小。总的来说,这些发现证明了为可持续包装和农业材料生产高填充物含量生物复合材料的可行性。
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引用次数: 0
Microencapsulation of red palm oil with soy protein concentrate–carrageenan conjugates for compound dark chocolate applications 红棕榈油与大豆浓缩蛋白-卡拉胶偶联物的微胶囊化,用于复合黑巧克力
Pub Date : 2025-10-14 DOI: 10.1039/D5FB00278H
Haida Setyani, Arima Diah Setiowati, Sri Rahayoe, Chusnul Hidayat and Arifin Dwi Saputro

Red palm oil (RPO) is a rich source of carotenoids but is susceptible to degradation and possesses a distinct palm-like odor and taste that may affect the sensory quality of food products. Microencapsulation is considered a potential approach to address these challenges. This study aimed to minimize the aftertaste of RPO through the characterization and formulation of the microencapsulation process. Soy Protein Concentrate (SPC) and carrageenan (CG) were conjugated at various ratios, with the optimal ratio being 3 : 1, which demonstrated improved emulsifying properties, a higher degree of glycation (DG), and greater formation of Maillard reaction products. The resulting microcapsules exhibited a high encapsulation efficiency of up to 82.27% at an oil-to-wall material ratio of 1 : 3, along with good color retention and in situ absorption, as indicated by 82% carotenoid absorption in an in situ intestinal study. The addition of RPO microcapsules to dark chocolate bars did not affect the texture, melting point, morphology, and sensory attributes. However, it had a significant effect (p < 0.05) on color and rheology parameters. Overall, the encapsulation of RPO using the SPC–CG conjugate as the wall material effectively masked the inherent palm-like taste and odor of the oil when incorporated into the chocolate product, making them undetectable to panelists. These findings support the application of protein–polysaccharide conjugates as a wall material for encapsulating bioactive compounds in functional food products.

红棕榈油(RPO)是类胡萝卜素的丰富来源,但容易降解,并具有独特的棕榈气味和味道,可能会影响食品的感官质量。微胶囊被认为是解决这些挑战的潜在方法。本研究旨在通过表征和配方的微胶囊化工艺,最大限度地减少RPO的余味。大豆浓缩蛋白(SPC)和卡拉胶(CG)以不同的比例偶联,最佳比例为3:1,其乳化性能更好,糖基化程度更高,美拉德反应产物生成率更高。在油壁比为1:3的情况下,微胶囊的包封效率高达82.27%,同时具有良好的保色性和原位吸收,在原位肠道研究中类胡萝卜素吸收率为82%。在黑巧克力中添加RPO微胶囊对巧克力的质地、熔点、形态和感官属性没有影响。但对颜色和流变参数有显著影响(p < 0.05)。总体而言,使用SPC-CG共轭物作为壁材的RPO封装有效地掩盖了纳入巧克力产品时固有的棕榈味和油的气味,使小组成员无法检测到它们。这些发现支持了蛋白质-多糖偶联物作为功能食品中包封生物活性化合物的壁材的应用。
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引用次数: 0
Formulation and characterization of basil-flavoured oat-based milk substitute ice cream as a sustainable alternative to dairy ice cream 罗勒风味燕麦基牛奶替代冰淇淋的配方和特性,作为乳制品冰淇淋的可持续替代品
Pub Date : 2025-10-09 DOI: 10.1039/D5FB00232J
Deepika Shrestha, Alisha Pradhan, V. Sai Sharanya Palletti, R. B. Swethapriya and M. Srijaya

