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Optimization of La2−xSrxCuO4 Single Crystal Film Growth via Molecular Beam Epitaxy 分子束外延法优化La2−xSrxCuO4单晶薄膜生长
IF 1.7 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-20 DOI: 10.3390/condmat8010013
Xi He, Xiaotao Xu, Xiaoyan Shi, I. Božović
Atomic layer-by-layer molecular beam epitaxy (ALL-MBE) combined with ozone is one of the best methods to fabricate single-crystal thin films of complex oxides. Cuprate such as La2−xSrxCuO4 (LSCO) is a representative complex-oxide high-temperature superconductor (HTS) material. Our group utilizes this method to produce high-quality single-crystal HTS films with atomically smooth surfaces and interfaces. In addition, ALL-MBE enables us to engineer multilayer heterostructures with atomic precision. This allows the fabrication of tunnel junctions, various nanostructures, and other HTS devices of interest for superconducting electronics. We have synthesized over three thousand LSCO thin films in the past two decades. These films’ structural and electronic properties have been studied and characterized by various methods. Here, we distill the extensive experience we accumulated into a step-by-step protocol to fabricate atomically perfect LSCO films. The recipe includes substrate preparation, ozone generation and distillation, source calibration, the in situ monitoring of the film synthesis, post-growth annealing, and ex situ characterization. It discloses a reproducible way to fabricate single-crystal LSCO films for basic research and HTS electronic applications.
原子逐层分子束外延(ALL-MBE)与臭氧相结合是制备复杂氧化物单晶薄膜的最佳方法之一。铜酸盐如La2−xSrxCuO4(LSCO)是一种具有代表性的复合氧化物高温超导体(HTS)材料。我们的团队利用这种方法生产出具有原子级光滑表面和界面的高质量单晶HTS薄膜。此外,ALL-MBE使我们能够以原子精度设计多层异质结构。这允许制造隧道结、各种纳米结构和超导电子领域感兴趣的其他HTS器件。在过去的二十年里,我们已经合成了3000多个LSCO薄膜。这些薄膜的结构和电子性能已经通过各种方法进行了研究和表征。在这里,我们将积累的丰富经验提炼成一个循序渐进的方案,以制造原子级完美的LSCO薄膜。该配方包括衬底制备、臭氧生成和蒸馏、源校准、膜合成的原位监测、生长后退火和非原位表征。它公开了一种用于基础研究和HTS电子应用的可重复制备单晶LSCO膜的方法。
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引用次数: 2
Acknowledgment to the Reviewers of Condensed Matter in 2022 对2022年凝聚态物质评审员的致谢
IF 1.7 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-17 DOI: 10.3390/condmat8010010
High-quality academic publishing is built on rigorous peer review [...]
高质量的学术出版建立在严格的同行评审基础上〔…〕
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引用次数: 0
Second-Neighbor Hopping Effects in the Two-Dimensional Attractive Hubbard Model 二维吸引Hubbard模型中的第二邻居跳跃效应
IF 1.7 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-17 DOI: 10.3390/condmat8010011
Rodrigo A. Fontenele, Nathan Vasconcelos, N. Costa, T. Paiva, R. R. dos Santos
The emergence of superconductivity (SC) in lattice models, such as the attractive Hubbard one, has renewed interest since the realization of cold-atom experiments. However, reducing the temperature in these experiments is a bottleneck; therefore, investigating how to increase the energy scale for SC is crucial to cold atoms. In view of this, we examine the effects of next-nearest-neighbor hoppings (t′) on the pairing properties of the attractive Hubbard model in a square lattice. To this end, we analyze the model through unbiased Quantum Monte Carlo simulations for fixed density n=0.87, and perform finite-size scaling analysis to the thermodynamic limit. As our main result, we notice that the existence of further hopping channels leads to an enhancement of the pairing correlations, which, in turn, increases the ground-state order parameter Δ. Finally, at finite temperatures, for t′/t≠0, this enhancement of pairing correlations leads to an increase in the critical temperature Tc. That is, the fine-tuning of second-neighbor hoppings increases the energy scales for SC, and may be a route by which cold-atom experiments can achieve such a phase and to help us further understand the nature of this phenomenon.
