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Gamma irradiation effects in two epoxy resins and a polyimide 两种环氧树脂和一种聚酰亚胺的辐照效应
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69546
R. Fouracre, H. M. Banford, D. Tedford, W. Huiming, X. Cao
Changes in the electrical properties of insulators exposed to high levels of ionizing radiation can have a significant effect on the lifetime of equipment incorporating such material. In order to obtain a knowledge of the processes involved, a series of experiments were undertaken on the effects of gamma irradiation, at dose levels up to a few megagrays (MGy), on the DC conductivity and the thermally stimulated discharge current (TSDC) spectra of two epoxy resin samples and a polyimide. Among other findings it is shown that the curves for DC conductivity can be used to measure the glass transition temperature T/sub G/. Initial differential scanning calorimetry measurements had shown that the T/sub G/ of the as-produced resin was 189 degrees C. Irradiation to 1 MGy reduced this value to 90 degrees C, and this was little changed by annealing. The activation energy below T/sub G/ decreased as a sequence of irradiation, but increased after annealing of the sample. Comparison with the TSDC spectra shows that the T/sub G/ of the system is lowered by the irradiation process, and it has also been shown that annealing increases the T/sub G/, although at this dose level it does not return to its original value. Measurements on polyimide indicate that there is a change in conduction mechanism after irradiation.<>
暴露在高水平电离辐射下的绝缘体的电气特性的变化会对采用这种材料的设备的寿命产生重大影响。为了了解所涉及的过程,进行了一系列实验,研究了高达几兆射线(MGy)剂量水平的伽马辐照对两种环氧树脂样品和聚酰亚胺的直流电导率和热激放电电流(TSDC)光谱的影响。结果表明,直流电导率曲线可用于测量玻璃化转变温度T/sub G/。最初的差示扫描量热法测量表明,生产的树脂的T/sub G/为189℃,辐照至1 MGy将该值降至90℃,退火后变化不大。T/sub G/以下的活化能随辐照次数的增加而减小,退火后的活化能增加。与TSDC光谱的比较表明,辐照过程降低了系统的T/sub G/,退火也增加了系统的T/sub G/,但在该剂量水平下并没有恢复到原来的值。对聚酰亚胺的测量表明,辐照后其传导机制发生了变化。
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引用次数: 0
Effect of dissolved water on electrical conduction in liquid dielectrics 溶解水对液体介质导电性的影响
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69571
A. Ebe, N. Iijima, M. Sone, H. Mitsui
The state of water in liquid dielectric was analyzed by Fourier transform infrared spectroscopy during a conduction test. The liquid dielectric used was di-octyl-phthalate (DOP) with different proportions of water. The free water in DOP is shown to contribute to the conduction. The states of the free water or weakly bound water are shown to change under stress.<>
利用傅里叶变换红外光谱分析了电介质中水的导电状态。所使用的液体介质为邻苯二甲酸二辛酯(DOP)和不同比例的水。DOP中的自由水有助于导电。在应力作用下,自由水或弱结合水的状态会发生变化。
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引用次数: 1
Ramped voltage testing of transformer oil 变压器油斜坡电压试验
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69573
D.H. Ren, A. Watson
It has been shown that, compared with dimethyl siloxane, transformer oil has similar reproducible current characteristics as a function of ramped voltage applied up to a high prebreakdown electric stress, where it obeys the equation I varies as V/sup s/. Moreover, at a very high electric stress, the displacement current component apparently reverses, which was not previously observed in silicone oil. This abnormal phenomenon is very dependent upon the conditions. From an earlier study in silicone oil, the average current response to the rising and falling voltage appears on a log-log scale with two linear portions which are sharply divided. Transformer oil has similar characteristics under similar testing conditions, but with increasing voltage amplitude of the applied ramp the slopes of the linear portions are changed. These two lines may become one if the maximum voltage and ramp rate are very high. This is true for copper and aluminum electrodes at differing gap separations.<>
已经证明,与二甲基硅氧烷相比,变压器油具有类似的可重复电流特性,作为施加到高预击穿电应力的斜坡电压的函数,其中它服从等式I随V/sup /变化。此外,在非常高的电应力下,位移电流分量明显相反,这是以前在硅油中没有观察到的。这种不正常的现象很大程度上取决于条件。从早期对硅油的研究来看,对电压上升和下降的平均电流响应出现在对数对数刻度上,其中两个线性部分被划分得很明显。在相似的试验条件下,变压器油具有相似的特性,但随着施加斜坡的电压幅值的增加,线性部分的斜率会发生变化。如果最大电压和斜坡速率非常高,这两条线可能会合二为一。对于不同间隙间隔的铜和铝电极来说,这是正确的
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引用次数: 2
Effect of nuclear radiation on microstrip and dielectric antennas in space 空间核辐射对微带和介电天线的影响
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69545
A. Kumar
