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First Application in Oman of New Single Stage Retarded Sandstone Matrix Acidizing 新型单级缓速砂岩基质酸化在阿曼的首次应用
Pub Date : 2022-03-21 DOI: 10.2118/200297-ms
Hajir Qassabi, A. Rafliansyah, Johnny Falla, Ahmed Al-Yaaribi
The objective of matrix acidizing in sandstone reservoirs using acid systems that contains Hydrofluoric acid (HF) is to widen the pore throats and spaces in order to increase the permeability around the wellbore and also to remove formation damage. One of the major disadvantages of this acid system is the secondary and tertiary reactions, which may end up with precipitations that damage the formation. Because of this, pumping sufficient pre- flush and post-flush volumes of Hydrochloric acid (HCl) is critical to prevent such damaging reactions. However, the placement of such fluids still are a concern in multiple opened layers or long open intervals zones. Stimulating sandstone reservoirs in the Southern fields of the Sultanate of Oman is very challenging, especially in those that exhibit relatively low permeability. These formations, based on petrology work, contains significant amount of clays and feldspars, which make it difficult in the designing process of the acid formulation. A new version of HF acid system was recently developed. It is specially formulated, so it does not require the addition of Hydrochloric acid (HCl) pre-flush. Because of this, it can be pumped as a single stage system. In addition, its higher reactivity allows deeper penetration and it has the ability to minimize secondary reactions and damaging precipitates. Lab testing work was conducted to ensure the effectiveness of this single stage acid system. The results were promising as they show a good improvement in the rock permeability. These results were encouraging to carry field trials in the sandstone reservoirs in Oman Southern fields. Up to now, it has been pumped in these type of sandstones for oil producer wells and for water injector wells. The actual treatment using this system showed increased oil productivity by higher than 60% and higher than 80% in water injectivity. This paper presents the testing, designing and pumping of the single stage acid system, as well as the comparison with the conventional HF acid system in Southern fields of Oman. It outlines the laboratory work and analysis done as well as the field trials.
使用含氢氟酸(HF)的酸体系对砂岩储层进行基质酸化的目的是拓宽孔喉和孔隙空间,以增加井筒周围的渗透率,并消除地层损害。这种酸体系的主要缺点之一是二级和三级反应,最终可能产生损害地层的沉淀。因此,在冲洗前和冲洗后泵入足够量的盐酸(HCl)对于防止此类破坏性反应至关重要。然而,在多开放层或长开放层段的地层中,此类流体的放置仍然是一个问题。对阿曼苏丹国南部油田的砂岩储层进行增产是非常具有挑战性的,特别是在那些渗透率相对较低的地区。根据岩石学研究,这些地层含有大量的粘土和长石,这给酸配方的设计过程带来了困难。最近开发了一种新型的HF酸体系。它是特殊配方,因此不需要添加盐酸(HCl)预冲洗。因此,它可以作为单级系统泵送。此外,其较高的反应性允许更深的穿透,并具有最大限度地减少二次反应和破坏性沉淀的能力。进行了实验室测试工作,以确保该单级酸体系的有效性。结果表明,岩石的渗透性得到了很好的改善,这是有希望的。这些结果鼓舞了阿曼南部油田砂岩储层的现场试验。到目前为止,已在采油井和注水井中泵入这类砂岩。使用该系统的实际处理表明,采油能力提高了60%以上,注水能力提高了80%以上。介绍了阿曼南部油田单级酸系统的试验、设计和泵送情况,并与常规HF酸系统进行了比较。它概述了实验室工作和所做的分析以及现场试验。
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引用次数: 0
Feasibility of Ion-Modified Water for Low Salinity Water Flooding: A Case Study for Ultra-High-Salinity Carbonate Reservoir in Akanskoe Oilfield Tatarstan, Russia 离子改性水用于低矿化度水驱的可行性——以俄罗斯鞑靼斯坦Akanskoe油田超高矿化度碳酸盐岩油藏为例
Pub Date : 2022-03-21 DOI: 10.2118/200046-ms
M. Varfolomeev, Mojtaba Rezaei Koochi, C. Yuan, R. Khayrtdinov, A. Mustafin, M. Glukhov, R. Kadyrov, V. Sudakov, S. Usmanov
