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Transient voltage and injection in insulators 绝缘子的瞬态电压和注入
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69567
R. Coelho, L. Levy, D. Sarrail
The authors discuss 'local' models applicable to thin samples in which the injected charge density exceeds the intrinsic one. Experimental results are presented on such 'electrically inhomogeneous' samples. The experiment was performed on a Kapton sample in a space simulation chamber. The constant mobility hypothesis is valid provided that the initial field across the sample does not exceed some critical value. Comparison of the decay curves for bulk and surface charges permits an evaluation of the injection coefficient and its evolution. This in turn may help to improve the understanding of injection processes in dielectric materials, and to assess the effects of surface treatments.<>
作者讨论了适用于注入电荷密度超过本征电荷密度的薄样品的“局部”模型。在这种“电不均匀”样品上给出了实验结果。实验是在空间模拟室内对卡普顿样品进行的。如果样品的初始场不超过某个临界值,则恒定迁移率假设是有效的。通过比较体积电荷和表面电荷的衰减曲线,可以对注入系数及其演化进行评估。这反过来可能有助于提高对介电材料注入过程的理解,并评估表面处理的影响
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引用次数: 0
Charge buildup in polypropylene irradiated with monoenergetic electron beams 单能电子束辐照聚丙烯中的电荷积聚
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69547
H. Ding, G. Sessler
Charge buildup in 30- mu m-thick films of polypropylene irradiated with monoenergetic electron beams of 10-45-keV energy is investigated. Using the split-Faraday cup, the mean charge depths at the beginning of electron injection, at the termination of injection, and 10 minutes after injection are measured. It is found that the depth increases with time during and after charging and depends on the 1.7th power of the electron energy. The depth increases also with the amount of injected charge. From the dynamics of charge motion during irradiation, the tradition-induced conductivity is determined a function of dose rate. It amounts to approximately 10/sup -14/ ( Omega .cm)/sup -1/ at 10/sup 4/ rad/s and is thus about an order of magnitude smaller than in Teflon.<>
研究了10- 45kev单能电子束辐照30 μ m厚聚丙烯薄膜的电荷形成。利用劈裂法拉第杯,测量了电子注入开始时、注入结束时和注入后10分钟的平均电荷深度。研究发现,在充电过程中和充电后,深度随时间的增加而增加,并取决于电子能量的1.7次方。深度也随着注入药量的增加而增加。根据辐照过程中电荷运动的动力学,确定了传统诱导电导率是剂量率的函数。在10/sup 4/ rad/s时,它的大小约为10/sup -14/ (Omega .cm)/sup -1/,因此比聚四氟乙烯小一个数量级
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引用次数: 4
The high field conductivity in organosilicon plasma polymers 有机硅等离子体聚合物的高场导电性
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69561
P. Kazimierski, M. Kryszewski, J. Tyczkowski
The electrical conductivity by electron hopping in the case of high electric fields is discussed with special attention to the Poole-Frenkel generation mechanism. Computer simulations of charge carriers tunneling between different kinds of localized states are presented. The model consequence is the existence of the exp(F/F/sub 0/) term in high-field direct current. These theoretical results are supported by measurements of current versus voltage characteristics for thin films of plasma polymers obtained by glow discharge in vapors of different organosilicon monomers. The present model also implies the existence of temperature-independent direct current in the case of sufficiently high electric fields.<>
讨论了高电场条件下电子跳变的电导率,重点讨论了普尔-弗伦克尔的产生机理。给出了不同局域态间载流子隧穿的计算机模拟。模型的结果是在高场直流电中存在exp(F/F/sub 0/)项。通过在不同有机硅单体的蒸汽中发光放电获得的等离子体聚合物薄膜的电流与电压特性的测量支持了这些理论结果。本模型还表明,在足够高的电场条件下,存在与温度无关的直流电。
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引用次数: 0
Effect of dissolved water on electrical conduction in liquid dielectrics 溶解水对液体介质导电性的影响
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69571
A. Ebe, N. Iijima, M. Sone, H. Mitsui
The state of water in liquid dielectric was analyzed by Fourier transform infrared spectroscopy during a conduction test. The liquid dielectric used was di-octyl-phthalate (DOP) with different proportions of water. The free water in DOP is shown to contribute to the conduction. The states of the free water or weakly bound water are shown to change under stress.<>
利用傅里叶变换红外光谱分析了电介质中水的导电状态。所使用的液体介质为邻苯二甲酸二辛酯(DOP)和不同比例的水。DOP中的自由水有助于导电。在应力作用下,自由水或弱结合水的状态会发生变化。
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引用次数: 1
DC discharge phenomena in artificial air for an undersea habitat 海底生境人工空气中的直流放电现象
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69535
K. Kokari, N. Sugawara, Y. Kaneko, H. Tagashira
The electrical discharge characteristics of mixtures of helium and oxygen having a constant oxygen partial pressure were investigated to evaluate the safety of electric systems used in an undersea habitat. A comparison is made with the discharge characteristics of air. The spark breakdown voltage of the mixtures of helium and oxygen is at least 1.3 times higher than that of dry air throughout the pressure range studied (from 0.4 to 4.91 MPa). The minimum corona onset voltage was lower at pressures up to about 1.3 MPa than that of dry air. It was confirmed that at pressure higher than 1.3 MPa, it is possible to use even the usual electrical equipment in the mixture of helium and oxygen prevalent in an undersea habitat. It is noted that the spark breakdown voltage for the mixture of helium and oxygen has a plateau in the pressure range from 0.8 to 2 MPa.