The effect of nuclear radiation in space on dielectric material used in microstrip and dielectric antennas is described. It has been shown that the primary effect of nuclear radiation on materials based on PTFE (polytetrafluoroethylene) is the reduction of molecular weight by breaking the large polymer molecule into smaller parts. There is an increase in brittleness, and this reaction is maximized in the presence of air. The degree to which PTFE is affected is essentially a function of the amount of energy absorbed regardless of the nature of the radiation. The susceptibility of electronic dielectric materials as a function of the total nuclear radiation dose is shown. Usually, the dose rate of 10 rad/h is quoted for the Van Allen belt. At this rate PTFE could operate for more than five years before a threshold level of damage would be detectable electrically and mechanically. Space-proven dielectric antennas are briefly discussed, with particular emphasis on the GTE GSTAR satellite reflector antenna which is fed by a dielectric loaded horn array. The elongation loss caused by radiation on a number of polyimide materials is shown.<>
介绍了空间核辐射对微带天线和介电天线所用介质材料的影响。研究表明,核辐射对聚四氟乙烯基材料的主要影响是通过将大的聚合物分子分解成较小的部分而使分子量降低。脆性会增加,而这种反应在有空气的情况下达到最大。聚四氟乙烯受影响的程度基本上是吸收能量量的函数,与辐射的性质无关。给出了电子介质材料的磁化率随总核辐射剂量的函数。范艾伦带的剂量率通常为10拉德/小时。按照这个速度,聚四氟乙烯可以工作五年以上,然后才能在电气和机械上检测到损坏的阈值水平。简要讨论了经空间验证的介质天线,重点介绍了由介质加载喇叭阵列馈电的GTE - GSTAR卫星反射器天线。显示了辐射对许多聚酰亚胺材料造成的伸长率损失。
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引用次数: 3
Evaluation of high temperature capacitor dielectrics 高温电容电介质的评价
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69589
A. Hammoud, I. Myers
Four candidate materials were evaluated for use as high-temperature capacitor dielectrics. The materials investigated were polybenzimidazole polymer and three aramid papers. The samples were characterized with and without heat treatment in terms of their dielectric constant and loss. These properties of the heat-treated samples were also evaluated in a temperature range of 20 to 250 degrees C in the presence of electrical stress of 60 Hz, 50 V/mil. The AC and DC breakdown strengths of both dry and impregnated samples were determined at ambient conditions. The preliminary data indicate that heat treatment of the materials tested improves their dielectric properties and breakdown voltages. The AC and DC dielectric strengths are further improved upon impregnation with a suitable liquid.<>
评估了四种候选材料作为高温电容器介质的使用。所研究的材料是聚苯并咪唑聚合物和三芳纶纸。在介电常数和损耗方面对样品进行了热处理和不热处理的表征。在60 Hz, 50 V/mil的电应力下,在20至250℃的温度范围内对热处理样品的这些性能进行了评估。在环境条件下,测定了干燥和浸渍试样的交流击穿强度和直流击穿强度。初步数据表明,经热处理后的材料的介电性能和击穿电压有所提高。用合适的液体浸渍后,交流和直流介电强度进一步提高。
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引用次数: 13
Oxidation dependence of breakdown strength of XLPE 交联聚乙烯击穿强度的氧化依赖性
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69553
G. Gagnon, S. Pélissou, M. Wertheimer
It has been shown in a previous study (P. Rohl, 1982) that the breakdown strength of polyethylene increases with increasing oxidation levels. The purpose of the research reported here is to verify this somewhat surprising result. Unlike the earlier work, cross-linked polyethylene (XLPE), the principal insulation used in extruded cables, is utilized. The authors correlate dielectric breakdown measurements with oxidation, monitored by Fourier transform infrared (FTIR) spectroscopy, and the results are interpreted using the modified free-volume theory. It is found that the breakdown strength E/sub b/ indeed shows a slight tendency to increase with the oxidation level. In particular, the authors found a correlation between E/sub b/ and the degree of oxidation, expressed in terms of the carbonyl band (1741 cm/sup -1/) absorption. The exact reasons for this behavior are not clear at this time, but appear to be compatible with the modified free-volume theory breakdown.<>
先前的一项研究(P. Rohl, 1982)表明,聚乙烯的击穿强度随着氧化水平的增加而增加。这里报告的研究目的是为了验证这个有点令人惊讶的结果。与早期的工作不同,交联聚乙烯(XLPE)是挤压电缆中使用的主要绝缘材料。作者将介质击穿测量与氧化相关联,通过傅里叶变换红外(FTIR)光谱监测,并使用修正的自由体积理论解释结果。击穿强度E/sub b/随氧化水平的升高有轻微的上升趋势。特别是,作者发现E/sub b/与氧化程度之间存在相关性,以羰基带(1741 cm/sup -1/)吸收来表示。这种行为的确切原因目前还不清楚,但似乎与修改后的自由体积理论的崩溃是一致的
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引用次数: 3
Ferrite-impregnated fibre-glass composites as microwave absorbers 铁氧体浸渍玻璃纤维复合材料作为微波吸收剂
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69580
A. Kumar