The growing demand for sustainable dairy alternatives has driven innovation in plant-based frozen desserts like oat-based milk substitutes (OMS). In this study, whole oat groats were processed into a plant-based milk substitute using the combined acid–enzyme hydrolysis technique, leveraging their low environmental impact and desirable techno-functional properties, including effective emulsifying and stabilizing capacities to develop basil-flavored oat-based milk substitute ice cream. Among the various formulations explored, OMS replacing dairy milk at 50% and 100% levels, in combination with 10% basil leaf extract, demonstrated superior acceptability and was used for the development of ice cream. The physicochemical, rheological, textural, nutritive, storage, organoleptic, and microbial parameters of the Basil-Flavoured Oat-based Milk Substitute (BF-OMS) ice creams were assessed and compared with full-cream dairy milk (FCDM) ice cream as the control. The experimental samples showed optimum pH and titrable acidity values, i.e., 6.91–6.94 and 0.25–0.27%, respectively. The resultant higher total carbohydrate (40.7–51.76%), total solids (48.70–55.95%), and total ash content (1.05–1.15%) in OMS ice creams led to an increased viscosity of the OMS ice-cream mix, ranging from 35.13 to 146 cP, improving their melting properties and structural integrity. BF-OMS ice creams exhibited pseudoplastic, non-Newtonian behaviour with higher viscosities than the control and a strong power law model fit (R2 = 0.998). The presence of β-glucans in the OMS might have contributed to enhanced gelling and water-binding capacities, resulting in desirable firmness and a smooth texture. The nutritional analysis showed that the partially substituted BF-OMS ice cream maintained the protein content (4.69%), comparable to the control (5.39%). Both 50% and 100% BF-OMS ice-creams had lower fat content (1.1–2.25%) compared to the control (4.1%). Additionally, OMS ice creams exhibited significantly higher total polyphenol content (45.44–46.68 mg GAE/100 g) and DPPH inhibition activity (89.85–92.81%) than the control. More importantly, an increment was observed in total polyphenols (26.34–58.05%) and DPPH inhibition activity (1.70%) in experimental samples at the end of 15 days of storage, indicating enhanced antioxidant potential during storage studies. Overall, the findings suggest that BF-OMS ice creams with dairy milk substitution can support a more sustainable industry transition with high consumer acceptance.

对可持续乳制品替代品的需求不断增长,推动了以植物为基础的冷冻甜点的创新,如燕麦牛奶替代品(OMS)。在本研究中,利用酸酶联合水解技术将全麦加工成植物基牛奶替代品,利用其低环境影响和理想的技术功能特性,包括有效的乳化和稳定能力,开发出罗勒风味燕麦基牛奶替代品冰淇淋。在探索的各种配方中,OMS在50%和100%的水平上替代牛奶,与10%罗勒叶提取物结合,显示出优越的可接受性,并用于冰淇淋的开发。对罗勒风味燕麦代乳(BF-OMS)冰淇淋的理化、流变、质构、营养、贮藏、感官和微生物等参数进行了评价,并与全脂乳(FCDM)冰淇淋作对照。实验样品的最佳pH值为6.91 ~ 6.94,可滴定酸度为0.25 ~ 0.27%。由此产生的OMS冰淇淋中较高的总碳水化合物(40.7-51.76%)、总固体(48.70-55.95%)和总灰分含量(1.05-1.15%)导致OMS冰淇淋混合物的粘度增加,范围从35.13到146 cP,改善了它们的熔化性能和结构完整性。BF-OMS冰淇淋表现出假塑性、非牛顿行为,粘度高于对照组,符合强幂律模型拟合(R2 = 0.998)。OMS中β-葡聚糖的存在可能有助于增强凝胶和水结合能力,从而产生理想的硬度和光滑的质地。营养分析表明,部分替代的BF-OMS冰淇淋保持了4.69%的蛋白质含量,与对照组的5.39%相当。50%和100% BF-OMS冰淇淋的脂肪含量(1.1-2.25%)均低于对照组(4.1%)。此外,OMS冰淇淋的总多酚含量(45.44 ~ 46.68 mg GAE/100 g)和DPPH抑制活性(89.85 ~ 92.81%)显著高于对照。更重要的是,贮藏15 d后,实验样品的总多酚含量(26.34 ~ 58.05%)和DPPH抑制活性(1.70%)均有所增加,表明贮藏过程中抗氧化能力增强。总体而言,研究结果表明,使用牛奶替代的BF-OMS冰淇淋可以支持更具可持续性的行业转型,并具有较高的消费者接受度。
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引用次数: 0
Deep learning-based approach for classifying mandarin orange maturity 基于深度学习的柑桔成熟度分类方法
Pub Date : 2025-10-08 DOI: 10.1039/D5FB00408J
Raj Singh, C. Nickhil, Konga Upendar, Poonam Mishra and Sankar Chandra Deka

