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Effect of ZnCl2, H3PO4, and KOH activation on low-temperature NH3-denitration performance of activated carbon ZnCl2、H3PO4和KOH活化对活性炭低温nh3脱硝性能的影响
IF 1.7 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-11-14 DOI: 10.1002/clen.202300148
Bangfu Huang, Wanjun Li, Zhe Shi, Linjing Yang, Zhenjing Wen, Gaoyong Zi, Liubin Luo

This study aims to explore the effect of the activator type, activation time, and activator concentration on the denitration performance of activated carbon (AC). Combined with denitration experiments, scanning electron microscopy, pore size analysis, and Fourier transform infrared spectroscopy characterization methods, an orthogonal experiment was conducted using zinc chloride (ZnCl2), phosphoric acid (H3PO4), and potassium hydroxide (KOH) as activators to explore the interaction between various factors and their effect on the denitration performance of AC. The results show that the denitration rate of ZnCl2-activated AC is generally low because a high concentration of ZnCl2 will block the micropores of AC and destroy the original structure. The denitration rate of H3PO4-activated AC decreased with the increase in H3PO4 concentration, especially severe blockage occurred on the AC-H3 surface. KOH activation can optimize the pore structure of AC and generate some oxygen-containing functional groups, which is beneficial to improve the adsorption performance of AC. Orthogonal experiments showed that the activator type had the most obvious effect on the denitration rate, followed by the activation time, whereas reagent concentration had little effect on the denitration rate. The optimum activation condition was 3 mol L−1 KOH at 80°C for 3.5 h.

本研究旨在探讨活化剂类型、活化时间和活化剂浓度对活性炭(AC)脱硝性能的影响。结合脱硝实验、扫描电镜、孔径分析、傅立叶变换红外光谱表征等方法,对氯化锌(ZnCl2)、磷酸(H3PO4)、和氢氧化钾(KOH)作为活化剂,探索各种因素之间的相互作用及其对活性炭脱硝性能的影响。结果表明,高浓度的ZnCl2会堵塞活性炭的微孔,破坏活性炭原有结构,因此ZnCl2活化的活性炭脱硝率普遍较低。随着H3PO4浓度的增加,H3PO4活化AC的脱硝速率降低,特别是AC- h3表面出现严重堵塞。KOH活化可以优化活性炭的孔隙结构,生成一些含氧官能团,有利于提高活性炭的吸附性能。正交实验表明,活化剂类型对脱硝率的影响最明显,其次是活化时间,而试剂浓度对脱硝率的影响较小。最佳活化条件为3mol L−1 KOH,在80℃下活化3.5 h。
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引用次数: 0
Cover Picture: Clean Soil Air Water. 11/2023 封面图片:11/2023清洁土壤空气水
IF 1.7 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-11-14 DOI: 10.1002/clen.202370111
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引用次数: 0
Masthead: Clean Soil Air Water. 11/2023 报头:清洁土壤空气水。11/2023
IF 1.7 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-11-14 DOI: 10.1002/clen.202370112
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引用次数: 0
Evaluation and economic value of Hedera colchica in urban land management 耧斗菜在城市土地管理中的评估和经济价值
IF 1.7 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-11-09 DOI: 10.1002/clen.202200279
Mahsa Sadat Mirhosseini, Keivan Saeb, Masoud Kiadaliri, Aptin Rahnavard

Carbon sequestration is the process of capturing, securing and storing carbon dioxide from the atmosphere. In this study, the carbon sequestration capacity of Hedera colchica was investigated in soil of a semiarid region in Iran. Samples were taken from plants cultivated in the semiarid area of the polluted metropolis of Tehran and the amount of sequestered carbon in the aboveground and underground parts of the plant was measured. The conversion coefficient of carbon sequestration of plant organs (stem, leaf, and root) was determined separately by the combustion method. Carbon tax policy was used to evaluate the carbon sequestration function, as the shadow price of carbon. The results showed a significant difference in the amount of carbon sequestration in different organs of the plant. Stems and roots with 29.3 and 4.3 t ha−1, respectively, showed the highest and lowest amount of carbon deposition. The results of the economic value showed that the carbon shadow price was $40567.6 ha−1 on average. In general, the results of this study showed that the organs of H. colchica can have a beneficial effect in the process of carbon sequestration.

