The objective of this study was to determine the authorship, provenance, and technology of the mudejar enamelled tiles from the Olite Castle (northern Spain, 14th century). According to previous knowledge, Olite’s enamelled tiles had been manufactured in Manises (Valencia, Spain). The analysis of ceramic pastes revealed the existence of two different chemical compositions, suggesting the use of two different clay sources, probably one from the Tudela area, and another from the Tafalla–Olite area. Those probably made in the Tudela area stood out with a higher diopside (CaMgSi2O6) content. Those probably made in the Tafalla–Olite area stood out for their calcium-bearing minerals, such as calcite (CaCO3) or gehlenite (Ca2Al(AlSi)O7). On this basis, production in Manises has been ruled out. However, it is highly probable that the artisans of Manises would have led the production from Tudela. The study of the firing temperatures and composition of the enamels indicated that the production methods and materials used in Tafalla–Olite (800–850 °C) and Tudela (higher than 900 °C) were different, reflecting the influence of local and Manises artisans, respectively. In Olite tiles, enamel was applied following recipes from the 14th and 15th centuries.
{"title":"The Enamelled Tiles of Olite’s Castle (Spain): Characterization, Provenance, and Manufacture Technology","authors":"Iván Ruiz-Ardanaz, Esther Lasheras, Adrián Durán","doi":"10.3390/cryst14090813","DOIUrl":"https://doi.org/10.3390/cryst14090813","url":null,"abstract":"The objective of this study was to determine the authorship, provenance, and technology of the mudejar enamelled tiles from the Olite Castle (northern Spain, 14th century). According to previous knowledge, Olite’s enamelled tiles had been manufactured in Manises (Valencia, Spain). The analysis of ceramic pastes revealed the existence of two different chemical compositions, suggesting the use of two different clay sources, probably one from the Tudela area, and another from the Tafalla–Olite area. Those probably made in the Tudela area stood out with a higher diopside (CaMgSi2O6) content. Those probably made in the Tafalla–Olite area stood out for their calcium-bearing minerals, such as calcite (CaCO3) or gehlenite (Ca2Al(AlSi)O7). On this basis, production in Manises has been ruled out. However, it is highly probable that the artisans of Manises would have led the production from Tudela. The study of the firing temperatures and composition of the enamels indicated that the production methods and materials used in Tafalla–Olite (800–850 °C) and Tudela (higher than 900 °C) were different, reflecting the influence of local and Manises artisans, respectively. In Olite tiles, enamel was applied following recipes from the 14th and 15th centuries.","PeriodicalId":10855,"journal":{"name":"Crystals","volume":"1 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hengzheng Li, Shuai Chen, Yang Chen, Yan Liu, Zichen Tao, Yinghe Qin, Conghu Liu
In order to improve the wear resistance of copper and enhance the surface properties of copper parts, this article uses BN nanoparticles as a reinforcing phase and the laser remelting method to prepare a Cu/BN remelted layer on the copper surface. The surface morphology, crystal structure, microhardness, and wear resistance of the samples were tested and characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), a microhardness tester, and a friction and wear tester. The effects of laser frequency, pulse width, and energy density on the surface morphology and wear resistance of the samples were analyzed and studied, and the effects of the laser parameters on the properties of the Cu/BN remelted layer were discussed. The research results indicate that laser frequency, pulse width, and energy density have a direct impact on the surface morphology and properties of the Cu/BN remelted layer, but the impact mechanism by the above parameters on the remelted layer is different. The effects of laser frequency on the remelted layer are caused by changes in the overlap mode of the remelting points, while laser pulse width and energy density are achieved through changes in remelting intensity. When the laser frequency is 10 Hz, the pulse width is 10 ms, and the energy density is 165.8 J/mm2, the Cu/BN remelted layer has better surface properties.
