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Adsorption kinetics and isotherm models of heavy metals by various adsorbents: An overview 各种吸附剂对重金属的吸附动力学和等温线模型综述
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-06-15 DOI: 10.1080/10643389.2023.2221157
Jianlong Wang, X. Guo
Abstract Heavy metal pollution has become one of the most severe environmental issues. Adsorption is an effective method for removing heavy metals from aquatic environments. The adsorption isotherm and kinetics models can provide information on the adsorption process, maximal adsorption capacity, and mass transfer steps, which are essential to evaluate the performance of an adsorbent and to design an adsorption system. In this review, the adsorption kinetics and isotherms of heavy metals by various adsorbents were summarized and discussed in depth. First, the sources of heavy metal pollution and the adsorption technology to remove heavy metals were reviewed. The adsorption capacity of Cu, Cd, Zn, Ni, Cr, As, Fe, Hg, Co, Sr, and Cs by biosorbents (e.g. algae, agriculture waste biochar/activated carbon, and bacteria) and by abiotic adsorbents (e.g. metal–organic frameworks (MOFs), microtubes, polymers, clays, minerals, and coal) were systematically summarized. Second, the origins, basic assumptions, importance, physical meanings, and applications of the adsorption kinetics and isotherm models were discussed in depth. Third, the methods for selecting adsorption models in different conditions were explained, and the statistical parameters which can be applied to evaluate the performance of the models were illustrated. Finally, two Excel sheets are provided for solving the adsorption models, which are available in Supplementary Information. This review article will deepen the understanding of the interaction between heavy metals and adsorbents and facilitate the development of adsorptive technology for heavy metal removal from water and wastewater.
摘要重金属污染已成为最严重的环境问题之一。吸附是去除水生环境中重金属的有效方法。吸附等温线和动力学模型可以提供关于吸附过程、最大吸附容量和传质步骤的信息,这对于评估吸附剂的性能和设计吸附系统至关重要。本文对各种吸附剂对重金属的吸附动力学和等温线进行了综述和深入讨论。首先,综述了重金属污染的来源和吸附去除重金属的技术。系统总结了生物吸附剂(如藻类、农业废弃物生物炭/活性炭和细菌)和非生物吸附剂,如金属-有机框架(MOFs)、微管、聚合物、粘土、矿物和煤)对Cu、Cd、Zn、Ni、Cr、As、Fe、Hg、Co、Sr和Cs的吸附能力。其次,深入讨论了吸附动力学和等温线模型的起源、基本假设、重要性、物理意义和应用。第三,解释了在不同条件下选择吸附模型的方法,并说明了可用于评估模型性能的统计参数。最后,提供了两张Excel表来求解吸附模型,可在补充信息中获得。这篇综述文章将加深对重金属与吸附剂相互作用的理解,并有助于开发从水中和废水中去除重金属的吸附技术。
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引用次数: 9
Effects of biochar on the accumulation of necromass-derived carbon, the physical protection and microbial mineralization of soil organic carbon 生物炭对土壤有机质碳积累、物理保护和微生物矿化的影响
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-06-05 DOI: 10.1080/10643389.2023.2221155
Yalan Chen, Ke Sun, Yan Yang, Bo Gao, Hao Zheng
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引用次数: 4
Progress and future prospects in co-planting with hyperaccumulators: Application to the sustainable use of agricultural soil contaminated by arsenic, cadmium, and nickel 与超积累植物共同种植的进展和未来前景:在砷、镉和镍污染农业土壤可持续利用中的应用
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-06-02 DOI: 10.1080/10643389.2023.2215684
Xiaoming Wan, Weibin Zeng, Wenchang Cai, Mei Lei, X. Liao, Tongbin Chen