This paper presents the feasibility of the application of ion-modified water for enhanced oil recovery (EOR) in low permeable carbonate reservoir with ultra-high salinity of more than 220000 mg/L. Influence of different ions on wettability alteration, interfacial tension (IFT), scale tendency, recovery factor, and water injectivity was investigated. For choosing the optimized injection-water sequence, different types of water (formation water, distilled water, fresh water, and ion-modified water) were used. First, their effects on wettability alteration by measuring contact angle (oil-water-rock) and IFT were evaluated. Then, core flooding experiments were carried out to investigate how different injection sequence affects the oil recovery and injectivity. Furthermore, the scale tendency of different salts was simulated. The results showed that Mg2+ is the most effective ion. The addition of Mg2+ can fast change the oil-wet (130°) carbonate rock to water-wet (29°). The presence of mono-valent ions has negative effects on the effectiveness of Mg2+ on wettability alteration. Also, the presence of Mg2+ in fresh water and distilled water can reduce oil-water IFT two times lower. Core flooding experiments showed that after fresh water or formation water flooding (until 100% water cut), the sequent diluted formation water (diluted 10 times) yielded incremental oil recovery of about 3-5%, while the Mg2+ modified water obtained incremental oil recovery of about 8-18%. This indicates that Mg2+ modified water has a promising prospect in EOR in carbonate reservoirs. A comprehensive analysis combining contact angle measurements, IFT testing, and core flooding experiments indicates that the high efficiency of Mg2+ modified fresh water for EOR mainly benefits from its strong wettability alteration ability. In addition, it was found that the existence of Mg2+ and SO42− can reduce the tendency of precipitation of salts compared with using only fresh water or diluted formation water. This work proves that ion-modified water by adding Mg2+ to fresh water can be an effective, low cost and environment-friendly EOR method for low-permeability carbonate reservoirs with ultra-high salinity. Simultaneously, this research provides some basic data that can help to enrich the theory for developing low salinity water flooding for EOR.
介绍了离子改性水应用于220000 mg/L以上超高矿化度低渗透碳酸盐岩储层提高采收率的可行性。研究了不同离子对润湿性变化、界面张力、结垢倾向、采收率和注水能力的影响。为了选择最佳注水顺序,采用了不同类型的水(地层水、蒸馏水、淡水和离子改性水)。首先,通过测量接触角(油-水-岩)和IFT来评价它们对润湿性变化的影响。通过岩心驱油实验,研究了不同注入顺序对采收率和注入能力的影响。此外,还模拟了不同盐类的结垢趋势。结果表明,Mg2+是最有效的离子。Mg2+的加入能使130°的油湿型碳酸盐岩快速转变为29°的水湿型碳酸盐岩。一价离子的存在对Mg2+润湿性改变的有效性有负面影响。此外,淡水和蒸馏水中Mg2+的存在可使油水IFT降低2倍。岩心驱油实验表明,淡水或地层水驱油(至含水率100%)后,后续稀释地层水(稀释10倍)的产油量增量约为3-5%,而Mg2+改性水的产油量增量约为8-18%。这表明Mg2+改性水在碳酸盐岩储层提高采收率方面具有广阔的应用前景。结合接触角测量、IFT测试和岩心驱替实验综合分析表明,Mg2+改性淡水提高采收率的高效主要得益于其较强的润湿性蚀变能力。此外,与仅使用淡水或稀释的地层水相比,Mg2+和SO42−的存在可以降低盐的沉淀趋势。本研究证明,在淡水中加入Mg2+离子改性水是一种有效、低成本、环保的超低矿化度碳酸盐岩低渗透储层提高采收率方法。同时,本研究也为开发低矿化度水驱提高采收率提供了一些基础数据。
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引用次数: 2
Velocity Strings in Sultanate of Oman Gas Fields; A Case Study 阿曼苏丹国气田速度串研究案例研究
Pub Date : 2022-03-21 DOI: 10.2118/200241-ms
N. Janusz
Petroleum Development Oman operates large amount of gas wells in Sultanate of Oman. Due to the liquid loading occurring in these ageing assets, PDO has already installed 110+ Velocity String completions in the various gas fields across the concession area. In the 2015–2019 period, 39 wells in the Saih Rawl field were retrofitted with Velocity Strings. This paper presents the integrated and standardized approach to Velocity String candidate selection and compares the production performance post-installation against the forecast.