自冷原子实验实现以来,晶格模型中超导性(SC)的出现重新引起了人们的兴趣,例如吸引人的Hubbard模型。然而,在这些实验中降低温度是一个瓶颈;因此,研究如何提高SC的能量尺度对冷原子来说至关重要。鉴于此,我们研究了次近邻跳跃(t ')对方形晶格中吸引Hubbard模型的配对性质的影响。为此,我们通过无偏量子蒙特卡罗模拟分析了固定密度n=0.87的模型,并对热力学极限进行了有限尺寸的缩放分析。作为我们的主要结果,我们注意到进一步的跳频通道的存在导致配对相关性的增强,这反过来又增加了基态序参数Δ。最后,在有限温度下,当t′/t≠0时,配对相关性的增强导致临界温度Tc的增加。也就是说,第二近邻跳跃的微调增加了SC的能量尺度,并且可能是冷原子实验可以实现这样一个阶段的途径,并帮助我们进一步理解这种现象的本质。
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引用次数: 0
Detection of Surface States in Quantum Materials ZrTe2 and TmB4 by Scanning Tunneling Microscopy 扫描隧道显微镜检测量子材料ZrTe2和TmB4的表面态
IF 1.7 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-16 DOI: 10.3390/condmat8010009
M. V. Ale Crivillero, J. Souza, Vicky Hasse, M. Schmidt, N. Shitsevalova, S. Gabáni, K. Siemensmeyer, K. Flachbart, S. Wirth
Scanning Tunneling Microscopy and Spectroscopy (STM/S), with its exceptional surface sensitivity and exquisite energy resolution, is well suited for the investigation of surface states down to atomic length scales. As such, it became an essential tool to probe the surface states of materials, including those with non-trivial topology. One challenge, however, can be the preparation of clean surfaces which allow the study of preferably unchanged surface properties with respect to the bulk amount. Here, we report on the STM/S of two materials, ZrTe2 and TmB4. The former cleaves easily and defects can be examined in detail. However, our STS data can only qualitatively be compared to the results of band structure calculations. In the case of TmB4, the preparation of suitable surfaces is highly challenging, and atomically flat surfaces (likely of B-termination) were only encountered rarely. We found a large density of states (DOS) at the Fermi level EF and a mostly featureless differential conductance near EF. Further efforts are required to relate our results to the electronic structure predicted by ab initio calculations.
扫描隧道显微镜和光谱学(STM/S)以其卓越的表面灵敏度和精致的能量分辨率,非常适合研究表面状态到原子长度尺度。因此,它成为探测材料表面状态的重要工具,包括那些具有非平凡拓扑结构的材料。然而,一个挑战可能是制备干净的表面,以便研究相对于体积量最好不变的表面特性。本文报道了ZrTe2和TmB4两种材料的STM/S。前者容易开裂,缺陷可以详细检查。然而,我们的STS数据只能定性地与波段结构计算的结果进行比较。在TmB4的情况下,制备合适的表面是极具挑战性的,并且原子平面(可能是b终止)很少遇到。我们发现在费米能级EF有一个大的态密度(DOS),在EF附近有一个基本无特征的微分电导。需要进一步的努力将我们的结果与从头计算预测的电子结构联系起来。
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引用次数: 0
Experimental and Theoretical Investigation of High-Resolution X-ray Absorption Spectroscopy (HR-XAS) at the Cu K-Edge for Cu2ZnSnSe4 Cu2ZnSnSe4在Cu K边缘的高分辨X射线吸收光谱的实验与理论研究
IF 1.7 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-13 DOI: 10.3390/condmat8010008
Wei Xu, Yujun Zhang, K. Ishii, H. Wadati, Yingcai Zhu, Z.H. Guo, Qianshun Diao, Zhen Hong, Haijiao Han, Lidong Zhao
Energy sustainability is critical for social activities in the human world. The quaternary compound Cu2ZnSnSe4 (CZTSe), as a promising candidate for thin-film solar cell absorption with medium-level thermoelectric performance, is of interest for the purpose of utilizing solar energy. The defect chemistry and atomic ordering in this particular compound also triggers interests in understanding its crystallographic structure as well as defects. Hereby, high energy resolution X-ray absorption spectroscopy is employed to investigate the electronic and geometric structural complexity in pristine and cobalt-doped Cu2ZnSnSe4. The occupational atomic sites of Cu are found to be mixed with the Zn atoms, forming CuZn anti-defects, which serve as a knob to tune local electronic structures. With proper doping, the band structure can be manipulated to improve the optical and thermoelectric properties of the CZTSe compounds.
能源可持续性对人类社会活动至关重要。季元化合物Cu2ZnSnSe4 (CZTSe)是一种具有中等热电性能的薄膜太阳能电池吸收材料,是利用太阳能的重要材料。这种特殊化合物的缺陷化学和原子顺序也引起了人们对其晶体结构和缺陷的兴趣。因此,采用高能分辨率x射线吸收光谱研究了原始Cu2ZnSnSe4和钴掺杂Cu2ZnSnSe4的电子和几何结构复杂性。Cu的占位原子位与Zn原子混合,形成Cu的反缺陷,作为调节局部电子结构的旋钮。通过适当的掺杂,可以控制其能带结构,从而改善CZTSe化合物的光学和热电性能。
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引用次数: 0
Is Nematicity in Cuprates Real? Cuprates中的Nematicity是真的吗?
