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Stress-Corrosion Cracking of a Nuclear Steam-Generator Vessel at Low Concentrations of Chloride Ion 核蒸汽发生器容器在低浓度氯离子下的应力腐蚀开裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0048814
A nuclear steam-generator vessel constructed of 100-mm thick SA302, grade B, steel was found to have a small leak. The leak originated in the circumferential closure weld joining the transition cone to the upper shell. The welds had been fabricated from the outside by the submerged arc process with a backing strip. The backing was back gouged off, and the weld was completed from the inside with E8018-C3 electrodes by the shielded metal arc process. Striations of the type normally associated with progressive or fatigue-type failures including beach marks that allowed tracing the origin of the fracture to the pits on the inner surface of the vessel were revealed. Copper deposits with zinc were revealed by EDS examination of discolorations. Pitting was revealed to have been caused by poor oxygen control in the steam generators and release of chloride into the steam generators. It was concluded by series of controlled crack-propagation-rate stress-corrosion tests that A302, grade B, steel was susceptible to transgranular stress-corrosion attack in constant extension rate testing with as low as 1 ppm chloride present. It was recommended to maintain the coolant environment low in oxygen and chloride. Copper ions in solution should be eliminated or minimized.
一艘核蒸汽发生器容器由100毫米厚的SA302 B级钢建造,发现有小泄漏。泄漏源自连接过渡锥与上壳体的周向封闭焊缝。焊缝采用埋弧焊法从外部制造,并附有衬条。背衬被凿掉,用E8018-C3电极通过屏蔽金属电弧工艺从内部完成焊接。通常与进行性或疲劳型故障相关的条纹,包括沙滩痕迹,可以追溯到断裂的起源,直到船内表面的凹坑。用能谱分析发现了含锌铜矿床的变色。发现点蚀是由于蒸汽发生器中的氧气控制不良和氯化物释放到蒸汽发生器中造成的。通过一系列控制裂纹扩展速率的应力腐蚀试验得出结论:在低至1ppm氯化物的恒扩展速率试验中,A302 B级钢易发生穿晶应力腐蚀。建议保持低氧和低氯化物的冷却剂环境。应消除或尽量减少溶液中的铜离子。
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引用次数: 0
Weld Cracking in Boiler Tubes Caused by Molten Copper Penetration 熔铜渗透引起的锅炉管焊缝开裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001482
Penetration by molten copper occurred in the economizer of a large water-tube boiler. A cross section through a weld and the crack in the tube revealed a crack was an intergranular fissure. Small fissures of the same type also extended from its flanks. The main fissure was filled with an oxide scale in which were embedded particles having the appearance of metallic copper. It was concluded that the cracking that occurred at the time of re-welding was due to intergranular penetration by copper present in the deposit within the tubes, which had not been completely removed prior to welding. Subsequently, it was ascertained that trouble had been experienced with the centrifugal feed pumps, resulting in scuffing of some bronze rings. The presumption is that bronze particles had been carried in mechanical suspension in the feed water and deposited in the economizer tubes.
某大型水管锅炉省煤器发生熔铜侵彻现象。通过焊缝和管内裂纹的横截面显示,裂纹为晶间裂纹。同样类型的小裂缝也从它的侧面延伸出来。主要的裂缝充满了氧化层,其中嵌入了金属铜外观的颗粒。结果表明,在重焊时发生的裂纹是由于焊前未完全清除的铜在管内沉积的晶间渗透造成的。随后,确定离心给水泵出现了故障,导致一些青铜环磨损。假设青铜颗粒以机械悬浮的方式携带在给水中,并沉积在省煤器管中。
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引用次数: 0
Failure Analysis of Superheater Outlet Header 过热器出口集管失效分析
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001526
H. Thielsch, R. Smoske, F. J. Cone, J. Husband
In Nov. 1998, the west superheater outlet header at an electricity generating plant began to leak steam. Subsequent investigation revealed the presence of a crack that extended for 360 deg around the full circumference of the header and through the full cross-sectional thickness. The subsequent inspection of this header and the east superheater header revealed the presence of extremely severe ligament cracking. They operated at 2400 psi (16.5 MPa) and a temperature of 540deg C (1005 deg F). Both were fabricated from seamless pipe produced in accordance with ASME Specification SA-335, and the steel was Grade P22, a 2.25Cr-1Mo alloy steel. Visual and metallurgical evaluations showed the cracking in the west superheater outlet header was caused by thermal fatigue. Tube holes had served as a preferential site for thermal fatigue cracking.