阿曼石油开发公司在阿曼苏丹国经营着大量的气井。由于这些老化资产中出现了液体负荷,PDO已经在特许区域的各个气田安装了110多个速度管柱完井。在2015-2019年期间,Saih Rawl油田的39口井进行了Velocity管柱改造。本文介绍了速度管柱候选选择的集成和标准化方法,并将安装后的生产性能与预测进行了比较。
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引用次数: 0
Well Revival in an Offshore Marginal Field Using Through Tubing Straddle Gas Lift Technology - A Case Study 利用跨管气举技术在海上边缘油田进行油井改造—案例研究
Pub Date : 2022-03-21 DOI: 10.2118/200075-ms
R. Vijay, M. Khanna, PJ Sarma
LG is a marginal offshore field lying in the west coast of India. Well A and B in field LG were completed using 4 ½ - in and 3 ½ - in single-string multizone completion intersecting gas and oil-bearing zones. During the initial phase of its production, the wells only produced gas, until the oil-bearing sands were perforated, and the wells produced commingled gas and oil. These wells had been flowing naturally on self-drive and recently ceased to flow after showing gradual decline in their production. The diagnosis suggested a failure of Vertical Lift Performance (VLP) indicating a need to change the production technique and possibly a need for artificial lift in the wells to bring them online. The paper discusses an innovative and cost-effective approach involving the implementation of through-tubing mechanical straddle pack-off with gas lift assistance to bring the wells back to production and increasing the overall recovery from the field. A detailed analysis of the various techniques for bringing the well online was evaluated keeping in mind the associated cost and time for each method. The considerations lead to the plan of introducing gas lift as an artificial lift method for these wells. Wells A and B were not equipped with any gas lift mandrel for introducing artificial gas lift. Workover for these wells would result in higher cost, time & risk factors for the wells. The economic viability of such a workover was not justifiable given the incremental production anticipated. After performing a detailed technical and economic analysis, the decision was made to implement a through-tubing gas lift technique using a straddle packer conveyed on slickline across the circulation Sliding Sleeve Door (SSD). The straddle pack-off was to be introduced in the existing 4 ½ - in and 3 ½ - in production tubing with internally mounted gas lift mandrels/orifice valves. Detailed modelling was performed to determine the correct orifice size for different lift parameters. The operations in candidate wells A and B were successfully conducted and the surface setup for the gas lift was installed. The mechanical pack-off was set at the desired depths without any issue, and the gas was injected through the annulus leading to instantaneous production from the well. The total operations period was minimal as compared to the workover operations, far safer and more cost-effective for the production enhancement achieved. This paper describes the job design, technique implemented, and challenges overcome during the successful activation of a theoretically dead well to 1000 BOPD production, establishing the viability of through-tubing gas lifting. Learnings from the paper will help professionals plan for such well interventions involving the use of mechanical straddle pack off for gas lift operations.
LG是位于印度西海岸的一个边缘海上油田。LG油田的A井和B井分别采用了4 1 / 2英寸和3 1 / 2英寸的单管柱多层完井,并与含气层和含油层相交。在生产的初始阶段,这些井只产气,直到含油砂岩射孔,这些井才开始产油气混合。这些井一直处于自驱状态,最近在产量逐渐下降后停止了生产。诊断结果表明,垂直举升性能(VLP)出现故障,表明需要改变生产技术,可能需要在井中进行人工举升以使其上线。本文讨论了一种创新且具有成本效益的方法,该方法涉及在气举辅助下实施过油管机械跨式封隔,以使油井恢复生产并提高油田的整体采收率。考虑到每种方法的相关成本和时间,详细分析了使油井上线的各种技术。考虑到这些因素,我们计划在这些井中引入气举作为人工举升方法。A井和B井没有安装人工气举的气举心轴。对这些井进行修井将导致更高的成本、时间和风险因素。考虑到预期的增产,这种修井的经济可行性是不合理的。在进行了详细的技术和经济分析后,作业者决定采用跨立封隔器,通过钢丝绳通过循环滑套门(SSD)进行气举。跨式封隔器将被引入现有的4½in和3½in生产油管中,这些油管内部安装有气举心轴/孔板阀。进行了详细的建模,以确定不同升力参数下正确的孔口尺寸。候选井A和B的作业成功进行,并安装了气举地面装置。机械封隔器安装在所需的深度,没有任何问题,气体通过环空注入,从而实现了井的瞬时生产。与修井作业相比,总作业周期最短,更安全,更具成本效益,实现了增产。本文介绍了作业设计、实施的技术以及在成功激活一口理论上无活井至1000桶/天的生产过程中所克服的挑战,从而确立了通过油管气举的可行性。从论文中获得的知识将有助于专业人员制定涉及气举作业中使用机械跨式封隔器的井干预计划。
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引用次数: 0
Precision Shut-In and Pressure Control Drilling in Injection Wells Around Adjustment Well Based on Injection-Production Data Mining 基于注采数据挖掘的调整井周围注水井精密关井控压钻井
Pub Date : 2022-03-21 DOI: 10.2118/200030-ms
L. Zhong, Tongchun Hao, Jie Xu, Xiaocheng Zhang, Xiaopeng Wang, Tao Xie, Tao Lin, Lei Zhang
Affected by the surrounding injection and production wells, the formation near the infill adjustment well is in an abnormal pressure state, and drilling and completion operations are prone to complex situations and accidents such as leakage and overflow. The conventional shut down method is to close all water injection wells within 500 meters from the adjustment well to ensure the safety of the operation, but at the same time reduce the oil field production. This paper proposes a design method for shut-in of water injection wells around adjustment wells based on injection-production data mining. This method is based on the influence of correlation of complex pressure wells under injection and production conditions, and uses water injection index and fluid production index as research objects. Data mining methods are used to find highly correlated wells for precise adjustment instead of conventional adjustment. This method was applied to 20 infill adjustment wells in the Penglai Oilfield in Bohai Sea. The correlation between injection and production wells was calculated using the water injection index and fluid production index of more than 500 injection wells and production wells. Controlling the precise shut-in of highly correlated wells ensures that well pressures are kept within safe limits during drilling and completion operations and that no abnormalities occur. Low-relevant wells do not take shut-in adjustment measures. After a single adjustment well is drilled, the surrounding injection wells can increase the water injection volume by more than 5000m3. This method achieves accurate shut-in for water injection wells that are highly correlated with the adjustment well. Under the premise of ensuring the safety of drilling operations, the impact of adjusting drilling and completion on oilfield development is minimized, and oilfield production efficiency is improved. It has good application and promotion value.
