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Sensitivity and application of pseudo-steady-state constant for refracturing horizontal wells with fracture reorientation in anisotropic tight oil reservoirs 各向异性致密油裂缝定向重复压裂水平井拟稳态常数敏感性及应用
Pub Date : 2023-01-01 DOI: 10.1016/j.uncres.2023.01.005
Ruoyu Li , Mingxian Wang , Ruifei Wang , Ying Tang

Fetkovich or Blasingame type rate decline analysis is a common and practical method to obtain reservoir parameters and evaluate well productivity. Pseudo-steady-state constant is an indispensable parameter for establishing these new type rate decline curves and works as a bridge linking conventional productivity and new type productivity. Refracturing is widely used to enhance tight oil wells’ productivity and improve their economic benefits, the pseudo-steady-state constant of refracturing horizontal wells has been presented in our previous research, but an in-depth discussion on the definition, accuracy, sensitivity, and application of this constant has not been conducted. It results in the insufficient understanding of the physical meaning, characteristics, and functions of pseudo-steady-state constant at present. In this study, taking the derived pseudo-steady-state constant for refracturing horizontal wells with fracture reorientation as an example, its accuracy was verified by an equivalent model presented in the literature, and the sensitivity of relevant key parameters on this constant was investigated. For the refracturing horizontal well defined in this study, pseudo-steady-state constant is independent of time, and related to fracture conductivity, fracture face damage, reorientation fracture number and permeability anisotropy. Results show that this constant decreases with the increase of fracture conductivity, but tends to remain unchanged when fracture conductivity increases to a certain extent. Meanwhile, this constant shows a positive correlation with fracture face damage and permeability anisotropy, but an inverse correlation with reorientation fracture number. Blasingame type rate decline curves of refracturing horizontal wells with fracture reorientation were also established, regarding as a practical application of this pseudo-steady-state constant and a concrete manifestation of its bridge-linking function. These type curves are directly conducive to the inversion of reservoir properties and fracturing parameters and the prediction of future productivity for refracturing horizontal wells. More importantly, this study is helpful to understand and strengthen the role and importance of pseudo-steady-state constant, and also beneficial to the establishment of new type rate decline curves of other similar models.

Fetkovich或Blasingame型递减率分析是获得储层参数和评价井产能的一种常用而实用的方法。拟稳态常数是建立这些新型生产率下降曲线的一个不可或缺的参数,是连接传统生产率和新型生产率的桥梁。重复压裂被广泛用于提高致密油井的产能和提高其经济效益,我们以前的研究中已经提出了重复压裂水平井的拟稳态常数,但尚未对该常数的定义、精度、灵敏度和应用进行深入讨论。这导致目前人们对伪稳态常数的物理意义、特性和函数认识不足。本研究以导出的具有裂缝重新定向的折射水平井拟稳态常数为例,通过文献中提出的等效模型验证了其准确性,并研究了相关关键参数对该常数的敏感性。对于本研究中定义的折射水平井,伪稳态常数与时间无关,与裂缝电导率、裂缝面损伤、重定向裂缝数和渗透率各向异性有关。结果表明,该常数随裂缝电导率的增加而减小,但当裂缝电导率增加到一定程度时,该常数趋于不变。同时,该常数与裂缝面损伤和渗透率各向异性呈正相关,但与重定向裂缝数呈负相关。针对这种拟稳态常数的实际应用及其桥接作用的具体体现,建立了具有裂缝重新定向的折射水平井的Blasingame型速率递减曲线。这些类型曲线直接有利于折射水平井储层性质和压裂参数的反演以及未来产能的预测。更重要的是,本研究有助于理解和加强伪稳态常数的作用和重要性,也有利于建立其他类似模型的新型速率下降曲线。
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引用次数: 2
Study on dynamic and static elastic moduli of shale oil by different loading methods 不同加载方式下页岩油动、静态弹性模量研究
Pub Date : 2023-01-01 DOI: 10.1016/j.uncres.2023.03.002
Huiyuan Bian , Fei Wang , Wenan Chen , Haiwen Wang