1998年11月,某发电厂的西部过热器出口集管开始泄漏蒸汽。随后的调查显示,存在一个360度的裂缝,该裂缝围绕着头部的整个周长和整个横截面厚度。随后对这个头部和东面过热器头部的检查显示存在极其严重的韧带断裂。它们的工作压力为2400psi (16.5 MPa),温度为540摄氏度(1005华氏度)。它们都是由符合ASME规范SA-335的无缝管制成的,钢为P22级,一种2.25Cr-1Mo合金钢。目视和金相评价表明,西过热器出口集箱开裂是由热疲劳引起的。管孔是热疲劳开裂的首选部位。
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引用次数: 1
Stress Corrosion Cracking of Expansion Bellows of Steam Main 蒸汽总管膨胀波纹管的应力腐蚀开裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001398
Several articulated bellows of 10 in. ID developed leakage from the convolutions after a service life of some 18 months. One of the units received from examination showed cracking at the crown of a convolution and at the attachment weld to the pipe. Sectioning of the bellows revealed many others cracks on the internal surface which did not penetrate to the outside. Microscopical examination showed multiple intergranular, tree-like cracking typical of stress-corrosion cracking. Concentration of sodium hydroxide occurred in the bellows unit and the stress-corrosion cracking which developed was of the form known as caustic cracking. It was recommended that water for de-superheater use should be taken after the deaerator and prior to the addition of salts which may deposit or concentrate in the desuperheater.
几个10英寸铰接风箱。在大约18个月的使用寿命后,ID出现了卷曲泄漏。从检查中收到的一个单元显示,在卷积的顶部和管道的连接焊缝处存在裂纹。对风箱的切片显示,内部表面有许多其他的裂缝,这些裂缝没有渗透到外部。显微检查显示多重晶间、树状裂纹,为典型的应力腐蚀裂纹。在波纹管装置中产生了高浓度的氢氧化钠,由此产生的应力腐蚀开裂形式为苛性碱开裂。建议在除氧器之后,在添加可能沉积或集中在除氧器中的盐之前,取用于除氧器的水。
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引用次数: 0
Intergranular Fracture of Steam Generator Tubes 蒸汽发生器管的晶间断裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0090881
A power plant using two steam generators (vertical U-tube and shell heat exchangers, approximately 21 m (68 ft) high with a steam drum diameter of 6 m (20 ft)) experienced a steam generator tube rupture. Each steam generator contained 11,012 Inconel alloy 600 (nickel-base alloy) tubes measuring 19 mm OD, nominal wall thickness of 1.0 mm (0.042 in.), and average length of 18 m (57.75 ft). The original operating temperature of the reactor coolant was 328 deg C (621 deg F). A tube removal effort was conducted following the tube rupture event. Investigation (visual inspection, SEM fractographs, and micrographs) showed evidence of IGSCC initiating at the OD and IGA under ridgelike deposits that were analyzed and found to be slightly alkaline to very alkaline (caustic) in nature. Crack oxide analysis indicated sulfate levels in excess of expected values. The analysis supported the conclusion that that the deposits formed at locations that experienced steam blanketing or dryout at the higher levels of the steam generators. Recommendations included steam generator water-chemistry controls, chemical cleaning, and reduction of the primary reactor coolant system temperature.
一个发电厂使用两个蒸汽发生器(垂直u型管和壳式热交换器,大约21米(68英尺)高,蒸汽鼓直径6米(20英尺))经历了蒸汽发生器管破裂。每个蒸汽发生器包含11012根外径19毫米、公称壁厚1.0毫米(0.042英寸)、平均长度18米(57.75英尺)的镍基合金(Inconel) 600管。反应堆冷却剂的初始工作温度为328摄氏度(621华氏度)。在管道破裂事件发生后,进行了管道拆除工作。调查(目视检查、SEM断口和显微照片)显示,IGSCC起源于OD和IGA,在脊状沉积物下进行分析,发现其性质为微碱性到强碱性(腐蚀性)。裂纹氧化物分析表明硫酸盐含量超过了预期值。分析支持了这样的结论,即沉积物形成于蒸汽发生器较高水平经历蒸汽覆盖或干燥的位置。建议包括蒸汽发生器水化学控制、化学清洗和降低主反应堆冷却剂系统温度。
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引用次数: 0
Failure of a Superheater Outlet Tube 过热器出口管失效
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001011
T. D. da Silveira, I. Le May
After some 87,000 h of operation, failure took place in the bend of a steam pipe connecting a coil of the third superheater of a steam generator to the outlet steam collector. The unit operated at 538 deg C and 135 kPa, producing 400 t/h of steam. The 2.25Cr-1Mo steel pipe in which failure took place was 50.8 mm in diam with a nominal wall thickness of 8 mm. It connected to the AISI 321 superheater tube by means of a butt weld and was one of 46 such parallel connecting tubes. The Cr-Mo tubing was situated outside the heat transfer zone of the superheater. The overall sequence of failure involved overheating of the Cr-Mo outlet tubes, heavy oxidation, oxide cracking on thermal cycling, thermal fatigue cracking plus oxidation, creep-controlled crack growth, and rapid plastic deformation and rupture. This failure was indicative of excess temperature of the steam coming from the heat transfer zone of the coil. It showed that many damage mechanisms may combine in the transition from fracture initiation to final failure. The presence of grain boundary sliding as an indication of creep damage was useful in the characterization of the stress level as high and showed that the process of creep was not operative throughout the life of the equipment.