受周围注采井的影响,充填调整井附近地层处于异常压力状态,钻完井作业容易发生泄漏、溢流等复杂情况和事故。常规关井方法是关闭距调整井500米范围内的所有注水井,在保证作业安全的同时降低油田产量。提出了一种基于注采数据挖掘的调整井周围注水井关井设计方法。该方法基于注采条件下复杂压力井相关性的影响,以注水量指数和产液指数为研究对象。利用数据挖掘方法寻找高相关井进行精确平差,代替常规平差。将该方法应用于渤海蓬莱油田20口充填调整井。利用500多口注水井和生产井的注水指数和产液指数,计算了注水井和生产井之间的相关性。控制高度相关井的精确关井,可确保在钻井和完井作业期间将井压保持在安全范围内,不会发生异常。低相关井不采取关井调整措施。单井调整后,周边注水井可增加注水量5000m3以上。该方法可实现与调整井高度相关的注水井的精确关井。在保证钻井作业安全的前提下,尽量减少调钻完井对油田开发的影响,提高油田生产效率。具有良好的应用和推广价值。
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引用次数: 0
Hydraulic Fracturing Challenges and Solutions for the Development of a Low Permeability Oil Reservoir – Case History from Offshore West Africa 低渗透油藏开发的水力压裂挑战与解决方案——西非海上的历史案例
Pub Date : 2022-03-21 DOI: 10.2118/200115-ms
G. Tassone, M. Giammancheri, S. Banoori, Sabino Parziale, V. Mittiga, R. Ilyasov, Nicolas Dupouy, B. Reilly
The operator in West Africa embarked upon the "N" field offshore development in 2016 with 13 multi-stage horizontal wells being fracture-stimulated in Phase-I, with further wells being planned in next development phases. Due to the complex nature of the reservoir, which is a multilayered sandstone characterized by high heterogeneity and low permeability, wellbore connections are often located in structurally altered areas with high presence of faults. The unpredictable local re-orientation of the stresses has resulted in complications for the fracturing operations with multiple fractures being induced. This paper presents the challenges and solutions implemented for delivering more consistent fracturing execution and well productivity improvements. The horizontal wells in the "N" field were hydraulically fractured using the "plug-and-perf" method with up to four fractured intervals. The quality of the near-wellbore connection and the observations of complex near-wellbore fracture geometries have hindered far-field proppant distribution and limited maximum proppant concentration inside the fracture. When fracturing this tight formation, controlling the opening of the pressure-dependent multiple fractures was identified as a critical issue. An engineering breakdown process and adapted frac strategy was implemented to minimize the multiple fractures generated at the formation. For the early hydraulic fracture treatments performed, conservative treatment designs were applied in order to avoid premature screenout with the consequence of increasing operative time. Implemented solutions have shown to improve the near-wellbore connections and increase well productivity. The successful outcomes are attributed to the implementation of improved perforating strategies, the optimization of fracturing fluid performance, an engineered fracturing breakdown process, and the development of a frac decision tree for improved decision making. The hydraulic frac strategy has been tailored well-by-well depending on the reservoir conditions (e.g. faults, permeability thickness, contacts), and on the operational conditions interpreted from the diagnostic injection tests (e.g. near wellbore tortuosity, net pressure). The holistic implementation of these new concepts for hydraulic fracturing and field development have delivered positive production results beyond initial expectations. For the horizontal wells intersecting the deep low permeability "D" reservoir, the risk of multiple fractures and influence of tortuosity have been diminished through corrective techniques and unique solutions applied for each fracturing stage.