Experiments on the dynamic and static elastic parameters under distinct loading conditions help clarify the effects of loading rate and strain amplitude on dynamic and static elastic moduli, and gain further insight into the moduli. Significant scientific guidance are provided for fracturing transformation of oil shale reservoirs. AutoLab 1500, servo-controlled triaxial equipment with ultrasonic transducers, is used in an elastic parameter test on shale oil samples. The test concludes that the loading rate moves the dynamic elastic modulus little, with a maximum change rate of 0.8%, while it significantly affects the static elastic modulus by 31.7% at most. In the loading or unloading phase, the larger the initial differential stress (or strain), the higher the dynamic Young's modulus. The static elastic modulus, on the other hand, presents a significant negative correlation with the stress amplitude. To be specific, the smaller the strain amplitude, the higher the measured modulus; the larger the strain amplitude, the smaller the modulus. Given the loading rate, the smaller the differential stress, the smaller the difference between the dynamic and static elastic moduli. This study can provide a reference base for fracturing construction in oil shale.

不同加载条件下的动静态弹性参数实验有助于阐明加载速率和应变幅度对动静态弹性模量的影响,并进一步了解模量。为油页岩油藏的压裂改造提供了重要的科学指导。AutoLab1500是一种带超声波换能器的伺服控制三轴设备,用于页岩油样品的弹性参数测试。试验结果表明,加载速率对动弹性模量的影响较小,最大变化率为0.8%,而对静弹性模量的最大影响为31.7%。在加载或卸载阶段,初始微分应力(或应变)越大,动态杨氏模量就越高。另一方面,静态弹性模量与应力振幅呈显著负相关。具体地说,应变幅度越小,测得的模量就越高;应变幅度越大,模量越小。给定加载速率,差异应力越小,动态和静态弹性模量之间的差异就越小。本研究可为油页岩压裂施工提供参考依据。
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引用次数: 1
Characteristics of water occurrence in coalbed methane reservoir 煤层气储层水赋存特征
Pub Date : 2023-01-01 DOI: 10.1016/j.uncres.2022.11.003
Xiaoxiao Sun , Junjie Yi , Jing Li

The presence of water, competing with methane for the space, weakens the ability of methane adsorption and diffusion in coal dramatically. The study on the occurrence of water in coal has direct effects on coalbed methane exploitation. In this study, NMR technology was used to obtain water vapor adsorption curves, moreover, the surface adsorption, water cluster formation and pore filling of water in coal pores of coal samples were characterized. Meanwhile, the method based on NMR was first used to quantify the water in different occurrence state in coal pores. The results show that modified BET model can not fit the data in all the pressure history of high rank coal with well-developed micropores and mesopores. Moreover, for pores in high-rank anthracite coal, adsorption water is mainly the indirect adsorption water, and for pores of low-rank bituminous coal, the proportion of direct adsorption water is 50%.

水的存在,与甲烷争夺空间,极大地削弱了甲烷在煤中的吸附和扩散能力。研究煤中水分的赋存状态,对煤层气的开采有着直接的影响。本研究利用核磁共振技术获得了水蒸气吸附曲线,并对煤样品的表面吸附、水团簇的形成和水在煤孔隙中的填充进行了表征。同时,首次采用核磁共振方法对煤孔隙中不同赋存状态的水进行了定量。结果表明,改进的BET模型不能拟合微孔和中孔发育的高阶煤的所有压力历史数据。此外,对于高阶无烟煤的孔隙,吸附水主要是间接吸附水,而对于低阶烟煤的孔隙,直接吸附水的比例为50%。
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引用次数: 1
Fluid mobility calculation based on improved window parameters optimized S-transform for reservoir delineation 基于改进窗口参数优化s变换的储层圈定流体流度计算
Pub Date : 2023-01-01 DOI: 10.1016/j.uncres.2023.02.001
Junjie Liu , Chenfei Zhao , Haojie Wu , Fuai Zhang , Nan Yan