{"title":"The Effects of Laser Parameters on the Wear Resistance of a Cu/BN Remelted Layer","authors":"Hengzheng Li, Shuai Chen, Yang Chen, Yan Liu, Zichen Tao, Yinghe Qin, Conghu Liu","doi":"10.3390/cryst14090809","DOIUrl":"https://doi.org/10.3390/cryst14090809","url":null,"abstract":"In order to improve the wear resistance of copper and enhance the surface properties of copper parts, this article uses BN nanoparticles as a reinforcing phase and the laser remelting method to prepare a Cu/BN remelted layer on the copper surface. The surface morphology, crystal structure, microhardness, and wear resistance of the samples were tested and characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), a microhardness tester, and a friction and wear tester. The effects of laser frequency, pulse width, and energy density on the surface morphology and wear resistance of the samples were analyzed and studied, and the effects of the laser parameters on the properties of the Cu/BN remelted layer were discussed. The research results indicate that laser frequency, pulse width, and energy density have a direct impact on the surface morphology and properties of the Cu/BN remelted layer, but the impact mechanism by the above parameters on the remelted layer is different. The effects of laser frequency on the remelted layer are caused by changes in the overlap mode of the remelting points, while laser pulse width and energy density are achieved through changes in remelting intensity. When the laser frequency is 10 Hz, the pulse width is 10 ms, and the energy density is 165.8 J/mm2, the Cu/BN remelted layer has better surface properties.","PeriodicalId":10855,"journal":{"name":"Crystals","volume":"12 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142202492","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In order to study the mechanism of microcrack generation in the process of pulsed laser polishing of zirconia ceramics and the influence of laser polishing process parameters on the surface temperature and surface stress, this paper establishes a finite element computational model of pulsed laser polishing of zirconia ceramics based on the COMSOL Multiphysics multi-physics field simulation software. Firstly, in the process of establishing the finite element model, the temperature field and stress field coupling is used to analyze the temperature field and stress field changes during the laser polishing process, which reveals the microcrack generation mechanism and size characteristics of zirconia ceramics in the process of pulsed laser polishing. Secondly, through parameterized scanning, the variation rules of surface temperature and surface stress were studied under different process parameters of laser power, scanning speed, pulse frequency and pulse width. Finally, the validity of the finite element calculation model is verified by the pulsed laser polishing zirconia ceramics experiment. The results show that, in a certain energy range, the high-energy laser beam can effectively reduce the surface roughness of the material, and with the increase in the time of laser action on the surface layer of the material, it will cause the temperature and thermal stress of the surface layer of the material to continue to accumulate, and when the stress value exceeds the yield limit of the material, cracks will form in the surface layer of the material; because the laser power, scanning speed, pulse frequency and pulse width are used to affect the laser energy density, and then, the pulse width will be affected by the process parameters of the laser energy density, and thus the surface temperature and thermal stress of the surface layer of the material. Because the laser power, scanning speed, pulse frequency and pulse width all affect the thermal stress on the material surface by influencing the laser energy density acting on the material surface, the laser energy density is the main influencing factor of the dimensional characteristics of the microcracks. In addition, the microcrack width and depth will increase when the laser energy density acting on the material surface layer increases.
{"title":"Pulsed Laser Polishing of Zirconia Ceramic Microcrack Generation Mechanism and Size Characterization Study","authors":"Zhanwang Zhou, Zhenyu Zhao, Jin He, Ruikang Shi","doi":"10.3390/cryst14090810","DOIUrl":"https://doi.org/10.3390/cryst14090810","url":null,"abstract":"In order to study the mechanism of microcrack generation in the process of pulsed laser polishing of zirconia ceramics and the influence of laser polishing process parameters on the surface temperature and surface stress, this paper establishes a finite element computational model of pulsed laser polishing of zirconia ceramics based on the COMSOL Multiphysics multi-physics field simulation software. Firstly, in the process of establishing the finite element model, the temperature field and stress field coupling is used to analyze the temperature field and stress field changes during the laser polishing process, which reveals the microcrack generation mechanism and size characteristics of zirconia ceramics in the process of pulsed laser polishing. Secondly, through parameterized scanning, the variation rules of surface temperature and surface stress were studied under different process parameters of laser power, scanning speed, pulse frequency and pulse width. Finally, the validity of the finite element calculation model is verified by the pulsed laser polishing zirconia ceramics experiment. The results show that, in a certain energy range, the high-energy laser beam can effectively reduce the surface roughness of the material, and with the increase in the time of laser action on the surface layer of the material, it will cause the temperature and thermal stress of the surface layer of the material to continue to accumulate, and when the stress value exceeds the yield limit of the material, cracks will form in the surface layer of the material; because the laser power, scanning speed, pulse frequency and pulse width are used to affect the laser energy density, and then, the pulse width will be affected by the process parameters of the laser energy density, and thus the surface temperature and thermal stress of the surface layer of the material. Because the laser power, scanning speed, pulse frequency and pulse width all affect the thermal stress on the material surface by influencing the laser energy density acting on the material surface, the laser energy density is the main influencing factor of the dimensional characteristics of the microcracks. In addition, the microcrack width and depth will increase when the laser energy density acting on the material surface layer increases.","PeriodicalId":10855,"journal":{"name":"Crystals","volume":"4 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142202496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fiora Artusio, Rafael Contreras-Montoya, José A. Gavira
The Special Issue “Advances in Pharmaceutical Crystals: Control over Nucleation and Polymorphism” collects eight papers focusing on different aspects of crystallization processes for pharmaceuticals [...]
