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Rupture of a Carbon Steel Tube Because of Hydrogen-Induced Cracking and Decarburization 碳素钢管因氢致开裂和脱碳而破裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0048309
A 75 mm OD x 7.4 mm wall thickness carbon steel boiler tube ruptured. A substantial degree of corrosion on the water-side surface leaving a rough area in the immediate vicinity of the rupture was revealed by visual examination. Decarburization and extensive discontinuous intergranular cracking was revealed by microscopic examination of a cross section through the tube wall at the fracture. It was concluded that the rupture occurred because of hydrogen damage involving the formation of methane by the reaction of dissolved hydrogen with carbon in the steel. Hydrogen was produced by the chemical reaction that corroded the internal tube surface. Steel embrittled by hydrogen can be restored only if grain boundary cracking or decarburization had not occurred but since the material embrittled in this manner, its replacement was recommended.
75mm外径× 7.4 mm壁厚的碳钢锅炉管破裂。通过目测发现,在靠近破裂处的水面上有相当程度的腐蚀,留下了一个粗糙的区域。断口处管壁断面的显微检查显示脱碳和广泛的不连续晶间裂纹。结果表明,钢中溶解的氢与碳反应生成甲烷是氢损伤所致。氢气是由腐蚀管内表面的化学反应产生的。氢脆的钢只有在晶界开裂或脱碳没有发生的情况下才能恢复,但由于材料以这种方式脆化,建议更换。
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引用次数: 0
Fractured Turbine Blades 涡轮叶片断裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001228
F. Naumann, F. Spies
In an electric power station, seven turbine blades out of 112 broke or cracked within 8 to 14 months after commencement of operation. The blades in question were all located on the last running wheel in the low pressure section of a 35,000 kW high pressure condensing turbine. They were milled blades without binding wires and cover band. They did not fracture at the fastening, i.e. the location of highest bending stress, but in a central region which was 165 to 225 mm away from the gripped end. The blades were fabricated from a stainless heat-treatable chromium steel containing 0.2C and 13.9Cr. Microstructural examination showed the blades were destroyed by flexural vibrations which evidently reached their maximum amplitude at the location of fracture. Erosion of the inlet edge, possibly in connection with vibration-induced corrosion cracking, contributed to fracture.
在某电站,112个涡轮机叶片中有7个在开始运行后的8至14个月内破裂或破裂。这些叶片都位于35000千瓦高压冷凝汽轮机低压段的最后一个运转轮上。它们是磨碎的刀片,没有绑扎线和盖带。它们没有在紧固处断裂,即最高弯曲应力的位置,而是在距离夹紧端165至225毫米的中心区域断裂。叶片由含0.2C和13.9Cr的不锈钢热处理铬钢制成。显微组织检查表明叶片受弯曲振动破坏,弯曲振动在断口处明显达到最大振幅。入口边缘的侵蚀,可能与振动引起的腐蚀开裂有关,导致了断裂。
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引用次数: 0
The Identification of the Origins of Some Deposits in a Steam Turbine 某汽轮机中某些沉积物成因的鉴定
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001658
J. Thornley, J. K. Sutherland
The intermediate pressure (IP) turbine of a thermal generating station is driven by steam from the boiler's reheater. On one particular IP turbine, a thick deposit was found on the insides of the rotor blade shrouds in two instances two years apart. The source of the deposits was not known; bulk chemical analysis had simply shown that iron was a major component. Optical microscopy and electron microprobe analysis were used to identify the deposits. In the first instance, the deposit was found to be debris that was left in the reheater tubes during boiler modification and swept to the turbine by the steam. There were still some of these debris particles present when the incident two years later was investigated but generally the second deposit was found to be of two layer oxide particles which were shown to have spalled from 2-14% chromium reheater tube surfaces.