Time-frequency analysis is an important tool for seismic signal analysis and time-frequency resolution is the key to high-precision reservoir prediction. The time-frequency method of conventional S-transform is difficult to meet the requirements of high precision reservoir prediction at present. In this paper, an improved window-parameter optimization S-transform (IWPOST) method is proposed. In the IWPOST method, the scale parameters of the window function can be adaptively obtained according to the amplitude spectrum of the actual signal, and a new optimization adjustment parameter is introduced to further improve the window parameters. The comparison analysis of the synthetic signals shows that the IWPOST method has better time-frequency aggregation and can maintain high resolution at both high-frequency and low-frequency. Finally, the proposed method is used to extract the reservoir fluid mobility attribute from the real seismic data and the results indicate that the fluid mobility has a higher time resolution and exhibits better performance for reservoir delineation. The proposed method is conducive to delineate the reservoir range and provides reference for the exploration and development of the oil and gas reservoirs in this area.

时频分析是地震信号分析的重要工具,时频分辨率是高精度储层预测的关键。传统的S变换时频方法难以满足目前高精度储层预测的要求。本文提出了一种改进的窗口参数优化S变换(IWPOST)方法。在IWPOST方法中,可以根据实际信号的幅度谱自适应地获得窗口函数的尺度参数,并引入新的优化调整参数来进一步改进窗口参数。对合成信号的比较分析表明,IWPOST方法具有更好的时频聚合性能,在高频和低频下都能保持较高的分辨率。最后,将所提出的方法用于从真实地震数据中提取储层流体流动性属性,结果表明,流体流动性具有更高的时间分辨率,在储层圈定方面表现出更好的性能。该方法有利于圈定储层范围,为该区油气藏勘探开发提供参考。
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引用次数: 0
Geological characteristics and resources potential of shale oil in Chang 7 Member of Upper Triassic Yanchang Formation in Fuxian area, southern Ordos Basin, western China 鄂尔多斯盆地南部抚仙地区上三叠统延长组长7段页岩油地质特征及资源潜力
Pub Date : 2023-01-01 DOI: 10.1016/j.uncres.2023.06.001
Ruyue Wang , Guanping Wang , Gang Zhao , Menhui Qian , Yuejiao Liu , Weiling He , Zhihao Li

Ordos Basin is rich in shale oil resources. Fuxian area in the southern Ordos Basin is an important area where Sinopec is expected to make a breakthrough in the exploration and development of lacustrine shale oil. To further identify the exploration target of shale oil in Chang 7 Member of Fuxian area, Ordos Basin, this study systematically analyzed the sedimentary characteristics, source rock characteristics, reservoir characteristics, oil-bearing characteristics, fracability and preservation conditions of Chang 7 Member in this area. The results show that: (1) the organic matter abundance of shale in the Chang 7 Member is high, and its type is dominated by type I-II1; the maturity is also relatively high, with Ro generally greater than 0.8% in the central and western parts, which is favorable for the generation and accumulation of shale oil. The development of fractures is pretty low, and thus the structure preservation conditions are relatively favorable. Delta front deposits are mainly developed in the northeastern part, while deep lake - semi-deep lake mudstone and gravity-flow deposits are developed in the western part, and the shale oil types are mainly type II and III. (2) Comparing with the western Ordos Basin, the reservoir in Fuxian area has rapid lateral variation and relatively thin cumulative thickness; the thickness of high-quality shale and maturity are low, resulting in low intensity of hydrocarbon generation and low mobility of oil-bearing saturation. Therefore, there is still a need for further improvement and refinement in the exploration evaluation, effective development and engineering techniques. (3) Integrating sedimentary characteristics with shale oil types, source conditions, oil-bearing properties, mobility, fracability and preservation conditions, it is clarified that the Type II shale oil of Chang 72 sub-,Member in Fuxian area is the current realistic exploration type of shale oil, and its favorable target is located in the development area of delta front in the central part and gravity flow in the western part.