The precise prediction of fruit maturity is essential for determining the optimal harvest time. It helps to reduce postharvest losses and maintain consistent fruit quality for consumers. Traditional methods for assessing maturity depend largely on manual inspection. This process is subjective, time-consuming, and prone to human error. Deep learning approaches, particularly convolutional neural networks (CNNs), offer a promising alternative by automating classification with high precision and consistency. This research seeks to identify the most effective deep-learning algorithms for predicting the maturity of mandarin oranges. In this study, the performance of four convolutional neural network architectures (EfficientNet-B0, ResNet50, VGG16, and a Custom CNN) was investigated for the classification of mandarin oranges based on their maturity levels: unripe, ripe, and overripe. The primary dataset comprised 1095 images, with each category containing 365 images. The deep learning models achieved the best accuracy rates of 98% for both EfficientNet-B0 and ResNet50, 83% for VGG16, and an impressive 99% for the Custom CNN, considering primary images. By comparing these models on a balanced dataset, this work offers a practical guide for researchers and practitioners on selecting models for assessing fruit maturity. Notably, EfficientNet-B0, ResNet50, and the Custom CNN exhibited significantly higher success rates compared to VGG16 and existing models, making them particularly recommendable for the development of an efficient automated system for harvesting and sorting mandarin oranges in the near future. The results aim to identify potential applications for improving agricultural practices, quality assessment, and overall efficiency in the food industry.

准确预测果实成熟度对确定最佳采收时间至关重要。它有助于减少采后损失,并为消费者保持一致的水果质量。评估成熟度的传统方法主要依赖于人工检查。这个过程是主观的、耗时的,而且容易出现人为错误。深度学习方法,特别是卷积神经网络(cnn),通过高精度和一致性的自动分类提供了一个很有前途的选择。本研究旨在确定预测柑桔成熟度的最有效的深度学习算法。在这项研究中,研究了四种卷积神经网络架构(EfficientNet-B0、ResNet50、VGG16和Custom CNN)对柑桔成熟度(未成熟、成熟和过熟)进行分类的性能。主数据集包含1095张图像,每个类别包含365张图像。考虑到原始图像,深度学习模型在EfficientNet-B0和ResNet50上的准确率都达到了98%,在VGG16上达到了83%,在Custom CNN上达到了令人印象深刻的99%。通过在平衡数据集上比较这些模型,本工作为研究人员和从业者选择评估水果成熟度的模型提供了实用指南。值得注意的是,与VGG16和现有模型相比,EfficientNet-B0、ResNet50和Custom CNN显示出明显更高的成功率,这使得它们在不久的将来特别值得推荐用于开发高效的柑橘收获和分类自动化系统。研究结果旨在确定在改善农业实践、质量评估和食品工业整体效率方面的潜在应用。
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引用次数: 0
Characterisation of water-soluble Nannochloropsis oceanica protein fractions: physical and functional properties 水溶性纳米海洋绿藻蛋白质组分的表征:物理和功能特性
Pub Date : 2025-10-08 DOI: 10.1039/D5FB00372E
Thi Phuong Linh Le, Jayani Samarathunga, Katrina Strazdins, Jeroen Rens and Benu Adhikari

This study presents a comprehensive physical and functional characterisation of water-soluble protein fractions extracted from defatted Nannochloropsis oceanica biomass, including electrostatic surface charge, water-absorption and oil-absorption capacities, foaming, emulsion formation and stability, and thermal behaviour, including denaturation and gelation, benchmarked against two widely used commercial proteins such as milk protein (MP) and soybean protein (SP). The water-soluble N. oceanica protein fractions (NP) showed comparable or superior surface charge density, water-absorption capacity, and oil-absorption capacity relative to MP and SP. NP achieved the highest emulsion activity index (131 m2 g−1), the greatest emulsion stability index (121 days), and the most negative zeta potential (−59.3 mV). It also produced the smallest emulsion droplet size among the tested proteins. Its denaturation temperature was 71 °C, indicating good thermal stability. NP formed heat-induced gels at 95 °C with a minimum concentration of 10% (w/w), although the resulting gels were not as firm as those formed by SP. These results indicate that NP possesses emulsifying, thermal, and gelling properties suitable for a range of food applications. Given its sustainable origin and multi-functional performance, NP holds promise as a novel protein ingredient in future foods.