{"title":"Advances in Pharmaceutical Crystals: Control over Nucleation and Polymorphism","authors":"Fiora Artusio, Rafael Contreras-Montoya, José A. Gavira","doi":"10.3390/cryst14090805","DOIUrl":"https://doi.org/10.3390/cryst14090805","url":null,"abstract":"The Special Issue “Advances in Pharmaceutical Crystals: Control over Nucleation and Polymorphism” collects eight papers focusing on different aspects of crystallization processes for pharmaceuticals [...]","PeriodicalId":10855,"journal":{"name":"Crystals","volume":"47 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142202490","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gallium nitride (GaN) semiconductors and their broadband InGaN alloys in their hexagonal phase have been extensively studied over the past 30 years and have allowed the development of blue-ray lasers, which are essential disruptive developments. In addition to high-efficiency white light-emitting diodes, which have revolutionized lighting technologies and generated a great industry around these semiconductors, several transistors have been developed that take advantage of the characteristics of these semiconductors. These include power transistors for high-frequency applications and high-power transistors for power electronics, among other devices, which have far superior achievements. However, less effort has been devoted to studying GaN and InGaN alloys grown in the cubic phase. The metastable or cubic phase of III-N alloys has superior characteristics compared to the hexagonal phase, mainly because of the excellent symmetry. It can be used to improve lighting technologies and develop other devices. Indium gallium nitride, InxGa1−xN alloy, has a variable band interval of 0.7 to 3.4 eV that covers almost the entire solar spectrum, making it a suitable material for increasing the efficiencies of photovoltaic devices. In this study, we successfully synthesized high-quality cubic InGaN films on MgO (100) substrates using plasma-assisted molecular beam epitaxy (PAMBE), demonstrating tunable emissions across the visible spectrum by varying the indium concentration. We significantly reduced the defect density and enhanced the crystalline quality by using an intermediate cubic GaN buffer layer. We not only developed a heterostructure with four GaN/InGaN/GaN quantum wells, achieving violet, blue, yellow, and red emissions, but also highlighted the immense potential of cubic InGaN films for high-efficiency light-emitting diodes and photovoltaic devices. Achieving better p-type doping levels is crucial for realizing diodes with excellent performance, and our findings will pave the way for this advancement.