鄂尔多斯盆地页岩油资源丰富。鄂尔多斯盆地南部富县地区是中国石化在湖相页岩油勘探开发方面有望取得突破的重要地区。为进一步确定鄂尔多斯盆地富县地区长7段页岩油勘探目标,本研究系统分析了该区长7段的沉积特征、烃源岩特征、储层特征、含油特征、可压裂性和保存条件。结果表明:(1)长7段页岩有机质丰度较高,类型以Ⅰ-Ⅱ1型为主;成熟度也相对较高,中西部Ro普遍大于0.8%,有利于页岩油的生成和聚集。裂缝发育程度较低,结构保存条件相对有利。东北部主要发育三角洲前缘沉积,西部发育深湖-半深湖泥岩和重力流沉积,页岩油类型主要为Ⅱ型和Ⅲ型。(2)与鄂尔多斯盆地西部相比,富县地区储层横向变化快,累积厚度相对较薄;优质页岩的厚度和成熟度较低,导致生烃强度低,含油饱和度流动性低。因此,在勘探评价、有效开发和工程技术方面仍需进一步改进和完善。(3) 将沉积特征与页岩油类型、来源条件、含油性质、流动性、可压裂性和保存条件相结合,阐明富县地区长72亚段II型页岩油是目前较为现实的页岩油勘探类型,其有利靶区位于中部三角洲前缘和西部重力流发育区。
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引用次数: 0
Facies, textural and geochemical evaluation of the post-Santonian sandstones in the Bida basin, Nigeria: Implications for control on hydrocarbon sandstone reservoir characteristics and paleoenvironments 尼日利亚Bida盆地后三东期砂岩相、结构和地球化学评价:对油气砂岩储层特征和古环境的控制意义
Pub Date : 2023-01-01 DOI: 10.1016/j.uncres.2023.03.004
Godwin Okumagbe Aigbadon , Obinna Chigoziem Akakuru , Ernest Orji Akudo , Samuel Okechukwu Onyekuru , Kizito Ojochenemi Musa , Ikenna Arisi Obasi , Azuka Ocheli , Zulaihat Jummai Sanni , Jamilu Bala Ahmed II , Mu’ awiya Baba Aminu , Robert Lamja , Ogaga Esharive

Using a combination of field observations, textural analysis, scanning electron microscopy (SEM), mineralogical X-ray diffraction (XRD), X-ray fluorescence spectroscopy (XRF), and thin-section analysis, the hydrocarbon and paleoenvironmental characteristics of the Cretaceous sandstones of the southern Bida Basin, Nigeria, were evaluated. SEM data were used to display the mineral morphology, degree of cementation and presence of clay minerals on the grain surfaces and their pores on both sandstones of the Patti and Lokoja formations. The lithofacies analyses revealed three distinct facies associations. The XRD data showed that for the Lokoja and Patti sandstone reservoirs contained quartz from 49 to 67% and 43–68%, respectively. The XRF data also showed that both formations' sandstone reservoirs have a high percentage of silicon and low aluminum content. The grain size study showed that the Lokoja sandstone reservoirs include medium-coarse sandstone (−0.63 to 1.30 ф) that are poorly-moderately sorted (0.72–1.82 ф). In contrast, the Patti Formation is primarily made up of fine-medium sandstones at investigated outcrops, which typically display reasonably good to poor sorting (0.70–2.53 ф). The skewness of the sandstone reservoirs ranged from fine to coarse, and their kurtosis ranged from very platykurtic to leptokurtic. The research area's predominant depositional environments include shoreface/foreshore, estuary mudflat, and estuarine delta with fluvial interference, according to an analysis that combined sedimentary facies and textural data. This demonstrates that the sandstones from the two units have moderate quality prospective hydrocarbon reservoirs based on their physical and chemical characteristics.

