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A determining method of the water consultancy project quality guarantee deposit considering the contractor's credit level under the incomplete information condition 不完全信息条件下考虑承包商信用水平的供水咨询工程质量保证金确定方法
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29435
Xiangtian Nie, Zihan Chen, Min Li, Bo Wang
This paper studies the quality monitoring decision-making and quality guarantee deposit withhold- ing strategy of the owner in the construction supply chain composed of the owner and the contractor in the engineering construction project under different information environments. Taking the qual- ity monitoring level and quality guarantee deposit retention as the owner’s decision variables and the credit level as the contractor’s decision variables, when the owner’s quality monitoring cost and the contractor’s credit are non-concave and non-convex functions, the optimal solution of the owner’s quality monitoring decision and quality guarantee deposit retention strategy under symmetric information, asymmetric information and incomplete information are deduced by using the maximum principle. Through simulation calculation, the decision results under different information conditions are analyzed. It helps to improve the effectiveness and reliability of the owner’s quality monitoring and realize the expected quality control objectives and quality benefits.
本文研究了不同信息环境下工程建设项目中由业主和承包商组成的施工供应链中业主的质量监控决策和质量保证金扣缴策略。以质量监控水平和质量保证金留存为业主决策变量,信用水平为承包商决策变量,当业主质量监控成本和承包商信用为非凹非凸函数时,得到对称信息下业主质量监控决策和质量保证金留存策略的最优解。利用极大值原理推导了不对称信息和不完全信息。通过仿真计算,分析了不同信息条件下的决策结果。有助于提高业主质量监控的有效性和可靠性,实现预期的质量控制目标和质量效益。
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引用次数: 0
Adsorptive removal of chloroxylenol and chlorophene from aqueous solutions using carbon-halloysite nanocomposites obtained from corrugated cardboard as a carbon precursor 以瓦楞纸板为碳前驱体的碳-高岭土纳米复合材料吸附去除水溶液中的氯二酚和氯苯
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29212
B. Szczepanik, Laura Frydel, P. Słomkiewicz, D. Banaś, I. Stabrawa, A. Kubala-Kukuś
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引用次数: 0
Preparation and adsorption performance of CTMAB-bentonite on landfill leachate ctmab -膨润土的制备及其对垃圾渗滤液的吸附性能
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29486
Hongyu Shi, Yao Zhang, J. Ye, Jiajin Yu, Lijun Luo, Hong Wang, Min Yang, Guizhen Li
The toxic organic pollutant with high concentration in landfill leachate is increasingly harmful to human health. In order to treat landfill leachate more efficiently, a novel cheap organobentonite (CTMAB-bentonite) was successfully prepared from Na-bentonite modified with cetyltrimethylam-monium bromide (CTMAB) as intercalation agent. The CTMAB-bentonite were characterized by X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy, and the effects of contact time, CTMAB concentration, temperature and pH on the adsorption performance were investigated. XRD analysis results showed that CTMAB with concentration of 4 mmol/5 g was successfully intercalated into bentonite, and the layer spacing of CTMAB-bentonite increased by 6 Å than larger that before modification. The adsorption experiment results indicated that the best adsorption time is 60 min, pH and temperature have little effect on the adsorption performance. The adsorption process of landfill leachate conforms to the Freundlich and pseudo-second-order kinetic model, which indicated a multimolecular layer and chemical adsorption, respectively. Thermodynamic parameters confirmed that adsorption process was spontaneous and exothermic. Bentonite modified by CTMAB has a satisfactory adsorption effect on leachate and satisfactory adsorption capacity. CTMAB-bentonite was an excellent adsorbent for removal of landfill leachate which was promising in the field of wastewater treatment.