研究了在一定氧分压条件下氦气和氧气混合物的放电特性,以评价海底栖息地电气系统的安全性。并与空气的放电特性进行了比较。在研究的整个压力范围内(从0.4到4.91 MPa),氦气和氧气混合物的火花击穿电压至少是干燥空气的1.3倍。在1.3 MPa左右的压力下,最小电晕起始电压比干燥空气低。经证实,在高于1.3兆帕的压力下,在海底栖息地普遍存在的氦气和氧气混合物中,甚至可以使用通常的电气设备。注意到氦氧混合物的火花击穿电压在0.8 ~ 2mpa的压力范围内有一个平台。
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引用次数: 0
Partial discharge characteristics of gas impregnated polymeric insulation systems 气体浸渍聚合物绝缘系统的局部放电特性
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69533
G. Letha, A. Venkatasami, T. Govindan
Experimental investigations conducted on a large number of experimental model samples made with polypropylene film and impregnated with SF/sub 6/ are reported. Samples and experiments were designed to identify and highlight the effects of critical factors, such as electrode material and configuration, winding tension, gas filling pressure, and impregnation cycle, on the partial-discharge behavior of the samples. It is noted that the results could serve as useful design data for the design of SF/sub 6/-filled high-voltage equipment using polypropylene film in particular and any plastic film in general.<>
本文报道了大量聚丙烯膜浸渍SF/sub - 6/的实验模型试样的实验研究。设计了样品和实验,以确定和突出电极材料和配置、缠绕张力、充气压力和浸渍周期等关键因素对样品部分放电行为的影响。本文的研究结果可以作为设计SF/sub - 6/填充高压设备的有用数据,特别是使用聚丙烯薄膜和任何塑料薄膜。
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引用次数: 0
Gamma irradiation effects in two epoxy resins and a polyimide 两种环氧树脂和一种聚酰亚胺的辐照效应
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69546
R. Fouracre, H. M. Banford, D. Tedford, W. Huiming, X. Cao
Changes in the electrical properties of insulators exposed to high levels of ionizing radiation can have a significant effect on the lifetime of equipment incorporating such material. In order to obtain a knowledge of the processes involved, a series of experiments were undertaken on the effects of gamma irradiation, at dose levels up to a few megagrays (MGy), on the DC conductivity and the thermally stimulated discharge current (TSDC) spectra of two epoxy resin samples and a polyimide. Among other findings it is shown that the curves for DC conductivity can be used to measure the glass transition temperature T/sub G/. Initial differential scanning calorimetry measurements had shown that the T/sub G/ of the as-produced resin was 189 degrees C. Irradiation to 1 MGy reduced this value to 90 degrees C, and this was little changed by annealing. The activation energy below T/sub G/ decreased as a sequence of irradiation, but increased after annealing of the sample. Comparison with the TSDC spectra shows that the T/sub G/ of the system is lowered by the irradiation process, and it has also been shown that annealing increases the T/sub G/, although at this dose level it does not return to its original value. Measurements on polyimide indicate that there is a change in conduction mechanism after irradiation.<>
暴露在高水平电离辐射下的绝缘体的电气特性的变化会对采用这种材料的设备的寿命产生重大影响。为了了解所涉及的过程,进行了一系列实验,研究了高达几兆射线(MGy)剂量水平的伽马辐照对两种环氧树脂样品和聚酰亚胺的直流电导率和热激放电电流(TSDC)光谱的影响。结果表明,直流电导率曲线可用于测量玻璃化转变温度T/sub G/。最初的差示扫描量热法测量表明,生产的树脂的T/sub G/为189℃,辐照至1 MGy将该值降至90℃,退火后变化不大。T/sub G/以下的活化能随辐照次数的增加而减小,退火后的活化能增加。与TSDC光谱的比较表明,辐照过程降低了系统的T/sub G/,退火也增加了系统的T/sub G/,但在该剂量水平下并没有恢复到原来的值。对聚酰亚胺的测量表明,辐照后其传导机制发生了变化。