采用野外观测、结构分析、扫描电子显微镜(SEM)、矿物学X射线衍射(XRD)、X射线荧光光谱(XRF)和薄片分析相结合的方法,对尼日利亚比达盆地南部白垩纪砂岩的油气和古环境特征进行了评价。SEM数据用于显示帕蒂组和洛科贾组砂岩的矿物形态、胶结程度以及颗粒表面及其孔隙上粘土矿物的存在。岩相分析揭示了三种不同的岩相组合。XRD数据显示,Lokoja和Patti砂岩储层的石英含量分别为49%至67%和43%至68%。XRF数据还表明,这两个地层的砂岩储层都具有高百分比的硅和低铝含量。粒度研究表明,Lokoja砂岩储层包括中粗砂岩(−0.63至1.30ф),其分选较差-中等(0.72至1.82ф)。相比之下,帕蒂组主要由调查露头处的细中砂岩组成,这些砂岩通常表现出相当好到较差的分选(0.70–2.53ф)。砂岩储层的倾斜度从细到粗不等,峰度从极平峰度到细峰度不等。根据结合沉积相和结构数据的分析,研究区的主要沉积环境包括海岸面/前滨、河口滩涂和受河流干扰的河口三角洲。这表明,根据其物理和化学特征,这两个单元的砂岩具有中等质量的潜在油气藏。
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引用次数: 3
Brittleness assessment of the shale oil reservoir based on neural network method: A case study of the Yanchang Formation, Ordos Basin 基于神经网络方法的页岩油储层脆性评价——以鄂尔多斯盆地延长组为例
Pub Date : 2023-01-01 DOI: 10.1016/j.uncres.2022.12.003
Wei Ju , Yan Liang , Shengbin Feng , Honggang Xin , Yuan You , Weike Ning , Guodong Yu

The Chang 7 oil-bearing layer of Yanchang Formation is rich in shale oil resources. However, the reservoir indicates strong reservoir heterogeneity and has obvious differences in productivity among wells. The brittleness acts as an important factor causing the above phenomenon. Studies on rock mechanical properties and brittleness evaluation can provide technical support for drilling and fracturing design, but current methods have many disadvantages such as difficulty in obtaining parameters. In this study, the neural network method is used to construct the relationship between elastic modulus, Poisson's ratio and logging curve on the basis of measured rock mechanical parameters, construct rock mechanics parameter profile in the whole well section of Chang 7 oil-bearing layer, and finally quantitative evaluate shale oil reservoir brittleness. The results indicate that, (1) the neural network method is an effective method for rock mechanical parameter prediction and brittleness evaluation. The error between the predicted and measured values of elastic modulus and Poisson's ratio is low, generally within 10%; (2) according to the brittleness evaluation results, on the whole, the brittleness index of the Chang 72 reservoir is high, and the brittleness index of the Chang 73 reservoir is low. The results can provide scientific guidance for benefit development of Chang 7 shale oil in the Ordos Basin.

延长组长7油层页岩油资源丰富。但储层非均质性强,井间产能差异明显。脆性是导致上述现象的一个重要因素。岩石力学性能和脆性评价的研究可以为钻井和压裂设计提供技术支持,但目前的方法存在参数难以获取等缺点。本研究采用神经网络方法,在实测岩石力学参数的基础上,构建弹性模量、泊松比与测井曲线的关系,构建长7油层全井段岩石力学参数剖面,最终定量评价页岩油藏脆性。结果表明:(1)神经网络方法是一种有效的岩石力学参数预测和脆性评价方法。弹性模量和泊松比的预测值与实测值之间的误差较低,一般在10%以内;(2) 根据脆性评价结果,长72油藏总体上脆性指数较高,长73油藏脆性指数较低。研究结果可为鄂尔多斯盆地长7页岩油的效益开发提供科学指导。
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引用次数: 2
Study on calculation of transversely isotropic dynamic rock mechanical parameters and conversion model between dynamic parameters and static parameters 横向各向同性岩石动态力学参数计算及动、静参数转换模型研究
Pub Date : 2023-01-01 DOI: 10.1016/j.uncres.2023.07.002
Zichao Ma , Nailing Xiu , Haifeng Fu , Bing Hou , Dong Chen , Changming Hou

