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Sulfur-driven approaches to cadmium detoxification: From soil microbials to plant-based mechanisms 硫驱动的镉解毒方法:从土壤微生物到植物机制
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-07-21 DOI: 10.1080/10643389.2025.2532644
Qing Xia, Chuanyu Chang, Fang Huang, Xinbin Feng, Hua Zhang
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引用次数: 0
Plant-rhizosphere microbe interactions and their roles in nitrogen cycles under periodic flooding: From cooperation mechanisms to ecological responses 周期性洪水下植物-根际微生物相互作用及其在氮循环中的作用:从合作机制到生态响应
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-07-21 DOI: 10.1080/10643389.2025.2530941
Tian Gao, Yi Li, Nan Yang, Wei Xiong, Xiaodan Liang, Yingjie Wang
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引用次数: 0
Underrecognized three-carbon chlorinated aliphatic hydrocarbons: Occurrence, regulation, and treatment strategies 未被充分认识的三碳氯化脂肪烃:发生、调节和处理策略
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-07-18 DOI: 10.1080/10643389.2025.2484889
Maria Jose Jimenez Vizcarra, Zhiqian Han, Peng Gao, Meng Wang
Three-carbon chlorinated aliphatic hydrocarbons (3C-CAHs) are a group of contaminants widely used in various industrial processes. Despite their frequent occurrence in diverse environmental matrices and established toxicity, these compounds receive much less attention compared to their shorter-chain counterparts such as trichloroethylene and dichloroethylene, leading to significant gaps in regulations and knowledge about their contamination levels and treatment approaches. This review aims to address these notable research gaps on 3C-CAHs, exploring their use, discharge, occurrence, fate, and transport across environmental matrices. By comparing them with one- and two-carbon CAHs, we highlight the unique properties and toxicity profiles of 3C-CAHs. Furthermore, we discuss state-of-the-art treatment techniques for 3C-CAHs, focusing on adsorption, chemical treatment, and biodegradation, and identify respective advantages and limitations. We also summarize regulations at state and federal levels in the U.S. and globally, underscoring the inadequacy of existing regulations for many 3C-CAH compounds. Lastly, we propose future research needs to further advance our understanding of the current contamination status of 3C-CAHs and to promote the development of sustainable and effective treatment methods for mitigating their environmental impacts. Overall, through this review, we aim to raise awareness and stimulate discussion on the importance of addressing 3C-CAHs in environmental management strategies.
三碳氯化脂肪烃(3C-CAHs)是一类广泛应用于各种工业生产过程的污染物。尽管这些化合物经常出现在不同的环境基质中,并具有确定的毒性,但与三氯乙烯和二氯乙烯等短链化合物相比,它们受到的关注要少得多,导致有关其污染水平和处理方法的法规和知识存在重大差距。本文旨在解决3C-CAHs的研究空白,探讨它们的使用、排放、发生、命运和在环境基质中的运输。通过将它们与一碳和二碳CAHs进行比较,我们突出了3C-CAHs的独特性质和毒性特征。此外,我们讨论了3C-CAHs的最新处理技术,重点是吸附、化学处理和生物降解,并确定了各自的优势和局限性。我们还总结了美国和全球各州和联邦层面的法规,强调了许多3C-CAH化合物现有法规的不足。最后,我们提出了未来的研究需要进一步提高我们对3C-CAHs污染现状的认识,并促进开发可持续有效的处理方法来减轻其对环境的影响。总的来说,通过这篇综述,我们旨在提高人们对解决3C-CAHs在环境管理战略中的重要性的认识并激发讨论。
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引用次数: 0
Peracetic acid-driven advanced oxidation processes for wastewater treatment: Demystifying organic radicals and non-radical species 废水处理中过氧乙酸驱动的高级氧化工艺:揭开有机自由基和非自由基的神秘面纱
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-07-18 DOI: 10.1080/10643389.2025.2495637
Guanglei Yao, Xuefei Zhou, Haiping Gao, Tongcai Liu, Yalei Zhang, Jiabin Chen
Peracetic acid (PAA) based advanced oxidation processes (AOPs) have received increasing attention in wastewater treatment. However, it is challenging to identify the radical and/or non-radical species and elucidate the intrinsic interaction mechanisms involved in PAA-based AOPs. This work presents a systematic review of the selective generation mechanisms of radicals (hydroxyl and organic radicals), with a focus on organic radicals, and non-radical species (reactive complexes (RC), high-valent metals (HVM), singlet oxygen (1O2), and electron transfer process (ETP)). Furthermore, we examine various strategies for the precise identification and characterization of radical and/or non-radical species (e.g., quenching, chemical probes, spectroscopy, mass spectrometry, and electrochemical testing), and emphasize existing controversies. Subsequently, we provide an in-depth discussion of the reaction mechanisms between the reactive species and the contaminants/water matrices, as well as the potential for generating halogenated byproducts. Finally, we highlight the challenges and opportunities of the PAA-based AOPs in wastewater treatment, aiming to inspire future research endeavors that promote the practical application of PAA-based AOPs in wastewater treatment.