氮化镓（GaN）半导体及其六方宽带 InGaN 合金在过去 30 年中得到了广泛的研究，并开发出了蓝光激光器，这是至关重要的颠覆性发展。高效白光发光二极管彻底改变了照明技术，并围绕这些半导体催生了一个巨大的产业，除此之外，利用这些半导体的特性还开发出了多种晶体管。其中包括用于高频应用的功率晶体管和用于电力电子设备的大功率晶体管等，这些器件都取得了卓越的成就。然而，人们在研究以立方相生长的氮化镓和氮化铟合金方面投入的精力较少。与六方相相比，III-N 合金的稳定相或立方相具有更优越的特性，这主要是因为它具有出色的对称性。它可用于改进照明技术和开发其他设备。氮化铟镓（InxGa1-xN 合金）具有 0.7 至 3.4 eV 的可变带区间，几乎覆盖了整个太阳光谱，因此是提高光伏设备效率的合适材料。在这项研究中，我们利用等离子体辅助分子束外延（PAMBE）技术在氧化镁（100）衬底上成功合成了高质量的立方 InGaN 薄膜，并通过改变铟的浓度在可见光谱范围内实现了可调发射。通过使用中间立方氮化镓缓冲层，我们大大降低了缺陷密度，提高了结晶质量。我们不仅开发出了具有四个 GaN/InGaN/GaN 量子阱的异质结构，实现了紫光、蓝光、黄光和红光的发射，还凸显了立方 InGaN 薄膜在高效发光二极管和光伏器件方面的巨大潜力。实现更好的 p 型掺杂水平对于实现性能卓越的二极管至关重要，而我们的研究成果将为这一进步铺平道路。
{"title":"Review of the Properties of GaN, InN, and Their Alloys Obtained in Cubic Phase on MgO Substrates by Plasma-Enhanced Molecular Beam Epitaxy","authors":"Edgar López Luna, Miguel Ángel Vidal","doi":"10.3390/cryst14090801","DOIUrl":"https://doi.org/10.3390/cryst14090801","url":null,"abstract":"Gallium nitride (GaN) semiconductors and their broadband InGaN alloys in their hexagonal phase have been extensively studied over the past 30 years and have allowed the development of blue-ray lasers, which are essential disruptive developments. In addition to high-efficiency white light-emitting diodes, which have revolutionized lighting technologies and generated a great industry around these semiconductors, several transistors have been developed that take advantage of the characteristics of these semiconductors. These include power transistors for high-frequency applications and high-power transistors for power electronics, among other devices, which have far superior achievements. However, less effort has been devoted to studying GaN and InGaN alloys grown in the cubic phase. The metastable or cubic phase of III-N alloys has superior characteristics compared to the hexagonal phase, mainly because of the excellent symmetry. It can be used to improve lighting technologies and develop other devices. Indium gallium nitride, InxGa1−xN alloy, has a variable band interval of 0.7 to 3.4 eV that covers almost the entire solar spectrum, making it a suitable material for increasing the efficiencies of photovoltaic devices. In this study, we successfully synthesized high-quality cubic InGaN films on MgO (100) substrates using plasma-assisted molecular beam epitaxy (PAMBE), demonstrating tunable emissions across the visible spectrum by varying the indium concentration. We significantly reduced the defect density and enhanced the crystalline quality by using an intermediate cubic GaN buffer layer. We not only developed a heterostructure with four GaN/InGaN/GaN quantum wells, achieving violet, blue, yellow, and red emissions, but also highlighted the immense potential of cubic InGaN films for high-efficiency light-emitting diodes and photovoltaic devices. Achieving better p-type doping levels is crucial for realizing diodes with excellent performance, and our findings will pave the way for this advancement.","PeriodicalId":10855,"journal":{"name":"Crystals","volume":"54 35 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142202493","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sn-Pb perovskite solar cells, which have the advantages of low toxicity and a simple preparation process, have witnessed rapid development in recent years, with the power conversion efficiency for single-junction solar cells exceeding 23%. Nevertheless, the problems of poor crystalline quality of Sn-Pb perovskite films arising from rapid crystallization rate and facile oxidation of Sn2+ to Sn4+ have become key issues for the further development of Sn-Pb perovskite solar cells. Herein, we report the incorporation of triazinamide (N-(6-methyl-3-oxo-2,5-dihydro-1,2,4-Triazin-4(3H)-YL) acetamide) as an additive to regulate the crystalline growth of Sn-Pb perovskite films, resulting in films with low trap density and large grain size. The triazinamide additive effectively passivated defects in the perovskite films. As a result, the triazinamide-modified perovskite solar cells achieved a higher efficiency of 15.73%, compared with 13.32% for the control device, significantly improving device performance. Notably, the optimal triazinamide-modified perovskite solar cell maintained 72% of its initial power conversion efficiency after being stored in an air environment for nearly 300 h, while only 18% of the power conversion efficiency of the control perovskite solar cell was retained. This study proposes an effective strategy for fabricating highly efficient and stable Sn-Pb perovskite solar cells.