The shale oil reservoirs in the Jimsar Sag are strongly heterogeneous. Therefore, it is of practical significance to relate the dynamic elastic stiffness to the static elastic stiffness under the assumption of transverse isotropy. The acquisition of stiffness parameters depends on lab measurements or Sonic Scanner logging. Aiming at the problem that the lab measurements results are limited and discontinuous, the acquisition of special logging data is difficult in the well site, a method using only the conventional well-log data to predict the dynamic elastic stiffnesses of shale is proposed. Inspired by ultrasonic experimental test method, the study simplified the types of tested waves and complemented missing datas. According to the experimental proof, we concluded that: (1) Under the assumption of transverse isotropy, using simplified Thmosen model and velocity conversion relationship can accurately calculate the P-wave and S-wave velocities in the 45° angle direction. (2) Compared with the conventional isotropic algorithm, specify this algorithm can better reflect real mechanical conditions of the formation, and better characterize the variation of mechanical parameters with depth. (3) Effective conversion models between dynamic elastic modulus and static elastic modulus in vertical and horizontal directions were obtained in some areas of Jimsar.

吉木萨尔凹陷页岩油气藏具有强烈的非均质性。因此,在横向各向同性假设下,将动弹性刚度与静弹性刚度联系起来具有实际意义。刚度参数的获取取决于实验室测量或声波扫描仪测井。针对实验室测量结果有限、不连续、井场特殊测井数据采集困难的问题,提出了一种仅利用常规测井数据预测页岩动弹性刚度的方法。受超声波实验测试方法的启发,该研究简化了测试波形的类型,并补充了缺失的数据。根据实验证明,我们得出结论:(1)在横向各向同性假设下,使用简化的Thmosen模型和速度转换关系,可以准确地计算45°角方向上的P波和S波速度。(2) 与传统的各向同性算法相比,指定该算法可以更好地反映地层的真实力学条件,更好地表征力学参数随深度的变化。(3) 在吉木萨尔的一些地区,得到了动弹性模量与静弹性模量在垂直和水平方向上的有效转换模型。
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引用次数: 0
Source rock and reservoir qualities of middle Jurassic Lianggaoshan lacustrine shale at fuxing area, Sichuan Basin: Implication for shale-oil enrichment 四川盆地复兴地区中侏罗统凉高山湖相页岩烃源岩与储层物性:页岩油富集意义
Pub Date : 2023-01-01 DOI: 10.1016/j.uncres.2022.11.002
Pengwei Wang , Zhongbao Liu , Dianwei Zhang , Xiong Li , Haotian Liu , Lin Zhou , Peng Li

The shale oil exploration, in the Middle Jurassic Lianggaoshan Formation in the Fuxing area of Sichuan Basin, is in preliminary stage, requiring further in-depth study on shale oil and gas enrichment conditions. The lithological, organic geochemical, and reservoir characteristics of the Lianggaoshan Formation shale were analyzed using a suite of tests, including common thin section observation, organic carbon determination, pyrolysis experiment, combined N2-high pressure mercury test and argon ion polishing-scanning electron microscope, to elucidate source rock and reservoir qualities and their variation in vertical. Results suggest that the medium-carbon argillaceous shale, medium-carbon shell calcareous-argillaceous shale, and low-carbon argillaceous shale facies were mainly developed in Member 1 and Member 2 of the Lianggaoshan Formation. The medium-carbon argillaceous shale facies in the sub-layer ④ was rich in organic matter, with abundant sapropel, chitinous and secondary organic components, which were considered as a set of medium-quality source rocks. The medium-carbon shell calcareous-argillaceous shale and low-carbon argillaceous shale in the sub-layers ② and ③ have relatively low organic matter abundance, with vitrinite and inertinite as major organic microscopic components, revealing poor hydrocarbon generation potential. The porosity of shale reservoirs in sub-layers ②‒④ was higher than 3.0%, with predominant mesopores, followed by macropores, consisting of mainly clay mineral pores, organic pores, and microfractures related to organic matter. The medium-carbon argillaceous shale facies at the Lianggaoshan Formation is high-quality source rocks and reservoirs and is thus a potential target for lacustrine shale oil exploration in the Fuxing area of the Sichuan Basin.