本研究以两种广泛使用的商业蛋白质如牛奶蛋白(MP)和大豆蛋白(SP)为基准,对从脱脂海洋纳米叶绿素生物质中提取的水溶性蛋白质组分进行了全面的物理和功能表征,包括静电表面电荷、吸水和吸油能力、泡沫、乳液形成和稳定性,以及热行为,包括变性和凝胶化。水溶性海洋海棠蛋白组分(NP)的表面电荷密度、吸水能力和吸油能力与水溶性海洋海棠蛋白组分(NP)相当或优于水溶性海洋海棠蛋白组分(MP)和水溶性海洋海棠蛋白组分(SP)。NP的乳化活性指数最高(131 m2 g−1),乳化稳定性指数最高(121天),zeta电位最高(- 59.3 mV)。在测试的蛋白质中,它也产生了最小的乳剂液滴。其变性温度为71℃,热稳定性好。NP在95°C下形成热诱导凝胶,最低浓度为10% (w/w),尽管所得凝胶不如SP形成的凝胶牢固。这些结果表明NP具有乳化,热和胶凝性能,适用于一系列食品应用。鉴于其可持续来源和多功能性能,NP有望成为未来食品中的新型蛋白质成分。
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引用次数: 0
Co-encapsulation of vitamin D3 and curcumin in plant protein-based nanoemulsions: formulation optimization, characterization, and in vitro digestion 植物蛋白纳米乳中维生素D3和姜黄素的共包封:配方优化、表征和体外消化
Pub Date : 2025-10-08 DOI: 10.1039/D5FB00262A
Márcia Marques, Raquel F. S. Gonçalves, Daniel A. Madalena, Luís Abrunhosa, António A. Vicente and Ana C. Pinheiro

This study aimed to develop plant-based nanoemulsions (NE) for co-encapsulation of vitamin D3 and curcumin, comparing the emulsifying properties of pea and potato proteins. Different oil and protein concentrations were tested, and formulations with the smallest particle size were characterized and submitted to harmonized static in vitro digestion. Formulations prepared with the highest protein concentration (10%) and lowest oil concentration (1%) led to NE with smallest particle size and lowest polydispersity index (PDI). Curcumin and vitamin D3 were successfully co-encapsulated in both protein NE. During digestion, NE showed instability, particularly in the gastric phase, in which an increase in particle size was observed. Pea protein NE exhibited higher curcumin bioaccessibility (76.06 ± 12.05%) than potato protein NE (42.88 ± 3.58%), while the bioaccessibility of vitamin D3 did not show significant differences. Curcumin stability was also higher in pea protein NE (21.44 ± 1.97%) compared to potato protein NE (12.38 ± 1.97%). These results showed that pea protein is more suitable for produced plant-based NE for co-encapsulation of these bioactive compounds. This work contributes to the development of plant-based NE as promising carriers for the co-encapsulation of bioactive compounds, envisaging the fortification of food products, especially plant-based foods, in response to the growing demand for sustainable alternatives.

本研究旨在开发植物基纳米乳(NE),用于维生素D3和姜黄素的共包封,并比较豌豆和马铃薯蛋白的乳化特性。测试了不同的油和蛋白质浓度,并对最小粒径的配方进行了表征,并提交了协调静态体外消化。以最高蛋白质浓度(10%)和最低油浓度(1%)配制的配方得到的NE粒径最小,PDI最低。姜黄素和维生素D3成功地包被在蛋白NE中。在消化过程中,NE表现出不稳定性,特别是在胃期,观察到颗粒大小增加。豌豆蛋白NE对姜黄素的生物可及性(76.06±12.05%)高于马铃薯蛋白NE(42.88±3.58%),而维生素D3的生物可及性差异不显著。豌豆蛋白NE的姜黄素稳定性(21.44±1.97%)高于马铃薯蛋白NE(12.38±1.97%)。这些结果表明,豌豆蛋白更适合用于生产基于植物的NE来共包封这些生物活性化合物。这项工作有助于以植物为基础的NE作为生物活性化合物共包封的有前途的载体的发展,设想强化食品,特别是植物性食品,以响应对可持续替代品日益增长的需求。
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引用次数: 0
Sustainable valorization of fish byproducts and acid whey through lactic acid bacteria fermentation into bioactive hydrolysates 鱼类副产品和酸乳清通过乳酸菌发酵成生物活性水解物的可持续增值
Pub Date : 2025-10-08 DOI: 10.1039/D5FB00444F
Chih-Chun Kuo, Da Chen, Rafael Jiménez-Flores, Macdonald Wick and Osvaldo Campanella