{"title":"Defect Passivation for Highly Efficient and Stable Sn-Pb Perovskite Solar Cells","authors":"Tengteng Li, Fupeng Ma, Yafeng Hao, Huijia Wu, Pu Zhu, Ziwei Li, Fengchao Li, Jiangang Yu, Meihong Liu, Cheng Lei, Ting Liang","doi":"10.3390/cryst14090802","DOIUrl":"https://doi.org/10.3390/cryst14090802","url":null,"abstract":"Sn-Pb perovskite solar cells, which have the advantages of low toxicity and a simple preparation process, have witnessed rapid development in recent years, with the power conversion efficiency for single-junction solar cells exceeding 23%. Nevertheless, the problems of poor crystalline quality of Sn-Pb perovskite films arising from rapid crystallization rate and facile oxidation of Sn2+ to Sn4+ have become key issues for the further development of Sn-Pb perovskite solar cells. Herein, we report the incorporation of triazinamide (N-(6-methyl-3-oxo-2,5-dihydro-1,2,4-Triazin-4(3H)-YL) acetamide) as an additive to regulate the crystalline growth of Sn-Pb perovskite films, resulting in films with low trap density and large grain size. The triazinamide additive effectively passivated defects in the perovskite films. As a result, the triazinamide-modified perovskite solar cells achieved a higher efficiency of 15.73%, compared with 13.32% for the control device, significantly improving device performance. Notably, the optimal triazinamide-modified perovskite solar cell maintained 72% of its initial power conversion efficiency after being stored in an air environment for nearly 300 h, while only 18% of the power conversion efficiency of the control perovskite solar cell was retained. This study proposes an effective strategy for fabricating highly efficient and stable Sn-Pb perovskite solar cells.","PeriodicalId":10855,"journal":{"name":"Crystals","volume":"8 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142202494","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The split-sleeve cold expansion technology is widely used in the aerospace industry, particularly for fastening holes, to enhance the fatigue life of components. However, to ensure proper assembly and improve surface integrity, reaming of the cold-expanded holes is necessary. This study investigates the effects of cold expansion and reaming processes on the fatigue performance of 7050-T7451 aluminum alloy. Fatigue tests, residual stress measurements, and microstructural analyses of the hole edges were conducted on specimens with four different hole diameters after cold expansion and reaming. It was found that the depth of reaming significantly affects fatigue life. During the cold expansion process, the compressive residual stress formed around the hole effectively improves fatigue performance. The experiments demonstrated that reaming by 0.2 mm to 0.4 mm helps eliminate minor defects, thereby improving fatigue life. However, reaming beyond 0.5 mm may lead to stress relief and the removal of dense grains at the hole edges, reducing fatigue life. Therefore, determining the optimal reaming size is crucial for enhancing the reliability of aerospace fasteners.
{"title":"Experimental Study of Reaming Sizes on Fatigue Life of Cold-Expanded 7050-T7451 Aluminum Alloy","authors":"Muyu Guan, Qichao Xue, Zixin Zhuang, Quansheng Hu, Hui Qi","doi":"10.3390/cryst14090803","DOIUrl":"https://doi.org/10.3390/cryst14090803","url":null,"abstract":"The split-sleeve cold expansion technology is widely used in the aerospace industry, particularly for fastening holes, to enhance the fatigue life of components. However, to ensure proper assembly and improve surface integrity, reaming of the cold-expanded holes is necessary. This study investigates the effects of cold expansion and reaming processes on the fatigue performance of 7050-T7451 aluminum alloy. Fatigue tests, residual stress measurements, and microstructural analyses of the hole edges were conducted on specimens with four different hole diameters after cold expansion and reaming. It was found that the depth of reaming significantly affects fatigue life. During the cold expansion process, the compressive residual stress formed around the hole effectively improves fatigue performance. The experiments demonstrated that reaming by 0.2 mm to 0.4 mm helps eliminate minor defects, thereby improving fatigue life. However, reaming beyond 0.5 mm may lead to stress relief and the removal of dense grains at the hole edges, reducing fatigue life. Therefore, determining the optimal reaming size is crucial for enhancing the reliability of aerospace fasteners.","PeriodicalId":10855,"journal":{"name":"Crystals","volume":"93 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142202495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In recent years, many studies have been published on CVD diamond growth, but the reason for the irregular blue surface fluorescence of CVD