垃圾渗滤液中高浓度的有毒有机污染物对人体健康的危害日益严重。为了更有效地处理垃圾渗滤液,以十六烷基三甲溴化铵(CTMAB)为插层剂对钠基膨润土进行改性,制备了一种新型廉价的有机膨润土(CTMAB-膨润土)。采用x射线衍射(XRD)和傅里叶变换红外光谱对CTMAB-膨润土进行了表征,考察了接触时间、CTMAB浓度、温度和pH对吸附性能的影响。XRD分析结果表明,浓度为4 mmol/5 g的CTMAB成功嵌入膨润土,CTMAB-膨润土的层间距比改性前增大了6 Å。吸附实验结果表明,最佳吸附时间为60 min, pH和温度对吸附性能影响不大。垃圾渗滤液的吸附过程符合Freundlich和拟二级动力学模型,分别为多分子层吸附和化学吸附。热力学参数证实吸附过程为自发的放热过程。经CTMAB改性的膨润土对渗滤液具有满意的吸附效果和吸附容量。ctmab -膨润土是一种去除垃圾渗滤液的优良吸附剂,在污水处理领域具有广阔的应用前景。
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引用次数: 0
Optimization of chemical oxygen demand removal from petroleum refinery wastewater by electrocoagulation using tubular electrochemical reactor with a novel design 新型管式电化学反应器电絮凝法去除炼油废水中化学需氧量的优化设计
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29139
G. F. Naser, T. Mohammed, A. Abbar
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引用次数: 0
The study on visible photocatalytic activity of an oxalate-extended Pb(II) coordination polymer 草酸延伸型铅(II)配位聚合物可见光催化活性研究
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29546
Jia-Jia Zhang, Yu-Chang Wang, Juan Jin, Wen-Fu Yan, Ying-Chun Guo, Yuan-Peng Wang, Pei-Yu Duan, Li-Xia Yang, Fa-Ju Hou, Jun-Shen Liu
Under the hydrothermal method, a Pb(II) coordination polymer [Pb(ox)(phen) 2 ]·5H 2 O 1 (ox = oxalate, phen = 1,10-phenanthroline) was obtained. Ox ligands exhibit a m 2 -coordination mode, which connect Pb 2+ centers into a 1-D single-chain with ancillary phen molecules. Interestingly, adjacent phen molecules between the chains exist π…π stacking interaction, which extend the 1-D chain into a 2-D supramolecular layer. Compound 1 showed outstanding photocatalytic performance and the degradation efficiency of methylene blue with H 2 O 2 could reach 95.69% under the irradiation of visible light at pH = 10. In addition, 5 cycles of degradation experiments were also carried out, and it was found that the degradation efficiency values with and without H 2 O 2 were reduced by 1.46% and 1.08%, respectively. It was also discussed that which free radical played the dominant role in the photocatalytic process. What’s more, we speculated the possible reaction mechanism based on the Mott–Schottky curve. Meanwhile, the UV visible diffuse reflection of compound 1 was also investigated.
水热法制备了一种Pb(II)配位聚合物[Pb(ox)(phen) 2]·5h2o (ox =草酸盐,phen = 1,10-菲罗啉)。Ox配体呈现m2 -配位模式,将pb2 +中心与辅助性苯分子连接成一维单链。有趣的是,链之间相邻的phen分子存在π…π堆叠相互作用,将一维链扩展到二维超分子层。化合物1表现出优异的光催化性能,在pH = 10的可见光照射下,h2o2对亚甲基蓝的降解效率可达95.69%。此外,还进行了5次循环降解实验,发现有和没有h2o2的降解效率值分别降低了1.46%和1.08%。并讨论了哪些自由基在光催化过程中起主导作用。并根据Mott-Schottky曲线推测了可能的反应机理。同时对化合物1的紫外可见漫反射进行了研究。
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引用次数: 0
Gemini cationic surfactant based 4-(dimethylamino)benzaldehyde: surface characteristics and biological activity, a straightforward one-step synthesis Gemini阳离子表面活性剂基4-(二甲氨基)苯甲醛:表面特性和生物活性,简单一步合成
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29503
M. Bekhit, S. Shafek, M. Younus
A novel three Gemini cationic surfactants was created in this study by one step of alkylating 4-(dimethylamino)benzaldehyde with 1,6-dibromohexane, 1,8-dibromooctane, and 1,10-dibromo-decane in acetone. The chemical structures of the generated cationic surfactants were examined using Fourier-transform infrared spectroscopy and proton nuclear magnetic resonance ( 1 H NMR). After measuring the surface tension at various temperatures, the surface parameters, including the critical micelle concentration (CMC), effectiveness (π CMC ), maximum surface excess (Γ max ), efficiency (Pc 20 ), and minimum surface area ( A min ), were calculated. Adsorption and micellization’s thermodynamic characteristics were calculated, and the results revealed that both processes are sponta-neous. It is clear that the Gemini surfactants created have a high tendency to adsorb at the interfaces as well as micellize in the majority of their solutions. The antibacterial activity of the generated surfactants against Gram-negative, Gram-positive, and fungus was examined. The Gemini surfac-tants’ antibacterial effectiveness was enhanced from 22 to 36 mm by an increase in their hydrophobicity and spacer length.