2016年,西非的运营商开始了“N”油田的海上开发,在第一阶段进行了13口多级水平井的压裂改造,并计划在下一个开发阶段开发更多的井。由于储层性质复杂,是一种多层砂岩,具有高非均质性和低渗透率的特点,因此井眼连接处通常位于构造蚀变区,并且存在大量断层。不可预测的局部应力重新定向导致了多道裂缝的压裂作业的复杂性。本文介绍了实现更一致的压裂执行和提高油井产能所面临的挑战和解决方案。“N”油田的水平井采用“桥塞射孔”方法进行水力压裂,压裂段最多可达4段。近井连接的质量和对复杂近井裂缝几何形状的观察阻碍了远场支撑剂的分布,并限制了裂缝内最大支撑剂浓度。在对这种致密地层进行压裂时,控制与压力相关的多道裂缝的开度是一个关键问题。为了最大限度地减少地层中产生的多重裂缝,实施了工程分解过程和适应的压裂策略。对于早期进行的水力压裂治疗,采用保守的治疗设计,以避免过早筛出导致手术时间增加。实施的解决方案已经证明可以改善近井连接并提高油井产能。成功的结果归功于改进的射孔策略、优化的压裂液性能、设计的压裂分解过程,以及改进决策树的开发。根据油藏条件(如断层、渗透率厚度、接触面)和诊断性注入测试解释的操作条件(如近井弯曲度、净压力),对每口井的水力压裂策略进行了定制。在水力压裂和油田开发中全面实施这些新概念,取得了超出最初预期的积极生产效果。对于与深层低渗透“D”型储层相交的水平井,通过在每个压裂阶段采用校正技术和独特的解决方案,降低了多裂缝的风险和弯曲的影响。
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引用次数: 0
Synthesis and Application of a Low Formation Damage Clay Stabilizer 低地层损害粘土稳定剂的合成与应用
Pub Date : 2022-03-21 DOI: 10.2118/200039-ms
Lei Liang, Yanling Wang, Bin Liu, Yongfei Li, Longhao Tang, B. Bai, Yehui Zhang
To develop a low formation damage clay stabilizer, a kind of organic polyether amine clay stabilizer (OPACS) was synthesized. Compared with the commercial clay stabilizers, the application performance of the OPACS was investigated. OPACS was synthesized with 1, 2-propanediol, 2-(chloromethyl)oxirane and ammonia as main raw materials. The molecular structure of OPACS were characterized by FTIR and NMR, and its anti-swelling performance was tested by centrifugation. Other performance, including its temperature resistance, acid and alkali resistance, elution resistance and etc., were also researched. Different permeability cores were used to test the formation damage of OPACS, and its anti-swelling mechanism was studied by SEM. The FTIR and NMR spectra showed that the expected product structure was synthesized. When the clay stabilizer was adding with 2.0 wt.%, the anti-swelling rate of OPACS was over 90% which was better than the commercial clay stabilizers (about 80%) we bought. At the temperature range of 20 °C-120 °C and the pH range of 2-12, the anti-swelling rate of OPACS changed less than 2.5%. In the long-term efficacy test, the elution recovery rate of OPACS was higher than 92% within the concentration between 0.5 wt.%-3.0 wt.%. Natural cores with different permeability were selected for core flow experiments. The test results showed that the permeability recovery rate of cores were more than 95% treated with OPACS, which meant the formation damage value was less than 5%. From the SEM of clay treated with different clay stabilizers, we could find out the structure of clay treated with OPACS was more compact than those treated with other stabilizers we bought. These results have shown that OPACS can effectively inhibit the water absorption swelling of clay and recovery formation damage, which are helpful to the EOR and friendly to the environment.