过氧乙酸(PAA)基深度氧化工艺(AOPs)在废水处理中受到越来越多的关注。然而,确定自由基和/或非自由基种类以及阐明paas基AOPs的内在相互作用机制具有挑战性。本文对自由基(羟基自由基和有机自由基)的选择性生成机制进行了系统的综述,重点介绍了有机自由基和非自由基(反应性配合物(RC)、高价金属(HVM)、单线态氧(1O2)和电子转移过程(ETP))。此外,我们研究了各种用于精确鉴定和表征自由基和/或非自由基物种的策略(例如,淬火,化学探针,光谱,质谱和电化学测试),并强调了现有的争议。随后,我们深入讨论了反应物质与污染物/水基质之间的反应机制,以及产生卤化副产物的可能性。最后,我们强调了paas基AOPs在废水处理中的挑战和机遇,旨在启发未来的研究工作,促进paas基AOPs在废水处理中的实际应用。
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引用次数: 0
Pretreatments of lignocellulosic biomass for biohydrogen biorefinery: Recent progress, techno-economic feasibility and prospectives 木质纤维素生物质用于生物制氢的预处理:最新进展、技术经济可行性和前景
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-07-18 DOI: 10.1080/10643389.2025.2484892
Zi-Tong Zhao, Jie Ding, Ji-Wei Pang, Mei-Yi Bao, Geng Luo, Bo-Yuan Wang, Bing-Feng Liu, Lu-Yan Zhang, Nan-Qi Ren, Shan-Shan Yang
Dark fermentation (DF) of lignocellulosic biomass (LB) is expected to play a critical role in building a green hydrogen supply chain toward the carbon-neutral society. Due to its inherent recalcitrance, biomass demands pretreatment to increase its digestibility. Various pretreatment techniques have been extensively investigated to improve the digestibility of feedstocks. However, no systematic review of pretreatment to promote biohydrogen fermentation has been conducted. Besides, studies analyzing the economic feasibility of pretreatment technologies are lacking. The aim of this review is to analyze the current pretreatment techniques and research results based on different driving forces. Intense thermochemical pretreatment dissolves lignin and hemicellulose and forms various inhibitors that interfere with the physiological and metabolic functions of the microbiota. Moreover, the issues related to the detoxification methods of inhibitors and their impacts on biomass fermentation were highlighted. The possibility of bioaugmentation of hydrogen-producing microflora with genetically engineered or naturally resistant bacteria may serve to be an effective in situ detoxification protocol. Moreover, the recycling techniques related to pretreatment were also discussed. Black liquor is a huge carbon reservoir with great potential to produce products such as biohydrogen and the value-added products generated will help reduce the environmental degradation caused by black liquor. Furthermore, the technical and economic viability of the current pretreatment methods and the prospects were also discussed. Increased costs related with buffering, reduced productivity and energy efficacy are critical factors contributing to the costs of bio-H2 production. For every 20% increase in H2 yield, production costs are decreased by 8%.