Abstract Co-planting two or more species on the same piece of land, with overlapping time or not, has been suggested to increase both crop production and long-term sustainability. On soils that are slightly or moderately contaminated with heavy metals, hyperaccumulators have been co-planted with crops to clean the soil and produce safe agricultural products. Despite the increasing number of greenhouse experiments and field trials that investigate the co-planting mechanisms and efficiency, the consistency, stability, and applicability of this technology and its contribution to sustainability remain unclear. From published literature, we collected 118 co-planting combinations involving hyperaccumulators, and compared them with their monoculture controls. Co-planting averagely decreased the shoot arsenic concentration by ∼23.4% and cadmium by ∼13.4%. Co-planting controls the crop contamination as long as the hyperaccumulator and crop species are correctly selected, and the soil heavy metal is within the safe range. Further, a sustainability assessment criterion for the utilization of contaminated agricultural soil was proposed, taking As-contaminated soil as an example. A decision framework and a guideline for co-planting were established to aid in the decision-making. The outlook of co-planting as a sustainable solution and the future development were prospected. Graphical Abstract
摘要有人建议,在同一块土地上共同种植两个或两个以上的物种,无论时间是否重叠,都可以提高作物产量和长期可持续性。在受重金属轻度或中度污染的土壤上,超积累植物与作物共同种植,以清洁土壤并生产安全的农产品。尽管研究共同种植机制和效率的温室实验和田间试验越来越多,但这项技术的一致性、稳定性和适用性及其对可持续性的贡献仍不清楚。从已发表的文献中,我们收集了118个涉及超积累植物的共植组合,并将其与单一栽培对照进行了比较。共植使地上部砷浓度平均降低23.4%,镉浓度平均降低13.4%。只要正确选择超积累植物和作物物种,土壤重金属在安全范围内,共植就能控制作物污染。此外,以砷污染土壤为例,提出了农业污染土壤利用可持续性评价标准。制定了一个共同种植的决策框架和指导方针,以帮助决策。展望了合作种植作为一种可持续的解决方案的前景和未来的发展。图形摘要
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引用次数: 0
A critical review of environmental exposure, metabolic transformation, and the human health risks of synthetic musks 合成麝香的环境暴露、代谢转化和人类健康风险综述
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-05-31 DOI: 10.1080/10643389.2023.2217068
Na Luo, Yanpeng Gao, Xiaoyi Chen, Mei Wang, Xiaolin Niu, Guiying Li, T. An
Abstract Synthetic musks (SMs) have been widely used as fragrance ingredients in various daily consumer products. Due to their mass production and usage, the presence of SMs has been reported in environmental and human biological samples, raising global concerns over human health effects. This review outlines the current knowledge on human exposure pathways and internal exposure to environmental SMs. The biotransformation of SMs in humans is also highlighted. Compared to exposure through inhalation and oral ingestion pathways, dermal contact from SMs-containing personal care products is the dominant pathway, accounting for 82–93% of total human SMs daily exposure. After penetrating the skin barrier, SMs can be absorbed by the dermis, causing potential skin irritation. Regarding internal human exposure, around half of the limited studies focused on breast milk, indicating considerable risks for vulnerable global populations (e.g. pregnant women and babies). The health effects of SMs are assessed synergistically based on the existing data and our calculated toxicological predictions. SMs could induce endocrine disruption and mutagenic toxicity according to historical analysis of data. Our computational toxicology data suggested negative impacts on the cardiovascular system for the first time. However, caution should be applied when interpreting adverse health effects using the available data, as the effective toxic doses of different SMs in laboratory studies were greater than actual environmental concentrations in most cases. Based on an analysis of research progress, this review also proposed the need to study the relationship between long-term low-dose exposure and adverse human health effects in future research. Graphical abstract