火力发电厂的中压汽轮机是由锅炉再热器的蒸汽驱动的。在一个特定的IP涡轮上,在相隔两年的两个实例中,在转子叶片罩的内部发现了厚沉积物。矿床的来源尚不清楚;大量化学分析只是表明铁是主要成分。利用光学显微镜和电子探针对矿床进行了鉴定。在第一个例子中,沉积物被发现是在锅炉改造期间留在再加热管中的碎片,并被蒸汽扫到涡轮机上。当两年后对事故进行调查时,仍然有一些碎片颗粒存在,但通常发现第二层沉积物是两层氧化颗粒,显示从2-14%铬的再热器管表面脱落。
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引用次数: 0
Failure of a Steel Superheater Tube 钢过热器管失效
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0091028
Failure occurred in a steel superheater tube in a power plant. The tube was specified as ASTM A 213 grade T 22, and the reported operating conditions were 13 MPa (1900 psi) at 482 deg C (900 deg F). The tube carried superheated steam and was coal fired. Investigation (visual inspection, 2% nital etched 297x images, chemical analysis, and SEM fractographs) supported the conclusion that the superheater tube failed as a result of long-term overheating. Substantial creep damage reduced the strength of the tube to the point that overload failure occurred. No recommendations were made.
某电厂钢过热器管发生故障。该管被指定为ASTM A 213等级t22,报告的工作条件为13 MPa (1900 psi),温度为482摄氏度(900华氏度)。该管携带过热蒸汽并以煤为燃料。调查(目视检查,2%初始蚀刻297x图像,化学分析和SEM断口图)支持过热器管由于长期过热而失效的结论。大量的蠕变损伤使钢管的强度降低到发生过载失效的程度。没有提出任何建议。
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引用次数: 0
Corrosion of Copper Cooling-Water Tubing in a Heat Exchanger 换热器中铜冷却水管的腐蚀
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001700
A.H. Khan
A straight-tube cooler type heat exchanger had been in service for about ten years serving a coal pulverizer in Georgia. Non-potable cooling water from a local lake passed through the inner surfaces of the copper tubing and was cooling the hot oil that surrounded the outer diametral surfaces. Several of the heat exchangers used in the same application at the plant had experienced a severe reduction in efficiency in the past few years. One heat exchanger reportedly experienced some form of leakage following discovery of oil contaminating the cooling water. This heat exchanger was the subject of a failure investigation to determine the cause and location of the leaks. Corrosion products primarily contained copper oxide, as would be expected from a copper tubing. The product also exhibited the presence of a significant amount of iron oxides. Metallographic cross sectioning of the tubes and microscopic analysis revealed several large and small well rounded corrosion pits present at the inner diametral surfaces. The cause of corrosion was attributed to corrosive waters that were not only corroding the copper, but were corroding steel pipes upstream from the tubing.
一种直管冷却器式热交换器已经在乔治亚州的一个煤粉厂服役了大约十年。来自当地湖泊的非饮用冷却水穿过铜管的内表面,冷却围绕在外径表面的热油。在过去几年中,该厂同一应用中使用的几个热交换器的效率严重下降。据报道,在发现油污染冷却水后,一个热交换器出现了某种形式的泄漏。该热交换器是故障调查的对象,以确定泄漏的原因和位置。腐蚀产物主要含有氧化铜,就像铜管一样。该产品还显示出大量氧化铁的存在。管材的金相断面和显微分析显示,在管材的内径表面有几个大小不一的圆形腐蚀坑。腐蚀的原因是腐蚀性水不仅腐蚀了铜,而且腐蚀了管道上游的钢管。
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引用次数: 0
Evaluation of Gas Turbine Hot Section Blade Cracking under Oxidation, TMF, and Creep Conditions 氧化、TMF和蠕变条件下燃气轮机热段叶片开裂的评价
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0090114
The first-stage blades in a model 501D5 gas turbine had 16 cooling holes. After 32,000 h of service, the blades exhibited cracking at the cooling holes. The blade material was wrought Udimet 520 alloy, with nominal composition of 57Ni-19Cr-12Co-6Mo-1W-2Al-3Ti-0.05C-0.005B. The cooling holes' surface was not coated. Investigation supported the conclusions that the cracking at the cooling holes was due to grain-boundary oxidation and nitridation at the cooling hole surface, embrittlement and loss of local ductility of the base alloy, temperature gradient from the airfoil surface to the cooling holes, which led to relatively high thermal stresses at the holes located at the thicker sections of the airfoil, and stress concentration of 2.5 at the cooling hole and the presence of relatively high total strain (an inelastic strain of 1.2%) at the cooling hole surface. Recommendations include applying the specially designed methods given in this case study to estimate the metal temperature and stresses in order to predict the life of turbine blades under similar operating conditions.