IF 1.7 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-10 DOI: 10.3390/condmat8010007
I. Božović, Xi He, A. Bollinger, R. Caruso
In La2-xSrxCuO4 (LSCO), a prototype high-temperature superconductor (HTS) cuprate, a nonzero transverse voltage is observed in zero magnetic fields. This is important since it points to the breaking of the rotational symmetry in the electron fluid, the so-called electronic nematicity, presumably intrinsic to LSCO (and other cuprates). An alternative explanation is that it arises from extrinsic factors such as the film’s inhomogeneity or some experimental artifacts. We confront this hypothesis with published and new experimental data, focusing on the most direct and sensitive probe—the angle-resolved measurements of transverse resistivity (ARTR). The aggregate experimental evidence overwhelmingly refutes the extrinsic scenarios and points to an exciting new effect—intrinsic electronic nematicity.
在原型高温超导体(HTS)铜酸盐La2-xSrxCuO4(LSCO)中,在零磁场中观察到非零横向电压。这一点很重要,因为它指出了电子流体中旋转对称性的破坏,即所谓的电子向列性,可能是LSCO(和其他铜酸盐)固有的。另一种解释是,它是由外在因素引起的,如薄膜的不均匀性或一些实验伪影。我们用已发表的新实验数据来对抗这一假设,重点关注最直接、最灵敏的探针——横向电阻率的角度分辨测量(ARTR)。总的实验证据压倒性地驳斥了外在的情景,并指出了一种令人兴奋的新效应——内在电子向列性。
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引用次数: 1
Thermodynamics in Stochastic Conway’s Game of Life 随机Conway生命游戏中的热力学
IF 1.7 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-09 DOI: 10.3390/condmat8020047
K. Pomorski, Dariusz Kotula
Cellular automata can simulate many complex physical phenomena using the power of simple rules. The presented methodological platform expresses the concept of programmable matter, of which Newton’s laws of motion are an example. Energy is introduced as the equivalent of the “Game of Life” mass, which can be treated as the first level of approximation. The temperature presence and propagation was calculated for various lattice topologies and boundary conditions, using the Shannon entropy measure. This study provides strong evidence that, despite the principle of mass and energy conservation not being fulfilled, the entropy, mass distribution, and temperature approach thermodynamic equilibrium. In addition, the described cellular automaton system transitions from a positive to a negative temperature, which stabilizes and can be treated as a signature of a system in equilibrium. The system dynamics is presented for a few species of cellular automata competing for maximum presence on a given lattice with different boundary conditions.
元胞自动机可以利用简单规则的力量模拟许多复杂的物理现象。所提出的方法论平台表达了可编程物质的概念,牛顿运动定律就是其中的一个例子。能量被引入为“生命游戏”质量的等价物,可以被视为第一级近似。使用香农熵测度计算了各种晶格拓扑和边界条件下的温度存在和传播。这项研究提供了强有力的证据,表明尽管质量和能量守恒原理没有得到满足,熵、质量分布和温度都接近热力学平衡。此外,所描述的元胞自动机系统从正温度转变为负温度,这是稳定的,并且可以被视为处于平衡状态的系统的特征。给出了几种细胞自动机在不同边界条件下竞争给定格上最大存在性的系统动力学。
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引用次数: 2
Magnetic Studies of Iron-Doped Probable Weyl Semimetal WTe2 铁掺杂可能的Weyl半金属WTe2的磁性研究
IF 1.7 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-06 DOI: 10.3390/condmat8010006
Andranik Khachatryan, E. Charnaya, M. Likholetova, E. Shevchenko, M. Lee, L. Chang, S. Naumov, A. Perevalova, E. Marchenkova, V. Marchenkov
The non-trivial topology of electronic bands in Weyl semimetals originates from band inversion due to strong spin–orbit coupling. The Weyl semimetals have pairs of Weyl gap-less nodes in the bulk Brillouin zone. The tungsten ditelluride WTe2 likely belongs to type II Weyl semimetals. Doping WTe2 with magnetic ions could induce magnetic ordering in this crystal, which provides prospects for practical applications. We studied the magnetic properties of the iron-doped single crystals Fe0.03W0.97Te2, annealed and unannealed, in comparison with the undoped WTe2. Measurements of the dc magnetization were carried out from 1.8 to 400 K. We revealed pronounced ferromagnetic ordering that was affected by annealing. Anomalies associated with antiferromagnetism and paramagnetism were also found. The magnetic order was suppressed by a field of 60 kOe. The rise in susceptibility with increasing temperature was observed at high temperatures in all samples and was treated using a model developed for Weyl semimetals. The Curie–Weiss law fit at 60 kOe showed that the effective magnetic moment was close to that of Fe2+. Metamagnetism was demonstrated for the unannealed doped WTe2 crystal. The data for the heat capacity of the iron-doped sample agreed with results for the undoped WTe2.