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引用次数: 0
Theoretical analysis for rapid thermal endurance methods of insulating materials 绝缘材料快速热耐久方法的理论分析
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69543
Z. Yingsuo, Bai Yi
The authors show by analysis and examples that the rapid thermal endurance testing methods of insulating materials are all approximate and simulations, in spite of the fact that some seem to have a strictly mathematical derivation or theoretical demonstration. It is suggested that the merits of the rapid methods should be evaluated by comparing test results with conventional aging.<>
作者通过分析和实例表明,尽管有些方法似乎有严格的数学推导或理论论证,但绝缘材料的快速热耐久性测试方法都是近似和模拟的。建议通过与常规老化试验结果的比较来评价快速老化方法的优劣
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引用次数: 2
Influence of paper insulation on acceptable gas-in-oil levels in transformers 纸绝缘对变压器可接受油中气体含量的影响
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69572
M. Duval, F. Langdeau, P. Gervais, G. Bélanger
The influence of cellulose on acceptable gas-in-oil levels in high-voltage transformers as indicated by the value of the CO/sub 2//CO ratio is assessed by means of dissolved-gas analysis. The results presented here are based on 6932 gas-in-oil analyses on 1320 Hydro-Quebec transformers over a period of 20 years. Preliminary results indicate that C/sub 2/H/sub 4/ levels are affected by cellulose participation for both arcing and hot spots. The effect can be felt starting from CO/sub 2//CO ratios <6 for arcing and <2 for hot spots. These results suggest that the acceptable and dangerous levels of dissolved C/sub 2/H/sub 4/ in power transformers must be greatly reduced as the CO/sub 2//CO ratio in the oil decreases.<>
用溶解气体分析的方法评估了纤维素对高压变压器中可接受的油中气体含量的影响,该影响由CO/sub - 2//CO比值值表示。本文给出的结果是基于对1320台魁北克水电变压器在20年间进行的6932次油中气分析。初步结果表明,C/sub - 2/H/sub - 4/水平受纤维素参与弧区和热点的影响。从CO/ sub2 //CO比值开始可以感受到这种影响。
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引用次数: 13
Electrical conduction phenomena of oil/polymer systems 油/聚合物体系的导电现象
Pub Date : 1989-10-29 DOI: 10.1109/CEIDP.1989.69570
S. Ochiai, H. Iwasaki, T. Mizutani, M. Ieda
Oil-polymer interactions were investigated using various combinations of polymer and oil. The current magnitudes in oil-polymer systems were in the following order: LDPE>HDPE>PP>PET>>FEP. These results are discussed, considering the solubility parameter (SP), the crystallinity of the polymer, and impurities in the polymer. It was found that the magnitude of the charging current in oil-polymer systems cannot be explained by the SP value alone. It is affected by impurities in the polymer (including antioxidant) close to the oil-polymer interface. Antioxidant is extracted from the polymer during sulfuric acid treatment. The treatment of sulfuric acid reduces the current and changes the TSC (thermally stimulated current) spectrum.<>
采用不同的聚合物和油的组合研究了油-聚合物的相互作用。目前在油-聚合物体系中的含量为:LDPE>HDPE>PP>PET> FEP。考虑到溶解度参数(SP)、聚合物的结晶度和聚合物中的杂质,对这些结果进行了讨论。发现油聚合物体系中充电电流的大小不能仅用SP值来解释。它受靠近油-聚合物界面的聚合物中杂质(包括抗氧化剂)的影响。在硫酸处理过程中从聚合物中提取抗氧化剂。硫酸的处理降低了电流并改变了TSC(热激电流)谱。
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Conference on Electrical Insulation and Dielectric Phenomena,
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