The absorption of microwaves in a composite containing a random distribution of iron-oxide particles embedded in fiberglass composites is considered. Generally, iron-oxide particles in the form of spheres or cylinders are held together by a binder such as fiberglass. Since weight and structural integrity of the composite are also of concern in many applications, it is desirable to choose the optimum volume fraction of iron-oxide particles and adjust the shape, size, and distribution of particles to obtain the required mass density and microwave absorbing properties. A short review of mixture theories is given. Results are shown for spherical conducting particles in a pure dielectric host medium and are compared with experimental data. Results (real and imaginary parts of the permittivity and permeability, loss tangent, reflection coefficient, and attenuation per unit length) on iron-oxide impregnated fiberglass composites in the frequency range of 1 to 12 GHz are reported.<>
研究了含随机分布氧化铁颗粒的玻璃纤维复合材料对微波的吸收。一般来说,球状或圆柱形的氧化铁颗粒是由一种粘合剂(如玻璃纤维)粘合在一起的。由于复合材料的重量和结构完整性在许多应用中也受到关注,因此希望选择氧化铁颗粒的最佳体积分数,并调整颗粒的形状、大小和分布,以获得所需的质量密度和微波吸收性能。本文对混合理论作了简要的回顾。给出了纯介电介质中球形导电粒子的计算结果,并与实验数据进行了比较。报道了氧化铁浸渍玻璃纤维复合材料在1 ~ 12 GHz频率范围内的介电常数和磁导率的实部和虚部、损耗正切、反射系数和单位长度衰减。
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引用次数: 1
Influence of wet ageing on the electrical breakdown strength of XLPE cable slices 湿老化对交联聚乙烯电缆片电击穿强度的影响
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69551
C. Chauvet, C. Laurent, C. Mayoux
In order to investigate the consequences of water-induced degradation on the dielectric breakdown field of polyethylene, the authors performed statistical electric breakdown strength measurements on cable slices previously aged in the presence of water. A Weibull analysis is performed on at least 40 sets of breakdown voltage data for each population, leading to a precise determination of the nominal breakdown field E/sub 0/. Comparison is made as a function of ageing time and testing conditions. Wet ageing under conditions of water tree development affects the breakdown strength of XLPE (cross-linked polyethylene) cable slices. The presence of water trees in the insulation must therefore be considered as potentially harmful.<>
为了研究水诱导降解对聚乙烯介电击穿场的影响,作者对先前在存在水的情况下老化的电缆片进行了统计电击穿强度测量。威布尔分析对每个群体至少40组击穿电压数据进行了分析,从而精确确定了标称击穿场E/sub 0/。比较了老化时间和试验条件的函数关系。水树发育条件下的湿老化影响交联聚乙烯电缆片的击穿强度。因此,绝缘材料中存在的水柱必须被认为是潜在的有害物质。
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引用次数: 3
Dielectric strength of crosslinked polyethylene: the effects of the volatile products of the crosslinking reaction 交联聚乙烯的介电强度:交联反应挥发产物的影响
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69590
Y. Shao, K. Sheu, D. Damon, S. Huang, J.F. Johnson
The breakdown field strength of recessed samples of XLPE (cross-linked polyethylene) containing varying amounts of acetophenone and cumene is shown to decrease with increasing sample thickness. This thickness dependence is more complicated than previously observed. The addition of small amounts of acetophenone to XLPE produces a small increase in the dielectric strength. Small concentrations of cumene have no effect. Results from both AC ramp to failure and impulse breakdown can be fit to Weibull distributions. The characteristic values obtained from ramp to failure measurements depend on the ramp rate as suggested by theory.<>
含有不同量的苯乙酮和异丙烯的交联聚乙烯(XLPE)凹模的击穿场强随着样品厚度的增加而减小。这种厚度依赖性比以前观察到的更为复杂。在交联聚乙烯中加入少量的苯乙酮可使其介电强度略有提高。小浓度的异丙苯没有影响。交流斜坡失效和脉冲击穿的结果都符合威布尔分布。从斜坡到失效测量得到的特征值取决于理论建议的斜坡速率。
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引用次数: 6
Comments on the definition of AC capacitance in ASTM-D150-81 对ASTM-D150-81交流电容定义的评析
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69579
S.L. Wang
The definition of capacitance in ASTM D150-81 is improved by considering the definition of complex capacitance. It is concluded that since the practical capacitor always has losses, it can be suitably represented by complex capacitance. The complex capacitance is closely related to relative complex permittivity, so that the concept of complex capacitance is very important in technology, and an accurate definition of complex capacitance is necessary for electrical engineering.<>
通过考虑复电容的定义,对ASTM D150-81中电容的定义进行了改进。结果表明,由于实际电容器存在损耗,用复电容来表示损耗是比较合适的。复电容与相对复介电常数密切相关,因此复电容的概念在技术上非常重要,对复电容的精确定义在电气工程中是必要的。
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引用次数: 2
期刊
Conference on Electrical Insulation and Dielectric Phenomena,
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