为研制低地层损害粘土稳定剂,合成了有机聚醚胺粘土稳定剂。通过与工业粘土稳定剂的比较,研究了OPACS的应用性能。以1,2 -丙二醇、2-(氯甲基)氧环烷和氨为主要原料合成OPACS。通过FTIR和NMR表征了OPACS的分子结构,并通过离心测试了其抗膨胀性能。对其耐温、耐酸、耐碱、耐洗脱等性能进行了研究。采用不同渗透率岩心对OPACS进行了地层损伤测试,并通过扫描电镜对其抗膨胀机理进行了研究。红外光谱和核磁共振光谱表明合成了预期的产物结构。当粘土稳定剂添加量为2.0 wt.%时,OPACS的抗膨胀率可达90%以上,优于我们购买的商品粘土稳定剂(约80%)。在温度为20℃~ 120℃,pH为2 ~ 12的条件下,OPACS的抗膨胀率变化小于2.5%。长期药效试验中,在0.5 wt.% ~ 3.0 wt.%的浓度范围内,OPACS的洗脱回收率大于92%。选取不同渗透率的天然岩心进行岩心流动实验。试验结果表明,经OPACS处理的岩心渗透率恢复率达95%以上,地层损伤值小于5%。通过对不同稳定剂处理过的粘土的SEM分析,发现OPACS处理过的粘土结构比其他稳定剂处理过的粘土更致密。结果表明,OPACS能有效抑制粘土的吸水膨胀和采收率地层损害,有利于提高采收率,对环境友好。
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引用次数: 0
Fines Migration During CO2 Injection: A Review of the Phenomenon and New Breakthrough CO2注入过程中微粒迁移现象综述及新突破
Pub Date : 2022-03-21 DOI: 10.2118/200134-ms
M. A. Md Yusof, Mohamad Arif Ibrahim, Ismail M. Saaid, A. Idris, M. Idress, M. A. Mohamed
Large volume of CO2 injection into the saline aquifer is considered to be the high potential CO2 storage method. Until now, the field of CO2 injectivity has been completely dominated by salt precipitation – and by far the most studied mechanism for the loss of injectivity. In this paper, our aim is to focus on recent findings on CO2 injectivity impairment by fines migration that should not be overlooked. This paper summarizes the state-of-the-art knowledge obtained from theoretical, field studies, and experimental observations on CO2 injectivity impairment by fines migration in saline aquifers in the sense of CO2 storage. By gathering various data from books, DOE papers, field reports and SPE publications, a detailed and high quality data set for fines migration during CO2 injection into saline aquifer is created. Key reservoir/fluid/rock information, operational parameters and petrophysical evaluations are assessments are provided, providing the basis for comprehensive data analysis. The results are presented in terms of boxplot and histogram, where histogram displays the distribution of each parameter and identifies the best suitable ranges for best practices; boxplots are used to detect the special cases and summarize the ranges of each parameter. Previous coreflooding experiments concluded that salt precipitation, mineral precipitation, dissolution and mobilization are the main mechanisms that caused CO2 injectivity impairments. Dissolution of carbonate minerals is dominant and it increases the poro spaces and connectivity of sandstone core samples. Conversely, detachment, precipitation of salt and clay minerals and deposition of fines particles decreases the flow are and even clog the flow paths despite net dissolution. However, the results are case dependent and lack generality in terms of quantifying the petrophysical damage. It has been highlighted that injection scheme (flow rate, time frame), mineral composition (clay content, sensitive minerals), particulate process in porous media (pore geometry, particle and carrier fluid properties), and thermodynamic conditions (pressure, temperature, salinity, CO2 and brine composition) give substantial effect on the fines migration during CO2 injection. Additionally, the current experimental work is limited to rendering time and difficult to identify the dynamic process of fines migration during CO2 injection. A list of potential additional work has therefore been presented in this paper including the establishment of microscopic visualization of CO2-brine-rock interactions with representative pore-network under reservoir pressure and temperature. This is the first paper to summarize the contribution of fines migration on CO2 injectivity impairment in saline aquifer.