以1,6-二溴己烷、1,8-二溴辛烷和1,10-二溴癸烷为原料,在丙酮中一步烷基化4-(二甲氨基)苯甲醛,合成了一种新型的三Gemini阳离子表面活性剂。利用傅里叶变换红外光谱和质子核磁共振(1h NMR)对合成的阳离子表面活性剂的化学结构进行了表征。在测量了不同温度下的表面张力后,计算了表面参数,包括临界胶束浓度(CMC)、效率(π CMC)、最大表面过剩(Γ max)、效率(pc20)和最小表面积(A min)。计算了吸附和胶束的热力学特性,结果表明这两个过程都是自发的。很明显,Gemini表面活性剂在大多数溶液中具有很高的界面吸附和胶束倾向。研究了合成的表面活性剂对革兰氏阴性菌、革兰氏阳性菌和真菌的抑菌活性。Gemini表面活性剂的抗菌效果通过疏水性和间隔长度的增加从22 mm提高到36 mm。
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引用次数: 0
Contents Vol. 293 目录第293卷
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29694
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引用次数: 0
Strontium removal from aquatic solution using electric arc furnace slag: kinetic, equilibrium and thermodynamic approach 利用电弧炉渣去除水中锶:动力学、平衡和热力学方法
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29559
Milena Tadić, Irena Nikolić, Nevana Cupara, D. Djurović, I. Milašević
This study investigated strontium removal from aqueous solution using electric arc furnace (EAF) slag. Influence of sorbent dosage (0.5–3 g/L), pH (2.5–9.5), initial concentration of Sr 2+ (50–300 ppm) and temperature (20°C–45°C) was evaluated. Optimal sorbent dosage and initial Sr 2+ concentration were found to be 1.5 g/L and 150 ppm, respectively. Kinetics, equilibrium and thermodynamic models were used to analyse the data. Kinetics of Sr 2+ adsorption onto EAF slag was evaluated using pseudo-first-order and pseudo-second-order models and results have shown that experimental data had a better fit with the pseudo-second-order model. Langmuir and Freundlich isotherm models were used for evaluating the adsorption equilibrium and it has been shown that Langmuir model better described isotherm data. Maximal adsorption capacities of 111.11, 129.87 and 156.25 mg/g were obtained at 20°C, 30°C and 45°C, respectively. Thermodynamic investigation indicated that adsorption of Sr 2+ onto EAF slag is endothermic in nature, spontaneous and more favorable at higher temperatures.
