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A comprehensive and quantitative comparison of organophosphate esters: Characteristics, applications, environmental occurrence, toxicity, and health risks 有机磷酸酯的综合定量比较:特性、应用、环境发生、毒性和健康风险
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-26 DOI: 10.1080/10643389.2024.2406587
Mengyan Huang, Lingjun Zeng, Chen Wang, Xuan Zhou, Yi Peng, Chongli Shi, Susu Wang, Yu Li, Damià Barceló, Hui Li
Organophosphate esters (OPEs) are substitutes for bromine flame retardants and are used in various consumer products. While OPEs have been extensively studied, the lack of systematic comparison among major OPEs contributes to ambiguity regarding their risks. Classified by substituents of Cl-OPEs, alkyl-OPEs, and aryl-OPEs, this review conducted a retrospective comparison and comprehensive analysis of physicochemical properties, use and regulation, environmental occurrence proportion, toxic effect thresholds, and degree of health risk, thus identifying typical high-risk OEPs that warrant greater scrutiny. Generally, Cl-OPEs and alkyl-OPEs exhibit higher concentration proportion than aryl-OPEs in various environmental media. Moreover, the toxic effects of Cl-OPEs and aryl-OPEs surpass those of alkyl-OPEs, notably tris(2-chloro-1(chloromethyl)ethyl) phosphate (TDCPP) and triphenyl phosphate (TPHP), alongside TDCPP, TPHP, tris(2-chloroisopropyl) phosphate (TCPP), tris(2-choroethyl) phosphate (TCEP), tris(2-butoxyethyl) phosphate (TBOEP), and tributyl phosphate (TNBP) as the most typical OPEs. Although OPEs at environment concentrations pose limited threats to human health, further assessment of the health risks posed by typical high-risk OPEs in sensitive populations is remain necessary. Overall, this review offers a more comprehensive perspective on the differences between typical OPEs and provides valuable insights into their future use and regulation.
有机磷酸酯(OPEs)是溴类阻燃剂的替代品,被用于各种消费品中。虽然对 OPE 进行了广泛的研究,但由于缺乏对主要 OPE 进行系统的比较,导致对其风险的认识模糊不清。本综述按照 Cl-OPEs、烷基-OPEs 和芳基-OPEs 的取代基进行分类,对其理化性质、用途和法规、环境发生比例、毒性效应阈值和健康风险程度进行了回顾性比较和综合分析,从而确定了值得进一步研究的典型高风险 OEPs。一般来说,Cl-OPE 和烷基-OPE 在各种环境介质中的浓度比例高于芳基-OPE。此外,Cl-OPEs 和芳基-OPEs 的毒性作用也超过了烷基-OPEs,尤其是磷酸三(2-氯-1(氯甲基)乙基)酯(TDCPP)和磷酸三苯酯(TPHP),与 TDCPP 并驾齐驱、TPHP、磷酸三(2-氯异丙基)酯(TCPP)、磷酸三(2-氯乙基)酯(TCEP)、磷酸三(2-丁氧基乙基)酯(TBOEP)和磷酸三丁酯(TNBP)是最典型的 OPE。尽管环境浓度下的 OPE 对人体健康的威胁有限,但仍有必要进一步评估典型的高风险 OPE 对敏感人群的健康风险。总之,本综述从更全面的角度阐述了典型 OPE 之间的差异,并为今后的使用和监管提供了有价值的见解。
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引用次数: 0
Antibiotic and microplastic co-exposure: Effects on Daphnia magna and implications for ecological risk assessment 抗生素和微塑料的共同暴露:对大型蚤的影响以及对生态风险评估的影响
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-25 DOI: 10.1080/10643389.2024.2406575
Mengyuan Pei, Jingyuan Fan, Chenxi Zhang, Jiake Xu, Yujian Yang, Haotian Wei, Cheng Zhang, Lusheng Zhu, Peng Gao
The pervasive presence of antibiotics and microplastics in aquatic environments poses a significant ecological concern. These contaminants, known for their environmental persistence and bioaccumula...
抗生素和微塑料在水生环境中的普遍存在引发了重大的生态问题。这些污染物以其环境持久性和生物累积性而闻名。
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引用次数: 0
The joint environmental fates and ecotoxicity of graphene-family nanomaterials and co-existing contaminants in the aquatic environment: A review 水生环境中石墨烯族纳米材料与共存污染物的共同环境归宿和生态毒性:综述
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-03 DOI: 10.1080/10643389.2024.2398837
Kangying Wu, Qixing Zhou, Jing Xu, Hui Zeng, Xiangang Hu, Shaohu Ouyang
Graphene family nanomaterials (GFNs), serving as vectors or catalysts for co-existing contaminants (e.g., heavy metal ions and organic chemicals) in water systems, have raised significant environme...