摘要合成麝香(SM)已被广泛用作各种日常消费品的香料成分。由于SM的大规模生产和使用,据报道在环境和人类生物样本中存在SM,这引发了全球对人类健康影响的担忧。这篇综述概述了目前关于人类暴露途径和环境SM内部暴露的知识。还强调了SM在人类中的生物转化。与通过吸入和口服途径暴露相比,含有个人护理产品的SM的皮肤接触是主要途径,占人类SM每日暴露总量的82-93%。SM穿透皮肤屏障后,可被真皮吸收,引起潜在的皮肤刺激。关于人体内部暴露,大约一半的有限研究集中在母乳上,这表明全球弱势群体(如孕妇和婴儿)面临相当大的风险。SM的健康影响是根据现有数据和我们计算的毒理学预测进行协同评估的。根据历史数据分析,SM可引起内分泌紊乱和致突变毒性。我们的计算毒理学数据首次表明对心血管系统有负面影响。然而,在使用现有数据解释不良健康影响时应谨慎,因为在大多数情况下,实验室研究中不同SM的有效毒性剂量大于实际环境浓度。在分析研究进展的基础上,这篇综述还提出了在未来的研究中需要研究长期低剂量暴露与人类健康不良影响之间的关系。图形摘要
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引用次数: 0
Metabolic modeling of synthetic microbial communities for bioremediation 用于生物修复的合成微生物群落的代谢建模
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-05-31 DOI: 10.1080/10643389.2023.2212569
Lvjing Wang, Xiaoyu Wang, Hao Wu, Hai-xia Wang, Yihan Wang, Zhenmei Lu
Abstract The genome-scale metabolic model (GEM), a mathematical representation of whole-cell metabolism, enables in silico high-throughput simulations of metabolic flux distribution under different conditions. As a mechanistic and quantitative framework at the system level, GEMs have been applied to investigate microbial interactions and provide guidelines for the rational design of synthetic microbial communities that can perform the desired functions and provide novel strategies for bioremediation. Here, we review different types of microbial interactions and their research progress in environmental remediation. The detailed process of GEM reconstruction and the current main automatic reconstruction programs as well as knowledge databases are summarized. Exciting recent application studies combining metabolic models, omics, and machine learning approaches are also presented. The combination of these methods improves the predictive ability and broadens the applications of GEMs. However, extensive work is still needed to deeply understand and arbitrarily use GEMs to describe the metabolic interactions of microbial communities and apply them in pollutant biodegradation. Finally, an in-depth discussion of the current challenges and limitations of metabolic models provides us with an outlook for their future development in environmental science, especially synthetic microbiology. Graphical abstract
摘要基因组规模代谢模型(GEM)是全细胞代谢的数学表示,能够在不同条件下对代谢通量分布进行计算机高通量模拟。作为系统层面的机制和定量框架,GEMs已被应用于研究微生物相互作用,并为合理设计能够发挥所需功能的合成微生物群落提供指导,并为生物修复提供新的策略。在此,我们回顾了不同类型的微生物相互作用及其在环境修复中的研究进展。概述了GEM重构的详细过程、当前主要的自动重构程序以及知识库。还介绍了结合代谢模型、组学和机器学习方法的令人兴奋的最新应用研究。这些方法的结合提高了GEMs的预测能力,拓宽了其应用范围。然而,要深入理解和任意使用GEMs来描述微生物群落的代谢相互作用,并将其应用于污染物生物降解,还需要大量的工作。最后,深入讨论代谢模型目前的挑战和局限性,为我们展望其在环境科学,特别是合成微生物学中的未来发展提供了前景。图形摘要
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引用次数: 0
Interactions between cadmium and nutrients and their implications for safe crop production in Cd-contaminated soils 镉污染土壤中镉与养分的相互作用及其对作物安全生产的影响
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-05-11 DOI: 10.1080/10643389.2023.2210985
Y. Zhu, Zhuang Yao, Xiaohui Sun, S. Du