大量注入含盐含水层的CO2被认为是高潜力的CO2储存方法。到目前为止,CO2注入领域完全由盐降水主导,也是迄今为止研究最多的注入损失机制。在本文中,我们的目标是集中在最近的研究结果,二氧化碳注入能力的损害,不应忽视的细颗粒迁移。本文总结了从二氧化碳储存的意义上,从理论、实地研究和实验观察中获得的最新知识。通过收集书籍、DOE论文、现场报告和SPE出版物中的各种数据,建立了二氧化碳注入盐水含水层过程中细颗粒迁移的详细和高质量数据集。提供了关键储层/流体/岩石信息、作业参数和岩石物性评价,为综合数据分析提供了依据。结果以箱线图和直方图的形式呈现,其中直方图显示每个参数的分布,并确定最佳实践的最合适范围;箱线图用于检测特殊情况并总结每个参数的范围。以往的岩心驱油实验表明,盐沉淀、矿物沉淀、溶解和动员是导致CO2注入能力受损的主要机制。碳酸盐矿物溶蚀作用占主导地位,增加了砂岩岩心样品的孔隙空间和连通性。相反,分离、盐和粘土矿物的沉淀以及细颗粒的沉积减少了流动,甚至阻塞了流动路径,尽管有净溶解。然而,在量化岩石物理损伤方面,结果是个案性的,缺乏通用性。注入方案(流速、时间框架)、矿物组成(粘土含量、敏感矿物)、多孔介质中的颗粒过程(孔隙几何形状、颗粒和载体流体性质)以及热力学条件(压力、温度、盐度、CO2和盐水组成)对CO2注入过程中的颗粒运移有重要影响。此外,目前的实验工作受渲染时间的限制,难以识别CO2注入过程中细颗粒运移的动态过程。因此,本文提出了一系列潜在的额外工作,包括在储层压力和温度下建立具有代表性孔隙网络的co2 -盐水-岩石相互作用的微观可视化。本文首次总结了细粒运移对含盐含水层CO2注入能力损害的贡献。
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引用次数: 0
Modeling Supercritical CO2 and Hydrocarbon Adsorption in Nanopores 模拟超临界CO2和碳氢化合物在纳米孔中的吸附
Pub Date : 2022-03-21 DOI: 10.2118/200068-ms
A. Haghshenas, Mohammad Hamedpour
Secure storage of carbon dioxide in underground reservoirs has been an increasingly interesting topic for the researches in the recent decade. The literature includes great works covering the idea of storing CO2 in depleted oil and gas fields or deep saline aquifer. In this study, long-term adsorption of CO2 and hydrocarbon gases is discussed as another opportunity to permanently store greenhouse gases and reduce the amount of the carbon dioxide that enters atmosphere. The simplified local-density (SLD) theory was used for matching the experimental data and providing predictions of high-pressure supercritical adsorption isotherms of CO2 and hydrocarbon gases. The SLD model is able to capture the contributions from the fluid-fluid and fluid-solid interactions and, despite the typical assumption of uniform bulk phase density, the model plots the variable density profile of the fluids in nanopore. An extensive set of adsorption measurements available in the literature is used in this evaluation. The slit and cylindrical pore geometry are assessed and the effect of the pressure, temperature, pore size and fluid composition is also discussed in detail. The results show that the SLD-PR model can predict absolute adsorption of the CO2 and hydrocarbon gases within the experimental uncertainty range. For heavier components (C3+), the model illustrates a thicker adsorbed wall close to the pore surface, the adsorption is enhanced while the pressure is increased to a certain point. This observation is in line with the pore-fluid interaction energy which shows a positive trend in terms of molecular size and pressure. In addition, it is concluded that the pore size lower than 2 nm show an exponentially high interest in adsorbing the gas molecules at supercritical conditions. Finally, the results recommend that the simplified local density model gives promising estimates for converting excess adsorption data to absolute adsorption data and calculating the storage capacity of the reservoir rock. Using the outcomes of this study, millions of tons of carbon dioxide can be safely stored in carefully selected high-organic content rocks. The proposed method can also have some applications in predicting the hydrocarbon-in-place and production behavior in shale reservoirs with high organic carbon content.
近十年来,二氧化碳在地下水库中的安全储存已成为研究的热点。这些文献包括一些伟大的作品,涵盖了在枯竭的油气田或深盐水含水层中储存二氧化碳的想法。在本研究中,我们讨论了二氧化碳和碳氢化合物气体的长期吸附,作为永久储存温室气体和减少进入大气的二氧化碳量的另一个机会。采用简化的局部密度(SLD)理论对实验数据进行拟合,并对CO2和烃类气体的高压超临界吸附等温线进行了预测。SLD模型能够捕捉流体-流体和流体-固体相互作用的贡献,并且,尽管典型的假设是均匀的体相密度,该模型绘制了纳米孔中流体的可变密度分布。在此评估中使用了文献中广泛的吸附测量方法。对狭缝孔和圆柱孔的几何形态进行了评价,并详细讨论了压力、温度、孔径和流体成分对孔隙结构的影响。结果表明,SLD-PR模型可以在实验不确定度范围内预测CO2和烃类气体的绝对吸附。对于较重的组分(C3+),模型表明靠近孔表面的吸附壁较厚,当压力增加到一定程度时,吸附增强。这与孔液相互作用能在分子大小和压力方面呈正趋势一致。此外,还得出了在超临界条件下,孔径小于2 nm对气体分子的吸附表现出指数高的兴趣。最后,结果表明,简化的局部密度模型为将过量吸附数据转换为绝对吸附数据和计算储层岩石的存储容量提供了有希望的估计。利用这项研究的结果,数百万吨二氧化碳可以安全地储存在精心挑选的高有机质含量岩石中。该方法在预测高有机碳页岩储层的含油气量和生产动态方面也具有一定的应用价值。
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引用次数: 0
In-Situ Wettability Determination Using Magnetic Resonance Restricted Diffusion 原位润湿性的磁共振限制扩散测定
Pub Date : 2022-03-21 DOI: 10.2118/200167-ms
Azzan Al Yaarubi, Chanh Cao Minh, Nate Bachman, A. Valori, Suryanarayana Guntupalli, Khalsa Al Hadidi