四川盆地复兴地区中侏罗世梁高山组页岩油勘探尚处于初步阶段,需要进一步深入研究页岩油气富集条件。采用常规薄片观测、有机碳测定、热解实验、N2高压汞联合测试和氩离子抛光扫描电子显微镜等一系列测试手段,对梁高山组页岩的岩性、有机地球化学和储层特征进行了分析,阐明烃源岩和储层的性质及其在垂向上的变化。结果表明,梁高山组一、二段主要发育中碳泥质页岩、中碳壳钙质泥质页岩和低碳泥质泥岩相。④亚层中碳泥质页岩相富含有机质,含丰富的腐泥质、壳质和次生有机质成分,是一套中等质量的烃源岩。②、③亚层中碳壳钙质泥质页岩和低碳泥质页岩有机质丰度较低,主要有机微观组分为镜质组和惰质组,生烃潜力较差。②-④亚层页岩储层孔隙度大于3.0%,以中孔为主,大孔次之,主要由粘土矿物孔隙、有机孔隙和与有机质有关的微裂缝组成。梁高山组中碳泥质页岩相为优质烃源岩和储层,是四川盆地复兴地区湖相页岩油勘探的潜在目标。
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引用次数: 5
Water-methane interactions in coal: Insights from molecular simulation 煤中水-甲烷相互作用:来自分子模拟的见解
Pub Date : 2023-01-01 DOI: 10.1016/j.uncres.2023.01.004
Yanbin Yao , Chu Zhang , Shun Ye , Xiaoxiao Sun , Hao Wu

Water distribution can affect the storage and transport of methane in coal. There are many reports involving the distribution of water and methane in coal, but the microscopic mechanism of water-methane interaction is still unclear. In this study, realistic molecular structure models of bituminous and anthracite coals were constructed based on the chemical structures of two coal samples. And the chemical structures were analyzed by solid-state nuclear magnetic resonance, Fourier-transform infrared, and X-photoelectron spectroscopy. Then slit-pore models with different pore sizes were constructed based on the molecular structures to simulate the methane-water interaction in bituminous and anthracite coals. Results show that water molecules tend to form water bridges and water films in the pores of bituminous and anthracite coals, respectively. The significant displacement of pre-adsorbed water by methane was observed through simulation. It is found that the water molecules on the pore surface and the interfaces of small-size water bridges are more easily displaced by methane. In the larger pores, methane molecules mainly drive water molecules to agglomerate larger water bridges in bituminous coal. While methane molecules mainly drive water molecules to cover the pore surface and form a thicker water film in anthracite coal. This study provides new insights into the microscopic distribution and interaction mechanism of fluids in coal.

水的分布会影响甲烷在煤中的储存和运输。关于水和甲烷在煤中的分布,已有许多报道,但水与甲烷相互作用的微观机制尚不清楚。在本研究中,基于两个煤样的化学结构,建立了烟煤和无烟煤的真实分子结构模型。并用固态核磁共振、傅立叶变换红外光谱和X光电子能谱对其化学结构进行了分析。然后根据分子结构建立了不同孔径的狭缝孔模型,模拟了烟煤和无烟煤中甲烷与水的相互作用。结果表明,水分子在烟煤和无烟煤的孔隙中分别形成水桥和水膜。通过模拟观察到甲烷对预吸附水的显著驱替。研究发现,甲烷更容易取代孔隙表面和小尺寸水桥界面上的水分子。在较大的孔隙中,甲烷分子主要驱动水分子在烟煤中聚集较大的水桥。而在无烟煤中,甲烷分子主要驱动水分子覆盖孔隙表面,形成较厚的水膜。这项研究为煤中流体的微观分布和相互作用机制提供了新的见解。
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引用次数: 1
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Unconventional Resources
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