固碳是捕捉、保护和储存大气中二氧化碳的过程。本研究调查了伊朗半干旱地区土壤中 Hedera colchica 的固碳能力。样本取自德黑兰污染严重的大都市半干旱地区种植的植物,并测量了植物地上部分和地下部分的固碳量。采用燃烧法分别测定了植物器官(茎、叶、根)固碳的转化系数。采用碳税政策作为碳的影子价格来评估固碳功能。结果表明,植物不同器官的固碳量差异显著。茎和根的固碳量最高,分别为 29.3 吨/公顷和 4.3 吨/公顷。经济价值结果显示,碳影子价格平均为 40567.6 美元/公顷-1。总之,该研究结果表明,可乐果器官在固碳过程中具有有益作用。
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引用次数: 0
Recovery of phosphorus from aqueous media as vivianite by crystallization 通过结晶以维维安石的形式从水介质中回收磷
IF 1.7 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-11-08 DOI: 10.1002/clen.202300142
Nurdan Buyukkamaci, Seda Karabacakogullari, Duygu Totur Pamik

Since phosphorus resources are limited, optimal management of available phosphorus (P) and phosphorus recovery is a vital issue for the entire world. Studies continue on more efficient and economical phosphorus recovery techniques from wastewater and sludge. Recovery of phosphorus as vivianite is a current issue worldwide and studies are ongoing. Vivianite is a valuable mineral used in some industrial facilities and agricultural activities. Therefore, recovery of P from wastewater based on vivianite formation not only contributes to the sustainable use of phosphorus but also provides potential economic opportunities. In this study, it was aimed to determine the recovery potential of phosphorus as vivianite and to evaluate the effects of operational conditions on phosphorus recovery. For this purpose, two types of lab-scale crystallizer, semibatch completely mixed and fluidized bed, were used. In experimental studies, the effects of operating parameters such as pH, Fe/P ratio, Fe feeding rate, and P concentration for vivianite crystallization were investigated. The highest phosphorus recovery was found at a Fe/P ratio of 1.8 and P removal efficiency of up to 69% was achieved by vivianite crystallization.

由于磷资源有限,对可用磷(P)的优化管理和磷回收对全世界来说都是一个至关重要的问题。从废水和污泥中回收磷的更高效、更经济的技术研究仍在继续。以维维安石的形式回收磷是当前全球面临的一个问题,相关研究仍在进行中。vivianite 是一种宝贵的矿物,可用于某些工业设施和农业活动。因此,基于薇薇安石的形成从废水中回收磷不仅有助于磷的可持续利用,还提供了潜在的经济机会。本研究旨在确定磷作为 vivianite 的回收潜力,并评估操作条件对磷回收的影响。为此,使用了两种实验室规模的结晶器,即半间歇式完全混合结晶器和流化床结晶器。在实验研究中,考察了 pH 值、铁/磷比例、铁进料速度和磷浓度等操作参数对维维安石结晶的影响。在 Fe/P 比为 1.8 时,磷的回收率最高,维安石结晶对磷的去除率高达 69%。
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引用次数: 0
Evaluation of radon-induced radiation risk in indoor environments 评估室内环境中的氡诱发辐射风险
IF 1.7 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-11-03 DOI: 10.1002/clen.202300124
Nedime İrem Elek, Nebiye Füsun Çam, Buket Canbaz Öztürk

In general people spend most of their time in enclosed environments, therefore, they are exposed to indoor radon and its progeny. The paper discusses the variables influencing indoor radon levels. It assesses the correlation between indoor radon levels with temperature, humidity, and pressure, as well as seasonal variables. Radon activity concentrations were measured in Ege University's laboratories and Classroom using a digital radon gas detector. After statistical analysis, the results were compared to committee-permissible limit levels (ICRP, WHO, and EU). It was found that the average radon activity concentrations were below the recommended 300 Bq m–3 limit value (EU), ranging from 58.4 to 216.0 Bq m–3. This study emphasized the significance of measuring and assessing the indoor radon levels in laboratories and classrooms in particular, in order to safeguard the students and faculty members from radon-related health issues.