石墨烯族纳米材料(GFNs)是水系统中同时存在的污染物(如重金属离子和有机化学品)的载体或催化剂,对环境造成了重大影响。
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引用次数: 0
Bridging knowledge gaps in human chemical exposure via drinking water with non-target screening 通过非目标筛选弥合人类通过饮用水接触化学品方面的知识差距
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-01 DOI: 10.1080/10643389.2024.2396690
Davide Ciccarelli, Saer Samanipour, Helena Rapp-Wright, Stefan Bieber, Thomas Letzel, Jake W. O’Brien, Tim Marczylo, Timothy W. Gant, Paolo Vineis, Leon P. Barron
Fundamental knowledge gaps still exist in the exposome, especially regarding analytical space coverage, mapping and prioritization of a very large number of diverse chemical structures. This review...
暴露组的基本知识仍然存在差距,特别是在分析空间覆盖、大量不同化学结构的映射和优先排序方面。本综述...
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引用次数: 0
Unraveling eutrophication controversies: Innovative strategies and holistic perspectives 消除富营养化争议:创新战略和整体视角
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-24 DOI: 10.1080/10643389.2024.2392987
Pengfei Hei, Tingting Yang, Lei Huang, Yan Liu, Jing Yang, Yizi Shang, Lian Feng, Guoxian Huang
Eutrophication remains a persistent global water quality challenge despite extensive investigations. Numerous reviews highlight multifaceted controversies, and scholars from diverse fields have att...
尽管进行了广泛的调查,但富营养化仍是全球水质面临的一项长期挑战。许多评论强调了多方面的争议,来自不同领域的学者也对富营养化进行了研究。
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引用次数: 0
Rethinking strategies to attenuate organic pollutants: Mechanisms and challenges of catalytic pollutants polymerization 重新思考减缓有机污染物的战略:催化污染物聚合的机理与挑战
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-24 DOI: 10.1080/10643389.2024.2393511
Shiyu Zuo, Yan Wang, Jinquan Wan, Yongwen Ma, Zhicheng Yan, Min Tang
There exist two distinct pathways for the migration and conversion of organic pollutants in natural water, namely degradation and polymerization. From the perspective of the carbon cycle in the wat...
有机污染物在天然水中的迁移和转化有两种不同的途径,即降解和聚合。从水体碳循环的角度来看,降解和聚合是有机污染物迁移和转化的主要途径。
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引用次数: 0
Full life cycle of uranium toward ore-soil-root-shoot system: A comprehensive review 矿石-土壤-根系-根系的铀全生命周期:全面回顾
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-01 DOI: 10.1080/10643389.2024.2386104
Shaojie Zheng, Di Guo, Xuyuan Yang, Yu Liu, Shihao Liu, Wenwen Tian, Zhirui Niu, Hua Huang
Uranium is a naturally occurring radionuclide with chemical toxicity, derived from deposits formed through complex processes. In recent years, uranium utilization activities have increased uranium ...
铀是一种天然放射性核素,具有化学毒性,来自经过复杂过程形成的矿床。近年来,铀利用活动增加了铀...
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引用次数: 0
Effect of biochar, graphene, carbon nanotubes, and nanoparticles on microbial denitrification: A review 生物炭、石墨烯、碳纳米管和纳米颗粒对微生物脱氮的影响:综述
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-07-30 DOI: 10.1080/10643389.2024.2386086
Anhang Li, Jiachao Yao, Nan Li, Changjie Shi, Mengwei Bai, Zeyu Wang, Dzmitry Hrynsphan, Tatsiana Savitskaya, Jun Chen
Nitrogen pollution poses a substantial threat to water bodies, making the exploration of effective treatment technologies imperative. Among these, biological denitrification stands out as one of th...
氮污染对水体构成了巨大威胁,因此探索有效的处理技术势在必行。在这些技术中,生物脱氮技术尤为突出。
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引用次数: 0
Dissimilatory iron-reducing microorganisms: The phylogeny, physiology, applications and outlook 溶铁还原微生物:系统发育、生理学、应用与展望
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-07-29 DOI: 10.1080/10643389.2024.2382498
Nanlan Zhao, Hao Ding, Xuji Zhou, Tom Guillemot, Zuotao Zhang, Nan Zhou, Hui Wang
Dissimilatory iron reduction (DIR) is an important form of microbial respirations and a key part of iron biogeochemical cycle. A wide range of both bacteria and archaea that can conserve energy thr...
吸收性铁还原(DIR)是微生物呼吸的一种重要形式,也是铁生物地球化学循环的一个关键部分。许多细菌和古细菌都能通过吸收铁来保存能量。
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引用次数: 0
Environmental behavior, toxic potencies, and risks of liquid crystal monomers: A critical review 液晶单体的环境行为、毒性和风险:重要综述
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-07-11 DOI: 10.1080/10643389.2024.2373948
Jiawei Cheng, Xiaojuan Li, Yawen Yuan, Mengxiao Wang, Yunsong Mu, Xiaoli Zhao, Fengchang Wu, John P. Giesy
Liquid crystal monomers (LCMs), prized for their unique optical properties, are ubiquitous in a range of electronic products. However, their growing use and disposal have led to a continuous influx...
液晶单体 (LCM) 因其独特的光学特性而倍受青睐,在各种电子产品中无处不在。然而,由于液晶单体的使用量和废弃量不断增加,导致大量的液晶单体不断涌现。
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引用次数: 0
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