501D5型燃气轮机的第一级叶片有16个冷却孔。在使用32,000 h后,叶片在冷却孔处出现裂纹。叶片材料为Udimet 520合金,公称成分为57Ni-19Cr-12Co-6Mo-1W-2Al-3Ti-0.05C-0.005B。冷却孔表面未涂覆。研究结果表明,冷却孔开裂是由于冷却孔表面晶界氧化和氮化、基体合金的脆化和局部延性丧失、翼型表面到冷却孔的温度梯度导致翼型较厚截面孔处的热应力相对较高所致。冷却孔处应力集中为2.5,冷却孔表面存在较高的总应变(非弹性应变为1.2%)。建议包括应用本案例研究中给出的特别设计的方法来估计金属温度和应力,以便预测涡轮叶片在类似操作条件下的寿命。
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引用次数: 0
Failure Analysis of a Large Centrifugal Blower 大型离心鼓风机的失效分析
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001136
R. Tait, G. Garrett, D. P. Spencer
A fracture mechanics based failure analysis and life prediction of a large centrifugal fan made from low-carbon, medium-strength steel was undertaken following shortcomings in attempts to explain its fatigue life from start stop cycles alone. Measurements of the fracture toughness and flaw size at failure, coupled with quantitative SEM fractography using striation spacing methods, revealed that the cyclic stress amplitudes just prior to failure were much larger than expected, in this particular case. Subsequent improvements in fan design and fabrication have effectively alleviated the problem of slow, high cycle fatigue crack growth, at normal operating stresses in similar fans.
针对单从启停循环来解释大型离心风机疲劳寿命存在的缺陷,对低碳中等强度钢离心风机进行了基于断裂力学的失效分析和寿命预测。对断裂韧性和破裂时缺陷尺寸的测量,加上使用条纹间距方法的定量SEM断口分析,表明在这种特殊情况下,破裂前的循环应力幅值比预期的要大得多。风扇设计和制造的后续改进有效地缓解了类似风扇在正常工作应力下缓慢,高周疲劳裂纹扩展的问题。
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引用次数: 0
Cracking in a Steam Generator U-Tube 蒸汽发生器u形管开裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0090277
A rupture of a thirty-year-old U-tube on a steam generator for a closed-cycle pressurized-water nuclear power plant occurred, resulting in limited release of reactor water. A typical tube bundle can be over 9 m (30 ft) tall and 3 m (10 ft) in diam with over 3,000 22-mm (7/8-in.) diam Inconel Alloy 600 tubes. Tube support plates (TSP) separate the tubes and allow flow of the heating water/steam. Inconel Alloy 600 is susceptible to intergranular stress-corrosion cracking over time, so investigation included review of operational records, maintenance history, and procedures. It also included FEA (thermal gradients, nonlinear material behavior, residual stress, changes in wall thickness during the formation of U-bends, and TSP distortions near the ruptured tube) of three-dimensional solid models of the U-tubes. The conclusion was that distortion of the TSPs and resulting “pinching” of the U-tubes, combined with the operational stresses, caused high stresses at the location where the tube cracked. The stresses were consistent with those required to initiate and propagate a longitudinal crack.