The growing accumulation of food byproducts and waste imposes environmental and economic challenges, highlighting the need for sustainable valorization strategies. This study investigated the usage of fish byproducts and acid whey through lactic acid bacteria (LAB) fermentation to produce bioactive fish protein hydrolysates (FPHs) with potential antioxidant and antibacterial properties. The effects of three formulations: acid whey (FAw), a starter culture (FLr), and their combination (FAwLr) on the fermentation and its products were systematically evaluated. LAB fermentation triggered protein hydrolysis, as demonstrated by the increased degrees of hydrolysis (DH). The fermentation process was also marked by significant microbial growth using FAwLr, with LAB populations above 108 CFU mL−1 by Day 3, accompanied by a rapid pH decline (<4.5). Viscosity of the fermented samples decreased in all formulations, showing smaller consistency indexes and larger flow behavior indexes, indicating enhanced protein hydrolysis and a reduced structural complexity of the system over time. Antioxidant activity, measured by DPPH (2,2-diphenyl-1-picrylhydrazyl), ABTS 2,2′-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid), and FRAP (Ferric Reducing Antioxidant Power) assays, was significantly improved in all formulations containing acid whey. The antibacterial activity against Listeria innocua and Escherichia coli showed formulation-dependent effects. The combination of acid whey and LAB (FAwLr) exhibited the strongest antibacterial properties, lowering both the minimum inhibitory and bactericidal concentrations. These results highlight the synergistic effects of acid whey and LAB in producing multifunctional bioactive hydrolysates with both antioxidant and antibacterial activities, showcasing a sustainable approach to converting waste streams into value-added ingredients.

粮食副产品和废物的日益积累带来了环境和经济挑战,突出了可持续增值战略的必要性。本研究研究了利用鱼类副产品和酸性乳清通过乳酸菌(LAB)发酵生产具有潜在抗氧化和抗菌性能的生物活性鱼蛋白水解物(FPHs)。系统评价了酸乳清(FAw)、发酵剂(FLr)及其组合(FAwLr) 3种配方对发酵及其产物的影响。从水解度(DH)的增加可以看出,乳酸发酵引发了蛋白质水解。发酵过程中也有显著的微生物生长,到第3天,LAB数量超过108 CFU mL - 1,伴随着pH值的快速下降(<4.5)。在所有配方中,发酵后的样品粘度都有所下降,稠度指数变小,流动行为指数增大,表明随着时间的推移,蛋白质水解增强,体系结构复杂性降低。通过DPPH(2,2-二苯基-1-吡啶肼)、ABTS 2,2 ' -氮化氮-(3-乙基苯并噻唑-6-磺酸)和FRAP(铁还原抗氧化能力)测定,所有含有酸性乳清的配方的抗氧化活性都显著提高。对李斯特菌和大肠杆菌的抑菌活性呈配方依赖性。酸性乳清与乳酸菌(falr)的组合具有最强的抗菌性能,降低了最低抑菌浓度和杀菌浓度。这些结果强调了酸乳清和乳酸菌在生产具有抗氧化和抗菌活性的多功能生物活性水解物方面的协同作用,展示了将废物流转化为增值成分的可持续方法。
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引用次数: 0
Sustainable development of dairy-based functional beverages enriched with bee pollen: a circular economy approach 含蜂花粉的乳制品功能性饮料的可持续发展:循环经济途径
Pub Date : 2025-10-03 DOI: 10.1039/D5FB00337G
Eliara Acipreste Hudson, Herlândia Cotrim Santos, Laís Fernanda Batista, Jaqueline de Paula Rezende, Kely de Paula Correa, Izabela Maria Montezano de Carvalho, Márcia Cristina Teixeira Ribeiro Vidigal and Ana Clarissa dos Santos Pires