一般来说,人们大部分时间都呆在封闭的环境中,因此会接触到室内氡及其后代。本文讨论了影响室内氡含量的各种变量。它评估了室内氡含量与温度、湿度和压力以及季节性变量之间的相关性。在埃格大学的实验室和教室使用数字式氡气检测仪测量了氡活度浓度。经过统计分析后,将结果与委员会允许的极限水平(ICRP、WHO 和 EU)进行了比较。结果发现,平均氡活度浓度低于建议的 300 Bq m-3 限值(欧盟),从 58.4 到 216.0 Bq m-3 不等。这项研究强调了测量和评估实验室(尤其是教室)室内氡气水平的重要性,以保障师生免受氡气相关健康问题的影响。
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引用次数: 0
Advancements in biodigester technology through the study of anaerobic digestion using statistical optimization and bioaccelerators 通过利用统计优化和生物加速器研究厌氧消化,推动生物发酵技术的发展
IF 1.7 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-11-01 DOI: 10.1002/clen.202300102
Pablo Inocêncio Monteiro, André Bellin Mariano, Bianca do Santos Padilha, Yann Domingues de Moraes, Letícia Zaguine, Leonardo Rey Oliveira Lopes, Marcelo Lacerda de Moraes, Rúbia Martins Bernardes Ramos, Michele Rigon Spier

Advances in biodigester technology have been promoted by the growing study of anaerobic digestion, with the aim of improving processes related to the utilized waste load. This research used the statistical tool Central Composite Rotatable Design to optimize the combination of microorganisms and enzymes for biodigestion. The experiment involved testing two microorganisms (EA and EB) and five enzymes (amylase, protease, lipase, cellulase, and amyloglucosidase) with food waste from nearby restaurants and WWTP sludge as an inoculant. The experiment was set up as Central Composite Rotatable Design (CCRD) 26-1, with 50 trials and a concentration of 14.5 g of volatile solids per liter. The dependent variables of cumulative biogas production (BG) and cumulative biomethane production (BM) were evaluated. The results showed that the independent variables EB and CA had negative and significant effects on BG and BM production. With optimized process conditions, the bioaccelerator significantly improved BG and BM responses compared to control trials by 72% and 88%, respectively. The biodigestion technique is a viable option for the treatment of organic waste, and the use of bioaccelerators may be a promising approach to improving biodigestion processes. This study contributes to the ongoing research on anaerobic digestion and biodigester technology, which seeks to improve the sustainable management of organic waste while producing renewable energy.

厌氧消化研究的不断发展推动了生物发酵技术的进步,其目的是改进与利用废物负荷相关的工艺。本研究使用统计工具 "中央复合可旋转设计 "来优化生物消化微生物和酶的组合。实验包括测试两种微生物(EA 和 EB)和五种酶(淀粉酶、蛋白酶、脂肪酶、纤维素酶和淀粉葡萄糖苷酶)与来自附近餐馆的厨余垃圾以及作为接种剂的污水处理厂污泥。实验设置为中央复合可旋转设计(CCRD)26-1,共进行 50 次试验,浓度为每升 14.5 克挥发性固体。对因变量累积沼气产量(BG)和累积生物甲烷产量(BM)进行了评估。结果表明,自变量 EB 和 CA 对 BG 和 BM 产量有显著的负向影响。在优化工艺条件下,与对照试验相比,生物加速器显著提高了 BG 和 BM 响应,分别提高了 72% 和 88%。生物发酵技术是处理有机废物的一种可行方法,使用生物加速器可能是改进生物发酵过程的一种有前途的方法。这项研究为正在进行的厌氧消化和生物发酵技术研究做出了贡献,该研究旨在改善有机废物的可持续管理,同时生产可再生能源。
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引用次数: 0
Potential positive effects of natural sunlight on a biological system for landfill leachate treatment 自然阳光对垃圾渗滤液处理生物系统的潜在积极影响
IF 1.7 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-10-27 DOI: 10.1002/clen.202300065
Liyun Cai