Abstract Cadmium availability and accumulation in edible parts of plants are affected by multiple processes in the rhizosphere and plants, especially the interactions between Cd and mineral nutrients. The application of mineral nutrients in the soil could influence Cd activity through diverse processes, such as precipitation, adsorption, and competitive uptake, by sharing the same transporters/channels or chelation sites. Therefore, optimization of nutrient supply is considered an economical, efficient, and environment-friendly method for restricting Cd content in crops. In this review, the physiological and biochemical interactions between Cd and other essential elements (iron, nitrogen, phosphorus, calcium, zinc, manganese, silicon, and selenium) are discussed, providing theoretical support for developing nutrient management strategies to minimize Cd accumulation in edible parts and guarantee food safety. Graphical Abstract
摘要镉在植物可食用部位的有效性和积累受到根际和植物的多种过程的影响,特别是镉与矿物质营养物质之间的相互作用。土壤中矿物质营养素的应用可以通过共享相同的转运蛋白/通道或螯合位点,通过不同的过程影响Cd的活性,如沉淀、吸附和竞争吸收。因此,优化养分供应被认为是限制作物镉含量的一种经济、高效、环保的方法。本文讨论了镉与其他必需元素(铁、氮、磷、钙、锌、锰、硅和硒)之间的生理生化相互作用,为制定营养管理策略以最大限度地减少镉在可食用部位的积累并保证食品安全提供了理论支持。图形摘要
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引用次数: 9
Antiepileptic drugs in aquatic environments: Occurrence, toxicity, transformation mechanisms and fate 水生环境中的抗癫痫药物:发生、毒性、转化机制和命运
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-05-11 DOI: 10.1080/10643389.2023.2209010
Quanzhen Liu, Long Wang, Xiong Xu, Saihong Yan, Jinmiao Zha, Donghong Wang, Dan Zhu
Abstract The increasing consumption of antiepileptic drugs (AEDs) has led to their widespread presence in aquatic environments, which poses a serious threat to human health and aquatic organisms. However, there is currently lack of a review to provide basic data and research directions for future scholars. This article was carried out to summarize toxicity, analytical methods, concentrations, transformation mechanisms and fate of AEDs and their metabolites/transformation products in aquatic environments according to existing literature. AEDs and their metabolites/transformation products were widely found in surface water, groundwater and drinking water with concentrations from ng L−1-μg L−1. AEDs at environmentally relevant concentrations have affected aquatic ecosystem, and partial AEDs could commonly cause the damage of antioxidant capacity for some aquatic organisms. The transformation of AEDs was always in the direction of oxidation, and hydroxylated and ketonizated products were conductive objectives in three pathways including human body, microorganisms and water treatment processes as the difference of transformation pathways was also observed. AEDs were supposed to dominate the concentration distribution in water phase than in sediment phase due to their chemical properties. Furthermore, photolysis was a main process for AEDs in the photic zone of receiving waters. Meanwhile, the current deficiencies of AEDs research are also pointed out. It is mainly reflected in the insufficient toxicity data and incomplete transformation pathways of AEDs and their metabolites/transformation products, which will underestimate their environmental hazards. Finally, the article also pointed out that more attention should be paid to identifying transformation products combining mechanisms analysis with nontarget analysis. Graphical Abstract
摘要随着抗癫痫药物消费量的增加,抗癫痫药物在水生环境中广泛存在,对人类健康和水生生物造成了严重威胁。然而,目前还缺乏一篇综述为未来的学者提供基础数据和研究方向。本文根据已有文献,对AEDs及其代谢物/转化产物在水生环境中的毒性、分析方法、浓度、转化机制和命运进行了综述。AEDs及其代谢物/转化产物广泛存在于地表水、地下水和饮用水中,浓度在ng L−1-μ L−1之间。与环境相关浓度的aed对水生生态系统产生了影响,部分aed通常会对某些水生生物的抗氧化能力造成损害。在人体、微生物和水处理过程中,抗氧药物的转化始终是向氧化方向进行的,羟基化和酮化产物是三种途径的传导目标,并观察到转化途径的差异。AEDs的化学性质决定了其在水相的浓度分布比在沉积物相的浓度分布更占优势。此外,在接收水体的光解过程是aed的主要过程。同时,也指出了目前aed研究的不足。主要表现在对aed及其代谢物/转化产物的毒性数据不充分,转化途径不完整,低估了其环境危害。最后,文章还指出应将机理分析与非目标分析相结合,重视转化产物的识别。图形抽象
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引用次数: 3