研究了利用电弧炉炉渣去除水溶液中的锶。考察了吸附剂用量(0.5-3 g/L)、pH(2.5-9.5)、Sr 2+初始浓度(50-300 ppm)和温度(20°C - 45°C)的影响。最佳吸附剂投加量为1.5 g/L, sr2 +初始浓度为150 ppm。采用动力学、平衡和热力学模型对数据进行了分析。采用拟一阶和拟二阶模型对电炉渣对Sr 2+的吸附动力学进行了评价,结果表明,实验数据与拟二阶模型吻合较好。采用Langmuir和Freundlich等温线模型评价吸附平衡,结果表明Langmuir模型能较好地描述等温线数据。在20°C、30°C和45°C条件下,吸附量分别为111.11、129.87和156.25 mg/g。热力学研究表明,电炉渣对Sr 2+的吸附本质上是吸热的、自发的,且在较高温度下更有利于吸附。
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引用次数: 0
Biosorption of methylene blue dye using banana floret:: kinetic, equilibrium, thermodynamic and mass transfer studies 香蕉花吸附亚甲基蓝染料的动力学、平衡、热力学和传质研究
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29348
Clint Sutherland, Beverly Chittoo, Vikash Laltoo
Colour removal from effluents remains one of the most challenging requirements faced by indus - tries due to the difficulty of degrading dyes which consequently escape conventional wastewater treatment processes and persist in the environment. This study aimed to assess and optimise the dye adsorption performance of banana floret, a novel biosorbent. Batch experiments were con - ducted to assess the effects of particle size, pH, agitation, temperature, initial concentration and sorbent dose. Kinetic and equilibrium data were modelled, and mass transfer studies were con - ducted to elucidate the mechanisms of biosorption. Equilibrium data were best simulated using the Sips and Langmuir isotherm models. At an optimum pH of 6.0, biosorbent dose of 1.0 mg·L –1 and temperature of 300 K, a maximum sorption capacity of 219 mg·g –1 was observed. The kinetic data were best represented by the pseudo-second-order model. The dominant transport mechanism was attributed to intraparticle diffusion, while the dominant attachment mechanism was phys - ical sorption. The Taguchi method, in combination with analysis of variance, was used to deter - mine the optimum levels of operational parameters for maximising the biosorption of methylene blue by banana floret. The parameter group which produced the highest biosorption capacity and percent removal was determined to be A3-B1-C3 (initial concentration = 200 mg·L –1 , biosorbent dose = 500 mg·L –1 , contact time = 60 min) and A1-B3-C3 (initial concentration = 50 mg·L –1 , biosor - bent dose = 2000 mg·L –1 , contact time = 20 min), respectively. Among these parameters, the initial concentration had the most significant effect on the biosorption capacity, while sorbent dose was most significant on percent removal. A predictive model based on a quadratic equation which incorporates the factor interactions was successfully developed and validated.
由于染料难以降解,因此从废水中去除颜色仍然是工业面临的最具挑战性的要求之一,这些染料因此无法逃脱传统的废水处理工艺并持续存在于环境中。本研究旨在评价和优化新型生物吸附剂香蕉小花对染料的吸附性能。通过批量实验考察了粒径、pH、搅拌、温度、初始浓度和吸附剂用量对吸附效果的影响。对动力学和平衡数据进行了建模,并进行了传质研究以阐明生物吸附的机理。平衡数据用Sips和Langmuir等温线模型模拟效果最好。在最佳pH为6.0、生物吸附剂剂量为1.0 mg·L -1、温度为300 K的条件下,最大吸附量为219 mg·g -1。动力学数据最好用伪二阶模型表示。主要的输运机制是颗粒内扩散,而主要的附着机制是物理吸附。采用田口法,结合方差分析,确定了香蕉小花对亚甲基蓝生物吸附的最佳操作参数水平。结果表明,吸附量和去除率最高的参数组分别为A3-B1-C3(初始浓度= 200 mg·L - 1,生物吸附剂剂量= 500 mg·L - 1,接触时间= 60 min)和A1-B3-C3(初始浓度= 50 mg·L - 1,生物弯曲剂量= 2000 mg·L - 1,接触时间= 20 min)。其中,初始浓度对生物吸附能力的影响最为显著,而吸附剂剂量对去除率的影响最为显著。成功地建立并验证了基于二次方程的综合因素相互作用的预测模型。
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引用次数: 0
Efficient removal of polyethylene and polyvinyl chloride microplastics from water using a modified coagulation process supported by the addition of a surfactant 用添加表面活性剂的改性混凝法有效去除水中的聚乙烯和聚氯乙烯微塑料
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29398
Sabina Ziembowicz, M. Kida, P. Koszelnik
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引用次数: 1
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Desalination and Water Treatment
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