木质纤维素生物质(LB)的暗发酵(DF)有望在构建面向碳中和社会的绿色氢供应链中发挥关键作用。由于其固有的顽固性,生物质需要预处理以提高其消化率。各种预处理技术已被广泛研究,以提高原料的消化率。然而,目前还没有对预处理促进生物氢发酵进行系统的综述。此外,对预处理技术的经济可行性分析研究较少。本文旨在分析当前的预处理技术和基于不同驱动力的研究结果。强烈的热化学预处理溶解木质素和半纤维素,并形成各种抑制剂,干扰微生物群的生理和代谢功能。重点介绍了抑制剂解毒方法及其对生物质发酵的影响。利用基因工程或天然耐药细菌生物增强产氢微生物群的可能性可能是一种有效的原位解毒方案。并对预处理相关的回收技术进行了探讨。黑液是一个巨大的碳库,具有生产生物氢等产品的巨大潜力,其产生的增值产品有助于减少黑液对环境的破坏。并对现有预处理方法的技术经济可行性及前景进行了讨论。与缓冲相关的成本增加,生产力和能源效率的降低是影响生物h2生产成本的关键因素。氢气产量每增加20%,生产成本就会降低8%。
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引用次数: 0
Recent advances in layered double hydroxides for pharmaceutical wastewater treatment: A critical review 层状双氢氧化物在制药废水处理中的最新进展
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-07-18 DOI: 10.1080/10643389.2025.2488808
Yexiang Chen, Haihua Xu, M. Shahnawaz Khan, Shiqi Han, Sidi Zhu
In recent decades, pharmaceuticals, lauded for saving millions of lives, have surfaced as a new class of environmental contaminants. These compounds, originating primarily from hospital and industrial settings, often resist traditional treatment technologies and can persist in the environment for extended periods. The scarcity of water resources underscores the urgent need for innovative strategies for the effective management of pharmaceutical wastewater. Recently, layered double hydroxides (LDHs) have garnered considerable attention for their application in the remediation of pharmaceutical wastewater. This review explores the recent advancements in LDH-based adsorbents and membranes for pharmaceutical wastewater treatment. LDHs demonstrate superior adsorption capabilities due to their intercalation properties and structural versatility, effectively removing pharmaceutical contaminants such as antibiotics and anti-inflammatory drugs. Moreover, LDH-modified membranes enhance separation efficiency by improving permeability, selectivity, and fouling resistance. Advanced analytical techniques, including machine learning and synchrotron radiation, have provided deeper insights into the LDH mechanisms. However, challenges such as metal leaching, low mechanical durability, and limited scalability remain critical hurdles. Future research should focus on optimizing LDH stability, integrating adsorption with membrane separation techniques, and exploring hybrid treatment strategies. The recovery of valuable pharmaceuticals through LDH-based systems also presents a sustainable approach to wastewater management. This review highlights the potential of LDHs in pharmaceutical wastewater treatment while identifying key points for further development to enhance their practicality and large-scale application.