Activated sludge filtration performance is a significant mean to evaluate membrane fouling trend for wastewater treatment. Here the impact of sunlight irradiation on activated sludge filtration performance and microbial communities in sequencing batch reactors (SBRs) when treating raw landfill leachate were studied. The sludge in photic SBR (i.e., SBR exposed to natural sunlight) exhibited better filtration performance compared to dark SBR (i.e., SBR unexposed to sunlight). The removal efficiency of COD and NH4+-N in the photic SBR were slightly higher than those in the dark SBR. The contents of the extracellular polymeric substances (EPSs) of sludge in both SBRs initially increased and then decreased. However, in the later period, the sludge filtration performance worsened due to the fungal activity in the dark SBR. Natural sunlight irradiation promoted sludge filtration performance by affecting the microorganism structure in the photic SBR. The bacterial genus Thauera was dominant in the photic SBR (39.35%), whereas Planktosalinus and Ottowia were dominant in the dark SBR (16.84% and 12.55%, respectively). Natural sunlight irradiation had a prominent effect on the fungal diversity in the system, and filamentous bulking caused by the fungi genus Trichosporon’s proliferation was observed in the dark SBR but not in the photic SBR, which also increased the polysaccharide content.

活性污泥过滤性能是评估污水处理膜堵塞趋势的重要手段。本文研究了在处理垃圾填埋场渗滤液原液时,阳光照射对序批式反应器(SBR)中活性污泥过滤性能和微生物群落的影响。与暗色 SBR(即未受阳光照射的 SBR)相比,光色 SBR(即受自然阳光照射的 SBR)中的污泥具有更好的过滤性能。光照 SBR 对 COD 和 NH4+-N 的去除率略高于黑暗 SBR。两种 SBR 中污泥的胞外高分子物质(EPS)含量最初都有所上升,随后有所下降。但在后期,由于暗色 SBR 中真菌的活动,污泥过滤性能恶化。自然光照通过影响光照 SBR 中的微生物结构,促进了污泥过滤性能。细菌属 Thauera 在光照 SBR 中占优势(39.35%),而 Planktosalinus 和 Ottowia 在黑暗 SBR 中占优势(分别为 16.84% 和 12.55%)。自然阳光照射对系统中的真菌多样性有显著影响,在暗色 SBR 中观察到由真菌三孢属增殖引起的丝状隆起,而在光色 SBR 中没有观察到,这也增加了多糖含量。
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引用次数: 0
Optimization of effecting parameters for flue gas desulfurization in a self-priming venturi scrubber using response surface methodology 利用响应面方法优化自吸式文丘里洗涤器中的烟气脱硫效应参数
IF 1.7 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-10-24 DOI: 10.1002/clen.202300034
Manisha Bal, Payal Das, Bhim Charan Meikap

Hydrogen sulfide (H2S), a highly poisonous and corrosive gas, is regarded as a hazardous air pollutant with significant effects on human health. Hence, reduction of hydrogen sulfide (H2S) gas from the atmosphere is very essential. In the present work, self-priming venturi scrubber is employed to extract H2S gas from the air. Response surface methodology (RSM) with a central composite design (CCD) has been selected to investigate maximizing the H2S removal efficiency by optimizing the process variables. Experiments were carried out by altering the throat gas velocity, outer cylinder liquid level and inlet concentration of H2S. The analysis of variance (ANOVA) test showed that the parameters had a significant effect on the efficiency of H2S removal. A quadratic equation has been developed that accurately predicts the percentage of removal efficiency. The appropriateness of the generated model has been verified by the value of higher R2 resulting from the regression analysis. According to the observations, the velocity of throat gas has the highest effect on the H2S removal efficiency, whereas inlet H2S concentration has the least effect.

硫化氢(H2S)是一种剧毒的腐蚀性气体,被认为是对人类健康有重大影响的有害空气污染物。因此,减少大气中的硫化氢(H2S)气体至关重要。本研究采用自吸式文丘里洗涤器来提取空气中的 H2S 气体。研究人员选择了采用中心复合设计(CCD)的响应面方法(RSM),通过优化工艺变量来最大限度地提高 H2S 去除效率。实验通过改变喉管气速、外筒液面和 H2S 入口浓度来进行。方差分析(ANOVA)测试表明,这些参数对 H2S 去除效率有显著影响。建立的二次方程可以准确预测去除效率的百分比。回归分析得出的较高 R2 值验证了所生成模型的适当性。根据观察结果,喉管气体速度对 H2S 去除效率的影响最大,而入口 H2S 浓度的影响最小。
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引用次数: 0
Masthead: Clean Soil Air Water. 10/2023 刊头:清洁土壤空气水。2023年10月
IF 1.7 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2023-10-11 DOI: 10.1002/clen.202370102
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引用次数: 0
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Clean-soil Air Water
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