一座闭式循环压水核电站蒸汽发生器上一根使用了30年的u型管发生破裂,导致反应堆水有限释放。一个典型的管束可以超过9米(30英尺)高,直径3米(10英尺),有超过3000根22毫米(7/8英寸)直径的Inconel Alloy 600管。管道支撑板(TSP)将管道分开,并允许加热水/蒸汽流动。随着时间的推移,Inconel Alloy 600容易发生晶间应力腐蚀开裂,因此调查包括审查操作记录、维护历史和程序。并对u型管三维实体模型进行了有限元分析(热梯度、非线性材料行为、残余应力、u型弯形成过程中壁厚的变化以及破裂管附近的TSP变形)。结论是,tsp的扭曲和由此导致的u型管的“挤压”,再加上操作应力,在管破裂的位置造成了高应力。应力与启动和扩展纵向裂纹所需的应力一致。
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引用次数: 0
Failure of Gas Turbine Last- Stage Bucket 燃气轮机末级斗失效
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0091761
Turbine buckets in a 37.5-MW gas turbine made of Udimet 500 superalloy failed in service. The power plant was located 1 km (0.6 miles) from the Pacific Ocean and operated on No. 2 diesel fuel, which was supplied by tanker ship. Turbine bucket failures occurred on three units after 2500 to 6400 h of operation. Investigation (visual inspection, metallographic examination, and stress analysis) supported the conclusion that the differing microstructure of the airfoil resulted in changes in mechanical properties. Because normal operation includes cycling of loads and temperatures, the shroud tip fractured due to thermomechanical fatigue in its degraded state. Recommendations included special chromium or silicon-rich coating to minimize corrosion in gas turbines operating in a marine environment with operating temperatures in the range of type 2 corrosion (650 to 750 deg C, or 1200 to 1380 deg F). Additionally, it was suggested that fuel delivery, handling, and treatment be high quality, to maintain fuel contamination within design limits, and inlet air filtration must be designed for the coastal site. Also, changing the bucket tip by increasing its thickness and changing the casting technique would reduce the stress and make the design more tolerant of corrosion.
由Udimet 500高温合金制成的37.5 mw燃气轮机的涡轮桶在使用中失败。该发电厂位于距离太平洋1公里(0.6英里)处,使用2号柴油燃料,由油轮供应。运行2500 ~ 6400小时后,有3台机组出现透平斗故障。调查(目视检查,金相检查,和应力分析)支持的结论,不同的微观结构的翼型导致在机械性能的变化。由于正常的操作包括载荷和温度的循环,在其退化状态下,由于热机械疲劳而导致叶冠尖端断裂。建议包括特殊的铬或富硅涂层,以尽量减少在海洋环境中运行的燃气轮机的腐蚀,工作温度在2型腐蚀范围内(650至750摄氏度,或1200至1380华氏度)。此外,建议燃料输送,处理和处理要高质量,以保持燃料污染在设计范围内,并且必须为沿海站点设计进口空气过滤。此外,通过增加桶尖的厚度和改变铸造技术来改变桶尖,可以减少应力,使设计更耐腐蚀。
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引用次数: 0
A Case of Caustic Cracking at a Tube Expansion 膨胀管腐蚀开裂一例
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001406
Caustic cracking is the term used to describe one of the forms in which stress-corrosion cracking manifests itself in carbon steels. In the present study, persistent leakage occurred after ten weeks of service from tube expansions in the steam and mud drum of a two-drum D type boiler, which failed to respond to repeated expansion. The leakage was traced to circumferential cracking in the portion of Fe-0.11C-0.46Mn-0.018S-0.011P tubes within the expanded region. Microscopic examination indicated that all cracks started from the outer surface of the tubes in the expanded portion. The form of cracking which was mostly intergranular. Examination at higher magnification disclosed that a selective attack had taken place on the carbide constituents of the pearlite grains. An alkaline deposit on the fireside surface of the tube resulted from the evaporation of boiler water which had found its way past the tube expansions. This indicated that this operation had not resulted in a satisfactorily tight joint.
苛性碱开裂是用来描述应力腐蚀开裂在碳钢中表现出来的一种形式的术语。在本研究中,双筒D型锅炉的蒸汽和泥浆筒管膨胀,在使用十周后发生持续泄漏,对反复膨胀没有反应。泄漏的原因是膨胀区域内Fe-0.11C-0.46Mn-0.018S-0.011P管的圆周开裂。显微检查表明,所有裂纹都是从膨胀部分的管的外表面开始的。裂纹形式多为晶间裂纹。在高倍镜下观察发现,珠光体晶粒的碳化物成分发生了选择性攻击。炉管的炉边表面上有一种碱性沉积物,这是由于锅炉水的蒸发,这些水已经通过了管道的膨胀。这表明该手术并没有产生令人满意的紧密关节。
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引用次数: 0
期刊
ASM Failure Analysis Case Histories: Power Generating Equipment
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