diamond under ultra-deep UV radiation (i.e., under DiamondView) is still unclear. Here, a batch of as-grown and LPHT-annealed CVD synthetic diamond samples from a Chinese company in Zhejiang were analyzed for the various spectral (infrared (IR), UV–visible absorption, Raman, and photoluminescence (PL)) characteristics to explore the origin of surface blue fluorescence. The results show that the samples are nitrogen-doped type IIa CVD synthetic diamonds. Spectral peaks of the earlier CVD products, e.g., 3123 cm−1 (NVH0) (IR absorption spectrum) and 596/597 nm (PL emission spectrum), are absent in these samples, while the peaks at 736.5/736.8 nm (SiV−) in the UV or PL spectra are less common. PL spectra and DiamondView fluorescence indicate that the samples have generally strong luminescence peaks at 637 nm in the NV− center, 575 nm in the NV0 center, and other luminescence peaks caused by nitrogen-related defects. The as-grown samples observed under DiamondView show orange-red fluorescence accompanied by striations due to step-flow growth, and blue fluorescence appears as irregular threads or bundles on the surface. The LPHT-annealed sample shows weaker fluorescence with localized patches of green fluorescence contributed by weak H3 centers. The micro-IR spectra suggest that the unique blue fluorescence in the CVD diamond may be related to the dislocations caused by sp3-CH2 due to the incomplete dehydrogenation of hydrocarbon groups in the raw material.
{"title":"Spectral Characteristics of Nitrogen-Doped CVD Synthetic Diamonds and the Origin of Surface Blue Fluorescence","authors":"Yu Zhang, Guanghai Shi, Zixuan Xie","doi":"10.3390/cryst14090804","DOIUrl":"https://doi.org/10.3390/cryst14090804","url":null,"abstract":"In recent years, many studies have been published on CVD diamond growth, but the reason for the irregular blue surface fluorescence of CVD diamond under ultra-deep UV radiation (i.e., under DiamondView) is still unclear. Here, a batch of as-grown and LPHT-annealed CVD synthetic diamond samples from a Chinese company in Zhejiang were analyzed for the various spectral (infrared (IR), UV–visible absorption, Raman, and photoluminescence (PL)) characteristics to explore the origin of surface blue fluorescence. The results show that the samples are nitrogen-doped type IIa CVD synthetic diamonds. Spectral peaks of the earlier CVD products, e.g., 3123 cm−1 (NVH0) (IR absorption spectrum) and 596/597 nm (PL emission spectrum), are absent in these samples, while the peaks at 736.5/736.8 nm (SiV−) in the UV or PL spectra are less common. PL spectra and DiamondView fluorescence indicate that the samples have generally strong luminescence peaks at 637 nm in the NV− center, 575 nm in the NV0 center, and other luminescence peaks caused by nitrogen-related defects. The as-grown samples observed under DiamondView show orange-red fluorescence accompanied by striations due to step-flow growth, and blue fluorescence appears as irregular threads or bundles on the surface. The LPHT-annealed sample shows weaker fluorescence with localized patches of green fluorescence contributed by weak H3 centers. The micro-IR spectra suggest that the unique blue fluorescence in the CVD diamond may be related to the dislocations caused by sp3-CH2 due to the incomplete dehydrogenation of hydrocarbon groups in the raw material.","PeriodicalId":10855,"journal":{"name":"Crystals","volume":"25 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142202497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Germanium (Ge) is a system-forming material of IR photonics for the atmospheric transparency window of 8–14 µm. For optics of the 3–5 µm range, more widespread silicon (Si), which has phonon absorption bands in the long-wave region, is predominantly used. A technology for growing Ge single crystals has been developed, allowing the production of precision optical parts up to 500 mm in diameter. Ge is used primarily for the production of transparent optical parts for thermal imaging devices in the 8–14 µm range. In addition, germanium components are widely used in a large number of optical devices where such properties as mechanical strength, good thermal properties, and climatic resistance are required. A very important area of application of germanium is nonlinear optics, primarily acousto-optics. The influence of doping impurities and temperature on the absorption of IR radiation in germanium is considered in detail. The properties of germanium photodetectors are reported, primarily on the effect of photon drag of holes. Optical properties in the THz range are considered. The features of optical properties for all five stable isotopes of germanium are studied. The isotopic shift of absorption bands in the IR region, caused by phonon phenomena, which was discovered by the authors for the first time, is considered.