近几十年来,因拯救了数百万人的生命而备受赞誉的药品,已成为一类新的环境污染物。这些化合物主要来自医院和工业环境,往往抵抗传统的治疗技术,并可在环境中长期存在。水资源的稀缺强调了迫切需要创新战略来有效管理制药废水。近年来,层状双氢氧化物(LDHs)在制药废水修复中的应用受到了广泛的关注。本文综述了ldh基吸附剂和膜用于制药废水处理的最新进展。由于其插层特性和结构的通用性,LDHs具有优越的吸附能力,可以有效地去除抗生素和抗炎药物等药物污染物。此外,ldh改性膜通过提高渗透性、选择性和抗污性来提高分离效率。先进的分析技术,包括机器学习和同步辐射,为LDH机制提供了更深入的见解。然而,诸如金属浸出、低机械耐久性和有限的可扩展性等挑战仍然是关键障碍。未来的研究应着眼于优化LDH的稳定性,将吸附与膜分离技术相结合,探索混合处理策略。通过基于ldh的系统回收有价值的药物也为废水管理提供了一种可持续的方法。本文综述了LDHs在制药废水处理中的潜力,并指出了进一步发展的重点,以提高其实用性和大规模应用。
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引用次数: 0
Advancements of heavy metals control in the environment from detection to separation and recovery: Emerging microfluidics strategy 环境中重金属控制从检测到分离和回收的进展:新兴的微流体策略
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-07-03 DOI: 10.1080/10643389.2025.2483534
Xiaoyun Liu, Hongrui Xiang, Jiawei Li, Wenchao Zhang, Feiping Zhao, Qingwei Wang, Meiqing Shi, Yunyan Wang, Xu Yan, Liyuan Chai
Investigating the fate of heavy metals, especially natural environmental processes, requires innovation and precise technologies that can offer knowledge at the microscopic scale. Breakthrough of the microfluidics involved in heavy metals control has accelerated in recent years along with realization of the ubiquity, non-degradability, bioaccumulation, mobility and reactivity of heavy metals in the environment. This review explores recent advances in microfluidic applications for heavy metal control, spanning detection, separation, and recovery. Among microreactors, droplet-based systems demonstrate exceptional performance in detecting trace contaminants, achieving detection limits below 0.5 µg/L through enhanced mixing and reaction efficiency. For separation, liquid-liquid extraction microreactors stand out, with optimized interfaces yielding extraction efficiencies of up to 99.3% for cadmium (Cd) under specific flow and pH conditions. In the realm of recovery, electrochemical microreactors have shown potential for selective deposition, achieving high recovery rates at optimized current densities and tailored electrode materials. Future work will focus on the design and development of functional integration and scale-up of microfluidic systems/platforms, particularly in terms of the flexibility of microfluidic device design and assembly, as well as the efficiency of mass and heat transfer and reactions. The precise process control characteristics of microfluidic systems make them highly promising for applications in environmental monitoring, pollution control, and resource recovery.
调查重金属的命运,特别是自然环境过程,需要创新和精确的技术,可以在微观尺度上提供知识。近年来,随着重金属在环境中的普遍存在性、不可降解性、生物蓄积性、迁移性和反应性的实现,微流控技术在重金属控制方面的突破加快。本文综述了近年来微流体在重金属控制、检测、分离和回收等方面的应用进展。在微反应器中,基于液滴的系统在检测微量污染物方面表现出色,通过增强混合和反应效率,检测限低于0.5 μ g/L。在分离方面,液液萃取微反应器脱颖而出,在特定的流量和pH条件下,其优化的界面对镉(Cd)的萃取效率高达99.3%。在回收领域,电化学微反应器已经显示出选择性沉积的潜力,在优化的电流密度和定制的电极材料下实现高回收率。未来的工作将集中在微流控系统/平台的功能集成和规模扩展的设计和开发上,特别是在微流控装置设计和组装的灵活性以及传质、传热和反应的效率方面。微流控系统精确的过程控制特性使其在环境监测、污染控制和资源回收等方面具有很大的应用前景。
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引用次数: 0
New trend on chemical structure representation learning in toxicology: In reviews of machine learning model methodology 毒理学中化学结构表征学习的新趋势:机器学习模型方法综述
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-07-03 DOI: 10.1080/10643389.2025.2469868
Jiabin Zhang, Lei Zhao, Wei Wang, De-Feng Xing, Zhen-Xing Wang, Jun Ma, Aijie Wang, Nan-Qi Ren, Duu-Jong Lee, Chuan Chen
Computer-assisted virtual screening using structure-activity relationship (QSAR) models is a surrogate method for reducing the need for costly animal experiments. However, traditional QSAR models face significant challenges, such as the ‘activity cliff’ phenomenon and small datasets, which limit their ability to generalize and predict toxicity. This review examines transistion of digital encodings form in molecules and its corresponding models, introducing from molecule descriptors to three advanced types of molecular representations based on deep learning techniques. We highlight the importance of deep learning models that can not only capture molecular similarity in chemical space to address the ‘activity cliff’ problem but also improve model performance through feature fusion. As alternative solutions to reduce reliance on feature engineering potentially, graph neural network, convolutional neural network and large lanuage model and their related training paradigm such as transfer learning could give another opportunity for toxicity model setting in terms of data insuffient dealing etc. This work could help potential deep learning modelers to build robust model, setting the stage for groundbreaking advancements in further development and application of toxicity prediction models.