Weyl半金属中电子能带的非平凡拓扑源于强自旋轨道耦合引起的能带反转。Weyl半金属在大块布里渊区有对Weyl无间隙节点。二碲化钨WTe2可能属于II型Weyl半金属。在WTe2中掺杂磁性离子可以诱导该晶体的磁有序,具有实际应用前景。研究了铁掺杂单晶Fe0.03W0.97Te2在退火和未退火条件下的磁性能,并与未掺杂的WTe2进行了比较。在1.8 ~ 400k范围内进行了直流磁化测量。我们发现明显的铁磁有序受到退火的影响。与反铁磁性和顺磁性相关的异常也被发现。磁序被60克的磁场抑制了。在高温下观察到所有样品的磁化率随温度升高而升高,并使用为Weyl半金属开发的模型进行处理。居里-魏斯定律在60koe处的拟合表明,有效磁矩与Fe2+的有效磁矩接近。未退火的掺杂WTe2晶体具有超磁特性。铁掺杂样品的热容数据与未掺杂WTe2的结果一致。
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引用次数: 0
Charge–Phase Duality and Cotunneling of Fluxons in SQUID-like Nanorings 鱿鱼状纳米结构中通量子的电荷-相对偶性和共隧穿
IF 1.7 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2022-12-31 DOI: 10.3390/condmat8010005
A. Latyshev, A. G. Semenov, A. Zaikin
Employing charge–flux duality for Josephson junctions and superconducting nanowires, we predict a novel effect of fluxon cotunneling in SQUID-like nanorings. This process is strictly dual to that of Cooper pair cotunneling in superconducting transistors formed by a pairs of Josephson tunnel junctions connected in series. Cooper pair cotunneling is known to lift Coulomb blockade in these structures at low temperatures. Likewise, fluxon cotunneling may eliminate the magnetic blockade of superconducting phase fluctuations in SQUID-like nanorings, driving them into an insulating state.
利用约瑟夫逊结和超导纳米线的电荷-通量对偶性,我们预测了类SQUID纳米环中磁通共穿的新效应。这一过程与由一对串联的约瑟夫逊隧道结形成的超导晶体管中的库珀对共隧穿过程严格双重。众所周知,在低温下,库珀对协同隧道可以解除这些结构中的库仑阻塞。同样,磁通子共隧道可以消除类似SQUID的纳米环中超导相位波动的磁阻塞,使它们进入绝缘状态。
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引用次数: 0
Destructive Interference of the Superconducting Subband Condensates in the Quasi-1D Multigap Material Nanostructures 准一维多间隙材料纳米结构中超导子带凝聚的破坏性干涉
IF 1.7 Q3 PHYSICS, CONDENSED MATTER Pub Date : 2022-12-28 DOI: 10.3390/condmat8010004
W. Pasek, M. H. Degani, M. Z. Maialle
This modelling work concerns the effects of the interference between two partial subband condensates in a quasi-one-dimensional superconducting superlattice. The iterative under-relaxation with phase control method is used to solve Bogoliubov–de Gennes equations in the envelope ansatz. This method—easily generalisable to a wide class of multiband superconducting systems—allows us to obtain both the constructive and the destructive interference solution. The discussion is centred on the latter case, with one of the condensates collapsing with increased inter-subband coupling strength, due to the other—the dominating one—imposing its symmetry on the overall order parameter. The in-depth qualitative analysis is made of underlying intra-subband and inter-subband dynamics, such as the possible factors determining the dominant subband condensate or the ones determining the region where the destructive solution coexists with the constructive one. A comprehensive discussion with the recent works concerning inter-band coupling effects follows, pointing that the destructive solution is nearly universally omitted.
这项建模工作涉及准一维超导超晶格中两个部分子带凝聚体之间的干涉效应。采用迭代欠松弛相位控制方法求解包络变换中的Bogoliubov–de Gennes方程。这种方法很容易推广到广泛的一类多频带超导系统中,使我们能够获得相长和相消干涉解。讨论集中在后一种情况上,其中一个凝聚体随着子带间耦合强度的增加而坍缩,因为另一个——占主导地位的凝聚体——将其对称性强加于整个阶参数上。对潜在的子带内和子带间动态进行了深入的定性分析,例如确定主子带凝聚的可能因素,或者确定破坏性解与构造性解共存的区域的因素。下面对最近关于带间耦合效应的工作进行了全面的讨论,指出破坏性解几乎普遍被省略。
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引用次数: 0
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Condensed Matter
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