Microalgae biofilm carbon and nitrogen sequestration as a tool for economic and environmental sustainability 微藻生物膜碳氮固存作为经济和环境可持续性的工具
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-05-07 DOI: 10.1080/10643389.2023.2209492
A. Ugya, Hui Chen, Qiang Wang
Abstract The continuous release of greenhouse gases (GHG) is negatively affecting the sustainability of the ocean as a carbon sink via acidification and ocean warming. The capture and storage of GHGs is important to reduce the long-term effects of the emissions. The use of microalgae biofilms for GHG sequestration is a promising method due to their ability to adapt to different environmental conditions and their rapid growth characteristics. The current review shows how the process of microalgae biofilm sequestration of carbon and nitrogen contributes to economic and environmental sustainability. The review shows that the use of wastewater as a medium for the cultivation of microalgae biofilm is cost effective and will increase the economic feasibility of the use of microalgae biofilm for GHG sequestration, but the dynamic nature of microalgae biofilm structure, which is directly influenced by the type of substrate, liquid flow, and environmental conditions, is a limitation. The results of the current review cannot assure that the use of microalgae biofilm is highly economically viable using techno-economic analysis due to the lack of accessible data showing the precise estimation operating expenditures and capital expenditures. The current review also shows that the use of microalgae biofilm for GHG capture will lead to environmental sustainability because the increase in availability of bioresources caused by microalgae biofilm cultivation will lead to a decrease in the world’s economic dependency on fossil resources. Graphical abstract
温室气体(GHG)的持续释放通过酸化和海洋变暖对海洋作为碳汇的可持续性产生负面影响。温室气体的捕获和储存对于减少排放的长期影响非常重要。微藻生物膜具有适应不同环境条件的能力和快速生长的特点,是一种很有前途的温室气体固存方法。本文综述了微藻生物膜固碳和固氮过程对经济和环境可持续性的贡献。综上所述,利用废水作为培养基培养微藻生物膜具有成本效益,并将提高微藻生物膜固存温室气体的经济可行性,但微藻生物膜结构的动态性是一个限制,它直接受底物类型、液体流量和环境条件的影响。目前的审查结果不能保证使用微藻生物膜是高度经济可行的技术经济分析,因为缺乏可获得的数据显示精确估计的运营支出和资本支出。目前的综述还表明,利用微藻生物膜进行温室气体捕获将导致环境的可持续性,因为微藻生物膜培养引起的生物资源可用性的增加将导致世界经济对化石资源的依赖减少。图形抽象
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引用次数: 1
Coal ash for removing toxic metals and phenolic contaminants from wastewater: A brief review 粉煤灰去除废水中有毒金属和酚类污染物的研究进展
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-05-05 DOI: 10.1080/10643389.2023.2206781
A. Labidi, Haitao Ren, A. Sial, Hong Wang, E. Lichtfouse, Chuanyi Wang
Abstract Over the past few years, population growth, industrial progress and climate change have led to water scarcity. Thus, water pollution caused by hazardous soluble and insoluble pollutants, such as toxic metals and phenolic compounds, has become an important problem that should be dealt with urgently. For instance, new methods have been introduced to convert low-cost raw materials (i.e. coal fly ash and coal bottom ash “wastes-to-resource”) into suitable materials for new cleaner production to achieve sustainability goals in wastewater-containing toxic metals and phenolic compounds purification. Obviously, the functionalization of coal fly ash and bottom ash enhances the ability of coal ash-based entities as potential materials in wastewater remediation technologies. Here, we review the application of coal ashes, including coal bottom ash and fly ash-based materials for toxic metals and phenolic compounds removal. We also examine their