{"title":"Germanium Single Crystals for Photonics","authors":"Grigory Kropotov, Vladimir Rogalin, Ivan Kaplunov","doi":"10.3390/cryst14090796","DOIUrl":"https://doi.org/10.3390/cryst14090796","url":null,"abstract":"Germanium (Ge) is a system-forming material of IR photonics for the atmospheric transparency window of 8–14 µm. For optics of the 3–5 µm range, more widespread silicon (Si), which has phonon absorption bands in the long-wave region, is predominantly used. A technology for growing Ge single crystals has been developed, allowing the production of precision optical parts up to 500 mm in diameter. Ge is used primarily for the production of transparent optical parts for thermal imaging devices in the 8–14 µm range. In addition, germanium components are widely used in a large number of optical devices where such properties as mechanical strength, good thermal properties, and climatic resistance are required. A very important area of application of germanium is nonlinear optics, primarily acousto-optics. The influence of doping impurities and temperature on the absorption of IR radiation in germanium is considered in detail. The properties of germanium photodetectors are reported, primarily on the effect of photon drag of holes. Optical properties in the THz range are considered. The features of optical properties for all five stable isotopes of germanium are studied. The isotopic shift of absorption bands in the IR region, caused by phonon phenomena, which was discovered by the authors for the first time, is considered.","PeriodicalId":10855,"journal":{"name":"Crystals","volume":"20 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142202499","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
To improve the electrochemical activity and discharge performance of an aluminum-air (Al-air) battery, a commercial 6061 alloy (Al6061) was selected as the anode, and CeO2 was also added inside the anode to enhance its performance. The CeO2/Al6061 composite was prepared using selective laser melting (SLM) technology. The influence of hatch spacing on the forming quality, corrosion resistance, and discharge performance of the anode was studied in detail. The results showed that with an increase in hatch spacing, the density, corrosion resistance, and discharge performance of the anode first increased and then decreased. When the hatch spacing is 0.13 mm, the anode has the best forming quality. At this point, the density reaches 98.39%, and the self-corrosion rate (SCR) decreases to 2.596 × 10−4 g·cm−2·min−1. Meanwhile, the anode exhibits its highest electrochemical activity and discharge voltage, which is up to −1.570 V. The change in anode performance is related to the defects generated during the SLM forming process. For samples with fewer defects, the anode can dissolve uniformly, while for samples with more defects, the electrode solution is prone to penetrate the defects, causing uneven corrosion and reducing electrochemical and discharge activity.
{"title":"The Effect of Hatch Spacing on the Electrochemistry and Discharge Performance of a CeO2/Al6061 Anode for an Al-Air Battery via Selective Laser Melting","authors":"Yinbiao Li, Weipeng Duan","doi":"10.3390/cryst14090797","DOIUrl":"https://doi.org/10.3390/cryst14090797","url":null,"abstract":"To improve the electrochemical activity and discharge performance of an aluminum-air (Al-air) battery, a commercial 6061 alloy (Al6061) was selected as the anode, and CeO2 was also added inside the anode to enhance its performance. The CeO2/Al6061 composite was prepared using selective laser melting (SLM) technology. The influence of hatch spacing on the forming quality, corrosion resistance, and discharge performance of the anode was studied in detail. The results showed that with an increase in hatch spacing, the density, corrosion resistance, and discharge performance of the anode first increased and then decreased. When the hatch spacing is 0.13 mm, the anode has the best forming quality. At this point, the density reaches 98.39%, and the self-corrosion rate (SCR) decreases to 2.596 × 10−4 g·cm−2·min−1. Meanwhile, the anode exhibits its highest electrochemical activity and discharge voltage, which is up to −1.570 V. The change in anode performance is related to the defects generated during the SLM forming process. For samples with fewer defects, the anode can dissolve uniformly, while for samples with more defects, the electrode solution is prone to penetrate the defects, causing uneven corrosion and reducing electrochemical and discharge activity.","PeriodicalId":10855,"journal":{"name":"Crystals","volume":"186 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142202500","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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