The growing demand for sustainable and functional foods has driven the development of novel formulations that both valorize dairy co-products and incorporate functional ingredients. Six fermented dairy beverages were developed by partially replacing skim milk (0–75%, w/w) with buttermilk and/or sweet cheese whey. The formulations were enriched with 1% bee pollen, banana, and honey, fermented using a commercial yogurt culture, and stored at 4 °C. We evaluated the proximate composition, pH and titratable acidity, water-holding capacity (WHC) and syneresis, antioxidant activity, colloidal stability (Turbiscan Stability Index – TSI), rheological behavior, texture, and sensory properties. All formulations exhibited similar acidification profile during storage (pH change from 4.45 to 4.15 and acidity from 0.82 to 0.92% lactic acid over 30 days), indicating unaltered lactose fermentation despite milk replacement. Formulations containing 37.5% of buttermilk or whey achieved higher WHC (>60%) and lower syneresis (∼9–10%), correlating with low TSI values (<0.9) and pseudoplastic rheology. Textural analyses showed that the same formulations achieved a balance between gel strength and cohesiveness, without compromising adhesiveness or elasticity. Antioxidant assays revealed that 75% buttermilk samples exhibited the greatest radical-scavenging activity (DPPH: 72.5 ± 2.1%; ABTS: 63.8 ± 1.9%), underscoring the influence of polar lipids on functionality. Sensory tests pointed to the high acceptance of moderate-replacement samples, linked to creamy, sweet, yogurt-like attributes, whereas 75% whey samples scored lower due to bitterness. Overall, moderate substitution with buttermilk or whey, combined with bee pollen enrichment, produces stable, antioxidant-rich, and consumer-acceptable beverages, supporting functional food development and the circular economy in the dairy sector.

对可持续和功能性食品日益增长的需求推动了新型配方的发展,这些配方既能使乳制品副产品增值,又能纳入功能性成分。用脱脂牛奶和/或甜奶酪乳清部分替代脱脂牛奶(0-75%,w/w),开发了6种发酵乳制品饮料。配方中添加1%的蜂花粉、香蕉和蜂蜜,使用商业酸奶培养物发酵,并在4°C保存。我们评估了其近似组成、pH值和可滴定酸度、保水能力(WHC)和协同作用、抗氧化活性、胶体稳定性(Turbiscan stability Index - TSI)、流变行为、质地和感官特性。所有配方在储存过程中都表现出相似的酸化特征(30天内pH值从4.45变化到4.15,酸度从0.82变化到0.92%),表明尽管更换了牛奶,乳糖发酵没有改变。含有37.5%酪乳或乳清的配方获得了更高的WHC (>60%)和更低的协同作用(~ 9-10%),与低TSI值(<0.9)和假塑性流变学相关。结构分析表明,相同的配方实现了凝胶强度和黏性之间的平衡,而不影响黏性或弹性。抗氧化实验显示,75%的酪乳样品具有最强的自由基清除活性(DPPH: 72.5±2.1%;ABTS: 63.8±1.9%),强调极性脂质对功能的影响。感官测试表明,与奶油、甜味、酸奶类似的特性有关的中度替代样品的接受度很高,而75%的乳清样品由于苦味而得分较低。总的来说,适度替代酪乳或乳清,结合蜂花粉浓缩,生产出稳定、富含抗氧化剂和消费者可接受的饮料,支持功能食品的发展和乳制品行业的循环经济。
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引用次数: 0
Investigation of polymer blend formulation and homogenization dynamics in the development of biodegradable, hydrophobic, and heat-resistant seaweed-based bioplastic straws 可生物降解、疏水和耐热海藻基生物塑料吸管的聚合物共混配方和均质动力学研究
Pub Date : 2025-10-03 DOI: 10.1039/D5FB00344J
Wahyu Ramadhan, Joko Santoso, Uju, Rahadiyan Garuda Langit Dewangga, Mario Natanael, Muhammad Aldy Luthfiansyah, Adinda Yulya Rachmawati and Zacky Arivaie Santosa

The demand for biodegradable straws has grown in response to environmental concerns regarding plastic waste. This study aimed to develop and optimize seaweed-based bioplastic straws with enhanced hydrophobicity, mechanical integrity, and biodegradability. Four base formulations combining agar, starch, carrageenan, and konjac were evaluated, with the B9 formulation (comprising agar and starch) selected as the most promising due to its superior thermal stability and low water absorption. This formulation was then used in a process optimization stage, where various homogenization parameters (speed, temperature, and time) were tested. The best-performing straw from this stage, referred to as low-speed-S-B9 (B9 processed under low-speed homogenization), demonstrated the most favorable overall performance, achieving a contact angle of 115.31 ± 1.15°, water absorption below 100.27 ± 2.67%, and tensile strength of 60.76 ± 2.78 MPa. SEM analysis revealed a dense and cohesive matrix structure, while FTIR spectra showed the main polysaccharide functional groups in all samples, with additional peaks reflecting each formulation's chemical composition. Thermal degradation profiles confirmed its heat resistance, with delayed onset and higher char residue. Mechanical and flexural tests showed the low-speed straw maintained high elongation and comparable bending resistance to commercial paper straws. Finally, soil burial testing confirmed full biodegradation of the straw within 60 days. These results confirm that low-speed homogenization of seaweed-based formulations offers a scalable and sustainable strategy to produce biodegradable straws with functional properties suitable for real-world use.