Wettability is a critical reservoir and petrophysical evaluation parameter that is often ignored. Both disciplines often assume the formations are water-wet for simplicity and because wettability measurement on cores often carries a high degree of uncertainty. With the expansion of unconventional carbonate reservoirs development and interest in enhanced oil recovery (EOR), the importance of understanding wettability at the native state and its variability with various injection fluids is becoming critical. For practical purposes, a fast and accurate determination method, ideally at in-situ conditions, is desired. It is widely recognized that nuclear magnetic resonance (NMR) is very sensitive to the strength of the fluid-rock interactions, and therefore, has been long considered as a good candidate for wettability determination. The NMR methodology was first applied in the laboratory using T2 relaxation measurements. For instance, sample wettability is inferred from a shift of the oil peak to shorter T2 values compared with the bulk T2 response of a live oil in the case of oil-wet system. The main practical limitation to the applicability of the T2 shift-based evaluation of wettability is the usually poor separation of oil and water peaks in the T2 spectrum. Furthermore, the bulk T2 of live oils must be measured and the core sample must be perfectly cleaned to quantify the NMR surface relaxation effect. Recently, a method based on two-dimensional mapping of NMR diffusion versus T2 was developed and validated with Amott-Harvey and USBM lab measurements. This method has two advantages. First, separation between the oil and water signals is greatly improved compared with the one-dimensional T2. Second, key properties such as tortuosity, represented by the electrical cementation factor m, and effective surface relaxivity can be inferred from the two-dimensional NMR maps using the restricted-diffusion model. The wettability index can then be estimated from the effective surface relaxivities. The laboratory results on cores suggest that it is possible to obtain reservoir wettability using downhole NMR measurements. This requires high-resolution, high signal-to-noise ratio (SNR) data and improved processing techniques to separate oil and water signals. We examined the NMR restricted-diffusion wettability technique utilizing log data collected in an observation well completed with plastic casing. This well is used to monitor oil desaturation during different phases of an EOR pilot consisting of water, alkaline surfactant (ASP), and polymer floods. A downhole NMR tool that simultaneously records T1, T2 and diffusion at multiple depth of investigation (DOI) was used. This device allowed to periodically collect high-quality NMR data with SNR higher than 50. The targeted reservoir is a sandstone containing hydrocarbon with viscosity of 90 cP. The computed wettability consistently showed mildly oil-wet condition at the selected depth and over the analyzed
润湿性是一个重要的储层和岩石物性评价参数,但往往被忽略。为了简单起见,这两门学科通常都假设地层是水湿的,因为岩心的润湿性测量通常具有很高的不确定性。随着非常规碳酸盐岩储层开发的扩大和对提高采收率(EOR)的兴趣,了解天然状态下的润湿性及其随不同注入流体的变化变得至关重要。为了实际目的,需要一种快速准确的测定方法,理想情况下是在原位条件下。人们普遍认为核磁共振(NMR)对流体-岩石相互作用的强度非常敏感,因此长期以来一直被认为是测定润湿性的良好候选者。核磁共振方法首次应用于实验室,使用T2弛豫测量。例如,在油湿体系中,样品的润湿性可以从油峰值的位移推断为较短的T2值,而不是活体油的总体T2响应。基于T2位移的润湿性评价的适用性的主要实际限制是T2谱中油和水峰的分离通常很差。此外,必须测量活性油的体积T2,并且必须对岩心样品进行完全清洗,以量化核磁共振表面弛豫效应。最近,一种基于核磁共振扩散与T2的二维映射的方法被开发出来,并通过amot - harvey和USBM实验室测量进行了验证。这种方法有两个优点。首先,与一维T2相比,油水信号的分离度大大提高。其次,利用限制扩散模型可以从二维核磁共振图中推断出关键属性,如弯曲度(由电胶结因子m表示)和有效表面弛豫度。然后可以根据有效表面松弛度估算润湿性指数。岩心的实验室结果表明,利用井下核磁共振测量可以获得储层润湿性。这需要高分辨率、高信噪比(SNR)的数据和改进的处理技术来分离油水信号。我们利用在一口塑料套管完井的观测井中收集的测井数据,检验了核磁共振限制扩散润湿性技术。该井用于监测EOR试验中不同阶段的原油脱饱和度,包括水、碱性表面活性剂(ASP)和聚合物驱。井下核磁共振工具可以同时记录T1、T2和多重探测深度(DOI)下的扩散。该装置允许定期收集高质量的核磁共振数据,信噪比高于50。目标储层为含烃的砂岩,黏度为90 cP。在选定的深度和分析的时间间隔内,计算的润湿性一致显示为轻度油湿状态。
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引用次数: 0
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