structural properties and functionalization to enhance their affinities toward these pollutants in aqueous environment. Even though each process has its own benefits and limitations, coal ash-based materials appear promising for the removal of toxic metals and phenolic compounds using adsorption, membrane filtration, and photocatalysis. Overall, the study on the availability of coal fly ash and bottom ash for wastewater treatment have resulted in high removal efficiencies for toxic metals and phenolic compounds. In the future, new recycling methods for coal ashes as new water purification agents should be further studied and advanced processes should be investigated in order to achieve wastewater remediation purposes. Graphical abstract
在过去的几年里,人口增长、工业进步和气候变化导致了水资源短缺。因此,有毒金属、酚类化合物等有害可溶性和不溶性污染物对水体的污染已成为亟待解决的重要问题。例如,已采用新方法将低成本原料(即煤飞灰和煤底灰“废物转化为资源”)转化为新的清洁生产的适当材料,以实现含有毒金属和酚类化合物净化废水的可持续性目标。粉煤灰和底灰的功能化明显增强了粉煤灰基实体作为废水修复技术中潜在材料的能力。本文综述了粉煤灰,包括煤底灰和粉煤灰基材料在去除有毒金属和酚类化合物方面的应用。我们还研究了它们的结构性质和功能化,以增强它们在水环境中对这些污染物的亲和力。尽管每一种方法都有自己的优点和局限性,但煤灰基材料似乎很有希望通过吸附、膜过滤和光催化去除有毒金属和酚类化合物。总的来说,粉煤灰和底灰用于废水处理的可行性研究已经取得了对有毒金属和酚类化合物的高去除效率。今后应进一步研究粉煤灰作为新型净水剂的回收利用新方法,探索先进工艺,以达到废水的修复目的。图形抽象
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引用次数: 0
Elevated O3 threatens biological communications mediated by plant volatiles: A review focusing on the urban environment O3升高威胁植物挥发物介导的生物通讯:城市环境综述
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-04-20 DOI: 10.1080/10643389.2023.2202105
Noboru Masui, K. Shiojiri, Evgenios Agathokleous, A. Tani, T. Koike
Abstract Plant volatiles, particularly biogenic volatile organic compounds (BVOCs), emitted in urban areas have attracted attention as olfactory signals between plants and other organisms, including insects. However, in urban areas, elevated ozone (O3) levels inhibit plant growth and degrade olfactory signals, including both insect pheromones and BVOCs, resulting in disrupted biological communication. In this article, we review recent findings on how O3 modifies olfactory interactions, focusing on both the emitters and receivers of these signals. The influence of O3 on herbivorous insects and their enemies alters the pressure caused by herbivorous damage in the field, which can affect the development of the defensive capacities of plants at the hereditary level. To address the challenges posed by O3 in biological interactions, BVOC characteristics (e.g., emission rate and species, blend composition, O3 reactivity, and oxidative products) and O3 effects on insects (e.g., preference and antennal detectivity) should be clarified. At the same time, BVOC emissions are expected to increase with rising temperatures, which will likely increase the impact of BVOCs on O3 formation in the future. Therefore, it is necessary to devise strategies, such as selecting non- or low BVOC emitters, to regulate BVOC emissions from urban greening plants and mitigate O3 risks to olfactory interactions and plant health. Graphical Abstract
摘要植物挥发物,特别是生物源性挥发性有机化合物(BVOCs)作为植物与昆虫等生物之间的嗅觉信号,在城市环境中受到广泛关注。然而,在城市地区,臭氧(O3)水平升高会抑制植物生长并降解嗅觉信号,包括昆虫信息素和BVOCs,导致生物交流中断。在本文中,我们回顾了O3如何改变嗅觉相互作用的最新发现,重点关注这些信号的发射器和接收器。O3对草食性昆虫及其天敌的影响改变了田间草食性伤害造成的压力,从而在遗传水平上影响植物防御能力的发育。为了解决O3在生物相互作用中带来的挑战,应该澄清BVOC的特性(如排放率和种类、混合成分、O3反应性和氧化产物)和O3对昆虫的影响(如偏好和触角探测性)。同时,BVOC的排放量预计会随着气温的升高而增加,这可能会增加BVOC对未来O3形成的影响。因此,有必要制定策略,如选择无或低BVOC排放者,以调节城市绿化植物的BVOC排放,减轻O3对嗅觉相互作用和植物健康的风险。图形抽象
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引用次数: 3
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