由于对塑料垃圾的环境担忧,对可生物降解吸管的需求有所增长。本研究旨在开发和优化具有增强疏水性、机械完整性和生物降解性的海藻基生物塑料吸管。对琼脂、淀粉、卡拉胶和魔芋的四种基质配方进行了评价,其中B9配方(由琼脂和淀粉组成)因其优越的热稳定性和低吸水性而被选为最有前途的配方。然后将该配方用于工艺优化阶段,其中测试了各种均质参数(速度,温度和时间)。低速s -B9(低速均质处理的B9)是本阶段表现最好的秸秆,其整体性能最优,接触角为115.31±1.15°,吸水率低于100.27±2.67%,抗拉强度为60.76±2.78 MPa。扫描电镜(SEM)分析显示基质结构致密,具有内聚性,红外光谱(FTIR)显示了所有样品中主要的多糖官能团,另外的峰反映了每种配方的化学成分。热降解曲线证实了其耐热性,具有延迟发作和较高的焦渣。力学和弯曲试验表明,低速吸管保持较高的伸长率和相当的抗弯性能,以商业纸吸管。最后,土壤掩埋试验证实秸秆在60天内完全生物降解。这些结果证实,海藻基配方的低速均质化为生产具有适合实际使用的功能特性的可生物降解吸管提供了一种可扩展和可持续的策略。
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引用次数: 0
Valorization of legume by-products in functional formulations: phytochemicals and their simulated gastrointestinal fate 功能性配方中豆科副产物的增值:植物化学物质及其模拟胃肠道命运
Pub Date : 2025-10-02 DOI: 10.1039/D5FB00273G
Gulay Ozkan, Mustafa Tahsin Yilmaz, Elwira Sieniawska, Benita Hryć, Mehmet Çağlar Tülbek and Esra Capanoglu

The high bioactive content of legume by-products enables their utilization in the development of value-added food products. Thus, this study explores the valorization of legume by-products (chickpea hulls (CH), faba bean hulls (FH), and lentil hulls (LH)) through the formulation of novel functional infusions. The effects of in vitro digestion on the phenolic content and antioxidant potential of these infusions were assessed. Aqueous-methanolic (75%) and aqueous extracts of these samples were also evaluated in terms of total phenolic content (TPC), total flavonoid content (TFC), and antioxidant capacity. According to the results, FH and LH showed higher TPC (1002 and 1320 mg GAE/100 g, respectively) and TFC (961 and 986 mg CE/100 g, respectively) values (p < 0.05). Similarly, among the infusions (CHI, FHI, and LHI), which were all prepared from their respective samples, the FHI and LHI exhibited higher levels of TPC, TFC, and antioxidant capacity before and after in vitro digestion (p < 0.05). Additionally, comprehensive LC-ESI-MS/MS phenolic profiling showed the great potential for the retention of individual phenolics in newly formulated infusions. These results suggest that legume by-products have great potential for value-added applications as functional ingredients in infusion formulations, contributing to their sustainable utilization and offering health-promoting properties.

豆类副产品的高生物活性含量使其能够用于开发增值食品。因此,本研究探讨了豆类副产物(鹰嘴豆壳(CH),蚕豆壳(FH)和扁豆壳(LH))的价值通过新型功能注射剂的配方。考察体外消化对其酚类物质含量和抗氧化能力的影响。研究了水甲醇(75%)和水提取物的总酚含量(TPC)、总黄酮含量(TFC)和抗氧化能力。结果表明,FH和LH具有较高的TPC值(分别为1002和1320 mg GAE/100 g)和TFC值(分别为961和986 mg CE/100 g) (p < 0.05)。同样,从各自的样品中制备的输注(CHI、FHI和LHI)中,FHI和LHI在体外消化前后表现出更高的TPC、TFC水平和抗氧化能力(p < 0.05)。此外,全面的LC-ESI-MS/MS酚类分析显示,在新配制的输液中,单个酚类物质的保留具有很大的潜力。这些结果表明,豆类副产物作为功能成分在输液制剂中具有很大的增值应用潜力,有助于其可持续利用并具有促进健康的特性。
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引用次数: 0
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Sustainable Food Technology
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