运行约87,000小时后,连接蒸汽发生器第三个过热器盘管与出口蒸汽收集器的蒸汽管弯曲处发生故障。该装置在538摄氏度和135千帕的温度下工作,产生400吨/小时的蒸汽。发生破坏的2.25Cr-1Mo钢管直径为50.8 mm,公称壁厚为8mm。它通过对焊连接到AISI 321过热器管,是46个这样的平行连接管之一。Cr-Mo管位于过热器传热区外。总体失效顺序包括Cr-Mo出口管过热、重氧化、热循环氧化裂纹、热疲劳裂纹加氧化、蠕变控制裂纹扩展以及快速塑性变形和断裂。这种故障表明来自盘管传热区的蒸汽温度过高。结果表明,在从断裂萌生到最终破坏的过渡过程中,多种损伤机制可能结合在一起。晶界滑动的存在作为蠕变损伤的指示,在表征应力水平较高时是有用的,并表明蠕变过程在设备的整个使用寿命期间都不会发生。
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引用次数: 0
Wind Turbine Failures 风力发电机故障
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001692
I. May, C. Bagnall
Two blade-detachment failures in large (600 kW) wind turbine generators were investigated. In the first case, bolt failures were established as the initial failure event. A fatigue crack reached a critical length, fast fracture developed and was then arrested as the bolt unloaded. Crack growth resumed when loading increased with cracking or fracture of adjacent bolts. The problem was identified as one of insufficient preload on the bolts. In the second failure on a different unit, a retaining nut on a blade assembly split, allowing a roller bearing to slide off a shaft and a blade to separate at its attachment hub. The failure was observed to be by fatigue. It was determined that pieces of the outer retaining rib (or flange) on the bearing inner cage had fractured by fatigue and were trapped between the nut and the bearing, producing excessive cyclic loading on the nut by a wedging action as the blade pitch adjusted during a revolution. Fatigue of the rim occurred as a result of inadequate lubrication in the bearing, which led to load transfer across the rollers, onto the rim.
对两种大型(600kw)风力发电机组叶片脱落故障进行了研究。在第一种情况下,将锚杆破坏作为初始破坏事件。当疲劳裂纹达到临界长度时,快速断裂发展并随着螺栓卸载而停止。当加载增加,相邻螺栓开裂或断裂时,裂纹恢复扩展。问题被确定为螺栓预紧力不足。在另一个单元的第二个故障中,叶片组件上的固定螺母裂开,导致滚子轴承从轴上滑落,叶片在其连接轮毂处分离。据观察,这次损坏是由于疲劳造成的。经确定,轴承内保持架上的外护肋(或法兰)由于疲劳而断裂,卡在螺母和轴承之间,在旋转过程中叶片螺距调整时,楔入作用对螺母产生了过度的循环载荷。轮辋的疲劳是由于轴承润滑不足造成的,这导致负载在滚子上转移到轮辋上。
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引用次数: 0
Corrosion-Fatigue Fracture of an H21 Tool Steel Safety-Valve Spring in Moist Air H21工具钢安全阀弹簧在潮湿空气中的腐蚀疲劳断裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0046874
The safety valve on a steam turbogenerator was set to open when the steam pressure reaches 2400 kPa (348 psi). The pressure had not exceeded 1790 kPa (260 psi) when the safety-valve spring shattered into 12 pieces. The steam temperature in the line varied from about 330 to 400 deg C (625 to 750 deg F). Because the spring was enclosed and mounted above the valve, its temperature was probably slightly lower. The 195 mm (7 in.) OD x 305 mm (12 in.) long spring was made from a 35 mm (1 in.) diam rod of H21 hot-work tool steel. It had been in service for about four years and had been subjected to mildly fluctuating stresses. Analysis (visual inspection, 0.3x photographs, 0.7x light fractographs, and metallographic examination) supported the conclusions that the spring failed by corrosion fatigue that resulted from application of a fluctuating load in the presence of a moisture-laden atmosphere. Recommendations included replacing all safety valves in the system with new open-top valves that had shot-peened and galvanized steel springs. Alternatively, the valve springs could be made from a corrosion-resistant metal-for example, a 300 series austenitic stainless steel or a nickel-base alloy, such as Hastelloy B or C.