使用结构-活性关系(QSAR)模型的计算机辅助虚拟筛选是减少昂贵的动物实验需求的替代方法。然而,传统的QSAR模型面临着重大挑战,例如“活动悬崖”现象和小数据集,这限制了它们概括和预测毒性的能力。本文研究了数字编码形式在分子及其相应模型中的转换,介绍了从分子描述符到基于深度学习技术的三种高级分子表示类型。我们强调了深度学习模型的重要性,它不仅可以捕获化学空间中的分子相似性来解决“活动悬崖”问题,还可以通过特征融合提高模型性能。图神经网络、卷积神经网络和大型语言模型及其相关的训练范式(如迁移学习)作为潜在的减少对特征工程依赖的替代解决方案,可以在数据处理不足等方面为毒性模型设置提供另一个机会。这项工作可以帮助潜在的深度学习建模者建立稳健的模型,为进一步开发和应用毒性预测模型奠定突破性的进展。
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引用次数: 0
Advances in anammox process for municipal wastewater treatment plants: A review focusing on applied study and full-scale implementation cases 城市污水处理厂厌氧氨氧化工艺研究进展:以应用研究和大规模实施案例为重点
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-07-03 DOI: 10.1080/10643389.2025.2483522
Xin Yin, Wenqi Li, Meng Zhang, Rui Du, Chongjun Chen
Anaerobic ammonia oxidation (anammox) has become a prominent research topic in municipal wastewater treatment. It features significant advantages such as reduced organic carbon demand, decreased sludge generation, and realized energy-saving operations. This review summarizes the implementation situation of the anammox process in municipal wastewater treatment. First, the performance, process, and applied studies of the anammox process in sidestream and mainstream treatments are discussed. Additionally, full-scale implementation cases of the anammox process for treating municipal wastewater in various countries and regions were presented. Finally, future directions for anammox process in practical engineering were proposed to support energy self-sufficiency and carbon neutrality.
厌氧氨氧化(anammox)已成为城市污水处理领域的一个重要研究课题。它具有显著的优势,如减少有机碳需求,减少污泥产生,实现节能运行。综述了厌氧氨氧化工艺在城市污水处理中的应用现状。首先介绍了厌氧氨氧化工艺在侧流和主流处理中的性能、工艺及应用研究。此外,还介绍了不同国家和地区厌氧氨氧化工艺处理城市污水的全面实施案例。最后,提出了厌氧氨氧化工艺在实际工程中的发展方向,以支持能源自给和碳中和。
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引用次数: 0
Diffusive gradients in thin films (DGT) for measuring potentially bioavailable pesticide residues in soil systems: Current challenges and perspectives 用于测量土壤系统中潜在生物可利用农药残留的薄膜扩散梯度(DGT):当前的挑战和前景
IF 12.6 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-06-23 DOI: 10.1080/10643389.2025.2520553
Vijay Kumar Aralappanavar, Binoy Sarkar, Casey L. Doolette, Leigh Donnellan, Sean Mason, Michael Rose, Peter Hoffmann, Hao Zhang, Enzo Lombi
{"title":"Diffusive gradients in thin films (DGT) for measuring potentially bioavailable pesticide residues in soil systems: Current challenges and perspectives","authors":"Vijay Kumar Aralappanavar, Binoy Sarkar, Casey L. Doolette, Leigh Donnellan, Sean Mason, Michael Rose, Peter Hoffmann, Hao Zhang, Enzo Lombi","doi":"10.1080/10643389.2025.2520553","DOIUrl":"https://doi.org/10.1080/10643389.2025.2520553","url":null,"abstract":"","PeriodicalId":10823,"journal":{"name":"Critical Reviews in Environmental Science and Technology","volume":"47 1","pages":""},"PeriodicalIF":12.6,"publicationDate":"2025-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144341462","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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