当蒸汽压力达到2400千帕(348 psi)时,蒸汽汽轮发电机上的安全阀被设置为打开。当安全阀弹簧破碎成12片时,压力还没有超过1790千帕(260 psi)。管道中的蒸汽温度在330到400摄氏度(625到750华氏度)之间变化。由于弹簧是封闭的,安装在阀门上方,其温度可能略低。195毫米(7英寸)外径× 305毫米(12英寸)长弹簧由35毫米(1英寸)直径的H21热加工工具钢杆制成。它已经服役了大约四年,承受了轻微的波动应力。分析(目视检查、0.3倍照片、0.7倍光断口和金相检查)支持这样的结论,即弹簧失效是由于在充满水分的大气中施加波动载荷造成的腐蚀疲劳。建议包括用喷丸和镀锌钢弹簧更换系统中的所有安全阀。另外,气门弹簧可以由耐腐蚀金属制成,例如300系列奥氏体不锈钢或镍基合金,如哈氏合金B或C。
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引用次数: 0
Fatigue Fracture of a 6150 Steel Main Shaft in a Coal Pulverizer 煤粉机6150钢主轴疲劳断裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0047813
After being in service for ten years the ball-and-race coal pulverizer was investigated after noises were noted in it. Its lower grinding ring was attached to the 6150 normalized steel outer main shaft while the upper grinding ring was suspended by springs from a spider attached to the shaft. A circumferential crack in the main shaft at an abrupt change in shaft diam just below the upper radial bearing was revealed by visual examination. The smaller end of the shaft was found to be slightly eccentric with the remainder when the shaft was set up in a lathe to machine out the crack for repair welding. The crack was opened by striking the small end of the shaft and the shaft was broken 1.3 cm away from the crack in the process. A previous fracture that resulted from torsional loading acting along a plane of maximum shear was revealed almost perpendicular to the axis of the shaft. Faint lines parallel to the visible crack thought to be fatigue cracks were revealed on examination of the machined surface. The shaft was repaired by welding a new section and machined to required diameters and tapers to avoid abrupt changes.
球套式粉碎机在投入使用十年后,对其产生的噪声进行了调查。它的下磨削环连接在6150正火钢外主轴上,上磨削环通过连接在轴上的悬架上的弹簧悬浮。目视检查发现,在上径向轴承下方轴径突变处,主轴上有圆周裂纹。当在车床上安装轴时,发现轴的较小端与其余部分略有偏心,以便将裂纹用于修复焊接。通过击打轴的小端打开裂缝,在此过程中轴在距离裂缝1.3 cm处断裂。先前由于扭转载荷沿最大剪切面作用而导致的骨折几乎垂直于轴的轴线。在对加工表面的检查中,发现了与被认为是疲劳裂纹的可见裂纹平行的微弱线条。通过焊接新部分修复轴,并将其加工成所需的直径和锥度,以避免突然变化。
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引用次数: 0
Rupture of Water Wall Tubes of a Boiler 锅炉水冷壁管破裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001479
Several ruptures took place in the front wall tubes of a water tube boiler. Some rupture samples showed ductile failure while others showed brittle failure. Specimens taken from the rupture where a thick edge had been produced, i.e., with little evidence of prior plastic deformation, showed a coarse microstructure indicative of gross overheating. The examination indicated that failure in the main resulted from gross overheating arising from water starvation as could have been due to a number of causes. The ruptures in some tubes were of the type commonly found in overheated tubes, the material being drawn out to a feather edge at the time of rupture. Other ruptures in the same and other tubes were of a more brittle type, this being associated with penetration of material by molten copper derived from scale.
某水管锅炉前壁管发生多处断裂。一些断裂样品表现为延性破坏,而另一些则表现为脆性破坏。从已经产生厚边缘的破裂处提取的样品,即几乎没有先前塑性变形的证据,显示出粗糙的微观结构,表明严重过热。检查表明,主要故障是由于缺水引起的严重过热造成的,这可能是由于许多原因造成的。有些管子的破裂是在过热的管子中常见的类型,材料在破裂时被拉出到羽毛边缘。在同一管道和其他管道中的其他破裂是一种更脆的类型,这与来自水垢的熔融铜渗透材料有关。
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引用次数: 0
期刊
ASM Failure Analysis Case Histories: Power Generating Equipment
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